A laboratory study on capillary sealing efficiency of Iranian shale and anhydrite caprocks

Caprock has the most important role in the long term safety of formation gas storage. The caprocks trap fluid accumulated beneath, contribute to lateral migration of this fluid and impede its upward migration. The rapid upward passage of invasive plumes due to buoyancy pressure is prevented by capillary pressure within these seal rocks. In the present study, two main seal rocks, from the Zagros basin in the southwest of Iran, a shale core sample of Asmari formation and an anhydrite core sample of Gachsaran formation, were provided. Absolute permeabilities of shale and anhydrite cores, considering the Klinkenberg effect, were measured as 6.09 × 10⁻¹⁸ and 0.89 × 10⁻¹⁸ m², respectively. Capillary sealing efficiency of the cores was investigated using gas breakthrough experiments. To do so, two distinct techniques including step by step and residual capillary pressure approaches were performed, using carbon dioxide, nitrogen and methane gases at temperatures of 70 and 90 °C, under confining pressures in the range 24.13–37.92 MPa. In the first technique, it was found that capillary breakthrough pressure of the cores varies in the range from 2.76 to 34.34 MPa. Moreover, the measurements indicated that after capillary breakthrough, gas effective permeabilities lie in range 1.85 × 10⁻²¹ – 1.66 × 10⁻¹⁹ m². In the second technique, the minimum capillary displacement pressure of shale varied from 0.66 to 1.45 MPa with the maximum effective permeability around 7.76 × 10⁻²¹ – 6.69 × 10⁻²⁰ m². The results indicate that anhydrite caprock of the Gachsaran formation provides proper capillary sealing efficacy, suitable for long term storage of the injected CO₂ plumes, due to its higher capillary breakthrough pressure and lower gas effective permeability.     

Effects of trophic ecology and habitat use on maternal transfer of contaminants in four species of young of the year lamniform sharks

Organic contaminant and total mercury concentrations were compared in four species of lamniform sharks over several age classes to examine bioaccumulation patterns and gain insights into trophic ecology. Contaminants found in young of the year (YOY) sharks were assumed to be derived from maternal sources and used as a proxy to investigate factors that influence maternal offloading processes. YOY white (Carcharodon carcharias) and mako (Isurus oxyrinchus) sharks had comparable and significantly higher concentrations of PCBs, DDTs, pesticides, and mercury than YOY thresher (Alopias vulpinus) or salmon (Lamna ditropis) sharks. A significant positive relationship was found between YOY contaminant loads and maternal trophic position, suggesting that trophic ecology is one factor that plays an important role in maternal offloading. Differences in organic contaminant signatures and contaminant concentration magnitudes among species corroborated what is known about species habitat use and may be used to provide insights into the feeding ecology of these animals.     

Estimation of hydrocarbon biodegradation rates in marine environments: A critical review of the Q10 approach

Offshore oil & gas industry is moving exploration and production activities into Arctic and deep water regions. Governmental regulations require environmental impact assessments before operations to evaluate the possible effects of accidental oil releases. These are often performed by numerical fate models, like the Oil Spill Contingency and Response (OSCAR) model, which has become an industry standard in Norway. In this model, biodegradation rates are adjusted to local conditions by temperature compensation according to a Q₁₀ approach. Q₁₀ is the multiplier by which rates of enzymatic reactions increase at a 10 °C temperature rise. Herein, this Q₁₀ approach implemented in the OSCAR model is investigated based on published data and novel obtained results. Overall, biodegradation rate predictions calculated by temperature compensation are found to be questionable, and choosing one universal Q₁₀ value is considered not feasible. The high variation in Q₁₀ values is herein attributed to indirect effects of temperature.     

King Canute muses in the South Seas: Why aren’t Pacific Islands transitioning to low carbon sea transport futures?

Transition to low carbon sea transport is a logical response to the extreme dependency of the Pacific Islands region on imported fossil fuel, its significant vulnerability to the effects of climate change and the critical shipping needs of Pacific Island countries (PICs). Building on previous work in low carbon sea transport in the Pacific, this paper further considers the barriers to achieving such transition by assessing, through a ‘post-Paris Agreement’ lens, the Intended Nationally Determined Contributions (INDCs) submitted by PICs and contrasting these to the near total lack of investment and planning for low carbon transition in the transport sector with the parallel occurrence in the electricity sector where ~USD 2 billion of donor investment is deployed or queued despite electricity using only ~20% of fossil fuel across the region. Consistent with recent international studies, inadequate and inappropriate financing and policy have been identified as dominant transition barriers for low carbon sea transport development in PICs. This paper further examines the regional level barriers to policy development, and finds them inhibited by the silo nature of the major regional actors. The implications that the Paris Agreement has for climate financing to support the essential research and capacity development needed to underpin a successful low carbon sea transport transition strategy at any useful scale and speed are also considered in this paper.     

Capturing channelized reservoir connectivity uncertainty with amalgamation curves

During reservoir characterization all the geological uncertainties affecting the quantity and distribution of hydrocarbons should be captured to assess the risks affecting final recovery.In a typical modeling workflow the geological uncertainties are accounted for through the construction of a sufficiently large set of 3-D static models. Out of this set, a few representative models are selected and dynamically simulated so as to correlate the geological characteristics of the reservoir with its dynamic performance and to propagate the uncertainty onto the final recovery factors, yet maintaining the computational run time acceptable. In channelized depositional environments, which are strongly heterogeneous, the selection approach must also account for channel connectivity, which plays a key role in the possibility of efficiently draining the reservoir for a reasonable number of wells.This study can be seen as a step forward in the assessment of the risks associated to the development of channelized reservoirs under the assumption that a way to express the concept of channel connectivity is channel amalgamation. Channel amalgamation is here defined through amalgamation curves which are numerically described using a set of indexes whose combination provide spatial information of channel intersections. These indexes were calculated for a full set of 3-D geological models and used to steer the selection of a representative model sub-set for subsequent fluid flow simulations.The validity of the index-based selection was verified on different sets of synthetic reservoir models through the evaluation of the representativeness of the model sub-set in reproducing the uncertainty of the original dataset. Eventually, the existence of a strong correlation between channel amalgamation and production performance was proved. From a practical perspective, the possibility to include channel amalgamation in the assessment of the geological models can considerably improve the representativeness of the selected models for uncertainty propagation thus reducing significantly the number of geological models to be considered.     

Behavioral responses of California sea lions to mid-frequency (3250–3450 Hz) sonar signals

Military sonar has the potential to negatively impact marine mammals. To investigate factors affecting behavioral disruption in California sea lions (Zalophus californianus), fifteen sea lions participated in a controlled exposure study using a simulated tactical sonar signal (1 s duration, 3250–3450 Hz) as a stimulus. Subjects were placed into groups of three and each group received a stimulus exposure of 125, 140, 155, 170, or 185 dB re: 1 μPa (rms). Each subject was trained to swim across an enclosure, touch a paddle, and return to the start location. Sound exposures occurred at the mid-point of the enclosure. Control and exposure sessions were run consecutively and each consisted of ten, 30-s trials. The occurrence and severity of behavioral responses were used to create acoustic dose–response and dose–severity functions. Age of the subject significantly affected the dose–response relationship, but not the dose–severity relationship. Repetitive exposures did not affect the dose–response relationship.     

Quantitative evaluation of the reservoir potential and controlling factors of semi-deep lacustrine tempestites in the Eocene Lijin Sag of the Bohai Bay Basin,East China

Ancient lacustrine storm-deposits that act as petroleum reservoirs are seldom reported. The Lijin Sag, which is located in the southeastern corner of the Bohai Bay Basin in East China, is a NE–SW trending Cenozoic half-graben basin. Some of its Eocene deposits (Bindong deposits) were interpreted as lacustrine tempestites. The Bindong tempestites, which developed in the lower part of the upper fourth member of the Shahejie Formation (Es4¹), constitute a new kind of petroleum reservoir and are novel petroleum exploration targets in the Bindong Area. However, the characteristics of the Es4¹ Bindong tempestite reservoirs and their controlling factors are poorly understood. Point-count analyses of thin sections, scanning electron microscope image analyses, X-ray diffractometry data, and the petrophysical parameters of the Bindong tempestite reservoirs were utilized to estimate the reservoir quality. The reservoirs have undergone significant diagenetic alteration, which can be divided into negative and positive aspects. The negative alteration includes compaction, authigenic minerals, and cementation such as carbonates, clay minerals and overgrowths of quartz and feldspar. The uneven distribution of carbonate cement increased the reservoir’s heterogeneity, with carbonate cement commonly precipitating along the sandstone-mudstone contacts. The primary porosity was severely reduced because of compaction and extensive carbonate cementation. Positive alteration includes dissolution, carbonate cementation, undercompaction and fractures. Carbonate cementation exhibited both positive and negative effects on the reservoir quality. Overall, the objective reservoir quality is quite poor. A quantitative evaluation of the reservoirs’ potential was conducted. The cutoff values of several of the reservoir’s parameters were calculated. The lower limits of the porosity and permeability are 8.35–5.85% and 1.2587–0.2753 × 10^–3 μm², respectively, depending on the depth. The upper limits of the carbonate and mud content are approximately 18.5% and 9–10%, respectively. A fundamental understanding of these characteristics will provide necessary information for extracting hydrocarbons from analogous subsurface reservoirs.     

The importance of missing strain in Deep Water Fold and Thrust Belts

Deep water fold and thrust belts (DWFTBs) are sedimentary wedges that accommodate plate-scale deformation on both active and passive continental margins. Internally, these wedges consist of individual structures that strongly influence sediment dispersal, bathymetry and fluid migration. Most DWFTB studies investigate basin- and intra-wedge- scale processes using seismic reflection profiles, yet are inherently limited by seismic resolution. Of critical importance is strain distribution and its accommodation on discrete faults compared to distributed deformation. Recent studies have considered strain distribution by investigating regional reflection DWFTBs profiles within coupled systems, which contain down-dip compression and up-dip extension. There is broad agreement of a mis-balance in compression versus extension, with ∼5% excess in the latter associated with horizontal compaction, yet this remains unproven.Using two exceptionally well exposed outcrops in the Spanish Pyrenees we consider deformation of DWFTB at a scale comparable to, and beyond, seismic resolution for the first time. By coupling outcrop observations (decametre to hectometre scale) with a re-evaluation of seismic profiles from the Orange Basin, South Africa, which contains one of the best imaged DWFTBs globally, we provide a unique insight into the deformation from metre to margin scale. Our observations reveal hitherto unrecognised second order structures that account for the majority of the previously recognised missing strain. This re-evaluation implies that ∼5% missing strain should be accounted for in all DWFTBs, therefore existing studies using restorations of the sediment wedge will have underestimated crustal shortening in active margins, or sedimentary shortening in gravity driven systems by this amount. In contrast to previous studies, our observations imply that the majority of this strain is accommodated on discrete fault surfaces and this can explain the occurrence and location of a range of intra-wedge processes that are intimately linked to structures including sediment dispersal, fluid migration pathways and reservoir compartmentalisation.