Blowing in the wind: III. Accretion of dust rims by chondrule-sized particles in a turbulent protoplanetary nebula

The fabric of primitive meteorites is dominated by small but macroscopic particles—chondrules, refractory mineral inclusions (CAIs), metal grains, and their like. One interesting aspect of these particles is that they are often surrounded by well-attached rims of fine-grained dust which appear to have been “accreted” onto solid mineral cores. The rim thickness varies from one meteorite to another, but there seems to be a proportionality between the thickness of the rim and the size of the core. We make use of recently derived analytical expressions for absolute and relative velocities of chondrule-and-CAI-sized particles in a weakly turbulent nebula (Cuzzi and Hogan, 2003, paper I of this series) to assess the acquisition of fine-grained accretionary dust rims by particles in the chondrule-to-CAI size range. We compare these predictions with meteoritic observations, and show how the existence of fairly compact dust rims on chondrules and similar size objects can be easily understood within the turbulent nebula context. We estimate the time needed to accrete such rims to be in the 10²-10³ year range. More observations of the form of the correlation between rim and core diameter in dust-rimmed chondrules are needed in order to strongly constrain the environment and history of these objects.     

The distributions and ages of refractory objects in the solar nebula

Refractory objects such as Calcium, Aluminum-rich Inclusions, Amoeboid Olivine Aggregates, and crystalline silicates, are found in primitive bodies throughout our Solar System. It is believed that these objects formed in the hot, inner solar nebula and were redistributed during the mass and angular momentum transport that took place during its early evolution. The ages of these objects thus offer possible clues about the timing and duration of this transport. Here we study how the dynamics of these refractory objects in the evolving solar nebula affected the age distribution of the grains that were available to be incorporated into planetesimals throughout the Solar System. It is found that while the high temperatures and conditions needed to form these refractory objects may have persisted for millions of years, it is those objects that formed in the first 10⁵ years that dominate (make up over 90%) those that survive throughout most of the nebula. This is due to two effects: (1) the largest numbers of refractory grains are formed at this time period, as the disk is rapidly drained of mass during subsequent evolution and (2) the initially rapid spreading of the disk due to angular momentum transport helps preserve this early generation of grains as opposed to later generations. This implies that most refractory objects found in meteorites and comets formed in the first 10⁵ years after the nebula formed. As these objects contained live ²⁶Al, this constrains the time when short-lived radionuclides were introduced to the Solar System to no later than 10⁵ years after the nebula formed. Further, this implies that the t=0 as defined by meteoritic materials represents at most, the instant when the solar nebula finished accreting significant amounts of materials from its parent molecular cloud.     

The evolution of the water distribution in a viscous protoplanetary disk

Astronomical observations have shown that protoplanetary disks are dynamic objects through which mass is transported and accreted by the central star. This transport causes the disks to decrease in mass and cool over time, and such evolution is expected to have occurred in our own solar nebula. Age dating of meteorite constituents shows that their creation, evolution, and accumulation occupied several Myr, and over this time disk properties would evolve significantly. Moreover, on this timescale, solid particles decouple from the gas in the disk and their evolution follows a different path. It is in this context that we must understand how our own solar nebula evolved and what effects this evolution had on the primitive materials contained within it. Here we present a model which tracks how the distribution of water changes in an evolving disk as the water-bearing species experience condensation, accretion, transport, collisional destruction, and vaporization. Because solids are transported in a disk at different rates depending on their sizes, the motions will lead to water being concentrated in some regions of a disk and depleted in others. These enhancements and depletions are consistent with the conditions needed to explain some aspects of the chemistry of chondritic meteorites and formation of giant planets. The levels of concentration and depletion, as well as their locations, depend strongly on the combined effects of the gaseous disk evolution, the formation of rapidly migrating rubble, and the growth of immobile planetesimals. Understanding how these processes operate simultaneously is critical to developing our models for meteorite parent body formation in the Solar System and giant planet formation throughout the galaxy. We present examples of evolution under a range of plausible assumptions and demonstrate how the chemical evolution of the inner region of a protoplanetary disk is intimately connected to the physical processes which occur in the outer regions.     

Experiments on the photophoretic motion of chondrules and dust aggregates—Indications for the transport of matter in protoplanetary disks

In a set of 16 drop tower experiments the motion of sub-millimeter to millimeter-sized particles under microgravity was observed. Illumination by a halogen lamp induced acceleration of the particles due to photophoresis. Photophoresis on dust-free chondrules, on chondrules, glass spheres and metal spheres covered with SiC dust and on pure SiC dust aggregates was studied. This is the first time that photophoretic motion of millimeter-sized particles has been studied experimentally. The absolute values for the photophoretic force are consistent with theoretical expectations for spherical particles. The strength of the photophoretic force varies for chondrules, dust covered particles and pure dust from low to strong, respectively. The measurements support the idea that photophoresis in the early Solar System can be efficient to transport solid particles outward.     

Compound chondrule formation in the shock-wave heating model: Three-dimensional hydrodynamics simulation of the disruption of a partially-molten dust particle

We carried out three-dimensional hydrodynamics simulations of the disruption of a partially-molten dust particle exposed to high-speed gas flow to examine the compound chondrule formation due to mutual collisions between the fragments (fragment-collision model; [Miura, H., Yasuda, S., Nakamoto, T., 2008a. Icarus194, 811-821]).In the shock-wave heating model, which is one of the most plausible models for chondrule formation, the gas friction heats and melts the surface of the cm-sized dust particle (parent particle) and then the strong gas ram pressure causes the disruption of the molten surface layer. The hydrodynamics simulation shows details of the disruptive motion of the molten surface, production of many fragments and their trajectories parting from the parent particle, and mutual collisions among them. In our simulation, we identified 32 isolated fragments extracted from the parent particle. The size distribution of the fragments was similar to that obtained from the aerodynamic experiment in which a liquid layer was attached to a solid core and it was exposed to a gas flow. We detected 12 collisions between the fragments, which may result in the compound chondrule formation. We also analyzed the paths of all the fragments in detail and found the importance of the shadow effect in which a fragment extracted later blocks the gas flow toward a fragment extracted earlier. We examined the collision velocity and impact parameter of each collision and found that 11 collisions should result in coalescence. It means that the ratio of coalescent bodies to single bodies formed in this disruption of a parent particle is R_coa=11/(32-11)=0.52. We concluded that compound chondrule formation can occur just after the disruption of a cm-sized molten dust particle in shock-wave heating.     

Origin of three-dimensional shapes of chondrules: I. Hydrodynamics simulations of rotating droplet exposed to high-velocity rarefied gas flow

The origin of three-dimensional shapes of chondrules is an important information to identify their formation mechanism in the early solar nebula. The measurement of their shapes by using X-ray computed topography suggested that they are usually close to perfect spheres, however, some of them have rugby-ball-like (prolate) shapes [Tsuchiyama, A., Shigeyoshi, R., Kawabata, T., Nakano, T., Uesugi, K., Shirono, S., 2003. Lunar Planet. Sci. 34, 1271-1272]. We considered that the prolate shapes reflect the deformations of chondrule precursor dust particles when they are heated and melted in the high velocity gas flow. In order to reveal the origin of chondrule shapes, we carried out the three-dimensional hydrodynamics simulations of a rotating molten chondrule exposed to the gas flow in the framework of the shock-wave heating model for chondrule formation. We adopted the gas ram pressure acting on the chondrule surface of in a typical shock wave. Considering that the chondrule precursor dust particle has an irregular shape before melting, the ram pressure causes a net torque to rotate the particle. The estimated angular velocity is for the precursor radius of r₀=1 mm, though it has a different value depending on the irregularity of the shape. In addition, the rotation axis is likely to be perpendicular to the direction of the gas flow. Our calculations showed that the rotating molten chondrule elongates along the rotation axis, in contrast, shrinks perpendicularly to it. It is a prolate shape. The reason why the molten chondrule is deformed to a prolate shape was clearly discussed. Our study gives a complementary constraint for chondrule formation mechanisms, comparing with conventional chemical analyses and dynamic crystallization experiments that have mainly constrained the thermal evolutions of chondrules.     

Breakup of liquids by high velocity flow and size distribution of chondrules

As a new approach to understanding the chondrule formation process, we carried out aerodynamic experiments in which a liquid layer was attached to solid cores, and the breakup of this layer occurred by means of the interaction with a high-velocity gas flow. The size distribution of the dispersed droplets was investigated and compared with the size distributions of chondrules. Both distributions had an exponential form. Using the experimental results, the hydrodynamic pressure to produce the chondrule size distributions was estimated to be ∼ 10⁴ Pa.     

Fragment-collision model for compound chondrule formation: Estimation of collision probability

We propose a new scenario for compound chondrule formation named as “fragment-collision model,” in the framework of the shock-wave heating model. A molten cm-sized dust particle (parent) is disrupted in the high-velocity gas flow. The extracted fragments (ejectors) are scattered behind the parent and the mutual collisions between them will occur. We modeled the disruption event by analytic considerations in order to estimate the probability of the mutual collisions assuming that all ejectors have the same radius. In the typical case, the molten thin () layer of the parent surface will be stripped by the gas flow. The stripped layer is divided into about 200 molten ejectors (assuming that the radius of ejectors is 300 μm) and then they are blown away by the gas flow in a short period of time (). The stripped layer is leaving from the parent with the velocity of depending on the viscosity, and we assumed that the extracted ejectors have a random velocity Δv of the same order of magnitude. Using above values, we can estimate the number density of ejectors behind the parent as . These ejectors occupy ∼9% of the space behind the parent in volume. Considering that the collision rate (number of collisions per unit time experienced by an ejector) is given by Rcoll=σcollneΔv, where σcoll is the cross-section of collision [e.g., Gooding, J.K., Keil, K., 1981. Meteoritics 16, 17-43], we obtain by substituting above values. Since most collisions occur within the short duration () before the ejectors are blown away, we obtain the collision probability of Pcoll∼0.36, which is the probability of collisions experienced by an ejector in one disruption event. The estimated collision probability is about one order of magnitude larger than the observed fraction of compound chondrules. In addition, the model predictions are qualitatively consistent with other observational data (oxygen isotopic composition, textural types, and size ratios of constituents). Based on these results, we concluded that this new model can be one of the strongest candidates for the compound chondrule formation. It should be noted that all collisions do not necessarily lead to the compound chondrule formation. The formation efficiency and the future works which should be investigated in the forthcoming paper are also discussed.     

Shock-wave heating model for chondrule formation: Hydrodynamic simulation of molten droplets exposed to gas flows

Millimeter-sized, spherical silicate grains abundant in chondritic meteorites, which are called as chondrules, are considered to be a strong evidence of the melting event of the dust particles in the protoplanetary disk. One of the most plausible scenarios is that the chondrule precursor dust particles are heated and melt in the high-velocity gas flow (shock-wave heating model). We developed the non-linear, time-dependent, and three-dimensional hydrodynamic simulation code for analyzing the dynamics of molten droplets exposed to the gas flow. We confirmed that our simulation results showed a good agreement in a linear regime with the linear solution analytically derived by Sekyia et al. [Sekyia, M., Uesugi, M., Nakamoto, T., 2003. Prog. Theor. Phys. 109, 717-728]. We found that the non-linear terms in the hydrodynamical equations neglected by Sekiya et al. [Sekiya, M., Uesugi, M., Nakamoto, T., 2003. Prog. Theor. Phys. 109, 717-728] can cause the cavitation by producing negative pressure in the droplets. We discussed that the fragmentation through the cavitation is a new mechanism to determine the upper limit of chondrule sizes. We also succeeded to reproduce the fragmentation of droplets when the gas ram pressure is stronger than the effect of the surface tension. Finally, we compared the deformation of droplets in the shock-wave heating with the measured data of chondrules and suggested the importance of other effects to deform droplets, for example, the rotation of droplets. We believe that our new code is a very powerful tool to investigate the hydrodynamics of molten droplets in the framework of the shock-wave heating model and has many potentials to be applied to various problems.     

UV photolysis, organic molecules in young disks, and the origin of meteoritic amino acids

The origin of complex organic molecules such as amino acids and their precursors found in meteorites and comets is unknown. Previous studies have accounted for the complex organic inventory of the Solar System by aqueous chemistry on warm meteoritic parent bodies, or by accretion of organics formed in the interstellar medium. This paper proposes a third possibility: that complex organics were created in situ by ultraviolet light from nearby O/B stars irradiating ices already in the Sun’s protoplanetary disk. If the Sun was born in a dense cluster near UV-bright stars, the flux hitting the disk from external stars could be many orders of magnitude higher than that from the Sun alone. Such photolysis of ices in the laboratory can rapidly produce amino acid precursors and other complex organic molecules. I present a simple model coupling grain growth and UV exposure in a young circumstellar disk. It is shown that the production may be sufficient to create the Solar System’s entire complex organic inventory within 10⁶ yr. Subsequent aqueous alteration on meteoritic parent bodies is not ruled out.     

Size distributions of chondrules and dispersed droplets caused by liquid breakup: An application to shock wave conditions in the solar nebula

We present the results of an aerodynamic liquid dispersion experiment using initially molten silicate samples. We investigate the threshold of breakup and the size distribution of dispersed droplets. The breakup threshold is consistent with the previous experiments using water and a mixture of water and glycerol. Also, we confirm the previous results that the size distributions of dispersed droplets are represented by an exponential form and that the characteristic size of dispersed droplets is related to the dynamic pressure of high-velocity gas flow. The size distribution has a similar form to that of chondrules, though the experiment is not exactly corresponding to the shock heating models for chondrule formation that consider solid precursors which are molten by the shocks. The experimental results indicate that, if liquid chondrule-precursors were dispersed by high-velocity flow, the dynamic pressure of the flow is ∼10 kPa. A chondrule formation condition in a shock-wave heating model suggests that this pressure can be realized at the regions within ∼1 AU in the minimum solar-nebula mass models. However, if the nebula had a larger mass and gravitational instabilities occurred, this pressure may be realized in the spiral arms at 2-3 AU and chondrules may be formed in asteroid belt.     

The dynamics of Jupiter and Saturn in the gaseous protoplanetary disk

We study the possibility that the mutual interactions between Jupiter and Saturn prevented Type II migration from driving these planets much closer to the Sun. Our work extends previous results by Masset and Snellgrove [Masset, F., Snellgrove, M., 2001. Mon. Not. R. Astron. Soc. 320, L55-L59], by exploring a wider set of initial conditions and disk parameters, and by using a new hydrodynamical code that properly describes for the global viscous evolution of the disk. Initially both planets migrate towards the Sun, and Saturn's migration tends to be faster. As a consequence, they eventually end up locked in a mean motion resonance. If this happens in the 2:3 resonance, the resonant motion is particularly stable, and the gaps opened by the planets in the disk may overlap. This causes a drastic change in the torque balance for the two planets, which substantially slows down the planets' inward migration. If the gap overlap is substantial, planet migration may even be stopped or reversed. As the widths of the gaps depend on disk viscosity and scale height, this mechanism is particularly efficient in low viscosity, cool disks. The initial locking of the planets in the 2:3 resonance is a likely outcome if Saturn formed at the edge of Jupiter's gap, but also if Saturn initially migrated rapidly from further away. We also explore the possibility of trapping in other resonances, and the subsequent evolutions. We discuss the compatibility of our results with the initial conditions adopted in Tsiganis et al. [Tsiganis, K., Gomes, R., Morbidelli, A., Levison, H.F., 2005. Nature 435, 459-461] and Gomes et al. [Gomes, R., Levison, H.F., Tsiganis, K., Morbidelli, A., 2005. Nature 435, 466-469] to explain the current orbital architecture of the giant planets and the origin of the Late Heavy Bombardment of the Moon.     

Planetesimal formation by turbulent concentration

The formation of 1-1000 km diameter planetesimals from dust grains in a protoplanetary disk is a key step in planet formation. Conventional models for planetesimal formation involve pairwise sticking of dust grains, or the sedimentation of dust grains to a thin layer at the disk midplane followed by gravitational instability. Each of these mechanisms is likely to be frustrated if the disk is turbulent. Particles with stopping times comparable to the turnover time of the smallest eddies in a turbulent disk can become concentrated into dense clumps that may be the precursors of planetesimals. Such particles are roughly millimeter-sized for a typical protoplanetary disk. To survive to become planetesimals, clumps need to form in regions of low vorticity to avoid rotational breakup. In addition, clumps must have sufficient self gravity to avoid break up due to the ram pressure of the surrounding gas. Given these constraints, the rate of planetesimal formation can be estimated using a cascade model for the distribution of particle concentration and vorticity within eddies of various sizes in a turbulent disk. We estimate planetesimal formation rates and planetesimal diameters as a function of distance from a star for a range of protoplanetary disk parameters. For material with a solar composition, the dust-to-gas ratio is too low to allow efficient planetesimal formation, and most solid material will remain in small particles. Enhancement of the dust-to-gas ratio by 1-2 orders of magnitude, either vertically or radially, allows most solid material to be converted into planetesimals within the typical lifetime of a disk. Such dust-to-gas ratios may occur near the disk midplane as a result of vertical settling of short-lived clumps prior to clump breakup. Planetesimal formation rates are sensitive to the assumed size and rotational speed of the largest eddies in the disk, and formation rates increase substantially if the largest eddies rotate more slowly than the disk itself. Planetesimal formation becomes more efficient with increasing distance from the star unless the disk surface density profile has a slope of −1.5 or steeper as a function of distance. Planetesimal formation rates typically increase by an order-of-magnitude or more moving outward across the snow line for a solid surface density increase of a factor of 2. In all cases considered, the modal planetesimal size increases with roughly the square root of distance from the star. Typical modal diameters are 100 km and 400 km in the regions corresponding to the asteroid belt and Kuiper belt in the Solar System, respectively.     

The origin of non-porphyritic pyroxene chondrules in UOCs: Liquid solar nebula condensates?

A total of 56 non-porphyritic pyroxene and pyroxene/olivine micro-objects from different unequilibrated ordinary chondrites were selected for detailed studies to test the existing formation models. Our studies imply that the non-porphyritic objects represent quickly quenched liquids with each object reflecting a very complex and unique evolutionary history. Bulk major element analyses, obtained with EMPA and ASEM, as well as bulk lithophile trace element analyses, determined by LA-ICP-MS, resulted in unfractionated (solar-like) ratios of CaO/Al₂O₃, Yb/Ce as well as Sc/Yb in many of the studied objects and mostly unfractionated refractory lithophile trace element (RLTE) abundance patterns. These features support an origin by direct condensation from a gas of solar nebula composition. Full equilibrium condensation calculations show that it is theoretically possible that pyroxene-dominated non-porphyritic chondrules with flat REE patterns could have been formed as droplet liquid condensates directly from a nebular gas strongly depleted in olivine. Thus, it is possible to have enstatite as the stable liquidus phase in a 800 × Cl dust-enriched nebular gas at a ptot of 10⁻³ atm, if about 72% of the original Mg is removed (as forsterite?) from the system. Condensation of liquids from vapor (primary liquid condensation) could be considered as a possible formation process of the pyroxene-dominated non-porphyritic objects. This process can produce a large spectrum of chemical compositions, which always have unfractionated RLTE abundances. Late stage and subsolidus metasomatic events appear to have furthered the compositional diversity of chondrules and related objects by addition of moderately volatile and volatile elements to these objects by exchange reactions with the chondritic reservoir (e.g., V, Cr, Mn, FeO as well as K and Na). The strong fractionation displayed by the volatile lithophile elements could be indicative of a variable efficiency of metasomatic processes occurring during and/or after chondrule formation. Histories of individual objects differ in detail from each other and clearly indicate individual formation and subsequent processing.     

Two-dimensional transport of solids in viscous protoplanetary disks

Large-scale radial transport of solids appears to be a fundamental consequence of protoplanetary disk evolution based on the presence of high temperature minerals in comets and the outer regions of protoplanetary disks around other stars. Further, inward transport of solids from the outer regions of the solar nebula has been postulated to be the manner in which short-lived radionuclides were introduced to the terrestrial planet region and the cause of the variations in oxygen isotope ratios in the primitive materials. Here, both outward and inward transport of solids are investigated in the context of a two-dimensional, viscously evolving protoplanetary disk. The dynamics of solids are investigated to determine how they depend on particle size and the particular stage of protoplanetary disk evolution, corresponding to different rates of mass transport. It is found that the outward flows that arise around the disk midplane of a protoplanetary disk aid in the outward transport of solids up to the size of CAIs s and can increase the crystallinity fraction of silicate dust at 10 AU around a solar mass star to as much as ∼40% in the case of rapidly evolving disks, decreasing as the accretion rate onto the star slows. High velocity, inward flows along the disk surface aid in the rapid transport of solids from the outer disk to the inner disk, particularly for small dust. Despite the diffusion that occurs throughout the disk, the large-scale, meridonal flows associated with mass transport prevent complete homogenization of the disk, allowing compositional gradients to develop that vary in intensity for a timescale of one million of years. The variations in the rates and the preferred direction of radial transport with height above the disk midplane thus have important implications for the dynamics and chemical evolution of primitive materials.     

A liquid-supported condensation of major minerals in the solar nebula: Evidence from glasses in the Kaba (CV3) chondrite

Glasses, in the Kaba CV3 chondrite, occur as mesostasis in chondrules and aggregates and as inclusions in olivines, both confined or open and connected to the mesostasis. The inclusions in olivine and the glassy mesostasis of aggregates seem to have formed contemporaneously. The confined glass inclusions and open inclusions in olivine were formed during olivine growth and the mesostasis glass during olivine aggregation. All glasses have high trace element contents (10-20×CI) with unfractionated CI-normalized abundances of refractory trace elements. In contrast, V, Mn, Li, and Cr are depleted in all glasses with respect to the refractory trace elements, as is Rb in the glass inclusions in olivine but not in the mesostasis glass. This abundance pattern indicates vapor fractionation and a common condensation origin for both glasses. Glasses of confined glass inclusions in olivine have a SiAlCa-rich composition with a chondritic Ca/Al ratio. Glasses of open glass inclusions and mesostasis are poor in Ca and enriched in alkalis. However, Ca contents of olivines indicate crystallization from a Ca-rich melt of a composition similar to that of the glass inclusions. In addition, trace element abundances indicate that these glasses (liquids) probably had an original composition similar to that of the inclusion glass. They apparently lost Ca in exchange for alkalis in a metasomatic exchange reaction, presumably with the vapor. There is now growing evidence that liquids can indeed condense from a solar nebula gas, provided the gas/dust ratio is sufficiently low. In these regions with enhanced oxygen fugacity as compared to that of a nebula of solar composition, liquids (the glass precursor) probably played an important role in growing crystals from the vapor by liquid-phase epitaxy. The glasses appear to be the remnants of this thin liquid layer interface that supported the growth of olivine from the vapor following the Vapor-Liquid-Solid process. This liquid will have a refractory composition and will have trace element contents which are in equilibrium with the vapor, and, therefore, will not change much during the time of olivine growth. The composition of the liquid seems to be unconstrained by the phases it is in contact with. Samples of this liquid will be retained as glass inclusions in olivine. The glassy mesostasis could also be a sample of this liquid that got trapped in inter-crystal spaces. The mesostasis glass subsequently behaved as an open system and its Ca was exchanged—presumably with the vapor—for the alkali elements Na, K, and Rb. In contrast, glass inclusions in olivine were protected by the host, could not react, and thus preserved the original composition of this liquid.     

Concentration and sorting of chondrules and CAIs in the late Solar Nebula

The high concentration and sorting of chondrules, sub-mm sized spherules found in undifferentiated meteorites, is one of the great unsolved mysteries in planetology. Here we present a unifying explanation for these phenomena based on the assumption that chondrules were present when the Solar Nebula was optically thin but had a significant amount of gas. An immediate consequence is that chondrules feel a force known as photophoresis. Photophoresis is based on a temperature gradient over the surface of a particle resulting from absorption of radiation and non-uniform interaction with its gaseous environment. In comparison to well-known forces originating from starlight, i.e. radiation pressure, Poynting-Robertson drag, or the Yarkovski effect, photophoresis can be stronger by many orders of magnitude in gaseous environments. In the application discussed here photophoresis concentrates chondrules and CAIs, which are both found in chondrites, in the region of the asteroid belt. Chondrules from any place in the Solar Nebula will be dragged to the asteroid belt region, while smaller dust particles and their aggregates will be removed from this region at the same time. This leads to a high relative concentration of chondrules, sorted with respect to their thermal conductivity, density, and size, for building chondrite parent bodies. Furthermore, photophoresis prevents CAIs from being lost to the Sun.     

A shock-wave heating model for chondrule formation II. Minimum size of chondrule precursors

Chondrule formation due to the shock wave heating of dust particles with a wide variety of shock properties are examined. We numerically simulate the steady postshock region in a framework of one-dimensional hydrodynamics, taking into account many of the physical and chemical processes that determine the properties of the region, especially nonequilibrium chemical reactions of gas species. We mainly focus on the dust particle shrinkage due to the evaporation in the postshock hot gas and the precursor size conditions for chondrule formation. We find that the small precursors whose radii are smaller than a critical value, , cannot form chondrules because they evaporate away completely in the postshock region. The minimum value of is about 10 μm, though it depends on the shock speed and the preshock gas density. Furthermore, we demonstrate the chondrule size distributions which are formed through the shock-wave heating. These results indicate that the shock-wave heating model can be regarded as a strong candidate for the mechanism of chondrule formation.     

Crystallization of cosmic dust from highly supersaturated silicate vapor in a rapidly cooled environment

Growth conditions and the resultant morphology of cosmic forsterite and enstatite particles condensed from the vapor were investigated experimentally as a function of growth temperature and supersaturation using flash-heating by CO₂ laser irradiation. Forsterite particles grew dominantly, followed by a few pyroxenes. No silica minerals were observed. The forsterite morphology changed systematically depending on the temperature (T) and the vapor supersaturation (σ). As the temperature decreased and the vapor supersaturation increased, the forsterite morphology changed from a bulky type (T=1000-1450 °C, σ<97) to a platy type (T=700-1000 °C, σ=97-161), then to a columnar needle shape (T=500-820 °C, σ=131-230), and finally to a droplet type (T<500 °C, σ>230). Very thin polygonal growth steps, which suggest vapor-solid (VS) growth, were detected on the surface of the faceted bulky and platy forsterite particles. Transmission electron microscopic (TEM) observation showed that the tip of the columnar and needle-shaped forsterite was covered with an amorphous layer. This amorphous coverage illustrates that a liquid phase can be condensed from the vapor, even under the stable conditions where crystalline forsterite is stable. This amorphous layer plays a role in the vapor-liquid-solid (VLS) mechanism of the forsterite particles. The difference in the growth mechanism as a function of vapor supersaturation and temperature can be explained by metastable liquid condensation. The experimentally synthesized coexisting patterns of VS-grown and VLS-grown olivine particles resemble the pattern of matrix olivine or chondrule rims in primitive meteorites. Forsterite can crystallize more easily than either pyroxene or silica minerals, which is consistent with the dominance of forsterite in cometary dust particles, as suggested by its infrared spectrum.