Characteristics and genesis of the polygonal fault system in southern slope of the Qiongdongnan Basin,South China Sea

Based on 3D seismic data, the polygonal fault system (PFS) discovered in the southern slope of the Qiongdongnan (QDN) Basin was studied through fine seismic interpretation and coherent cube analysis. The results show that: ① the PFS is mostly composed of small plate-type faults, with fault length of 1–3 km, maximum fault throw of 20–40 m and dip angle of 25°–45°; ② the PFS is mainly observed in the Huangliu Formation, deposited in the early stage of fast slope depression; ③ the PFS is layer-bound and can be separated into two tiers by T31′ interface with obvious channel incision features; ④ the PF of tier2 exhibit “y” structural style, including two parallel faults, master fault and associated fault, dipping in opposite directions. Their intersection relationship can be divided into three classes, and 14 sub-classes based on the fault intersection relationship of master fault and its associated fault; ⑤ the PFS is dominated by two strikes: NE60° and NW150°, indicating that it was controlled by tensile stress produced by differential settlement between the Xisha uplift and QDN basin; and ⑥ its genesis was jointly controlled by the syneresis of clay minerals and overpressure cyclical dehydration.     

Benthic response to shellfish farming in Thau lagoon: Pore water signature

Vertical distributions of dissolved species across the sediment–water interface (SWI), including major cations (sodium, potassium, magnesium, calcium), minor cations (lithium, strontium, barium), redox sensitive species (dissolved manganese, iron, sulfate, sulfide, ammonium) and other chemical parameters (pH, alkalinity, soluble reactive phosphorous, dissolved silica) were studied in a Mediterranean lagoon used for intensive shellfish farming. In order to quantify the impact of this activity on diagenetic processes and the influence of seasonal changes, two stations contrasted with respect to organic carbon fluxes were sampled in Thau lagoon from March 2001 to August 2002 during four field campaigns in winter, spring, summer and fall. Well-defined layers enriched with redox sensitive species were observed following the conventional sequence of early diagenetic reactions. However, differences were observed between both stations in depths and thickness layers. Concentration gradients extended down to more than 92 cm depth at the central position of the lagoon (station C4 – 8 m depth) and down to 40 cm depth inside shellfish farming zones (station C5 – 9 m depth). Station C4 showed an unusual diagenetic signature: sharp dissolved oxygen, iron, nitrate and manganese gradients existed at the SWI but gradients of dissolved sulfide and alkalinity as well as other parameters (dissolved silica, Ba, etc.) were recorded only from 25 to 30 cm depth downward. Seasonal changes were observed in pore water composition as deep as 30–50 cm in station C4 (only 15 cm in station C5). The center of the lagoon is not directly subjected to biodeposits deriving from shellfish activity. Isotopic and bioturbation data allowed to rule out a reworking of the sediment deeper than a few centimeters. In addition to organic content of the sediment, physical parameters were likely to induce the 10–20 cm gap between dissolved iron and sulfide profile as well as the higher vertical extent of diagenetic sequence observed at station C4. Conversely to station C5, station C4 underwent stronger currents and wave effect probably generating advective transport of water through the sediment, but no permeability data were available to confirm this hypothesis. During summer, climatic conditions generated vertical stratification of the water column and transient suboxic conditions at the bottom. Such conditions drove the upward shift of redox fronts, compacting the diagenetic sequence. These effects were reinforced at station C5 by shellfish and its farm structures (mainly attenuation of current and increased heat absorption).     

Late Pleistocene–Holocene seismic stratigraphy of Nha Trang shelf,central Vietnam

The late Pleistocene–Holocene stratigraphic architecture on the steep and narrow shelf off Nha Trang, central Vietnam has been explored by high resolution seismic profiles integrated with sediment core data. Sequence stratigraphic results reveal five major seismic units and three bounding surfaces which are composed of two distinctive sequences. Those sequences are bounded by two regional unconformities (SB1, SB2) which have been formed in respond to different sea-level regimes. The revealed relict beach–ridge deposits at water depth of about ∼130 m below the present water depth indicate that the Last Glacial Lowstand (LGM) sea-level in this area was lower than in neighboring areas and it probably resulted from subsidence due to high sedimentation rate and/or neotectonic movements of the East Vietnam Fault System. The late Pleistocene high amplitude of sea-level change during a long fourth-order and superimposed by shorter fifth-order cycle is the principal factor in reorganizing the formation of the Nha Trang continental shelf sequence. Other local controlling factors as fluctuations in sediment supply, morphological variations of the LGM surface, subsidence rate and hydrodynamic conditions provided the distinctive features of the Nha Trang shelf sequence stratigraphic model in comparison with neighboring other areas.     

Diagenesis of a tight gas sand reservoir: Upper Cretaceous Mesaverde Group,Piceance Basin,Colorado

The Upper Cretaceous Mesaverde Group in the Piceance Basin, western Colorado, contains thick sections of low porosity, low permeability sandstones that are reservoirs for large accumulations of hydrocarbon gas. The Mesaverde sandstones are lithic arkoses and feldspathic litharenites, containing quartz, plagioclase, variable K-feldspar, chert, and volcanic rock fragments. Important diagenetic processes that have affected the sandstones include compaction, dissolution of feldspar and/or alteration to clay, precipitation of carbonate and quartz cements, precipitation of illite, and alteration of detrital clays (mixed-layer illite–smectite). Porosity is relatively constant; a decrease in primary porosity downward is approximately balanced by an increase in secondary porosity, with significant microporosity in authigenic and diagenetic clays. K-feldspar is almost completely absent below 5500 feet (1675 m). Fibrous illite is relatively abundant above this depth and variable in abundance below. The K–Ar ages of the clays increase with depth, from 40 m.y. at the top of the sampled section to 55 m.y. at the base, indicating illitization of a precursor smectite at approximately the 100 °C isotherm. Samples with abundant fibrous illite have relatively smaller age values. Mass balance calculations indicate that dissolution of K-feldspar, illitization of smectite and precipitation of fibrous illite were coupled. These reactions suggest the transport of dissolved potassium upward hundreds of feet (100–300 m) in the section, possibly associated with water driven vertically by the migration of gas.     

Diagenesis and reservoir properties of Middle Jurassic sandstones,Traill Ø, East Greenland: The influence of magmatism and faulting

The c. 500 m thick Middle Jurassic sandstones of the fluvial Bristol Elv and marine Pelion Formations of the East Greenland Basin are evaluated here in order to improve the understanding of the processes that influenced the diagenetic evolution. The study may help to predict the reservoir properties of sandstones affected by magmatism and faulting, both in general and specifically in undrilled areas on- and offshore East Greenland and, in the Vøring Basin on the Mid-Norwegian shelf. The study shows a variety of authigenic mineral phases dominated by quartz cement, carbonate cement, illite and iron-oxide. One of the clear differences between the two formations is the presence of early carbonate-cemented horizons in the marine sandstones; these horizons are inferred to reflect a primary concentration of biogenic clasts and fossil shells. Intense quartz cementation occurs primarily in the fluvial sandstones but the marine sandstones are also highly quartz-cemented. Two episodes of burial and uplift are recorded in the diagenetic sequence and widespread grain-crushing in coarse-grained intervals is believed to result from overpressure and subsequent compaction due to sudden pressure release along major faults. Maximum burial depths may only have been around 2000–2500 m. Cathodoluminescence analyses show that grain crushing was followed by intense quartz cementation. The quartz cement is to a great deal believed to have formed due to increased surface area from crushing of detrital quartz grains, creating fresh nucleation sites for the quartz. Cathodoluminescence investigations also show that only minor pressure dissolution has taken place between detrital quartz grains and that the ubiquitous quartz cementation displays several growth zones, and was thus in part the result of the introduction of silica-rich extra-formational fluids related to the flow of hot fluids along reactivated faults and increased heat flow and temperature due to magmatism. This interpretation is supported by fluid inclusion homogenization temperatures between 117 and 158 °C in quartz cements. In one of the two study areas, the development of macroscopic stylolites has significantly enhanced quartz cementation, probably in connection with thermal convection flow. As a result of the magmatic and fault-related quartz cementation and illitization, the reservoir quality of the sandstone formations deteriorated and changed drastically.     

Sediment mounds and other sedimentary features related to hydrate occurrences in a columnar seismic blanking zone of the Ulleung Basin, East Sea, Korea

A mound related to a cold vent in a columnar seismic blanking zone (CSBZ) was formed around site UBGH1-10 in the central Ulleung Basin (2077 m water depth), East Sea, Korea. The mound is 300–400 m wide and 2–3 m high according to multi-beam bathymetry, 2–7 kHz sub-bottom profiler data, and multi-channel reflection seismic data. Seafloor topography and characteristics were investigated using a remotely operated vehicle (ROV) around site UBGH1-10, which is located near the northern part of the mound. The origin of the mound was investigated through lithology, mineralogy, hydrate occurrence, and sedimentary features using dive cores, piston cores, and a deep-drilling core. The CSBZ extends to ∼265 ms two-way traveltime (TWT) below the seafloor within a mass-transport deposit (MTD) unit. Gas hydrate was entirely contained 6–141 m below the seafloor (mbsf) within hemipelagic deposits intercalated with a fine-grained turbidite (HTD) unit, characteristically associated with high resistivity values at site UBGH1-10. The hydrate is commonly characterized by veins, nodules, and massive types, and is found within muddy sediments as a fracture-filling type. Methane has been produced by microbial reduction of CO₂, as indicated by C₁/C₂₊, δ¹³CCH4, and δD₄CH analyses. The bowl-shaped hydrate cap revealed at 20–45 ms TWT below the seafloor has very high resistivity and high salinity, suggesting rapid and recent gas hydrate formation. The origin of the sediment mound is interpreted as a topographic high formed by the expansion associated with the formation of the gas hydrate cap above the CSBZ. The lower sedimentation rate of the mound sediments may be due to local enhancement of bottom currents by topographic effects. In addition, no evidence of gas bubbles, chemosynthetic communities, or bacterial mats was observed in the mound, suggesting an inactive cold vent.     

Diagenetically induced shear failure of fine-grained sediments and the development of polygonal fault systems

Polygonal fault systems (PFS) are widely developed along many continental margin basins and some interior cratonic and foreland basins. They are networks of small normal faults that are usually found in tiers which are crudely layer-bound successions consisting mainly of fine-grained sediments. Their origin has been widely debated with explanations ranging from dewatering of overpressured layers to gravitational loading under fixed lateral boundary conditions. Their distribution in fine-grained intervals suggests that their genesis is connected to their initial lithology. Recent experimental work suggests that diagenesis of clay-rich sediments can lead to shear failure under low confining stresses. This explanation accords well with all subsurface observations of PFS made to date, and seems the most likely mechanism to explain their genesis. This diagenetic mode of shear fracturing in fine-grained sediments could be much more prevalent than in polygonal fault systems alone, and this has significant implications for shale gas exploration, CO₂ sequestration and exploration for methane hydrates.     

Diagenesis and reservoir quality of sandstones with ancient “deep” incursion of meteoric freshwater——An example in the Nanpu Sag,Bohai Bay Basin,East China

An example of diagenesis and reservoir quality of buried sandstones with ancient incursion of meteoric freshwater is presented in this study. The interpretation is based on information including porosity and permeability, petrography, stable isotopic composition of authigenic minerals, homogenization temperatures (T_h) of aqueous fluid inclusions (AFIs), and pore water chemistry. These sandstones, closely beneath or far from the regional unconformity formed during the late Paleogene period, are located in the thick Shahejie Formation in the Gaoliu area of Nanpu Sag, Bohai Bay Basin, East China. Early-diagenetic calcite cements were leached to form intergranular secondary pores without precipitation of late-diagenetic calcite cements in most sandstones. Feldspars were leached to form abundant intragranular secondary pores, but with small amounts of concomitant secondary minerals including authigenic quartz and kaolinite. The mass imbalance between the amount of leached minerals and associated secondary minerals suggests that mineral leaching reactions occurred most likely in an open geochemical system, and diagenetic petrography textures suggest that advective flow dominated the transfer of solutes from leached feldspars and calcites. Low salinity and ion concentrations of present pore waters, and extensive water rock interactions suggest significant incursion of meteoric freshwater flux in the sandstones. Distances of the sandstones to the regional unconformity can reach up to 1800 m, while with significant uplift in the Gaoliu area, the burial depth of such sandstones (below sea level) can be less than 800–1000 m during the uplift and initial reburial stage. Significant uplift during the Oligocene period provided substantial hydraulic drive and widely developed faults served as favorable conduits for downward penetration of meteoric freshwater from the earth's surface (unconformity) to these sandstone beds. Extensive feldspar leaching has been occurring since the uplift period. Coupled high T_h (95∼115 °C) of AFI and low δ¹⁸O_(SMOW) values (+17∼+20‰) within the quartz overgrowths show that quartz cementation occurred in the presence of diagenetic modified meteoric freshwater with δ¹⁸O_(SMOW) values of −7∼−2‰, indicating that authigenic quartz only have been formed during the late reburial stage when meteoric fresh water penetration slowed down. Secondary pores in thin sections and tested porosity suggest that meteoric freshwater leaching of feldspars and calcite minerals generated approximately 7–10% enhanced secondary porosity in these sandstones. Meteoric freshwater leaching reactions cannot be ignored in similar sandstones that located deep beneath the unconformity, with great uplift moving these sandstones above or close to sea level and with faults connecting the earth's surface with the sandstone beds.     

Seal rock deformation by polygonal faulting,offshore Uruguay

Due to a lack of borehole data, reservoir and seal rock presence in frontier basins is typically inferred from seismic reflection data. However, analysis of the geometry and kinematic development of polygonal fault systems (PFS), which almost exclusively form within very fine-grained strata, provides another, largely untested method to infer reservoir and seal rock presence. We here use very high-quality 3D seismic reflection data from offshore Uruguay and a range of quantitative GIS-based techniques to document the planform and cross-sectional characteristics of a basin-scale (>6400 km²) PFS, and to investigate the role that stratigraphic variations in the Tertiary deep-water host-rock have on its geometrical variability and kinematic development. We demonstrate that a series of likely sandstone-rich deep-water deposits occur at the base of and within the main PFS tier. The geometric characteristics and throw distribution on individual polygonal faults suggest these sandstone-rich deep-water deposits represent a mechanical barrier to fault propagation, thus influencing fault height and areal density and, in some cases, strike. We argue that in largely unexplored, deep-to ultra-deep water basins, such as those characterizing offshore Uruguay, the distribution and geometric attributes of PFS can be used to delineate sandstone-rich reservoir bodies. Furthermore, these characteristics may help exploration geoscientists better understand seal heterogeneity and quality in data-poor basins.     

Contourite identification along Italian margins: The case of the Portofino drift (Ligurian Sea)

A brief review of the published evidence of current deposits around Italy is the occasion to test the robustness of matching bottom current velocity models and seafloor morphologies to identify contourite drifts not yet documented. We present the result of the regional hydrodynamic model MARS3D in the Northern Tyrrhenian and Ligurian Sea with horizontal resolution of 1.2 km and 60 levels with focus on bottom current: data are integrated over summer and winter 2013 as representative of low and high intensity current conditions.The Eastern Ligurian margin is impacted by the Levantine Intermediate Water (LIW) with modeled mean velocity of bottom current up to 20 cm s⁻¹ in winter 2013 and calculated bottom shear stress exceeding 0.2 N m⁻² in water depth of 400–800 m. By crossing this information with seafloor morphology and geometry of seismic reflections, we identify a sediment drift formerly overlooked at ca 1000 m water depth. The Portofino separated mounded drift has a maximum thickness of at least 150 m and occurs in an area of mean current velocity minimum. Independent evidence to support the interpretation include bottom current modelling, seafloor morphology, seismic reflection geometry and sediment core facies. The adjacent areas impacted by stronger bottom currents present features likely resulted from bottom current erosion such as a marine terrace and elongated pockmarks.Compared to former interpretation of seafloor morphology in the study area, our results have an impact on the assessment of marine geohazards: submarine landslides offshore Portofino are small in size and coexist with sediment erosion and preferential accumulation features (sediment drifts) originated by current-dominated sedimentary processes. Furthermore, our results propel a more general discussion about contourite identification in the Italian seas and possible implications.     

Sulfate reduction and anaerobic methane oxidation in Black Sea sediments

Beyond the shelf break at ca. 150 m water depth, sulfate reduction is the only important process of organic matter oxidation in Black Sea sediments from the surface down to the sulfate–methane transition at 2–4 m depth. Sulfate reduction rates were measured experimentally with ³⁵SO₄²⁻, and the rates were compared with results of two diffusion-reaction models. The results showed that, even in these non-bioirrigated sediments without sulfide reoxidation, modeling strongly underestimated the high reduction rates near the sediment surface. A hybrid modeling approach, in which experimentally measured rates in the upper sediment layers force a model that includes also the deeper layers, probably provides the most realistic estimate of sulfate reduction rates. Areal rates of sulfate reduction were 0.65–1.43 mmol SO₄²⁻ m⁻² d⁻¹, highest in sediments just below the chemocline. Anaerobic methane oxidation accounted for 7–11% of the total sulfate reduction in slope and deep-sea sediments. Although this methane-driven sulfate reduction shaped the entire sulfate gradient, it was only equivalent to the sulfate reduction in the uppermost 1.5 cm of surface sediment. Methane oxidation was complete, yet the process was very sluggish with turnover times of methane within the sulfate–methane transition zone of 20 yr or more.     

Ground-Truthing 11- to 12-kHz side-scan sonar imagery in the Norwegian–Greenland Sea: Part II: Probable diapirs on the Bear Island fan slide valley margins and the Vøring Plateau

SeaMARC II (11- to 12-kHz) side-scan sonar revealed hundreds of small strong-backscatter spots, tens to 500?m in diameter, along the lips of the Bear Island fan slide valley. New bathymetry, deep-tow side-scan, deep-tow profiles, heatflow, and gravity cores were collected for ground-truth. These mounds are probably mud diapirs (or mud-built mounds) typically 10–75?m high, formed by glacial sediment mobilized by Late Pleistocene slide events. The mounds are arranged along NNE trending lines, suggesting control by intrasedimentary faults ca. 0.5–1 km apart. Diapirs examined on the Vøring Plateau exhibit WNW structural control. No heatflow anomaly was found in four stations on or next to diapirs in either area.     

Development and post-depositional deformation of a Middle Eocene deep-water sandy depositional system in the Sørvestsnaget Basin,SW Barents Sea

Three-dimensional seismic data from the Sørvestsnaget Basin, SW Barents Sea supported by well data, are used to investigate a Middle Eocene deep-water depositional system. The system forms a NNW-oriented sediment accumulation, characterized by increased seismic amplitudes, and abrupt western termination. The data indicate that post-depositional sand remobilization and injection led to formation of sub-circular sediment blocks up to several km wide to the east of the main accumulation. The deep-water depositional system was deformed by wing-like sandstone intrusions, extending 200–400 m upwards from the margins of the parent sand bodies. The intrusions have polygonal or broadly circular plan view geometries. Deformation is inferred to have been associated with overpressure of the sand bodies as a result of rapid burial, fluid migration into the sealed sand bodies from deeper sources via synsedimentary faults, and fluid drainage from the surrounding mudrock during early compaction. The final triggering mechanism for sand remobilization and injection is inferred to have been fracture propagation due to differential compaction and/or fault-induced earthquakes. The injectite complexes are often associated with folding of overlying strata, which we relate to differential compaction. Intrusion of sand took place during the Middle Eocene. Post-depositional sand remobilization and injection have important implications for hydrocarbon exploration because they cause changes in the reservoir primary architecture, connectivity and structure.     

Petrological and geochemical constraints on diagenesis and deep burial dissolution of the Ordovician carbonate reservoirs in the Tazhong area,Tarim Basin,NW China

Deeply buried (4500–7000 m) Ordovician carbonate reservoirs in the Tazhong area, Tarim Basin, NW China show obvious heterogeneity with porosity from null in limestones and sweet dolostones to 27.8% in sour dolostones, from which economically important oils, sour gas and condensates are currently being produced. Petrographic features, C, O, Sr isotopes were determined, and fluid inclusions were analyzed on diagenetic calcite, dolomite and barite from Ordovician reservoirs to understand controls on the porosity distribution. Ordovician carbonate reservoirs in the Tazhong area are controlled mainly by initial sedimentary environments and eo-genetic and near-surface diagenetic processes. However, vugs and pores generated from eogenetic and telogenetic meteoric dissolution were observed to have partially been destroyed due to subsequent compaction, filling and cementation. In some locations or wells (especially ZG5-ZG7 Oilfield nearby ZG5 Fault), burial diagenesis (e.g. thermochemical sulfate reduction, TSR) probably played an important role in quality improvement towards high-quality reservoirs. C2 calcite and dolomite cements and barite have fluid inclusions homogenization temperatures (Ths) from 86 to 113 °C, from 96 to 128 °C and from 128 to 151 °C, respectively. We observed petrographically corroded edges of these high-temperature minerals with oil inclusions, indicating the dissolution must have occurred under deep-burial conditions. The occurrence of TSR within Ordovician carbonate reservoirs is supported by C3 calcite replacement of barite, and the association of sulfur species including pyrite, anhydrite or barite and elemental sulfur with hydrocarbon and ¹²C-rich (as low as −7.2‰ V-PDB) C3 calcite with elevated Ths (135–153 °C). The TSR may have induced burial dissolution of dolomite and thus probably improved porosity of the sour dolostones reservoirs at least in some locations. In contrast, no significant burial dissolution occurred in limestone reservoirs and non-TSR dolostone reservoirs. The deeply buried sour dolostone reservoirs may therefore be potential exploration targets in Tarim Basin or elsewhere in the world.     

Hydrocarbon plumbing systems above the Snøhvit gas field: Structural control and implications for thermogenic methane leakage in the Hammerfest Basin,SW Barents Sea

Based on the analysis of the high-resolution 3D seismic data from the SW Barents Sea we study the hydrocarbon plumbing system above the Snøhvit and Albatross gas field to investigate the geo-morphological manifestation and the dynamics of leakage from the reservoir. Fluid and gas escape to the seafloor is manifested in this area as mega-pockmarks 1–2 km-wide, large pockmarks (<100 m wide) and giant pockmarks 100–300 m-wide. The size of the mega pockmarks to the south of the study area may indicate more vigorous venting, whilst the northern fluid flow regime is probably characterised by a widespread fluid and gas release. Buried mega depressions and large-to-giant pockmarks are also identified on the base Quaternary and linked to deep and shallow faults as well as to seismic pipes. A high density of buried and seafloor giant pockmarks occur above a network of faults overlying an interpreted Bottom Simulating Reflector (BSR), whose depth coincides with the estimated base of the hydrate stability zone for a thermogenically derived gas hydrate with around 90 mol% methane. Deep regional faults provide a direct route for the ascending thermogenic fluids from the reservoir, which then leaked through the shallow faults linked to seismic pipes. It is proposed that the last episodic hydrocarbon leakage from the reservoir was responsible for providing a methane source for the formation of gas hydrates. We inferred that at least two temporally and dynamically different fluid and gas venting events took place in the study area: (1) prior to late Weichselian and recorded on the Upper Regional Unconformity (URU) and (2) following the Last Glacial Maximum between ∼17 and 16 cal ka BP and recorded on the present-day seafloor.     

Diagenesis in salt dome roof strata: Barite - calcite assemblage in Jebel Madar,Oman

Halokinesis causes a dynamic structural evolution with the development of faults and fractures, which can act as either preferential fluid pathways or barriers. Reconstructing reactive fluid flow in salt dome settings remains a challenge. This contribution presents for the first time a spatial distribution map of diagenetic phases in a salt dome in northern Oman. Our study establishes a clear link between structural evolution and fluid flow leading to the formation of diagenetic products (barite and calcite) in the salt dome roof strata. Extensive formation of diagenetic products occurs along NNE-SSW to NE-SW faults and fractures, which initiated during the Santonian (Late Cretaceous) and were reactivated in the Miocene, but not along the E-W fault, which was generated during Early Paleocene time. We propose that the diagenetic products formed by mixing of a warm (100 °C) saline (17 wt% NaCl eq.) ⁸⁷Sr enriched (⁸⁷Sr/⁸⁶Sr: 0.71023) fluid with colder (35 °C) meteoric fluid during Miocene to Pleistocene. The stable sulphur and strontium isotope composition and fluid inclusion data indicate that a saline fluid, with sulphate source derived from the Ara Group evaporite and Haima Supergroup layers, is the source for barite formation at about 100 °C, predominantly at fault conjunctions and minor faults away from the main graben structure in the dome. In the Miocene, the saline fluid probably ascended along a halokinesis-related fault due to fluid overpressure (due to the rising salt and impermeable layers in the overlying stratigraphic sequence), and triggered the formation of barite due to mixing with barium-rich fluids, accompanied by a drop in temperature. Subsequently, evolving salt doming with associated fault activity and erosion of the Jebel allows progressively more input of colder meteoric fluids, which mix with the saline warmer fluid, as derived from stable isotope data measured in the progressively younger barite-associated calcite, fault zone calcite and macro-columnar calcite. The reconstructed mixing model indicates a 50/50 to 90/10 meteoric/saline fluid mixing ratio for the formation of fault zone calcite, and a 10 times higher concentration of carbon in the saline fluid end member compared to the meteoric fluid end member. The presented mixing model of salt-derived fluids with meteoric fluids is suggested to be a general model applicable to structural diagenetic evolution of salt domes world wide.     

Seismic velocities on the Nova Scotian margin to estimate gas hydrate and free gas concentrations

This article provides new constraints on gas hydrate and free gas concentrations in the sediments at the margin off Nova Scotia. Two-dimensional (2-D) velocity models were constructed through simultaneous travel-time inversion of ocean-bottom seismometer (OBS) data and 2-D single-channel seismic (SCS) data acquired in two surveys, in 2004 and 2006. The surveys, separated by ∼5 km, were carried out in regions where the bottom-simulating reflection (BSR) was identified in seismic reflection datasets from earlier studies and address the question of whether the BSR is a good indicator of significant gas hydrate on the Scotian margin. For both datasets, velocity increases by 200–300 m/s at a depth of approximately 220 m below seafloor (mbsf), but the results of the 2006 survey show a smaller velocity decrease (50–80 m/s) at the base of this high-velocity layer (310–330 mbsf) than the results of the 2004 survey (130 m/s). When converted to gas hydrate concentrations using effective medium theory, the 2-D velocity models for both datasets show a gas hydrate layer of ∼100 m thickness above the identified BSR. Gas hydrate concentrations are estimated at approximately 2–10% for the 2006 data and 8–18% for the 2004 survey. The reduction in gas hydrate concentration relative to the distance from the Mohican Channel structure is most likely related to the low porosity within the mud-dominant sediment at the depth of the BSR. Free gas concentrations were calculated to be 1–2% of the sediment pore space for both datasets.     

Spatial and temporal variations in sediment accumulation and their impacts on coral communities in the Sanya Coral Reef Reserve,Hainan, China

This study investigated the spatial and temporal variations of sediment accumulation and their impacts on coral communities in four sites at two or three depths (3 m, 6 m and 9 m) at the Sanya Coral Reef Reserve by deploying sediment traps on the sea floor during 2007–2009. Rainfall and typhoon events, which appeared to control sediment accumulation in the sea floor of the coral reef, were positively correlated with total sediment and sand-sized (i.e. 63–2000 µm) sediment accumulation. Sediment accumulation rate significantly decreased with the distance far away from the coast in Sanya. The mean sediment accumulation rates in Ximaozhou, Luhuitou and Xiaodonghai during 2007 to 2009 were close to 20 mg cm⁻² d⁻¹, and they were significantly higher than that in Yalongwan, probably as a result of terrestrial soil erosion caused by strong coast human activities (e.g. coastal construction, dredging and hillside clearing). Correlation analysis revealed that silt-clay-sized sediment accumulation rate was highly negatively correlated with total live coral cover and coral cover in some taxa, such as Montipora and branching Porites. whereas, Diploastrea heliopora was positively correlated with silt-clay-sized sediment accumulation. Correlation analysis also suggested that silt-clay-sized sediment accumulation had a higher efficiency in predicting the spatial variation of total live coral cover in Sanya than did the total sediment accumulation. Based on this investigation, we conclude that high rates of sediment accumulation pose a severe threat to the Sanya Coral Reef Reserve, highlighting the importance of integrated watershed management practices in the Sanya Coral Reef Reserve.     

Characteristics,genesis and parameters controlling the development of a large stratabound HTD body at Matienzo (Ramales Platform,Basque–Cantabrian Basin,northern Spain)

At Matienzo (Basque–Cantabrian Basin, northern Spain), a large stratabound HTD body (4 by 2 km² and 80–400 m thick) delimited by two parallel sinistral strike-slip faults is exposed in Aptian carbonates. The margins of the HTD body are characterised by dolomite “tongues” indicating that some limestone beds were more prone to dolomitisation. However, no clear relationship between HTD occurrence and precursor limestone facies can be established. Massive limestone beds, as found at the top of the HTD body, act as barriers to hydrothermal processes, since no dolomite is present in or above these beds. Three types of dolomites have been differentiated, i.e. 1) matrix, 2) coarse crystalline and 3) zebra dolomite. The distribution of the dolomite types is attributed to ascending fluid flow and changing degree of dolomite oversaturation.The dolomite body was formed by two dolomitisation phases under burial conditions. No indications for a synsedimentary/early diagenetic dolomitisation have been observed. The first dolomitisation phase is characterized by ferroan dolomite and the second by non-ferroan dolomite. The two HTD phases are characterised by depleted δ¹⁸O-values (ranging between −10‰ and −16‰ V-PDB), δ¹³C-values similar to the Aptian–Albian marine signature and homogenisation temperatures of primary fluid inclusions between 120 °C and 150 °C. The dolomitising fluid was enriched in ⁸⁷Sr compared to Aptian seawater, excluding the latter as an unmodified fluid source for dolomitisation. Microthermometry of primary fluid inclusions indicates that the dolomitising fluid evolved from a moderate saline (9.7 – 14.0 wt% NaCl) to a more saline (10.9 – 21.0 wt% NaCl) H₂O–NaCl brine. The dolomitising fluid likely originated from evaporated seawater. Fluid circulation through the dolomitised strata is inferred to have taken place during the tectonically active period of the late Albian throughout which important sinistral-strike slip movements along basement faults occurred.