Organic geochemical identification of reservoir oil–gas–water layers in the Junggar Basin,NW China

The identification of reservoir oil–gas–water layers is a fundamental task in petroleum exploration and exploitation, but is difficult, especially in cases of complex hydrocarbon migration and accumulation. In such cases, hydrocarbon remigration and dysmigration take place very commonly, leading to the presence of residual or paleo-oil accumulations and layers, which cannot be easily identified or misinterpreted as oil layers by conventional logging and geophysical data. In this paper, based on a case study in the Luxi area of the central Junggar Basin, NW China, we seek to characterize such layers in terms of organic geochemistry. We suggest specific indicator parameters of organic geochemistry such as the chloroform bitumen content of reservoir extracts, which is usually >1.0% in oil layers. We explore the application of grains containing oil inclusions (GOI) (the ratio of mineral grains containing oil inclusions to the total number of mineral grains) for the identification of oil–gas–water layers in the Junggar Basin for the first time; this method has been used elsewhere. The maximum GOI values for the oil layers, oil–water layers, water layers and dry layers are >11%, 7%–11%, 6%–7% and <6%, respectively. In addition, gas layers and heavy-oil layers that are difficult to identify by conventional organic geochemical parameters were identified using biomarkers. The typical characteristics of the soluble reservoir bitumen in the gas layers include a much greater abundance of tricyclic terpanes (two times in general) relative to pentacyclic terpanes and a tricyclic terpane distribution of C₂₀ > C₂₁ > C₂₃. In contrast, the typical characteristic of the heavy-oil layers is the presence of 25-norhopanes in reservoir bitumen extracts. These specific indicators can be applied in the Junggar Basin and in similar settings elsewhere.     

Heat oscillation in the upper ocean of the southern South China Sea

Data used in this study are temperature/depth profiles taken over the upper 400 m of the ocean in the southern South China Sea (4°-14° N, 106°-120° E) for the period 1961-1973. The data are analyzed on the grid 2 (latitude) by 2 (longitude) in space and bimonthly in time. The vertically averaged temperature (TAV) over the upper 100 m of the ocean is calculated as the estimate of the heat content in the upper ocean.The TAV is cooler in the northwest region of the study area and warmer in the southeast in the annual and seasonal mean figures. The first EOF (Empirical Orthogonal Function) of anomalous TAV accounts for 41 % of the total variance for the period 1961-1973. The time function associated with it displays a significant interannual changes in the heat content, with 2-4 a oscillation period and associated with the ENSO events. During ENSO event TAV increases with the tendency of increasing towards equator along the basin. This anomalous states also exist in the water layers below 100 m depth. T     

Numerical computation of tidal currents in the eastern and southern parts of the East China Sea

Numerical simulation on diurnal and semidiurnal tidal currents is made for the eastern and southern parts of the East China Sea bounded by the Tsushima, islands of Kyushu and Ryukyu in the east and extending to the central Taiwan Strait in the south. The numerical computation shows that the rapid variation in the seabed topography near the Okinawa Trough may cause computational instability and this instability can be removed by setting a suitable lateral eddy viscosity. The computed results are in good agreement with the observations and indicate that the tidal currents in the greater part of the area studied rotate clockwise. An M2 current-amphidromic point exists in the southern part of the Korea Strait and another one appears in the west of Okinawa with less certainty. K1 and M2 cotidal charts based on the observed and computed tidal currents in the sea and the observed tides on the coast are also given.     

The distribution of methane in the Tokyo-wan

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How does the pore-throat size control the reservoir quality and oiliness of tight sandstones? The case of the Lower Cretaceous Quantou Formation in the southern Songliao Basin,China

Pore-throat size is a very crucial factor controlling the reservoir quality and oiliness of tight sandstones, which primarily affects rock-properties such as permeability and drainage capillary pressure. However, the wide range of size makes it difficult to understand their distribution characteristics as well as the specific controls on reservoir quality and oiliness. In order to better understand about pore-throat size distribution, petrographic, scanning electron microscopy (SEM), pressure-controlled mercury injection (PMI), rate-controlled mercury injection (RMI), quantitative grain fluorescence (QGF) and environmental scanning electron microscopy (ESEM) investigations under laboratory pressure conditions were performed on a suite of tight reservoir from the fourth member of the Lower Cretaceous Quantou Formation (K₁q₄) in the southern Songliao Basin, China. The sandstones in this study showed different types of pore structures: intergranular pores, dissolution pores, pores within clay aggregates and even some pores related to micro fractures. The pore-throat sizes vary from nano- to micro-scale. The PMI technique views the pore-throat size ranging from 0.001 μm to 63 μm and revealed that the pore-throats with radius larger than 1.0 μm are rare and the pore-throat size distribution curves show evident fluctuations. RMI measurements indicated that the pore size distribution characteristics of the samples with different porosity and permeability values look similar. The throat size and pore throat radius ratio distribution curves had however significant differences. The overall pore-throat size distribution of the K₁q₄ tight sandstones was obtained with the combination of the PMI and RMI methods. The permeability is mainly contributed by a small part of larger pore-throats (less than 30%) and the ratio of the smaller pore-throats in the samples increases with decreasing permeability. Although smaller pore-throats have negligible contribution on reservoir flow potential, they are very significant for the reservoir storage capacity. The pore-throats with average radius larger than 1.0 μm mainly exist in reservoirs with permeability higher than 0.1mD. When the permeability is lower than 0.1mD, the sandstones are mainly dominated by pore-throats with average radius from 0.1 μm to 1.0 μm. The ratio of different sized pore-throats controls the permeability of the tight sandstone reservoirs in different ways. We suggest that splitting or organizing key parameters defining permeability systematically into different classes or functions can enhance the ability of formulating predictive models about permeability in tight sandstone reservoirs. The PMI combined with QGF analyses indicate that oil emplacement mainly occurred in the pore-throats with radius larger than about 0.25–0.3 μm. This result is supported by the remnant oil micro-occurrence evidence observed by SEM and ESEM.     

Peculiarities of the Earth’s crust sedimentary layer structure in the Falkland Basin

An electronic databank including the results of seismic investigations and schemes of the sediment thickness’s distribution patterns was built up for two seismostratigraphic complexes in the Falkland Basin. The interface’s border was dated, and the sedimentation rates were estimated for each complex. An integrated map of the cumulative thickness of the deposits and sedimentation rates was developed. The lowest limits of the parameters of the sedimentation process were characterized for the sedimentary layers affected by compaction and erosion.     

Hydrological characterization of the Ob’ Inlet in the summer and autumn seasons

The assessment of the hydrological regime under the high- and low-water conditions in the Ob’ Inlet was based on the results of two comprehensive surveys performed by the VNIRO and IO RAS in the summer and autumn of 2010. The summer hydrological regime, which is associated with the peak of the biological activity, was compared with the late autumn one, which was closely followed by the freeze up. Special attention was paid to the assessment of the interseasonal variability of the hydrological state and the processes that continued in the area of the mixing of the riverine waters (the outflux from the Ob’ Inlet) and the water of the Kara Sea. We followed the transition of the hydrologic front from the summer stratification (high waters) into the autumn distortion driven by the intensive mixing of the waters under a sharp decrease in the river discharge.     

Variability of the circulation in the southern Huanghai Sea and East China Sea during the two investigative cruises in June 1999

1IntroductionAlotofworkonthestudyofthecircula-tionintheHuanghai(Yellow)Sea(HS)andEastChinaSea(ECS)hasbeenmadeandreviewedbyscientists,suchasSu(1998),Suetal.(1994),Guan(1985),YuanandSu(1983,2000),Yuanetal.(1997,1988,1994,2001),Tangetal.(2000)andsoon.Inthispapertheseworks willnotbereviewedagainduetolimitationofpages.Thejointinvestigationontheair-seainteractionprocessofcycloneoutbreakoverthesouthernHuanghaiSeaandEastChinaSeawascarriedoutinthecooperativestudybytheChinese(in-clusiveofTaiwa…     

A fuzzy distinguishability on species composition similarities of pelagic fishes in different years in the southern Taiwan Strait

I\rnooUcrIoxThe drpdric fish species cor-npositlon is an imPOrtant element 1n the study of fish ecologyand plays an important guiding role ln fishery preduction and roouLrces rnanagement. Lin(l988) and Zhang (1994 and l995) have studied the simi1drities of mpulation COtwsition ofame s1ngle species of different yea-rs including hairtail Trichuras haumee and yellDw cndertwinena cmi. But no rePOrt is available on the discridrination of the sidrildrities amongmuLlt1ple sPecies composition of…     

Diagenetic evolution of the upper Cretaceous limestone and sandstone exhumed reservoirs in the western Basque–Cantabrian Basin,North Spain

The Basque–Cantabrian Basin (NE Spain) has been considered one of the most interesting areas for hydrocarbon exploration in the Iberian Peninsula since the 60th to 70th of last century. This basin is characterized by the presence of numerous outcrops of tar sands closely associated with fractures and Triassic diapirs. The aims of this work is to establish the diagenetic evolution of the Upper Cretaceous reservoir rocks with special emphasis in the emplacement of oil and their impact on reservoir quality. The studied rocks are constituted of carbonates and sandstones that contain massive quantities of bitumen filling vugs and fractures.Petrographic results indicate that the carbonate rocks from Maestu outcrops are bioclastic grainstones and wackestones, whereas the tar sandstones from Atauri and Loza outcrops are dominated by quartzarenites and subordinated subarkoses. The paragenetic sequence of the main diagenetic phases and processes include, pyrite, bladed and drusy calcite cement, calcite overgrowths, silicification of bioclasts and microcrystalline rhombic dolomite cement, and first stage of oil emplacement, blocky calcite cement, coarse crystalline calcite cement, calcitized dolomite, calcite veins, saddle dolomite and stylolites filled by the second phase of oil entrance. Together with the above mentioned diagenetic alterations, the arenites are affected by early kaolinitization of feldspars and the scarce formation of clay rim and epimatrix of illite. All sandstones and dolomitized carbonate rocks show high intercrystalline and intergranular porosity which is full by biodegraded hydrocarbons (solid bitumen). The biodegradation affects alkanes, isoprenoids and partially hopanes and steranes saturated hydrocarbons. Aromatics hydrocarbons, like naphthalenes, phenanthrenes, dibenzothiophenes and triaromatics are also affected by biodegradation. Results indicate that the first HC emplacement corresponds to early stage of calcite and dolomite cementation, and the second and more important emplacement is related to fracturation processes resulting in the formation of excellent reservoirs.     

The structure of the Falkland Basin’s lithosphere

The peculiarities of the crustal structure within the Falkland Basin have been discussed. Maps of the free-air and Bouguer (2.3 g/cm³) gravity anomalies and their transforms have been made. The complex analysis of the anomalous gravity field has allowed us to confirm the continental origin of the crust. The zoning of the crust has been performed. The crust is thinned and is enriched in basic and ultrabasic intrusions. A map demonstrating the distribution of the faults within the studied water area has been made. A conclusion has been reached about the leading role played by tension processes throughout the evolution of the crust within the studied water area.     

Late Eocene–early Miocene provenance evolution of the Crocker Fan in the southern South China Sea

There are many large-scale Cenozoic sedimentary basins with plentiful river deltas, deep-water fans and carbonate platforms in the southern South China Sea. The Crocker Fan was deposited as a typical submarine fan during the late Eocene–early Miocene, and stretches extensively across the entire Sarawak–Sabah of the northern Borneo area. However, systematic analyses are still lacking regarding its sediment composition and potential source suppliers. No consensus has been reached yet on the provenance evolution and sedimentary infilling processes, which seriously impeded the oil-and-gas exploration undertakings. By combining with sedimentary-facies identification, heavy mineral assemblages, elemental geochemistry and detrital zircon U-Pb dating, this paper aims to generalize an integrated analysis on the potential provenance terranes and restore source-to-sink pathways of the Crocker Fan. In general, the Crocker Fan was initially formed over the Cretaceous–lower/middle Eocene Rajang Group by an angular Rajang unconformity. The continual southward subduction of the proto-South China Sea resulted in magmatic activities and subsequent regional deformation and thrusting along the Lupar Line in the northern Borneo. The lowermost Crocker sequence is featured by a thick conglomerate layer sourced from in-situ or adjacent paleo-uplifts. From the late Eocene to the early Miocene, the Crocker Fan was constantly delivered with voluminous detritus from the Malay Peninsula of the western Sundaland. The Zengmu Basin was widely deposited with delta plain and neritic facies sediments, while the Brunei-Sabah Basin, to the farther east, was ubiquitously characterized by turbiditic sequences. The Crocker Fan successions are overall thick layers of modest-grained sandstones, which formed high-quality reservoirs in the southern South China Sea region.     

Abundance pattern of heterotrophic nanoflagellates in the southern Taiwan Strait

The analysis of 103 samples collected quantitatively from the southern Taiwan Strait (22°4'-24°3'N, 117°5'-119°9'E), China, in August 1997 indicates that the abundance of heterotrophic nanoflagellates (HNF) ranges from 391 to 1 846 ×103 cell/dm3, with an average of 949 × 103 cell/dm3, and 96.2% of cells are in size of 2-22 μm in all HNF met in the samples. The HNF cells are 9.83-45.79 μg/dm3 after conversion from cell number to carbon content, with an average of 22.82 μg/dm3 . The HNF abundance is relatively low in comparison with other areas. The nitrogen and phosphorus nutrients of the water are lower than previous investigations, which may be caused by the El Nino. The biomass of HNF is higher in southern waters, where cell concentration is 3-5 folds higher than that in other waters, and nearly 2-fold as high as the average of the investigated areas. The HNF is mainly habitat in 0-30 m water layer. Both horizontal and vertical HNF distribution must be influenced by hy-drographical dynamic pro     

The circulation in the southern Huanghai Sea and northern East China Sea in June 1999

On the basis of hydrographic data and current measurement (the mooring system, vessel-mounted ADCP and toward ADCP) data obtained in June 1999, the circulations in the southern Huang-hai Sea (HS) and northern East China Sea (ECS) are computed by using the modified inverse method. The Kuroshio flows northeastward through eastern part of the investigated region and has the main core at Section PN, a northward flow at the easternmost part of Section PN, a weaker anti-cyclonic eddy between these two northward flows, and a weak cyclonic eddy at the western part of Section PN. The above current structure is one type of the current structures at Section PN in ECS. The net northward volume transport (VT) of the Kuroshio and the offshore branch of Taiwan Warm Current (TWCOB) through Section PN is about 26.2×106m3/s in June 1999. The VT of the inshore branch of Taiwan Warm Current (TWCIB) through the investigated region is about 0.4×106m3/s. The Taiwan Warm Current (TWC) has much effect on the currents over the     

The amplifying effect of southern continental shelf of the East China Sea on semidiurnal tides

The coast of Zhejiang Province is a zone of maximum tidal ranges in China. One of the causes is the influence of the adjacent continental shelf. A model is presented in this paper, whose theory suggests that the amplitudes of semidiurnal tides should be amplified on the southern continental shelf of the East China Sea, while those of diurnal tides should not. The values computed from the equations are basically in agreement with observations.     

Geochemical changes of the terrigenous sediments in the southern South China Sea and their paleoenvironmental implications during the last 31 ky

Fifty-six subsamples of the 86GC core were collected from the southern South China Sea continental slope. Major and trace elements, including rare earth elements (REEs), of detrital matters in these sediments were measured. The patterns of chondrite normalized REEs and the discrimination plots based on major and trace elements, respectively, indicate that the terrigenous sediments around this area had been supplied with one dominating provenience during the last 31 ky. The co-operation of sea level changes with the East Asian winter monsoon-related rainfall and sea water circulations should be the main mechanism causing the geochemical characteristics variations. Higher ratios of Al/Ti and some other elements to Ti, except P/Ti and Mn/Ti, are present during the last glacial sea-level low stand and the winter monsoon periods owing to increased fluvial input of material with low Ti content from the Mekong River, followed by strengthened chemical weathering intensity, causing higher Al₂O₃ and most other elements contents. The elemental patterns imply general warm and very humid climate in the tropical areas during the last glacial times; however, the climate since the last deglaciation was very changeable, especially during the Holocene. Even so, it can still be certain that the climate during the early part (29–24 ky B.P.) of the last glacial maximum was much worse than during other stages. Additionally, it is very likely that the 8 k cold event and the Younger Dryas event have been impressed in the geochemical record of this core.     

Peculiarities of the Rock–Fluid System of the Subduction Zone in the South Caspian Basin

Izvestiya, Atmospheric and Oceanic Physics - The goal of this study is to identify the properties of the rock–fluid system in the subduction zone of lithospheric plates using the example of...     

Temporal variation of intertidal seagrass in southern China (2008–2014)

Understanding the temporal dynamics of seagrasses and the major influences on seagrass growth is critical for seagrass habitat conservation and administration. However, little work has been done regarding these issues in southern China. To examine inter-annual and seasonal variations of the intertidal Halophila ovalis community in southern China, we conducted quarterly sampling using the SeagrassNet methodology and assessed environmental conditions as well as direct anthropogenic impacts on the seagrass meadow from July 2008 to October 2014. Our study demonstrated strong inter-annual and seasonal dynamics of the intertidal seagrass meadow in the study area. Generally, the community performed best (highest seagrass cover, leaf area, shoot density, total biomass) in summer and worst in spring among the 4 seasons. The temporal variations in the seagrass community attributes (e.g. above-ground biomass) were significantly affected by precipitation, atmospheric visibility, and salinity, while leaf width was significantly negatively correlated with temperature, atmospheric visibility and salinity. Temperature was a major factor influencing the seagrass community (both macroalgae and seagrass), with temperature data showing an inverse relationship between seagrass and macroalgae. The above-ground: below-ground biomass ratio and leaf width of H. ovalis were the most sensitive plant parameters monitored when assessing environmental interactions. Human physical disturbances did not have a significant effect on seagrass dynamics in the study area. We concluded that long-term monitoring (like SeagrassNet) is valuable in understanding the relationship between environmental variables and seagrasses.     

Geochemical evolution of Oligocene–Middle Miocene sediments in the deep-water area of the Pearl River Mouth Basin,northern South China Sea

The deep-water area of the Pearl River Mouth Basin in the South China Sea has received much scientific attention since the Ocean Drilling Program (ODP) Leg 184 in 1999 due to its potential economic prospects and distinct tectono-sedimentary evolutionary processes. In this study, we present the composition of major and trace elements from two newly sampled deep-water boreholes (BY6 and LW3) in the Baiyun Sag of the southern Pearl River Mouth Basin. The geochemical evolution in the Oligocene–Middle Miocene, as well as potential controlling factors, are investigated based on a comparative study with previous data from ODP site 1148 and borehole PY33. The Chemical Index of Alteration (CIA) and A–CN–K plot reveal that the observed weathering trends are not compatible for the four discussed boreholes. Sedimentary sorting is primarily observed in borehole PY33, where data trend away from the A apex to the feldspar join in the A–CN–K plot and show a spread of Al₂O₃/SiO₂ and Nb/Zr ratios. Compared to chemical weathering and hydrodynamic sorting, provenance has a greater impact on sediment composition of the deep-water area. From the north, the Pearl River was the primary sediment supply. However, a positive Eu anomaly and the provenance discrimination diagrams (i.e., La/Th versus Th/Yb and Zr/Co versus Th/Co) reveal the mafic nature of borehole BY6 sediments in the Zhuhai–Lower Zhujiang (32.0–18.5 Ma) and Upper Hanjiang (13.8–10.5 Ma) formations. These compositions are unusual and differ from the well-defined felsic sources in the majority of the Baiyun Sag; these discrepancies are likely related to multistage magmatism. The sediments at site 1148 are characterized by slightly enriched heavy rare earth elements and relatively high Zr/Co ratios, which could possibly be caused by zircon enrichment from local sources.     

Characteristics of nitrogen forms in the southern Huanghai Sea surface sediments

The distributions of different forms of nitrogen in the surface sediments of the southern Huanghai Sea are different and affected by various factors. The contents of IEF-N, SOEF-N and TN gradually decrease eastward, and those of SAEF-N northward, while those of WAEF-N westward. Around the seaport of the old Huanghe (Yellow) River, the contents of both SOEF-N and TN are the highest. Among all the factors, the content of fine sediment is the predominant factor to affect the distributions of different forms of nitrogen. The contents of IEF-N, SOEF-N, and TN have visibly positive correlation with the content of f‘me sediments, and the correlative coefficient is 0.68, 0.58 and 0.71 respectively, showing that the contents of the three forms of nitrogen increase with those of f-me sediments. The content of WAEF-N is related to that of fine sediments to a certain extent, with a correlative coefficient of 0.35; while the content of SAEF-N is not related to that of fine sediments, showing that the content of SAEF-N is not controlled by fine grain-size fractions of sediments. In addition, the distributions of different forms of nitrogen are also interacted one another, and the contents of IEF-N and SOEF-N are obviously affected by TN, while those of inorganic nitrogen (WAEF-N, SAEF-N and IEF-N) are not affected by SOEF-N and TN obviously, although they are interacted each other.