Ozone abundance on Mars from infrared heterodyne spectra: II. Validating photochemical models

Ozone is an important observable tracer of martian photochemistry, including odd hydrogen (HO_x) species important to the chemistry and stability of the martian atmosphere. Infrared heterodyne spectroscopy with spectral resolution ?¹⁰⁶ provides the only ground-based direct access to ozone absorption features in the martian atmosphere. Ozone abundances were measured with the Goddard Infrared Heterodyne Spectrometer and the Heterodyne Instrument for Planetary Wind and Composition at the NASA Infrared Telescope Facility on Mauna Kea, Hawai'i. Retrieved total ozone column abundances from various latitudes and orbital positions (LS=40°, 74°, 102°, 115°, 202°, 208°, 291°) are compared to those predicted by the first three-dimensional gas phase photochemical model of the martian atmosphere [Lefèvre, F., Lebonnois, S., Montmessin, F., Forget, F., 2004. J. Geophys. Res. 109, doi:10.1029/2004JE002268. E07004]. Observed and modeled ozone abundances show good agreement at all latitudes at perihelion orbital positions (LS=202°, 208°, 291°). Observed low-latitude ozone abundances are significantly higher than those predicted by the model at aphelion orbital positions (LS=40°, 74°, 115°). Heterogeneous loss of odd hydrogen onto water ice cloud particles would explain the discrepancy, as clouds are observed at low latitudes around aphelion on Mars.     

Multiple techniques for mineral identification on Mars:: a study of hydrothermal rocks as potential analogues for astrobiology sites on Mars

Spectroscopic studies of Mars analog materials combining multiple spectral ranges and techniques are necessary in order to obtain ground truth information for interpretation of rocks and soils on Mars. Two hydrothermal rocks from Yellowstone National Park, Wyoming, were characterized here because they contain minerals requiring water for formation and they provide a possible niche for some of the earliest organisms on Earth. If related rocks formed in hydrothermal sites on Mars, identification of these would be important for understanding the geology of the planet and potential habitability for life. XRD, thermal properties, VNIR, mid-IR, and Raman spectroscopy were employed to identify the mineralogy of the samples in this study. The rocks studied here include a travertine from Mammoth Formation that contains primarily calcite with some aragonite and gypsum and a siliceous sinter from Octopus Spring that contains a variety of poorly crystalline to amorphous silicate minerals. Calcite was detected readily in the travertine rock using any one of the techniques studied. The small amount of gypsum was uniquely identified using XRD, VNIR, and mid-IR, while the aragonite was uniquely identified using XRD and Raman. The siliceous sinter sample was more difficult to characterize using each of these techniques and a combination of all techniques was more useful than any single technique. Although XRD is the historical standard for mineral identification, it presents some challenges for remote investigations. Thermal properties are most useful for minerals with discrete thermal transitions. Raman spectroscopy is most effective for detecting polarized species such as CO₃, OH, and CH, and exhibits sharp bands for most highly crystalline minerals when abundant. Mid-IR spectroscopy is most useful in characterizing Si-O (and metal-O) bonds and also has the advantage that remote information about sample texture (e.g., particle size) can be determined. Mid-IR spectroscopy is also sensitive to structural OH, CO₃, and SO₄ bonds when abundant. VNIR spectroscopy is best for characterizing metal excitational bands and water, and is also a good technique for identification of structural OH, CO₃, SO₄, or CH bonds. Combining multiple techniques provides the most comprehensive information about mineralogy because of the different selection rules and particle size sensitivities, in addition to maximum coverage of excitational and vibrational bands at all wavelengths. This study of hydrothermal rocks from Yellowstone provides insights on how to combine information from multiple instruments to identify mineralogy and hence evidence of water on Mars.     

Ozone abundance on Mars from infrared heterodyne spectra: I. Acquisition, retrieval, and anticorrelation with water vapor

Observations of ozone on Mars were made using the Goddard Space Flight Center's Infrared Heterodyne Spectrometer and Heterodyne Instrument for Planetary Wind and Composition at the NASA Infrared Telescope Facility. Ozone is an important observable tracer of martian photochemistry. Infrared heterodyne spectroscopy with spectral resolution ?¹⁰⁶ is the only technique that directly measures ozone in the martian atmosphere from the surface of the Earth. Ozone column abundances down to the martian surface were acquired in seven data sets taken between 1988 and 2003 at various orbital positions (LS=40°, 74°, 102°, 115°, 202°, 208°, 291°). Ozone abundances are compared with those retrieved using ultraviolet techniques, showing good agreement. Odd hydrogen (HO_X) chemistry predicts anticorrelation of ozone and water vapor abundances. Retrieved ozone abundances consistently show anticorrelation with corresponding water vapor abundances, providing strong confirmation of odd hydrogen activity. Deviation from strict anticorrelation between the observed total column densities of ozone and water vapor suggests that constituent vertical distribution is an additional, significant factor.     

The dispersal of pyroclasts from Apollinaris Patera, Mars: Implications for the origin of the Medusae Fossae Formation

The Medusae Fossae Formation (MFF) has long been thought to be of Amazonian age, but recent studies propose that a significant part of its emplacement occurred in the Hesperian and that many of the Amazonian ages represent modification (erosional and redepositional) ages. On the basis of the new formational age, we assess the hypothesis that explosive eruptions from Apollinaris Patera might have been the source of the Medusae Fossae Formation. In order to assess the likelihood of this hypothesis, we examine stratigraphic relationships between Apollinaris Patera and the MFF and analyze the relief of the MFF using topographic data. We predict the areal distribution of tephra erupted from Apollinaris Patera using a Mars Global Circulation Model (GCM) combined with a semi-analytical explosive eruption model for Mars, and compare this with the distribution of the MFF. We conclude that Apollinaris Patera could have been responsible for the emplacement of the Medusae Fossae Formation.     

Desert methane: Implications for life detection on Mars

Methane, a potential biosignature, has recently been detected in the martian atmosphere. This Note focuses on field investigations/operational simulations and laboratory studies which resulted in successful detection of methane within arid terrestrial soils, as distinct from the usual methanogen environment, but in at least partial analogy to martian conditions.     

Possible long-term decline in impact rates: 1. Martian geological data

Quantin et al. [Quantin, C., Allemand, P., Mangold, N., Delacourt, C., 2004a. Icarus 172, 555-572] tabulated crater count data for 56 landslides along the walls of Valles Marineris. Under the assumption of a constant cratering rate after about 3 Gyr ago, as used in the 1999-2005 iterations of the crater chronology isochron system of Hartmann, and in the Hartmann and Neukum system, these data indicate a regularly increasing rate of landslides, which would be difficult to explain. We suggest that these data may support a decline in inner Solar System cratering rates by about a factor of 3 since 3 Gyr ago, not unlike predictions based on asteroid belt collision models. Such a decline is also supported by our review of data on lunar impact melts and glass spherules in a companion paper [Hartmann, W.K., Quantin, C., Mangold, N., 2007. Icarus 186, 11-23]. Such models produce not only a more uniform rate of landslides over the last 3 Gyr, but also a more uniform rate of resurfacing processes which also had an apparent increase under the assumption of a constant cratering rate.     

The jovian anticyclone BA: II. Circulation and interaction with the zonal jets

In this second part of our study of the large jovian anticyclone BA we present detailed measurements of its internal circulation and numerical models of its interaction with the zonal jets and nearby cyclonic regions. We characterized the flow using high-resolution observations obtained by the Cassini spacecraft in December 2000 (9 months after the genesis of BA as a result of the merger of two large White Ovals), by the ACS camera onboard HST in January 2005 and April 2006 and by the New Horizons spacecraft in February 2007. Cloud motions were derived from high-resolution images using an automatic correlator that provides a large sampling of the motions in images separated by short time intervals (30 min-2 h). The internal wind structure did not change when the oval changed its color reddening in late 2005-early 2006 and all four datasets from 2000 to 2007 consistently show a similar wind regime: an asymmetric intense anticyclonic vortex with faster winds in its Southern portion with mean speeds of 110 m/s and peak velocities of 135 m/s. These speeds are slightly higher than those measured in the three White Ovals predecessors of BA by the Voyagers [Mitchell, J.L., Beebe, R.F., Ingersoll, A.P., Garneau, G.W., 1981. J. Geophys. Res. 86, 8751-8757] and Galileo [Vasavada, A.R., and 13 colleagues, 1998. Icarus 135, 265-275] but not as much as it has been recently reported [Simon-Miller, A.A., Chanover, N.J., Orton, G.S., Sussman, M., Tsavaris, I.G., Karkoschka, E., 2006. Icarus 185, 558-562; Cheng, A.F., and 14 colleagues, 2008. Astronom. J. 135, 2446-2452]. The asymmetry of the velocities in the vortex is a consequence of the interaction of BA with the zonal circulation and emerges as a natural result in high-resolution simulations of the vortex dynamics using the EPIC model.     

The jovian anticyclone BA: III. Aerosol properties and color change

A study of the vertical cloud structure of oval BA and its red color change is presented in this third part of our complete analysis. A large interest in Jupiter’s anticyclone BA was created by its reddening that occurred between 2005 and 2006. In this work we quantify the color change in oval BA by using images taken with the Advanced Camera for Surveys (ACS) onboard the Hubble Space Telescope (HST) in six filters from the near ultraviolet (F250W) to the deep methane band in the near infrared (F892N). Reflectivity changes are noteworthy in nadir viewing geometry at the ultraviolet and blue wavelengths (F250W, F330W and F435W filters) but almost undetectable or inside error bars in the rest of filters (F550M, F658N and F892N). The observed reflectivity variations are discussed in terms of a commonly accepted vertical cloud structure model for jovian anticyclones in order to explore some causes for the color alteration. Our models of the observed reflectivity variation show that the vortex clouds did not change its vertical extension (top pressure) or its optical depth. We find that a change occurred in the absorbing properties of the particles populating the upper aerosols (single scattering albedo and imaginary refractive index). A discussion on the thermo-physical and dynamical properties of the vortex that could be in the origin of the color change is also presented.     

Interannual Variability of Martian Global Dust Storms: Simulations with a Low-Order Model of the General Circulation

We present simulations of the interannual variability of martian global dust storms (GDSs) with a simplified low-order model (LOM) of the general circulation. The simplified model allows one to conduct computationally fast long-term simulations of the martian climate system. The LOM is constructed by Galerkin projection of a 2D (zonally averaged) general circulation model (GCM) onto a truncated set of basis functions. The resulting LOM consists of 12 coupled nonlinear ordinary differential equations describing atmospheric dynamics and dust transport within the Hadley cell. The forcing of the model is described by simplified physics based on Newtonian cooling and Rayleigh friction. The atmosphere and surface are coupled: atmospheric heating depends on the dustiness of the atmosphere, and the surface dust source depends on the strength of the atmospheric winds. Parameters of the model are tuned to fit the output of the NASA AMES GCM and the fit is generally very good.Interannual variability of GDSs is possible in the LOM, but only when stochastic forcing is added to the model. The stochastic forcing could be provided by transient weather systems or some surface process such as redistribution of the sand particles in storm generating zones on the surface. The results are sensitive to the value of the saltation threshold, which hints at a possible feedback between saltation threshold and dust storm activity. According to this hypothesis, erodable material builds up as a result of a local process, whose effect is to lower the saltation threshold until a GDS occurs. The saltation threshold adjusts its value so that dust storms are barely able to occur.     

Rosetta-Alice observations of exospheric hydrogen and oxygen on Mars

The European Space Agency’s Rosetta spacecraft, en route to a 2014 encounter with comet 67P/Churyumov-Gerasimenko, made a gravity assist swing-by of Mars on 25 February 2007, closest approach being at 01:54 UT. The Alice instrument on board Rosetta, a lightweight far-ultraviolet imaging spectrograph optimized for in situ cometary spectroscopy in the 750-2000 Å spectral band, was used to study the daytime Mars upper atmosphere including emissions from exospheric hydrogen and oxygen. Offset pointing, obtained five hours before closest approach, enabled us to detect and map the H i Lyman-α and Lyman-β emissions from exospheric hydrogen out beyond 30,000 km from the planet’s center. These data are fit with a Chamberlain exospheric model from which we derive the hydrogen density at the 200 km exobase and the H escape flux. The results are comparable to those found from the Ultraviolet Spectrometer experiment on the Mariner 6 and 7 fly-bys of Mars in 1969. Atomic oxygen emission at 1304 Å is detected at altitudes of 400-1000 km above the limb during limb scans shortly after closest approach. However, the derived oxygen scale height is not consistent with recent models of oxygen escape based on the production of suprathermal oxygen atoms by the dissociative recombination of .     

Observations of martian gullies and constraints on potential formation mechanisms: II. The northern hemisphere

The formation process(es) responsible for creating the observed geologically recent gully features on Mars has remained the subject of intense debate since their discovery. We present new data and analysis of northern hemisphere gullies from Mars Global Surveyor data which is used to test the various proposed mechanisms of gully formation. We located 137 Mars Orbiter Camera (MOC) images in the northern hemisphere that contain clear evidence of gully landforms and analyzed these images in combination with Mars Orbiter Laser Altimeter (MOLA) and Thermal Emission Spectrometer (TES) data to provide quantitative measurements of numerous gully characteristics. Parameters we measured include apparent source depth and distribution, vertical and horizontal dimensions, slopes, orientations, and present-day characteristics that affect local ground temperatures. Northern hemisphere gullies are clustered in Arcadia Planitia, Tempe Terra, Acidalia Planitia, and Utopia Planitia. These gullies form in craters (84%), knobby terrain (4%), valleys (3%), other/unknown terrains (9%) and are found on all slope orientations although the majority of gullies are equator-facing. Most gullies (63%) are associated with competent rock strata, 26% are not associated with strata, and 11% are ambiguous. Assuming thermal conductivities derived from TES measurements as well as modeled surface temperatures, we find that 95% of the gully alcove bases with adequate data coverage lie at depths where subsurface temperatures are greater than 273 K and 5% of the alcove bases lie within the solid water regime. The average alcove length is 470 m and the average channel length is 690 m. Based on a comparison of measured gully features with predictions from the various models of gully formation, we find that models involving carbon dioxide, melting ground ice in the upper few meters of the soil, dry landslide, and surface snowmelt are the least likely to describe the formation of the martian gullies. Although some discrepancies still exist between prediction and observation, the shallow and deep aquifer models remain as the most plausible theories. Interior processes involving subsurface fluid sources are generally favored over exogenic processes such as wind and snowfall for explaining the origin of the martian gullies. These findings gleaned from the northern hemisphere data are in general agreement with analyses of gullies in the southern hemisphere [Heldmann, J.L., Mellon, M.T., 2004. Icarus 168, 285-304].     

Isotope fractionation in the photochemical escape of O from Mars

The production of energetic and escaping neutral O atoms at the current epoch in the martian thermosphere is thought to be dominated by the dissociative recombination process:

     

“Methane on Mars: A product of H2O photolysis in the presence of CO”: Response to V.A. Krasnopolsky

The detection of CH₄ in the martian atmosphere, at a mixing ratio of about 10 ppb, prompted Krasnopolsky et al. [Krasnopolsky, V.A., Maillard, J.P., Owen, T.C., 2004. Icarus 172, 537-547] and Krasnopolsky [Krasnopolsky, V.A., 2006. Icarus 180, 359-367] to propose that the CH₄ is of biogenic origin. Bar-Nun and Dimitrov [Bar-Nun, A., Dimitrov, V., 2006. Icarus 181, 320-322] proposed that CH₄ can be formed in the martian atmosphere by photolysis of H₂O in the presence of CO. We based our arguments on a clear demonstration that CH₄ is formed in our experiments, and on thermodynamic equilibrium calculations, which show that CH₄ formation is favored even in the presence of oxygen at a mixing ratio 1.3×¹⁰⁻³, as observed on Mars. In the present comment, Krasnopolsky [Krasnopolsky, V.A., 2007. Icarus, in press (this issue)] presents his arguments against the suggestion of Bar-Nun and Dimitrov [Bar-Nun, A., Dimitrov, V., 2006. Icarus 181, 320-322], based on the effect of O₂ on CH₄ formation, the absence of kinetic pathways for CH₄ formation and on the inadequacy of thermodynamic equilibrium calculations to describe the martian atmosphere. In this rebuttal we demonstrate that experiments with molecular oxygen at a ratio of O₂/CO₂=(8.9-17)×¹⁰⁻³, exceeding the martian ratio, still form CH₄. Thermodynamic equilibrium calculations replicate the experimental CH₄ mixing ratio to within a factor of 1.9 and demonstrate that CH₄ production is favored in the martian atmosphere, which is obviously not in thermodynamic equilibrium. Consequently, we do not find the presence of methane to be a sign of biological activity on Mars.     

Enhanced CO2 trapping in water ice via atmospheric deposition with relevance to Mars

It has been suggested that inclusions of CO₂ or CO₂ clathrate hydrates may comprise a portion of the polar deposits on Mars. Here we present results from an experimental study in which CO₂ molecules were trapped in water ice deposited from CO₂/H₂O atmospheres at temperatures relevant for the polar regions of Mars. Fourier-Transform Infrared spectroscopy was used to monitor the phase of the condensed ice, and temperature programmed desorption was used to quantify the ratio of species in the generated ice films. Our results show that when H₂O ice is deposited at 140-165 K, CO₂ is trapped in large quantities, greater than expected based on lower temperature studies in amorphous ice. The trapping occurs at pressures well below the condensation point for pure CO₂ ice, and therefore this mechanism may allow for CO₂ deposition at the poles during warmer periods. The amount of trapped CO₂ varied from 3% to 16% by mass at 160 K, depending on the substrate studied. Substrates studied were a tetrahydrofuran (C₄H₈O) base clathrate and Fe-montmorillonite clay, an analog for Mars soil. Experimental evidence indicates that the ice structures are likely CO₂ clathrate hydrates. These results have implications for the CO₂ content, overall composition, and density of the polar deposits on Mars.     

Spectral study of the Eunomia asteroid family : I. Eunomia

We present color ratio curves of the S-Asteroid 15 Eunomia, which have been extracted from high-precision photometric lightcurves obtained in three different VNIR wavelength bands at the Bochum Telescope, La Silla. The measured color ratio curves and near infrared spectra were used to derive a detailed surface composition model whose shape has been computed by V-lightcurve inversions. According to this analysis, the asteroid shows on one hemisphere a higher concentration of pyroxene, which causes an increased 440/700 nm and a reduced 940/700 nm reflectance ratio as well as a pronounced 2-μm absorption band. The remaining surface shows a higher concentration of olivine, leading to a reduced 440/700 nm and slightly increased 940/700 nm color ratio. In addition, we found that the maximum of the 440/700 nm color ratio curve coincide with the minimum of the 940/700 nm color ratio curve and vice versa. We demonstrate on the basis of USGS laboratory spectra that this anti-cyclical behavior can be explained by choosing Fe-rich olivine and a pyroxene with moderate Fe content as varying mineral phases. Furthermore, our observations confirm that 15 Eunomia is an irregular elongated and at least partially differentiated body. Previous spectral investigations of several smaller fragments of the Eunomia asteroid family revealed that the amount of fragments showing an increased pyroxene content exceeds the amount of pyroxene-poor fragments (Nathues, 2000, DLR Forschungsbericht, ISSN 1434-8454). This finding together with the observation that the major fraction of Eunomia's surface is enriched in olivine let us claim that a large fraction of the original pyroxene-enriched crust layer has been lost due to a major collision that created the Eunomia asteroid family. Significant spectral evidences, consistent with high concentrations of metals have been found neither in the rotational resolved spectra of 15 Eunomia nor in its fragments. This led to the conclusion that either no core consisting mainly of metals exists or that an eventual one has not been unearthed by the impact.     

Dust deposition at the Mars Pathfinder landing site: observations and modeling of visible/near-infrared spectra

Temporal variations in the visible/near-infrared reflectance spectra of the radiometric calibration targets on the Mars Pathfinder (MPF) lander obtained by the Imager for Mars Pathfinder (IMP) camera reveal the effects of aeolian dust deposition at the MPF site throughout the mission. Sky brightness models in combination with two-layer radiative transfer models were used with these data to track changes in dust opacity on the radiometric calibration targets (RCTs) to constrain the dust deposition rate and the spectral properties of the deposited dust. Two-layer models were run assuming both linear and nonlinear dust accumulation rates, and suggest that RCT dust optical depth at the end of the 83-sol mission was 0.08 to 0.16, or on the order of 5- to 10-μm thickness for plausible values for dust porosity and grain size. These values correspond to dust fall rates of about 20-45 μm per Earth year, consistent with previous studies of dust deposition on Mars. The single scattering albedos of the dust derived from the models fall between those previously determined for atmospheric dust and bright soils. Comparisons of relative reflectance spectra calibrated using observed RCT radiances from late in the mission versus using radiances from modeled (dust-free) RCTs also reveal distinct spectral differences consistent with dust on the RCTs. Temporal variations in RCT dust opacity are not clearly linked to known passages of vortices at the MPF site, but overall suggest that deposition of dust onto the targets by local dust devils may be favored over erosion. Analyses of temporal changes in visible/near-infrared spectra will provide valuable information for future missions by constraining how dust deposition affects landed spacecraft operability (e.g., solar power availability), instrument calibration, and interpretations of surface mineralogy and composition.     

Quantitative compositional analysis of martian mafic regions using the MEx/OMEGA reflectance data: 2. Petrological implications

The primary objectives of this paper are to determine the modal mineralogy of selected low albedo terrains of different ages ranging from Noachian to Amazonian exposed on the surface of Mars. This analysis is conducted using the spectral modeling of the Observatoire pour la Minéralogie, l'Eau, les Glaces, et l'Activité (OMEGA) reflectance data. Results from this work are consistent with the major results of previous spectroscopic studies: plagioclase (40-60% in volume) and high calcium pyroxene (20-40%, HCP) are the dominant minerals of the most regions. Low calcium pyroxene (10-15%, LCP) and minor amounts of olivine are also present. The oldest terrains are characterized by the largest amount of LCP and the lowest concentration of plagioclase. These overall compositions are consistent with two-pyroxene basalts. The particle sizes are in the range of a few hundreds of micrometers, which is in good agreement with the thermal inertia of the martian low albedo regions. In the region around the Nili Fossae, localized concentrations of olivine up to 40% with millimeter particle size similar to picritic basalts observed in situ by the Spirit rover in the Gusev crater are inferred. Chemical compositions are calculated for the first time from OMEGA spectra. They are quite consistent with Gusev rocks and shergottite compositions but they appear to be significantly SiO₂-poorer than Thermal Emission Spectrometer data. A decreasing low calcium pyroxene abundance with the decreasing age of the low albedo regions is reported. This may be indicative of decreasing degree of partial melting as thermal flux decreases with time. We propose that the ancient Noachian-aged, LCP-rich terrains could have been formed from H₂O-bearing melts. Then, dry, basaltic volcanism occurred leading to decreasing LCP abundance with time due to decreasing degree of partial melting. The olivine-bearing material modeled in Nili Fossae resembles the composition of ALH77005 and Chassigny meteorites consistent with prior studies. Implications on the formation of the basaltic Shergottites are discussed.     

Estimating the water content of hydrated minerals using reflectance spectroscopy: I. Effects of darkening agents and low-albedo materials

The apparent strength of absorptions due to H₂O near 1.9 and 3 μm in reflectance spectra is strongly affected by sample albedo. This study uses experimental and analytical approaches to quantify the effects of albedo on estimating the water content of hydrated minerals using various band parameters. We compare spectral band parameters for a series of low-albedo physical and numerical mixtures to measured water contents. Physical experiments consist of montmorillonite, clinoptilolite, and palagonite mixed with lesser amounts of carbon black and ilmenite, whereas numerical mixtures are composed of these host minerals mixed with a material of constant, low albedo. We find the effective single-particle absorption-thickness parameter provides the best correlation to water content, independent of composition and albedo, when derived from continuum-removed single scattering albedo spectra. Uncertainties in estimated water content are on the order of ±1 wt% using this method. The normalized optical path length parameter provides the best correlation to water content when using reflectance spectra, yielding estimates within ±1.6 wt% H₂O. The accuracy of these models is related to the physical nature of the darkening material. Scattering and absorption efficiencies are easier to model for intimate mixtures containing relatively large, dark grains than mixtures dominated by coatings of a fine-grained, strongly absorbing material. This suggests the physical properties that give rise to the albedo of a material are an important factor for accurate estimates of absolute water content.     

Mars CO2 cycle: Effects of airborne dust and polar cap ice emissivity

Mars General Circulation Model (GCM) simulations are presented to illustrate the importance of the ice emissivity of the seasonal CO₂ polar caps in regulating the effects of airborne dust on the martian CO₂ cycle. Simulated results show that atmospheric dust suppresses CO₂ condensation when the CO₂ ice emissivity is high but enhances it when the CO₂ ice emissivity is low. This raises the possibility that the reason for the repeatable nature of the CO₂ cycle in the presence of a highly variable dust cycle is that the CO₂ ice emissivity is “neutral” - the value that leads to no change in CO₂ condensation with changing atmospheric dust. For this GCM, the “neutral” emissivity is approximately 0.55, which is low compared to observed cap emissivities. This inconsistency poses a problem for this hypothesis. However, it is clear that the CO₂ ice emissivity is a critical physical parameter in determining how atmospheric dust affects the CO₂ cycle on Mars.