Trace elements and their correlations in hand-dug wells in a laterite environment in a semi-arid region: case study of Tikaré, Northern Burkina Faso

In many regions of the world and especially in arid and semi-arid areas, groundwater is the major source of drinking water for most of the rural population. The main reason is probably its accessibility through hand-dug wells. However, the resource is supplied in most of the cases to the population as raw water because groundwater is assumed to be safe. In that situation, the water chemistry and quality is usually not well known. Therefore, a study in Tikaré, northern Burkina Faso (West Africa) was carried out analysing fourteen trace elements to characterise their concentration patterns and correlations. The assessment of the quality and the chemistry of water resources is also done in order to forecast if any danger to the population might exist regarding the trace elements. The samples analysed were from 22 wells, 2 boreholes and 1 surface water location (small dam) in a laterite environment. This dam is recharging water to the underlying aquifer during and short after the rainy season. It was found that the most dominated trace elements are Fe and Mn. In summary, nearly all the studied trace elements were below the recommended limit in the drinking water guidelines of the WHO (Guidelines from Drinking Water Standards, 1984). The main source of the trace elements in groundwater seems to be the bedrock dominated by volcano-sedimentary schist and basalt. At least for the analysed area, with only limited traditional mining activities close to the sampling zone, there is no danger for humans to consume the extracted water regarding the analysed trace elements. Some good relationships were also found between some trace elements and major ions.     

An improved BP neural network based on evaluating and forecasting model of water quality in Second Songhua River of China

Taking the Second Songhua River which lies in the northeast of China as a study area, this paper firstly designs the improved BP neural network water evaluating and forecasting model of which 13 water evaluating items are selected as nodes in input layer; 6 classes of evaluating results are selected as nodes of output layer; then, with the ＂0, 1＂ identified pattern and continually practiced comparisons, ＂13-9-5-6＂ double hidden layers with optimized training structure are confirmed; on the basis of this work, the water quality of the Second Songhua River was evaluated and forecasted at the end. The results showed that in the six classes of predefined water quality in 157 stations, none of them belongs to class Ⅰ, and classes Ⅱ, Ⅲ, Ⅳ and Ⅴ are as follows： 8.91%, 58.59%, 18.47%, 1.91% and 12.1%, respectively; the precision of these evaluating and forecasting results is 82.8%.     

Genetic nature of apatite–magnetite ore in North Gurvunur deposit,western Transbaikal region

The paper gives a mineralogical and geochemical characterization of the North Gurvunur deposit, which was discovered in the Eravna ore district. The ore is composed of apatite–magnetite paragenesis. Apatite is distinguished by elevated LREE concentrations; some of them are contained in emulsion-type impregnation of monazite. Hematitization, carbonate, quartz, and pyrite veinlets formed at the postore stage, and gypsum–anhydrite mineralization is widespread in the supraore sequence. Two groups of endogenic minerals are distinguished by oxygen isotopic composition. One of them comprises magnetite and apatite, which are characterized by a homogeneous composition throughout the section of the ore lode and are close to the mantle source. The oxygen–isotope temperature calculated for the apatite–magnetite couple (620–800°C) provides evidence for magmatic origin of ore. The δ¹⁸O of fluid in equilibrium with hematite is 8.0–8.5‰ and shows a certain enrichment in crustal component; carbonates of postore veinlets reveal participation of meteoric water. The study has made it possible to refer the North Gurvunur deposit to the Kiruna type.     

A nonlinear modeling and forecasting system of earth fractures based on coupling of artificial neural network and geographical information system—exemplified by earth fractures in Yuci City,Shanxi, China

Earth fracturing or fissuring is a natural phenomenon and a major geohazard in many countries. The factors that cause the earth to fracture were analyzed in Yuci City, in Shanxi Province of China using the geographical information system (GIS). A nonlinear simulation and assessment model of earth fracturing was established using the artificial neural network (ANN) technology to simulate the structure and function of the neural network (NN) of the human brain with engineering technology. The developed nonlinear modeling and forecasting system was used to assess and forecast the earth fracture hazard in Yuci City. The results of this study provided useful and essential information for scientific policy-making in the areas of city planning, environmental protection, and land development.     

The Bagassi gold deposits on the eastern margin of the Houndé greenstone belt,Burkina Faso

The Bagassi gold deposits are situated on the West African craton and hosted in Palaeoproterozoic rocks of the Houndé greenstone belt, southwest Burkina Faso. High-grade gold mineralisation is hosted in quartz–gold ± pyrite veins-lodes (V_1A), in dilational zones and narrow shears in the Bagassi granitoid, and forms the majority of the resource–reserve portfolio in the Bagassi exploration permits, with gold grades of 18–21 g/t. Shear hosted gold-pyrite mineralisation in quartz veins in dilational jogs (V_1B) occurs along narrow discontinuous shear zones that trend north-northwest in Birimian-aged metabasaltic units, and forms a secondary gold resource. Gold mineralisation is restricted to formation in the late Eburnean Orogeny and formed during a change from east-west to transcurrent compression and shearing. The Bagassi deposits demonstrate that granitoids emplaced prior to onset of the Eburnean Orogeny represent viable gold mineralisation in host rocks that are increasingly seen to be associated with significant gold resources.     

Mapping the sub-trappean Mesozoic sediments in the western part of Narmada–Tapti region of Deccan Volcanic Province,India

Deccan Traps spread over large parts of south, west and central India, possibly hiding underneath sediments with hydrocarbon potential. Here, we present the results of seismic refraction and wide-angle reflection experiments along three profiles, and analyze them together the results from all other refraction profiles executed earlier in the western part of Narmada–Tapti region of the Deccan Volcanic Province (DVP). We employ travel time modelling to derive the granitic basement configuration, including the overlying Trap and sub-trappean sediment thickness, if any. Travel time skips and amplitude decay in the first arrival refraction data are indicative of the presence of low velocity sediments (Mesozoic), which are the low velocity zones (LVZ) underneath the Traps. Reflection data from the top of LVZ and basement along with the basement refraction data have been used to derive the Mesozoic sediment thickness.In the middle and eastern parts of the study region between Narmada and Tapti, the Mesozoic sediment thickness varies between 0.5 and 2.0 km and reaches more than 2.5 km south of Sendhwa between Narmada and Tapti Rivers. Thick Mesozoic sediments in the eastern parts are also accompanied by thick Traps. The Mesozoic sediments along the present three profiles may not be much prospective in terms of its thickness, except inside the Cambay basin, where the subtrappean sediment thickness is about 1000–1500 m. In the eastern part of the study area, the deepest section (>4 km) has thick (∼2 km) Mesozoic sediments, but with almost equally thick Deccan Trap cover. Results of the present study provide important inputs for future planning for hydrocarbon exploration in this region.     

Origin of Mesozoic ophiolitic mélanges in the western Yarlung Zangbo suture zone,SW Tibet

The petrogenesis and tectonic evolution of the Mesozoic ophiolitic mélanges in the western section of the Yarlung Zangbo suture zone (YZSZ) remain controversial. In this paper, we present the results of whole-rock geochemical and SrNd isotope analyses, zircon UPb ages and in situ LuHf isotopic data obtained from mafic rocks of the northern and southern sub-belts of the western YZSZ Mesozoic ophiolitic mélanges to help us understand these controversial issues. Diabases and dolerites from the northern sub-belt and gabbros from the southern sub-belt exhibit variable fore-arc basalt (FAB)-like geochemical compositions and have zircon UPb ages of ∼126.4–120.3 Ma. In addition, gabbro-diabases from the northern sub-belt have boninite series affinities and yield a zircon UPb age of ∼125.7 Ma. These results, along with previous studies on the YZSZ Mesozoic ophiolitic mélanges and the Gangdese arc, reveal that the western YZSZ Mesozoic ophiolites were likely generated over multiple stages in the epicontinental Gangdese fore-arc basin as the Yarlung Zangbo Neo-Tethyan Ocean subducted northward in front of the Lhasa terrane. The Early Cretaceous FAB-like and boninite series mafic rocks were formed by the reinitiation of subduction, which was followed by a retreat of the subduction zone and the creation of the fore-arc basin and strong hyperextension, accompanied by asthenosphere upwelling at ∼130–120 Ma. During this process, the upwelling asthenosphere underwent decompressional melting with limited penetration of slab-derived fluids and gave rise to the N-MORB (normal mid-ocean ridge basalt)-like basaltic magmas that intruded the overlying, previously generated depleted mantle as FAB-like gabbro, diabase and dolerite sills or dykes. Then, boninitic magmas represented by boninitic gabbro-diabases were generated by remelting the extremely depleted residual mantle source, which was metasomatized by a small amount of slab-derived fluids, following previous extractions of FAB-like magma.     

Fault-block structure and state of stress in the Earth’s crust of the Gusinoozersky Basin and the adjacent territory,western Transbaikal region

The geological structure and tectonophysics of the Gusinoozersky Basin—a tectonotype of Mesozoic depressions in the western Transbaikal region—is discussed. New maps of the fault-block structure and state of stress in the Earth’s crust of the studied territory are presented. It is established that the Gusinoozersky Basin was formed in a transtensional regime with the leading role of extension oriented in the NW-SE direction. The transtensional conditions were caused by paths of regional tension stresses oriented obliquely to the axial line of the basin, which created a relatively small right-lateral strike-slip component of separation (in comparison with normal faulting) along the NE-trending master tectonic lines. The widespread shear stress tensors of the second order with respect to extension are related to inhomogeneities in the Earth’s crust, including those that are arising during displacement of blocks along normal faults. Folding at the basin-range boundary was brought about by gravity effects of normal faulting. The faults and blocks in the Gusinoozersky Basin remained active in the Neogene and Quaternary; however, it is suggested that their reactivation was a response to tectonic processes that occurred in the adjacent Baikal Rift Zone rather than to the effect of a local mantle source.     

Metallogenic efficiency from deposit to region–A case study in western Zhejiang Province,southeastern China

Metallogenic (ore) efficiency can be defined as the ratio of metal reserves to its total supply, and we expanded a typical efficiency-calculation model available at the single mineral scale to the regional scale. A new cell-based model was developed by analogy and by taking some other influences into account: i) a thicker sedimentary cover; ii) regional ore- and rock-controlling structures and their intersections; iii) the crustal heterogeneity unrelated and related to ores; and iv) metallic geochemical anomalies. Finally, a regional contour map of weighted efficiency, which is essential to metallogenic prediction, was obtained. It shows that the efficiency anomalies can provide a much better target area for ore-positioning than do metallic content anomalies, and greater ore efficiency may indicate the likelihood of occurrence of mineral deposits that are larger in size (reserves). Taking northwestern Zhejiang province as a case study, in which the geochemistry of Mesozoic porphyries plausibly show considerable mineralized potential, we found that due to the lower magmatic temperature, delayed exsolution of the hydrothermal solution, and very thick sedimentary cover, the Cu-polymetal ore efficiency associated with granitic plutons in this area is generally low; the relatively higher ore-productivity (efficiency) appears mainly in and around small rock bodies, rock margins, and the contacting zone between different lithologies. Most ore spots, no matter their size, fall into areas with nonzero efficiency values. There seems to be no interdependence between most ore spots of smaller size and ore efficiency, whereas efficiency is essential to regional small- and medium-scaled metallogensis.     

Assessment of heavy metals contamination in soils of Dexing region, Jiangxi Province, China

Heavy metal contamination has attracted huge concern due to its toxicity, abundance and persistence in the environment, and subsequent accumulation in soil, sediment and water. Mining is one of the most important sources of heavy metals in the environment. Mining-milling operations and disposal of tailings （the finely ground remains of milled ores） in addition to smelting and metal refining provide significant sources of pollution. Mining and mineral processing in the Dexing region of China have been carried out for over forty years and have contaminated the soils with heavy metals, Many studies were conducted to assess and establish the extent of heavy metal contamination in the soils due to mining. The aim of this work was to assess the environmental impact of mining on soils in the Dexing region and to identify the main factors involved in heavy metals dispersion. A 4800 km^2 study area was assessed with respect to its heavy metals on the basis of the current guideline values. In order to assess the extent of heavy metals contamination resulting from past mining activities in the Dexing region, 919 soil samples were collected and analyzed for As, Hg, Cd, Cr, Zn, Cu and Pb, Heavy metals levels were determined using inductively couple plasma-atomic emission spectrometry and X-ray fluorescence spectrometry. Results of soil samples reported concentrations between 1.790-899 mg/kg for As, 0.034-4.980 mg/kg for Hg, 0.043-8.330 mg/kg for Cd, 10-666 mg/kg for Cr, 25-18500 mg/kg for Zn, 6-1825 mg/kg for Cu, and 16-1312 mg/kg for Pb, respectively. The maximum values of As, Hg, Cd, Cr, Zn, Cu and Pb concentration in soils were up to 60, 33, 41, 7, 185, 52 and 37 times higher than the tolerable level, respectively. Meanwhile, the single-factor pollution index and Nemerow pollution index were used to assess the environment quality of heavy metals contamination.     

Complexity in hydro-seismicity of the Koyna–Warna region,India

Koyna–Warna region in western India is known to be the largest case of the reservoir-triggered seismicity in the world with M6.3 earthquake in 1967. This region continues to be seismically active even after 45 years with occurrences of earthquakes up to M5.0. The porous crustal rocks of Koyna–Warna region respond to changes in the prevailing stress/strain regime. This crustal section is highly fractured and is being fed by rivers and reservoirs. It is also subjected to fluctuating plate boundary forces and significant gravity-induced stresses due to crustal inhomogeneities. These changes induce variations in the water level in bore wells before, during and after an earthquake, and their study can help in understanding the earthquake genesis in the region. The ongoing seismicity thus requires understanding of coupled hydrological and tectonic processes in the region. Water table fluctuations are a reflection of the ongoing hydro-tectonics of the region. The fractal dimension of water levels in the bore wells of the region can be used as measure of the nonlinear characteristics of porous rock, revealing the underlying complexity. In this paper, we present values of correlation dimensions of the water level data in the bore wells using the nonlinear time series methodology. The spatiotemporal changes in the fractal dimensions have also been determined. The results show that hydro-seismically the region behaves as a low-dimensional nonlinear dynamical system.     

Role of Multiple Décollement Horizons in the Structural Style of the Sefid-Zakhur Anticline in the Fars Province,Zagros Belt

Geotectonics - The geometry of the Sefid-Zakhur anticline, a gas reservoir in the Fars province, and the main controlling factors of the structural style in this anticline are studied in this...     

Petrogenesis of the Neogene volcanic units in the NE–SW-trending basins in western Anatolia,Turkey

The western Anatolian volcanic province formed during Eocene to Recent times is one of the major volcanic belts in the Aegean–western Anatolian region. We present new chemical (whole-rock major and trace elements, and Sr, Nd, Pb and O isotopes) and new Ar/Ar age data from the Miocene volcanic rocks in the NE–SW-trending Neogene basins that formed on the northern part of the Menderes Massif during its exhumation as a core complex. The early-middle Miocene volcanic rocks are classified as high-K calc-alkaline (HKVR), shoshonitic (SHVR) and ultrapotassic (UKVR), with the Late Miocene basalts being transitional between the early-middle Miocene volcanics and the Na-alkaline Quaternary Kula volcanics (QKV). The early-middle Miocene volcanic rocks are strongly enriched in large ion lithophile elements (LILE), have high ⁸⁷Sr/⁸⁶Sr_(i) (0.70631–0.71001), low ¹⁴³Nd/¹⁴⁴Nd_(i) (0.512145–0.512488) and high Pb isotope ratios (²⁰⁶Pb/²⁰⁴Pb = 18.838–19.148; ²⁰⁷Pb/²⁰⁴Pb = 15.672–15.725; ²⁰⁸Pb/²⁰⁴Pb = 38.904–39.172). The high field strength element (HFSE) ratios of the most primitive early-middle Miocene volcanic rocks indicate that they were derived from a mantle source with a primitive mantle (PM)-like composition. The HFSE ratios of the late Miocene basalts and QKV, on the other hand, indicate an OIB-like mantle origin—a hypothesis that is supported by their trace element patterns and isotopic compositions. The HFSE ratios of the early-middle Miocene volcanic rocks also indicate that their mantle source was distinct from those of the Eocene volcanic rocks located further north, and of the other volcanic provinces in the region. The mantle source of the SHVR and UKVR was influenced by (1) trace element and isotopic enrichment by subduction-related metasomatic events and (2) trace element enrichment by “multi-stage melting and melt percolation” processes in the lithospheric mantle. The contemporaneous SHVR and UKVR show little effect of upper crustal contamination. Trace element ratios of the HKVR indicate that they were derived mainly from lower continental crustal melts which then mixed with mantle-derived lavas (~20–40%). The HKVR then underwent differentiation from andesites to rhyolites via nearly pure fractional crystallization processes in the upper crust, such that have undergone a two-stage petrogenetic evolution.     

Changes in annual and seasonal temperature extremes in the arid region of China, 1960–2010

Daily data of minimum and maximum temperature from 76 meteorological stations for 1960–2010 are used to detect the annual and seasonal variations of temperature extremes in the arid region, China. The Mann–Kendall test and Sen estimator are used to assess the significance of the trend and amount of change, respectively. Fifteen temperature indices are examined. The temperature extremes show patterns consistent with warming, with a large proportion of stations showing statistically significant trends. Warming trends in indices derived from daily minimum temperature are of greater magnitudes than those from maximum temperature, and stations along the Tianshan Mountains have larger trend magnitudes. The decreases in frequency for cold extremes mainly occur in summer and autumn, while warm extremes show significant increases in frequency in autumn and winter. For the arid region as a whole, the occurrence of cold nights and cold days has decreased by ?1.89 and ?0.89 days/decade, respectively, and warm nights and warm days has increased by 2.85 and 1.37 days/decade, respectively. The number of frost days and ice days exhibit significant decreasing trends at the rates of ?3.84 and ?2.07 days/decade. The threshold indices also show statistically significant increasing trends, with the extreme lowest temperatures faster than highest temperatures. The diurnal temperature range has decreased by 0.23 °C/decade, which is in accordance with the more rapid increases in minimum temperature than in maximum temperature. The results of this study will be useful for local human mitigation to alterations in water resources and ecological environment in the arid region of China due to the changes of temperature extremes.     

Development of a three-dimensional basin model to evaluate the site effects in the tectonically active near-fault region of Gölyaka basin,Düzce,Turkey

Natural Hazards - The high seismicity and tectonic activity of the study area located in a near-fault region in Gölyaka, Düzce, results in a bedrock geometry highly complex in the sense...     

Gold–Silver mineralization in porphyry–epithermal systems of the Baimka trend,western Chukchi Peninsula,Russia

Mineralogical, fluid inclusion, and geochemical studies of precious metal mineralization within the Baimka trend in the western Chukchi Peninsula have been preformed. Porphyry copper–molybdenum–gold deposits and prospects of the Baimka trend are spatially related to monzonitic rocks of the Early Cretaceous Egdygkych Complex. Four types of precious metal-bearing assemblages have been identified: (1) chalcopyrite + bornite + quartz with high-fineness native gold enclosed in bornite, (2) low-Mn dolomite + quartz + sulfide (chalcopyrite, sphalerite, galena, tennantite-tetrahedrite) ± tourmaline with low-fineness native gold and hessite, (3) rhodochrosite + high-Mn dolomite + quartz + sulfide (chalcopyrite, sphalerite, galena, tennantite- tetrahedrite) with low-fineness native gold, electrum, acanthite, Ag and Au–Ag tellurides, and Ag sulfosalts, and (4) calcite + quartz + sulfide (chalcopyrite, sphalerite, galena) with low-fineness native gold, Ag sulfides and selenides, and Ag-bearing sulfosalts. Study of fluid inclusions from quartz, sphalerite, and fluorite have revealed that hydrothermal ores within the Baimka trend precipitated from fluids with strongly variable salinity at temperatures and pressures ranging from 594 to 104°C and from 1200 to 170 bar, respectively. An indicator of vertical AgPbZn/CuBiMo geochemical zoning is proposed. The value range of this indicator makes it possible to estimate the erosion level of the porphyry–epithermal system. The erosion level of the Baimka deposits and prospects deepens in the following order: Vesenny deposit → Pryamoi prospect → Nakhodka prospect → Peschanka deposit → III Vesenny prospect.     

Stratigraphic correlation of the Devonian sequence in the Blantyre Sub-basin,Darling Basin,western New South Wales∗

Seismic sections and the analysis of lithostratigraphic units from well-log data were used to develop a new stratigraphic correlation of the Winduck, Snake Cave and Ravendale Intervals for the Blantyre Sub-basin. The stratigraphic boundaries of the intervals were defined at marked changes in well-log characteristics, and depth estimates of the boundaries were derived from the well-log data in Mt Emu 1, Blantyre 1 and Kewell East 1. Six seismic-stratigraphic boundaries have been identified in the seismic sections to show the continuity of the latest Silurian to Holocene sediments throughout the Blantyre Sub-basin; from bottom to top they are: H-1, base of the Winduck Interval; H-2, base of the Snake Cave Interval; H-3, base of the Ravendale Interval; H-4/5 base of the undifferentiated Upper Carboniferous/Permian sediments; and H-6 base of the undifferentiated Cenozoic sediments. All stratigraphic boundaries are based on good continuous markers, with strong amplitudes throughout the whole sub-basin. A three-dimensional geological model was developed from the seismic data to map out the geometry of the key reflectors, and hence the structure and stratigraphy of the Winduck, Snake Cave and Ravendale Intervals in the areas where these intervals have been preserved. This model has better defined the Wilcannia High and two smaller highs around the Mt Emu 1 and Snake Flat 1 wells, and further defines the relationships between the stratigraphy, sub-basin geometry and development of complex structures in the Blantyre Sub-basin.     

Land degradation assessment based on environmental geoindicators in the Fortaleza metropolitan region,state of Ceará, Brazil

This paper summarizes the results obtained by land degradation assessment in the Fortaleza Metropolitan Region, in the state of Ceará, Brazil. Area assessment was done in a two-phase study: the characterization of the environmental components by field and laboratory work, and a more detailed study in the degraded sites. Environmental geoindicators were used to classify the degradation level for each drainage basin as low, intermediate, or high. Coastal erosion, gravitational mass movements, dune movements, water erosion, sedimentation, water pollution, sanitary landfills in inappropriate sites, caves and abandoned mines of aggregates exploitation and occupation in swamp areas are the main land degradation sources registered in the region. Among the drainage basins for degradation level, 5 were classified as high, 3 as intermediate, and 4 as low. These problems have affected the people living in the region and demanded heavy investments to rehabilitate degraded areas.