基于TUV模式的银川光化辐射通量特征及其影响因子

利用TUV模式计算分析了银川光化辐射通量变化特征,探讨了云、气溶胶、臭氧柱浓度、NO_(2)柱浓度等因子对银川光化辐射通量的影响。结果表明:2019年7—9月银川月平均光化辐射通量分别为6.5E+16光子数·cm^(-2)·s^(-1)、5.6E+16光子数·cm^(-2)·s^(-1)和4.7E+16光子数·cm^(-2)·s^(-1),日最大值出现在13:00;波长小于325 nm时,光化辐射通量随波长增加缓慢上升,波长在325—480 nm之间时,光化辐射通量迅速升高,波长大于480 nm时,光化辐射通量随波长增加变化较小,此特征在中午前后较早晚表现更明显;云光学厚度和气溶胶光学厚度对光化辐射通量的衰减作用具有明显的“U”型日变化特征,比较而言,气溶胶光学厚度对光化辐射通量衰减作用的“U”型波形更为宽广;光化辐射通量衰减率对较低的云光学厚度的变化更敏感;光化辐射通量随气溶胶光学厚度增加而减小的变率要比随云光学厚度增加而减小的变率小;光化辐射通量对单次散射反照比大于0.6的强散射性气溶胶的变化更敏感,且气溶胶光学厚度越大,此特性整体表现越明显;波长指数对光化辐射通量的影响相对较小。     

水面蒸发量的一种气候学计算方法

用北京日射站和官厅蒸发站的辐射和蒸发资料对彭曼公式进行订正,得出修正公式 E_0=(ΔH_0+γE_α)/(Δ+γ) H_0=1/59[0.95Q_A(0.167+0.583n/N)-σT_a~4(0.32-0.26e_a~(1/2))(0.30+0.70n/N)] E_a=0.13(e_a-e_d)(1+0.77u),其中H_0是表示为蒸发量单位的辐射平衡,E_a是由风速和饱和差决定的“干燥力”。 自由水面的蒸发量E可用下式表示 E=E_0-F/L,其中F是水面向下的热通量,在升温季节为正值,在降温季节为负值。由于缺少水温梯度观测资料,F不能直接计算。本文建议,对升温或降温季节分别建立水面蒸发E倚蒸发势E_0的回归方程。得出北京地区各月蒸发量的计算公式如下 0.963 E_0-7.0 4—7月 E=0.902 E_0+26.0 9—10月 E_0 8月     

用t+t12代替Tm作气压高度差订正

为了简化Tm值的计算方法,我们提出了用t t_(12)值代替Tm值查算气压高度差订正值的方法。 大家知道,Tm=(t t_(12))/2 h/400 (1)式中Tm为气柱平均温度,t为观测时的气温,t_(12)为观测前12小时的气温,h为气压表水银槽拔海高度。 我们可以把上式改写为: (Tm-h/400)×2=t t_(12) (2) 这样在查气压高度差订正值时就不用计算Tm值,只要计算出t t_(12)值就可以了。 具体做法是先用已做好的气压高度差订正表中的     

利用简化动力学近似分析黑河实验区的感热通量

本文利用简化动力学近似．运用统计和参数化两种方法分析了黑河实验区的感热通量．结果表明：不稳定条件下绿洲区的感热通量与近地面辐射温度(T3)和空气温度(Ta)之差符合幂定律方程；沙漠地区符合形式为H=f[u(T2-Ta)]的幂定律方程。利用从实验得到的热传输附加阻尼表示式kB^-1=0．2u(T2-Ta)用于对空气动力学阻尼(ra)的参数化，可适用于不同下垫面．并得到了比较满意的感热通量值．最后利用以上结果计算了实验区的潜热通量并做了比较分析。     

第一规定等压面高度查算简表的制作

要求算本站第一规定等压面的高度,规范只给了地面气压与第一规定等压面间0℃、干燥时的厚度,若平均温度及相对湿度不是0℃或干燥,则需进行订正,最后加上本站的拔海高度,才能求出本站第一规定等压面的高度。 目前,台站在查算第一规定等压面高度时,通常采用的办法是,求出K值后拉计算尺、查曲线图和查     

08时小图报微机编报中5appp组的一种计算方法

1 思路在省局业务处《气业发(1991)038号》文件中规定,一般航危报站应用地面测报程序《DMCX—A_2》编发08时小图报时,为求三小时变量△P_3需用08时气压自记订正差值去订正05时气压自记读数,用订正后的05时气压自记值来代替三小时前本站气压。这种计算方法需单独启动程序DEF·Z来计算气压值,并要经过两次手工计算,比较繁琐且易出差错。实际上,若用08时气压自记订正差值来作为05时气压自记订正差值,便有:P05=PJS+(P08-PJ8)     

区域极轨卫星ATOVS辐射偏差订正方法研究

近年来,卫星辐射资料在数值天气预报(NWP)系统中的直接同化研究取得了长足进展。为了利用TIROS业务垂直探测器(ATOVS)的辐射资料,必须对卫星观测辐射值的系统性偏差进行订正。在ECMWF原全球TOVS辐射偏差订正方案基础上,结合ATOVS资料特征和中国的实际情况,建立了适用于区域NOAA-15/16/17极轨气象卫星ATOVS辐射资料的偏差订正方案。该方案偏差订正分两步进行:首先进行扫描偏差订正,然后进行气团偏差订正。扫描偏差是临边测量相对于星下点测量的系统偏差,统计显示该种偏差具有一定的纬度依赖性,所以订正时按每10度的纬度带分别进行订正。气团偏差订正主要就是根据当时的天气条件进行订正,而天气条件一般用预报因子来定量表示。文中从中国国家气象中心T213背景场导出预报因子:(1)1000—300 hPa的厚度,(2)200—50 hPa的厚度,(3)模式地表温度,(4)总可降水量。模式预报因子的使用从观念上将对观测值的订正变为对计算前向辐射值的订正问题。试验结果表明,订正结果显著。     

中国西北大气沙尘光学特性的数值试验

利用 1991年 2月下旬～ 5月中旬HEIFE张掖和沙漠站的大气浑浊度观测、地面辐射观测及同期卫星资料 ,借助NCARCCM 3中的辐射模式CRM ,模拟估算了我国西北大气沙尘气溶胶的部分光学参数 ,单次散射反照率 (ω0 )和光学厚度比 [k(τλ=8～ 14 /τλ=0 .55) ]。计算结果表明 ,清洁天ω0 和k(τλ =8～ 14 /(τλ =0 .55)在沙漠和绿洲均为 0 .94和 0 .1;浑浊天ω0 在绿洲为 0 .90 ,沙漠为 0 .84 ;k(τλ=8～ 14 /τλ =0 .55)在绿洲为 0 .3 ,沙漠为 0 .4。在气候模式中 ,可将我国西部沙尘源区大气沙尘的ω0 和k(τλ =8～ 14 /τλ=0 .55)分别取为 0 .88和 0 .3。     

中国西部干旱地区太阳直接辐射通量密度与大气质量的关系

本文根据中国西部干旱地区大气物理状态(大气可降水量和大气浑浊度)的变化范围,利用太阳直接辐射通量密度的理论计算公式,计算了各种大气透明系数状况下的太阳直接辐射通量密度。计算结果表明,大气质量m=2时的透明系数P_2和m相同时,由于水汽和气溶胶的含量配置不同而引起太阳直接辐射通量密度的差异,在辐射日变程的主要时段(m=1-3)内并不大。于是得到各种透明系数P_2状况下太阳直接辐射通量密度随大气质量变化的平均关系。不同海拔高度比较,当透明系数P_2相同时,各自的大气物理状态虽然不同,但m相同时的太阳直接辐射通量密度基本相同。现有的表征太阳直接辐射通量密度值和大气质量联系的关系式都不能很好地描述计算结果。根据太阳直接辐射通量密度随大气质量变化的特性,我们提出了新的关系式。最后,整理了不同拔海高度和不同地理景观的四个日射站(西藏那曲、青海格尔木、甘肃敦煌和民勤)的多年观测资料。经验计算结果与观测值比较,一致性良好。     

使用AHDM4．1应注意的几个问题

1　关于 3次站 0 2时定时值的输入3次站 0 2时定时值大部分台站采用订正后的自记值代替 ,但在输入数据时 ,风速要进行四舍五入。2　关于 0 2时水气压、相对湿度、露点温度的求算方法 1 :每天按干球温度输入订正后的 0 2时温度自记值或求算出的 0 2时气温值 ,并在其后加“*”;湿球温度输入订正后的 0 2时相对湿度自记值 ,并在其后加“*”;气压输入订正后的 0 2时气压自记值 ,并在其后加“*”。月末在完成“D”文件后 ,执行 AHDM4.1中 YCZF菜单中第一项 [8]计算生成水气压、相对湿度、露点温度。将二者进行比较 ,发现问题可以及时改正。方…     

Tidal currents off the antarctic ice barrier,Queen Maud Land

Observations of tidal currents in lat. 71° 01 S, long. 10° 55 W indicate that a semi-diurnal tidal wave progresses towards the WSW, that is, parallel to the main direction of the barrier. ForM ₂ the cotidal hour appears to be about 7^h, in good agreement with the value 6.7^h, that is derived from observations of the atmospheric pressure. Furthermore, the current measurements indicate that the ratio(K ₁+O₁)/(M₂+S₂) is large, perhaps as large as 2.5.

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Zusammenfassung Beobachtungen der Gezeitenströmungen in 71° 01 S und 10° 55 W lassen erkennen, daß eine halbtägige Gezeitenwelle gegen WSW, also parallel zur Hauptrichtung der Eisbarriere, wandert. FürM ₂ scheint das Flutstundenintervall etwa 7 Stunden zu betragen und damit gut zu dem Wert von 6,7 Stunden zu stimmen, der aus Beobachtungen des Luftdrucks abgeleitet wird. Ferner lassen Strömungsmessungen erkennen, daß der Quotient(K ₁+O₁)/(M₂+S₂) mit etwa 2,5 groß ist.

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Résumé Des observations des courants de marée, faites à 71° 01 S et 10° 55 W, montrent qu'une vague de marée semi-diurne progresse en direction WSW, ce qui est parallèle à la direction principale de la limite de la banquise. PourM ₂ l'heure cotidale paraît être de 7^h environ, ce qui correspond assez bien avec la valeur de 6.7^h déduite des observations de la pression atmosphérique. En outre les mesures du courant indiquent que le quotient(K ₁+O₁)/(M₂+S₂) est assez grand et comporte environ 2.5.

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With 1 Figure.     

On Transpiration and Soil Moisture Content Sensitivity to Soil Hydrophysical Data

Sensitivity of evapotranspiration E and root zone soil moisture content θ to the parameterization of soil water retention Ψ(θ) and soil water conductivity K(Ψ), as well as to the definition of field capacity soil moisture content, is investigated by comparing Psi1-PMSURF and Theta-PMSURF models. The core of PMSURF (Penman–Monteith Surface Fluxes) consists of a 3-layer soil moisture prediction module based on Richard’s equation in combination with the Penman–Monteith concept for estimating turbulent heat fluxes. Psi1- PMSURF and Theta-PMSURF differ only in the parameterization of the moisture availability function F_ma. In Psi1,F_ma is parameterized by using Ψ(θ) and K(Ψ) hydrophysical functions; in Theta, F_ma is parameterized by using hydrophysical parameters: the field capacity θ_f and wilting point θ_w soil moisture contents. Both Psi1 and Theta are based on using soil hydrophysical data, that is, there is no conceptual difference between them in the parameterization of E even if in Psi1F_ma depends on 12 parameters, while in Theta only on two soil/vegetation parameters. Sensitivity tests are performed using the Cabauw dataset. Three soil datasets are used: the vG (van Genuchten), CH/vG (Clapp and Hornberger/van Genuchten) and CH/PILPS (Clapp and Hornberger/Project for Intercomparison of Land-surface Parameterization Schemes) datasets. The vG dataset is used in van Genuchten’s parameterization, while in Clapp and Hornberger’s the CH/vG and CH/PILPS datasets are used. It is found that the consistency of soil hydrophysical data in the simulation of transpiration is quite important. The annual sum of E obtained by Psi1E^Psi1, differs from the annual sum of E obtained by Theta, E^Theta, because of the inconsistency between the fitting parameters of Ψ(θ) and K(Ψ) and the θ_f, and not because of the differencies in the parameterization of F_ma. Further, θ_f can be estimated not only on the basis of using soil hydrophysical functions (the θ_f so obtained is θ^Soil_f) but also on the basis of analysing the transpiration process (the θ_fso obtained is θ^tr_f). θ^tr_f values estimated from the condition E^Theta ≈ E^Psi1 are in acceptable accordance with the θ^Soil_f values proposed by Wösten and co-workers. The results are useful in optimizing the parameterization of transpiration in land-surface schemes.     

A variable K planetary boundary-layer model

The steady-state, homogeneous and barotropic equations of motion within the planetary boundary layer are solved with the assumption that the coefficient of eddy viscosity varies as K(Z) = K _O(1–Z/h) ^p , where h is the height of the bounday layer and p is a parameter which depends on atmospheric stability. The solutions compare favourably with observed velocity profiles based on the Wangara data.     

Kritische Bemerkung zur Frage der Temperatur-abhängigkeit der Ozonverteilung

Zusammenfassung A. undE. Vassy haben in der Frage der Temperatur-abhängigkeit des Ozongehalts der Atmosphäre aus der Gleichung loge _n –logJ _n logK(T _n ) geschlossen, daß auch die Gleichung loge _n logJ _n +logK(T _n ) gültig sei. Es wird hier nun gezeigt, daß die bei der ersten Gleichung erlaubten Vernachlässigungen bei der zweiten zu großen Fehlern führen können und daß daher von A. undE. Vassy kein Beweis für die Richtigkeit der Beziehunge=J.K(T) erbracht ist.

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Summary In the question of temperature dependence of ozone content of the atmosphere A. andE. Vassy have concluded from the equation loge _n –logJ _n logK(T _n ) that also the formula loge _n logJ _n +logK(T _n ) must be valid. In this paper it is proved that the neglections which may be admitted for the first equation, can conduct to great errors. Therefore A. andE. Vassy have not produced a proof for the correctness of the equatione=J.K(T).

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Résumé A. etE. Vassy en étuidant le problème de la teneur de l'ozone atmosphérique en relation avec la température ont admis que l'équation loge _n –logJ _n logK(T _n ) entraînait aussi la relation loge _n logJ _n +logK(T _n ). On montre ici que les simplifications admises pour la première équation conduisent pour l'application de la seconde à de fortes erreurs, et que par conséquent ces auteurs n'ont pas fourni de preuve de la justesse de la relatione=J.K(T).

     

Henry's law and the behavior of weak acids and bases in fog and cloud

Experimental data from two field experiments on ground based clouds were used to study the distribution of formic acid, acetic acid, ammonia and S(IV) species between liquid and gas phase. The ratio of the concentrations of these compounds between the phases during concurrent measurements was compared to ratios expected according to Henry's law (considering the pH influence). Large discrepancies of several orders of magnitude were seen. Three hypotheses have been investigated to explain the observed discrepancies: The existence of a microscale equilibrium which does not persist in a bulk sample, a thermodynamic shift of the equilibrium due to competing reactions, and nonequilibrium conditions due to mass transfer limitations. Approximate quantitative calculations show that none of these hypotheses is sufficient to explain all of the discrepancies, so a combination of different effects seems to be responsible for this observation. The same theoretical considerations also suggest that mass transfer limitation may be an important factor for highly soluble compounds. The data presented here indicates that it is not possible to simply extrapolate interstitial gas phase composition from measured bulk liquid phase concentrations of a fog or cloud.Notation [r _max] liquid phase molar uptake rate (mol l^–1 s^–1) - [A _g ] concentration ofA in gas phase (atm) - [A _l ] concentration ofA in liquid phase (mol l^–1) - [A _g , 0] concentration ofA in gas phase (atm) at time 0 - LWC liquid water content (g m^–3) - R universal gas constant (0.082 l atm mol^–1 K^–1 - D _g diffusivity (for all gases 0.1 cm² s^–1 was used) - K _H ^* effective Henry's law coefficient (mol l^–1 atm^–1) - t _f lifetime of fog droplet (s) - a droplet radius (cm) - accommodation coefficient - R factor of discrepancy - T temperature (K) - v mean molecular speed (cm s^–1) formic acid: 35 000 acetic acid: 31 000 ammonia: 58 000     

Prediction of the abiotic degradability of organic compounds in the troposphere

A statistically relevant correlation between the reaction rate coefficient, k _OH, for the OH radical reaction with 161 organic compounds in the gas phase at 300 K, and the corresponding vertical ionisation energies E _i,v, reveals two classes of compounds: aromatics where –log(k _OH/cm³s^-1)3/2E _i,v(eV)–2 and aliphatics where –log(k _OH/cm³s^-1)4/5E _i,v(eV)+3. The prediction of the rate coefficient, k _OH, for the reaction of OH with organic molecules from the above equations has a probability of about 90%. Assuming a global diurnal mean of the OH radical concentration of 5×10⁵ cm³, the upper limit of the tropospheric half-life of organic compounds and their persistence can be estimated.     

Henry's law coefficients for aqueous solutions of acetone,acetaldehyde and acetonitrile,and equilibrium constants for the addition compounds of acetone and acetaldehyde with bisulfite

Vapor phase concentrations of acetone, acetaldehyde and acetonitrile over their aqueous solutions were measured to determine Henry's law partition coefficients for these compounds in the temperature range 5–40 °C. The results are for acetone: ln(H ₁/atm)=–(5286±100)T+(18.4±0.3); acetaldehyde: ln(H ₁/atm)=–(5671±22)/T+(20.4±0.1); and acetonitrile: ln(H ₁/atm)=–(4106±101)/T+(13.8±0.3). Artificial seawater of 3.5% salinity in place of deiionized water raisesH ₁ by about 15%. A similar technique has been used to measure the equilibrium constants for the addition compounds of acetone and acetaldehyde with bisulfite in aqueous solution. The results are ln(K ₁/M ^–1)=(4972±318)/T–(11.2±1.1) and ln(K ₁/M ^–1)=(6240±427)/T–(8.1±1.3), respectively. The results are compared and partly combined with other data in the literature to provide an average representation.     

Solubility of HOCl in water and aqueous H2SO4 to stratospheric temperatures

Henry's law constants K_H (mol kg^–1 atm^–1) for the reaction HOCl_(g)=HOCl_(aq) near room temperature, literature data for the associated enthalpy change, and solubilities of HOCl in aqueous H₂SO₄ (46 to 60 wt%) at temperatures relevant to the stratosphere (200 KT230 K) are shown to be thermodynamically consistent. Effective Henry's law constants [H*=mHOCl/pHOCl, in mol kg^–1 atm^–1] of HOCl in aqueous H₂SO₄ are given by: ln(H*)=6.4946–mH₂SO₄(–0.04107+54.56/T)–5862 (1/T_o–1/T) where T(K) is temperature and T_o=298.15K. The activity coefficient of HOCl in aqueous H₂SO₄ has a simple Setchenow-type dependence upon H₂SO₄ molality.     

Comparison of human radiation exchange models in outdoor areas

Results from the radiation components of seven different human thermal exchange models/methods are compared. These include the Burt, COMFA, MENEX, OUT_SET* and RayMan models, the six-directional method and the new Park and Tuller model employing projected area factors (f _p) and effective radiation area factors (f _eff) determined from a sample of normal- and over-weight Canadian Caucasian adults. Input data include solar and longwave radiation measured during a clear summer day in southern Ontario. Variations between models came from differences in f _p and f _eff and different estimates of longwave radiation from the open sky. The ranges between models for absorbed solar, net longwave and net all-wave radiation were 164, 31 and 187?W?m^?2, respectively. These differentials between models can be significant in total human thermal exchange. Therefore, proper f _p and f _eff values should be used to make accurate estimation of radiation on the human body surface.     

A comparison of turbulence statistics in the surface layer over plant canopies with those over several other surfaces

Turbulence statistics, including higher order moments, in the surface layer over plant canopies were compared with those observed over several different surfaces, using a nondimensional height (z – d)/z ₀: The values of (z – d)/z ₀extend over a very wide range from 10 over plant canopies to 10⁷ over the ocean. Several properties such as intensities of turbulence and skewness factors show a remarkable height-dependency in the air layer below (z – d)/z ₀ = 10², which is supposed to be much influenced by the underlying surface. In that layer, some peculiar phenomena, such as a downward energy transport and positive flux of shear stress, are frequently observed.