Geochronological problems related to polymetamorphism in the Limpopo Complex, South Africa

The integration of new and published geochronologic data with structural, magmatic/anatectic and pressure–temperature (P–T) process information allow the recognition of high-grade polymetamorphic granulites and associated high-grade shear zones in the Central Zone (CZ) of the Limpopo high-grade terrain in South Africa. Together, these two important features reflect a major high-grade D₃/M₃ event at ~ 2.02 Ga that overprinted the > 2.63 Ga high-grade Neoarchaean D₂/M₂ event, characterized by SW-plunging sheath folds. These major D₂/M₂ folds developed before ~ 2.63 Ga based on U–Pb zircon age data for precursors to leucocratic anatectic gneisses that cut the high-grade gneissic fabric. The D₃/M₃ shear event is accurately dated by U–Pb monazite (2017.1 ± 2.8 Ma) and PbSL garnet (2023 ± 11 Ma) age data obtained from syntectonic anatectic material, and from sheared metapelitic gneisses that were completely reworked during the high-grade shear event. The shear event was preceded by isobaric heating (P = ~ 6 kbar and T = ~ 670–780 °C), which resulted in the widespread formation of polymetamorphic granulites. Many efforts to date high-grade gneisses from the CZ using PbSL garnet dating resulted in a large spread of ages (~ 2.0–2.6 Ga) that reflect the polymetamorphic nature of these complexly deformed high-grade rocks.     

Stages and conditions of metamorphism of mafic granulites in the Early Precambrian complex of the Angara–Kan terrane (southwestern Siberian Craton)

We present results of study of mineral assemblages and PT-conditions of metamorphism of mafic garnet–two-pyroxene and two-pyroxene granulites in the Early Precambrian metamorphic complex of the Angara–Kan terrane as well as the U–Pb age and trace-element and Lu–Hf isotope compositions of zircon from these rocks and the zircon/garnet REE distribution coefficients. The temperatures of metamorphism of two-pyroxene granulites are estimated as 800–870 to ~ 900 °C. Mafic garnet–two-pyroxene granulites contain garnet coronas formed at 750–860 °C and 8–9.5 kbar. The formation of the garnet coronas proceeded probably at the retrograde stage during cooling and was controlled by the rock composition. The age (1.92–1.94 Ga) of zircon cores, which retain the REE pattern typical of magmatic zircon, can be taken as the minimum age of protolith for the mafic granulites. The metamorphic zircon generation in the mafic granulites is represented by multifaceted or soccerball crystals and rims depleted in Y, MREE, and HREE compared to the cores. The age of metamorphic zircon in the garnet–two-pyroxene (~ 1.77 Ga) and two-pyroxene granulites (~ 1.85 and 1.78 Ga) indicates two episodes of high-temperature metamorphism. The presence of one generation (1.77 Ga) of metamorphic zircon in the garnet–two-pyroxene granulites and, on the contrary, the predominance of 1.85 Ga zircon in the two-pyroxene granulites with single garnet grains suggest that the formation of the garnet coronas proceeded at the second stage of metamorphism. The agreement between the zircon/garnet HREE distribution coefficients and the experimentally determined values at 800 °C suggests the simultaneous formation of ~ 1.77 Ga metamorphic zircon and garnet. Zircon formation by dissolution/reprecipitation or recrystallization in a closed system without exchange with the rock matrix is confirmed by the close ranges of ¹⁷⁶Hf/¹⁷⁷Hf values for the core and rims. The positive ε_Hf values (up to + 6.2) for the zircon cores suggest that the protolith of mafic granulites are derived from depleted-mantle source. The first stage of metamorphism of the mafic granulites and paragneisses of the Kan complex (1.85–1.89 Ga) ended with the formation of collisional granitoids (1.84 Ga). The second stage (~ 1.77 Ga) corresponds to the intrusion of the second phase of subalkalic leucogranites of the Taraka pluton and charnockites (1.73–1.75 Ga).     

P–T conditions of the cratonic rocks and Eastern Ghats granulites along the Eastern Ghats Frontal Thrust,Jeypore (Orissa), India

The Eastern Ghats Frontal Thrust (EGFT) demarcates the boundary between the Archaean/Paleoproterozoic cratonic rocks to the west, and the Meso/Neoproterozoic granulites of the Eastern Ghats Mobile Belt (EGMB) to the east. At Jeypore (Orissa, India), mafic schists and granites of the cratonic domain document a spatial increase in the metamorphic grade from greenschist facies (garnet, clinozoisite – absent varieties) in the foreland to amphibolite facies (clinozoisite- and garnet-bearing variants) progressively closer to the EGFT. Across the EGFT, the enderbite–charnockite gneisses and mafic granulites of EGMB preserves a high-grade granulite facies history; amphibolite facies overprinting in the enderbite–charnockite gneisses at the cratonic fringe is restricted to multi-layered growth of progressively Al, Ti – poor hornblende at the expense of pyroxene and plagioclase. In associated mafic granulites, the granulite facies gneissic layering is truncated by sub-centimeter wide shear bands defined by synkinematic hornblende + quartz intergrowth, with post-kinematic garnet stabilized at the expense of hornblende and plagioclase. Proximal to the contact, these granulites of the Eastern Ghats rocks are intruded by dolerite dykes. In the metadolerites, the igneous assemblage of pyroxene–plagioclase is replaced by intergrown hornblende + quartz ± calcite that define the thrust-related fabric and are in turn mantled by coronal garnet overgrowth, while scapolite is stabilized at the expense of recrystallized plagioclase and calcite. Petrogenetic grid considerations and thermobarometry of the metamorphic assemblages in metadolerites intrusive into granulites and mafic schists within the craton confirm that the rocks across the EGFT experienced prograde heating (T_max value ∼650–700 °C at P ∼ 6–8 kbar) along the prograde arm of a seemingly clockwise P–T path. Since the dolerites were emplaced post-dating the granulite facies metamorphism, the prograde heating is correlated with renewed metamorphism of the granulites proximal to the EGFT. A review of available age data from rocks neighboring the EGFT suggests that the prograde heating of the cratonic granites and the re-heating of the Eastern Ghats granulites are Pan – African in age. The re-heating may relate to an Early Paleozoic Pan-Gondwanic crustal amalgamation of older terrains or reactivation along an old suture.     

Metamorphic P–T path of mafic granulites from Eastern Hebei: Implications for the Neoarchean tectonics of the Eastern Block,North China Craton

This study documents the metamorphic evolution of mafic granulites from the Eastern Hebei Complex in the Eastern Block of the North China Craton. Mafic granulites from Eastern Hebei occur as boudins or enclaves within Neoarchean high-grade TTG gneisses. Petrographic observations reveal three characteristic metamorphic mineral assemblages in the mafic granulites: the pre-peak hornblende + plagioclase + ilmenite + quartz + sphene assemblage (M₁) existing as mineral inclusions within coarse-grained peak assemblage (M₂) represented by garnet + clinopyroxene + orthopyroxene + plagioclase + hornblende + ilmenite + quartz, and post-peak assemblage (M₃) marked by garnet + quartz ± ilmenite symplectites surrounding the peak pyroxene and plagioclase. Based on pseudosection modeling calculated in the NCFMASHTO model system using the program THERMOCALC, P–T conditions of the pre-peak (M₁), peak (M₂) and post-peak (M₃) assemblages are constrained at 600–715 °C/6.0 kbar or below, 860–900 °C/9.6–10.3 kbar, and 790–810 °C/9.6–10.4 kbar, respectively. These P–T estimates, combined with their mineral compositions and reaction relations, define an anticlockwise P–T path incorporating isobaric cooling subsequent to the peak medium-pressure granulite-facies metamorphism for the mafic granulites from Eastern Hebei. Such an anticlockwise P–T path suggests that the end-Neoarchean metamorphism of the Eastern Hebei Complex correlated closely with underplating and intrusion of voluminous mantle-derived magmas. In conjunction with other geological considerations, a mantle-plume model is favored to interpret the Neoarchean tectonothermal evolution of the Eastern Hebei Complex and other metamorphic complexes in the Eastern Block. The prograde amphibolite-facies metamorphism (M₁) was initiated due to the upwelling of the relatively cooler mantle plume head, followed by the peak medium-pressure granulite-facies metamorphism (M₂) as triggered by the uprising hotter plume “tail”, and finally when plume activity ceased, the heated metamorphic crust experienced nearly isobaric cooling (M₃).     

The Meso-Neoarchaean Belomorian eclogite province: Tectonic position and geodynamic evolution

The aim of this paper is to review the main features of the Meso-Neoarchaean Belomorian eclogite province (BEP) in the northeastern Fennoscandian Shield, including regional and local geology, geochemistry, petrology and geochronology and to compare the Belomorian eclogites with Precambrian eclogites elsewhere. Two eclogite associations have been recognized within Belomorian TTG gneisses: (1) the subduction-type Salma association and (2) Gridino eclogitized mafic dykes. Protoliths of the Salma eclogites represent a sequence comprising gabbro, Fe–Ti gabbro and troctolites, formed at ~ 2.9 Ga in a slow-spreading ridge setting (like the Southwest Indian Ridge). The main subduction and eclogite-facies events occurred between ~ 2.87 and ~ 2.82 Ga. Injection of mafic magma into an active continental margin setting, recorded by the Gridino dyke swarm, is attributed to subduction of a mid-ocean ridge, commencing at 2.87 Ga. Crustal delamination of the active margin and subsequent involvement of the lower crust in subduction between 2.87 and 2.82 Ga ago caused high-pressure metamorphism of the Gridino dykes, culminating in eclogite-facies conditions between 2.82 and 2.78 Ga and accompanying amalgamation of the Karelia, Kola and Khetolamba blocks and formation of the Mesoarchaean Belomorian accretionary–collisional orogen. The clockwise P–T paths of the Salma and Gridino associations cross the granulite-facies P–T field. Detailed metamorphic studies indicate a complicated post-eclogite history with thermal events and fluid infiltration, related to plume activity at 2.72–2.70, ~ 2.4 and ~ 1.9 Ga. The eclogite assemblages were exhumed to mid-to-lower crustal depths at ~ 1.7 Ga, while erosion or younger tectonic events were responsible for final exhumation to the surface. Comparison of P–T–t paths and data for peak metamorphic parameters demonstrates the general similarity of the Archaean and Palaeoproterozoic eclogites worldwide and their association with anomalously “hot” environments. The occurrence of high-T conditions during eclogite-facies metamorphism can be attributed to either subduction of a mid-ocean ridge (Archaean, BEP) or to interaction with mantle plumes (Proterozoic).     

Metamorphic evolution of the Maud Belt: P–T–t path for high-grade gneisses in Gjelsvikfjella,Dronning Maud Land,East Antarctica

A metamorphic petrological study, in conjunction with recent precise geochronometric data, revealed a complex P–T–t path for high-grade gneisses in a hitherto poorly understood sector of the Mesoproterozoic Maud Belt in East Antarctica. The Maud Belt is an extensive high-grade, polydeformed, metamorphic belt, which records two significant tectono-thermal episodes, once towards the end of the Mesoproterozoic and again towards the late Neoproterozoic/Cambrian. In contrast to previous models, most of the metamorphic mineral assemblages are related to a Pan-African tectono-thermal overprint, with only very few relics of late Mesoproterozoic granulite-facies mineral assemblages (M₁) left in strain-protected domains. Petrological and mineral chemical evidence indicates a clockwise P–T–t path for the Pan-African orogeny. Peak metamorphic (M_2b) conditions recorded by most rocks in the area (T = 709–785 °C and P = 7.0–9.5 kbar) during the Pan-African orogeny were attained subsequent to decompression from probably eclogite-facies metamorphic conditions (M_2a).The new data acquired in this study, together with recent geochronological and geochemical data, permit the development of a geodynamic model for the Maud Belt that involves volcanic arc formation during the late Mesoproterozoic followed by extension at 1100 Ma and subsequent high-grade tectono-thermal reworking once during continent–continent collision at the end of the Mesoproterozoic (M₁; 1090–1030 Ma) and again during the Pan-African orogeny (M_2a, M_2b) between 565 and 530 Ma. Post-peak metamorphic K-metasomatism under amphibolite-facies conditions (M_2c) followed and is ascribed to post-orogenic bimodal magmatism between 500 and 480 Ma.     

Detrital zircon U–Pb age and Hf isotope constrains on the generation and reworking of Precambrian continental crust in the Cathaysia Block,South China: A synthesis

The South China Block, consisting of the Yangtze and the Cathaysia blocks, is one of the largest Precambrian blocks in eastern Asia. However, the early history of the Cathaysia Block is poorly understood due largely to intensive and extensive reworking by Phanerozoic polyphase orogenesis and magmatism which strongly overprinted and obscured much of the Precambrian geological record. In this paper, we use the detrital zircon U–Pb age and Hf isotope datasets as an alternative approach to delineate the early history of the Cathaysia Block. Compilation of published 4041 Precambrian detrital zircon ages from a number of (meta)sedimentary samples and river sands exhibits a broad age spectrum, with three major peaks at ~ 2485 Ma, ~ 1853 Ma and ~ 970 Ma (counting for ~ 10%, ~ 16% and ~ 24% of all analyses, respectively), and four subordinate peaks at ~ 1426 Ma, ~ 1074 Ma, ~ 780 Ma and ~ 588 Ma. Five of seven detrital zircon age peaks are broadly coincident with the crystallisation ages of ~ 1.89–1.83 Ga, ~ 1.43 Ga, ~ 1.0–0.98 Ga and ~ 0.82–0.72 Ga for known igneous rocks exposed in Cathaysia, whereas, igneous rocks with ages of ~ 2.49 Ga and ~ 0.59 Ga have not yet been found. The Hf isotopic data from 1085 detrital zircons yield Hf model ages (T_DM^C) between ~ 4.19 Ga and ~ 0.81 Ga, and the calculated εHf(t) values between − 40.2 and 14.4. The Archean detrital zircons are exclusively oval in shape with complicated internal textures, indicating that they were sourced by long distance transportations and strong abrasion from an exotic Archean continent. In contrast, the majority of detrital zircons in age between ~ 1.9 and ~ 0.8 Ga are euhedral to subhedral crystals, indicative of local derivation by short distance transportations from their sources. The oldest crustal basement rocks in Cathaysia were most likely formed by generation of juvenile crust and reworking of recycled Archean components in Late Paleoproterozoic at ~ 1.9–1.8 Ga, rather than in the Archean as previously speculated. Reworking and recycling of the continental crust are likely the dominant processes for the crustal evolution of Cathaysia during the Mesoproterozoic to Neoproterozoic time, with an intervenient period of significant generation of juvenile crust at ~ 1.0 Ga.Precambrian crustal evolutions of the Cathaysia Block are genetically related to the supercontinent cycles. By comparing detrital zircon data from Cathaysia with those for other continents, and integrating multiple lines of geological evidence, we interpret the Cathaysia Block as an orogenic belt located between East Antarctica, Laurentia and Australia during the assembly of supercontinent Columbia/Nuna at ~ 1.9–1.8 Ga. The Cathaysia Block amalgamated with the Yangtze Block to form the united South China Block during the Sibao Orogeny at ~ 1.0–0.89 Ga. The Laurentia–Cathaysia–Yangtze–Australia–East Antarctica connection gives the best solution to the paleo-position of Cathaysia in supercontinent Rodinia. The significant amount of ~ 0.6–0.55 Ga detrital zircons in Cathaysia and West Yangtze have exclusively high crustal incubation time of > 300 Ma, indicating crystallisation from magmas generated dominantly by crustal reworking. This detrital zircon population compares well with the similar-aged zircon populations from a number of Gondwana-derived terranes including Tethyan Himalaya, High Himalaya, Qiangtang and Indochina. The united South China–Indochina continent was likely once an integral part of Gondwanaland, connected to northern India by a “Pan-African” collisional orogen.     

Timing of metamorphism in the Paleoproterozoic Jiao-Liao-Ji Belt: New SHRIMP U–Pb zircon dating of granulites,gneisses and marbles of the Jiaobei massif in the North China Craton

The Paleoproterozoic Jiao-Liao-Ji Belt lies in the Eastern Block of the North China Craton, with its southern segment extending across the Bohai Sea into the Jiaobei massif. High-pressure pelitic and mafic granulites have been recently recognized in the Paleoproterozoic Jingshan Group (Jiaobei massif). New SHRIMP U–Th–Pb geochronology combined with cathodoluminescence (CL) imaging of zircon has been applied to the determination of the timing of the metamorphism of the high-temperature and high-pressure granulites and associated gneisses and marbles. Metamorphic zircons in these high-pressure granulites, gneisses and marbles occur as either single grains or overgrowth (or recrystallization) rims surrounding and truncating oscillatory-zoned magmatic zircon cores. Metamorphic zircons are all characterized by nebulous zoning or being structureless, with high luminescence and relatively low Th/U values. Metamorphic zircons from two high-pressure mafic granulites yielded ²⁰⁷Pb/²⁰⁶Pb ages of 1956 ± 41 Ma and 1884 ± 24 Ma. One metamorphic zircon from a garnet–sillimanite gneiss also gave an apparent ²⁰⁷Pb/²⁰⁶Pb age of 1939 ± 15 Ma. These results are consistent with interval of ages of c. 1.93–1.90 Ga already obtained by previous studies for the North and South Liaohe Groups and the Laoling Group in the northern segment of the Jiao-Liao-Ji Belt. Metamorphic zircons from a high-pressure pelitic granulite and two pelitic gneisses yielded weighted mean ²⁰⁷Pb/²⁰⁶Pb ages of 1837 ± 8 Ma, 1821 ± 8 Ma and 1836 ± 8 Ma respectively. Two diopside–olivine–phlogopite marbles yielded weighted mean ²⁰⁷Pb/²⁰⁶Pb ages of 1817 ± 9 Ma and 1790 ± 6 Ma. These Paleoproterozoic metamorphic ages are largely in accordance with metamorphic ages of c. 1.85 Ga produced from the Ji'an Group in the northern segment of the Jiao-Liao-Ji Belt and c. 1.86–1.80 Ga obtained for the high-pressure pelitic granulites from the Jingshan Group in the southern segment. As this metamorphic event was coeval with the emplacement of A-type granites in the Jiao-Liao-Ji Belt and its adjacent areas, it is interpreted as having resulted from a post-orogenic or anorogenic extensional event.     

Petrogenesis of Derraman Peralkaline granite (Oulad Dlim Massif,West African Craton Margin,Morocco): New constraints from zircon Hf and O isotopic compositions

The Archean Bulautad gneisses in the East of the Ouled Dlim domain adjacent to the Reguibat Rise (West African Craton, Southern Morocco) are intruded by peralkaline A-type granites. These granites form two kilometer-sized bodies, North Derraman and Derraman Highs, and a few small satellites. Prior studies have shown that the chemical and mineralogical compositions of these granites are remarkably uniform, and the North Derraman and Derraman Highs are hypersolvus aegirine–riebeckite granites. The North Derraman granite is intruding the ca. 3.12 Ga Bulautad gneisses while the Derraman High body is emplaced within the ca. 2.84 Ga Leglat schists. Here we present new zircon oxygen and hafnium isotopes data that help to understand the nature of the granite magmatic sources. We analyzed 20 Zircons from one sample in the North Derraman granite core. The zircons have an average δ¹⁸O of 5.26 ± 0.22, similar to that of mantle zircons. Their ɛHf525Ma is negative between–3.8 and–11.1 with an average of–6.8 ± 0.7, and their Hf model age is ca. 1.8 Ga, similar to the available whole-rock Nd model age. Combined with previous whole-rock major and trace element studies, our new data suggest that the Derraman granite magmatic sources were ca. 1.8 Ga crustal fenites that formed by refertilization of lower crust granulites by mantle-derived alkaline melts and fluids, likely during the Paleoproterozoic alkaline magmatism that gave rise to the neighboring ca. 1.8 Ga Gleibat Lafhouda carbonatites. The so-generated fenites likely remained undisturbed in the crust until the Middle Cambrian, when they remelted during the rifting event that affected the northern Gondwana at that time.     

A review of the pressure–temperature–time evolution of the Limpopo Belt: Constraints for a tectonic model

Published literature argues that the Limpopo Belt can be subdivided into three zones, each with a distinctive geological character and tectono-metamorphic fingerprint. There are currently two contrasting schools of thought regarding the tectono-metamorphic evolution of the CZ. One camp argues that geochronological, structural and prograde pressure–temperature (P–T) evidence collectively indicate that the CZ underwent tectono-metamorphism at ca. 2.0 Ga which followed a clockwise P–T evolution during a transpressive orogeny that was initiated by the collision of the Kaapvaal and Zimbabwe cratons. Deformation and metamorphism consistent with this scenario are observed in the southern part of the NMZ but are curiously absent from the whole of the SMZ. The opposing view argues that the peak metamorphism associated with the collision of the Kaapvaal and Zimbabwe cratons occurred at ca. 2.6 Ga and the later metamorphic event is an overprint associated with reactivation along Archean shear zones. Post-peak-metamorphic conditions, which at present cannot be convincingly related to either a ca. 2.6 or 2.0 Ga event in the CZ reveal contrasting retrograde paths implying either near-isothermal decompression and isobaric cooling associated with a ‘pop-up’ style of exhumation or steady decompression–cooling linked to exhumation controlled by erosion. Recent data argue that the prograde evolution of the ca. 2.0 Ga event is characterised by isobaric heating prior to decompression–cooling. Contrasting P–T paths indicate that either different units exist within the CZ that underwent different P–T evolutions or that some P–T work is erroneous due to the application of equilibrium thermobarometry to mineral assemblages that are not in equilibrium. The morphology of the P–T path(s) for the ca. 2.6–2.52 Ga event are also a matter of dispute. Some workers have postulated an anticlockwise P–T evolution during this period whilst others regard this metamorphic event as following a clockwise evolution. Granitoid magmatism is broadly contemporaneous in all three zones at ca. 2.7–2.5 suggesting a possible causal geodynamic link. P–T contrasts between and within the respective zones prevent, at present, the construction of a coherent and inter-related tectonic model that can account for all of the available evidence. Detailed and fully-integrated petrological and geochronological studies are required to produce reliable P–T–t paths that may resolve some of these pertinent issues.     

Isotope (U–Pb,Sm–Nd,Rb–Sr) geochronology of alkaline basic plutons of the Kuznetsk Alatau

On the northeastern slope of the Kuznetsk Alatau, small differentiated alkaline basic intrusive massifs form an isometric area ~ 100 km across. They are composed of subalkalic and alkali gabbroids, basic and ultrabasic foidolites, nepheline and alkali syenites, and carbonatites. Results of complex (U–Pb, Sm–Nd, and Rb–Sr) isotope dating suggest that alkaline basic magmatism developed at two stages, in the Middle Cambrian–Early Ordovician (~ 510–480 Ma) and in the Early–Middle Devonian (~ 410–385 Ma). Finding of accessory zircons (age 1.3–2.0 Ga) in alkaline rocks suggests that the ascent of mantle plume was accompanied by the melting of fragments of Proterozoic mature continental crust composing the basement of the Caledonian orogen of the Kuznetsk Alatau. Probably, parental Cambrian–Ordovician alkaline mafic melts initiated metasomatism and lithosphere erosion. During the next melting of lithosphere substrate in ~ 100 Myr, this caused the generation of magmas of similar composition with inherited isotope parameters (ε_Nd(T) ≈ + 4.8 to + 5.7, T_Nd(DM) ≈ 0.8–0.9 Ga) pointing to the similar nature of their matter sources in the moderately depleted mantle.     

Ra-partitioning between phlogopite and silicate melt and 226Ra/Ba–230Th/Ba isochrons

In this study we experimentally determine phlogopite/melt partition coefficients of Ra and other trace elements in a lamproitic system. This work was achieved using an analytical technique (LA-ICP-MS) with low detection limits (~ 0.01 fg) permitting the measurement of the very low Ra concentrations feasible in experiments (~ 1 ppb). D_Ra^{phlogopite/melt} was determined to 2.28 ± 0.44 and 2.84 ± 0.47 in two experiments, the ratio D_Ra/D_Ba is around 1.6. The compatibility of Ra in phlogopite results from an ionic radius being close to the apex of the lattice strain parabola for earth alkalis in the large XII-coordinated interlayer site of phlogopite. A re-evaluation of D_Ra and D_Ra/D_Ba for magmatic minerals containing appreciable Ra, yields D_Ra^mineral/melt ranging from ~ 2.6 for phlogopite down to 2–3 ? 10^? 5 for pyroxenes, and D_Ra/D_Ba^mineral/melt from ~ 4 for leucite to 2 ? 10^? 2 for orthopyroxene. The influence of melt composition on D_Ra/D_Ba is less than 10%. All investigated minerals have different D_Ra/D_Ba, strongly fractionating Ra from Ba. Thus, for magmatic systems, (²²⁶Ra)/Ba in the various minerals is not constant, these minerals do not form a straight line in the (²²⁶Ra)/Ba–(²³⁰Th)/Ba system at the time of crystallization and thus, there is no (²²⁶Ra)/Ba–(²³⁰Th)/Ba isochron at t₀. ²²⁶Ra–²³⁰Th–Ba mineral dating is thus applicable only to model ages calculated from mineral–glass pairs with known D_Ra.     

Zircon ages and Hf isotopic constraints on sources of clastic metasediments of the Slyudyansky high-grade complex,southeastern Siberia: Implication for continental growth and evolution of the Central Asian Orogenic Belt

We present results of combined in situ U–Pb dating of detrital zircons and zircon Hf and whole-rock Nd isotopic compositions for high-grade clastic metasedimentary rocks of the Slyudyansky Complex in eastern Siberia. This complex is located southwest of Lake Baikal and is part of an early Paleozoic metamorphic terrane in the eastern part of the Central Asian Orogenic Belt (CAOB). Our new zircon ages and Hf isotopic data as well as whole-rock Nd isotopic compositions provide important constraints on the time of deposition and provenance of early Paleozoic high-grade metasedimentary rocks as well as models of crustal growth in Central Asia. Ages of 0.49–0.90 Ga for detrital zircons from early Paleozoic high-grade clastic sediments indicate that deposition occurred in the late Neoproterozoic and early Paleozoic, between ca. 0.62–0.69 and 0.49–0.54 Ga. Hf isotopic data of 0.82–0.69 Ga zircons suggest Archean and Paleoproterozoic (ca. 2.7–2.8 and 2.2–2.3 Ga; Hfc = 2.5–3.9 Ga) sources that were affected by juvenile 0.69–0.82 Ga Neoproterozoic magmatism. An additional protolith was also identified. Its zircons yielded ages of 2.6–2.7 Ga, and showed high positive ε_Hf(t) values of +4.1 to +8.0, and Hf model ages t_Hf(DM) = t_Hfc = 2.6–2.8 Ga, which is nearly identical to the crystallization ages. These isotopic characteristics suggest that the protolith was quite juvenile. The whole-rock Nd isotopic data indicate that at least part of the Slyudyansky Complex metasediments was derived from “non-Siberian” provenances. The crustal development in the eastern CAOB was characterized by reworking of the early Precambrian continental crust in the early Neoproterozoic and the late Neoproterozoic–early Paleozoic juvenile crust formation.     

Reprint of “Depositional environment and tectonic implications of the Paleoproterozoic BIF in Changyi area,eastern North China Craton: Evidence from geochronology and geochemistry of the metamorphic wallrocks”

The Changyi banded iron formation (BIF) in the eastern North China Craton (NCC) occurs within the Paleoproterozoic Fenzishan Group. Three types of metamorphic wallrocks interbedded with the BIF bands are identified, including plagioclase gneisses and leptynites, garnet-bearing gneisses and amphibolites. Protolith reconstruction suggests that the protoliths of the plagioclase gneisses and leptynites are mainly graywackes with minor contribution of pelitic materials, the garnet-bearing gneisses are Fe-rich pelites contaminated by clastics, and the amphibolites are tholeiitic rocks. Trace elements of La, Th, Sc and Zr of the plagioclase gneisses and leptynites and the garnet-bearing gneisses support that these meta-sedimentary rocks were probably derived from recycling of Archean rocks with felsic and mafic materials differentiated into different rock types. ²⁰⁷Pb/²⁰⁶Pb ages of detrital zircons from the meta-sedimentary rocks concentrate at 2.7–3.0 Ga, confirming their derivation from the Archean rocks. The presence of several Paleoproterozoic detrital zircons (2240 to 2246 Ma), however, also suggests minor involvement of Paleoproterozoic materials. The Archean detrital zircons have ε_Hf(t) values varying from − 0.7 to 7.6, which mainly fall between the 3.0 Ga and 3.3 Ga average crustal evolution lines on the age vs. ε_Hf(t) diagram, further illustrating that the rocks providing materials for the meta-sedimentary rocks mainly originated from partial melting of a Mesoarchean crust. This is strongly supported by their crust-like trace element distribution patterns (such as Nb, Ta, P and Ti depletion) and ancient Nd depleted mantle model ages (T_DM = 2.9–3.4 Ga). In addition, the remarkably high ε_Hf(t) values (7.5 to 9.3) of the Paleoproterozoic detrital zircons constrain the Paleoproterozoic materials to originate from a depleted mantle. The amphibolites show low SiO₂ (46.5 to 52.8 wt.%) and high MgO (5.68 to 10.9 wt.%) contents, crust-like trace element features and low ε_Nd(t) values (− 4.5 to − 0.3), suggesting that these ortho-metamorphic rocks were mainly derived from subcontinental lithospheric mantle with some contamination by Archean crustal materials. Since an intra-continental environment was required for the formation of the above metamorphic rocks, these rocks not only confine the depositional environment of the Changyi BIF to be an intra-continental rift, but also support the rifting processes of the eastern NCC during Paleoproterozoic.     

Ultrahigh-temperature metamorphism and anticlockwise P–T–t path of Paleozoic granulites from north Qinling-Tongbai orogen,Central China

Mafic and semi-pelitic granulites from the Qinling-Tongbai orogen in central China preserve petrological evidence and mineral paragenesis suggesting four distinct stages of metamorphic evolution. The prograde history (M₁) is recorded by the occurrence of cordierite, orthopyroxene and biotite inclusions in garnet porphyroblasts of the peak-metamorphic (M₂) assemblage. Peak-metamorphism was followed by cooling with minor decompression (M₃), which formed symplectites and coronitic textures. The greenschist facies retrograde metamorphic assemblage (M₄) is represented by hydrous minerals replacing minerals of the M₂ and M₃ assemblages. We present LA-ICPMS zircon U-Pb data which show ages of 432 ± 4 Ma for the peak metamorphism and 403 to 426 Ma for the retrograde stage. Microstructural analysis, P–T pseudosections, and mineral isopleths in conjunction with the zircon U-Pb ages define an anticlockwise P–T–t path. The P–T estimates for peak metamorphic conditions of 880–920 °C and 8.0–10 kbar suggest that these rocks witnessed extreme crustal metamorphism under ultrahigh-temperature conditions. The anticlockwise trajectory reported in this study is comparable with similar P–T paths recorded from subduction–collision settings, and correlate the Tongbai granulites to hot orogens developed within a Paleozoic collisional suture. We propose a ridge subduction and slab window setting to explain the formation of the Tongbai orogen, in a convergent plate setting associated with the northward subduction of the Paleo-Tethyan Qinling Ocean.     

Archaean to Palaeoproterozoic high-grade evolution of the Belomorian eclogite province in the Gridino area,Fennoscandian Shield: Geochronological evidence

The Belomorian eclogite province was repeatedly affected by multiple deformation episodes and metamorphism under moderate to high pressure. Within the Gridino area, high pressure processes developed in a continental crust of tonalite–trondhjemite–granodiorite (TTG) affinity that contains mafic pods and dykes, in which products of these processes are most clearly evident. New petrological, geochemical and geochronological data on mafic and felsic rocks, including PT-estimates, mineral chemistry, bulk rock chemistries, REE composition of the rocks and zircons and U–Pb and Lu–Hf geochronology presented in the paper make it possible to reproduce the magmatic and high-grade metamorphic evolution in the study area. In the framework of the extremely long-lasting geologic history recorded in the Belomorian province (3–1.7 Ga), new geochronological data enabled us to define the succession of events that includes mafic dyke emplacement between 2.87 and 2.82 Ga and eclogite facies metamorphism of the mafic dykes between ~ 2.82 and ~ 2.72 Ga (most probably in the time span of 2.79–2.73 Ga). The clockwise PT path of the Gridino association crosses the granulite- and amphibolite-facies PT fields during the time period of 2.72 Ga to 2.64 Ga. A special aspect of this work concerns the superposed subisobaric heating (thermal impact) with an increase in the temperature to granulite facies conditions at 2.4 Ga. Later amphibolite facies metamorphism occurred at 2.0–1.9 Ga. Our detailed geochronological and petrological studies reveal a complicated Mesoarchaean–Palaeoproterozoic history that involved deep subduction of the continental crust and a succession of plume-related events.     

Conflicting P–T paths within the Central Zone of the Limpopo Belt: A consequence of different thermobarometric methods?

A single metapelitic sample from the Verbaard locality, near Messina was investigated in order to construct a P–T path and moreover, highlight pertinent contradictions in the current P–T database. Interpretations based on P–T pseudosections, garnet isopleth thermobarometry and mineral mode/isopleth modelling indicate that the mineral assemblages, textures and zonations developed in the metapelite formed along a single clockwise P–T path. The metamorphic evolution is characterized by an early high-pressure phase at 10–11 kbar/800 °C, followed by a simultaneous pressure decrease and temperature increase to ∼8/850 °C and subsequent retrogression via decompression-cooling to 4–5 kbar at T < 650 °C. Growth zoning in garnet provides evidence for an earlier, prograde history, however, as potential melt-loss was not accounted for this must be deemed speculative. The results of this study agree entirely with that of [Zeh, A., Klemd, R., Buhlmann, S., Barton, J.M. 2004. Pro- and retrograde P–T evolution of granulites of the Beit Bridge Complex (Limpopo Belt, South Africa); constraints from quantitative phase diagrams and geotectonic implications. Journal of Metamorphic Geology 22, 79–95], who adopted a similar approach to thermobarometry i.e. pseudosections. The results are, however, inconsistent with recent publications that argue for a twofold, metamorphic history defined by two decompression-cooling paths (DC1 ∼2.6 Ga and DC2 ∼2.0 Ga) that are separated by an isobaric heating path (∼2.0 Ga). The disparity in the results obtained from different workers can be explained by an examination of the thermobarometric methods employed. The methodology employed to derive the twofold, polymetamorphic P–T path appears to be erroneous. At present, the most reliable and robust method for determining P–T paths is the pseudosection approach to thermobarometry. Future modelling of Limpopo Belt granulites should adopt this strategy and ensure potential melt-loss is taken into account. Alternatively, this potential problem can be avoided altogether by investigating rocks of mafic composition.     

Zircon ages and Nd–Hf isotopes in UHT granulites of the Ider Complex: A cratonic terrane within the Central Asian Orogenic Belt in NW Mongolia

The Ider Complex of the Tarbagatai Block in northwestern Mongolia is part of a Precambrian microcontinental terrane in the Central Asian Orogen Belt and has experienced a polymetamorphic tectono-metamorphic evolution. We have investigated an enderbitic gneiss, derived from a quartz diorite and a charnockite, derived from a leucogranite, and zircon SHRIMP data reveal late Archaean protolith ages of 2520–2546 Ma for these rocks. Metamorphic overgrowth on these zircons as well as newly-formed metamorphic zircons document a high-temperature metamorphic event (T = 930–950 °C) at about 1855–1860 Ma. Nd whole-rock isotopic systematics show these and other gneisses of the Ider Complex straddling the CHUR-line in a Nd isotope evolution diagram, suggesting both crustal reworking and input of some juvenile material, with Nd model ages ranging between ca. 2.5 and 3.1 Ga. Hf-in-zircon isotopic data provide a similar pattern and also yielded Archaean Hf crustal model ages. The metamorphic zircons seem to have inherited their Hf isotopic composition from the igneous grains, suggesting a complex process of dissolution, transportation, and re-precipitation involving a fluid phase during high-grade metamorphism. The zircon age patterns do not make it possible to unambiguously assign the Tarbagatai Block to any of the cratons bordering the Central Asian Orogenic Belt, since age peaks at ca. 2520–2550 and ca. 1860 Ma are common in the Siberian, North China and Tarim cratons.     

Tectono-magmatic evolution of the Gaoligong belt,southeastern margin of the Tibetan plateau: Constraints from granitic gneisses and granitoid intrusions

The Gaoligong belt is located in the southeastern margin of the Tibetan plateau, and is bound by the Tengchong and Baoshan blocks. This paper presents new data from zircon geochronology, geochemistry, and whole-rock Sr–Nd–Pb–Hf isotopes to evaluate the tectonic evolution of the Gaoligong belt. The major rock types analysed in the present study are granitic gneiss, granodiorite, and granite. They are metaluminous to peraluminous and belong to high-K, calc-alkaline series. Laser ablation inductively coupled plasma mass spectrometry (LA–ICP–MS) analyses of zircons from nine granitic rocks yielded crystallization ages of 495–487 Ma, 121 Ma, 89 Ma, and 70–63 Ma. The granitoids can be subdivided into the following four groups. (1) Early Paleozoic granitic gneisses with high ε_Nd(t) and ε_Hf(t) values of − 1.06 to − 3.45 and − 1.16 to 2.09, and model ages of 1.16 Ga to 1.33 Ga and 1.47 Ga to 1.63 Ga, respectively. Their variable ⁸⁷Sr/⁸⁶Sr and Pb values resemble the characteristics of the Early Paleozoic Pinghe granite in the Baoshan block. Our data suggest that the rocks were derived from the break-off of the Proto-Tethyan oceanic slab between the outboard continent and the Baoshan block, which induced the partial melting of Mesoproterozoic pelitic sources mixed with depleted mantle materials. (2) Early Cretaceous granodiorites with low ε_Nd(t) and ε_Hf(t) values of − 8.92 and − 4.91 with Nd and Hf model ages of 1.41 Ga and 1.49 Ga, respectively. These rocks have high initial ⁸⁷Sr/⁸⁶Sr (0.711992) and lower crustal Pb values, suggesting that they were derived from Mesoproterozoic amphibolites with tholeiitic signature, leaving behind granulite residue at the lower crust. (3) Early Late Cretaceous granites with low ε_Nd(t) and ε_Hf(t) values of − 9.58 and − 4.61 with Nd and Hf model ages of 1.43 Ga and 1.57 Ga, respectively. These rocks have high initial ⁸⁷Sr/⁸⁶Sr (0.713045) and lower crustal Pb isotopic values. These rocks were generated from the partial melting of Mesoproterozoic metapelitic sources resulting from the delamination of thickened lithosphere, following the closure of the Bangong–Nujiang Ocean and collision of the Lhasa–Qiangtang blocks. (4) Late Cretaceous to Paleogene granitic gneisses with low ε_Nd(t) and ε_Hf(t) values of − 4.41 to − 10 and − 5.95 to − 8.71, Nd model ages ranging from 1.08 Ga to 1.43 Ga, and Hf model ages from 1.53 Ga to 1.67 Ga, respectively. These rocks show high initial ⁸⁷Sr/⁸⁶Sr (0.713201 and 714662) and lower crustal Pb values. The data suggest that these rocks are likely related to the eastward subduction of the Neo-Tethyan Oceanic slab, which induced partial melting of Mesoproterozoic lower crustal metagreywacke. The results presented in this study from the Gaoligong belt offer important insights on the evolution of the Proto-Tethyan, Bangong–Nujiang, and Neo-Tethyan oceans in the southeastern margin of the Tibetan Plateau.     

Mesoproterozoic magmatic events in the eastern North China Craton and their tectonic implications: Geochronological evidence from detrital zircons in the Shandong Peninsula and North Korea

Whether any Grenvillian magmatic records are preserved in the North China Craton (NCC) is a key issue to understand the Proterozoic tectonic evolution of the NCC and its correlation to the supercontinent Rodinia. Meso- to Neo-proterozoic sedimentary series is well exposed in the NCC, but magmatic events in this period, especially of 1.3–1.0 Ga, have seldom been reported. New U–Pb isotopic dating and Hf isotopic composition analyses have been carried out in this study using SIMS and LA–ICP-MS methods on detrital zircons from sandstones of the Tumen Group in the Shandong Peninsula and quartz sandstones of the Sangwon System in the Phyongnam Basin, North Korea. The age populations of the detrital zircons of the Tumen Group are at ~ 2.5 Ga, ~ 1.85 Ga, ~ 1.7 Ga, ~ 1.58 Ga, ~ 1.5 Ga, ~ 1.36 Ga and ~ 1.2 Ga and those of the Sangwon System are at 1.88–1.86 Ga, ~ 1.78 Ga, 1.62–1.58 Ga, 1.46–1.41 Ga, ~ 1.32 Ga, ~ 1.17 Ga and ~ 980 Ma. Most of the age peaks of Neoarchean and Proterozoic correspond to the significant tectonic-magmatic-thermal events previously recognized in the NCC, revealing that the main provenances of the Tumen Group and the Sangwon System are Early Precambrian basement and Late Paleo- to Meso-proterozoic magmatic rocks of the NCC. Furthermore, the youngest detrital zircon ages of ~ 1.1 Ga from the Tumen Group and 984 Ma from the Sangwon System, as well as 910 Ma Rb–Sr whole rock isochron age of a limestone from the Tumen Group and 899 Ma mafic sills intruding the Sangwon System suggest that both groups were deposited in the Neoproterozoic, coevally with the Qingbaikou System in the Yanliao Aulacogen. The common zircon ages of 1.3–1.0 Ga from the Tumen Group and the Sangwon System, as well as the contemporaneous Penglai and Yushulazi Group in the eastern margin of the NCC, indicate that during the deposition of these sediments there have been significant contributions from Grenvillian magmatic rocks in the eastern NCC. This may provide clues to understand the possible relationship of the NCC and the supercontinent Rodinia. Moreover, the positive εHf (t) and ~ 2.8 Ga crust model ages of detrital magmatic zircons of 2.8–2.4 Ga suggest that there have been significant crustal growth at ~ 2.8 Ga in the eastern margin of the NCC, same as in other areas of the NCC.