Mineralogy and petrology of sample 67075 and the origin of lunar anorthosites

Plagioclase in cataclastic anorthosite 67075 occurs as angular matrix grains and as recrystallized clasts of micro-anorthosite. Olivines are Fe-rich and fall into two compositional groupings. Large grains of pyroxene show exceptionally well-developed exsolution lamellae analogous to those observed in pyroxenes from layered complexes. The low-Ca component in both pigeonites and augites shows varying degrees of inversion to orthopyroxene. The lattices of host and lamellae may deviate slightly (up to 2°) from the ideal orientation. Very slow cooling from magmatic temperatures is required to produce the coarse exsolution textures and inversion features. Augite macrocrystals are distinctly subcalcic indicating crystallization at temperatures around1100 ± 50°C while host-lamellae pairs and small grains in lithic clasts and matrix indicate reequilibration on a micron scale to temperatures less than 800°C. Pyroxene compositions tend to cluster into two groups both of which are among the most Fe-rich reported for highland pyroxenes. Ti and Al contents of pyroxenes are very low and Ti, Cr, and Mn follow well-established magmatic differentiation trends. The high Cr content may reflect low?O₂ conditions and/or early crystallization of olivine and plagioclase.The⁸⁷Sr/⁸⁶Sr ratios in lunar anorthosites are the lowest reported for any lunar rock. It is likely that anorthosites formed as cumulates during the major differentiation episode which occurred prior to～4.3AE. Recrystallization features are common and³⁹Ar/⁴⁰Ar ages cluster around 4.0 AE. This may be the result of the intense bombardment prior to 4.0 AE which caused repeated cycles of in-situ fracturing and granulation followed by recrystallization. The low siderophile element content and the inferred slow cooling indicate a plutonic source region (10km) not frequently plumbed by impact events. The Fe-rich silicates indicate crystallization from a melt at an advanced stage of fractionation. However, the low REE abundances are not consistent with late-stage crystallization. Plagioclase apparently crystallized relatively early and was concentrated by flotation and/or convection currents while the mafic minerals crystallized from a fractionated trapped liquid. The chemical, isotopic, and mineralogical data place stringent constraints on the nature of genetically related rocks and the relationship of anorthosites to other members of the ANT suite does not appear to be one ofsimple fractionation. The data presented in this paper are consistent with the Taylor-Jake?model of lunar evolution.     

Paleointensity determinations of lunar samples

Evidence for the existence of an ancient lunar field comes from the NRM of lunar rocks and from measurements of local lunar surface magnetic fields. Even when the Fe particles present in the rocks possess enough magnetic stability to preserve a record of the original magnetizing field, there are considerable difficulties in estimating the strength of the field, primarily because of the chemical changes which take place on heating in the laboratory. These difficulties are discussed together with a paleointensity method involving heating in a more indirect way. A tentative interpretation of the results of paleointensity-age measurements is given.     

On the origin of eucrites and diogenites

Eleven eucrites have been analysed for major, minor and some trace (K, Sr, Zr, Y, Ba and Ni) constituents. These data are interpreted in terms of an igneous fractionation model according to which the observed enrichment trends of various elements in eucrite liquids are considered to be indicative of the simultaneous fractionation of plagioclase and pyroxene. Serra de Magéand Moore County are representatives of the cumulates thus formed. The achondrite Binda, a monomict breccia of howarditic composition, is interpreted as a possible precursor to the eucrite liquids. The derivation of a parent eucrite liquid from material of this composition could have occurred by fractionation of orthopyroxene. Diogenites are considered to represent the orthopyroxenites thus formed. The original liquid from which Binda and the eucrites were derived must, in terms of this model, have been more mafic than Binda.     

Mineralogy of phyllosilicate-rich micrometeorites and comparison with Tagish Lake and Sayama meteorites

Four phyllosilicate-rich micrometeorites (MMs) were investigated by a synchrotron radiation X-ray diffraction technique and transmission electron microscopy. Three are saponite-rich MMs and one is a serpentine-rich one. In the saponite-rich MMs, we could not find serpentine, and vice versa in the serpentine-rich MM. In the saponite-rich MMs, major constituent minerals are saponite, Fe- and Ni-bearing sulfides, and magnetite. Two saponite-rich MMs contain fine-grained magnesiowüstite-rich aggregates. The aggregates consist of <50 nm polygonal magnesiowüstite coexisting with minor Fe sulfide grains. Their texture, chemical composition, and the result of heating experiments on matrix fragments of the Tagish Lake carbonaceous chondrite strongly suggest that these aggregates were formed by the breakdown of Mg- and Fe-rich carbonate grains when the MMs entered the Earth’s atmosphere. The estimated major mineral assemblage of the saponite-rich MMs before entering the Earth’s atmosphere is very similar to that of the Tagish Lake carbonate-rich lithology, and we suggest that the MMs and the meteorite were derived from similar asteroids. The major mineral assemblage and texture of the matrix of serpentine-rich MM are similar to the matrix of the Sayama CM2 chondrite that experienced heavy aqueous alteration. Chemical compositions of serpentine in the MM suggest that the degree of aqueous alteration of the MM is weaker than that of Sayama. In the MM, cronstedtite does not coexist with tochilinite, which is different from CM2 chondrites that experienced weak to moderate aqueous alteration. However, the possibility that the serpentine-rich MM was derived from the CM chondrite asteroid cannot be ruled out, because tochilinite can be preferentially decomposed during atmospheric entry heating due to its lower decomposition temperature than that of cronstedtite.     

Argon-lead isotopic correlation in samples from lunar maria: Records from the ancient lunar regolith

²⁰⁷Pb/²⁰⁶Pb of “low temperature sited” (LTS) lead as reported by Silver (1975) increases with⁴⁰Ar/³⁶Ar of trapped argon in thirteen samples from lunar maria. This strongly supports an earlier conclusion by (1972) that large (⁴⁰Ar/³⁶Ar)_T ratios represent ancient regolith records, and provides a rough (⁴⁰Ar/³⁶Ar)_T timescale.The erasure of (⁴⁰Ar/³⁶Ar)_T records in surface soils by the excavation of deep-seated, “fresh” bedrock and by erosion of particle surfaces via ion sputtering must have been counteracted by conserving processes in the regolith. Two such processes are relatively well understood: agglutinate formation and the excavation and comminution of soil breccias which have preserved an ancient (⁴⁰Ar/³⁶Ar)_T record. The frequency distribution of (⁴⁰Ar/³⁶Ar)_T in 82 “soils” from all Apollo missions suggests a third process, which requires that sizeable “pockets” of ancient regolith materials including soils have survived deep turnover for billions of years.Large-scale mobility of LTS lead throughout all of the regolith does not appear to occur.Inert gas ions with sufficient energy for trapping may have reached the lunar surface more than 3 b.y. ago.The Apollo 11 microbreccias appear to have been formed more than 3 b.y. ago from regoliththen extant on the surface.     

Determination of secondary electron emission characteristics of lunar soil samples

A procedure is described for the determination of the “apparent crossover voltage”, i.e. the value of the primary (bombarding) electron energy at which an insulating sample surface changes the average sign of its charge. This apparent crossover point is characteristic of the secondary emission properties of insulating powders such as the lunar soil samples. We found that lunar core samples from well-defined, distinct soil layers differ significantly in their secondary emission properties. This observation supports the suggestion that soil layers were deposited by an electrostatic transport process.     

一套格点化的中国区域逐日观测资料及与其它资料的对比

为高分辨率气候模式检验等的需要,基于2400余个中国地面气象台站的观测资料,通过插值建立了一套0.25°×0.25°经纬度分辨率的格点化数据集(CN05.1).CN05.1包括日平均和最高、最低气温,以及降水4个变量.插值通过常用的"距平逼近"方法实现,首先将计算得到的气候平均场使用薄板样条方法进行插值,随后使用"角距权重法"对距平场进行插值,然后将两者叠加,得到最终的数据集.将CN05.1与CN05、EA05和APHRO三种日气温和降水资料(四种资料的分析时段统一为1961—2005年)进行对比,分析了它们对气候平均态和极端事件描述上的不同,结果表明几者总体来说在中国东部观测台站密集的地方差别较小,而在台站稀疏的西部差别较大,相差最大的是青藏高原北部至昆仑山西段等地形起伏较大而很少或没有观测台站的地方,反映了格点化数据在这些地区的不确定性,在使用中应予以注意.     

Effect of galvanic distortions on the series and parallel magnetotelluric impedances and comparison with other responses

The series and parallel impedances of the magnetotelluric tensor are appraised in relation to their relative immunity to galvanic electric distortions. The distorted responses are modeled using the Groom-Bailey decomposition of the tensor in terms of twist, shear, statics and strike direction. These four parameters and the undistorted responses are normally considered as unknowns, and are obtained from field data through the solution of an inverse problem. In the present work we use the decomposition as a forward model to simulate distorted sounding curves. Starting with undistorted 2-d te and tm responses, the tensor is distorted by assuming arbitrary values of twist, shear, static and strike direction. By default, both series and parallel responses are immune to the strike direction because they are invariants under rotation. In addition, series responses are immune to twist and shear and parallel responses only to twist. The dependence of the latter on shear is in the form of a real factor that shifts downwards the amplitude curves. On the other hand, the effect of statics on both series and parallel responses is more complicated than that on the impedance tensor because it cannot be accounted for by a simple shift of the curves. On the whole, there is a positive balance on the part of the series and parallel impedances over the te and tm responses because some of the distortions are filtered out by the invariants. It is shown that invariance is not sufficient to be immune to any of the distortions. The example chosen is Eggers’ eigenvalues, which are immune only to the by-the-fault strike direction. Invariance is not necessary either, as evidenced by the phase tensor, whose elements depend on strike but are immune to all distortions. The derivations are illustrated using soundings from the synthetic coprod2s1 and field-recorded coprod2 and bc87 data sets.     

基于绕月单卫星和双星测量的月球重力场恢复仿真分析

月球重力场是月球科学研究的重要部分,是进一步了解月球内部结构和构造的基础,也是我国探月计划“嫦娥工程”一个重要的科学研究内容.本文针对“嫦娥工程”,利用GSFC/NASA/USA的GEODYNII/SOLVE轨道分析软件,分析计算了利用单星跟踪数据恢复月球重力场的能力,同时模拟计算了双星跟踪数据在恢复月球重力场方面的能力,结合可能的工程环境我们对两种情况分别给出了30天、60天和90天的计算结果.计算表明双星相比于单星对月球重力场的中低阶位系数有比较显著的改善.     

Neutron capture effects in lunar gadolinium and the irradiation histories of some lunar rocks

The Gd isotopic composition in 19 lunar rock and soil samples from three Apollo sites is reported. The analytical techniques and the high precision mass spectrometric measurements are discussed. Enrichments in¹⁵⁸GdO/¹⁵⁷GdO due to neutron capture range up to 0.75%. Integrated ‘thermal’ neutron fluxes derived from the isotopic anomalies of Gd are compared with spallation Kr data from aliquot samples to construct a model which gives both average cosmic-ray irradiation depths and effective neutron exposure ages (T_n) for some rocks. In the case of rock 12053, this yields an average sample location of ∼300 g/cm² below the lunar surface and an effective irradiation age of ∼230 my, compared to 99 my obtained by the⁸¹Kr-Kr method. Rock 14310 is the first lunar sample where Kr anomalies due to resonance neutron capture in Br are observed. A⁸¹Kr-Kr exposure age of 262 ± 7 my is calculated for this rock.     

在嫦娥一号探月工程中求定月球重力场

月球重力场制约着近月外空间物体的运动,同时环月飞行器的运动也反映了月球重力场的作用. 本文结合我国嫦娥一号探月工程,探讨了利用月球卫星的地面跟踪资料,求定月球重力场的基本理论和方法,分析了环月卫星的轨道高度、地面跟踪采样时间间隔和跟踪精度等对求定月球重力场的影响. 若单独利用我国嫦娥一号探月工程的地面跟踪数据,恢复30阶次左右的月球重力场模型是一个比较实际的目标. 地面跟踪最好能以75s的时间间隔进行采样,数据连续提供时间应不少于30个昼夜,月球卫星星下点的月面轨迹间距不大于110km.     

Thermomagnetic analysis of magnetite parts of serpentinite samples and results of other investigations

Summary The normal type of serpentinites consists of chrysotile. The magnetite parts are essential parts of the structure of chrysotile serpentinites (primary magnetite). Chrysotile is changed to antigorite by mechanical deformations. The magnetite parts of rock structure are lost and they sat down in the veins of serpentinite rocks (secondary magnetite). In this paper the thermomagnetic diagrams and the results of X-ray investigations of secondary and primary magnetite are described. Some results of susceptibility measurements are given. The secondary magnetite is characterized by a region of oxydation in the interval 280–400° C (secondary magnetite-Fe₂O₃-Fe₂O₃). The oxydation to -Fe₂O₃ is remarkably. On the thermomagnetic diagrams of primary magnetite no typical oxydation region is to be seen. The oxydation: primary magnetite-Fe₂O₃ is very small. The interval of measured susceptibility values amounts to (10–1500)·10^–6 cgs units. The essential variability of the main parts of serpentinite samples is characterized by the great changes of susceptibility values from point to point.The determined values of specific saturation magnetization (Gauss. cm³ g^–1), the X-ray powder data, and some results on remanent magnetization are given.

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Zusammenfassung Die Normaltypserpentinite bestehen aus Chrysotil. Der Magnetit ist Bestandteil der Struktur der Chrysotilserpentinite (primärer Magnetit). Unter dem Einfluß mechanischer Deformationen geht Chrysotil in Antigorit über. Die Magnetitanteile der Gesteinsstruktur gehen verloren und scheiden sich auf Klüften ab (sekundärer Magnetit). In der vorliegenden Arbeit werden die thermomagnetischen Abhängigkeiten und die Ergebnisse von Röntgenuntersuchungen des sekundären und primären Magnetits beschrieben. Es werden einige Ergebnisse der Suszeptibilitätsmessungen angeführt. Der sekundäre Magnetit wird durch einen Oxydationsbereich im Temperaturintervall 280–400° C charakterisiert (sekundärer Magnetit-Fe₂O₃-Fe₂O₃). Die Oxydation zu -Fe₂O₃ ist beträchtlich. Die thermomagnetischen Diagramme des primären Magnetits zeigen keinen typischen Oxydationsbereich. Die Oxydation: primärer Magnetit-Fe₂O₃ ist sehr gering. Das Intervall der gemessenen Suszeptibilitätswerte beträgt (10–1500)·10^–6 CGS-Einheiten. Die starke Veränderlichkeit der Hauptbestandteile der Serpentinitproben wird durch die großen Änderungen der Suszeptibilitätswerte von Punkt zu Punkt gekennzeichnet.Die gemessenen Werte der Sättigungsmagnetisierung (Gauss.cm³ g^–1), der Röntgenuntersuchungen und einige Ergebnisse über die remanente Magnetisierung werden gegeben.

     

Long-term preservation of amino acid racemization interlaboratory comparison samples

This report summarizes the present status and future preservation of four Interlaboratory Comparison Samples (ILC) used in the Amino Acid Racemization (AAR) community over the past 40 years. The ILC samples are now housed in the archival collection of Lamont-Doherty Earth Observatory.     

Palaeomagnetism and palaeogeography of Variscan formations of the Bohemian massif: A comparison with other regions in Europe

Summary Statistical evaluation of palaeomagnetic data from the Early Carboniferous to the Middle Triassic rocks in Europe, north of the Alpine tectonic belt, confirmed previously defined palaeotectonic stability of the whole European Plate since the Early Permian. The Trans-European Suture Zone represents a plate boundary, SW of which the Early Variscan and pre-Variscan formations show different degrees of palaeotectonic rotations, predominantly rotations of clockwise sense. A theoretical model simulating the translation and rotation movements was proposed showing that the West European Variscides underwent Hercynian palaeotectonic rotations comparable with the rotations derived for the Alpine tectonic belt.     

On the possibility of using lunar fines to determine the intensity of the ancient lunar magnetic field

The remanent magnetization of iron grains in lunar fines can be studied by allowing a sample of fines to acquire a depositional remanent magnetization (NRM) in the Thellier determination of an ancient lunar field intensity. Although a natural remanent magnetization (NRM) in the Thellier determination of an ancient lunar field intensity. Although a palaeointensity of ca. 1.0 Oe was determined by this method, several factors complicate the interpretation of the result. These include the origin and nature of the iron metal in lunar fines, and the time and acquisition process of its magnetization.     

Distributed velocity method of solving the convective-dispersion equation: 2. Error analysis and comparison with other methods

This is the second part of a two-part paper presenting a new method for treating convective-dispersive transport. The motivation for developing this technique arises from the demands of performing a risk assessment for a nuclear waste repository. These demands include computational efficiency over a relatively large range of Peclet numbers, the ability to handle chains of decaying radionuclides with rather extreme contrasts in both solution velocities and half lives and the ability to treat leach- or solubitity-limited sources. To the extent it has been tested to date, the distributed velocity method (DVM) appears to satisfy these demands. This part presents an error analysis employing statistical sampling and regression analysis techniques, and comparisons of DVM with other methods for convective-dispersive transport.     

The origin of the lunar surface

A mechanism is described how the lunar landscape could have originated by a chain reaction of volcanic eruptions. The mechanism consists of a sequence of three steps; surface solidification and fragmentation, gas formation and crack-wave interactions. A quantitative analysis is presented and it is shown that the volcanic chain reaction was most likely to occur around 10 million years after surface solidification.     

Primeval displacements of the lunar pole

The hypothesis that the magnetic field which magnetized the lunar crust was generated by the dynamo process in a small fluid iron core can now be tested. Because the Coriolis force was a dominant term in the equations of motion in this core, the mean lunar field was aligned along the ancient axis of rotation. From Hood's modelling of the magnetic anomalies in the lunar crust, mapped by the Apollo 15 and 16 subsatellites, the palaeo-directions of this field have been determined. From them, palaeopole positions have been determined and are found to be grouped with respect to age. The palaeoequators corresponding to ages 4 Ga and 3.85 Ga show close relationships with the circular maria or mascons on the near side and multi-ring basins of corresponding age on the far side. The polar displacements indicated from lunar palaeomagnetism can be explained by the changes in the moment of inertia tensor consequent on the excavation and later flooding of these circular mare. Small moons in the primeval Earth-Moon system are inferred to be the impacting bodies.     

Moments of the lunar disturbing force

Summary The components of the moments of the external force due to the gravitational effect of the Moon are derived, which causes disturbances in the motion of the Earth round its mass centre, taking into account the gravitational fields of both bodies in the form of a development in terms of harmonics upto degree n=4. This paper ties up with [3–5] and the notations are identical.     

On the interpretation of lunar magnetism

It is proved that if a spherical shell is magnetized in the direction of and proportional to a magnetic field of origin internal to the shell and the magnetizing field later disappears, no magnetic field exists external to the shell. Similarly if a spherical shell is magnetized parallel to and proportional to a magnetic field of external origin and this magnetizing field later disappears, the magnetic field internal to the shell is zero. These theorems are true only if these ideal conditions are met, but are applicable to the interpretation of the natural remanent magnetization of the lunar crust. It is shown that the present absence of a magnetic dipole field of the Moon supports the hypothesis that the magnetizing field was of internal origin but does not distinguish whether this was due to a dynamo in the lunar core or to a primaeval magnetization of its interior. Local magnetic fields around the Moon are interpreted as arising from the departure from sphericity of the shell and large craters.