Changes of δ<Superscript>18</Superscript>O and δD along the Dousitu River,Inner Mongolia,China, and their evidence of river water evaporation

On the basis of the hydrogeology of the Dousitu River drainage basin, the changes of water flow rate, δ¹⁸O and δD along the Dousitu River are discussed according to measured and analytical results. Changes of flow rate along the Dousitu River agree well with groundwater level contours and the recharge and discharge of groundwater to the river. When compared with other types of water in the area, it is obvious that the ¹⁸O and D of river waters have experienced evaporation. The changes of δ¹⁸O and δD along the Dousitu River are mainly caused by combined effects of groundwater recharge and river water evaporation. The recharge of groundwater makes δ¹⁸O and δD of the river water decrease. Evaporation makes δ¹⁸O and δD of the river water increase. The evaporation fractions of the river water are calculated using the kinetic fractionation theory. Results showed as much as 10–30% of water was evaporated in different segments of Dousitu River.     

Hydrochemical and isotopic study of groundwater in the Yinchuan plain, China

The Yinchuan plain is located in the arid climate zone of NW China. The western margin of the plain is the Helan mountain connecting a series of normal slip faults. The eastern margin of the plain connects with the Yellow River and adjacents with the Ordos platform. The south of the plain is bordered by the EN fault of the Niushou mountain. The bottom of the plain is the Carboniferous, Permian, or Ordovician rocks. Based on the analysis of groundwater hydrochemical and isotopic indicators, this study aims to identify the groundwater recharge and discharge in the Yinchuan plain, China. The hydrochemical types of the groundwater are HCO₃–SO₄ in the west, HCO₃–Cl in the middle, and Cl–SO₄ in the east. The hydrochemical types are HCO₃–SO₄ in the south, HCO₃–Cl and SO₄–HCO₃ in the middle. The hydrochemical types are complex in the north, mainly SO₄–HCO₃ and Cl–SO₄. Deuterium, ¹⁸O, and tritium values of groundwater indicate that groundwater recharge sources include precipitation, bedrock fissure water, and irrigation return water. Groundwater discharges include evaporation, abstraction, and discharge to surface water. According to the EW isotopic profile, the groundwater flow system (GFS) in the Yinchuan plain can be divided into local flow systems (LFS) and regional flow systems (RFS). Groundwater has lower TDS and higher tritium in the southern Yellow River alluvial plain and groundwater age ranges from 6 to 25 years. The range of groundwater renewal rates is from 11 to 15 % a^?1. The depth of the water cycle is small, and groundwater circulates fast and has high renewal rates. Groundwater has higher TDS and lower tritium in the northern Yellow River alluvial plain. The range of groundwater age is from 45 to 57 years, and renewal rate is from 6 to 0.1 % a^?1. The depth of the water cycle is larger. Groundwater circulates slowly and has low renewal rates.     

Origin and recharge estimates of groundwater in the ordos plateau,People’s Republic of China

Groundwater is a valuable resource in the semiarid Ordos Plateau region where abundant mineral resources, such as coal, natural gas, and halite, are present. With resources development, groundwater demand will increase dramatically. The origin identification and recharge estimates of groundwater are significant components of sustainable groundwater development in the Ordos Plateau. Groundwater and precipitation samples were taken and the isotopic compositions δ²H, δ¹⁸O, and chloride were analyzed to identify groundwater origins and to estimate recharge rates. The δ²H and δ¹⁸O of the groundwater show that the groundwater recharge is of meteoric origin. The chloride mass balance (CMB) method was used to quantify recharge rates of groundwater in the Ordos Plateau, which varies from 2.93 to 22.11% of the effective annual rainfall. Recharge rates estimated by CMB were compared with values obtained from other methods and were found to be in good agreement. This study can be used to develop effective programs for groundwater management and development.     

Fracture flow and groundwater compartmentalization in the Rollins Sandstone, Lower Mesaverde Group, Colorado, USA

 This paper presents a site-specific conceptual model of groundwater flow in fractured damage zones associated with faulting in a package of sedimentary rocks. The model is based on the results of field and laboratory investigations. Groundwater and methane gas inflows from fault-fracture systems in the West Elk coal mine, Colorado, USA, have occurred with increasing severity. Inflows of 6, 160 and 500 L s⁻¹ discharged almost instantaneously from three separate faults encountered in mine workings about 460 m below ground level. The faults are about 600 m apart. The δ ²H and δ ¹⁸O compositions of the fault-related inflow waters and the hydrodynamic responses of each fault inflow indicate that the groundwaters discharge from hydraulically isolated systems. ¹⁴C data indicate that the groundwaters are as much as 10,500 years old. Discharge temperatures are geothermal (≈30°C), which could indicate upwelling from depth. However, calculations of geothermal gradients, analysis of solute compositions of groundwater in potential host reservoirs, geothermometer calculations, and results of packer testing indicate that the fractured groundwater reservoir is the Rollins Sandstone (120 m thick) directly beneath the coal seams. The packer test also demonstrates that the methane gas is contained in the coal seams. A geothermal gradient of 70–80°C km⁻¹, related to an underlying intrusion, is probably responsible for the slightly elevated discharge temperatures. Large discharge volumes, as great as 8.2×10⁵m³ from the 14 South East Headgate fault (14 SEHG), rapid declines in discharge rates, and vertical and horizontal permeability (matrix permeability generally <0.006 Darcy) indicate fracture flow. An in-mine pumping test demonstrates that the 14 SEHG fault has excellent hydraulic communication with fractures 50 m from the fault. Aeromagnetic data indicate that the faults are tectonically related to an igneous body that is several thousand meters below the coal seams. Exploratory drilling has confirmed a fourth fault, and two additional faults are projected, based on the aeromagnetic data. The conceptual model describes a series of parallel, hydraulically separate groundwater systems associated with fault-specific damage zones. The faults are about 600 m apart. Groundwater stored in fractured sandstone is confined above and below by clayey layers. Received March 1999 / Revised, November 1999 / Accepted, December 1999     

Hydrochemical and isotopic evidence of recharge,apparent age,and flow direction of groundwater in Mayo Tsanaga River Basin,Cameroon: bearings on contamination

Unplanned exploitation of groundwater constitutes emerging water-related threats to MayoTsanaga River Basin. Shallow groundwater from crystalline and detrital sediment aquifers, together with rain, dams, springs, and rivers were chemically and isotopically investigated to appraise its evolution, recharge source and mechanisms, flow direction, and age which were used to evaluate the groundwater susceptibility to contamination and the basin’s stage of salinization. The groundwater which is Ca–Na–HCO₃ type is a chemically evolved equivalent of surface waters and rain water with Ca–Mg–Cl–SO₄ chemistry. The monsoon rain recharged the groundwater preferentially at an average rate of 74 mm/year, while surface waters recharge upon evaporation. Altitude effect of rain and springs show a similar variation of −0.4‰ for δ¹⁸O/100 m, but the springs which were recharged at 452, 679, and 773 m asl show enrichment of δ¹⁸O through evaporation by 0.8‰ corresponding to 3% of water loss during recharge. The groundwater which shows both local and regional flow regimes gets older towards the basins` margin with coeval enrichment in F⁻ and depletion in NO₃ ⁻. Incidentally, younger groundwaters are susceptible to anthropogenic contamination and older groundwaters are sinks of lithologenic fluoride. The basins salinization is still at an early stage.     

Recharge source and hydrogeochemical evolution of shallow groundwater in a complex alluvial fan system,southwest of North China Plain

Many cities around the world are developed at alluvial fans. With economic and industrial development and increase in population, quality and quantity of groundwater are often damaged by over-exploitation in these areas. In order to realistically assess these groundwater resources and their sustainability, it is vital to understand the recharge sources and hydrogeochemical evolution of groundwater in alluvial fans. In March 2006, groundwater and surface water were sampled for major element analysis and stable isotope (oxygen-18 and deuterium) compositions in Xinxiang, which is located at a complex alluvial fan system composed of a mountainous area, Taihang Mt. alluvial fan and Yellow River alluvial fan. In the Taihang mountainous area, the groundwater was recharged by precipitation and was characterized by Ca–HCO₃ type water with depleted δ¹⁸O and δD (mean value of −8.8‰ δ¹⁸O). Along the flow path from the mountainous area to Taihang Mt. alluvial fan, the groundwater became geochemically complex (Ca–Na–Mg–HCO₃–Cl–SO₄ type), and heavier δ¹⁸O and δD were observed (around −8‰ δ¹⁸O). Before the surface water with mean δ¹⁸O of −8.7‰ recharged to groundwater, it underwent isotopic enrichment in Taihang Mt. alluvial fan. Chemical mixture and ion exchange are expected to be responsible for the chemical evolution of groundwater in Yellow River alluvial fan. Transferred water from the Yellow River is the main source of the groundwater in the Yellow River alluvial fan in the south of the study area, and stable isotopic compositions of the groundwater (mean value of −8.8‰ δ¹⁸O) were similar to those of transferred water (−8.9‰), increasing from the southern boundary of the study area to the distal end of the fan. The groundwater underwent chemical evolution from Ca–HCO₃, Na–HCO₃, to Na–SO₄. A conceptual model, integrating stiff diagrams, is used to describe the spatial variation of recharge sources, chemical evolution, and groundwater flow paths in the complex alluvial fan aquifer system.     

Isotopic constraints on the origin of groundwater in the Ordos Basin of northern China

Despite its extreme aridity, the Ordos Basin in northern China is rich in groundwater. Many artesian wells or springs with large fluxes are utilized for drinking, irrigation and industrial production. In a search for the origin of the groundwater, a detailed investigation of the stable isotopes of oxygen and hydrogen in the local precipitation, the river water, the springs, the well water, as well as the soil water extracted from six soil profiles in the Ordos Basin, was carried out. The data show that δD, δ¹⁸O and TDS values of the river water are similar to those of groundwater, while the TDS values of the soil water are about ten times greater than those of groundwater. Furthermore, the mean isotopic compositions of the local precipitation are significantly higher than those of river water and groundwater. Based on the chloride mass balance method, the estimated recharge rates range from 5.2 to 17.2 mm/year, with a mean value of 10.5 mm/year. The results show that the main source of recharge of the groundwater in the Ordos Basin is not the local precipitation, but must come from a region where the precipitation is characterized by much lower δD and δ¹⁸O values. In addition, the groundwater in the Ordos Basin contains a component of mantle-derived ³He and crust-derived ⁴He suggesting that the groundwater may partly derive from flows through basement faults beneath the Ordos Basin.     

Groundwater flow modeling of Quaternary aquifer Ras Sudr,Egypt

Recently, Ras Sudr (the delta of Wadi Sudr) area received a great amount of attention due to different development expansion activities directed towards this area. Although Quaternary aquifer is the most prospective aquifer in Ras Sudr area, it has not yet completely evaluated. The present work deals with the simulation of the Quaternary groundwater system using a three-dimensional groundwater flow model. MODFLOW code was applied for designing the model of the Ras Sudr area. This is to recognize the groundwater potential as well as exploitation plan of the most prospective aquifer in the area. The objectives were to determine the hydraulic parameters of the Quaternary aquifer, to estimate the recharge amount to the aquifer, and to determine the hydrochemistry of groundwater in the aquifer. During this work, available data has been collected and some field investigation has been carried out. Groundwater flow model has been simulated using pilot points’ method. SEAWAT has been also applied to simulate the variable-density flow and sea water intrusion from the west. It can be concluded that: (1) the direction of groundwater flow is from the east to the west, (2) the aquifer system attains a small range of log-transformed hydraulic conductivity. It ranges between 3.05 and 3.35 m/day, (3) groundwater would be exploited by about 6.4 × 10⁶ m³/year, (4) the estimated recharge accounts for 3 × 10⁶ m³/year, (5) an estimated subsurface flow from the east accounts for 2.7 × 10⁶ m³/year, (6) the increase of total dissolved solids (TDS) most likely due to dilution of salts along the movement way of groundwater from recharge area to discharge area in addition to a contribution of sea water intrusion from the west. Moreover, it is worth to note that a part of TDS increase might be through up coning from underlying more saline Miocene sediments. It is recommended that: (1) any plan for increasing groundwater abstraction is unaffordable, (2) reliable estimates of groundwater abstraction should be done and (3) automatic well control system should be made.     

Interaction between deep and shallow groundwater systems in areas affected by Quaternary tectonics (Central Italy): a geochemical and isotope approach

Hydro- and isotope geochemistry are used to refine groundwater conceptual models in two areas of central Italy (Acque Albule Basin and Velino River Valley) affected by extensional Quaternary tectonics, where deep and shallow groundwater flow systems are interacting. The role of geology, of recent deposits filling the plains and of main tectonic features controlling groundwater flowpaths and deep-seated fluids emergences are investigated and discussed. Environmental isotopes (²H and ¹⁸O) confirm recharge in the surrounding carbonate aquifers, and meteoric origin of both shallow and deep groundwater. Major ion chemistry indicates a mixing between shallow Ca-HCO₃ groundwater from carbonate aquifers and deep Ca-HCO₃-SO₄ groundwater, characterised by higher salinity and temperature and high concentration in sulphates. Isotopic composition of dissolved sulphates (δ ³⁴S and δ ¹⁸O) and dissolved inorganic carbon (δ ¹³C), henceforth indicated as DIC, are used to verify the presence of different sources of groundwater, and to validate the mixing model suggested by the major ion analyses. Sulphate isotope composition suggests a marine origin for the groundwater characterised by elevated sulphate concentration, whose source is present in the deep buried sequences. Carbon isotope composition confirms the role of a DIC source associated to CO₂ degassing of a deep reservoir. Groundwater conceptual models are improved underlining the importance of Plio-Pleistocene sequences filling the tectonic depression. In the Acque Albule area, the travertine plateau represents a mixing stratified aquifer, where deep groundwater contribution is spread into the shallow aquifer. The alluvial–clastic–lacustrine leaky aquifer of Velino Valley enables a complete mixing of shallow and deep groundwater allowing spot-located discharge of deep groundwater along tectonic patterns and facilitating sulphate reduction in the lacustrine sediments, explaining locally the presence of H₂S.     

Sulphate Sources in the Sava and Ljubljanica Rivers, Slovenia, Inferred from Sulphur and Oxygen Isotope Compositions

Measurements were made of sulphur and oxygen isotope ratios of sulphate in some Slovenian rivers, lakes and tap waters. δ³⁴S ranged from −0.2 to + 13.3‰, δ¹⁸O ranged from +4.9 to + 13.6‰, and the sulphate content varied from 0.8 to 41.4 mg/L. Rivers flowing from the Julian Alps contain a very low amount of sulphate that is leached from a thin horizon of soil by rain. As confirmed by their low δ¹⁸O values, these sulphates do not enter the rivers directly in rain, but arise from biochemical cycling in the soil. The low δ³⁴S of this sulphate indicates that it originates from the oxidation of sedimentary sulphides. The evolution of sulphates along the river course was investigated for the Sava and Ljubljanica rivers. The variations observed in sulphate from the waters studied result from variations in the contribution of sulphates of different origin. Downstream the Sava River sulphate is depleted in the heavy isotopes of both sulphur and oxygen, with δ-values gradually tending toward the δ-values of groundwater sulphates in the watershed. In contrast, the δ-values of sulphate in the Ljubljanica River are almost constant and similar to those of sulphate in local groundwater. Introduction of water from Italian and Slovenian mines was recorded in the Soča River, where the lowest δ³⁴S value of sulphate sulphur (−0.2‰) was observed. In addition, the influence of sulphate from the oxidation of sedimentary sulphides was recorded in the Sotla River. No evidence was found for introduction of sulphate from factories.     

Groundwater recharge and flow in the Lower Cretaceous Nubian Sandstone aquifer in the Sinai Peninsula, using isotopic techniques and hydrochemistry

The present work was conducted in the Sinai Peninsula (1) to identify the recharge and flow characteristics and to evaluate the continuity of the Lower Cretaceous Nubian Sandstone aquifer; and (2) to provide information for the aquifer's rational appraisal. Isotopic and hydrochemical compositions combined with the geological and hydrogeological settings were used for this purpose. A considerable depletion in isotopic content (oxygen-18 and deuterium) and low d-excess values exist in the studied groundwater, reflecting the contribution of old meteoric water that recharged the aquifer in pluvial times. Modern recharge also occurs from precipitation that falls on the aquifer outcrops. The wide scatter of the data points around the two meteoric lines, the global meteoric water line (GMWL) and Mediterranean meteoric water line (MMWL), in the δ¹⁸O–δD diagram indicates considerable variation in recharge conditions (amount, altitude, temperature, air masses, distances from catchment, overland flow, etc.). The isotopic composition in the El-Bruk area is minimum (¹⁸O=–9.53‰), very close to the average value of the Western Desert Nubian Sandstone (¹⁸O=–10‰), where the local structural and lithologic conditions retard groundwater flow and the main bulk of water becomes noncyclic. The continuity of the aquifer in northern and central Sinai is evidenced by the isotopic similarity between samples taken from above and below the central Sinai Ragabet El-Naam fault, the distribution of potentiometric head, and hydrogeological cross sections. The combination of isotopic composition in terms of ¹⁸O and chemical composition in terms of TDS and salt contents is the basis for separating the studied groundwater into groups that reflect the recharge sources and isotopic and chemical modifications during flow. Electronic Publication     

Temporal and spatial differences in salinity and water chemistry in SW Florida estuaries: Effects of human-impacted watersheds

Three estuaries near Naples, Florida with variably modified watersheds have been investigated to understand the chemical consequences of altering drainage patterns. Blackwater River (near natural drainage, control site), Henderson Creek (moderately modified watershed), and Faka-Union Canal (severe channelization) were sampled for temperature, salinity, δ¹⁸O, δ¹³C of dissolved inorganic carbon (DIC), molality of CO₂ (ΣCO₂), and Mg:Ca and Sr:Ca ratios between freshwater and marine water end members over a 17-mo period. Carbon isotope composition followed similar seasonal patterns as salinity. Freshwater and seawater end members are more negative than the global average, likely reflecting equilibration with local carbon sources derived from mangrove leaf litter and groundwater. δ¹³C responds to differences in primary productivity between estuaries. Henderson Creek has higher primary productivity than Blackwater River (probable due to higher sewage input and agricultural runoff) and has more positive δ¹³C and lower ΣCO₂. δ¹⁸O is affected by seasonal input of freshwater from atmospheric precipitation, evaporation, and groundwater. Late summer and fall rains lower the δ¹⁸O of estuarine water, whereas evaporative conditions in the dry season elevate δ¹⁸O to values that can be more positive upstream than those from the Gulf of Mexico (estuarine inversion). Evaporation produces water in the Gulf of Mexico that is >1‰ more positive than the global sea surface average most of the year. The very negative δ¹⁸O values in Blackwater River and Henderson Creek likely reflect atmospheric and groundwater contribution. Mg:Ca and Sr:Ca ratios of Gulf water from all three estuaries are similar to global averages at low latitudes. Freshwater end members among estuaries are different in that Blackwater River has higher ratios, suggesting a groundwater contribution. Dolomitic rocks in the subsurface likely provide a source of Mg ions.     

Groundwater flow system in Bengal Delta,Bangladesh revealed by environmental isotopes

A total number of 328 groundwater samples are analysed to evaluate the groundwater flow systems in Bengal Delta aquifers, Bangladesh using environmental isotope (²H, ¹⁸O, ¹³C, ³H, and ¹⁴C) techniques. A well-defined Local Meteoric Water Line (LMWL) δ²H = 7.7 δ¹⁸O + 10.7 ‰ is constructed applying linear correlation analyses to the monthly weighted rainfall isotopic compositions (δ¹⁸O and δ²H). The δ¹⁸O and δ²H concentrations of all groundwater samples in the study area are plotted more or less over the LMWL, which provides compelling evidence that all groundwaters are derived from rainfall and floodwater with a minor localized evaporation effects for the shallow groundwaters. Tritium concentration is observed in 40 samples out of 41 with values varying between 0.3 and 5.0 TU, which represents an evidence of young water recharge to the shallow and intermediate aquifers. A decreasing trend of ¹⁴C activity is associated with the heavier δ¹³C values, which indicates the presence of geochemical reactions affecting the ¹⁴C concentration along the groundwater flow system. Both vertical and lateral decrease of ¹⁴C activity toward down gradient show the presence of regional groundwater flow commencing from the unconfined aquifers, which discharges along the coastal regions. Finally, shallow, intermediate, and deep groundwater flow dynamics has revealed in the Bengal Delta aquifers, Bangladesh.     

Spatio-temporal variations of δ<Superscript>2</Superscript>H and δ<Superscript>18</Superscript>O in precipitation and shallow groundwater in the Hilly Loess Region of the Loess Plateau,China

Groundwater is of utmost significance to socio-economic development and ecological recovery for the Loess Plateau. However, studies regarding the mechanism governing groundwater recharge over this area appear to be inadequate. This study is to examine the spatio-temporal variations of δ²H and δ¹⁸O in precipitation and shallow groundwater. On the basis of this, the mechanisms governing shallow groundwater recharge were explored. Precipitation and groundwater were sampled monthly from May to October during the period 2004–2006 at 13 sites in the Chabagou Catchment (187 km²). In the Caopingxigou Experimental Watershed (0.1 km²), meteorological variables were observed and rainfall larger than 5 mm was sampled immediately after each rain event. Across the area, 90% of the precipitation occurred from May to September primarily in the form of heavy rains or rainstorms with great spatial variability. There were about 30 localized rains in each year. It was indicated that there existed notable seasonality and pronounced spatial variability in precipitation isotopic compositions. Contributing factors and indications of isotopic compositions, as well as their climatic indications such as monsoon intensities and mixing processes of water vapor, were investigated. The δ²H–δ¹⁸O relation of groundwater was found to be δ²H = 3.22 × δ¹⁸O − 38.1, deviating from the local meteoric water line δ²H = 7.57 × δ¹⁸O + 3.9. The range of δ values in groundwater is shrunken to be 15–21% of that in individual precipitations, and groundwater in the middle reaches shows a wider range of δ values. Isotopic results showed that groundwater originates from precipitation with hydrogen and oxygen isotopic compositions being −69 and −9.7‰, respectively, and most groundwater experiences serious evaporation and adequate mixing with old water during infiltration or percolation in the aerated zone. It was also founded that obvious fluctuations of isotopic compositions in groundwater mainly appear in the middle reaches especially at sites that are close to valleys, suggesting varying sources of groundwater from precipitation, precipitation runoff, isotopically enriched surface water and/or lateral recharge of adjacent groundwater.     

Groundwater replenishment analysis by using natural isotopes in Ejina Basin, Northwestern China

The Ejina Basin underlying complex aquifers is located in the lower reaches of the Heihe River with an arid climate and 40 mm mean annual precipitation. As the balance of the natural ecosystem in the Ejina Basin is fragile and easily upset, it is very important to estimate and rationally use the limited groundwater resources to maintain the balance. Water samples were collected from the Heihe River and wells for chemical and isotopic measurements across the basin. The Piper diagram gives two main types of hydrochemical features. Against the background of the regional geology, combining isotope ¹⁸O, tritium, and chemical analysis with groundwater flows indicated by a shallow groundwater level contour map, different kinds of groundwater sources and ways to replenish groundwater were discovered. North of the study area are artesian wells that are replenished by the mountainous area at the boundary between China and Mongolia. Replenishment for most of the groundwater resources of the Gurinai oasis comes from the Heihe River seepage flow of the highly conductive paleochannel, not from the Badain Jaran Desert as indicated by TDS and tritium analysis. The different groundwater ages which are younger than 35 years were approximately estimated by radioactive isotope tritium (T). By such efforts, groundwater resources can be effectively evaluated with the engineering impact of the Heihe River Project.     

Hydrogeology of a coal-seam gas exploration area, southeastern British Columbia, Canada: Part 2. Modeling potential hydrogeological impacts associated with depressurizing

A three-dimensional, finite-element flow model was used to assess the hydrogeological effects of depressurizing coalbeds lying in the Weary Creek exploration block, Elk River valley, southeastern British Columbia, Canada. The simulation results permit, at an early stage, assessment of the environmental and economic implications of how the flow system may respond to depressurization. Estimated reservoir conditions for the coal-seam gas targets lying within the Upper Jurassic–Lower Cretaceous Mist Mountain Formation indicate that the coalbeds must be depressurized by up to 350 m to attain the critical gas desorption pressure. The simulations suggest that depressurizing has little effect on groundwater flux to the Elk River. Simulated water production for three depressurizing wells operating under steady-state, single-phase flow for initial reservoir conditions of 13 and 16.5 cm³/g is 645 m³/d (4,057 barrels/d) and 355 m³/d (2,233 barrels/d), respectively. Groundwaters collected from monitoring wells have relatively low salinity, ranging from about 250–1,300 mg/L. The groundwater is supersaturated with respect to Ca–Mg–Fe carbonates (calcite, dolomite, and siderite) and Al-bearing silicates, including kaolinite and illite. Dissolved trace-metal concentrations are low; only Fe, Cd, Cr, and Zn exceed Canadian water-quality guidelines for aquatic life. Groundwaters were devoid of the more soluble monocyclic aromatic organic compounds, including benzene, toluene, ethylbenzene, and polycyclic aromatic compounds, including naphthalene. Electronic Publication     

Determining Spatial and Temporal Inputs of Freshwater,Including Submarine Groundwater Discharge,to a Subtropical Estuary Using Geochemical Tracers,Biscayne Bay,South Florida

Geochemical mixing models were used to decipher the dominant source of freshwater (rainfall, canal discharge, or groundwater discharge) to Biscayne Bay, an estuary in south Florida. Discrete samples of precipitation, canal water, groundwater, and bay surface water were collected monthly for 2 years and analyzed for salinity, stable isotopes of oxygen and hydrogen, and Sr²⁺/Ca²⁺ concentrations. These geochemical tracers were used in three separate mixing models and then combined to trace the magnitude and timing of the freshwater inputs to the estuary. Fresh groundwater had an isotopic signature (δ ¹⁸O = −2.66‰, δD −7.60‰) similar to rainfall (δ ¹⁸O = −2.86‰, δD = −4.78‰). Canal water had a heavy isotopic signature (δ ¹⁸O = −0.46‰, δD = −2.48‰) due to evaporation. This made it possible to use stable isotopes of oxygen and hydrogen to separate canal water from precipitation and groundwater as a source of freshwater into the bay. A second model using Sr²⁺/Ca²⁺ ratios was developed to discern fresh groundwater inputs from precipitation inputs. Groundwater had a Sr²⁺/Ca²⁺ ratio of 0.07, while precipitation had a dissimilar ratio of 0.89. When combined, these models showed a freshwater input ratio of canal/precipitation/groundwater of 37%:53%:10% in the wet season and 40%:55%:5% in the dry season with an error of ±25%. For a bay-wide water budget that includes saltwater and freshwater mixing, fresh groundwater accounts for 1–2% of the total fresh and saline water input.     

Determination of groundwater flow regimes in underground storage caverns using tritium and helium isotopes

Understanding groundwater flow and chemical transport is crucial for operating underground storage caverns. Groundwater flow in the study area is mainly affected by cavern operating conditions, and groundwater chemistry in the study area is modified by disinfection activities for removing possible biological clogging and by mixing with cement pore water. It is significant to discern these two effects because wells affected by the disinfection activities, in particular, may have hydrological connections with water curtains in which disinfectant water was injected to remove the biological clogging. Concentration of tritium (³H) and helium isotopes (⁴He), and groundwater chemical compositions were used to confirm that there are hydrological connectivities between the water curtain and the well. Groundwater along the fault areas contains low total dissolved solid (TDS) and high ³H, suggesting that the faults may act as fast flow conduits, which is not inconsistent with previous studies. Certain diagnostic conditions (high concentrations of Na⁺, Cl⁻ and TDS and high pH) are presumed by the effect of disinfection activity, indicating that there are hydrological connections between the water curtain and the wells. This hypothesis is valid in YK2U and YK2L, but is not in YK12L, implying a closed system or an immobile water to explain the isotopic results.     

Response of groundwater chemistry to water deliveries in the lower reaches of Tarim River,Northwest China

In this paper, we analysed the monitored data from nine groundwater-monitoring transects in the lower reaches of Tarim River during the five times of stream water deliveries to the river transect where the stream flow ceased. The results showed that the groundwater depth in the lower reaches of Tarim River rose from −9.30 m before the conveyances to −8.17 and −6.50 m after the first and second conveyances, −5.81 and −6.00 m after the third and fourth the conveyance, and −4.73 m after the fifth. The horizontal extent of groundwater recharge was gradually enlarged along both sides of the channel of conveyance, i.e., from 250 m in width after the first conveyance to 1,050 m away from the channel after the fourth delivery. With the rising groundwater level, the concentrations of major anions Cl⁻, SO₄²⁻ and cations Ca²⁺, Mg²⁺, Na⁺, as well as total dissolved solids (TDS) in groundwater underwent a significant change. The spatial variations in groundwater chemistry indicated that the groundwater chemistry at the transect near Daxihaizi Reservoir changed earlier than that farther from it. In the same transect, the chemical variations were earlier in the monitoring well close to watercourse than that farther away from the stream. In general, the concentration of the major ions and TDS at each monitoring well increased remarkably when the water delivery started, and decreased with the continued water delivery, and then increased once again at the end of the study period. Hence, the whole study period may be divided into three stages: the initial stage, the intermediate stage and the later stage. According to the three stages of groundwater chemistry reaction to water delivery and the relationships between groundwater chemical properties and groundwater depths, we educe that under the situation of water delivery, the optimum groundwater depth in the lower reaches of the Tarim River should be −5 m.     

Ion chemistry of groundwater and the possible controls within Lhasa River Basin,SW Tibetan Plateau

In order to study the major ion chemistry and controls of groundwater, 65 groundwater samples were collected and their major ions measured from wells within Lhasa River Basin. Groundwater has the characteristics of slightly alkaline and moderate total dissolved solid (TDS). TDS concentration ranged from 122.0 to 489.9 mg/L with a median value of 271.2 mg/L. Almost all the groundwater samples suited for drinking and irrigation. The major cations of groundwater are Ca²⁺ and Mg²⁺, accounting for 59.6 and 31.3% of the cations, respectively. Meanwhile, HCO₃^? and SO₄^2? constituted about 56.7 and 36.9% of the anions, respectively, in Lhasa River Basin. The hydrochemical type of groundwater is HCO₃-SO₄-Ca-Mg. The chemical composition of groundwater samples located in the middle of Gibbs model, which indicates that the major chemical process of groundwater is controlled by rock weathering. Carbonate weathering was the dominant hydro-geochemical process controlling the concentration of major ions in groundwater within Lhasa River Basin, but silicate weathering also plays an important role.