SHRIMP U–Pb zircon ages of tuffaceous mudrocks in the Brockman Iron Formation of the Hamersley Range,Western Australia

Tuffaceous mudrocks are common in the banded iron‐formations (BIF) of the Brockman Iron Formation. These tuffaceous mudrocks are either stilpnomelane‐rich or siliceous. Their compositions reflect bimodal volcanic activity in the vicinity of the Hamersley BIF depositional site. They also contain complex zircon populations that record resedimentation, syndepositional volcanism and post‐depositional isotopic disturbance. The best estimates of depositional age are obtained from siliceous tuffaceous mudrocks in the Joffre Member that contain 2459 ± 3 Ma and 2454 ± 3 Ma zircon populations most likely derived from felsic volcanism coeval with BIF deposition. These dates constrain the sedimentation rates for the ～370 m‐thick Joffre Member BIF to >15 m per million years. Siliceous tuffaceous mudrocks are not present in the underlying ～120 m‐thick Dales Gorge Member and it is uncertain whether previously reported ages of ca 2479–2470 Ma for this unit reflect detrital/xenocrystic or syndepositional zircon populations in resedimented stilpnomelane‐rich tuffaceous mudrocks. The increased abundance of tuffaceous mudrocks in the Joffre Member suggests that a pulse of enhanced igneous and hydrothermal activity accompanied deposition of the bulk of the Brockman Iron Formation BIF after ca 2460 Ma. This preceded and culminated in the emplacement of the 2449 ± 3 Ma large igneous province represented by BIF and igneous rocks of the Weeli Wolli Formation and Woongarra Rhyolite.     

Devonian to Triassic Successions of the Changning-Menglian Belt, Western Yunnan, China

Phanerozoic strata are distributed in several north-south trending zones in the central part of the Changning-Menglian Belt. Four types of Devonian to Triassic stratigraphic successions can be identified: (1) elastics with limestone lenses in the mid-section, changing up-section into alternations of fine elastics and cherts; (2) elastics with chert intercalations and limestone lenses, and topped by Permian basic volcanics; (3) elastics-basic volcanics-carbonates-clastics; and (4) limestones, dolomitic limestones-dark gray thin-bedded limestones, argillaceous limestones, mudstones and siliceous mudstones. Devonian to Triassic cherts occur in different horizons and different zones from east to west. These cherts are usually transitional to their neighboring elastics. There is no continuous Devonian to Middle Triassic chert sequence in the central zone of the Changning-Menglian Belt as Liu et al. (1991,1993) reported. Volcanics and the overlying carbonates described by some workers as "seamount" sequences     

Chert occurrences in carbonate turbidites: examples from the Upper Jurassic of the Betic Mountains (southern Spain)

In Upper Jurassic carbonate turbidites of the Betic mountains (southern Spain), chert occurs in three morphologies: bedded chert, nodular chert and mottled chert. The last refers to a weak dispersed and selective silification which gives a speckled appearance to the rock. The three types of chert are formed by replacement of limestones and are associated with different calcareous facies. Turbidite packstones of Saccocoma and peloids, and turbidite lime mudstones of pelagic material contain bedded and nodular cherts. The silicification textures are mainly micro- and cryptocrystalline quartz, with local chalcedonic quartz (both length-fast and length-slow) which is more common in the packstones. Only mottled chert is produced where calcareous breccia beds are silicified. Mottled chert consists of micro- and cryptocrystalline quartz, length-slow chalcedonic quartz and mosaics or individual crystals of euhedral megaquartz. Beds and nodules are the result of early diagenetic silicification, with silica derived from the calcitization and dissolution of radiolarians and, subordinately, sponge spicules, whereas mottled chert is the consequence of later silicification in a probably Mg-rich environment. Early silicification is mainly confined to turbidite beds and only rarely occurs in the interbedded pelagic limestones. Turbidite sedimentation favours silicification because rapid burial of the transported siliceous tests prevents silica from the dissolution of tests passing into overlying sea water. A silica-rich interstitial fluid develops in the turbidite layer and this migrates to more permeable zones giving rise to bedded and nodular chert.     

Depositional processes of the Zhushadong and Mantou formations (Early to Middle Cambrian), Shandong Province,China: roles of archipelago and mixed carbonate–siliciclastic sedimentation on cycle genesis during initial flooding of the North China Platform

To understand the depositional processes and environmental changes during the initial flooding of the North China Platform, this study focuses on the Lower to Middle Cambrian Zhushadong and Mantou formations in Shandong Province, China. The succession in the Jinan and Laiwu areas comprises mixed carbonate and siliciclastic deposits composed of limestone, dolostone, stromatolite, thrombolite, purple and grey mudstone, and sandstone. A detailed sedimentary facies analysis of seven well‐exposed sections suggests that five facies associations are the result of an intercalation of carbonate and siliciclastic depositional environments, including local alluvial fans, shallowing‐upward carbonate–siliciclastic peritidal cycles, oolite dominant shoals, shoreface and lagoonal environments. These facies associations successively show a transition from an initially inundated tide‐dominated carbonate platform to a wave‐dominated shallow marine environment. In particular, the peritidal sediments were deposited during a large number of depositional cycles. These sediments consist of lime mudstone, dolomite, stromatolite and purple and grey mudstones. These shallowing‐upward cycles generally resulted from carbonate production in response to an increase of accommodation during rising sea‐level. The carbonate production was, however, interrupted by frequent siliciclastic input from the adjacent emergent archipelago. The depositional cycles thus formed under the influence of both autogenetic changes, including sediment supply from the archipelago, and allogenic control of relative sea‐level rise in the carbonate factory. A low‐relief archipelago with an active tidal regime allowed the development of tide‐dominated siliciclastic and carbonate environments on the vast platform. Siliciclastic input to these tidal environments terminated when most of the archipelago became submerged due to a rapid rise in sea‐level. This study provides insights on how a vast Cambrian carbonate platform maintained synchronous sedimentation under a tidal regime, forming distinct cycles of mixed carbonates and siliciclastics as the system kept up with rising relative sea‐level during the early stage of basin development in the North China Platform.     

广西南宁地区泥盆系硅质岩地球化学特征及沉积环境

泥盆纪时,广西南宁附近发育了一套从早泥盆世埃姆斯期到晚泥盆世弗拉斯期末的硅质岩建造,硅质岩多为薄层,灰黑到黑色,至弗拉斯阶上部变为灰黄色,水平纹理发育,常夹火山凝灰岩或与之互层。这套硅质岩SiO2含量高（一般>90％）,其他主量化学成分均很低（一般<5%）。TFe2O3和含量相对比较富集（平均含量3.32％）, Al2O3、TiO2、MgO和MnO相对贫乏（平均含量分别为0.71％、0.04％、0.10％和0.02％）。常量元素Fe/Ti、（Fe+Mn）/Ti和Al/（Al+Fe+Mn）比值的平均值分别为91.65,92.12和0.25,微量元素Ti/V和U/Th比值的平均值分别为4.57和4.09,其中U/Th比值在弗拉斯期早期达到最大。这些数据说明,硅质岩在形成时受到了明显的海底热液活动影响,而这种热液活动在弗拉斯期早期达到最强,后逐渐减弱,而热液活动的强度可能主要受盆地裂解（或张裂作用）的影响;因此,盆地拉张作用在弗拉斯期早期达到最强,这与硅质岩的空间分布是吻合的。     

Microplaty hematite ore in the Yilgarn Province of Western Australia: The geology and genesis of the Wiluna West iron ore deposits

The Wiluna West small (~ 130 Mt) high-grade bedded hematite ore deposits, consisting of anhedral hematite mesobands interbedded with porous layers of acicular hematite, show similar textural and mineralogical properties to the premium high-grade low-phosphorous direct-shipping ore from Pilbara sites such as Mt Tom Price, Mt Whaleback, etc., in the Hamersley Province and Goldsworthy, Shay Gap and Yarrie on the northern margin of the Pilbara craton. Both margins of the Pilbara Craton and the northern margin of the Yilgarn craton were subjected to sub-aerial erosion in the Paleoproterozoic era followed by marine transgressions but unlike the Hamersley Basin, the JFGB was covered by comparatively thin epeirogenic sediments and not subjected to Proterozoic deformation or burial metamorphism. The Joyner's Find greenstone belt (JFGB) in the Yilgarn region of Western Australia was exhumed by middle to late Cenozoic erosion of a cover of unmetamorphosed and relatively undeformed Paleoproterozoic epeirogenic sedimentary rocks that preserved the JFGB unaltered for nearly 2 Ga; thus providing a unique snapshot of the early Proterozoic environment.Acicular hematite, pseudomorphous after acicular iron silicate, is only found in iron ore and BIF that was exposed to subaerial deep-weathering in early Paleoproterozoic times (pre 2.2 Ga) and in the overlying unconformable Paleoproterozoic conglomerate derived from these rocks and is absent from unweathered rocks (Lascelles, 2002). High-grade ore and BIF weathered during later subaerial erosion cycles contain anhedral hematite and acicular pseudomorphous goethite. The acicular hematite was formed from goethite pseudomorphs of silicate minerals by dehydration in the vadose zone under extreme aridity during early Paleoproterozoic subaerial weathering.The principal high-grade hematite deposits at Wiluna West are interpreted as bedded ore bodies that formed from BIF by loss of chert bands during diagenesis and have been locally enriched to massive hematite by the introduction of hydrothermal specular hematite. No trace of chert bands are present in the deep saprolitic hematite and hematite–goethite ore in direct contrast to shallow supergene ore in which the trace of chert bands is clearly defined by goethite replacement, voids and detrital fill. Abundant hydrothermal microplaty hematite at Wiluna West is readily distinguished by its crystallinity.The genesis of the premium ore from the Pilbara Region has been much discussed in the literature and the discovery at Wiluna West provides a unique opportunity to compare the features that are common to both districts and to test genetic models.     

Mineralogy and geochemistry of banded iron formation and iron ores from eastern India with implications on their genesis

The geological complexities of banded iron formation (BIF) and associated iron ores of Jilling-Langalata iron ore deposits, Singhbhum-North Orissa Craton, belonging to Iron Ore Group (IOG) eastern India have been studied in detail along with the geochemical evaluation of different iron ores. The geochemical and mineralogical characterization suggests that the massive, hard laminated, soft laminated ore and blue dust had a genetic lineage from BIFs aided with certain input from hydrothermal activity. The PAAS normalized REE pattern of Jilling BIF striking positive Eu anomaly, resembling those of modern hydrothermal solutions from mid-oceanic ridge (MOR). Major part of the iron could have been added to the bottom sea water by hydrothermal solutions derived from hydrothermally active anoxic marine environments. The ubiquitous presence of intercalated tuffaceous shales indicates the volcanic signature in BIF. Mineralogical studies reveal that magnetite was the principal iron oxide mineral, whose depositional history is preserved in BHJ, where it remains in the form of martite and the platy hematite is mainly the product of martite. The different types of iron ores are intricately related with the BHJ. Removal of silica from BIF and successive precipitation of iron by hydrothermal fluids of possible meteoric origin resulted in the formation of martite-goethite ore. The hard laminated ore has been formed in the second phase of supergene processes, where the deep burial upgrades the hydrous iron oxides to hematite. The massive ore is syngenetic in origin with BHJ. Soft laminated ores and biscuity ores were formed where further precipitation of iron was partial or absent.     

Hydrothermal venting and basin evolution (Devonian,South China): Constraints from rare earth element geochemistry of chert

This paper presents rare earth element (REE) geochemistry of siliceous deposits from which hydrothermal activity and basin evolution are elucidated, in the Late Devonian, in the Yangshuo basin, South China, where siliceous deposits widely occurred as nodular chert in the deep-water limestones and bedded chert interbeded with tuffaceous chert in the early Late Devonian. Both nodular and bedded cherts are characterized by very low La abundances (avg. 2.07 and 2.49 ppm, respectively), intermediate negative Ce anomalies (Ce/Ce*: avg. 0. 69 and 0.61), slight to intermediate positive Eu anomalies (Eu/Eu*: avg. 1.33 and 1.57), and low to intermediate shale-normalized La_n/Yb_n values (avg. 0.86 and 0.52) and intermediate La_n/Ce_n values (avg. 1.61 and 1.72). These suggest both nodular and bedded cherts formed in the open marine basin of South China, rather than in the intracontinental rift basin as previously assumed, with involvement both with seawaters as indicated by intermediate negative Ce anomalies and generally LREE-depleted patterns, and hydrothermal vent fluids as indicated by convex, less LREE-depleted patterns with apparent positive Eu anomalies. In comparison with nodular and bedded chert, the tuffaceous chert has the highest La abundances (avg. 17.11 ppm), similar ranges of Ce anomalies (avg. 0.63) and La_n/Ce_n values (avg. 1.77), but lower La_n/Yb_n values (avg. 0.48) and no apparent positive Eu anomalies (avg. 0.97). This suggests that the tuffaceous fallouts were also significantly modified by the hydrothermal fluid and seawater. Rapid spatial variations of Eu/Eu* values and degree of LREE-depletions in the studied basin are recognized, characterizing a spatially differential hydothermal activity that is not well discriminated by major element features. Such a difference in hydrothermal activity is interpreted as having been related to the intensity and depth of syndepositional tectonic activity, reconciling the structural pattern unraveled by stratigraphic packages.     

Micro-scale tracing of Fe and Si isotope signatures in banded iron formation using femtosecond laser ablation

We have detected micrometre-scale differences in Fe and Si stable isotope ratios between coexisting minerals and between layers of banded iron formation (BIF) using an UV femtosecond laser ablation system connected to a MC-ICP-MS. In the magnetite–carbonate–chert BIF from the Archean Old Wanderer Formation in the Shurugwi Greenstone Belt (Zimbabwe), magnetite shows neither intra- nor inter-layer trends giving overall uniform δ⁵⁶Fe values of 0.9‰, but exhibits intra-crystal zonation. Bulk iron carbonates are also relatively uniform at near-zero values, however, their individual δ⁵⁶Fe value is highly composition-dependent: both siderite and ankerite and mixtures between both are present, and δ⁵⁶Fe end member values are 0.4‰ for siderite and −0.7‰ for ankerite. The data suggest either an early diagenetic origin of magnetite and iron carbonates by the reaction of organic matter with ferric oxyhydroxides catalysed by Fe(III)-reducing bacteria; or more likely an abiotic reaction of organic carbon and Fe(III) during low-grade metamorphism. Si isotope composition of the Old Wanderer BIF also shows significant variations with δ³⁰Si values that range between −1.0‰ and −2.6‰ for bulk layers. These isotope compositions suggest rapid precipitation of the silicate phases from hydrothermal-rich waters. Interestingly, Fe and Si isotope compositions of bulk layers are covariant and are interpreted as largely primary signatures. Moreover, the changes of Fe and Si isotope signatures between bulk layers directly reflect the upwelling dynamics of hydrothermal-rich water which govern the rates of Fe and Si precipitation and therefore also the development of layering. During periods of low hydrothermal activity, precipitation of only small amounts of ferric oxyhydroxide was followed by complete reduction with organic carbon during diagenesis resulting in carbonate–chert layers. During periods of intensive hydrothermal activity, precipitation rates of ferric oxyhydroxide were high, and subsequent diagenesis triggered only partial reduction, forming magnetite–carbonate–chert layers. We are confident that our micro-analytical technique is able to detect both the solute flux history into the sedimentary BIF precursor, and the BIF’s diagenetic history from the comparison between coexisting minerals and their predicted fractionation factors.     

北大巴山志留系滔河口组火山碎屑岩相序、组构特征及古火山作用环境分析

志留系滔河口组是一套发育于北大巴山地区的火山岩-火山碎屑岩-沉积岩组合。在1:10000地质填图和大比例地质剖面实测基础上,通过详细的火山碎屑岩相序和组构分析,本文在滔河口组火山-地层中共识别和划分出22个岩相,5个相组合类型。区域岩相测量与对比揭示,滔河口组火山-沉积宏观序列自下而上由玄武岩相(一般下部为块状粗粒/细粒玄武岩相、上部为枕状玄武岩相)、凝灰角砾岩相、再沉积富辉石火山碎屑砾岩相、无结构或叠瓦状凝灰质粗砾岩相、凝灰质砂岩相、生物灰岩相或泥岩相构成。岩相组合横向变化显示滔河口组古火山活动西强东弱,火山活动类型为斯托柏林型(Strombolian-type eruption)喷发。相对地,研究区西部火山-沉积序列发育较为完整。滔河口组的地层序列与岩石组合与板内火山活动产物相似,本文认为北大巴山地区志留系滔河口组火山岩-火山碎屑岩-沉积岩组合形成于洋岛或海山构造环境,是板内拉伸作用的产物。     

广西来宾铁桥剖面中上二叠统沉积微相

对广西来宾铁桥剖面中二叠统茅口组和上二叠统吴家坪组进行了详细的沉积相研究,共识别出4个沉积相和10个微相,分别为:盆地相（含层状硅质岩微相、含透镜状灰岩的层状硅质岩微相）、下斜坡相（含与灰岩互层的层状硅质岩微相、夹层状硅质岩的灰岩微相、浊流沉积的灰岩微相）、上斜坡相（含夹硅质条带或薄层的灰岩微相、夹硅质团块或条带灰岩微相、灰岩微相、碎屑流等重力流沉积的灰岩微相）和台地边缘相（钙质海绵礁灰岩微相）。野外观测表明,茅口组和吴家坪组各为一个向上变浅的沉积旋回,但两个旋回的演化具有明显的差异,茅口组整体上是由盆地相向斜坡相演化的过程,以发育浊流、碎屑流等重力流沉积为特征,而吴家坪组是由盆地相到斜坡相至台地边缘相,再到斜坡相的演化过程,沉积微相变化频繁。该剖面的沉积微相交替记录了海平面变化过程,表现为茅口期持续下降,吴家坪早期快速上升,中期逐步下降,晚期又升高的特征。     

湘南宁远一带中、上泥盆统碳酸盐岩复理石建造的发现

我们于1979年至1980年底,在湘南宁远、江永、江华、道县、兰山一带进行了野外调查工作,发现本区中、上泥盆统碳酸盐岩具有明显的复理石建造特征,值得提供大家参考。     

Facies and facies association of the siliciclastic Brak River and carbonate Gemsbok formations in the Lower Ugab River valley,Namibia, W. Africa

The Neoproterozoic Zerrissene Turbidite Complex of central-western Namibia comprises five turbiditic units. From the base to the top they are the Zebrapüts Formation (greywacke and pelite), Brandberg West Formation (marble and pelite), Brak River Formation (greywacke and pelite with dropstones), Gemsbok River Formation (marble and pelite) and Amis River Formation (greywacke and pelites with rare carbonates and quartz-wacke).In the Lower Ugab River valley, five siliciclastic facies were recognised in the Brak River Formation. These are massive and laminated sandstones, classical turbidites (thick- and thin-bedded), mudrock, rare conglomerate and breccia. For the carbonate Gemsbok River Formation four facies were identified including massive non-graded and graded calcarenite, fine grained evenly bedded blue marble and calcareous mudrock. Most of these facies are also present in the other siliciclastic units of the Zerrissene Turbidite Complex as observed in other areas.The vertical facies association of the siliciclastic Brak River Formation is interpreted as representing sheet sand lobe to lobe-fringe palaeoenvironment with the abandonment of siliciclastic deposition at the top of the succession. The vertical facies association of the carbonate Gemsbok Formation is interpreted as the slope apron succession overlain by periplatform facies, suggesting a carbonate slope sedimentation of a prograding depositional shelf margin.If the siliciclastic–carbonate paired succession would represent a lowstand relative sea-level and highstand relative sea-level, respectively, the entire turbidite succession of the Zerrissene Turbidite Complex can be interpreted as three depositional sequences including two paired siliciclastic–carbonate units (Zebrapüts-Brandberg West formations; Brak River–Gemsbok formations) and an incomplete succession without carbonate at the top (Amis River Formation).     

Sedimentology of cherts in the Early Proterozoic Wishart Formation, Quebec-Newfoundland, Canada

The siliciclastic Wishart Formation of the Early Proterozoic Labrador trough is a high-energy shelf deposit. Wishart sandstones contain both interstitial chert with textures of void-filling cement and thin chert intercalations contaminated with siliciclastic mud. Although volumetrically minor, these cherts occur in several thin, areally extensive stratigraphic intervals. The Wishart contains intraclasts of both the chert-cemented sandstone and the impure chert layers (as well as several other types of chert sand and gravel). This suggests the cherts formed penecontemporaneously, which is consistent with the absence of any signs of replacement in all but one of the chert types and the clear-cut distinctions between chert types, even where they are side by side in a single thin section. The origin which appears to be most compatible with available evidence is that the cherts represent silica precipitated from thermal waters that rose through the sediments of the Wishart shelf and discharged into suprajacent seawater. A biogenic origin is unlikely in view of the lack of appropriate organisms during the Early Proterozoic and the rapidity with which the cements formed. A volcanogenic origin is unlikely because volcaniclastic textures are plentiful in associated formations but absent from the Wishart. Precipitation induced by evaporative concentration is unlikely in view of the widespread evidence of tidal currents and the lack of evidence of desiccation in the Wishart. Finally, the cherts are not restricted to the lowest-energy facies, and therefore they presumably did not accumulate as a background sediment. Deposition of silica above the sediment/water interface was probably made possible by ambient concentrations of silica that were significantly higher than those of Phanerozoic seawater. Cherts with similar textures occur in other Early Proterozoic sediments, most notably arenitic or granular iron-formations.     

Facies analysis of the Semanggol Formation,South Kedah,Malaysia: A possible Permian–Triassic boundary section

Although the Permian–Triassic Semanggol Formation is widely distributed in northwestern Peninsula Malaysia and is made of various lithofacies, its sedimentology and possible relation with the Permian–Triassic boundary (PTB) were not considered before. In this study, detailed facies analysis was conducted for two sections of the Semanggol Formation at the Bukit Kukus and Baling areas, South Kedah to clarify its sedimentology and relation to the PTB. Four facies from the Permian part of the Semanggol Formation that were identified at the Bukit Kukus section include laminated black mudstone, interbedded mudstone and sandstone, volcanogenic sediments, and bedded chert. In Baling area, the Triassic part of the formation is classified into three members. The lower member comprises of claystone and bedded chert facies, while the middle member is composed of sandstone and claystone interbeds (rhythmite). On the other hand, the upper member is grouped into two main units. The lower unit is mainly claystone and includes two facies: the varve-like laminated silt and clay and massive black claystone. The upper unit is composed of various sandstone lithofacies ranging from hummocky cross stratified (HCS) sandstone to thinly laminated sandstone to burrowed sandstone facies. The HCS sandstones occur as two units of fine-grained poorly sorted sandstone with clay lenses as flaser structure and are separated by a hard iron crust. They also show coarse grains of lag deposits at their bases. The laminated black mudstone at the lowermost part of the Semanggol Formation represents a reducing and quite conditions, which is most probably below the fairweather wave base in offshore environment that changed upwards into a fining upward sequence of tide environment. Abundance of chert beds in the volcanogenic sediments suggests the deposition of tuffs and volcanic ashes in deep marine setting which continues to form the Permian pelagic bedded chert and claystone. The bedded chert in the lower member of the Triassic section suggests its formation in deep marine conditions. The rhythmic sandstone and claystone interbeds of the middle member are suggestive for its formation as a distal fan of a turbidite sequence. Lithology and primary sedimentary structure of the upper member suggest its deposition in environments range from deep marine represented by the varve-like laminated silt and clay to subtidal environment corresponds to the massive black claystone to coastal environment represented by the hummocky sandstone units and reaches the maximum regression at the hiatus surface. Another cycle of transgression can be indicated from the second hummocky unit with transgressive lag deposits that develops to relatively deeper conditions as indicated from the formation of relatively thick laminated sandstone and bioturbated massive sandstone facies that represent tidal and subtidal environment, respectively. Late Permian lithological variation from the radiolarian chert into early Triassic claystone probably resulted from a decrease in productivity of radiolarians and might represent a PTB in the Semanggol Formation. Volcanogenic sediments in the studied section can be used as an evidence for volcanic activities at the end of the Permian, which is probably connected to the nearby volcanic ash layers in the eastern China, the ultimate cause of the PTB in this area. Black mudstone in the Permian part of the studied section may be interrelated to the Latest Permian Anoxia that started to build in the deep ocean well before the event on shallow shelves.     

The lower Devonian Kowmung volcaniclastics: A deep‐water succession of mass‐flow origin,northeastern Lachlan Fold Belt,N.S.W.

The Lower to ?Middle Devonian Kowmung Volcaniclastics form the upper part of a succession of Upper Siluran to mid‐Devonian flyschoid rocks in the Yerranderie area of N.S.W., and contain two major facies associations. (1) A mudstone facies association represents the ambient, background sedimentation, comprising predominantly buff mudstone that is host to an assemblage of coarser‐grained sediments, including graded‐bedded to massive siltstone, sandstone, conglomerate, allodapic limestone, and large allochthonous limestone blocks and associated limestone breccia. Bouma sequences are common, sole structures occur and maximum bed thickness is about 3 m. (2) A volcaniclastic facies association intrudes and interrupts the accumulation of the ambient mudstone facies association, and contains massive to partly graded, quartzofeldspathic siltstone, sandstone, breccia and conglomerate. Sedimentation units in the volcaniclastic facies association are up to 120 m thick. The two facies associations interfinger. Stratigraphically, the base of the Kowmung Volcaniclastics is taken as the first sedimentation unit of the volcaniclastic facies association. The mudstone facies association below this level is part of the Siluro‐Devonian Taralga Group.

Both facies associations were deposited in relatively deep‐water. The dominant transport process in both associations was mass‐flow, involving granular mass‐flows (turbidity currents, grain flows), debris flows and avalanches. Massive mudstone is hemipelagic in origin. The volcaniclastic facies association probably represents a submarine volcanic apron around the emergent, volcanic Bindook Complex. Grossly, the succession coarsens upwards, and there is evidence of several sources of sediment, rather than a single point at the head of a submarine fan.

Provenance is diverse. In the mudstone facies association, framework grains in sandstone are microlitic volcanic‐rock fragments with a mafic to intermediate volcanic source. Clasts in conglomerate and breccia are consistent with derivation from the regionally extensive, quartzose Ordovician flyschoid successions. Clasts of ?penecontemporaneous limestone also occur. The volcaniclastic facies association was probably derived largely from the nearby, coeval Bindook Complex, which consists of silicic ash‐flow and ash‐fall tuff, lava, associated sediment and granitoids. Detritus was either derived directly from volcanic eruptions or was worked in fringing littoral and fluvial environments prior to redeposition by mass‐flow. Quartzite boulders mixed with volcanic clasts in the conglomerate suggest that Ordovician quartzarenite was also exposed around the volcanic complex. Tentative provenance correlations have been made between the different rock units in the Kowmung Volcaniclastics and their possible sources in the northern part of the Bindook Complex.     

Middle Archean ocean ridge hydrothermal metamorphism and alteration recorded in the Cleaverville area, Pilbara Craton, Western Australia

A hydrothermally metamorphosed greenstone complex, capped by bedded cherts and banded iron formations (BIFs), is exposed in the Cleaverville area, Pilbara Craton, Western Australia. It has been interpreted as an accretionary complex characterized by both a duplex structure and an oceanic plate stratigraphy, and is shown to represent a 3.2 Ga upper oceanic crust. Three metamorphic zones are identified in the basaltic greenstones. The metamorphic grade increases from sub-greenschist facies (zones A and B) to greenschist facies (zone C) under low-pressure conditions. The boundaries between three mineral zones are subparallel to the bedding plane of overlying chert/BIF, and metamorphic temperature increases stratigraphically downward. The zones correspond to the thermal structure of ocean-floor metamorphism, at a mid-ocean ridge.
The uppermost greenstone in the study area is more pervasively altered and carbonatized than the modern upper oceanic crust. This indicates the enrichment of CO₂ in the metamorphic fluid by which widespread formation of carbonate occurred, compared with a narrow stability region of Ca-Al silicates. It is, therefore, suggested that the Archean hydrothermal alteration played a more important role in fixation of CO₂ than present-day ocean-ridge hydrothermal alteration, as an interaction between sea water and oceanic crust.     

The role of wave reworking on the architecture of storm sandstone facies, Bell Island Group (Lower Ordovician), eastern Newfoundland

Stacked shallow marine cycles in the Lower Ordovician, Bell Island Group, of Bell Island, Newfoundland, show upward thickening and upward coarsening sequences which were deposited on a storm-affected shelf. In the Beach Formation each cycle has a facies sequence comprised, from base to top, of dark grey mudstones, light grey mudstones, tabular sandstones and mudstones, lenticular sandstones and mudstones, and thick bedded lenticular sandstones, reflecting a progressive increase of wave orbital velocities at the sediment surface. The mudstones and tabular sandstones reflect an environment in which the sea floor lay in the lower part of the wave orbital velocity field and in which tempestites were deposited as widespread sheets from weak combined flow currents. The lenticular sandstones in the succeeding facies are wave reworked sands, commonly lying in erosional hollows and having erosional tops and internal hummocky cross-stratification. Planar lamination is relatively uncommon and sole marks are mainly absent. In this facies oscillatory currents were dominant and accumulated sand in patches generally 10–30 m in diameter. The facies formed on the inner shelf where the oscillatory currents generated by storm waves had powerful erosional effects and also determined the depositional bedforms. Mud partings and second-order set boundaries within sandstone beds are believed to separate the products of individual storms so that many lenticular sandstone beds represent the amalgamation of several event beds. This interpretation has important implications for attempts to estimate event frequency by counting sandstone beds within a sequence and for estimates of sand budgets during storm events. The thick bedded lenticular facies appears to have been formed by erosion of the mud beds between the lenticular sands, leading to nearly complete amalgamation of several lenticular sand bodies except for residual mud partings. In the overlying Redmans Formation the process of amalgamation progressed even further so that nearly all the mud partings were removed, resulting in the formation of thick bedded tabular sandstones. Sequence stratigraphic analysis of the cyclical sequence suggests that the cycles were eustatically controlled. The rising limb of the sea level curve produced only the dark grey mudstone part of the cycle while the remainder of the cycle was deposited on the falling limb. There is a gradational but rapid facies transition from the tabular to the lenticular sandstone facies which is interpreted as occurring at the inflexion point on the falling limb. The thick bedded facies of the Beach Formation and the thick bedded tabular facies of the Redmans Formation represent periods of maximum sea level fall. The stacked cycles in the Beach Formation are interpreted as an aggradational, high frequency sequence or parasequence set bounded at the top by a sequence boundary and succeeded by the three aggradational parasequences of the Redmans Formation. The recognition of storm facies with sandstone beds of very different bed length has important implications for the reservoir modelling of such facies.     

鄂西古生代硅质岩的地球化学特征及沉积环境

鄂西地区的上奥陶统五峰组、下志留统龙马溪组下部、下二叠统孤峰组和上二叠统大隆组中发育有薄层硅质岩。二叠系栖霞组、茅口组和吴家坪组灰岩中发育有结核状或似层状燧石。Fe Al Mn三角图 ,Cu、Ni、Co、Cr、Zr的关系 ,U Th判别图 ,Ba、As、Sb元素和REE配分模式等地球化学指标表明 :五峰组和龙马溪组层状硅质岩属于正常海水中生物化学和化学沉积 ;孤峰组和大隆组层状硅质岩、茅口组灰岩中燧石结核不属于典型的热水沉积相 ,但受热水作用的影响 ,而孤峰组硅质岩受热水作用明显。鄂西五峰组和龙马溪组硅质岩的沉积环境是四周被古陆或台地环绕的半封闭深水相滞流盆地。鄂西孤峰组和大隆组硅质岩的沉积环境是由裂陷作用形成的碳酸盐台地内部的盆地(或台沟 )滞流还原环境。CaO/(Fe +CaO)值和 (MgO/Al2 O3 )× 10 0值表明 :五峰组、龙马溪组和大隆组硅质岩沉积环境海水略有淡化。栖霞组、茅口组和吴家坪组含结核状或似层状燧石的生物灰岩 ,形成于陆棚上快速海侵和上升洋流形成的还原环境。