Late Quaternary climatic changes in southern Chile, as recorded in a diatom sequence of Lago Puyehue (40°40′ S)

A late Quaternary diatom stratigraphy of Lago Puyehue (40°40′ S, 72°28′ W) was examined in order to infer past limnological and climatic changes in the South-Chilean Lake District. The diatom assemblages were well preserved in a 1,122 cm long, ¹⁴C-dated sediment core spanning the last 17,900 years, and were in support of an early deglaciation of Lago Puyehue. The presence of a short cold spell in South Chile, equivalent to the Younger Dryas event in the Northern Hemisphere, the Antarctic Cold Reversal in Antarctica, or the Huelmo-Mascardi event in southern South America, was not clearly evidenced in the diatom data, although some climate instability may have occurred between 13,400 and 11,700 cal. yr. BP, and a relatively long period (between 16,850 and 12,810 cal. yr. BP) with low absolute abundances and biovolumes could be tentatively interpreted as a period of low rainfall and/or temperatures. An increase in the moisture supply to the lake was tentatively inferred at 12,810 cal. yr. BP. After 9,550 cal. yr. BP, inferred stronger and longer persisting summer stratification, may have been the result of the higher temperatures associated with an early-Holocene thermal optimum. The mid-Holocene appeared to be characterized by a decrease in precipitation, culminating around 5,000 cal. yr. BP, and rising again after 3,000 cal. yr. BP, likely associated with a previously documented lowered frequency and amplitude of El Niño events. An increase in precipitation during the late Holocene (3,000 cal. yr. BP–present) might have marked subsequent increased frequency of El Niño occurrences, leading to drier summers and slightly moister winters in the area.     

A pollen-based record of late glacial–Holocene climatic variability in the southern lake district, Chile

A pollen record from Puyehue area (40°S; 72°W) in the southern Lake District, Chile, indicates that prior to 13,410 ¹⁴C yr BP (ca. 16,500–15,200 cal yr BP), cold resistant and hygrophilous vegetation, particularly Nothofagus forest and myricaceous vegetation, covered the area. From ca. 15,000 cal yr BP onward, the forest became increasingly dense. Between 10,010 and 7450 ¹⁴C yr BP (ca. 11,000–8000 cal yr BP), the expansion of Nothofagus obliqua and the spread of grasses suggests the climate became warmer and semi-arid. Lowland deciduous forest (Nothofagus obliqua, Aextoxicon punctatum, Laurelia sempervirens) and Valdivian rainforest (Nothofagus dombeyi, Eucryphia cordifolia, Caldcluvia paniculata, Aextoxicon punctatum, Laureliopsis philippiana) were abundant. During the next two thousand years, stable warm climatic conditions prevailed, and the diversity of the vegetation increased. From 5760 to 1040 ¹⁴C yr BP (ca. 6500–900 cal yr BP), the North Patagonian rainforest expanded. The presence of Pilgerodendron/Fitzroya, together with Nothofagus forest, suggests that humid conditions prevailed. During the last millennium, human impact intensified and regional vegetation was disturbed, particularly the lowland deciduous forest and Valdivian rainforest. North-Patagonian and subantartic taxa, such as Podocarpus nubigena, Pilgerodendron/Fitzroya, Nothofagus dombeyi type, Austrocedrus chilensis and Drimys winteri, occupied the low and high-altitude parts of the Cordillera. Five hundred years ago, shrub and grasses expanded in the Nothofagus forest, suggesting that forest became more open under cool–cold, and humid climatic conditions. These conditions prevail to the present day. This is the fourth in a series of eight papers published in this special issue dedicated to the 17,900 year multi-proxy lacustrine record of Lago Puyehue, Chilean Lake District. The papers in this special issue were collected by M. De Batist, N. Fagel, M.-F. Loutre and E. Chapron.     

A multi-proxy record of the Last Glacial Maximum and last 14,500?years of paleoenvironmental change at Lone Spruce Pond, southwestern Alaska

Sediment cores from Lone Spruce Pond (60.007°N, 159.143°W), southwestern Alaska, record paleoenvironmental changes during the global Last Glacial Maximum (LGM), and during the last 14,500 calendar years BP (14.5?cal?ka). We analyzed the abundance of organic matter, biogenic silica, carbon, and nitrogen, and the isotope ratios of C and N, magnetic susceptibility, and grain-size distribution of bulk sediment, abundance of alder shrub (Alnus) pollen, and midge (Chironomidae and Chaoboridae) assemblages in a 4.7-m-long sediment sequence from the depocenter at 22?m water depth. The basal unit contains macrofossils dating to 25?C21?cal?ka (the global LGM), and is interpreted as glacial-lacustrine sediment. The open water requires that the outlet of the Ahklun Mountain ice cap had retreated to within 6?km of the range crest. In addition to cladocerans and diatoms, the glacial-lacustrine mud contains chironomids consistent with deep, oligotrophic conditions; several taxa associated with relatively warm conditions are present, suggestive of relative warmth during the global LGM. The glacial-lacustrine unit is separated from the overlying non-glacial lake sediment by a possible disconformity, which might record a readvance of glacier ice. Non-glacial sediment began accumulating around 14.5?cal?ka, with high flux of mineral matter and fluctuating physical and biological properties through the global deglacial period, including a reversal in biogenic-silica (BSi) content during the Younger Dryas (YD). During the global deglacial interval, the ??¹³C values of lake sediment were higher relative to other periods, consistent with low C:N ratios (8), and suggesting a dominant atmospheric CO₂ source of C for phytoplankton. Concentrations of aquatic faunal remains (chironomids and Cladocera) were low throughout the deglacial interval, diversity was low and warm-indicator taxa were absent. Higher production and air temperatures are inferred following the YD, when bulk organic-matter (OM) content (LOI 550?°C) increased substantially and permanently, from 10 to 30?%, a trend paralleled by an increase in C and N abundance, an increase in C:N ratio (to about 12), and a decrease in ??¹³C of sediment. Post-YD warming is marked by a rapid shift in the midge assemblage. Between 8.9 and 8.5?cal?ka, Alnus pollen tripled (25?C75?%), followed by the near-tripling of BSi (7?C19?%) by 8.2?cal?ka, and ??¹⁵N began a steady rise, reflecting the buildup of N and an increase in denitrification in soils. Several chironomid taxa indicative of relatively warm conditions were present throughout the Holocene. Quantitative chironomid-based temperature inferences are complicated by the expansion of Alnus and resulting changes in lake nutrient status and production; these changes were associated with an abrupt increase in cladoceran abundance and persistent shift in the chironomid assemblage. During the last 2,000?years, chironomid-assemblage changes suggest cooler temperatures, and BSi and OM values were generally lower than their maximum Holocene values, with minima during the seventh and eighth centuries, and again during the eighteenth century.     

Lake levels in the southern Bolivian Altiplano (19°–21°S.) during the Late Glacial based on diatom studies

This study is focused on the endorheic Uyni-Coipasa Basin located in the southern Bolivian Altiplano. Stratigraphical and fossil diatom studies based on a detailed radiocarbon chrnology revealed six phases in water-level changes and paleosalinity variations. At 15,430±80 yr B.P., lacustrine conditions settled in the southern Bolivian Altiplano. A saline lake, characterized by benthic meso-metasaline species, reached +4 m altitude above the present bottom of the basin. After 15,430±80 yr B.P., the level rapidly rose to +27 m, as suggested by a tychoplanktonic mesosaline flora. Between 14,500 years and 13,000 years, finely lanminated sediments at +32 m contained successively a dominance of epiphytic mesosaline to hypersaline species and tychoplanktonic oligosaline diatoms, indicating weak fluctuations in water-level and salinity. At 13,000 years, strong changes in the diatom flora occurred; epiphytic oligo-hypersaline diatoms were replaced by planktonic meso-polysaline species. They indicate a deep salt lake (the lake reached +100 m). After 12,000 years, the lake level abruptly dropped, as suggested by fluviatile sediments with a benthic mesopolysaline diatom flora. The main lake was replaced by shallow saline ponds. A wet pulse occurred at 11,400 years, characterized by low water level (+7 m) and high salinity. This lacustrine phase remained until 10,400 yr B.P. These data indicate changes in Precipitation minus Evaporation (P-E). Our regional interpretations are based on a comparison with teh available data on the northern (Lake Titicaca) and southern (Lipez are) Bolivian Altiplano and on the northern Chilean Altiplano (Atacama Desert).     

A statistical approach to disentangle environmental forcings in a lacustrine record: the Lago Chungará case (Chilean Altiplano)

A high resolution multiproxy study (magnetic susceptibility, X-ray diffraction, XRF scanner, gray-colour values, Total Organic Carbon, Total Inorganic Carbon, Total Carbon and Total Biogenic Silica) of the sedimentary infill of Lago Chungará (northern Chilean Altiplano) was undertaken to unravel the environmental forcings controlling its evolution using a number of different multivariate statistical techniques. Redundancy analyses enabled us to identify the main provenance of the studied proxies whereas stratigraphically unconstrained cluster analyses allowed us to distinguish the “outsiders” as result of anomalous XRF scanner acquisitions. Principal Component Analysis (PCA) was employed to identify and isolate the main underlying environmental gradients that characterize the sedimentary infill of Lago Chungará. The first eigenvector of the PCA could be interpreted as an indicator of changes in the input of volcaniclastic material, whereas the second one would indicate changes in water availability. The chronological model of this sedimentary sequence was constructed using 17 AMS ¹⁴C and 1 ²³⁸U/²³⁰Th dates in order to characterize the volcaniclastic input and the changes in water availability in the last 12,300 cal years BP. Comparison of the reconstructed volcaniclastic input of Lago Chungará with the dust particle record from the Nevado Sajama ice core suggested that the Parinacota volcano eruptions were the main source of dust during the mid and Late Holocene rather than the dry out lakes as has previously been pointed out. The comparison of the water availability reconstruction of Lago Chungará with three of the most detailed paleoenvironmental records of the region (Paco Cocha, Lake Titicaca and Salar Uyuni) showed an heterogeneous (and sometimes contradictory) temporal and spatial pattern distribution of moisture. Although the four reconstructions showed a good correlation, each lacustrine ecosystem responded differently to the moisture oscillations that affected this region. The variations in the paleoenvironmental records could be attributed to the dating uncertainities, lake size, lake morphology, catchment size and lacustrine ecosystem responses to the abrupt arid events.     

Climate change and human impact at Sacrower See (NE Germany) during the past 13,000 years: a geochemical record

Lacustrine sediments in north-eastern Germany have rarely been used as archives to address the effects of climate change and human impact on both lake ecosystem and landscape evolution for this region. Sacrower See, a hardwater lake located in Brandenburg, provides a unique sediment record covering the past 13,000 years which was used to reconstruct climatic and anthropogenic forcing on lacustrine sedimentation. Time control is provided by 12 AMS ¹⁴C dates of terrestrial plant remains, the Laacher See Tephra, and the onset of varve formation in AD 1870 (80 cal. BP). Geochemical (including XRF logging of major elements, CNS analyses as well as δ¹³C_org and δ¹⁵N measurements) and pollen analyses allowed detecting detailed environmental changes in the sediment record. During the Younger Dryas cold phase increased soil erosion and hypolimnetic oxygen depletion enhanced the nutrient supply to the lake water causing eutrophic conditions. The beginning of the Holocene is characterized by large changes in C/N ratios, total sulphur, δ¹³C of bulk organic matter as well as in K, Si, and Ti, reflecting the response of the lake’s catchment to climatic warming. Reforestation reduced the influx of detrital particles and terrestrial organic matter. The first, rather weak evidence of human impact is documented only in the pollen record at 5,500 cal. BP. However, until 3,200 cal. BP sedimentological and geochemical parameters indicate relatively stable environmental conditions. During periods of intense human impact at around 3,200, 2,800, and 900 cal. BP peaks in Ti and K represent phases of increased soil erosion due to forest clearing during the Bronze Age, Iron Age, and Medieval Times, respectively. In general, greater variation is observed in most variables during these perturbations, indicating less stable environmental conditions. The steady rise of biogenic silica accumulation rates during the Holocene reflects an increasing productivity of Sacrower See until diatoms were outcompeted by other algae during the last centuries. The applied multi-proxy approach fosters the interpretation of the sediment record to reveal a consistent picture of environmental change including environmental factors controlling lake ontogeny and the effects of human impact.     

Last deglaciation and Holocene environmental change at high altitude in the Pyrenees: the geochemical and paleomagnetic record from Marboré Lake (N Spain)

Sedimentological, geochemical and magnetic data in a ~ 7-m sequence from Marboré Lake (2612 m asl, central Pyrenees) provide information about environmental variability since the last glacier retreat (14.6 cal ka BP) in high-altitude Pyrenean environments. The sediment sequence is composed of millimeter- to centimeter-thick rhythmites made of finer greyish laminae and coarser-grain, carbonate-bearing laminae arranged in varied patterns throughout the sequence. Finer laminae are interpreted as deposition during periods of predominantly ice-covered conditions, whereas coarser, carbonate-bearing sediments reflect periods of higher runoff. The age model, based on 13 ¹⁴C dates and a reservoir effect assessed with ²¹⁰Pb and ¹³⁷Cs, is coherent with known synchronous vegetation changes across the Pyrenees. Warmer intervals such as GI-1 (14.6–12.8 cal ka BP, Bølling/Allerød period), 10.4–8.2 cal ka BP in the Early Holocene, 7.5–5.2 cal ka BP in the Mid Holocene and the Medieval Climate Anomaly (AD 900–1300), are characterized by peaks in productivity and higher carbonate preservation. Deposition during colder periods such as GS-1 (12.8–11.7 cal ka BP), the Neoglacial (ca. 5.2–3.5 cal ka BP) and the Little Ice Age (last 400 years) show an increase in finer laminae. The presence of magnetite throughout the whole section suggests that Marboré Lake maintained predominantly oxic conditions since its formation. Changes in magnetic properties and the increase in magnetite from 3.5 cal ka BP to present, however, indicate a more oxic environment at the lake bottom during the last few millennia. The occurrence of Pb concentration peaks in sediments of Roman and modern age demonstrates the global distribution of heavy metal deposition, even into high-mountain lakes.     

Flood response to rainfall variability during the last 2000 years inferred from the Taravilla Lake record (Central Iberian Range, Spain)

A sedimentological, geochemical and palynological study of the Taravilla Lake sequence (Central Iberian Range, NE Spain) provides a detailed record of allochthonous terrigenous layers that intercalate within the lacustrine sediments over the last 2000 years. These terrigenous layers are interpreted as the result of extreme hydrological events that caused higher clastic input to the basin. Anthropogenic influence caused by fires or deforestation is rejected as the main factor generating these layers because human impact, inferred from the pollen reconstruction, was minimal when the terrigenous layers reached their greatest frequency. The reconstructed occurrence of these events in the Taravilla Lake record is coherent with the paleoflood history of the Tagus River, characterized by a notable increase of extreme events at the beginning of the Little Ice Age. The Taravilla record suggests a relationship between the occurrence of extreme hydrological events, solar variability, and the North Atlantic Oscillation for the NE Iberian Peninsula.     

The San Nicolás succession of the Cauca paleolake: a late Holocene laminated ria lake record from the Neotropics

The stratigraphic, geochemical, and organic matter study of the late Holocene San Nicolás succession of the Cauca paleolake (Santa Fé–Sopetrán pull-apart basin) in the middle Cauca Valley, northern Colombia, suggests that it was deposited in a ria lake environment, at sedimentary accumulation rates in excess of 600 cm ky^?1 between ~3500 and ~500 yr BP. Laminated deposition occurred, first under igapo (black-water), and then under varzea (white-water) conditions. The transition occurred ca. 3000 yr BP, a time of major change in El Niño/Southern Oscillation (ENSO) behavior in the Cariaco Basin, thus reflecting the southern migration of the intertropical convergence zone and intensified rain upstream the Cauca Valley. A second, but less conspicuous change occurred ca. 2000 yr BP, which apparently corresponds to the intensified and/or more frequent ENSO activity in the Galapagos Islands. Our contribution describes, for the first time, a ria lake sedimentary succession from the northern Andes and demonstrates the high potential of these hitherto undervalued deposits for the reconstruction of the paleohydrological history of the northern Andes.     

A diatom-inferred record of reduced effective precipitation during the Last Glacial Coldest Phase (28.8–18.0?cal kyr BP) and increasing Holocene seasonality at Lake Pupuke, Auckland, New Zealand

A continuous, 1,420-cm sediment record from Lake Pupuke, Auckland, New Zealand (37°S) was analysed for diatom taxonomy, concentration and flux. A New Zealand freshwater diatom transfer function was applied to infer past pH, electrical conductivity, dissolved reactive phosphorus and chlorophyll a. A precise, mixed-effect regression model of age versus depth was constructed from 11 tephra and 13 radiocarbon dates, with a basal age of 48.2?cal kyr BP. Diatom-inferred changes in paleolimnology and climate corroborate earlier inferences from geochemical analyses (Stephens et al. 2012), with respect to the timing of marked climate changes in the Last Glacial Coldest Phase (LGCP; 28.8?C18.0?cal kyr BP), the Last Glacial Interglacial Transition (LGIT; 18.0 to ca. 12?C10?cal kyr BP) and the Holocene, the onset of which is difficult to discern from LGIT amelioration, but which includes an early climatic optimum (10.2?C8.0?cal kyr BP). The LGCP is readily defined by a reduction in lake level and effective precipitation, whereas the LGIT represents a period of rising lake level, with greater biomass during the Holocene. There was limited change in diatom assemblage structure, influx or inferred water quality during a Late Glacial Reversal (LGR; 14.5?C13.8?cal kyr BP), associated with heightened erosional influx. In contrast, an LGIT peak in paleoproductivity is recorded by increased diatom influx from 13.8 to 12.8?cal kyr BP. Changes in sediment influx and biomass record complex millennial-scale events attuned to the Antarctic Cold Reversal (ACR; 14.5?C12.8?cal kyr BP). Additional millennial-scale environmental change is apparent in the Holocene, with marked changes in lake circulation beginning at 7.6?cal kyr BP, including the onset of seasonal thermal stratification and rapid species turnover at 5.7?cal kyr BP. The most rapid diatom community turnover accompanied widely varying nutrient availability and greater seasonality during the last 3.3?cal kyr. Rising seasonality appears to have been linked to strengthened Southern Westerlies at their northern margins during the middle and late Holocene.     

Mid- to Late Holocene pollen and alluvial record of the arid Andean piedmont between 33° and 34°S,Mendoza, Argentina: Inferences about floodplain evolution

In arid and semiarid regions of Central West Argentina, paleoenvironmental conditions and history of the Holocene vegetation is still scanty. This paper presents the analysis of palynological records of two Mid- to Late Holocene alluvial sequences (La Escala -LES- and Brazo Abandonado -BA-) in the fluvial basin of the Arroyo La Estacada (33°27′S and 69°03′W), placed in the Cordillera Frontal central piedmont of Mendoza province. Variations in pollen assemblages of the two sequences related to the environments developed in the floodplains of the arroyo allowed us to infer the evolution of local plant communities. Between the ca. 4000 and 3000 ¹⁴C years BP and between ca. 500 and 400 ¹⁴C years BP, a larger representation of hydrophytic communities related to environments with local water availability was inferred; and between ca. 3000 and 500 ¹⁴C years BP an increase in shrubby xerophytic communities related to environments with lower water availability was detected. These results led us to propose that the Holocene pollen spectra fluctuations observed in the alluvial sedimentary sequences prove mainly changes in plant communities of the floodplain environment in response to the fluvial dynamics of the arroyo.     

Climate changes during the last glacial termination inferred from diatom-based temperatures and pollen in a sediment core from Längsee (Austria)

A sediment core section from Längsee, a small meromictic lake in the southern Alpine lowland (Carinthia, Austria) close to the Würmian ice margin, was investigated by means of diatoms and pollen. The main aims of the study were to reconstruct water temperature as a signal of climate change during the last glacial termination, compare the aquatic and terrestrial response to the changing climate, and place our findings into a climatic frame on the northern hemispheric scale. A calibration data set (ALPS06) of 116 lakes was constructed using data from newly studied lakes and from two previously published data sets and we established a transfer function for predicting summer epilimnetic water temperatures (SEWT). A locally weighted weighted average regression and calibration model (R _jack ²  = 0.89; RSMEP = 1.82°C) was applied to the fossil diatom assemblages in order to reconstruct SEWT. Three major sections were distinguished in the time window of approximately 19–13 cal ka BP, which fitted well with the oxygen isotope curve and the isotope-event stratigraphy from the Greenland ice-core GRIP. The first section was a warming period (SEWT range from 11.6 to 18.0°C; average 15.8°C = ca. 6°C below present) called the Längsee oscillation, which probably correlates with the warmer sub-section (GS-2b) of the Greenland Stadial 2. The subsequent section represents a climate cooling, called the Längsee cold period (SEWT range between 10.6 and 15.9°C; average 12.9°C), which probably corresponds with the sub-section GS-2a of the Greenland Stadial 2, the Heinrich 1 cold event of the North Atlantic, and partially the Gschnitz Stadial in the Alps. The Längsee cold period shows a tri-partition: Two colder phases are separated by a warmer inter-phase. The passive ordination of the core sample scores along maximum water depth indicated that the Längsee cold period was drier than the Längsee oscillation. Strong short-term fluctuations during the Längsee oscillation and the Längsee cold period indicate climate instability. The third section represented climate warming during the Längsee late glacial interstadial (=Greenland Interstadial 1, GI-1) with an average SEWT of 17.5°C. From the minor climatic fluctuations during this interstadial, mainly indicated by pollen, the fluctuation most likely related to the Gerzensee oscillation showed a SEWT decline. During the early immigration and expansion period of shrubs and trees, aquatic and terrestrial records showed distinct discrepancies that might have arose because of time lags in response and differences in sensitivity.     

Variation in the moisture regime of northeastern interior Alaska and possible linkages to the Aleutian Low: inferences from a late-Holocene δ18O record

Analyses of oxygen and carbon isotopes in bulk carbonate and Chara-stem encrustations, X-ray diffraction, and sediment composition from Keche Lake offer new information on climatic change over the past ~3,400?years in northeastern interior Alaska. The ??¹⁸O and ??D values of water samples from the lake and its inlet streams suggest that evaporation plays an important role in determining the isotopic composition of Keche Lake water at present. However, evaporative enrichment does not appear to be a major driver of the pronounced fluctuations in the bulk-carbonate ??¹⁸O record on the basis of comparison with Chara-??¹⁸O values. The ??¹⁸O values of bulk carbonate in the Keche Lake sediments vary by up to 10??? over the past 3,400?years, with maximum values of ?12??? around 3,400?cal BP and between 2,100 and 1,500?cal BP. High ??¹⁸O peaks are associated with sediments dominated by quartz, feldspar, and clay minerals suggesting the influence of detrital carbonate. Multi-millennial patterns of ??¹⁸O variation at Keche Lake appear to be linked with changes in watershed and sediment-depositional processes, which may be driven by varying moisture abundance associated with the position of the Aleutian Low (AL). The increasing trend of carbonate ??¹⁸O from 3,400 to ~2,100?cal BP probably reflects the increasing importance of a westerly AL, and the high frequency of ??¹⁸O spikes ~2,100?C1,500?cal BP may have resulted from the prevalence of a westerly AL position. Predominance of a westerly AL likely increased snowfall and winter temperature in the region. Such conditions would have promoted soil erosion and thermokarst activity during spring snowmelt, resulting in episodic large influxes of detrital carbonate to Keche Lake and elevating bulk-carbonate ??¹⁸O. Over the past 1,500?years, bulk-carbonate ??¹⁸O remained relatively high at Keche Lake but variation was much less pronounced than before. A broad ??¹⁸O peak centered ~400?cal BP may be related to enhanced winter moisture during the Little Ice Age, although our chronology is inadequate for a rigorous assessment of this interpretation. This study contributes a new ??¹⁸O record and offers additional information on past moisture-regime shifts associated with changing atmospheric-circulation patterns.     

Late Quaternary (24–10 ka BP) environmental history of the Neotropical lowlands inferred from ostracodes in sediments of Lago Petén Itzá, Guatemala

We inferred late Pleistocene and early Holocene (24–10 ka BP) environmental conditions in and around Lago Petén Itzá, Guatemala from ostracode remains in the lake sediments. Multivariate statistics were run on autecological information for 29 extant ostracode species collected in 63 aquatic ecosystems on the Yucatán Peninsula along a steep, increasing NW–S precipitation gradient and across a large altitudinal range. Conductivity and water depth are the most important factors that shape ostracode communities. Transfer functions were developed and applied to fossil ostracode assemblages in a ~76-m sediment core (PI-6, ~85 ka) taken in 71 m of water from Lago Petén Itzá, to infer past shifts in conductivity and water level. Results suggest climate was cold and wet during the Last Glacial Maximum (LGM). Alternating dry and wet conditions characterized the deglacial. Early Holocene climate was warmer and wetter. The LGM was characterized by low ostracode species richness (4 spp.) and abundance (<940 valves g⁻¹), dominance of benthic over nektobenthic taxa, abundant Physocypria globula, conductivity as low as 190 μS cm⁻¹, and clay-rich sediments with relatively high total organic carbon and low C/N ratios (<14), suggesting relatively deeper water at the core site associated with abundant precipitation. Greatest water depth at the core site during the LGM occurred late in the period and was ~50 m. The deglacial was characterized by drier conditions, higher ostracode species richness (6 spp.) and abundances up to 18,115 valves g⁻¹, dominance of nektobenthic species, and presence of shallow-water and littoral-zone indicators such as Heterocypris punctata and Strandesia intrepida, conductivity up to 550 μS cm⁻¹, C/N ratios as high as 37, and gypsum deposition. Lowest inferred lake depth at the core site during the deglacial was ~20 m. The early Holocene was characterized by high numbers of ostracode remains, up to 25,500 valves g⁻¹, and the presence of L. opesta and P. globula. Cytheridella ilosvayi was absent from late Pleistocene sediments, suggesting it colonized northern Central America during the Holocene.     

Chironomids as indicators of climate change: a 100‐lake training set from a subarctic region of northern Sweden (Lapland)

Multivariate numerical analyses (DCA, CCA) were used to study the distribution of chironomids from surface sediments of 100 lakes spanning broad ecoclimatic conditions in northern Swedish Lapland. The study sites range from boreal forest to alpine tundra and are located in a region of relatively low human impact. Of the 19 environmental variables measured, ordination by CCA identified mean July air temperature as one of the most significant variables explaining the distribution and the abundance of chironomids. Lossonignition (LOI), maximum lake depth and mean January air temperature also accounted for significant variation in chironomid assemblages. A quantitative transfer function was created to estimate mean July air temperature from sedimentary chironomid assemblages using weightedaveraging partial least squares regression (WAPLS). The coefficient of determination was relatively high (r² = 0.65) with root mean squared error of prediction (RMSEP, based on jack-knifing) of 1.13 °C and maximum bias of 2.1 °C, indicating that chironomids can provide useful quantitative estimates of past changes in mean July air temperature. The paper focuses mainly on the relationship between chironomid composition and July air temperature, but the relationship to LOI and depth are also discussed.     

Нigh-Quality Development Path of the Enclave Economy from the Perspective of Symbiosis: A Case Study of Guangqing Economic Cooperation Zone (Guangde Park)

The enclave economy is an important governance tool for promoting regional integration. Guangdong Province occupies the leading position in exploring the enclave economy model in China, which has effectively promoted the development of the east and northwest of Guangdong Province through the point to area approach. However, certain problems that are associated with the enclave economy concept, including a weak level of industrial relatedness, disconnection with the development of the local urban system, and inadequate interest driving mechanisms, need to be urgently addressed. The article aims to explore the high-quality development path of the enclave economy in the new era, taking advantage of the symbiosis theory. Based on field research and semi-structured interview methods, the present study attempts to not only probe into the cooperative relationship and mutually beneficial symbiosis mechanism among different actors in the enclave economy but also explore a more sustainable and mutually beneficial development enclave economy model. With respect to theoretical contribution, based on the symbiosis theory and the characteristics of the enclave economy, this study facilitates a better understanding of the high-quality development logic of the enclave economy from the perspective of symbiosis in particular and establishes a theoretical framework comprising the industrial symbiosis network-industrial symbiosis unit-interest symbiosis mechanism components. Empirically, this study takes the Guangqing Economic Cooperation Zone (Guangde Park) as the case study; reveals the development process and problems of the enclave economy, including the isolation of industry transplantation, fragmentation of industry-city units, and locking of interests and mismatch between rights and responsibilities; and proposes high-quality development strategies, such as establishing a cross-regional enclave economic circle, a resource-linking platform between industry and city, and a community of interests in industrial parks and towns, to form a more sustainable symmetric and mutually beneficial symbiotic mechanism. The key contribution of this study lies in the theoretical framework for the high-quality development of the enclave economy through the lens of symbiosis, which enriches the ways of analysis and cognitive logic of the enclave economy and advances cross-regional cooperation and enclave economy research. It enhances the cross-territorial geographic thinking of regional cooperation and enclave economy research, holding the potential to provide decision-making references for the promotion of regional coordinated development in Guangdong Province in the new period. It also has practical application value for relieving the pressure of unbalanced and insufficient regional development in China by promoting cross-municipal and cross-provincial cooperation. © 2023 Environmental Sanitation Engineering. All rights reserved.     

Environmental changes in northern New Zealand since the Middle Holocene inferred from stable isotope records (δ15N, δ13C) of Lake Pupuke

Maar lakes in the Auckland Volcanic Field are important high-resolution archives of Holocene environmental change in the Southern Hemisphere mid-latitudes. Stable carbon and nitrogen isotope analyses were applied on bulk organic matter and the green alga Botryococcus from a sediment core from Lake Pupuke (Auckland, North Island, New Zealand) spanning the period since 7,165?cal.?year BP. The origin of organic matter was established using total-organic?Ccarbon-to-nitrogen ratios (TOC/TN) as well as organic carbon (??¹³C_OM) and nitrogen (??¹⁵N) isotope composition of potential modern sources. This approach demonstrated that the contribution of allochthonous organic matter to the lake sediment was negligible for most of the record. The sedimentary TOC/TN ratios that are higher than Redfield ratio (i.e. >7) are attributed to N-limiting conditions throughout the record. Variations of nitrogen and carbon isotopes during the last 7,165?years are interpreted as changes in the dominant processes in the lake. While epilimnetic primary productivity controlled isotope composition before 6,600?cal.?year BP, microbial processes, especially denitrification and methane oxidation, caused overall shifts of the ??¹⁵N and ??¹³C values since the Mid-Holocene. Comparisons with climate reconstructions from the Northern Island suggest that changes in the wind-induced lake overturn and a shift to more pronounced seasonality were the most likely causes for lake-internal changes since 6,600?cal.?year BP.     

Greigite (Fe3S4) as an indicator of drought – The 1912–1994 sediment magnetic record from White Rock Lake, Dallas, Texas, USA

Combined magnetic and geochemical studies were conducted on sediments from White Rock Lake, a reservoir in suburban Dallas (USA), to investigate how land use has affected sediment and water quality since the reservoir was filled in 1912. The chronology of a 167-cm-long core is constrained by the recognition of the pre-reservoir surface and by 137Cs results. In the reservoir sediments, magnetic susceptibility (MS) and isothermal remanent magnetization (IRM) are largely carried by detrital titanomagnetite that originally formed in igneous rocks. Titanomagnetite and associated hematite are the dominant iron oxides in a sample from the surficial deposit in the watershed but are absent in the underlying Austin Chalk. Therefore, these minerals were transported by wind into the watershed. After about 1960, systematic decreases in Ti, Fe, and Al suggest diminished input of detrital Fe-Ti oxides from the surficial deposits. MS and IRM remain constant over this interval, however, implying compensation by an increase in strongly magnetic material derived from human activity. Anthropogenic magnetite in rust and ferrite spherules (from fly ash?) are more common in sediment deposited after about 1970 than before and may account for the constant magnetization despite the implied decrease in detrital Fe-Ti oxides. An unexpected finding is the presence of authigenic greigite (Fe3S4), the abundance of which is at least partly controlled by climate. Greigite is common in sediments that predate about 1975, with zones of concentration indicated by relatively high IRM/MS. High greigite contents in sediment deposited during the early to mid-1950s and during the mid-1930s correspond to several-year periods of below-average precipitation and drought from historical records. Relatively long water-residence times in the reservoir during these periods may have led to elevated levels of sulfate available for bacterial sulfate reduction. The sulfate was probably derived via the oxidation of pyrite that is common in the underlying Austin Chalk. These results provide a basis for the paleoenvironmental interpretation of greigite occurrence in older lake sediments. The results also indicate that greigite formed rapidly and imply that it can be preserved in the amounts produced over a short time span (in this lake, only a few years). This finding thus suggests that, in some lacustrine settings, greigite is capable of recording paleomagnetic secular variation.