2006年台湾屏东海外7.2级地震前福建漳州汰内井水氡异常分析

通过对福建华安县汰内井2005年以来的水氡测值进行分析,提取了中期及短期异常,认为这些异常与2006年12月26日台湾屏东海外7.2级地震有关。     

Comparison of liquefaction potential of loess in Lanzhou, China, and Memphis, USA

This paper presents an evaluation of the liquefaction potential of loess in Lanzhou, China, and Memphis, USA. The topography, stratigraphy, and genesis of loess in these two areas were investigated and compared. Several loess samples in each study area were taken and their physical indices were determined. In addition, the microstructures of these loess samples were investigated using an electron microscope, and dynamic triaxial tests were performed using an artificial seismic wave. The results of this investigation indicated that both Lanzhou loess and Memphis loess have a potential for liquefaction, but Memphis loess is less susceptible to liquefaction. Furthermore, Lanzhou loess and Memphis loess behave differently during ground shaking.     

甘肃岷县两次中强地震震源机制研究

利用地震震中周围7个台站的数字记录反演了甘肃岷县2003年11月13日ML5．5和2004年9月7日ML5．2地震的矩张量,得出了震源机制。将所得结果与用P波初动符号的结果进行了比较,二者具有较好的一致性。结合该地区的地震分布,对可能的发震断层进行了讨论。     

Attenuation of P,S, and coda waves in Koyna region,India

The attenuation properties of the crust in the Koyna region of the Indian shield have been investigated using 164 seismograms from 37 local earthquakes that occurred in the region. The extended coda normalization method has been used to estimate the quality factors for P waves and S waves , and the single back-scattering model has been used to determine the quality factor for coda waves (Q _c). The earthquakes used in the present study have the focal depth in the range of 1–9 km, and the epicentral distance vary from 11 to 55 km. The values of and Q _c show a dependence on frequency in the Koyna region. The average frequency dependent relationships (Q = Q ₀ f ⁿ) estimated for the region are , and . The ratio is found to be greater than one for the frequency range considered here (1.5–18 Hz). This ratio, along with the frequency dependence of quality factors, indicates that scattering is an important factor contributing to the attenuation of body waves in the region. A comparison of Q _c and in the present study shows that for frequencies below 4 Hz and for the frequencies greater than 4 Hz. This may be due to the multiple scattering effect of the medium. The outcome of this study is expected to be useful for the estimation of source parameters and near-source simulation of earthquake ground motion, which in turn are required in the seismic hazard assessment of a region.     

Comments on the use of Ti,Zr, Y,Sr, K,P and Nb in classification of basaltic magmas

The distribution of Ti, Zr, Y, Sr, K, P and Nb has been investigated at 55 sample sites within a single basaltic flow, the Cliefden Outcrop, which has adjusted to low-grade metamorphism of the prehnite-pumpellyite facies. The cluster of points in the plot of Ti, Zr and Y as proposed by Pearce and Cann shows that the ratio of these elements has remained relatively constant after metamorphism and would therefore have significance in attempts at classification of magma type. Likewise a plot involving Nb, Y, Zr and P as proposed by Floyd and Winchester shows only restricted scatter and appears useful. However, plots involving Sr or K show a scatter that is clearly related to metamorphic processes. Consequently, plots involving these two elements are likely to be of little use in classification in this case.Low-grade metamorphism is common, variable and not always recognized. The study concerned one style of alteration and revealed problems in the application of some classification schemes. Consequently it is apparent that much more rigorous testing is needed before classification schemes can be generally applied to sequences of basaltic rocks.     

Fractionation in the solar nebula,II. Condensation of Th,U, Pu,and Cm

Reasonable assumptions concerning activity coefficients allow the calculation of the relative volatility of the actinide elements under conditions expected during the early history of the solar system. Several of the light rare earths have volatilities similar to Pu and Cm and can be used as indicators of the degree of fractionation of these extinct elements. Uranium is considerably more volatile than either Pu or Cm, leading to fractionations of about a factor of 50 and 90 in the Pu/U and Cm/U ratio in the earliest condensates from the solar nebula. Ca, Al-rich inclusions from the Allende meteorite, including the coarse-grained inclusions, have a depletion of U relative to La of about a factor of three, suggesting that these inclusions may have been isolated from the nebular gas before condensation of U was complete. The inclusions, however, can be used to determine solar Pu/U and Cm/U ratios if the rare earth patterns are determined in addition to the other normal measurements.     

Sources of variability in springwater chemistry in Fool Creek,a high-elevation catchment of the Rocky Mountains,Colorado, USA

Springs are the point of origin for most headwater streams and are important regulators of their chemical composition. We analysed solute concentrations of water emerging from 57 springs within the 3 km² Fool Creek catchment at the Fraser Experimental Forest and considered sources of spatial variation among them and their influence on the chemical composition of downstream water. On average, calcium and acid neutralizing capacity (bicarbonate-ANC) comprised 50 and 90% of the cation and anion charge respectively, in both spring and stream water. Variation in inorganic chemical composition among springs reflected distinct groundwater sources and catchment geology. Springs emerging through glacial deposits in the upper portion of the catchment were the most dilute and similar to snowmelt, whereas lower elevation springs were more concentrated in cations and ANC. Water emerging from a handful of springs in a geologically faulted portion of the catchment were more concentrated than all others and had a predominant effect on downstream ion concentrations. Chemical similarity indicated that these springs were linked along surface and subsurface flowpaths. This survey shows that springwater chemistry is influenced at nested spatial scales including broad geologic conditions, elevational and spatial attributes and isolated local features. Our results highlight the role of overlapping factors on solute export from headwater catchments.     

Quench rates in air, water, and liquid nitrogen, and inference of temperature in volcanic eruption columns

We apply a geospeedometer previously developed in this lab to investigate cooling rate profiles of rhyolitic samples initially held at 720–750°C and quenched in water, liquid nitrogen, and air. For quench of mm-size samples in liquid nitrogen and in air, the cooling rate is uniform and is controlled by heat transfer in the quench medium instead of heat conduction in the sample. The heat transfer coefficient in ‘static’ air decreases with increasing sample size. For quench of mm-size samples in water, heat transfer in water is rapid and the cooling rate is largely controlled by heat conduction in the sample. Our experimental results are roughly consistent with previous calculations for cooling in air and in water (although constant heat transfer coefficients were used in these calculations), but cooling rate in liquid nitrogen is only 1.8–2.3 times that in ‘static’ air, and slower by a factor of 2 than calculated by previous authors. Cooling rate in compressed airflow is about the same as that in liquid nitrogen. The experimental results are applied to interpret cooling rates of pyroclasts in ash beds of the most recent eruptions of the Mono Craters. Cooling rates of pyroclasts are inversely correlated with sample size and slower than those in air. The results indicate that the hydrous species concentrations of the pyroclasts were frozen in the eruption column, rather than inside ash beds or in flight in ambient air. From the cooling rates, we infer eruption column temperature in a region where and at a time when hydrous species concentrations in a pyroclast were locked in. The temperature ranges from 260 to 570°C for the most recent eruptions of Mono Craters. These are the first estimates of temperatures in volcanic eruption columns. The ability to estimate cooling rates and eruption column temperatures from eruptive products will provide constraints to dynamic models for the eruption columns.     

Role of sediment in solute acquisition in the Himalayan glacier meltwater stream,Gangotri glacier,Uttarakhand, India

Low temperature in-stream solute acquisition in a glacial environment with very high suspended sediment is critical for downstream evolution of water chemistry. Present work is carried out on 18 km headwater reach from Gomukh (snout of the Gangotri glacier) to Gangotri along River Bhagirathi, India for understanding the hydrological processes controlling the solute acquisition in the glacial environment. This is the first attempt to conduct dissolution experiments with river bed sediments and meltwater considering different operating variables namely; contact time, seasonality, different sediment particle sizes, different sediment dose, effect of pH, wetting and crushing of bed sediments of the glacial stream. The role of sediment in low temperature solute acquisition process is characterized by sudden release of ions from the sediment in initial few seconds. Equilibrium time was observed to be 600 s (10 min). Further progressive increase in EC was observed from Gomukh to Gangotri, suggesting change in sediment surface characteristics/or source. Higher dissolution was observed from the bed sediments collected in June. It is found that the dissolution increases with increase in sediment doses but decreases with an increase in sediment particle size fraction. Higher solute acquisition was observed from crushed sediment because of an abundance of very fine particles having fresh, aggressive/reactive mineral surfaces which are capable of dissolution. The solute released from wetted sediment is significantly lower than the fresh sediment, which may be attributed to the destruction of microparticles adhering to mineral grains, the removal of fresh reactive surface sites, dissolution of rapidly weathered minerals such as calcite and evolution towards to equilibrium of the solution. Further, higher dissolution was observed with decrease in pH, which may be attributed to the availability of more hydrogen ion concentration of the solution, which favours more solute acquisition from sediment into meltwater.     

The Occurrence and Persistence of MTBE in Groundwater in Windham,Maine, USA

A study was conducted from July 1998 through November 2007 on the occurrence and distribution of the fuel oxygenate methyl tert-butyl ether (MTBE) in a large sand and gravel aquifer located in southern Maine. MTBE was detected in 44% of 129 water samples collected from monitoring wells in concentrations up to 38.7 µg/L (reporting limit = 0.1 µg/L). The number of wells with detectable quantities of MTBE declined slightly between 1999 and 2007, but in general MTBE persisted throughout the period of study. Overall, MTBE was detected more frequently in the shallow and more transmissive parts of the aquifer. There was a statistically significant difference (p < 0.001) for MTBE concentrations relative to nearby land uses. MTBE was detected in 83% of the samples collected from wells in low-density residential areas, in 50% of samples from urban areas, and in 60% of samples from undeveloped areas. The concentrations of MTBE in the test wells were compared across the sample dates for trends and seven wells had a positive trend (Mann–Kendall statistic), but none was significant at p < 0.05. Nine wells had a negative trend, but only one was significant at p < 0.05. Three wells had no trend. The absence of strong or even consistent trends indicates that MTBE persists in shallow groundwater, even after gasoline formulations were changed to reduce or eliminate MTBE.     

Mining,Environmental, Petroleum,and Engineering Industry Applications of Electromagnetic Techniques in Geophysics

Electromagnetic (EM) techniques are extremely important as a direct detection geophysical tool utilized in the base metal industry. They were developed in countries such as Canada, whose thin conductive weathering overburden did not hamper the penetration of EM signals and enabled exploration to depths on the order of 300 m. As a result, EM techniques were used widely in North America and Scandinavia for many years before they became common in countries with a thick conductive overburden, such as Australia. The 1980s and 1990s have seen the use of EM methods move from anomaly finding to mapping, as well as the development of better, faster and more accurate computer modelling algorithms. A review of EM papers, for the years 1998 to 2002, showed that most dealt with EM techniques as mapping tools. Airborne, ground and marine EM techniques are still being developed, as are data processing and interpretation software. The advent of robust 2-D and 3-D computer modelling and inversion algorithms has led to the acceptance of EM methods as a mapping tool for many environmental and petroleum industry applications, a trend which is expected to increase.     

Oceanographic distributions of cadmium,zinc, nickel,and copper in the North Pacific

Vertical profiles of Cd, Zn, Ni, and Cu have been determined at three stations in the North Pacific and in the surface waters on a transect from Hawaii to Monterey, California. The distributions found are oceanographically consistent and provide a needed confirmation and extension of several recent studies on the marine geochemistries of these metals. Cadmium concentrations average 1.4 pmol/kg in surface waters of the central North Pacific and show a strong correlation with the labile nutrients, phosphate and nitrate, increasing to values of 1.1 nmol/kg at depths corresponding to the phosphate maximum. Zinc is depleted in surface waters of the central gyre to an average value of 0.07 nmol/kg and increases to a deep maximum of 9 nmol/kg exhibiting a strong correlation with the nutrient silicate. Nickel concentrations average 2.1 nmol/kg in surface central gyre waters and increase to a deep maximum of 11 nmol/kg. Nickel is best correlated with a combination of phosphate and silicate. Copper averages less than 0.5 nmol/kg in surface waters of the central North Pacific and increases gradually to values of 5 nmol/kg in bottom waters. The Cu profiles show evidence of intermediate and deep water scavenging. The involvement of these metals in the internal biogeochemical cycles of the sea is responsible for their distributions which are predictable on the basis of oceanographic parameters.     

Acoustic properties of deformed rocks in the Nobeoka thrust,in the Shimanto Belt,Kyushu, Southwest Japan

Laboratory measurements for compressional and shear wave velocities (Vp and Vs, respectively) and porosity were conducted with core samples from the Nobeoka Thrust Drilling Project (NOBELL) under controlled effective pressure (5–65 MPa at 5 MPa intervals) and wet conditions. Samples were classified according to deformation texture as phyllite, foliated cataclasite, or non‐foliated cataclasite. Measured values of Vp, Vs, and porosity are within a range of 5.17–5.57 km/s, 2.60–2.71 km/s, and 2.75–3.10 %, respectively, for phyllite; 4.89–5.23 km/s, 2.46–2.57 km/s, and 3.58–4.53 %, respectively, for foliated cataclasite; and 4.90–5.32 km/s, 2.51–2.63 km/s, and 3.79–4.60 %, respectively, for non‐foliated cataclasite, which are all consistent with the previous laboratory experiments conducted with outcrop samples under dry conditions. However, our results also indicate higher Vp and Vs and lower porosity than those measured by the previous studies that adopted the wire‐line logging methods. The variations in Vp, Vs, and porosity are controlled by deformation structure and are greater for phyllite and foliated cataclasite than for non‐foliated cataclasite.     

Determination of nitrophenols,diaminotoluenes, and chloroaromatics in ammunition wastewater

Methods for the determination of three compound classes, i. e. diaminotoluenes, nitrophenols, and chloroaromatics in groundwater of a former ammunition plant are reported. Diaminotoluenes were extracted by discontinuous liquid/liquid-, nitrophenols by continuous liquid/liquid-extraction using dichloromethane, and chloroaromatics by solid-phase extraction. These compound classes may be analyzed by gas chromatography (GC) or gas chromatography coupled to mass spectrometry (GC/MS) without derivatization or after derivatization with N-methyl-bis(trifluoroacetamide) (MBTFA) or heptafluorobutyric anhydride (HFBA) in the case of diaminotoluenes and HFBA or acetic anhydride in the case of nitrophenols. An atomic emission detector (AED) coupled to a gas chromatograph may be employed for the analysis of chloroaromatics. High selectivity can be achieved using the characteristic wavelengths of chlorine. A variety of these compounds were identified and quantified in a groundwater sample from the former ammunition plant Elsnig (Saxony, Germany). Concentrations were in the lower ppb range. Thus, dichlorobenzenes which may have been used as substituents at the end of World War II could be identified in groundwater samples at this site.     

Catastrophic Tohoku earthquake of March 11, 2011, in Japan

The results of the comparative analysis of parameters of the Tohoku earthquake (Honshu Island, Japan) of March 11, 2011, 05:46 UTC and its aftershocks are presented.     

Investigation of Chemical Compositions of Urban,Industrial, Agricultural,and Rural Top‐soils in Izmir,Turkey

The top‐soil samples were collected from urban, industrial, agricultural, and rural sites to investigate the modification in the elemental composition due to anthropogenic influence in one of the biggest city of Turkey, namely Izmir. The elemental profiles were dominated by lithophilic elements such as Al, Ca, Fe, Mg, K, and sea salt element, Na, which is typical for Mediterranean region. The trace elemental concentrations showed significant variation with higher concentrations in the industrial sites, particularly in the vicinity of iron‐steel producers from scrap materials (EAF‐Steels). Lead, Zn, and Cd around EAF‐Steels were found to be higher than other sites. Comparison to universal upper crusts and local reference soil has shown that Izmir top‐soils were contaminated in terms of many trace elements, most probably due to anthropogenic activities. Correlation matrix, crustal enrichment factors, and factor analysis were applied to investigate the extent of soil modification and possible sources. The results indicated that the elemental profiles of top‐soils were mainly determined by parent materials; however, anthropogenic activities were found to be factor effective on the profile.     

Characteristics,origins, and significance of pyrites in deep-water shales

As important metal sulfides in the geochemical cycle of sulfur, the characteristics and formation processes of pyrites can provide useful clues regarding their environment. Based on previous findings, shale pyrites were divided into three major classes(euhedral pyrites, framboidal pyrites(framboids) and metasomatic pyrites) and six sub-classes in this study. At the microscopic scale, each type of pyrite is associated with a different formation process. Framboids are formed by burst nucleation in...