浙江杭州地区中下奥陶统岩石地层研究

笔者以城市基岩地质填图和剖面研究资料为基础,选择临安市板桥乡南山上中下奥陶统剖面为候选层型,根据剖面的地层层序、岩性组合、分界标志,结合区域变质的总体特征,重新厘定、划分了4个组级岩石地层单位,并依据荆山岭与板桥剖面的地层、生物化石对比,确定其地层时代为早中奥陶世。这对重建杭州地区层型剖面与地质遗迹保护、岩石地层填图、奥陶纪石灰岩矿产资源的开发利用都具有重要意义。     

西准噶尔哈拉阿拉特组的重新厘定及区域对比

根据西准噶尔玛依塔巴克一带区域地质调查最新成果,对《新疆岩石地层》中中晚石炭世哈拉阿拉特组重新进行厘定,建立哈拉阿拉特组副层型剖面,修正了原哈拉阿拉特组正层型剖面的地层层序,将原正层型剖面1~6层归早石炭世包古图组,将王玉净等划归下二叠统佳木河组的大套火山岩—火山碎屑岩组合置于哈拉阿拉特组下部。厘定后的哈拉阿拉特组分为7个岩性段,时代为晚石炭世。重新厘定后的本组,正确反映了其层序、岩石组合和地层学属性,为本区石炭系研究提供了准确完整的层序和对比剖面。     

川西金沙江一带志留—泥盆纪然西组的建立

川西金沙江一带的志留－泥盆纪地层，前人没有建立岩石地层单位。笔者通过地层清理，发现该套地层层序及与上覆地层接触关系清楚，岩性特征明显，且含一定生物化石，具备建立岩石地层单位条件。根据前人所测白玉县山岩乡然西剖面，将上述地层正式建组－然西组。本文对然西组层型剖面进行了描述。     

川西金沙江—带志留—泥盆纪然西组的建立

川西金沙江一带的志留—泥盆纪地层，前人没有建立岩石地层单位。笔者通过地层清理，发现该套地层层序及与上覆地层接触关系清楚，岩性特征明显，且含一定生物化石，具备建立岩石地层单位条件。根据前人所测白玉县山岩乡然西剖面，将上述地层正式建组───然西组。本文对然西组层型剖面进行了描述。     

四川省木里一带石炭纪邛依组的建立

四川木里一带的石炭纪地层，是一套区域浅变质碳酸盐岩、泥质岩、硅质岩及少量碎屑岩组合体，含牙形石、菊石、珊瑚类等化石，前人未建立岩石地层单位。笔者通过地层清理发现，该套地层顶底完整，层序、接触关系清楚，含有一定生物化石，岩性特征明显，具备建立岩石地层单位条件。故以木里邛依剖面为正层型剖面，将该套地层建立岩石地层单位－邛依组。本文对邛依组剖面进行了描述。     

四川省木里—带石炭纪邛依组的建立

四川木里一带的石炭纪地层，是一套区域浅变质碳酸盐岩、泥质岩、硅质岩及少量碎屑岩组合体，含牙形石、菊石、、珊瑚类等化石，前人未建立岩石地层单位。笔者通过地层清理发现，该套地层顶底完整，层序、接触关系清楚，含有一定生物化石，岩性特征明显，具备建立岩石地层单位条件。故以木里邛依剖面为正层型剖面，将该套地层建立岩石地层单位──邛依组。本文对邛依组剖面进行了描述。     

浙江煤山D剖面二叠系长兴组高精度岩石地层

基于对浙江煤山D剖面长兴组到下三叠统殷坑组岩石地层单元高精度的测量,选择了Yinetal.(1996)、盛金章等(1987)和赵金科等(1981)的地层资料,对比并修订了早期地层资料中的误差。重点标注了该剖面特殊岩性段,如黏土岩、碳酸盐化流纹质凝灰岩的产出层位,详尽描述了二叠系-三叠系界线附近的微观岩石地层特征,认为Y24e层顶部至Y27层为存在高度凝缩沉积或者沉积缺失的层段。这些高精度岩石地层材料将进一步推动二叠纪-三叠纪过渡期生物灭绝事件的后层型研究。     

羌塘盆地北部马料山侏罗纪布曲组地层古生物及沉积环境

详细描述了羌塘盆地北部乌兰乌拉湖地区马料山侏罗系剖面,将剖面划分为雀莫错组、布曲组和夏里组3个岩石地层单位,其中布曲组出露齐全,化石丰富。根据沉积环境及相对海平面变化规律将布曲组划分为2个沉积层序,并讨论了各体系域特征。依据马料山剖面布曲组的生物组合及分布特征建立了1个双壳类生物组合带即Chlamystipperi-Protocardiastricklandi组合带,并细分为3个组合亚带,其时限为中侏罗世巴通期。     

四川雅安地区早第三纪地层

下第三系名山组广泛分布于雅安地区，地层出露良好。本文简要介绍雅安国光山背斜东西两翼新测的地层剖面，将名山组（包括芦山组）划分成４段（砂岩粉砂岩段、粉砂岩泥岩泥灰岩段、泥岩粉砂岩段、泥岩段），并将芦山组归于名山组上部（Ⅳ段），从而取消该名称，综述了岩石组合特征、沉积环境，进行了生物地层和年代地层划分。     

信丰大塘盆地晚白垩世长岗群及其横坑里组、窑前组和新仓下组的建立

根据最新的地质调查成果，按岩石地层单位的命名原则，对江西信丰大塘盆地上白垩统进行了重新划分，建立了盆地相应的岩石地层单位。本文阐述该地层序列中段长岗群及其横坑里组、窑前组、新仓下组的建群、建组理由，描述其正层型剖面及含义特征，并对其时代进行讨论。     

Wavelength-dispersive X-ray fluorescence spectrometric determination of Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites

Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours.     

高压微波消解法测定醋酸纤维过滤器采集的微尘粒子中的砷镉钴铬铜铁锰镍铅钒锌

最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提     

Isotopic systematics of He,Ar, S,Cu, Ni,Re, Os,Pb, U,Sm, Nd,Rb, Sr,Lu, and Hf in the rocks and ores of the Norilsk deposits

This paper reports the first results of a study of 11 isotope systems (³He/⁴He, ⁴⁰Ar/³⁶Ar, ³⁴S/³²S, ⁶⁵Cu/⁶³Cu, ⁶²Ni/⁶⁰Ni, ⁸⁷Sr/⁸⁶Sr, ¹⁴³Nd/¹⁴⁴Nd, ^206–208Pb/²⁰⁴Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.     

硅酸盐中铁、锰、钛、钙、钾、磷、硅、铝、镁、钠、锶、铷、钡的X-射线荧光光谱定量测定

本文介绍样品经四硼酸锂熔融制成玻璃小饼。采用Lachance模式和理论a系数来校正元素间的效应,由3080E型X-射线荧光谱仪和DF-350B数据处理系统完成硅酸盐中十三个项目的测定。     

硅酸盐类样品中硅、铁、铝、钛、锰、钙、镁、钾、钠和磷的x射线荧光光谱测定

本文拟定了一种以熔融法制备样片,用X射线荧光光谱测定硅酸盐类样品中Si、Fe、Al、Tj、Mn、Ca、Mg、K、Na、P等元素的分析方法。在对不同靶材X光管和分光晶体实验对比的基础上,选择了最佳的测量条件。该法具有快速、准确,测量范围广,检测限低,价格便宜等优点。经过近百个各种类型标样或管理样品的分析对比表明,本法不仅适用于硅酸盐类岩石样品的分析,还适用于铁矿、铝土矿、碳酸盐类岩矿样品以及水泥、耐火材料等样品的分析。     

Viscous, cohesive, non-Newtonian, depositing, radial slurry flow

Mining induced subsidence can significantly affect mining costs where major surface facilities and natural environment need to be protected. Overburden grout injection is a technology used to control coal mine subsidence by injecting the mine waste material extracted from the coal back into the inter-burden rock during longwall mining. The flowing slurry is here categorised as a nonlinear viscous cohesive (Bingham plastic) fluid. During longwall mining the grout slurry is pumped into the separated beds of the rock mass through a central vertical borehole, which is drilled deep into the inter-burden rock strata above the coal seam. However, a blockage can occur in the injection system when the slurry velocity falls below a certain critical threshold velocity, indicating a material phase change from cohesive-viscous to cohesive-frictional. In situ field injection tests through boreholes have been simulated at a smaller scale at the CSIRO laboratory in Brisbane by pumping the slurry through a radial disk (gap = 4 mm) from its centre. Laboratory experiments indicate a general, nonlinear, cohesive, viscous, frictional model for shear behaviour of the slurry, in which the material shear parameters are functions of the disk radial distance. Complete dimensional and dimensionless analytical solutions have been developed based on an approach related to Bingham–Herschel–Bulkley fluid mechanics. The derived formulae include relations for minimum pump pressure, local pressure and pressure gradient, wall shear stress, volume rate, velocity and velocity gradient. The theoretical results match the experimental measurements. The experiments covered slurries with maximum particle sizes of 0.5 to 2 mm with about 50% being larger than 100 µm. The viscosities at the various solids concentrations were measured with a standard torsion viscometer. This study differs from the previous research in several distinct aspects, namely, consideration of the variable shear parameters rather than fixed values, inclusion of total nonlinear behaviour, and implementation of a friction function to mimic behaviour of the deposited and consolidating stiff slurry, which can cause a significant pressure rise as a result of the increased shear resistance.     

Mountains,nations, parks,and conservation

Between 1985 and 1991, two new mountain protected areas (MTNPA) covering more than 35,000 km² and based on participatory management models — the Makalu-Barun National Park and Conservation Area, Nepal, and Qomolangma Nature Preserve, Tibet Autonomous Region — were successfully established through the collaborative efforts of Woodlands Mountain Institute and conservationists in China and Nepal. Characteristics common to both projects include the importance of establishing (1) effective rationales, (2) local support constituencies, (3) a senior advisory group, (4) a task force, (5) linkages between conservation and development, and (6) fund raising mechanisms. The lessons derived from the experiences of Woodlands Mountain Institute are of significant value to others in preserving MTNPA. Increased collaboration and communication between all interested in conservation, however, will remain a critical component for expanding mountain protected area coverage to throughout the world.     

Regional distribution of Al,B, Ba,Ca, K,La, Mg,Mn, Na,P, Rb,Si, Sr,Th, U and Y in terrestrial moss within a 188,000 km2 area of the central Barents region: influence of geology,seaspray and human activity

Five hundred and ninety-eight samples of terrestrial moss (Hylocomium splendens and Pleurozium schreberi) collected from a 188,000 km² area of the central Barents region (NE Norway, N Finland, NW Russia) were analysed by ICP-AES and ICP-MS. Analytical results for Al, B, Ba, Ca, K, La, Mg, Mn, Na, P, Rb, Si, Sr, Th, U and Y concentrations are reported here. Graphical methods of data analysis, such as geochemical maps, cumulative frequency diagrams, boxplots and scatterplots, are used to interpret the origin of the patterns for these elements. None of the elements reported here are emitted in significant amounts from the smelting industry on the Kola Peninsula. Despite the conventional view that moss chemistry reflects atmospheric element input, the nature of the underlying mineral substrate (regolith or bedrock) is found to have a considerable influence on moss composition for several elements. This influence of the chemistry of the mineral substrate can take place in a variety of ways. (1) It can be completely natural, reflecting the ability of higher plants to take up elements from deep soil horizons and shed them with litterfall onto the surface. (2) It can result from naturally increased soil dust input where vegetation is scarce due to harsh climatic conditions for instance. Alternatively, substrate influence can be enhanced by human activity, such as open-cast mining, creation of ‘technogenic deserts’, or handling, transport and storage of ore and ore products, all of which magnify the natural elemental flux from bedrock to ground vegetation. Seaspray is another natural process affecting moss composition in the area (Mg, Na), and this is most visible in the Norwegian part of the study area. Presence or absence of some plant species, e.g., lichens, seems to influence moss chemistry. This is shown by the low concentrations of B or K in moss on the Finnish and Norwegian side of the (fenced) border with Russia, contrasting with high concentrations on the other side (intensive reindeer husbandry west of the border has selectively depleted the lichen population).     

NEW SET OF LOW CONCENTRATION STANDARDS FOR LA, CE, SM, YB, LU, Y, SC, V, NB AND TA IN SILICATES

We have developed a set of four synthetic standards for the rare earth and high field strength elements designed for use in the determination of those elements in silicates. The base material is a glass nominally at the eutectic of the MgO-Al₂O₃-SiO₂ ternary system. The nominal doping level was 2 wt% of the elements as oxides. To avoid problems associated with peak interference, the elements were doped in four separate glasses.