Assessing water quality using water quality index and multivariate analysis

Groundwater is increasingly gaining significance as the main solution to the water supply problems in Ghana, especially in the rural areas. This study was conducted to determine which factors play significant roles in the hydrochemistry of groundwater from the southern Voltaian formation. Conventional graphical and multivariate statistical methods were used. The study reveals three main factors controlling the hydrochemistry. Silicate mineral weathering and reverse cation exchange are the most important processes affecting the hydrochemistry of groundwater at this part of the formation. Interpolation maps created from factor scores suggest that these processes are the most pervasive, recording high scores almost everywhere in the study area. Carbonate mineral weathering is the second most important process in the hydrochemistry. This study finds that carbonate mineral weathering in the area is probably facilitated by carbonic acid rather than sulfuric acid. Chemicals from agricultural activities constitute the third most important process influencing groundwater quality in the area. Eighty samples were used to calculate water quality indices, WQI, which were in turn used to classify groundwater from the study area. Over 98% of the samples fall within the “Excellent” and “Good” categories, suggesting that groundwater from the southern Voltaian formation is generally acceptable for drinking purposes.     

Groundwater classification using multivariate statistical methods: Southern Ghana

This study demonstrates the strength of R-mode factor analysis and Q-mode hierarchical cluster analysis in determining spatial groundwater salinity groups in southeastern Ghana. Three hundred and eighty three (383) groundwater samples were taken from six hydrogeological terrains and surface water bodies and analyzed for the concentrations of the major ions, electrical conductivity and pH. Q-mode hierarchical cluster analysis and R-mode factor analysis were respectively used to spatially classify groundwater samples and determine the probable sources of variation in groundwater salinity. The quality of groundwater for irrigation was then determined using three major indices. The analyses revealed two major sources of variation in groundwater salinity: silicate mineral weathering on one hand, and seawater intrusion and anthropogenic contamination on the other. A plot of the factor scores for the two major sources of variation in the salinity revealed trends which can be used in hydrogeological mapping and assist in drilling potable water boreholes in southeastern Ghana. This study also revealed four major spatial groundwater groups: low salinity, acidic groundwaters which are mainly derived from the Birimian and Togo Series aquifers; low salinity, moderate to neutral pH groundwaters which draw membership mainly from samples of the Voltaian, Buem and Cape Coast granitoids; very high salinity waters which are not suitable for most domestic and irrigation purposes and are mainly from the Keta Basin aquifers; and intermediate salinity groundwaters consisting of groundwater from the Keta basin aquifers with minor contributions from the other major terrains. The major water type identified in this study is the Ca–Mg–HCO₃ type, which degrades into predominantly Na–Cl–SO₄ more saline groundwaters towards the coast.     

An assessment of the origin and variation of groundwater salinity in southeastern Ghana

Groundwater from the major aquifers in southeastern part of Ghana was sampled to determine the main controls on groundwater salinity in the area. This paper uses multivariate statistical methods, conventional graphical methods and stable isotope data to determine spatial relationships among groundwaters from the different hydrogeologic units in the area on the basis of salinity. Q-mode hierarchical cluster analysis (HCA) was used to spatially classify the samples, whilst R-mode factor analysis was used to reduce the dataset into two major principal components representing the sources of variation in the hydrochemistry. Analysis of the major chemical parameters suggests that the principal component responsible for salinity increment in the area is the weathering of minerals in the aquifers. This factor is especially more significant in the upland areas away from the coast. The second factor responsible for salinity in the area is the combined effects of seawater intrusion, and anthropogenic activities. This study finds that four major spatial groundwater groups exist in the area: low salinity, acidic groundwaters which are mainly derived from the Birimian and Togo Series aquifers; low salinity, moderate to neutral pH groundwaters which are mainly from the Voltaian, Buem and Cape Coast granitoids; very high salinity waters which are not suitable for most domestic and irrigation purposes and are mainly from the Keta aquifers; and intermediate salinity groundwaters comprising groundwater from the Keta basin aquifers with minor contributions from the other major terrains. The major water type identified in this study is the Ca–Mg–HCO₃ type, which degrades into predominantly Na–Cl–SO₄ more saline groundwaters toward the coast. Stable isotope data analyses suggest that groundwater in the Voltaian aquifers is largely of recent meteoric origin. The Birimian and Togo aquifers receive a component of recharge from the tributaries of the Densu and Volta Rivers, after the waters have undergone evaporative enrichment of the heavier isotopes. In the Keta basin, recharge is mainly from precipitation but an observed enrichment of ²H and ¹⁸O isotopes is probably due to seawater and evaporative effects since the water table there is very shallow. An analysis of the irrigation quality of groundwater from the six aquifers in the study area using sodium adsorption ratio and electrical conductivity suggests that most of the aquifers supply groundwater of acceptable quality for irrigation. The only exception is the Keta Basin area, where extremely high salinities and SAR values render groundwater from this basin unsuitable for irrigation purposes.     

Evaluation of geologic and geomorphologic influences on borehole productivity in crystalline bedrock aquifers of Limpopo Province, South Africa

Geologically complex crystalline aquifers underlie large parts of the semi-arid Limpopo Province where some of the greatest groundwater needs in South Africa occur. It is important to identify potentially high-yielding zones that can be targeted for water supply. The study covered four distinct geologic and morpho-structural domains within Limpopo Province, together covering about 23,500?km². Results from over 2,500 pumping test analyses indicate that bedrock type (e.g. pegmatite), lithological setting (e.g. aureole of granitoids), proximity and orientation of dykes and lineaments, topographic setting (e.g. slopes or valleys) and proximity of surface-water drainages may exert an influence on borehole productivity. No correlation between borehole productivity and weathering depth was found. Lineaments and dykes striking perpendicular to the current maximum horizontal stress seem to be more favourable targets, which is inconsistent with the predicted regime. Due to the complex geologic history, it is difficult to link open discontinuities to a distinct recent or past tectonic event. Regional stress-field data, as in this case, may not account for local, possibly highly significant, stress-field variations. The hydrogeologic importance of several factors related to groundwater occurrence, here presented, can be used as a working reference for future groundwater development programmes.     

Analysis of groundwater quality using water quality index and conventional graphical methods: the Volta region,Ghana

Conventional graphical and statistical methods were used with water quality indices to characterize the hydrochemistry of groundwater from the northern part of the Volta region of Ghana. The objective was to determine the processes that affect the hydrochemistry and the variation of these processes in space among the three main geological terrains: the Buem formation, Voltaian System and the Togo series that underlie the area, and to determine the suitability of groundwater from the area for drinking purposes. The Q-mode cluster analysis reveals three main water groups. The groups established from the Q-mode HCA appear to indicate different degrees of weathering which could further indicate varying levels of fracturing aquifer hydraulic properties. R-mode HCA and factor analysis (using varimax rotation and Kaiser Criterion) were then applied to determine the significant sources of variation in the hydrochemistry. This study finds that groundwater hydrochemistry in the area is controlled by the weathering of silicate and carbonate minerals, as well as the chemistry of infiltrating precipitation. Mineral activity diagrams for the CaO–Na₂O–Al₂O₃–SiO₂–H₂O and CaO–MgO–Al₂O₃–SiO₂–H₂O systems plotted for the area indicate stability in the smectite field and attribute hydrochemistry to the weathering of silicate minerals. Silicate mineral weathering and the effects of precipitation appear to be pervasive among all the three main geological terrains, whereas carbonate weathering is localized among the Voltaian aquifers. Cation exchange does not appear to play a significant role in the hydrochemistry but mild Water quality indices (WQI) were calculated for the samples using the concentrations of Na⁺, Ca²⁺, Mg²⁺, Cl⁻, NO₃ ⁻, F⁻, and EC at the various sample locations. The WQI values indicate that groundwater from the study area is of excellent quality for drinking purposes. WQI values from groundwater samples are averagely higher than samples taken from surface water sources in the area. This implies that geology has had an impact on the WQI of groundwater in the area.     

元宝山露天矿疏干优化设计

从影响元宝山露天矿地下水疏干的主要水文地质参数随机性特征分析入手,建立并求解了元宝山露天矿疏干工程优化设计的随机地下水管理模型,揭示了水文地质参数随机性对管理模型结果的影响,认为参数的随机性越大,管理结果越坏;置信水平越高,管理结果越坏,且渗透系数和边界条件对管理结果影响最大。      

Groundwater flow modeling and particle tracking for chemical transport in the southern Voltaian aquifers

Groundwater is the major source of water supply for most uses in the rural settlements in Ghana. A groundwater flow model was calibrated for some aquifers of the southern Voltaian sedimentary system under steady-state conditions. The objective was to determine estimates of the hydraulic conductivities of the different hydrostratigraphic units of the southern Voltaian, and the distribution of recharge from precipitation. Data on the stable isotopes of oxygen and hydrogen from the study area suggest that groundwater recharge in the area is from rainfall. The calibrated steady-state model suggests that aquifer hydraulic conductivities in the study area range from 1.19 to 6.3 m/day. Hydrostratigraphic unit specific hydraulic conductivities are discussed. The calibrated recharge ranges from 3.81e−05 m/day to 6.0e−04 m/day, which represents 0.9–6% of the precipitation in the form of rainfall. Six distinct flowpaths have been defined using particle tracking. The particle tracking simulation suggests travel times in the range of 380 to 5,199 years from recharge areas to discharge areas along the flowpaths identified. A contaminant dropped at the recharge areas in the central sections of the model area would travel at these rates along the flowpaths, assuming that advection is the dominant transport process. Inverse geochemical modeling indicates the dissolution of albite, K-feldspars and anorthite, respectively, along flowpaths I and IV. The inverse modeling along flowpaths I and IV suggest the dissolution of albite, K-feldspar and anorthite, respectively, at 1.085e−06, 3.16e−08 and 3.168e−07 mmol/year.     

Well productivity controlling factors in crystalline terrains of southeastern Brazil

Over the last decades, increasing water demands have fostered research to obtain high well yields in crystalline terrains where, besides the intrinsic properties of rocks, the groundwater flow depends on several factors. The depth of the wells, the lithotypes, the presence and thickness of sedimentary coverings and weathered layers, the landforms, the geological structures, and the effects of tectonic stresses are among the most investigated factors considered as determinant of well productivity. The influence of these factors on productivity of wells that exploit the Crystalline Aquifer System in the Jundiaí River Catchment, southeastern Brazil, is investigated in this work. The largest region of the studied area is located on the Precambrian Basement, partially covered by sedimentary deposits. The results show that the sedimentary deposits and the weathered layer are important for high well yield, but it also depends on the existence of a net of open fractures, in order to maintain high productivity. The sites that have more possibility of occurrence of such structures are the regional shear and fault zones and other minor structures with NW–SE and E–W directions, which characterize areas subjected to transtensional stress related to the neotectonics.     

Surficial geophysical deduction of the geomaterial and aquifer distributions at Ngor-Okpala local government area of Imo State, South Eastern Nigeria

Twenty seven vertical electrical sounding (VES) profiles surrounding four known traverses were obtained in Ngor-Okpala local government area of Imo state to examine the subsurface geomaterials and the associated groundwater potential. The VES data, constrained by borehole data, provided useful information about the subsurface hydrogeologic and lithologic conditions. From the validated interpretation, the area assessed has loamy soil, medium grained sands, well-sorted medium-grained/gravelly sands and river sand as the lithologic succession from top to the bottom of the depth penetrated. The aquifers in the area were found in the medium-grained sands and well-sorted medium-coarse-grained sands. The aquifer depth for all-season groundwater that would be devoid of draw-down can be found at a depth range of 42–50 m. The resistivity maps of selected depths exhibit sharp resistivity changes at depth due mainly to undulating subsurface topography. A map of the distribution of the kσ-values shows that good quality groundwater can be found in most parts of the area.     

Characterization of land subsidence induced by groundwater withdrawals in the plain of Beijing city,China

The plain of Beijing city in China suffers severe land subsidence owing to groundwater overdraft. The maximum subsidence rate could reach 6 cm/year through the 2000s. An integrated subsidence-monitoring program was designed, including levelling survey, borehole extensometers and multilayer monitoring of groundwater level, with the aim to understand both hydrological and mechanical processes and to characterize the land subsidence. From multilayer compaction monitoring, the major compression layers were identified. The major strata contributing to compression deformation are the second (64.5–82.3 m) and third (102–117 m) aquitards, which contributed around 39 % of the total subsidence. Meanwhile, irrecoverable deformations were also observed in the second (82.3–102 m) and third (117–148 m) confined aquifers; they exhibit elasto-plastic mechanical behavior, which is attributed to the thin beds of silt or silty clay. Stress–strain analysis and oedometer tests were conducted to study the aquifer-system response to pumping　and to estimate the specific storage of the major hydrogeologic units. The results reveal the creep behavior and elasto-plastic, visco-elasto-plastic mechanical behavior of the aquitards at different depths. The compressibility of the aquitards in the inelastic range is about one order of magnitude larger than for the elastic range.     

Sensitivity analysis for the GALDIT method based on the assessment of vulnerability to pollution in the northern Sfax coastal aquifer,Tunisia

Coastal aquifer of northern Sfax (Tunisia) suffers from the high risk to seawater intrusion and the water quality degradation due to the overexploitation. Hence, assessing the study area vulnerability to pollution is highly crucial so as to protect the groundwater resources. The assessment has been performed by applying the GALDIT method using Geographic Information System (GIS) software and multi-criteria evaluation techniques, and the sensitivity analysis approach to evaluate the effect of each GALDIT parameter on the vulnerability assessment. The GALDIT vulnerability map classifies the study area into three vulnerability classes: low vulnerability (30–50), moderate vulnerability (50–70), and high vulnerability (70–90), which represent 5, 30, and 65 % of the study area, respectively. The map illustrates that the coastal zones of the aquifer are the most threatened areas. The sensitivity analysis results show that the aquifer hydraulic conductivity (A) and the thickness of the aquifer (T) represent the determining factors in the modified vulnerability model. The real weight was used to elaborate the modified GALDIT model which was correlated with resistivity values for validation. This study could serve as a scientific basis for sustainable land planning and groundwater management in the study area.     

基于GMS的北京顺平地区三维地质结构模型

地下水数值模拟软件GMS提供了基于钻孔资料的三维地层生成模块,借助于GMS软件中地层模拟模块,利用钻孔数据、地层剖面资料、地质图和DEM数据,结合虚拟钻孔方法,构建了复杂地质结构区—北京顺平地区三维地层结构模型,模型包括太古宇密云群,长城系、蓟县系、青白口系、寒武系、奥陶系、石炭—二叠—侏罗系、深层第四系和浅层第四系等9组地层,刻画出了各层分布的空间范围,模拟了山区地表高程的起伏变化、断层产生的地层错动等情况,为研究区地质和水文地质条件分析及地下水数值模型的建立奠定了基础。     

Groundwater assessment in Salboni Block, West Bengal (India) using remote sensing, geographical information system and multi-criteria decision analysis techniques

An approach is presented for the evaluation of groundwater potential using remote sensing, geographic information system, geoelectrical, and multi-criteria decision analysis techniques. The approach divides the available hydrologic and hydrogeologic data into two groups, exogenous (hydrologic) and endogenous (subsurface). A case study in Salboni Block, West Bengal (India), uses six thematic layers of exogenous parameters and four thematic layers of endogenous parameters. These thematic layers and their features were assigned suitable weights which were normalized by analytic hierarchy process and eigenvector techniques. The layers were then integrated using ArcGIS software to generate two groundwater potential maps. The hydrologic parameters-based groundwater potential zone map indicated that the ‘good’ groundwater potential zone covers 27.14% of the area, the ‘moderate’ zone 45.33%, and the ‘poor’ zone 27.53%. A comparison of this map with the groundwater potential map based on subsurface parameters revealed that the hydrologic parameters-based map accurately delineates groundwater potential zones in about 59% of the area, and hence it is dependable to a certain extent. More than 80% of the study area has moderate-to-poor groundwater potential, which necessitates efficient groundwater management for long-term water security. Overall, the integrated technique is useful for the assessment of groundwater resources at a basin or sub-basin scale.     

Environmental applications of geophysical and geochemical methods to map groundwater quality at Tuticorin, Tamilnadu, India

Coastal aquifers can become polluted due to natural and human activities, such as intrusion of saline water, discharge of effluents in industrial areas and chemical weathering of natural geological deposits. The present study is aimed mainly at understanding the geophysical and chemical characteristics of groundwater near Tuticorin, Tamilnadu, India by studying the electrical resistivity distribution of the subsurface groundwater by applying the Schlumberger vertical electrical sounding (VES) technique followed by chemical analysis of water samples. A total of 20 VES soundings were carried out to understand the resistivity distribution of the area and 21 water samples were collected to analyze the chemical quality. The interpretation and analysis of the results have identified different hydrogeologic behaviors, a highly saline coastal aquifer and freshwater locations. The results obtained from geophysical and geochemical sampling are in good agreement with each other. The approach shows the efficacy of the combination of geophysical and geochemical methods to map groundwater contamination zones in the study area.     

Geoelectric resistivity sounding of riverside alluvial aquifer in an agricultural area at Buyeo,Geum River watershed,Korea: an application to groundwater contamination study

Twenty profiles of vertical electric soundings (VES) were obtained in a riverside alluvium at the Buyeo area, South Korea, to examine the variations of subsurface geology and associated groundwater chemistry. The combination of the VES data with the borehole data provided useful information on subsurface hydrogeologic conditions. The vestige of an ancient river channel (e.g. oxbow lake) was identified on the resistivity profiles by the lateral continuation of a near-surface perched aquifer parallel to the river. Such a perched aquifer is typically developed in the area with a clay-rich silty surface alluvium which prohibits the infiltration of oxygen. Therefore, groundwater below the oxbow lake shows a very low nitrate concentration and Eh values under the strong anoxic condition. The distribution of water resistivity is correlated with that of measured total dissolved solids concentration in groundwater, while the earth resistivity of the aquifer shows a significant spatial variation. It is interpreted that the earth resistivity of the aquifer is mainly controlled by the soil type rather than by the water chemistry in the study area.     

Vertical electrical sounding to delineate the potential aquifer zones for drinking water in Niamey city,Niger, Africa

Niger is a landlocked African country and the only source of surface water is the Niger River which flows in the western part of Niger and only few villages near to the river gets benefited from it, leaving most of the areas dependent on groundwater solely. The groundwater resources in Niger are mainly used for drinking, livestock and domestic needs. It can be observed that the water exploitation is minimal there due to several factors like undeveloped areas, less population, limited wells, rain-fed irrigation, etc. The delineation of potential aquifer zones is an important aspect for groundwater prospecting. Hence, the direct current (DC) resistivity soundings method also known as vertical electrical sounding (VES) is one of the most applied geophysical techniques for groundwater prospecting that was used in the capital city, Niamey of Niger. Twelve VES surveys, each of AB spacing 400 m were carried out in lateritic and granitic rock formations with a view to study the layer response and to delineate the potential zones. Potential aquifer zones were at shallow depth ranging from 10 to 25 m for the drilled borehole depth of 80–85 m in every village. Analysis of the result showed a good correlation between the acquired data and the lithologs.     

Controls on groundwater flow in the Bengal Basin of India and Bangladesh: regional modeling analysis

Groundwater for domestic and irrigation purposes is produced primarily from shallow parts of the Bengal Basin aquifer system (India and Bangladesh), which contains high concentrations of dissolved arsenic (exceeding worldwide drinking water standards), though deeper groundwater is generally low in arsenic. An essential first step for determining sustainable management of the deep groundwater resource is identification of hydrogeologic controls on flow and quantification of basin-scale groundwater flow patterns. Results from groundwater modeling, in which the Bengal Basin aquifer system is represented as a single aquifer with higher horizontal than vertical hydraulic conductivity, indicate that this anisotropy is the primary hydrogeologic control on the natural flowpath lengths. Despite extremely low hydraulic gradients due to minimal topographic relief, anisotropy implies large-scale (tens to hundreds of kilometers) flow at depth. Other hydrogeologic factors, including lateral and vertical changes in hydraulic conductivity, have minor effects on overall flow patterns. However, because natural hydraulic gradients are low, the impact of pumping on groundwater flow is overwhelming; modeling indicates that pumping has substantially changed the shallow groundwater budget and flowpaths from predevelopment conditions.     

Assessment of well design and sustainability in hard-rock formations in northern Ghana

Some of the main problems in well construction are associated with installation of casing, especially in the overburden. A total of 1,485 lined and open wells, drilled in the hard rocks of the Precambrian basement complex and Palaeozoic sedimentary (Voltaian) formations in northern Ghana were studied. Of these, 500 were directly monitored. It was observed that the surfaces within the production zones of open wells had weathered, leading to silting and reductions in depth and yield, posing physical water-quality challenges. Also, the average life span of the open wells is about 15 years. The fully lined wells, on the other hand, perform very well with time, lasting for over 40 years on average, with a more sustainable physical water quality over their life span. The comparative cost of constructing an open well was found to be about 26% less than that of a lined well due to less construction material requirements. Although open wells may be relatively cheaper than lined wells to construct in hard rocks, the life span is shorter and should not be encouraged for groundwater exploitation especially in community or rural water supply schemes.     

内蒙古翁牛特-库伦一带严重缺水区找水研究

翁牛特-库伦一带为西辽河平原周边的严重缺水区,区内地形、地貌及地质构造条件复杂,找水难度较大.在该区找水过程中充分利用了前人资料,综合研究区域水文地质条件及地下水的补径排规律,合理采用遥感、物探等各方面的新技术、新方法.主要寻找断层带脉状水、碳酸岩类裂隙溶洞水、古河道砂砾石松散岩类水等.通过两年的工作,为地方成井7眼,总涌水量达3464.91m³/d,缓解了部分地区的人畜饮用水紧张状况,起到了典型的示范作用.