Geochemical characteristics of gases from the largest tight sand gas field (Sulige) and shale gas field (Fuling) in China

This study performed a detailed geochemical analyses of the components, stable carbon isotopes of alkane gas and CO₂, stable hydrogen isotopes of alkane gas and helium isotopes of reproducing gas from the largest tight gas field (Sulige) and shale gas (Fuling) field in China. The comparative study shows that tight gas from the Sulige gas field in the Ordos Basin is of coal-derived origin, which is characterized by a positive carbon and hydrogen isotopic distribution pattern (δ¹³C₁ > δ¹³C₂ > δ¹³C₃ > δ¹³C₄; δ²H₁ > δ²H₂ > δ²H₃), i.e., the carbon and hydrogen isotopes increase with increasing carbon numbers. Carbon dioxide from this field are of biogenic origin and the helium is crust-derived. Shale gas from the Fuling shale gas field belongs to oil-derived gas which has complete carbon and hydrogen isotopic reversal of secondary alteration origin (δ¹³C₁ < δ¹³C₂ < δ¹³C₃; δ²H₁ < δ²H₂ < δ²H₃), i.e., the carbon and hydrogen isotopes decrease with increasing carbon numbers. Such complete isotopic reversal distribution pattern is due to the secondary alteration like oil or gas cracking, diffusion and so on under high temperature. In that case, positive carbon or hydrogen isotopic distribution pattern will change into complete isotopic reversal as the temperature increases. Carbon dioxide is of abiogenic origin resulting from the thermal metamorphism of carbonates and helium is crust-derived.     

Influence of detrital composition on the diagenetic history of tight sandstones with implications for reservoir quality: Examples from the Permian Xiashihezi Formation and Carboniferous Taiyuan Formation,Daniudi gas field,Ordos Basin,China

Tight-gas reservoirs, characterized by low porosity and low permeability, are widely considered to be the product of post-depositional, diagenetic processes associated with progressive burial. This study utilizes a combination of thin section petrography, scanning electron microscopy, microprobe and back scatter electron analysis, stable isotope geochemistry and fluid inclusion analysis to compare the diagenetic history, including porosity formation, within sandstones of the second member of Carboniferous Taiyuan Formation (C₃t₂) and the first member of Permian Xiashihezi Formation (P₁x₁) in the Ordos Basin in central China.In the P₁x₁ member, relatively high abundances of metamorphic rock fragments coupled with a braided river and lacustrine delta environment of deposition, produced more smectite for transformation to illite (50–120 °C). This reaction was driven by dissolution of unstable minerals (K-feldspar and rock fragments) during the early to middle stages of mesodiagenesis and consumed all K-feldspar. Abundant intragranular porosity (average values of 2.8%) and microporosity in kaolinite (average values of 1.5%) formed at these burial depths with chlorite and calcite developed as by-products.In the C₃t₂ member, relatively low abundances of metamorphic rock fragments coupled with an incised valley-coastal plain environment of deposition resulted in less smectite for transformation to illite. High K⁺/H⁺ ratios in the early pore waters related to a marine sedimentary environment of deposition promoted this reaction. Under these conditions, K-feldspar was partially preserved. During the middle to late stages of mesodiagenesis, K-feldspar breakdown produced secondary intragranular (average values of 1.4%) and intergranular pores (average values of 1.2%). Release of K⁺ ions promoted illitization of kaolinite with quartz overgrowths and ferrous carbonates developed as by-products.This study has demonstrated that whereas both members are typical tight-gas sandstones, they are characterized by quite different diagenetic histories controlled by the primary detrital composition, especially during mesodiagenesis. Types of secondary porosity vary between the two members and developed at different stages of progressive burial. The content of unstable detrital components, notably feldspar, was the key factor that determined the abundance of secondary porosity.     

Influence of natural fractures on gas accumulation in the Upper Triassic tight gas sandstones in the northwestern Sichuan Basin,China

The Upper Triassic Xujiahe Formation in the northwestern Sichuan Basin, China, is a typical tight gas sandstone reservoir that contains natural fractures and has an average porosity of 1.10% and air permeability less than 0.1 md because of compaction and cementation. According to outcrops, cores and image logs, three types of natural fractures, namely, tectonic, diagenetic and overpressure-related fractures, have developed in the tight gas sandstones. The tectonic fractures include small faults, intraformational shear fractures and horizontal shear fractures, whereas the diagenetic fractures mainly include bed-parallel fractures. According to thin sections, the microfractures also include tectonic, diagenetic and overpressure-related microfractures. The diagenetic microfractures consist of transgranular, intragranular and grain-boundary fractures. Among these fractures, intraformational shear fractures, horizontal shear fractures and small faults are predominant and significant for fluid movement. Based on the Monte Carlo method, these intraformational shear fractures and horizontal shear fractures improve the reservoir porosity and permeability, thus serving as an important storage space and primary fluid-flow channels in the tight sandstones. The small faults may provide seepage channels in adjacent layers by cutting through layers. In addition, these intragranular and grain-boundary fractures increase the connectivity of the tight gas sandstones by linking tiny pores. The tectonic microfractures improve the seepage capability of the tight gas sandstones to some extent. Low-dip angle fractures are more abundant in the T₃X³ member than in the T₃X² and T₃X⁴ members. The fracture intensities of the sandstones in the T₃X³ member are greater than those in the T₃X² and T₃X⁴ members. The fracture intensities do not always decrease with increasing bed thickness for the tight sandstones. When the bed thickness of the tight sandstones is less than 1.0 m, the fracture intensities increase with increasing bed thickness in the T₃X³ member. Fluid inclusion evidence and burial history analysis indicate that the tectonic fractures developed over three periods. The first period was at the end of the Triassic to the Early Jurassic. The tectonic fractures developed during oil generation but before the matrix's porosity and permeability reduced, which suggests that these tectonic fractures could provide seepage channels for oil migration and accumulation. The second period was at the end of the Cretaceous after the matrix's porosity and permeability reduced but during peak gas generation, which indicates that gas mainly migrated and accumulated in the tectonic fractures. The third period was at the end of the Eogene to the Early Neogene. The tectonic fractures could provide seepage channels for secondary gas migration and accumulation from the Upper Triassic Xujiahe Formation into the overlying Jurassic Formation.     

Formation of low permeability reservoirs and gas accumulation process in the Daniudi Gas Field,Northeast Ordos Basin,China

The Daniudi Gas Field is a typical large-scale coal-generated wet gas field located in the northeastern Ordos Basin that contains multiple Upper Paleozoic gas-bearing layers and considerable reserves of gas. Based on integrated analysis of reservoir petrology, carbonate cement C–O isotope, geochemistry of source rocks and HC gas and numerical basin modeling, a comprehensive study focusing on the formation of low permeability reservoirs and gas generation process uncovers a different gas accumulation scene in Daniudi Gas Field. The gas accumulation discovered was controlled by the reservoir permeability reduction and gas generation process, and can be divided into two distinct stages by the low permeability reservoir formation time: before the low permeability reservoir formation, the less matured gas was driven by buoyancy, migrated laterally towards NE and then accumulated in NE favorable traps during Late Triassic to early Early Cretaceous; after the low permeability reservoir formation, highly matured gas was driven by excessive pressure, migrated vertically and accumulated in-situ or near the gas-generating centers during early to late Early Cretaceous. The coupling relationship between reservoir diagenetic evolution and gas generation process controlled on gas accumulation of the Daniudi Gas Field. This study will aid in understanding the gas accumulation process and planning further E&D of the Upper Paleozoic super-imposed gas layers in the whole Ordos Basin and other similar super-imposed low permeability gas layer basins.     

Pore structure characteristics of tight sandstones in the northern Songliao Basin,China

Understanding the pore structure characteristics of tight gas sandstones is the primary purpose of reservoir evaluation and efforts to characterize tight gas transport and storage mechanisms and their controls. Due to the various pore types and multi-scale pore sizes in tight reservoirs, it is essential to combine several techniques to characterize pore structure. Scanning electron microscopy (SEM), nitrogen gas adsorption (N₂GA), mercury intrusion porosimetry (MIP) and nuclear magnetic resonance (NMR) were conducted on tight sandstones from the Lower Cretaceous Shahezi Formation in the northern Songliao Basin to investigate pore structure characteristics systematically (e.g., type and size distribution of pores) and to establish how significant porosity and permeability are for different pore types. The studied tight sandstones are composed of intergranular pores, dissolution pores and intercrystalline pores. The integration of N₂GA and NMR can be used as an efficient method to uncover full pore size distribution (PSD) of tight sandstones, with pore sizes ranging from 2 nm to dozens of microns. The full PSDs indicate that the pore sizes of tight sandstones are primarily distributed within 1.0 μm. With an increase in porosity and permeability, pores with larger sizes contribute more to porosity. Intercrystalline pores and intergranular/dissolution pores can be clearly distinguished on the basis of mercury intrusion and surface fractal. The relative contribution of intercrystalline pores to porosity ranges from 58.43% to 91.74% with an average of 79.74%. The intercrystalline pores are the primary contributor to pore space, whereas intergranular/dissolution pores make a considerably greater contribution to permeability. A specific quantity of intergranular/dissolution pores is the key to producing high porosity and permeability in tight sandstone reservoirs. The new two permeability estimation models show an applicable estimation of permeability with R² values of 0.955 and 0.962 for models using D_max (pore diameter corresponding to displacement pressure) and D_f (pore diameter at inflection point), respectively. These results indicate that both D_max and D_f are key factors in determining permeability.     

Diagenetic history of tight sandstones and gas entrapment in the Yulin Gas Field in the central area of the Ordos Basin,China

The Ordos Basin is a large cratonic basin with an area of 250,000 km² in central China. Upper Paleozoic coals and shales serve as gas source rocks with peak generation and migration at the end of the early Cretaceous. Recent exploration has verified the huge gas potential in the “basin-centered gas accumulation system” (BCGAS). However, the mechanism for the gas accumulation is controversial. With an integrated approach of thin-section petrography, ultra-violet fluorescence microscopy, fluid inclusion microthermometry, Raman microspectrometry, scanning electron microscopy, and X-ray diffractometry, we identified diagenetic trapping and evaluated the diagenetic history of sandstone reservoirs in the Yulin Gas Field in the central area, where structural, stratigraphic and/or sedimentary lithologic traps have not been found. It was revealed that three phases of diagenesis and hydrocarbon charging occurred, respectively, in the late Triassic, late Jurassic and at the end of the early Cretaceous. In the first two phases, acidic water entered the reservoir and caused dissolution and cementation, resulting in porosity increase. However, further subsidence and diagenesis, including compaction and cementation, markedly reduced the pore space. At the end of the early Cretaceous, the bulk of the gas migrated into the tight reservoirs, and the BCGAS trap was formed. In the updip portion of this system, cementation continued to occur due to low gas saturation and has provided effective seals to retain gas for a longer period of time than water block in the BCGAS. The mechanism for the gas entrapment was changed from water block by capillary pressure in the BCGAS to diagenetic sealing. The diagenetic seals in the updip portion of the sand body were formed after gas charging, which indicates that there is a large hydrocarbon exploration potential at the basin-centered area.     

Origin and distribution of hydrogen sulfide in the Yuanba gas field,Sichuan Basin,Southwest China

The Yuanba gas field in the Permian Changxing Formation (P₂c), which exhibits wide variations in its hydrogen sulfide (H₂S) concentration (1.20–12.16%), is a typical sour gas field in the northern Sichuan Basin. The sulfur-rich reservoir's solid bitumen (atomic S/C ratios are 0.032–0.142), and late calcite cement δ¹³C values, which are smaller than the δ¹³C values of the host dolostone, indicate that the H₂S originated from thermal sulfate reduction (TSR) and oil was involved in TSR. The gas souring index (GSI) of P₂c's gases is generally lower than 0.1. The ethane δ¹³C values increase as the GSI increases, although no obvious increase was observed in the methane δ¹³C values. The calcite cements' δ¹³C values (−15.36 to +4.56‰) in dolostone are heavier than the typical reported values, which implies that only limited heavy hydrocarbon gases were involved in TSR. No anhydrites developed in P₂c's reservoirs, and dissolved sulfate anions (SO₄²⁻) were mainly enriched during dolomitization. Insufficient dissolved SO₄²⁻ most likely caused the lower H₂S concentrations in the Permian to Triassic reservoirs in the northeastern Sichuan Basin compared to the Permian Khuff Formation in Saudi Arabia and the Jurassic Smackover Formation in Mississippi. Except for the SO₄²⁻ in residual water in paleo-oil zones, SO₄²⁻ from bottom water may also be involved in TSR; therefore, oil reservoirs with bottom water have more SO₄²⁻ and can produce more H₂S than pure oil reservoirs. This phenomenon may be the main cause of the great difference in the H₂S concentrations between reservoirs, while gravitational differentiation during late uplift most likely creates differences in H₂S concentrations in a single reservoir. Carbon dioxide (CO₂), which has a relatively heavy δ¹³C value (−3.9 to −0.3‰), may be the combined result of TSR, the balance between CO₂ and inorganic fluid systems, and carbonate decomposition.     

Hydrocarbon generation and expulsion characteristics of Eocene source rocks in the Huilu area,northern Pearl River Mouth basin,South China Sea: Implications for tight oil potential

In recent years, new oil reservoirs have been discovered in the Eocene tight sandstone of the Huilu area, northern part of the Pearl River Mouth basin, South China Sea, indicating good prospects for tight oil exploration in the area. Exploration has shown that the Huilu area contains two main sets of source rocks: the Eocene Wenchang (E₂w) and Enping (E₂e) formations. To satisfy the requirements for further exploration in the Huilu area, particularly for tight oil in Eocene sand reservoirs, it is necessary to re-examine and analyze the hydrocarbon generation and expulsion characteristics. Based on mass balance, this study investigated the hydrocarbon generation and expulsion characteristics as well as the tight oil resource potential using geological and geochemical data and a modified conceptual model for generation and expulsion. The results show that the threshold and peak expulsion of the E₂w source rocks are at 0.6% vitrinite reflectance and 0.9% vitrinite reflectance, respectively. There were five hydrocarbon expulsion centers, located in the western, eastern, and northern Huizhou Sag and the southern and northern Lufeng Sag. The hydrocarbon yields attributed to E₂w source rocks are 2.4 × 10¹¹ tons and 1.6 × 10¹¹ tons, respectively, with an expulsion efficiency of 65%. The E₂e source rock threshold and peak expulsion are at 0.65% vitrinite reflectance and 0.93% vitrinite reflectance, respectively, with hydrocarbon expulsion centers located in the centers of the Huizhou and Lufeng sags. The yields attributed to E₂e source rocks are 1.1 × 10¹¹ tons and 0.2 × 10¹¹ tons, respectively, with an expulsion efficiency of 20%. Using an accumulation coefficient of 7%–13%, the Eocene tight reservoirs could contain approximately 1.3 × 10¹⁰ tons to 2.3 × 10¹⁰ tons, with an average of 1.8 × 10¹⁰ tons, of in-place tight oil resources (highest recoverable coefficient can reach 17–18%), indicating that there is significant tight oil potential in the Eocene strata of the Huilu area.     

Quantitative analyses of porosity evolution in tight grainstones: A case study of the Triassic Feixianguan formation in the Jiannan gas field,Sichuan Basin,China

Tight grainstones, although widespread throughout the Lower Triassic Feixianguan Formation in the Sichuan Basin, have received little attention, in part, due to their lower porosity and greater heterogeneity relative to their dolostone counterparts. Based on data from cores and thin sections, as well as petrophysical properties, the Feixianguan grainstones, representing a major gas reservoir in the Jiannan gas field were systemically analysed to better understand porosity evolution in tight carbonates that have experienced original oil accumulation and subsequent thermal cracking during progressive burial. The grainstones were divided into two types according to whether pyrobitumen was present, and their porosity evolutions were quantitatively reconstructed. Taking 40% as the original porosity, the grainstones without pyrobitumen, which were ineffective palaeo-oil reservoirs, lost 21.94% and 3.13% of their porosities through marine and burial calcite cementation, respectively, and 13.34% by compaction, and have a current porosity of 1.59%, thus allowing them to serve as major present-day gas reservoirs. Comparatively, pyrobitumen-bearing grainstones, which were once palaeo-oil reservoirs, lost 23.96% and 2.36% of their porosities through marine and burial calcite cementation, respectively; 11.4% by compaction, and 1.44% by pyrobitumen and have a current porosity of 0.84%, thus making them ineffective gas reservoirs. This study provides a quantitative understanding of the close association between porosity evolution and reservoir effectiveness for the palaeo-oil charge and present-day gas accumulation with respect to diagenetic history, which is useful for the future exploration in tight gas limestone reservoirs.     

Quantitative impact of diagenesis on reservoir quality of the Triassic Chang 6 tight oil sandstones,Zhenjing area,Ordos Basin,China

The Upper Triassic Chang 6 sandstone, an important exploration target in the Ordos Basin, is a typical tight oil reservoir. Reservoir quality is a critical factor for tight oil exploration. Based on thin sections, scanning electron microscopy (SEM), X-ray diffraction (XRD), stable isotopes, and fluid inclusions, the diagenetic processes and their impact on the reservoir quality of the Chang 6 sandstones in the Zhenjing area were quantitatively analysed. The initial porosity of the Chang 6 sandstones is 39.2%, as calculated from point counting and grain size analysis. Mechanical and chemical compaction are the dominant processes for the destruction of pore spaces, leading to a porosity reduction of 14.2%–20.2% during progressive burial. The porosity continually decreased from 4.3% to 12.4% due to carbonate cementation, quartz overgrowth and clay mineral precipitation. Diagenetic processes were influenced by grain size, sorting and mineral compositions. Evaluation of petrographic observations indicates that different extents of compaction and calcite cementation are responsible for the formation of high-porosity and low-porosity reservoirs. Secondary porosity formed due to the burial dissolution of feldspar, rock fragments and laumontite in the Chang 6 sandstones. However, in a relatively closed geochemical system, products of dissolution cannot be transported away over a long distance. As a result, they precipitated in nearby pores and pore throats. In addition, quantitative calculations showed that the dissolution and associated precipitation of products of dissolution were nearly balanced. Consequently, the total porosity of the Chang 6 sandstones increased slightly due to burial dissolution, but the permeability decreased significantly because of the occlusion of pore throats by the dissolution-associated precipitation of authigenic minerals. Therefore, the limited increase in net-porosity from dissolution, combined with intense compaction and cementation, account for the low permeability and strong heterogeneity in the Chang 6 sandstones in the Zhenjing area.     

Numerical simulation of hydrocarbon migration in tight reservoir based on Artificial Immune Ant Colony Algorithm: A case of the Chang 81 reservoir of the Triassic Yanchang Formation in the Huaqing area,Ordos Basin,China

The hydrocarbon migration in tight reservoirs is a complex process, the fluid flow patterns of which are notably different from those of conventional reservoirs. Therefore, specific mathematical models are needed to simulate the secondary hydrocarbon migrations. This study presents a numerical simulation method based on Artificial Immune Ant Colony Algorithm (AIACA) to simulate the secondary hydrocarbon migrations in tight reservoirs. It consists of three core parts: (1) the release modes of artificial ants based on the intensity of hydrocarbon generation; (2) the wandering patterns of artificial ants under the control of the dynamic field and the distribution of pheromones; (3) the updating modes of pheromones based on the changes in reservoir wettability. The simulation of secondary migration can be realized by the observing the dynamic movements and accumulations of the artificial ants. The method has been tested in the Chang 8₁ tight sandstone reservoir, which is part of the Triassic Yanchang Formation in the Huaqing Area, Ordos Basin in China, and proved to be successful in matching the current data in exploration and development.     

Impact of diagenesis on reservoir quality and heterogeneity of the Upper Triassic Chang 8 tight oil sandstones in the Zhenjing area,Ordos Basin,China

Reservoir quality and heterogeneity are critical risk factors in tight oil exploration. The integrated, analysis of the petrographic characteristics and the types and distribution of diagenetic alterations in the Chang 8 sandstones from the Zhenjing area using core, log, thin-section, SEM, petrophysical and stable isotopic data provides insight into the factors responsible for variations in porosity and permeability in tight sandstones. The results indicate that the Chang 8 sandstones mainly from subaqueous distributary channel facies are mostly moderately well to well sorted fine-grained feldspathic litharenites and lithic arkose. The sandstones have ultra-low permeabilities that are commonly less than 1 mD, a wide range of porosities from 0.3 to 18.1%, and two distinct porosity-permeability trends with a boundary of approximately 10% porosity. These petrophysical features are closely related to the types and distribution of the diagenetic alterations. Compaction is a regional porosity-reducing process that was responsible for a loss of more than half of the original porosity in nearly all of the samples. The wide range of porosity is attributed to variations in calcite cementation and chlorite coatings. The relatively high-porosity reservoirs formed due to preservation of the primary intergranular pores by chlorite coatings rather than burial dissolution; however, the chlorites also obstruct pore throats, which lead to the development of reservoirs with high porosity but low permeability. In contrast, calcite cementation is the dominant factor in the formation of low-porosity, ultra-low-permeability reservoirs by filling both the primary pores and the pore throats in the sandstones. The eogenetic calcites are commonly concentrated in tightly cemented concretions or layers adjacent to sandstone-mudstone contacts, while the mesogenetic calcites were deposited in all of the intervals and led to further heterogeneity. This study can be used as an analogue to understand the variations in the pathways of diagenetic evolution and their impacts on the reservoir quality and heterogeneity of sandstones and is useful for predicting the distribution of potential high-quality reservoirs in similar geological settings.     

Impacts of the tectonic stress field on natural gas migration and accumulation: A case study of the Kuqa Depression in the Tarim Basin,China

Stress, fluid and temperature are three of the major factors that impact natural gas migration and accumulation. In order to study the influences of tectonic stress field on natural gas migration and accumulation in low-permeability rocks, we take the Kuqa Depression as an example and analyze the evolution of the structure and tectonic stress field at first. Then we study the influences of tectonic stress field at different tectonic episodes on fractures and fluid potentials through the numerical simulation method on the section across the KL2 gas field. We summarize two aspects of the impact of the tectonic stress field on natural gas migration and accumulation. Firstly, under the effects of the tectonic stress field, the rock dilation increases with the added stress and strain, and when the shear stress of rock exceeds its shear strength, the shear fractures are well developed. On one hand, the faults which communicate with the hydrocarbon source rocks become the main pathways for natural gas migration. On the other hand, these positions where fractures are well developed near faults can become good reservoirs for natural gas accumulation. Secondly, because fluid potentials decrease in these places near the faults where fractures are well developed, natural gas can migrate rapidly along the faults and accumulates. The impact of tectonic stress fields on natural gas migration and accumulation allows for hydrocarbon migration and accumulation in the low-permeability rocks in an active tectonic compressive setting.     

珠江口盆地东部珠一坳陷古近系不同类型烃源岩和原油热裂解生气特征

HZ26-6凝析气田为珠江口盆地东部珠一坳陷首次获得重大发现的凝析气藏,打破了近40年来珠一坳陷围绕原油展开勘探的传统局面,揭示了该区富油洼陷巨大的天然气勘探潜力。然而,对于珠一坳陷文昌组中深湖相泥岩这一主力油源岩的生气潜力以及生气特征,以及恩平组河沼相煤系烃源岩供气能力的认识则较为模糊,缺乏系统的生气机制研究。此类问题则可直接确定珠一坳陷天然气成因归属及勘探潜力。针对该问题,采用黄金管-高压釜封闭体系热模拟实验,对珠一凹陷典型文昌组和恩平组不同类型烃源岩和原油热裂解生成天然气过程及天然气碳同位素演化特征进行系统分析,并探讨惠州凹陷HZ26-6凝析气田天然气成因及主力气源岩。研究认为,珠一坳陷恩平组湖沼相煤系泥岩最大累积烃类气体产率为230.8 mL/g.TOC,甲烷产气率在Ro为1.1%之后呈指数增长,呈现出持续生气特征,且以干酪根裂解气为主;文昌组中深湖相泥岩最大累积烃类气体产率达428.30 mL/g.TOC,在～1.6% Ro阶段后开始大量产气,且高产气率实际上主要由油的二次裂解贡献为主;原油裂解气最大产率达693.6 mL/g.TOC,远高于文昌组及恩平组泥岩最大产气率,不同类型烃源岩及原油样品生成天然气组分碳同位素演化特征差异性明显;珠一坳陷文昌组偏腐泥型泥岩在1.3%～1.6% Ro阶段所生天然气甲烷及乙烷碳同位素组成与HZ26-6凝析气藏天然气具有较好的匹配性,为HZ26-6凝析气藏天然气的主力气源岩,恩平组湖沼相煤系泥岩及原油裂解气对该气藏未见明显成藏贡献。     

东海陆架盆地西湖凹陷孔雀亭区油气来源及运移方向

孔雀亭区是西湖凹陷油气勘探重点区带,油气来源及运移方向不清限制了勘探的进一步拓展。基于油气特征及分布研究,通过开展烃源岩及原油生物标志化合物特征对比分析、天然气成熟度计算,综合厘定了油气来源;结合油气运移效应分析明确了原油及天然气运移方向。结果表明,孔雀亭区原油主要来自平湖组下段和宝石组烃源岩,平湖组中段及上段少量贡献,原油自斜坡内生油次洼向高部位运移,是原油优势运聚方向;天然气具有斜坡带本地烃源岩及西次凹双重来源,以西次凹贡献为主,天然气自斜坡低带向高带侧向运移,并沿断层与斜坡带烃源岩自生天然气混合呈现垂向运移特征,斜坡低部位是天然气勘探有利区带。     

In situ stress field evaluation of deep marine tight sandstone oil reservoir: A case study of Silurian strata in northern Tazhong area,Tarim Basin,NW China

Deep marine tight sandstone oil reservoirs are the subject of considerable research around the world. This type of reservoir is difficult to develop due to its low porosity, low permeability, strong heterogeneity and anisotropy. A marine tight sandstone oil reservoir is present in the Silurian strata in the northern Tazhong area of the Tarim Basin, NW China, at a depth of more than 5000 m. The porosity is between 6% and 8%, and the gas permeability is between 0.1 and 1 × 10⁻³ μm². The features of this type of reservoir include the poor effects of conventional fracturing modifications and horizontal wells, which can lead to stable and low levels of production after staged fracturing. Here, we conduct a comprehensive evaluation of the mechanical properties of the rock and the in situ stress of the target tight sandstones by using numerous mechanical and acoustic property tests, conducing crustal stress analysis and using data from thin section observations. The dispersion correction technique is used to transform velocity at the experimental high frequency (1 MHz) to velocity at the logging frequency (20 kHz). The logging interpretation models of the transverse wave offset time, mechanical parameters and in situ stress are calculated, and each model represents a high precision prediction. Simulating the in situ stress field of the Silurian strata using a three-dimensional finite element method demonstrates that the average error between the simulation result and the measured value is less than 6%. The planar distribution of each principal stress is mainly controlled by the burial depth and fault distribution. By conducting in situ stress orientation analysis for the target layer via the analysis of paleomagnetism, borehole enlargement, fast shear wave orientation and stress field simulation, we show that the direction of the maximum horizontal stress is N45E. In this paper, a typical and successful comprehensive evaluation of the stress field of the deep tight sandstone oil reservoir is provided.     

南海北部气烟囱成因及其与油气及水合物运聚成藏关系

南海北部大陆边缘盆地油气勘探及天然气水合物调查与勘查评价中,地球物理资料尤其是二维/三维地震剖面上常见不同类型、不同特征且与油气藏及天然气水合物藏密切相关的地震反射模糊带等地震地质异常体,即“气烟囱”或“流体底辟”或“含气陷阱”。本文拟重点研究“气烟囱”成因及其与油气及天然气水合物运聚成藏的关系。油气勘探实践表明,气烟囱往往与油气藏尤其是天然气水合物藏伴生,且油气及水合物多处于其上覆或两侧位置附近。通过大量油气及天然气水合物勘探实践、地质地球物理资料综合分析及油气地球化学分析等,充分证实了气烟囱与其上覆或两侧附近的油气及天然气水合物藏具有密切的成因联系。研究表明,气烟囱作为连接和沟通烃源/气源供给系统与油气藏及水合物藏之间的重要桥梁和纽带,是油气（水合物）勘探中判识追踪油气藏及水合物藏成因、确定其烃源/气源供给系统活动特征的重要依据和指示。因此,深入分析研究气烟囱系统成因及类型,不仅能够追踪探索和判识确定油气及水合物成因,阐明其运聚成藏规律及控制因素,而且能够指导油气及水合物勘探部署与综合评价工作。同时,通过油气及水合物成因的地球化学分析,亦可判识确定其气烟囱成因及其对油气和水合物运聚成藏的控制影响作用。     

东海盆地X凹陷Y气田的天然气成因、成藏模式及勘探意义

本文旨在厘清东海盆地X凹陷Y气田天然气成因,建立成藏模式,以指导下步勘探部署。本文从天然气组分、烷烃气碳同位素、轻烃、凝析油生物标志化合物等分析入手,系统研究了油气成因类型及来源,并结合构造演化史、生烃史分析,建立了Y气田成藏模式,提出了大中型气田的勘探方向。主要认识如下：（1）天然气组分碳同位素、轻烃和埋藏史分析表明,Y气田天然气为凹中始新统平湖组烃源岩在龙井运动期（距今13 Ma）生成的高成熟煤型气;（2）凝析油姥鲛烷/植烷、规则甾烷等特征,反映了凹中区平湖组烃源岩发育于弱氧化−弱还原潮坪、潟湖沉积环境,生烃母质中存在一定数量的低等水生生物;（3）Y气田具有“凹中区平湖组烃源岩、花港组大型水道砂储集体、挤压构造作用”时空耦合的成藏模式,明确了凹中挤压背斜带是X凹陷大中型气田勘探的主攻方向。     

Impact of sedimentology,diagenesis, and solid bitumen on the development of a tight gas grainstone reservoir in the Feixianguan Formation,Jiannan area,China: Implications for gas exploration in tight carbonate reservoirs

Tight gas grainstone reservoirs in the third member of the Feixianguan Formation, Jiannan area, evolved from a paleo-oil accumulation as evidenced from abundant solid reservoir bitumen. Porosity evolution of the grainstones was studied by evaluating relative influences of sedimentology, diagenesis, and solid bitumen formed during cracking of accumulated oils. Grainstones exhibited regional-distinct effectiveness for paleo-oil and present-gas accumulations during oil window and subsequent gas window diagenesis. In the southern zone where grainstones were not subjected to subaerial exposure and meteoric diagenesis in the early diagenetic stage, paleoporosity at the time of oil charge was mainly controlled by sedimentologic factors (e.g., grain size, sorting, and grain type), and paleo-oil reservoirs only occurred in the ooid-dominated grainstones with good sorting and coarse grain size. In contrast, in the northern zone meteoric diagenesis was responsible for paleoporosity preservation due to the early mineral stabilization of grains and meteoric calcite cementation, which caused grainstones greater resistance to compaction. Hence, most of the grainstones in the northern zone, regardless of textural variables, formed effective reservoirs for paleo-oil accumulation. As the oil cracked to gas with increasing depth and temperature during the late oil window and initial gas window, solid bitumen occluded reservoir pores to varying degrees and caused paleo-oil reservoirs to be significantly heterogeneous or completely ineffective for gas accumulation. In contrast, most grainstones that were once ineffective oil reservoirs transformed into effective gas reservoirs due to no or minor influence of solid bitumen precipitation. The model of reservoir transformation development of tight grainstones provides a plausible explanation for key observations concerning the diagenetic and distribution differences between paleo-oil and present-gas reservoirs. It is useful in predicting the distribution of potential reservoirs in carbonate strata in future exploration.     

Spatial distribution and geochemistry of the nearshore gas seepages and their implications to natural gas migration in the Yinggehai Basin,offshore South China Sea

About 120 gas seepage vents were documented along the west and southwest coast of the Hainan Island, South China Sea, in water depths usually less than 50 m. The principal seepage areas include the Lingtou Promontory, the Yinggehai Rivulet Mouth, Yazhou Bay, the Nanshan Promontory and the Tianya Promontory. They occur along three major zones, reflecting the control by faults and lateral conduits within the basement. It is estimated that the total gas emission from these seepage vents is 294–956 m³/year. The seepage gases are characterized by a high CH₄ content (76%), heavy δ¹³C₁ values (−38 to −33‰) and high C₁/C_1–5 ratios (0.95–1.0), resembling the thermogenic gases from the diapiric gas fields of the Yinggehai Basin. Hydrocarbon–source correlation shows that the hydrocarbons in the sediments from seepage areas can be correlated with the deeply buried Miocene source rocks and sandstone reservoirs in the central depression. The 2D basin modeling results based on a section from the source rock center to the gas seepage sites indicate that the gas-bearing fluids migrated from the source rocks upward through faults or weak zones encompassed by shale diapirism or in up-dip direction along the sandstone-rich strata of Huangliu Formation to arrive to seabed and form the nearshore gas seepages. It is suggested that the seepage gases are sourced from the Miocene source rocks in the central depression of the Yinggehai Basin. This migration model implies that the eastern slope zone between the gas source area of the central depression and the seepage zone is also favorable place for gas accumulation.