Submarine hydrothermal manganese deposits in the Izu–Bonin – Mariana arc: An overview

Submarine hydrothermal manganese deposits are relatively common along the Izu–Bonin – Mariana (IBM) arc but hydrothermal iron crusts are much less so. The hydrothermal manganese deposits show characteristics typical of submarine hydrothermal manganese deposits found worldwide. Recent hydrothermal manganese deposits associated with active hydrothermal systems occur on seamounts or rifts located ∼ 5–40 km behind the volcanic front on the Shichito-Iwojima Ridge, IBM. Fossil hydrothermal manganese deposits associated with older hydrothermal systems occur on inactive seamounts located on ridges running parallel to the volcanic front in both forearc and back-arc settings. These fossil hydrothermal manganese deposits are generally overlain by younger hydrogenetic manganese crusts. Differences in minor element composition and in the rare earth element pattern of hydrothermal manganese deposits from the forearc and back-arc settings may reflect differences in the nature of substrate rocks or temperature of the hydrothermal fluids at these locations.     

Wind erosion on the north‐eastern Tibetan Plateau: constraints from OSL and U‐Th dating of playa salt crust in the Qaidam Basin

The arid Qaidam Basin is the largest (~3.88 × 10⁴ km²) basin on the north‐eastern Tibetan Plateau. Wind erosion in the area has been regarded as an important trigger for intra‐basin tectonic balance upheaval, geomorphologic development and as a major supplier of dust to the Chinese Loess Plateau downwind. An initial estimate of the rate of wind erosion (Kapp et al., 2011) based on geological cross‐sections has suggested up to 3.2 × 10⁴ km³ of sediments has been deflated over the past 2.8 Ma, lowering the landscape by an average of 0.29 mm/yr. In this paper we re‐evaluate this estimate by dating surface crusts present on three playas within the basin. Understanding the development of these playas is crucial to assessing the overall role of the wind in shaping the regional landscape because they are typically capped with a thick salt crust which effectively protects them from wind erosion. Optically stimulated luminescence (OSL) and U‐series dating from a pit section and from the top of a deep drill core, together with results from magnetostratigraphy and a climate proxy record correlated to the marine oxygen isotope record, are used here to determine the age of the playa plains and suggest that the salt crusts have an age of c. 0.1 Ma. This young age and the wide distribution of resistant thick salt crusts of the playa plains indicate a much lower degree of wind erosion than previously suggested. The crusts protect the surface from significant surface erosion (including sediment exhumation and unloading) and whilst some wind erosion does occur, it is unlikely to be sufficient to trigger tectonic uplift of the basin or to be a major dust source for the Loess Plateau as previously suggested. Copyright © 2013 John Wiley & Sons, Ltd.     

Isotopic evidence for uranium exchange during low-temperature alteration of oceanic basalt

Measurements of uranium concentration and the²³⁴U/²³⁸U activity ratio in oceanic basalts which have undergone low-temperature seafloor alteration indicate that uranium uptake is a pervasive occurrence but that the various phases involved behave differently with respect to this process. Palagonite exhibits uranium contents 8–20 times higher than unaltered glass coupled with low²³⁴U/²³⁸U, suggesting ongoing preferential leaching of²³⁴U. Altered crystalline interiors of several old basalts have²³⁴U/²³⁸U > 1, indicative of recent uranium exchange with seawater. The data also provide evidence for uranium sources with²³⁴U/²³⁸U higher than the seawater value of 1.14. Manganese crusts on basalts of a variety of ages have isotopic ratios indicating that they either are recent deposits or also have experienced continuing uranium exchange with seawater.     

Pb isotope geochemistry of lead,zinc, gold and silver deposit clustered region,Liaodong rift zone,northeastern China

As one of the important deposit-clustered regionsof China, the Liaodong (eastern Liaoning Province)rift zone contains many large lead, zinc, gold, boron,magnesite and talc ore deposits with a long mininghistory. Recently, large-scale Xiaotongjiapuzi gold andGaojiapuzi silver deposits were discovered in the re-gion. Much work on the origin of these deposits hasbeen carried out, however, the discrepancy on the ageand the metal source of the deposits still rem- discu…     

Assessing the use of U–Th methods to determine the age of cold-water calcareous algae

Calcitic crusts of calcareous red algae could be suitable material for age determination of raised marine deposits and palaeothermometry at annual to sub-annual resolution. We examined the potential of U–Th dating of cold-water calcareous algae by analysing fossil specimens (n=10) from Kapp Ekholm (Svalbard) and recent specimens from Norway (n=3) and Scotland (n=1). After initial measurements using α-spectrometry, thermal ionisation mass spectrometry (TIMS) was used to study the material in more detail. Recent specimens contain 0.19–1.55 μg g⁻¹ U, and the measured (²³⁴U/²³⁸U) activity ratios vary between 1.12 and 1.30. Fossil specimens contain 1–168 μg g⁻¹ U, and display variable and highly elevated initial (²³⁴U/²³⁸U) activity ratios. In general, the TIMS results show increasing (²³⁴U/²³⁸U) activity ratios and concentrations of U and Th with increasing stratigraphic age. From this it is evident that marine calcareous red algae contain U in-vivo and they experience substantial post-mortem uptake of U. We conclude that direct U–Th dating of fossil calcareous algae from raised marine deposits is not viable without further geochemical understanding of the in-vivo uptake and post-depositional pathways of U and Th in such deposits. Despite the convincing open-system behaviour of the material, comparison with previously published chronostratigraphy from the site shows that the calcareous algae generally yield ages that are too old. This is in contrast to the expected result based on simple continuous post-mortem U accumulation and calls for a complex model comprising migration of U and multi-component addition of Th (detrital/colloidal) to explain the observed trends.     

Pb‐isotope compositions of the Tasik Chini volcanic‐hosted massive sulfide deposit,Central Belt of Peninsular Malaysia: Implication for source region and tectonic setting

Lead isotope data of sulfides and host volcanic rocks from the Bukit Botol and Bukit Ketaya deposits, the two representative deposits of the Tasik Chini volcanic‐hosted massive sulfide (VHMS) deposit, Central Belt of Peninsular Malaysia, are reported. Lead isotope compositions of the associated sulfide minerals and volcanic rocks from the Bukit Botol deposit exhibit homogeneous and less radiogenic values (²⁰⁶Pb/²⁰⁴Pb showing a range of composition from 18.14 to 18.20, ²⁰⁷Pb/²⁰⁴Pb between 15.52 and 15.59 and ²⁰⁸Pb/²⁰⁴Pb from 37.96 to 38.35). Similarly, the Pb isotopic compositions of the host volcanic rocks from the Bukit Ketaya deposit yielded a narrow range to those of the sulfide samples (²⁰⁶Pb/²⁰⁴Pb from 18.04 to 18.20, ²⁰⁷Pb/²⁰⁴Pb between 15.43 and 15.57 and ²⁰⁸Pb/²⁰⁴Pb of 37.96 to 38.30). The uniform Pb‐isotope compositions of the sulfides in the ore horizon and the host volcanic rocks from both deposits suggest a derivation from a similar source reservoir and mineralization processes. In the framework of the tectonic model for the Central Belt of Peninsular Malaysia, both deposits display a range of lead isotopic compositions originated from mixing of bulk crust/juvenile arc and minor mantle sources, which are typical for VHMS deposits in an island arc–back arc setting.     

New index of ferromanganese crusts reflecting oceanic environmental oxidation

Ferromanganese crusts (hereinafter crusts) form in aerobic environment and the environmental oxida-tion degree is recorded by the redox sensitive element Co in the crusts. The ages of the layers from the surface to bottom of the crusts are determined, and main element contents at high resolution along the depth sections of three crusts from the Pacific Ocean are analyzed by an electron microprobe. Thus the variations of Co/(Fe Mn) and Co/(Ni Cu) with age/depth of the crust layers are obtained. By comparing the ratios of Co/(Fe Mn) and Co/(Ni Cu) with the δ 18O curves of the Pacific benthic foraminifera, we find that these two ratios can reflect the variation of the environmental oxidation state under which the crust layers deposit. The evolution of the oxidation degree reflected by the two indexes resembles the evo-lution of temperature since the Oligocene reflected by the δ 18O curves of the Pacific benthic foraminif-era. This suggests that the crust-forming environment after the Oligocene is controlled mainly by the oxygen-rich bottom water originated from the Antarctic bottom water (AABW). However it is not the case prior to the Oligocene. Furthermore it suggests that the environmental oxidation degree controls the formation of the crusts and the Co contents in the crusts. This explains why the Co contents in the crusts increase with time up to now.     

Source of lead in Central American and Caribbean mineralization,II. Lead isotope provinces

In an earlier study of Mesozoic and Cenozoic mineralization in Central America and the Caribbean region, we found that lead isotopic compositions of deposits in northern Central America, which is underlain by a pre-Mesozoic craton, ranged to higher²⁰⁶Pb/²⁰⁴Pb and²⁰⁷Pb/²⁰⁴Pb compositions than did deposits from elsewhere in the region, where the basement is Mesozoic oceanic material. Using 16 analyses for 12 new deposits, as well as new analyses for 11 of the samples studied previously, we have found that lead isotopic compositions correlate closely with crustal type but show little or no correlation with depth to the M-discontinuity. The deposits are divisible into three main groups including (in order of increasing²⁰⁷Pb/²⁰⁴Pb and²⁰⁸Pb/²⁰⁴Pb ratio): (1) deposits in southern Central America and all deposits in the Greater Antilles except Cuba; (2) all deposits in northern Central America; and (3) the Cuban deposits. Southern Central American and Caribbean lead is higher in²⁰⁷Pb/²⁰⁴Pb and²⁰⁸Pb/²⁰⁴Pb than most mid-ocean ridge basalts but could have been derived directly or indirectly from undepleted mantle. Northern Central America can be divided into the Maya block, which belongs to the Americas plate, and the Chortis block, which belongs to the Caribbean plate. Maya block deposits fall along a linear array whereas those of the Chortis block (except the Monte Cristo deposit) form a cluster. These results suggest that the Maya block is underlain by crust or mantle with a large range of U/Pb and Th/U ratios, whereas the Chortis block basement is more homogeneous. Two-stage model calculations indicate an age of about 2280±310 m.y. for the Maya block basement, although no such rocks are known in the region. Comparison of the Chortis block data to our recently published lead isotopic analyses of Mexican deposits shows considerable similarities suggesting that the Chortis block could have been derived from Mexico.     

Mineral accumulations induced by biological activity on granitic rocks in Qinghai Plateau,China

Fragments of weathered granitic rocks from the Kunlun Shan, Qinghai Plateau (China) were investigated to elucidate the in?uence of biotic crusts on the breakdown of granitic rocks in an alpine environment. Scanning electron microscopy with energy dispersive system and X‐ray diffractometry were used to describe the nature and properties of mineral accumulations on the rock surface. Results showed that organic salts such as calcium oxalate and calcium formate are associated with Aspicilia caesiocinera (Nyl.ex Malbr.) Arnold, Caloplaca sp., Xanthoria elegans (Link) Th.Fr., and Lecidea plana (Lahm) Nyl. Secondary accumulations of 2 : 1 clays minerals are found in A. caesiocinera while oxides of manganese are associated with X. elegans. Coatings of goethite (iron oxides) are believed to form from biological activity associated with the presence of hyphae and rodlet structures on the ?akes. Calcium oxalate crystallizes into several morphologies such as druse, hexagonal plates, and lenticular containing between 20 and 48 per cent calcium by weight. Calcium formate and iron oxide (goethite) occur together in the form of ‘red’ desert varnish. Observed ‘black’ coatings contain as much as 37 per cent manganese and 22 per cent iron. Clay accumulations have plate‐like morphology and contain c. 2 : 1 silicon to aluminium contents. We argue that organic acids from the activities of biotic crusts contribute to the breakdown of granitic rocks. Fungi accelerate the breakdown of granitic rocks through the growth of fungal hyphae along the 001 cleavage planes in primary chloritic minerals. Copyright © 2003 John Wiley & Sons, Ltd.     

The influence of the carbonate dissolution rate on the growth and composition of Co-rich ferromanganese crusts from Central Pacific seamount areas

The metal composition of oceanic ferromanganese deposits occurring in seamount regions (Line Islands chain and Mid-Pacific Mountains) varies with water depth and age. The results of metal determinations of carbonate plankton samples suggest that carbonate dissolution in the water column might have an important influence on the accretion and composition of hydrogenetic precipitates. Two ferromanganese crust generations of different age have been observed The precipitation of the older crust took probably place during early Oligocene, the younger crust began to form during middle Miocene. Between the two crust generations periods of carbonate sedimentation and of phosphorite deposition occur. The hydrogenetic formation of the crusts is controlled by the metal supply from the water column, according to the laws of colloidal surface chemistry.Dissolution experiments with carbonate plankton samples show that the main Fe source for the hydrogenetic crust formation are colloidal Fe-hydroxide particles being released in the water column from the dissolution of carbonate plankton skeletons. In the case of Mn, maximum dissolved Mn occurs in the oxygen minimum zone as the result of in-situ break-down of organic matter and the in-situ reduction of Mn-bearing solid phases. Closely beneath the oxygen minimum zone a Fe supply, mobilized within the oxygen minimum zone, has also to be taken into account. In the water column below the oxygen minimum zone, a mixture of colloidal particles of MnFe-oxyhydroxide and colloidal AlFe-silicate, precipitate together on the surface of substratum rocks. The mixing ratio of these colloidal phases controlling the metal composition of the ferromanganese precipitates, is depth-dependent and shows also temporal variations. In general, Mn/Fe ratio, Ni, and Co contents decrease with depth down to the calcite compensation depth.The most probable mechanism for the ultimate removal of Co and Ni from the water column might be a surface reaction. δ-MnO₂ is specifically able to absorb hydrous Co²⁺ and Ni²⁺ ions. Because of the surface enrichment of Co and the strong electrical field of Mn(IV), a subsequent oxidation of Co²⁺ to Co³⁺ takes place leading to higher enrichment of Co in comparison to Ni. The most important factor governing the high Co enrichment in the ferromanganese crusts is the growth rate: the lower the growth rate, the higher the Co content. Maximum values of up to 2% Co occurring in samples from water depths between 1500 and 1100 m [1] are related to lower carbonate dissolution rates and corresponding lower Fe supply.The metal supply from the water column is strongly related to distinct environmental factors such as bio-productivity, range of lysocline and calcite compensation depth, rate of carbonate dissolution, and activity of the Antarctic bottom water. Thus, our model shows that the growth periods and the metal composition of hydrogenetic seamount crusts are controlled by changes in the paleoceanography and reflect distinct environmental conditions.     

40Ar/39Ar dating of cryptomelane from the Baye manganese deposit, SW Yunnan, China: Implications for growth rate of supergene Mn-oxide veins

Supergene Mn-oxide deposits are commonly related to thick weathering profiles and form as a result of intense and prolonged weathering of Mn-bearing precursor rocks, processes facilitated by a combination of multiple factors including warm and wet climate, relatively quiescent tectonic environment, and favorable geomorphic setting. Precise age constraints of supergene Mn-oxides may provide valuable information on the climatic, tectonic, and geomorphic conditions prevailing in the geological past. ⁴⁰Ar/³⁹Ar laser incremental heating analysis of cryptomelane from the Baye manganese deposit, western Yunnan-Guizhou Plateau, SW China, was conducted to provide numerical constraints on the ages of supergene Mn enrichment and growth rates of Mn-oxide veins. In this study, two Mn-oxide veins of 3–6 cm thickness, termed as Vein A and B, respectively, were collected for ⁴⁰Ar/³⁹Ar dating. Vein A is subhorizontal and present in fractures parallel to schistosity of the Proterozoic spessartine schists, whereas Vein B is filled in nearly vertical fractures penetrating the schistosity. A combination of optical microscopy, XRD, SEM, and EMP analyses demonstrate that mineral grains extracted from both veins consist of pure, well-crystallized cryptomlane, which has acicular crystal forms and contains 0.96%–4.70% K₂O. Fourteen cryptomelane subsamples extracted from different growth bands of Vein A yield well-defined plateau ages ranging from 1.35 ± 0.05 to 1.16 ± 0.04 Ma (2σ), whereas seven subsamples obtained from Vein B have plateau ages ranging from 1.23 ± 0.05 to 1.01 ± 0.04 Ma (2σ). The age results permit estimation for the growth rates of both veins at ca. 115–153 and 34–67 mm Ma^?1, respectively. Distinct growth rates between Veins A and B are likely reflective of different fluid pressures during their formation governed by the orientation of the fractures hosting the veins. The growth rates calculated for both veins are 1–2 orders of magnitude higher than the values (<1–10 mm Ma^?1) estimated for Mn-oxide nodules in supergene Mn deposits elsewhere. The high growth rates obtained for the Baye samples are consistent with direct precipitation of tetravalent Mn-oxides from weathering solution in open cavities or fractures, characterized by incremental growth of Mn-oxide bands from the margin to the center of the cavities or fractures. In contrast, Mn-oxide nodules with low growth rates from other deposits formed through self-oxidation and self-catalization, and grow outwards from the nuclei. In addition, prevalence of warm and humid climate and prolonged tectonic uplift in the Yunnan Plateau may have also partly contributed to the rapid growth of Mn-oxides in the Baye deposit.     

The geochemistry of manganese in the Dead Sea

The most important source of dissolved manganese, Mn(II), to the Dead Sea is by upward diffusion from bottom sediments. This source contributes about 80 tons of Mn(II) each year. The concentration of dissolved manganese in the Dead Sea is extraordinarily high (7.03 mg 1^?1). It appears that the content (some 1.026 × 10⁶ tons) of dissolved manganese in the sea has remained constant during 1977–1979, although oxygen was introduced into deeper layers during the deepening of the pycnocline (1977–1978) and during the overturn of its water masses in the winter of 1978/79. The rate of oxidation of Mn(II) in Dead Sea water is extremely slow hence Mn(II) may practically be considered as the stable form of Mn in Dead Sea waters. Dilution by fresh water causes a pH rise and may facilitate faster oxidation of the dissolved divalent manganese. It is shown here that the shape of the Mn(II) profile, observed in the lake during 1963, may have developed by oxidation of Mn(II) in the more diluted upper layers and subsequent reduction of the oxidation products in the anoxic and more saline deeper layers during 260 years of continuous meromixis.     

CHEMICAL EQUILIBRIA AFFECTING THE BEHAVIOR OF MANGANESE IN NATURAL WATER

Abstract

The solubility of manganese in natural water is strongly influenced bychemical equilibria involving Mn⁺², Mn⁺³ and Mn⁺⁴ species, redox potential, pH, and dissolved species of bicarbonate and sulfate. The solubility of manganese is shown by graphs as a function of Eh and pH in the absence of sulfate and in the presence of several different fixed activities of bicarbonate and sulfate ranging from 10 to 2,000 ppm (parts per million). Solubility is increased by the complexes MnHCO⁺ ₃ and MnSO₄ aq. whose association constants are 63 and 190, respectively.

Divalent manganese is soluble to the extent of 0.10 to 1.0 ppm at equilibrium in most ground and surface water. Manganese is more soluble than iron under most possible conditions, especially inthe Eh-pH range common in river water.     

The Pomici di Avellino eruption of Somma-Vesuvius (3.9 ka bp). Part I: stratigraphy, compositional variability and eruptive dynamics

The stratigraphic succession of the Pomici di Avellino Plinian eruption from Somma-Vesuvius has been studied through field and laboratory data in order to reconstruct the eruption dynamics. This eruption is particularly important in the Somma-Vesuvius eruptive history because (1) its vent was offset with respect to the present day Vesuvius cone; (2) it was characterised by a distinct opening phase; (3) breccia-like very proximal fall deposits are preserved close to the vent and (4) the pyroclastic density currents generated during the final phreatomagmatic phase are among the most widespread and voluminous in the entire history of the volcano. The stratigraphic succession is, here, divided into deposits of three main eruptive phases (opening, magmatic Plinian and phreatomagmatic), which contain five eruption units. Short-lived sustained columns occurred twice during the opening phase (H_t of 13 and 21.5 km, respectively) and dispersed thin fall deposits and small pyroclastic density currents onto the volcano slopes. The magmatic Plinian phase produced the main volume of erupted deposits, emplacing white and grey fall deposits which were dispersed to the northeast. Peak column heights reached 23 and 31 km during the withdrawal of the white and the grey magmas, respectively. Only one small pyroclastic density current was emplaced during the main Plinian phase. In contrast, the final phreatomagmatic phase was characterised by extensive generation of pyroclastic density currents, with fallout deposits very subordinate and limited to the volcano slopes. Assessed bulk erupted volumes are 21 × 10⁶ m³ for the opening phase, 1.3–1.5 km³ for the main Plinian phase and about 1 km³ for the final phreatomagmatic phase, yielding a total volume of about 2.5 km³. Pumice fragments are porphyritic with sanidine and clinopyroxene as the main mineral phases but also contain peculiar mineral phases like scapolite, nepheline and garnet. Bulk composition varies from phonolite (white magma) to tephri-phonolite (grey magma).     

Spatial variation of U-Th series radionuclides and trace metals in deep-sea manganese encrustations

A series of measurements to assess the spatial variability on a scale of a few centimeters of UTh series nuclides and trace metals in surface layers of deep-sea ferromanganese encrustations are reported here. Two samples, one from an Atlantic seamount and another from MANOP site S in the Pacific are reported.The inventories of²³⁰Th_exc cm^?2 and²³¹Pa_exc cm^?2 as well as the ratios of the inventories are seen to vary by large amounts in samples only a few centimeters apart. These observations infer that the fluxes of these radionuclides to small areas on the ferromanganese crust may also vary with time. No strong correlation between the radioisotope inventories and concentrations of various elements has been observed.     

Space and time regularities in the distribution of dissolved and suspended manganese forms in Novosibirsk Reservoir water

The space and time regularities in the distribution, migration, and turnover of dissolved and suspended manganese forms in Novosibirsk Reservoir water are considered. The flux of dissolved manganese forms (Mn²⁺) from bottom sediments into the water mass is shown to reach its maximum in the under-ice period (since the late February to the mid-April), as well as in the period of maximal abundance of biota (August–early September), when reduction conditions form everywhere in reservoir bottom sediments. In this period, bottom sediments are the main source of manganese input into the reservoir water, their contribution reaching 250–400% relative to the inflowing river water; manganese vertical distribution in water is opposite to that of dissolved oxygen, and its concentration is in excess of the hygienic standards. The maximal flux of dissolved manganese forms (Mn⁴⁺) from water into bottom sediments is recorded in August–September (on the average, 0.17 g/(m² day)); it drops to 0.06 g/(m² day) during spring flood, and practically vanishes in the under-ice period.     

Dating of Late Pleistocene terrace deposits of the River Rhine using Uranium series and luminescence methods: Potential and limitations

Uranium-series dating of pedogenic carbonate crusts from fluvial gravels is tested using Optically Stimulated Luminescence (OSL) ages as references. OSL dating yielded ages of 30–15 ka and 13–11 ka, which correlate with the cold periods of the Last Glacial Maximum and the Younger Dryas. These ages are internally coherent and consistent with the geological background and are thus regarded as reliable. Most of the U/Th results scatter widely in the ²³⁰Th/²³²Th vs. ²³⁴U/²³²Th isochron diagram, making regression unrealistic. Semiquantitative age estimates from the data were found to be mostly older than the OSL ages and the geological context. It is suggested that a heterogeneous initial ²³⁰Th input, not relatable to a detrital component, is responsible for the observed discrepancies. This input may be due to bacterial activities and Th transport on organic colloids. It appears necessary to avoid samples where bacteria could have contributed to carbonate precipitation. Further, the relative importance of this problem decreases with sample age, so that U/Th dating of sinters is expected to be more reliable in the >100 ka age range.     

Mass-dependent cadmium isotopic variations in nature with emphasis on the marine environment

We report a survey of natural mass-dependent cadmium isotope fractionation measured by thermal ionization mass spectrometry using a double-spike technique (DS-TIMS). Over sixty samples of natural terrestrial Cd from diverse environments, including MORB, OIB, continental loess, hydrogenic and hydrothermal ferromanganese deposits, and sphalerites (both oceanic and from major continental ore deposits) were analysed. Our results are expressed in terms of ε^112/110Cd, which are deviations in ¹¹²Cd/¹¹⁰Cd from our in-house JMC Cd standard in parts per 10⁴. The total ε^112/110Cd variation is relatively small, with a range of only 5 ε-units, and is one-to-two orders of magnitude smaller than that previously found in meteorites.The MORB, OIB and loess ε^112/110Cd values are similar and provide a good estimate for the bulk silicate Earth (BSE) value which is ? 0.95 ± 0.12 relative to our Cd standard (ε^112/110Cd = + 0.16 relative to Münster JMC Cd). Taken together, these data suggest little Cd isotope fractionation takes place during crust–mantle segregation. Cd isotopic compositions of continental sphalerite (ZnS) deposits worldwide and high-temperature oceanic hydrothermal sulphides show remarkably similar ε^112/110Cd values, consistent with our estimate for the BSE. In contrast, mid-temperature oceanic sulphides from a single extinct hydrothermal chimney display over 4 ε-units variation — along with the most negative values. These variations are most probably caused by precipitation/redissolution of sulphide phases en route within the hydrothermal system.The ε^112/110Cd variability found in worldwide marine Fe–Mn deposits reflects the seawater Cd isotope signal upon precipitation from ambient seawater. A decrease in ε^112/110Cd is observed in passing from shallow-water Fe–Mn deposits to those from deeper waters (> 2000 m depth). This shift is explained by biological fractionation related to the uptake of dissolved seawater Cd by phytoplankton in the upper water column. The relatively uniform ε^112/110Cd values close to zero at great depths are consistent with regeneration and remineralization of Cd at depth. Our data suggest that Cd isotopes – much like the Cd/Ca ratio in foraminifera – could potentially serve as a proxy for past changes in biological productivity. The temporal Cd isotope record in a Fe–Mn crust archive at 2000 m depth from the NE Atlantic suggests no gross long-term changes in Cd cycling took place over the past 8 Ma.     

Sources and genesis of the Chinkuashih Au-Cu deposits in northern Taiwan: constraints from Os and Sr isotopic compositions of sulfides

The Chinkuashih district at northern Taiwan hosts one of the largest Au deposits in the western Pacific gold province. Gold were precipitated from hydrothermal solutions as native gold or incorporated into sulfides at a temperature range of 200-350 °C. The sulfides in ore mines have ¹⁸⁷Os/¹⁸⁸Os ratios varying from 0.139 to 0.249. The positive ¹⁸⁷Os/¹⁸⁸Os-1/Os correlation is consistent with derivation from the hybrid fluids containing various proportions of mantle and crustal components. The crustal component was the meteoric water that had acquired its Sr and Os isotopic signatures from the local sedimentary formations and dacitic intrusions. The mantle component was the magmatic fluid segregated from the dacitic magma by fractional crystallization. Based on the ¹⁸⁷Os/¹⁸⁸Os-1/Os correlation, the hybrid fluids forming the Chinkuashih sulfides contained less than 30% magmatic fluid, except for one sulfide sample from Hsumei, which required >40% magmatic fluid. Compared to meteoric water, the magmatic fluid contained a higher Os content (130 times higher) and was enriched in Os relative to Sr with an Os/Sr ratio two orders higher than that of the crustal fluid. Consequently, the Os budget in the hybrid fluids was controlled by the magmatic fluid, although the meteoric water was volumetrically dominated. If gold and Os behave similarly in chemistry, the Chinkuashih gold deposits are of mantle origin and the area where sulfides with the greatest mantle Os signature may host undiscovered gold deposits. Finally, the ¹⁸⁷Os/¹⁸⁸Os ratios of sulfides show no relationship with the mineral assemblages of sulfides, implying that the sulfide mineral assemblages reflect local surfacial redox conditions rather than the chemical characteristics of parental fluids.     

Temporal aspects of the abrasion of microphytic crusts under grain impact

Wind‐tunnel simulations of the response of two moss crusts to grain impact indicate that, given sufficient time, these surfaces will deteriorate under very low wind velocities only slightly above u_*t for the loose, saltating grains. In parallel with these experiments, the frequency distributions of ultimate strength and penetration energy were determined for each of the two crust types via penetrometry. Pohlia was found to be stronger than Tortula; but, even so, both of these crusts had ultimate strengths 20–350 times higher than the force delivered by a single grain impacting each surface at a velocity of 1 ms^?1. In comparison, the modulus of deformation and penetration energy data were very similar for the two surface types, especially for the weakest areas of crust development. This observation is in accord with the wind‐tunnel simulations that also found no consistent difference in the response of these two crust types to impact. In comparison with crusts formed by clay and salt, fibrous microphytic crusts are morphologically complex and typically weak. The notable elasticity of these surfaces does reduce the force of grain impact, and thereby provides some protection against rupture. One of the central conclusions of this study suggests that not only is the particle kinetic energy at impact important in crust breakdown, but also tiny fractures at points of localized stress concentration contribute to a progressive reduction in the integrity of the filament net. In some of the experiments conducted as part of this study, up to 50 or more minutes of constant bombardment was required to produce small abrasion marks on selected areas of the microphytic crust. This study prepares a foundation for future experiments needed to examine the breakdown of complex crusts formed in nature. Copyright © 2002 John Wiley & Sons, Ltd.