Source of lead in Central American and Caribbean mineralization,II. Lead isotope provinces

In an earlier study of Mesozoic and Cenozoic mineralization in Central America and the Caribbean region, we found that lead isotopic compositions of deposits in northern Central America, which is underlain by a pre-Mesozoic craton, ranged to higher²⁰⁶Pb/²⁰⁴Pb and²⁰⁷Pb/²⁰⁴Pb compositions than did deposits from elsewhere in the region, where the basement is Mesozoic oceanic material. Using 16 analyses for 12 new deposits, as well as new analyses for 11 of the samples studied previously, we have found that lead isotopic compositions correlate closely with crustal type but show little or no correlation with depth to the M-discontinuity. The deposits are divisible into three main groups including (in order of increasing²⁰⁷Pb/²⁰⁴Pb and²⁰⁸Pb/²⁰⁴Pb ratio): (1) deposits in southern Central America and all deposits in the Greater Antilles except Cuba; (2) all deposits in northern Central America; and (3) the Cuban deposits. Southern Central American and Caribbean lead is higher in²⁰⁷Pb/²⁰⁴Pb and²⁰⁸Pb/²⁰⁴Pb than most mid-ocean ridge basalts but could have been derived directly or indirectly from undepleted mantle. Northern Central America can be divided into the Maya block, which belongs to the Americas plate, and the Chortis block, which belongs to the Caribbean plate. Maya block deposits fall along a linear array whereas those of the Chortis block (except the Monte Cristo deposit) form a cluster. These results suggest that the Maya block is underlain by crust or mantle with a large range of U/Pb and Th/U ratios, whereas the Chortis block basement is more homogeneous. Two-stage model calculations indicate an age of about 2280±310 m.y. for the Maya block basement, although no such rocks are known in the region. Comparison of the Chortis block data to our recently published lead isotopic analyses of Mexican deposits shows considerable similarities suggesting that the Chortis block could have been derived from Mexico.     

Relationships between mineralization and silicic volcanism in the Central Andes

Studies of late Tertiary silicic volcanic centres in the Western and Eastern Cordilleras of the Central Andes show that three volcanic environments are appropriate sites for mineralization: (1) ring-fracture extrusions post-dating large calderas; (2) similar extrusions within ignimbrite shields; and (3) isolated, small silicic volcanoes. Subvolcanic tin mineralization in the Eastern Cordillera is located in silicic stocks and associated breccias of Miocene age. The Cerro Rico stock, Potosi, Bolivia, contains tin and silver mineralization and has an intrusion age apparently millions of years younger than that of the associated Kari Kari caldera. Similar age relationships between mineralization and caldera formation have been described from the San Juan province, Colorado. The vein deposits of Chocaya, southern Bolivia, were emplaced in the lower part of an ignimbrite shield, a type of volcanic edifice as yet unrecognized in comparable areas of silicic volcanism. The El Salvador porphyry copper deposit, Chile, is related to silicic stocks which may have been intruded along a caldera ring fracture. Cerro Bonete, Chile, provides a modern example of the volcanic superstructure which may have overlain isolated mineralized stocks and breccia pipes such as that of Salvadora at Llallagua, Bolivia.Existing models for the genesis of porphyry copper deposits suggest that they formed in granodioritic stocks located in the infrastructure of andesitic stratovolcanoes. Sites of porphyry-type subvolcanic tin mineralization in the Eastern Cordillera of Bolivia are distinguished by the absence of such andesitic structures. The surface expression of a typical subvolcanic porphyry tin deposit was probably an extrusive dome of quartz latite porphyry, sometimes related to a larger caldera structure. Evidence from the El Salvador porphyry copper deposit in the Eocene magmatic belt in Chile suggests that it too may be more closely related to a silicic volcanic structure than to an andesitic stratovolcano.The dome of La Soufriere, Guadeloupe is proposed as a modern analog for the surface expression of subvolcanic mineralization processes, the phreatic eruptions there suggesting the formation of hydrothermal breccia bodies in depth. Occurrence of mineralized porphyries, millions of years after caldera formation, does not necessarily indicate that intrusions and mineralization are not genetically related to the sub-caldera pluton, but may be a consequence of the long thermal histories (1–10 million years) of the lowermost parts of large plutons. Caldera formation can only inhibit mineralization by dispersal of ore metals when these are of magmatic origin, and ignimbrites should not be taken as being unlikely to be associated with porphyry mineralization. Whether ore metals are of wall rock or magmatic origin, the key to understanding the relationships between silicic volcanism and mineralization lies in the fractionation of trace elements within large zoned magma chambers during their igneous history, and their subsequent hydrothermal migration. Small, highly mineralized intrusions formed late in a caldera cycle (such as the Cerro Rico) may be due to the introduction of fresh supplies of mafic magma into the lower parts of the main pluton.     

中美洲古地震学专题讨论会

最近 ,在尼加拉瓜召开了一次古地震学专题讨论会 ,这是首都马那瓜地震烈度小区划项目的一部分。而马那瓜地震烈度小区划项目又是由挪威发展合作局 (NORAD)资助 ,且通过中美洲自然灾害防御协调中心(CEPREDENAC)的秘书处进行协调的中美洲地震减灾计划的一个组成部分。自 2 0世纪 80年代以来 ,危地马拉、萨尔瓦多、洪都拉斯、尼加拉瓜、哥斯达黎加及巴拿马等国在一个自然灾害评估和防灾方面的项目中进行着合作 ,旨在避免将来遭受诸如由1 986年萨尔瓦多、 1 976年危地马拉以及 1 972年尼加拉瓜等地震造成的灾难和经济损失。将古地震学引…     

Mercury levels in coral reefs along the Caribbean coast of Central America

Sediment and coral skeleton samples from 23 coral reefs along the Caribbean coast of Costa Rica and Panama (1497 km) were evaluated for total mercury (Hg). High levels of pollution were found in the entire region with averages of 18.9 and 71.3 ppb in coral skeletons and sediments respectively. Significantly higher contamination was found in Panamanian corals (21.4 ppb) while compared to Costa Rican reef sediments (85.9 ppb). Hg from several processes and non-point sources (e.g., erosion, runoff, flooding, mining, overuse of agrochemicals, industrial waste, ports, and refineries) may have affected the entire region. The widespread observed distribution suggests that Hg is being carried along long distances within the region due to its high concentrations found in “pristine” reefs. Forest burning and colonial mining residues may be considered as possible contamination factors.     

North American microtektites from the Caribbean Sea and their fission track age

Over 6000 microscopic glass spherules between 125 μm and 1 mm in diameter were found in a sediment core (RC9-58) from the Caribbean Sea. These glassy objects are mostly confined to a zone ～ 40 cm thick at a depth of ～ 250 cm. We believe that the microscopic glass objects are microtektites belonging to the North American strewnfield, based on their geographical location, appearance, physical properties, stratigraphic age (middle Upper Eocene), fission track age (～34.6 my) and major element compositions. The occurrence of North American microtektites in the Caribbean Sea indicates that the North American strewnfield is two to three times larger than previously indicated. An estimate on the abundance of microtektites in core RC9-58 indicates that the North American strewnfield may contain greater than 10¹⁷ g of tektite material.     

The isotopic composition of strontium in Central American ignimbrites

Voluminous sheets of rhyolitic ignimbrites were crupted during Miocene time in a region of Central America that is underlain by a thick sequence of middle Paleozoic and older metamorphic and plutonic rocks. Strontium isotopic ratios of fifteen ignimbrites range from 0.7035 to as high as 0.7175. These values are markedly higher than those measured for cale-alkaline lavas of the same province, but overlap the range found in basement rocks that may have served as source rocks for anateetic magmas. This relationship is in contrast to that found in the western United States where siliceous ignimbrites are not significantly richer in radiogenic strontium than are the basalt erupted through the same basement series. Several possible models for the origin of the large volumes of siliceous magma are examined in terms of major-element and isotopic relations, experimental studies of phase relations, and the thermal requirements of melting or assimilating basement rocks. A mathematical model for the effects of assimilation in open and closed systems permits a comparison of predicted chemical and isotopic compositions with those observed and places limits on the plausibility of various schemes of contamination with or without concurrent crystal fractionation. None of the models is without its flaws. Recent suggestions that large volumes of siliceous magma may be derived from the mantle or lower crust explain certain aspects of the Central American ignimbrites very well if one postulates that the high strontium ratios resulted from contamination of the magma with radiogenic strontium released by the break-down of mieas in basement rocks through which the magmas rose. Such a model fails to explain the apparent restriction of large rhyolitic ignimbrite cruptions to areas underlain by thick continental crust.     

Magnitude scale for the Central American tsunamis

Based on the tsunami data in the Central American region, the regional characteristic of tsunami magnitude scales is discussed in relation to earthquake magnitudes during the period from 1900 to 1993. Tsunami magnitudes on the Imamura-Iida scale of the 1985 Mexico and 1992 Nicaragua tsunamis are determined to bem=2.5, judging from the tsunami height-distance diagram. The magnitude values of the Central American tsunamis are relatively small compared to earthquakes with similar size in other regions. However, there are a few large tsunamis generated by low-frequency earthquakes such as the 1992 Nicaragua earthquake. Inundation heights of these unusual tsunamis are about 10 times higher than those of normal tsunamis for the same earthquake magnitude (M _s =6.9–7.2). The Central American tsunamis having magnitudem>1 have been observed by the Japanese tide stations, but the effect of directivity toward Japan is very small compared to that of the South American tsunamis.     

Tracer hydrology of the data-scarce and heterogeneous Central American Isthmus

Numerous socio-economic activities depend on the seasonal rainfall and groundwater recharge cycle across the Central American Isthmus. Population growth and unregulated land use changes resulted in extensive surface water pollution and a large dependency on groundwater resources. This work combines stable isotope variations in rainfall, surface water, and groundwater of Costa Rica, Nicaragua, El Salvador, and Honduras to develop a regionalized rainfall isoscape, isotopic lapse rates, spatial–temporal isotopic variations, and air mass back trajectories determining potential mean recharge elevations, moisture circulation patterns, and surface water–groundwater interactions. Intra-seasonal rainfall modes resulted in two isotopically depleted incursions (W-shaped isotopic pattern) during the wet season and two enriched pulses during the mid-summer drought and the months of the strongest trade winds. Notable isotopic sub-cloud fractionation and near-surface secondary evaporation were identified as common denominators within the Central American Dry Corridor. Groundwater and surface water isotope ratios depicted the strong orographic separation into the Caribbean and Pacific domains, mainly induced by the governing moisture transport from the Caribbean Sea, complex rainfall producing systems across the N-S mountain range, and the subsequent mixing with local evapotranspiration, and, to a lesser degree, the eastern Pacific Ocean fluxes. Groundwater recharge was characterized by (a) depleted recharge in highland areas (72.3%), (b) rapid recharge via preferential flow paths (13.1%), and enriched recharge due to near-surface secondary fractionation (14.6%). Median recharge elevation ranged from 1,104 to 1,979 m a.s.l. These results are intended to enhance forest conservation practices, inform water protection regulations, and facilitate water security and sustainability planning in the Central American Isthmus.     

Cl,F, and SO2 in Central American volcanic gases

The Cl, F, SO₂ contents and Cl/F and Cl/SO₄ ratios in Central American volcanic gases are examined. 10³?10⁵ tons SO₂ per day are given off during eruptions and 10² when a prominent vapor cloud persists between eruptive periods. Data regarding Cl and F and SO₄ from leachates, condensates, and incrustations are compared. Our data suggest circumpacific volcanoes are SO₂ poor relative to Cl and may be F poor although F is higher in basaltic Central American volcanoes than others.     

A gap in the North American Central Plains conductivity anomaly

The palaeotectonic models of the North American continent have been deeply influenced by the concept of a North American Central Plains conductivity anomaly (NACPCA) which was postulated as a result of large area, wide-spaced, array studies, using the Magnetic Deep Sounding (MDS) method.

A recent closely spaced magnetotelluric (MT) survey across this proposed anomaly near the Canadian-U.S. boundary by Jones and Savage (1986) failed to detect the NACPCA at the location suggested by the MDS. However, this survey did verify a conductivity anomaly discovered by Rankin and Kao (1979) and a new anomaly 75 km east of NACPCA. Our present study verifies this latter anomaly and quantitative results are presented. The striking isotropy in apparent resistivity does not prevent the interpretation of anomalous resistivity distributions. This is discussed in the text.

The failure of the MDS array studies to detect our anomaly is readily explainable by the wide station spacing; however, the failure of the MT survey to detect the NACPCA leads us to the conclusion that it may not be a continuous feature.     

山东中西部及邻近地区震源参数和场地响应的反演

利用山东数字地震台网10个地震台自2004年6月至2007年8月记录的数字波形资料,采用Atkinson（1992）方法反演了山东中西部及邻近地区的非弹性衰减,得到该地区Q值与频率的关系是Q（f）=382．2·f^0.443。运用Moya（2000）方法反演了10个台站的场地响应,得到了26个地震的震源参数,并对所得结果进行了初步讨论。     

Source of metals related to gold occurrences in Cameroon,Central African Belt

Suites of granitic and metamorphic rocks form a perfect geological environment in which to investigate the source of metals related to gold deposits. In the East Province of Cameroon, the source of metals-related gold(grade ～ 4.6 g/t) that occurs within metamorphic and granitic rocks remains ambiguous. The host rocks were subjected to XRF and ICP-MS whole-rock geochemistry and BSE/EDS mineral analyses to investigate the source(s) of metals related to gold in the Province. Petrographically, chalc...     

A strong-motion database from the Central American subduction zone

Subduction earthquakes along the Pacific Coast of Central America generate considerable seismic risk in the region. The quantification of the hazard due to these events requires the development of appropriate ground-motion prediction equations, for which purpose a database of recordings from subduction events in the region is indispensable. This paper describes the compilation of a comprehensive database of strong ground-motion recordings obtained during subduction-zone events in Central America, focusing on the region from 8 to 14° N and 83 to 92° W, including Guatemala, El Salvador, Nicaragua and Costa Rica. More than 400 accelerograms recorded by the networks operating across Central America during the last decades have been added to data collected by NORSAR in two regional projects for the reduction of natural disasters. The final database consists of 554 triaxial ground-motion recordings from events of moment magnitudes between 5.0 and 7.7, including 22 interface and 58 intraslab-type events for the time period 1976–2006. Although the database presented in this study is not sufficiently complete in terms of magnitude–distance distribution to serve as a basis for the derivation of predictive equations for interface and intraslab events in Central America, it considerably expands the Central American subduction data compiled in previous studies and used in early ground-motion modelling studies for subduction events in this region. Additionally, the compiled database will allow the assessment of the existing predictive models for subduction-type events in terms of their applicability for the Central American region, which is essential for an adequate estimation of the hazard due to subduction earthquakes in this region.     

华北中北部地区震源参数和场地响应的联合反演

利用遗传算法反演华北中北部地区27个地震震源谱的低频水平、拐角频率和25个台站的场地响应。具体方法是利用研究区的平均衰减模型对记录谱进行路径校正，然后假定每一个地震的ω^2模型，调整低频水平和拐角频率使所有台站场地响应的标准偏差最小，最后给出参与计算的每个台站的场地响应。结果表明，17个基岩台中11个台的场地响应在1～20Hz范围内接近1，6个基岩台的场地响应部分频段放大或缩小3倍以上。8个井下摆台站的场地响应形态相同，表现为低频放大，高频部分迅速衰减。地震矩与震级的关系为logM0=17．1 1．13ML，地震矩与震源半径的关系为logM0=19．4 0．0052r。     

Studies of volcanic ash from two recent Central American eruptions

The 1971 eruptions of Cerro Negro volcano in Nicaragua and Fuego volcano in Guatemala produced ash blankets with minimum volumes of 7 × 10⁷ m³ and 6 × 10⁷ m³, respectively. Seven new chemical analyses show that ash produced by both eruptions was basaltic and similar to previously — erupted lavas of both volcanoes. Both ash blankets were sampled areally and stratigraphically before they were affected by rain. Chemical analyses of soluble materials leached from these ashes show that near the end of both eruptions the concentrations of soluble materials increased by about an order of magnitude. These changes are believed to reflect changes in the composition of eruptive gases.     

Magnetic signatures related to orogenic gold mineralization,Central Lapland Greenstone Belt,Finland

A number of lode–gold occurrences are hosted by hydrothermally altered greenstones along the southern boundary of the Palaeoproterozoic Central Lapland Greenstone Belt. The hydrothermally altered and mineralised zones are related to a major thrust and shear zone system that extends much across northern Finland. Spatial correlation between mineralized zones, brittle structural features and chemical alteration was explored and identified from high-resolution aeromagnetic data, in combination with airborne electromagnetic and gamma-ray spectrometric data and coupled with petrophysical and palaeomagnetic studies. The most prominent magnetic, ductile signatures formed during the Svecofennian Orogeny (1900–1800 Ma), resulting in elastic, curved, continuous magnetic patterns. These elastic anomaly patterns were disturbed by tectonic stress from S–SW, resulting in parallel, regularly oriented fracture families and thrust faults normal to the main stress direction. According to aeromagnetic, palaeomagnetic and structural evidence, the thrust zone was active during the latest stage of the orogenic event, but was also reactivated at a later date. Airborne gamma-ray data reveals zones of potassic alteration in the ultramafic rock units in the vicinity of cross-sections of these two fault sets. Chemical and mineralogical changes during alteration and metamorphism strongly affected the mafic and ultramafic host rocks throughout the deformation zone. The strong potassium enrichment and coinciding destruction of magnetic minerals resulted in enhanced potassium concentration and reduction of magnetic anomaly amplitudes. Palaeomagnetic results indicate that the remanent magnetization for the altered ultramafic rocks along the thrust zone is of chemical origin (CRM) and was acquired at 1880–1840 Ma, which is presumed also to be the age of the chemical alteration related to gold mineralization.     

Vertical concentration profiles of lead in the Central Pacific at 15°N and 20°S

Concentrations of lead were measured in a surface transect and at two vertical profile stations (15°N and 20°S) in the Central Pacific. These measurements complement similar measurements made earlier in the North Pacific at 33°N and in the Northwest Atlantic at 34°N [1,2], as well as recent measurements of eolian lead input fluxes near each of these locations [3]. The new transect of surface water concentrations of lead corroborates previous measurements, which decrease from 13 ng/kg at 30°N to 4 ng/kg at 17°S in the Central Pacific [4]. This transect gradient is shown to overlie a similar geographic gradient of subsurface maximum concentrations of lead in the three Pacific vertical profile stations, decreasing from 14 ng/kg at 33°N to 11 ng/kg at 14°N to 2.5 ng/kg at 20°S. Lead concentrations at each of those locations exhibit maxima at 400 m, decreasing concentrations to 2500 m and approximately concentrations of 0.8–1.1 ng/kg below that depth. The subsurface maximum at the northwest Atlantic profile station (36 ng/kg at 34°N) is also congruent with surface water lead concentrations which decrease from 806 ng/kg to 32 ng/kg in an offshore transect from Rhode Island to 34°N, 66°W [5], and the shape of the Atlantic profile is congruent with those in the Pacific. There is a positive correlation between the magnitudes of eolian lead input fluxes and the magnitudes of the upper water maxima in lead concentration profiles at corresponding locations as follows: South Pacific easterlies 3 ng/cm² yr vs. 2.5 ng/kg; North Pacific easterlies 6 ng/cm² yr vs. 11 ng/kg; North Pacific westerlies 50 ng/cm² yr vs. 14 ng/kg; and North Atlantic westerlies 170 ng/cm² yr vs. 36 ng/kg.This relationship enables one to view the anthropogenic perturbations of the marine lead cycle on a global scale, since the industrial origin of eolian and seawater lead has been established by correlations between geographic patterns of industrial lead emissions to the atmosphere and isotopic ratios of industrial leads [3] and by geographic patterns of Pb/silicate-dust ratios and lead isotopic ratios in ocean surface waters [3–5]. These new data coupled with earlier biogeochemical data indicate that surface water concentrations of lead in the North Pacific and North Atlantic are now conservatively estimated to be 8 to 20-fold greater and those in the South Pacific are 2-fold greater than natural concentrations because of industrial emissions of lead to the atmosphere.     

Source and distribution of lead in the surface sediments from the South China Sea as derived from Pb isotopes

Rapid economic development in East Asian countries has inevitably resulted in environmental degradation in the surrounding seas, and concern for the environment and its protection against pollutants is increasing. Identification of sources of contaminants and evaluation of current environmental status are essential to environmental pollution management, but relatively little has been done in the South China Sea (SCS). In order to investigate the abundance, distribution, and sources of Pb within the SCS, stable Pb isotopes and their ratios were employed to assess the contamination status and to differentiate between natural and anthropogenic origins of Pb in the surface sediments. The total Pb concentrations in sediments varied from 4.18 to 58.7 mg kg⁻¹, with an average concentration of 23.6 ± 8.9 mg kg⁻¹. The observed Pb isotope ratios varied from 18.039 to 19.211 for ²⁰⁶Pb/²⁰⁴Pb, 15.228 to 16.080 for ²⁰⁷Pb/²⁰⁴Pb, 37.786 to 39.951 for ²⁰⁸Pb/²⁰⁴Pb, 1.176 to 1.235 for ²⁰⁶Pb/²⁰⁷Pb, and 2.468 to 2.521 for ²⁰⁸Pb/²⁰⁷Pb. The majority of these ratios are similar to those reported for natural detrital materials. Combined with Pb enrichment factor values, our results show that Pb found within most of the SCS sediments was mainly derived from natural sources, and that there was not significant Pb pollution from anthropogenic sources before 1998. Further studies are needed to reconstruct deposition history and for trend analysis.     

Site Response for the RSM Seismic Network and Source Parameters in the Central Apennines (Italy)

—?Thirty-three earthquakes which occurred in the Central Apennines (Italy) with Ml ranging from 2.4 to 3.7 have been spectrally analysed using digital recordings from twelve stations of the Rete Sismometrica Marchigiana (RSM) network. Data corrected for geometrical spreading and quality factor Q have been inverted by means of the Generalised Inversion Technique. Site responses have been compared with those obtained by H/V ratio. Site amplifications have been observed both at stations placed on Pleistocene sediments and at one station located at 1800?m altitude. Source parameters have been calculated by fitting the spectra with an automatic procedure adopting the ω² source model. The seismic moments range from 9.23?×?10¹⁹ to 4.28?×?10²¹ dyne-cm with an average M ₀ (S) to M ₀ (P) ratio of 1.13?±?0.38. The stress drops are generally low and they vary between 1.1 and 10.2?bar when estimated by using S source spectra, and between 0.5 and 7.1?bar when the P-source spectra are fitted. For the considered range of seismic moments we observe that the stress drop does not have significant dependence on event size.