Reservoir quality and rock properties modeling – Triassic and Jurassic sandstones,greater Shearwater area,UK Central North Sea

The complex burial and diagenetic histories of the Jurassic Fulmar and Triassic Skagerrak sandstones in the UK Central North Sea present significant challenges with regard to reservoir quality and rock property prediction. Commercial reservoir quality is retained despite deep burial and associated high temperatures and pressures. Shallow marine Fulmar sands are normally compacted (mean IGV = 26 ± 3%) yet have porosities of 21–33%. Porosity was preserved through inhibition of quartz cementation by clay and microquartz coatings, and enhanced by dissolution of framework grains (∼5%). Skagerrak fluvial sands are more compacted (mean IGV = 23 ± 2%), exhibit minor feldspar dissolution (<1%), and have porosities of 16–27%. Quartz cement averages only 2 ± 1.5% due to robust chlorite coats that cover 80% (±13%) of quartz surfaces.We modeled reservoir quality evolution using the forward diagenetic model Touchstone, which simulates porosity loss due to compaction and quartz cementation. Quantitative petrographic analyses and burial history data were used to calibrate Touchstone model parameters. The results were applied to deeper prospects for pre-drill prediction of porosity and permeability. In parallel, petrophysical data were used to characterize the elastic properties of the sandstones to provide a basis for quantitative seismic forward modeling. Experimental data and core-calibrated petrophysical results, reflecting variable in situ fluids and saturations, were used to build an elastic properties model. The model is robust and was used to generate fluid-filled sandstone properties, incorporating Touchstone results, for prospect-specific seismic attribute modeling. Well results from exploration wells are in good agreement with pre-drill Touchstone and elastic properties model predictions.     

The impact of composition on pore throat size and permeability in high maturity shales: Middle and Upper Devonian Horn River Group,northeastern British Columbia,Canada

Shale reservoirs of the Middle and Upper Devonian Horn River Group provide an opportunity to study the influence of rock composition on permeability and pore throat size distribution in high maturity formations. Sedimentological, geochemical and petrophysical analyses reveal relationships between rock composition, pore throat size and matrix permeability.In our sample set, measured matrix permeability ranges between 1.69 and 42.81 nanodarcies and increases with increasing porosity. Total organic carbon (TOC) content positively correlates to permeability and exerts a stronger control on permeability than inorganic composition. A positive correlation between silica content and permeability, and abundant interparticle pores between quartz crystals, suggests that quartz may be another factor enhancing the permeability. Pore throat size distributions are strongly related to TOC content. In organic rich samples, the dominant pore throat size is less than 10 nm, whereas in organic lean samples, pore throat size distribution is dominantly greater than 20 nm. SEM images suggest that in organic rich samples, organic matter pores are the dominant pore type, whereas in quartz rich samples, the dominant type is interparticle pores between quartz grains. In clay rich and carbonate rich samples, the dominant pore type is intraparticle pores, which are fewer and smaller in size.High permeability shales are associated with specific depositional facies. Massive and pyritic mudstones, rich in TOC and quartz, have comparatively high permeability. Laminated mudstone, bioturbated mudstone and carbonate facies, which are relatively enriched in clay or carbonate, have fairly low permeability.     

Microfabric and rock properties of experimentally compressed silt-clay mixtures

Oedometric mechanical compaction tests were performed on brine-saturated synthetic samples consisting of silt-clay mixtures to study changes in microfabric and rock properties as a function of effective stress. The silt consisted of crushed quartz (∼100%) with grain size range between 4 and 40 μm, whereas the clay consisted of 81% kaolinite, 14% mica/illite and 5% microcline of grain size between 0.4 and 30 μm. Five sample pairs ranging in composition from pure silt to pure clay were compacted to 5 and 50 MPa effective stress respectively. SEM studies were carried out to investigate microfabric changes in the mechanically compacted silt-clay mixtures. The degree of alignment of the different minerals present (quartz, mica/illite and kaolinite) were computed by using an image analysis software. Experimental compaction have measured the changes in the rock properties such as porosity and velocity as a function of effective stress for different mixtures of clay and silt. Clay-rich samples showed a higher degree of mineral orientation and lower porosity compared to silt-dominated samples as a function of effective stress. Pure clay sample had 11% porosity at 50 MPa effective stress whereas the pure silt sample retained about 29% porosity at the same effective stress. The experiments showed that low porosity down to 11% is possible by mechanical compaction only. A systematic increase in strain was observed in the silt-clay mixtures with increasing clay content but the porosity values found for the 50:50 silt-clay mixture were lower than that of 25:75 silt-clay mixture. No preferential mineral orientation is expected before compaction owing to the high initial porosity suggesting that the final fabric is a direct result of the effective stress. Both P- and S-wave velocities increased in all silt-clay mixtures with increasing effective stress. The maximum P- and S-wave velocities were observed in the 25:75 silt-clay mixture whereas the minimum Vp and Vs were recorded in the pure silt mixture. At 50 MPa effective stress P- wave velocities as high as 3 km/s resulted from experimental mechanical compaction alone. The results show that fine-grained sediment porosity and velocity are dependent on microfabric, which in turn is a function of grain size distribution, particle shape, sediment composition and stress. At 5 MPa effective stress, quartz orientation increased as a function of the amount of clay indicating that clay facilitate rotation of angular quartz grains. Adding clay from 25% to 75% in the silt-clay mixtures at 50 MPa effective stress decreased the quartz alignment. The clay mineral orientation increased by increasing both the amount of clay and the effective stress, the mica/illite fabric alignment being systematically higher than that of kaolinite. Even small amount of silt (25%) added to pure clay reduced the degree of clay alignment significantly. This study demonstrates that experimental compaction of well characterized synthetic mudstones can be a useful tool to understand microfabric and rock properties of shallow natural mudstones where mechanical compaction is the dominant process.     

Seismic inversion as a predictive tool for porosity and facies delineation in Paleocene fluvial/lacustrine reservoirs,Melut Basin,Sudan

The Melut Basin is a rift basin in the interior Sudan linked to the Mesozoic-Cenozoic Central and Western African Rift System. The Paleocene Yabus Formation is the main reservoir deposited in heterogeneous fluvial/lacustrine environment. Delineation of channel sandstone from shale is a challenge in reservoir exploration and development. We demonstrate a detailed 3D quantitative seismic interpretation approach that integrates petrophysical properties derived from well logs analysis. A porosity transform of acoustic impedance inversion provided a link between elastic and rock properties. Thus, we used seismic porosity to discriminate between different facies with appropriate validation by well logs. At the basin scale, the results revealed lateral and vertical facies heterogeneity in the Melut Basin. Good reservoir quality is observed in the Paleocene Yabus Formation. The sand facies indicated high porosity (20%) corresponding to low acoustic impedance (20000–24000 g ft/(cm3.s)). However, lower quality reservoir is observed in the Cretaceous Melut Formation. The porosity of sand/shale facies is low (5%), corresponding to high acoustic impedance (29000–34000 g ft/(cm3.s)). This suggests that the Yabus Sandstone is potentially forming a better reservoir quality than Melut Formation. At the reservoir scale, we evaluated the facies quality of Yabus Formation subsequences using petrophysical analysis. The subsequences YB1 to YB3, YB4 to YB7 and YB8 to YB10 showed relatively similar linear regressions, respectively. The subsequence of YB4 to YB7 is considered the best reservoir with higher porosity (25%). However, subsequence YB1 to YB3 showed lower reservoir quality with higher shale volume (30%). This attributed to floodplain shale deposits in this subsequence. Similarly, the high porosity (20%) recognized in deeper subsequences YB6 to YB9 is due to clean sand facies. We learnt a lesson that appropriate seismic preconditioning, exhaustive petrophysical analysis and well log validation are important keys for improved reservoir quality prediction results in fluvial/lacustrine basins.     

An enhanced understanding of the Basinal Bowland shale in Lancashire (UK), through microtextural and mineralogical observations

Variability in the Lower Bowland shale microstructure is investigated here, for the first time, from the centimetre to the micrometre scale using optical and scanning electron microscopy (OM, SEM), X-Ray Diffraction (XRD) and Total Organic Carbon content (TOC) measurements. A significant range of microtextures, organic-matter particles and fracture styles was observed in rocks of the Lower Bowland shale, together with the underlying Pendleside Limestone and Worston Shale formations encountered the Preese Hall-1 Borehole, Lancashire, UK. Four micro-texture types were identified: unlaminated quartz-rich mudstone; interlaminated quartz- and pyrite-rich mudstone; laminated quartz and pyrite-rich mudstone; and weakly-interlaminated calcite-rich mudstone. Organic matter particles are classified into four types depending on their size, shape and location: multi-micrometre particles with and without macropores: micrometre-size particles in cement and between clay minerals; multi-micrometre layers; and organic matter in large pores. Fractures are categorized into carbonate-sealed fractures; bitumen-bearing fractures; resin-filled fractures; and empty fractures. We propose that during thermal maturation, horizontal bitumen-fractures were formed by overpressuring, stress relaxation, compaction and erosional offloading, whereas vertical bitumen-bearing, resin-filled and empty fractures may have been influenced by weak vertical joints generated during the previous period of veining. For the majority of samples, the high TOC (>2 wt%), low clay content (<20 wt%), high proportion of quartz (>50 wt%) and the presence of a multi-scale fracture network support the increasing interest in the Bowland Shale as a potentially exploitable oil and gas source. The microtextural observations made in this study highlight preliminary evidence of fluid passage or circulation in the Bowland Shale sequence during burial.     

Identification,characterization, and statistical analysis of mudstone aggregate clasts,Cretaceous Carlile Formation,Central Alberta,Canada

While clastic mudstones and shale were traditionally interpreted to have been deposited in quiet water settings, recent flume experiments and studies have shown that mud can be transported in and deposited by traction currents as migrating ripples of mud aggregates. Despite these recent advances, mud aggregates have rarely been adequately described in the rock record.These mud aggregates and the sedimentary structures they form in mudstone successions are difficult to observe in the rock record due to compaction, which often obliterates the aggregates and flattens bedforms. This paper documents unambiguously identifiable sand sized mudstone aggregates in thin sections and SEM, transported in traction, and deposited in a series of prograding clinothems. These aggregates were sufficiently indurated to locally preserve shelter porosity, significantly improving the hydrocarbon reservoir properties.Grain size analysis of the aggregates was performed on thin sections, as well as disaggregated samples measured by a laser diffraction grain size analyzer for comparison. These analyses showed that sand sized aggregates often comprise more than half of the sediment volume. While the clay-rich composition of the Carlile Formation would suggest that it is a mudstone, statistical analysis of these grain size measurements show that it could alternatively be described as a silty sandstone. These findings potentially change how we think about mudstone classification, fine-grained sedimentation, and mudstone dominated petroleum reservoirs.     

Evolution of petrophysical properties of oil shales during high-temperature compaction tests: Implications for petroleum expulsion

The transport properties of Permian to Miocene oil shales (Torbanite, Posidonia, Messel, Himmetoglu, and Condor) were studied using petrophysical and geochemical techniques. The aims of this study were to assess permeability of oil shales, evaluate the evolution of porosity, specific surface area and intergranular permeability during high temperature compaction tests and to verify the suitability of intergranular permeability for petroleum expulsion. Measured permeability coefficients for two samples were 0.72 × 10⁻²¹ m² for the Eocene Messel shale and 2.63 × 10⁻²¹ m² for the Lower Jurassic Posidonia shale from S. Germany, respectively. BET specific surface areas of the original samples ranged from 0.7 to 10.6 m²/g and decreased after compaction to values from 0.3 to 3.7 m²/g. Initial porosity values ranged from 7.6 to 20.1 % for pre-deformation and from 9.99 to 20.7 % for post-deformation samples. Porosity increased during the high-temperature compaction experiments due to petroleum generation and expulsion. Permeability coefficients estimated using the Kozeny–Carman equation varied from 6.97 × 10⁻²⁴ m² to 5.22 × 10⁻²¹ m² for pre-deformation and from 0.2 × 10⁻²¹ m² to 4.8 × 10⁻²¹ m² for post-deformation samples reflecting the evolution of their porosity and BET specific surface areas. Measured and calculated permeability were similar for the Messel shale whereas calculated permeability was two orders of magnitude lower for the Posidonia shale from S. Germany. Petroleum expulsion efficiencies under the experimental conditions ranged from 38.6% for the Torbanite to 96.2% for the Posidonia shale from S. Germany. They showed strong positive correlation with the petroleum generation index (R² = 0.91) and poor correlations with porosity (R² = 0.46), average pore throat diameters (R² = 0.22), and compaction (R² = 0.02). Estimated minimum pore-system saturations for petroleum expulsion during the experiments were 12% for the Torbanite and 30% for the Posidonia shale from N. Germany. Pore-system saturation determines whether expulsion occurs mainly through matrix or fracture permeability. For samples with saturation levels above 20%, fracture permeability dominated during the experiments. Evidence based on the measured permeability coefficients, expulsion flow rates, consideration of capillary displacement during generation-related pore invasion and the existence of transport porosity suggests that fracture permeability is the principal avenue of petroleum expulsion from source rocks. This conclusion is supported by microscopic observations.     

Mineral types and organic matters of the Ordovician-Silurian Wufeng and Longmaxi Shale in the Sichuan Basin,China: Implications for pore systems,diagenetic pathways,and reservoir quality in fine-grained sedimentary rocks

Mineral types (detrital and authigenic) and organic-matter components of the Ordovician-Silurian Wufeng and Longmaxi Shale (siliceous, silty, argillaceous, and calcareous/dolomitic shales) in the Sichuan Basin, China are used as a case study to understand the control of grain assemblages and organic matter on pores systems, diagenetic pathway, and reservoir quality in fine-grained sedimentary rocks. This study has been achieved using a combination of petrographic, geochemical, and mercury intrusion methods. The results reveal that siliceous shale comprises an abundant amount of diagenetic quartz (40–60% by volume), and authigenic microcrystalline quartz aggregates inhibit compaction and preserve internal primary pores as rigid framework for oil filling during oil window. Although silty shale contains a large number of detrital silt-size grains (30–50% by volume), which is beneficial to preserve interparticle pores, the volumetric contribution of interparticle pores (mainly macropores) is small. Argillaceous shale with abundant extrabasinal clay minerals (>50% by volume) undergoes mechanical and chemical compactions during burial, leading to a near-absence of primary interparticle pores, while pores preserved between clay platelets are dominant with more than 10 nm in pore size. Pore-filling calcite and dolomite precipitated during early diagenesis inhibit later compaction in calcareous/dolomitic shale, but the cementation significantly reduces the primary interparticle pores. Pore-throat size distributions of dolomitic shale show a similar trend with silty shale. Besides argillaceous shale, all of the other lithofacies are dominated by OM pores, which contribute more micropores and mesopores and is positively related to TOC and quartz contents. The relationship between pore-throat size and pore volume shows that most pore volumes are provided by pore throats with diameters <50 nm, with a proportion in the order of siliceous (80.3%) > calcareous/dolomitic (78.4%) > silty (74.9%) > argillaceous (61.3%) shales. In addition, development degree and pore size of OM pores in different diagenetic pathway with the same OM type and maturity show an obvious difference. Therefore, we suggest that the development of OM pores should take OM occurrence into account, which is related to physical interaction between OM and inorganic minerals during burial diagenesis. Migrated OM in siliceous shale with its large connected networks is beneficial for forming more and larger pores during gas window. The result of the present work implies that the study of mineral types (detrital and authigenic) and organic matter-pores are better understanding the reservoir quality in fine-grained sedimentary rocks.     

Quartz cementation in Late Cretaceous mudstones,northern North Sea: Changes in rock properties due to dissolution of smectite and precipitation of micro-quartz crystals

Late Cretaceous mudstones from two wells located in the northern North Sea and the Norwegian Sea have been examined with respect to quartz cement. Two different types of quartz cement (Type 1 and Type 2) have been identified using SEM/EDS/CL-analysis of drill-bit cuttings at depths 2370–2670 m (80–85 °C). Type 1 appears as relatively large aggregates (30–100 μm) of depth/temperature related crypto- or microcrystalline to macrocrystalline irregular quartz cement formed by local re-crystallization of biogenic silica. The CL-responses of Type 1 quartz cement give a clear indication of an authigenic origin. Type 2 quartz cement represents relatively high amounts of extremely fine-grained micro-sized (1–3 μm) crystals embedded as discrete, short chains or small clusters/nests within the illitized clay matrix. The CL-responses of micro-quartz crystals indicate an authigenic origin. The micro-quartz is most probably sourced from silica released during the smectite to illite dissolution–precipitation reaction. The petrographic evidence indicates that most of the silica released by the smectite to illite reaction has not been exported out of the mudstones. The silica released produce a subtle inter-connected micro-quartz network interlocked with aggregates of micro-quartz and authigenic clay crystals. This micro-quartz cementation process causes a significant and sharp change in the mudstone stiffness at the onset of the chemical compaction regime. This is indicated by an abrupt increase in well log velocity (Vp) and change in seismic facies close to 2500 m (80/85 °C).     

Compaction model for quartzose sandstones application to the Garn Formation,Haltenbanken, Mid-Norwegian Continental Shelf

The compaction of quartzose sandstones is described by a macroscopical visco–elasto–plastic model, derived from microscopical considerations. This model considers that the reduction of total porosity (the relative pore volume) is related to the changes in the relative cemented volume and the relative intergrain volume. Furthermore, we consider that the variations of these two petrophysical parameters result from two physical mechanisms, mechanical compaction and closed system chemical compaction.The model has been calibrated for the Middle Jurassic Garn Formation from the Haltenbanken area of the Mid-Norwegian Continental Shelf. Around 300 data points from 17 wells have been used in this study. The viscous parameters have been optimised against the present day data. With total porosity data the best fit is obtained for an activation energy between 14 and 16 kJ/mole and a macroscopical viscosity at 15°C between 39 and 46 GpaMa (1.210²⁴–1.410²⁴ Pa.s). If quartz cement data are used, the best fit is obtained for an activation energy between 16 and 18 kJ/mole and a macroscopical viscosity at 15°C between 47 and 56 GpaMa (1.510²⁴–17.10²⁴ Pa.s).The visco–elasto–plastic compaction model has been tested in the Haltenbanken area of Mid Norway, with the result that observed porosity trends and pore pressures can be modelled. Using multiple 2-D basin modelling simulations the results of this model and its implications for fluid flow and petroleum systems analysis can be seen. The compaction method has significant impact on the simulated fluid flow and petroleum migration pattern.     

Evolution of structural and physical parameters of clays during experimental compaction

To provide a better understanding of sedimentary basin geological history, it is important to describe correctly the evolution of the various physical, mechanical and hydraulic properties of clayey rocks as a function of burial depth. As a contribution to this field, a programme of experimental studies on reworked clay samples compacted under various load pressures in oedometric conditions has been set up. The evolution of samples under compaction was followed with microscopic and macroscopic measurements. In a specially designed oedometric cell, samples are compacted under different total stresses from 0.1 to 50 MPa. In this cell, cylindrical cores are submitted to progressive loading from both ends under controlled pore pressure conditions. The symmetrical loading allows more even deformation about the midplane of the sample. This device allows the evolution of hydraulic pressure, radial stress, displacement and expelled pore fluid to be followed as a function of time. In a first step, kaolinite was chosen because it retains a high permeability (compared with other clays such as illite or smectite), which allows compaction tests to be performed within a few days. A complete set of measurements was performed after the tests. These measurements are: (1) micro-structures investigated by means of transmission electron microscopy (TEM), mercury porosimetry, water removal under low water vapour pressure, granulometry and specific area measured by ethylene glycol adsorption; and (2) various physical parameters measured including hydraulic conductivity and thermal conductivity. TEM gives an understanding of the arrangement of particles. It was found that each particle is composed of several crystal units, each unit formed by ≈25 individual kaolinite layers. During compaction, these particles remain undeformed, but are rotated. The angular distribution of grain orientation is a function of the applied effective stress. This reorientation is in agreement with the observed decrease in porosity and pore size. It also explains the occurrence of a strong anisotropy in the thermal conductivity and hydraulic permeability. The combination of these experimental results allows a qualitative and quantitative understanding of the behaviour of kaolinite with respect to parameters such as permeability, porosity, mechanical and thermal properties, the knowledge of which are necessary for basin modelling.     

Experimental evaluation of reservoir quality in Mesozoic formations of the Perth Basin (Western Australia) by using a laboratory low field Nuclear Magnetic Resonance

Accurate porosity and permeability evaluation of rock formations is critical to estimate the quality and resource potential of a reservoir. In addition to directly measure the porosity and pore size distribution, low field Nuclear Magnetic Resonance (NMR) is able to measure the effective porosity and estimate the in-situ formation permeability, though its robustness is arguable and requires calibrations on cores with specific lithologies.The Mesozoic formations of the central Perth Basin (Western Australia) host hot sedimentary aquifers and recently became key targets for geothermal heat extraction. A collection of cores was retrieved from three wells intersecting these units. The characterisation of their flow properties complements the current evaluation of the Perth Basin by adding new data on effective porosity, pore size distribution, pore geometry and calibration of predictive models for the permeability according to a comprehensive facies classification scheme.This study highlights the consistency of the NMR approach when compared to conventional helium injection method. Most favourable lithologies for well production correspond to very coarse to fine sandstones of fluvial channel fill with porosities >15% and permeabilities >>1 mD. Similarly, these facies exhibit (i) the highest effective porosities, (ii) the highest pore space to pore throat ratio, and (iii) the lowest contribution of clay bound water. These aspects confirm the importance of clay occurrence in the assessment of the flow efficiency of a formation.The Yarragadee Formation presents the best reservoir quality regarding its porosity and permeability, even though high discrepancies occur locally owing to the great variability of lithofacies encountered. The scattered values observed for the Lesueur Sandstone are likely to be due to the basin architecture and fault system which generate different mechanical compaction and secondary cementation. Given an adequate facies analysis, the NMR method represents a powerful tool to estimate the flow efficiency of a reservoir.     

Fracture patterns and petrophysical properties of carbonates undergoing regional folding: A case study from Kurdistan,N Iraq

The Zagros-Taurus fold and thrust belt hosts a prolific hydrocarbon system. Most hydrocarbon reserves are stored in naturally fractured reservoirs and such fracture systems can therefore have a significant impact on reservoir performance. Fractures are one of the most important paths for fluid flow in carbonate reservoirs, and industrial geoscientists and engineers therefore need to understand and study fracture patterns in order to optimise hydrocarbon production. The observed fracture patterns in outcrops may have implications on fluid flow and reservoir modelling in subsurface reservoirs, and we have therefore undertaken a case study of fracturing associated with regional folding in Iraqi Kurdistan. In this area, some exploration wells currently target Upper Triassic dolostones (Kurra Chine Formation) and/or Lower Jurassic limestones and dolomitised limestones (Sehkaniyan Formation). In both units hydrocarbon production comes mainly from secondary porosity created by dolomitisation, dissolution and fracturing. Both formations have undergone multiple phases of deformation associated with burial, uplift, folding and thrusting. We investigate some fracture pattern characteristics and some petrophysical properties of these units using selected outcrops around the Gara, Ora and Ranya anticlines that form folds directly traceable for 25–70 km. Our outcrop data is compared with subsurface fracture and petrophysical datasets reported from wells in the nearby Shaikhan and Swara Tika Fields. The 1-2-3D fracture attributes collected from outcrops are fracture orientation, type, spacing, intensity, length and cross-cutting and abutting relationships. Fracture orientations show a clear relationship to the local fold axis in both the outcrop and subsurface, although in some cases they appear to relate more to the present day in-situ maximum horizontal stress direction or local strike-slip faulting. Three stages of fracturing are proposed: pre-folding, early-folding and post-folding fractures. In addition, we report petrophysical properties - porosity, permeability and acoustic velocity of both the Kurra Chine and Sehkaniyan formations in relation to their structural position within folds and faults and stratigraphic level. The highest porosities and permeabilities are recorded in the hinges and backlimbs of the Gara Anticline. The best reservoir quality (highest porosity and permeability) is often found in areas associated with replacement dolomite i.e. solution vugs and intercrystalline porosity. The Kurra Chine Formation displays similar trends in velocity-porosity data at both outcrop and the subsurface. However, the Sehkaniyan Formation displays lower acoustic velocity for a given porosity at outcrop compared to the subsurface.     

Calibration of the mudrock compaction curve by eliminating the effect of organic matter in organic-rich shales: Application to the southern Ordos Basin,China

The mudrock log-derived compaction curve is a significant tool for investigating the primary migration of hydrocarbon, predicting fluid overpressure, estimating formation erosion thicknesses and restoring the buried history and paleo-structure of a basin. However, the presence of kerogen in organic-rich shales can create typically high logging values of the acoustic transit time. Thus, the abnormally high values of the acoustic transit time for organic-rich rocks may not truly reflect the porosity variations of subsurface rocks, leading to great uncertainties in the understanding of the mudstone compaction and a certain amount of error in the abnormal fluid pressure estimation when using the mudrock log-derived compaction curve. Therefore, it is necessary to recalibrate the mudstone compaction curve by eliminating the increment of the acoustic transit time caused by the kerogen content of organic-rich mudstones. Taking the southwest Ordos Basin as an example, this paper presents a new equivalent volume model based on the composition of organic-rich shale in which the kerogen content is also considered. Based on the quantitative relationship between the rock composition and the acoustic transit time, a quantitative formula for calculating the acoustic transit time increment caused by the kerogen is derived. This formula shows that the increment depends not only on the organic content but also on the occurrence state, pore size, pore fluid composition and other factors. X-ray diffraction (XRD) data were used to determine the main mineral composition of the mudstone and to calculate the acoustic transit time of the rock skeleton. Then, the mudstone compaction curve in the Zhenjing area was calibrated by combining the measured porosity and total organic carbon (TOC) of the mudstone based on the correction formula. The compaction characteristics varied significantly between before and after the calibration. The slope of the normal compaction trend (NCT) line decreased by 30–55%, and the acoustic transit time deviation from the NCT in the undercompaction interval decreased significantly. The overpressure at the maximum burial depth estimated by the equivalent depth method is in better agreement with the results obtained by numerical simulation after the calibration, and the porosity determined from the well log after the calibration is also closer to the true measured value. The method proposed in this paper is of great significance for improving the reliability and accuracy of compaction research on organic-rich mudstones, especially for the accurate estimation of abnormal pressure in the source rock layer. Additionally, it can be used as an effective reference for mudstone compaction studies in similar geological settings areas or basins.     

Quartz cement and its origin in tight sandstone reservoirs of the Cretaceous Quantou formation in the southern Songliao basin,China

The tight sandstones of the Cretaceous Quantou formation are the main exploration target for hydrocarbons in the southern Songliao basin. Authigenic quartz is a significant cementing material in these sandstones, significantly reducing porosity and permeability. For efficient predicting and extrapolating the petrophysical properties within these tight sandstones, the quartz cement and its origin need to be better understood. The tight sandstones have been examined by a variety of methods. The sandstones are mostly lithic arkoses and feldspathic litharenites, compositionally immature with an average framework composition of Q₄₃F₂₆L₃₁, which are characterized by abundant volcanic rock fragments. Mixed-layer illite/smectite (I/S) ordered interstratified with R = 1 and R = 3 is the dominating clay mineral in the studied sandstone reservoirs. Two different types of quartz cementation modes, namely quartz grain overgrowth and pore-filling authigenic quartz, have been identified through petrographic observations, CL and SEM analysis. Homogenization temperatures of the aqueous fluid inclusions indicate that both quartz overgrowths and pore-filling authigenic quartz formed with a continuous process from about 70 °C to 130 °C. Sources for quartz cement produced are the conversion of volcanic fragments, smectite to illite reaction and pressure solution at micro stylolites. Potassium for the illitization of smectite has been sourced from K-feldspar dissolution and albitization. Silica sourced from K-feldspars dissolution and kaolinite to illite conversion is probably only minor amount and volumetrically insignificant. The internal supplied silica precipitate within a closed system where the transport mechanism is diffusion. The quartz cementation can destroy both porosity and permeability, but strengthen the rock framework and increase the rock brittleness effectively at the same time.     

Evaluating the timing of hydrocarbon generation in the Devonian Duvernay Formation: paleomagnetic,rock magnetic and geochemical evidence

The physical and chemical changes associated with the thermal maturation of organic-rich shale have affected the paleomagnetic and rock magnetic characteristics of the Devonian Duvernay Formation in the Western Canada Sedimentary Basin. This formation has several lithofacies that correspond to deposition in platform, slope and deeper water settings under varied redox conditions. Shale, laminated mudstone and some massive mudstone facies show evidence of magnetic changes associated with maturation but wackestone, packstone and some massive mudstone facies appear to be unaffected by the process. Rock magnetic evidence suggests that thermal maturation induces a change in the magnetization carrier from magnetite and hematite to solely magnetite.The packstone and wackestone facies commonly show a reversed characteristic magnetization with a paleopole at 194°E, 70°N (A₉₅=13.2) of Late Cretaceous-age. Shale and laminated mudstone facies in immature areas of the basin have inclination-only characteristic remanent magnetization (ChRM) means that range from 55 to 67 °C, requiring a pre-Cretaceous magnetization age. Shale and laminated mudstone facies in mature areas of the basin have a much steeper ChRM in direction ranging from 77 to 83 °C. Their very steep nature suggests that step demagnetization has not completely removed a drilling-induced remanence in some wells.     

Petrology and depositional evolution of the Paleozoic rocks of Iraq

The study integrates petrographical and lithological data from deep exploration wells and outcrops in northern Iraq to better understand the sedimentary environments present in the basin and to evaluate the depositional evolution of the Paleozoic rocks in Iraq. The studied Paleozoic successions are represented by five sedimentary cycles of intracratonic sequences. These are dominated mainly by siliciclastic and mixed sedimentary packages, and are separated by major and minor unconformity surfaces. These cycles are as follow: the Ordovician cycle, represented by the Khabour Formation; the Silurian cycle, represented by the Akkas Formation; the Middle-Late Devonian to Early Carboniferous cycle, represented by the Chalki, Pirispiki, Kaista, Ora and Harur formations; the Permian–Carboniferous cycle, represented by the Ga’ara Formation and late Permian cycle, represented by the Chia Zairi Formation. Generally, the cycles are characterized by siliciclastic and mixed carbonate–clastic facies with abrupt changes during Late Paleozoic reflecting the environmental and tectonic events during this period. The Ordovician Khabour Formation is suggested to be of shallow marine environment of deposition with stacked transgressive and regressive cycles that are eustatically controlled. The shale of Silurian Akkas Formation was deposited in open-marine environment. Depositional regimes in the Late Devonian to Early Carboniferous are considered as a continuation of deposition in the subsiding basin with a wide geographic distribution that reflect the epicontinental or epeiric seas in a homoclinic ramp setting. The Permo-Carboniferous Ga’ara Formation was deposited in continental to paralic environment while the Late Permian Chia Zairi Formation represents the carbonate platform deposition. The study revealed that potential source rocks may include some shale beds of the Khabour Formation, hot shales of Akkas Formation and the shales of Ora Formation. The sandstones of the Khabour, Akkas and Kaista formations have good reservoir potential. The Late Permian carbonates of Chia Zairi Formation may be self-sourcing and contain multiple reservoirs. The occurrence of shale as source rocks and limestone as reservoir rocks and some evaporates as sealing horizons make the formation as a reservoir in its own right.     

Controls on reservoir quality of Lower Cretaceous tight sandstones in the Laiyang Sag,Jiaolai Basin,Eastern China: Integrated sedimentologic,diagenetic and microfracturing data

The Jiaolai Basin (Fig. 1) is an under-explored rift basin that has produced minor oil from Lower Cretaceous lacustrine deltaic sandstones. The reservoir quality is highly heterogeneous and is an important exploratory unknown in the basin. This study investigates how reservoir porosity and permeability vary with diagenetic minerals and burial history, particularly the effects of fracturing on the diagenesis and reservoir deliverability. The Laiyang sandstones are tight reservoirs with low porosity and permeability (Φ < 10% and K < 1 mD). Spatial variations in detrital supply and burial history significantly affected the diagenetic alterations during burial. In the western Laiyang Sag, the rocks are primarily feldspathic litharenites that underwent progressive burial, and thus, the primary porosity was partially to completely eliminated as a result of significant mechanical compaction of ductile grains. In contrast, in the eastern Laiyang Sag, the rocks are lithic arkoses that were uplifted to the surface and extensively eroded, which resulted in less porosity reduction by compaction. The tectonic uplift could promote leaching by meteoric water and the dissolution of remaining feldspars and calcite cement. Relatively high-quality reservoirs are preferentially developed in distributary channel and mouth-bar sandstones with chlorite rims on detrital quartz grains, which are also the locations of aqueous fluid flow that produced secondary porosity. The fold-related fractures are primarily developed in the silt–sandstones of Longwangzhuang and Shuinan members in the eastern Laiyang Sag. Quartz is the most prevalent fracture filling mineral in the Laiyang sandstones, and most of the small-aperture fractures are completely sealed, whereas the large-aperture fractures in a given set may be only partially sealed. The greatest fracture density is in the silt–sandstones containing more brittle minerals such as calcite and quartz cement. The wide apertures are crucial to preservation of the fracture porosity, and the great variation in the distribution of fracture-filling cements presents an opportunity for targeting fractures that contribute to fluid flow.