The age of supergene manganese deposits in Katanga and its implications for the Neogene evolution of the African Great Lakes Region

Supergene manganese deposits commonly contain K-rich Mn oxides with tunnel structure, such as cryptomelane, which are suitable for radiometric dating using the ³⁹Ar–⁴⁰Ar method. In Africa, Mn deposits have been dated by this method for localities in western and southern parts of the continent, whereas only some preliminary data are available for Central Africa. Here we present new ³⁹Ar–⁴⁰Ar ages for Mn oxide samples of the Kisenge deposit, in southwestern Katanga, Democratic Republic of the Congo. The samples represent supergene Mn oxide deposits that formed at the expense of primary Paleoproterozoic rhodochrosite-dominated carbonate ores. Main phases of Mn oxide formation are dated at c. 10.5 Ma, 3.6 Ma and 2.6 Ma for a core that crosses a mineralized interval. The latter shows a decrease in age with increasing depth, recording downward penetration of a weathering front. Surface samples of the Kisenge deposits also record a ≥ c.19.2 Ma phase, as well as c. 15.7 Ma, 14.2 Ma and 13.6 Ma phases. The obtained ages correspond to distinct periods of paleosurface development and stability during the Mio-Pliocene in Katanga. Because Katanga is a key area bordered to the North by the Congo Basin and to the East by the East African Rift System, these ages also provide constraints for the geodynamic evolution of the entire region. For the Mio-Pliocene, the Kisenge deposits record ages that are not systematically found elsewhere in Africa, although the 10.5–11 Ma event corresponds to a roughly simultaneous event in the Kalahari Manganese Field, South Africa. The rest of the Katanga paleosurface record differs somewhat from records for other parts of Africa, for which older, Eocene ages have been obtained. This difference is most probably related to the specific regional geodynamic context: uplift of the East African Plateau, with associated erosion, and the opening of the East African Rift System at c. 25 Ma are events whose effects, in the study area, interfere with those of processes responsible for the development of continent-wide paleosurfaces.     

The Saharan Metacraton

This article introduces the name “Saharan Metacraton” to refer to the pre-Neoproterozoic––but sometimes highly remobilized during Neoproterozoic time––continental crust which occupies the north-central part of Africa and extends in the Saharan Desert in Egypt, Libya, Sudan, Chad and Niger and the Savannah belt in Sudan, Kenya, Uganda, Congo, Central African Republic and Cameroon. This poorly known tract of continental crust occupies 5,000,000 km² and extends from the Arabian-Nubian Shield in the east to the Tuareg Shield to the west and from the Congo craton in the south to the Phanerozoic cover of the northern margin of the African continent in southern Egypt and Libya. The term “metacraton” refers to a craton that has been remobilized during an orogenic event but is still recognizable dominantly through its rheological, geochronological and isotopic characteristics. Neoproterozoic remobilization of the Saharan Metacraton was in the forms of deformation, metamorphism, emplacement of igneous bodies, and probably local episodes of crust formation related to rifting and oceanic basin development. Relics of unaffected or only weakly remobilized old lithosphere are present as exemplified by the Archean to Paleoproterozoic charnockites and anorthosites of the Uweinat massif at the Sudanese/Egyptian/Libyan boarder. The article explains why the name “Saharan Metacraton” should be used, defines the boundaries of the metacraton, reviews geochronological and isotopic data as evidence for the presence of pre-Neoproterozoic continental crust, and discusses what happened to the Saharan Metacraton during the Neoproterozoic. A model combining collisional processes, lithospheric delamination, regional extension, and post-collisional dismembering by horizontal shearing is proposed.     

The Pelusium Line—a major transcontinental shear

The Pelusium Line, which was defined by Neev (1975) off the Mediterranean coast of Israel, is suggested to form a transcontinental arcuate shear which extends along the following three segments:

1. (A) from Anatolia along the eastern Mediterranean down to the eastern limit of the Nile Delta;

2. (B) across Africa down to the Niger Delta; and

3. (C) across the Mid-Atlantic Ridge along the equatorial fracture zones.

A “Central Plate”, composed of South and East Africa and the Arabian and Sinai subplates, has been left laterally shifted along the Pelusium Line relative to the Northwest African Plate.     

Supergene manganese ore records 75 Myr-long Campanian to Pleistocene geodynamic evolution and weathering history of the Central African Great Lakes Region – Tectonics drives,climate assists

The southeastern part of the Democratic Republic of the Congo locally hosts Proterozoic manganese deposits. The deposits of Kisenge-Kamata are the most significant, but manganese ores are also known to occur at Kasekelesa (former Katanga Province) and Mwene-Ditu (former Kasai Province). For the present study, cryptomelane-rich samples from these two localities were dated, using the ⁴⁰Ar/³⁹Ar step-heating method with a CO₂ laser probe. The ages obtained are within a range of c. 77 Myr to c. 2 Myr. Cryptomelane formation took place at c. 76.4 Ma, c. 59.6 Ma, c. 45 Ma, c. 35 Ma, c. 23.8 Ma, c. 15.4 Ma, and c. 13.3 Ma at Kasekelesa, and it occurred at c. 35 Ma, c. 22.4 Ma, c. 15 Ma, c. 5.5–7.2 Ma, c. 3.6 Ma, and c. 2.1–2.3 Ma at Mwene-Ditu. The Campanian age (c. 76.4 Ma) recorded at Kasekelesa is the oldest ⁴⁰Ar/³⁹Ar age that has up to now been recorded for Mn ores from Africa. It documents the formation of oxidized ore along a Campanian or older erosion surface, which could be part of the ‘African Erosion Surface’. The complete age record suggests that continent-wide tectonics accounts for most of the recognized supergene ore formation episodes, controlled by vertical lithospheric movements that are ultimately responsible for alternating stages of landscape stability and erosion. Tectonics is thus regarded as the first-order control for secondary ore formation in Central Africa, over the last 80 Myr. Climate is a second-order control, because sufficient water supply is needed for supergene enrichment, whereby climatic conditions are recognized to have been favourable during some relatively cold Late Mesozoic and Paleogene periods, as well as during some humid and warm Neogene stages.     

The “El Pilote” fluorite skarn: A crucial deposit in the understanding and interpretation of the origin and mobilization of F from northern Mexico deposits

Fluorite deposits are widespread in northern Mexico and those deposits have traditionally been categorized as exclusively hydrothermal–magmatic in origin. Recently, two different fluorite-bearing type models have been proposed for the Northern Mexican deposits: (1) MVT-like deposits formed from basinal brines mobilized during the Laramide Orogeny (La Encantada deposit, Gonzalez-Partida et al., [Gonzalez-Partida, E., Carrillo-Chavez, A., Grimmer, J.O.W., Pironon, J., 2002. Petroleum-rich fluid inclusions in fluorite, Purisima mine, Coahuila, Mexico. International Geological Review 44 (8), 751–763.]; Tritlla et al., [Tritlla, J., Gonzalez-Partida, E., Levresse, G., Banks, D., Pironon, J., 2004. Fluorite deposits at Encantada-Buenavista, Mexico: products of Mississippi Valley type processes — a reply. Ore Geology Reviews 25, 329–332.]); and (2) fluorite-bearing skarns in close contact with rhyolite intrusives (Levinson, [Levinson, A.A., 1962. Beryllium–fluorine mineralization at Aguachile Mountain, Coahuila, Mexico. American Mineralogist 47, 67–75.]). The El Pilote fluorite deposit falls into the second category, and is the only known example of a magmatic-related fluorite deposit in the area. The fluorite trace-element patterns from both the El Pilote skarn and La Encantada MVT deposits display comparable and very low relative abundances as well as comparable chondrite-normalized REE patterns; this would suggest that the skarn F-source comes from the remobilization of a MVT fluorite manto.     

The role of “excess” CO2 in the formation of trona deposits

The prevailing theory for the formation of trona [Na₃(CO₃)(HCO₃) · 2(H₂O)] relies on evaporative concentration of water produced by silicate hydrolysis of volcanic rock or volcaniclastic sediments. Given the abundance of closed drainage basins dominated by volcanics, it is puzzling that there are so few trona deposits and present-day lakes that would yield dominantly Na–CO₃ minerals upon evaporation. Groundwater in the San Bernardino Basin (southeastern Arizona, USA and northeastern Sonora, Mexico) would yield mainly Na–CO₃ minerals upon evaporation, but waters in the surrounding basins would not. Analysis of the chemical evolution of this groundwater shows that the critical difference from the surrounding basins is not lithology, but the injection of magmatic CO₂. Many major deposits of trona and Na–CO₃-type lakes appear to have had “excess” CO₂ input, either from magmatic sources or from the decay of organic matter. It is proposed that, along with the presence of volcanics, addition of “excess” CO₂ is an important pre-condition for the formation of trona deposits.     

5: Late Variscan mineralizing systems related to orogenic processes: The French Massif Central

The French Massif Central constitutes an exceptional study area due to the diversity of its metallic deposits, its internal position in the Variscan belt, and the abundance of available geological, geophysical and metallogenic data obtained within the GeoFrance 3D programme. The deposits, formed towards the end of the orogenic evolution, represent the economic products of two distinct mineralizing systems, a Au ± Sb hydrothermal system and a W ± Sn and rare-metals magmatic–hydrothermal system, which were simultaneously active during a short time span between ca. 310 and 300 Ma.Two types of gold deposit can be distinguished on the basis of their depth of emplacement: “deep-seated” gold deposits developed under lithostatic to hydrostatic pressure during rapid exhumation, and “shallow” gold deposits emplaced under hydrostatic pressure with no significant uplift.Deposits of W ± Sn and rare-metals were emplaced in the upper crust during final crystallization of specialized magmas after their rapid ascent, perhaps enhanced by simultaneous regional uplift. The gold-bearing systems are associated with a complex network of re-activated crustal-scale faults initially active during the period between 335 and 315 Ma. Normal motion along the faults, coeval with 335 to 315 Ma granite–migmatite domes, played a major role in the 3D distribution of the hydrothermal plumbing system. Gold and related metals were carried within huge hydrothermal cells, which reached ca. 100 km by 10 km in area, and 30 km in depth. In contrast, granites rich in magmatophile elements (W, Sn, rare-metals) generated smaller hydrothermal cells (10 km by 10 km in area, and < 6 km deep). Extraction of metals, by both deep-seated fluids and specialized magmas, occurred during granulitization of the lower crust at 300 ± 15 Ma. In the French Massif Central, the genesis of the two late Carboniferous mineralizing systems coincided with the end of syn-collisional extension and ended just before post-collisional extension.     

Tectonic Evolution of the Lufilian Arc (Central Africa Copper Belt) During Neoproterozoic Pan African Orogenesis

The Lufilian arc of Central Africa (also called Katangan belt or Copperbelt) is a zone of low to highgrade metasedimentary (and subsidiary igneous) rocks of Neoproterozoic age hosting highgrade CuCoU and PbZn mineralizations. The Lufilian arc is located between the Congo and Kalahari cratons and defines a structure which is convex to the north. Three major phases of deformation characterize the construction of the Lufilian arc. The first phase (D1) called the “Kolwezian phase” developed folds and thrust sheets with a northward transport direction. D1 deformation occurred in the Lufilian arc between ca. 800 and 710 Ma, with a peak in the range 790–750 Ma. It is here correlated with the main deformation in the Zambezi belt. Southward-verging folds with the same trends as the D₁ structures were previously linked to a second tectonic event named Kundelunguian phase of the Lufilian orogeny. We show in this paper that they are backfolds developed during D1 along Katangan ramps and especially along the Kibaran foreland. The second phase (D2) of the Lufilian orogeny is the “Monwezi phase” including several large leftlateral strikeslip faults which have been activated successively. During this deformation phase, the eastern block of the belt rotated clockwise, giving the present day NWSE trend of D1 structures in this part of the Lufilian arc, and generating its convex geometry. The Mwembeshi dislocation, the major transcurrent shear zone separating the Zambezi and Lufilian arc, was mostly active during the D2 deformation phase. D2 deformation occurred between ca. 690 and 540 Ma. Such a long time interval is attributed to the migration of strikeslip faults developed sequentially from south to north, and probably to a slow convergence velocity during the collision between the Congo and Kalahari cratons. The third phase (D3) of the Lufilian orogeny is a late event called the “Chilatembo phase”, marked by structures transverse to the trends of the Lufilian arc. This deformation and the post-D_2′ uppermost Kundelungu sequence (Ks3 Plateaux Group), are younger than 540 Ma and probably early Paleozoic.     

中非铜钴成矿带地质特征与找矿前景分析

[研究目的]横跨刚果(金)和赞比亚边境地区的中非铜钴成矿带是世界上著名的沉积岩层控型铜钴成矿带,是全球第三大铜产地和第一大钴产地,然而其成矿规律和成矿潜力仍不明朗.[研究方法]本文通过对中非铜钴成矿带地质背景、构造演化与成矿、矿床时空分布规律、矿床模型等方面的研究,选择地层、构造、地球化学、遥感蚀变等与成矿密切相关的地...     

Genesis of sediment-hosted stratiform copper–cobalt deposits, central African Copperbelt

The Neoproterozoic central African Copperbelt is one of the greatest sediment-hosted stratiform Cu–Co provinces in the world, totalling 140 Mt copper and 6 Mt cobalt and including several world-class deposits (10 Mt copper). The origin of Cu–Co mineralisation in this province remains speculative, with the debate centred around syngenetic–diagenetic and hydrothermal-diagenetic hypotheses.The regional distribution of metals indicates that most of the cobalt-rich copper deposits are hosted in dolomites and dolomitic shales forming allochthonous units exposed in Congo and known as Congolese facies of the Katangan sedimentary succession (average Co:Cu = 1:13). The highest Co:Cu ratio (up to 3:1) occurs in ore deposits located along the southern structural block of the Lufilian Arc. The predominantly siliciclastic Zambian facies, exposed in Zambia and in SE Congo, forms para-autochthonous sedimentary units hosting ore deposits characterized by lower a Co:Cu ratio (average 1:57). Transitional lithofacies in Zambia (e.g. Baluba, Mindola) and in Congo (e.g. Lubembe) indicate a gradual transition in the Katangan basin during the deposition of laterally correlative clastic and carbonate sedimentary rocks exposed in Zambia and in Congo, and are marked by Co:Cu ratios in the range 1:15.The main Cu–Co orebodies occur at the base of the Mines/Musoshi Subgroup, which is characterized by evaporitic intertidal–supratidal sedimentary rocks. All additional lenticular orebodies known in the upper part of the Mines/Musoshi Subgroup are hosted in similar sedimentary rocks, suggesting highly favourable conditions for the ore genesis in particular sedimentary environments. Pre-lithification sedimentary structures affecting disseminated sulphides indicate that metals were deposited before compaction and consolidation of the host sediment.The ore parageneses indicate several generations of sulphides marking syngenetic, early diagenetic and late diagenetic processes. Sulphur isotopic data on sulphides suggest the derivation of sulphur essentially from the bacterial reduction of seawater sulphates. The mineralizing brines were generated from sea water in sabkhas or hypersaline lagoons during the deposition of the host rocks. Changes of Eh–pH and salinity probably were critical for concentrating copper–cobalt and nickel mineralisation. Compressional tectonic and related metamorphic processes and supergene enrichment have played variable roles in the remobilisation and upgrading of the primary mineralisation.There is no evidence to support models assuming that metals originated from: (1) Katangan igneous rocks and related hydrothermal processes or; (2) leaching of red beds underlying the orebodies. The metal sources are pre-Katangan continental rocks, especially the Palaeoproterozoic low-grade porphyry copper deposits known in the Bangweulu block and subsidiary Cu–Co–Ni deposits/occurrences in the Archaean rocks of the Zimbabwe craton. These two sources contain low grade ore deposits portraying the peculiar metal association (Cu, Co, Ni, U, Cr, Au, Ag, PGE) recorded in the Katangan sediment-hosted ore deposits. Metals were transported into the basin dissolved in water.The stratiform deposits of Congo and Zambia display features indicating that syngenetic and early diagenetic processes controlled the formation of the Neoproterozoic Copperbelt of central Africa.     

A risky business: Mining, rent and the neoliberalization of “risk”

Natural resource investment in the mining sector is often mediated through conflicts over rent distribution between corporate capital and landowner states. Recent rounds of neoliberal policy promoted by the World Bank have highlighted the need for landowner states to offer incentives in order to attract “high risk” capital investment. In Sub-Saharan Africa, in particular, countries have been pushed to offer attractive fiscal terms to capital, thereby lowering the proportion traditionally called rent. This paper examines how the concept of “risk” has been mobilized to legitimate such skewed distributional arrangements. While certain conceptions of social and ecological “risk” have been prevalent in political and social theoretic discourse on mining, such focus elides the overwhelming contemporary power of our notion of “neoliberal risk” – or the financial/market risks – in actually setting the distributional terms of mineral investment. We illustrate our argument by examining the nexus of World Bank mining policy promotion and Tanzanian policy in the late 1990s meant to attract foreign direct investment in gold production. In closing, we suggest that just as “risk” is used to legitimate attractive fiscal terms for investment, recent events highlight how skewed distribution of benefits may set into motion risks that corporate capital had not bargained for.     

Porphyry copper deposits of the CIS and the models of their formation

Deposits of the “porphyry” family (essentially porphyry copper and gold-porphyry copper, gold-bearing porphyry molybdenum-copper, gold-containing porphyry copper-molybdenum and porphyry molybdenum deposits) are associated in time and space with granitoid magmatism mainly in Phaerozoic volcano-plutonic belts. Whatever their age, the deposits belong to two types of belts: basaltic belts, representing axial zones of island arcs, or andesitic belts formed within active continental (Andean-type) margins.The petrochemistry of ore-bearing magmatism related to the nature of the substratum of volcano-plutonic belts, reveals a number of essential characteristics, both in composition and zonation of wallrock alteration and ore mineralization. These characterisics enabled previous researchers to establish four models of porphyry copper deposits based on their lithologic associations, e.g., “diorite”, “granodiorite”, “monzonite” and “granite”.Pophyry copper deposits are thought to be the product of self-generating “two-fluid mixing” ore-magmatic systems. Porphyry intrusions are pathways for energy and metals from deep-seated magma chambers, of which the upper mineralized parts are accessible for observation. The relationship between magmatic fluids and meteoric water participating in the ore-forming processes (dependent on the structural-petrophysical conditions of formation), provide a subdivision for the porphyry copper ore-magmatic systems into three types: “open”, “closed” and “transitional”.Concurrently, a common trend in the evolution of the systems has been established, from a nearly autoclave regime of structural-and ore-forming processes to a gradual increase in the importance of hydrothermal recycling. The completeness of the OMS (ore-magmatic system) development according to this scheme, which determines the existence of various OMS types, depends on many factors, the most important being the depth of formation of porphyry intrusive bodies, the petrophysical peculiarities of the host rocks and the palaeohydrogeological conditions of ore deposition.Although rock fracturing (especially defluidization: second boiling) and contraction are caused by the same mechanisms, the stockwork growth in “open” and “closed” systems, relative to the wall rock, takes place in opposite directions, primarily due to different petrophysical parameters of the near-stock environment.In “open” systems structural and ore metasomatic processes are finalized. Fractures extend progressively from porhyry stocks into the marginal parts of the intrusive framework and extension of large-scale recycling of magmatic and activated meteoric water, in the same direction, result in the formation of ore-bearing stockworks. These are large in all dimensions, cover mainly hanging-wall zones and are characterized by clearly defined concentric mineral zoning and extensive geochemical haloes.In a “closed” OMS with centripetal growing fractures, hydrothermal convection is stunted. The vertical extension of recycling cells is restricted and the volume of meteoric water involved in circulation during the period of ore deposition is relatively small. As a result, relatively small intra-intrusive lenticular stockworks are developed which are characterized by close co-existence of several generations of mineralization with fragmentary preservation of the earliest ones. These are characterized by the elements of “reverse” zoning, increased density of the veinlets and metal content, as well as poorly developed hanging-wall dispersion haloes.     

Geochemistry and Tectonic Setting of Mafic Igneous Units in the Neoproterozoic Katangan Basin, Central Africa: Implications for Rodinia Break-up

Geochemical compositions of mafic igneous rocks in the Katangan basin in Central Africa (Democratic Republic of Congo, hereafter Congo, and Zambia) provide the basis for the geodynamic interpretation of the evolution of this Neoproterozoic basin located between the Congo and Kalahari cratons. The Katangan basin is subdivided into five major tectonic units: the Katangan Aulacogen, the External Fold and Thrust Belt, the Domes Region, the Synclinorial Belt and the Katangan High. The metamorphosed mafic igneous rocks investigated occur in the Katangan Aulacogen, the External Fold and Thrust Belt and the Domes Region. The earliest magmatic activity produced continental tholeiites emplaced on Paleoproterozoic crust during the early stages of intraplate break-up. This continental tholeiite magmatism was followed by an association of alkaline and tholeiitic basalts emplaced in the Katangan continental rift and then by tholeiitic basalts with E-MORB affinity marking a young oceanic crust. These volcanic associations mark different stages of evolution from pre-rift continental break-up up to a continental rift similar to the East African rift system and then to a Red Sea type incipient oceanic rift. A similar evolution occurs in the Damaran basin in southwestern Africa, although no pre-rift continental tholeiites have been recorded in this segment of the Pan-African belt system.     

Kimberlite-hosted diamond deposits of southern Africa: A review

Following the discovery of diamonds in river deposits in central South Africa in the mid nineteenth century, it was at Kimberley where the volcanic origin of diamonds was first recognized. These volcanic rocks, that were named “kimberlite”, were to become the corner stone of the economic and industrial development of southern Africa. Following the discoveries at Kimberley, even more valuable deposits were discovered in South Africa and Botswana in particular, but also in Lesotho, Swaziland and Zimbabwe.A century of study of kimberlites, and the diamonds and other mantle-derived rocks they contain, has furthered the understanding of the processes that occurred within the sub-continental lithosphere and in particular the formation of diamonds. The formation of kimberlite-hosted diamond deposits is a long-lived and complex series of processes that first involved the growth of diamonds in the mantle, and later their removal and transport to the earth's surface by kimberlite magmas. Dating of inclusions in diamonds showed that diamond growth occurred several times over geological time. Many diamonds are of Archaean age and many of these are peridotitic in character, but suites of younger Proterozoic diamonds have also been recognized in various southern African mines. These younger ages correspond with ages of major tectono-thermal events that are recognized in crustal rocks of the sub-continent. Most of these diamonds had eclogitic, websteritic or lherzolitic protoliths.In southern Africa, kimberlite eruptions occurred as discrete events several times during the geological record, including the Early and Middle Proterozoic, the Cambrian, the Permian, the Jurassic and the Cretaceous. Apart from the Early Proterozoic (Kuruman) kimberlites, all of the other events have produced deposits that have been mined. It should however be noted that only about 1% of the kimberlites that have been discovered have been successfully exploited.In this paper, 34 kimberlite mines are reviewed with regard to their geology, mantle xenolith, xenocryst and diamond characteristics and production statistics. These mines vary greatly in size, grade and diamond-value, as well as in the proportions and types of mantle mineral suites that they contain. They include some of the world's richest mines, such as Jwaneng in Botswana, to mines that are both small and marginal, such as the Frank Smith Mine in South Africa. They include large diatremes such as Orapa and small dykes such as those mined at Bellsbank, Swartruggens and near Theunissen. These mines are all located on the Archaean Kalahari Craton, and it is apparent that the craton and its associated sub-continental lithosphere played an important role in providing the right environment for diamond growth and for the formation of the kimberlite magmas that were to transport them to the surface.     

Formation of volcanogenic massive sulfide deposits: The Kuroko perspective

The main objective of this paper is to identify the geochemical, hydrological, igneous and tectonic processes that led to the variations in the physical (size, geometry) and chemical (mineralogy, metal ratios and zoning) characteristics of volcanogenic massive sulfide deposits with respect to space (from a scale of mining district size area to a global scale) and time (from a < 10 000 year time scale to a geologic time scale).All volcanogenic massive sulfide deposits (VMSDs) appear to have formed in extensional tectonic settings, such as at mid ocean spreading centers, backarc spreading centers, and intracontinental rifts (and failed rifts). All VMSDs appear to have formed in submarine depressions by seawater that became ore-forming fluids through interactions with the heated upper crustal rocks. Submarine depressions, especially those created by submarine caldera formation and/or by large-scale tectonic activities (e.g., rifting), become most favorable sites for the formation of large VMSDs because of hydrological, physical and chemical reasons.The fundamental processes leading to the formation of VMSDs include the following six processes:

1. (1) Intrusion of a heat source (typically a 10³ km size pluton) into an oceanic crust or a submarine continental crust causes deep convective circulation of seawater around the pluton. The radius of a circulation cell is typically 5 km. The temperature of fluids that discharge on the seafloor increases with time from the ambient temperature to a typical maximum of 350°C, and then decreases gradually to the ambient temperatures in a time scale of 100 to 10 000 years. The majority of sulfide and sulfate mineralization occurs during the waxing stage of hydrothermal activity.

2. (2) Reactions between low temperature (T < 150°C) country rocks with downward percolating seawater cause to precipitate seawater SO²⁻₄ as disseminated gypsum and anhydrite in the country rocks.

3. (3) Reactions of the “modified” seawater with higher-temperature rocks at depths during the waxing stage cause the transformation of the “seawater” to metal- and H₂S-rich ore-forming fluids. The metals and sulfide sulfur are leached from the county rocks; the previously formed gypsum and anhydrite are reduced by Fe²⁺-bearing minerals and organic matter, providing additional H₂S. The mass of high temperature rocks that provide the metals and reduced sulfur is typically 10¹¹ tons ( 40 km³ in volume). The roles of magmatic fluids or gases are minor in most massive sulfide systems, except for SO₂ to produce acid-type alteration in some systems.

4. (4) Reactions between the ore-forming fluids and cooler rocks in the discharge zone cause alteration of rocks and precipitation of some ore minerals in the stockwork ores.

5. (5) Mixing of the ore-forming fluids with local seawater within unconsolidated sediments and/or on the seafloor causes precipitation of “primitive ores” with the black ore mineralogy (sphalerite + galena + pyrite + barite + anhydrite).

6. (6) Reactions between the “primitive ores” with later and hotter hydrothermal fluids cause transformation of “primitive ores” to “matured ores” that are enriched in chalcopyrite and pyrite.

Variations in the mineralogical and elemental characteristics, the geometry, and the size of submarine hydrothermal deposits are controlled by the following four parameters:

1. (A) The chemical and physical characteristics of seawater (composition, temperature, density), which depend largely on the geographical settings (e.g., equatorial evaporating basins),

2. (B) The chemical and physical characteristics of the plumbing system (lithology, fractures),

3. (C) The thermal structure of the plumbing system, which is determined largely by the ambient geothermal gradient, and the size and temperature of the intrusive, and

4. (D) The physical characteristics of the seafloor (depth, basin topography).

For example, the submarine hydrothermal deposits developed in basaltic plumbing systems are generally poor in Pb and Ba compared to those developed in felsic plumbing systems. The lower temperature systems are generally poorer in sulfides, but richer in iron oxides and sulfates. The higher temperature and larger hydrothermal systems tend to produce chalcopyrite and pyrite rich ores. Contrasts in the metal ratios between the Noranda-type Archean VMSDs and the younger VMSDs reflect the differences in the geothermal gradient of the plumbing systems. The submarine hydrothermal deposits developed in the near equatorial regions tend to form large continuous bedded type ores because of the likeliness of creating large stratified basins.The basic processes of submarine hydrothermal mineralization have remained essentially the same throughout the geologic history, from at least 3.5 billion year ago to the present.     

Digging into Google Earth: An analysis of “Crisis in Darfur”

Google publicists have suggested the Crisis in Darfur is an example of the Google Earth software’s “success at tangibly impacting what is happening on the ground.” Yet whether or not Google Earth’s interface, along with a medley of other media representations of the conflict, have impacted events on the ground or led to coherent policies of humanitarian intervention remains open to debate. This article draws upon critical approaches from media studies—namely discourse analysis—to analyze several aspects of the Google Earth/USHMM Crisis in Darfur project. While this project was no doubt developed with the noble intention of generating international awareness about widespread violence that has recently occurred in the Darfur region, it is important to evaluate how representations of global conflicts are changing with uses of new information technologies and whether such representations can actually achieve their desired impacts or effects. The article begins with a discussion of the Crisis in Darfur project’s history, proceeds to analyze some of the press coverage of the project and then moves to a critique of the layer using four categories of analysis: (1) the shifting role of satellite image; (2) the temporality of the interface; (3) the practice of conflict branding; and (4) the practice of “information intervention.” Throughout the article, I explore how the presentation of Darfur-related materials through Google Earth reproduces problematic Western tropes of African tragedy and misses an opportunity to generate public literacy around satellite images. I also consider how humanitarianism is intertwined with digital and disaster capitalism, and suggest that this instance of “information intervention” makes patently clear that high visual capital alone cannot resolve global conflicts.     

Gem corundum deposits of Madagascar: A review

Madagascar is one of the most important gem-producing countries in the world, including ruby and sapphires. Gem corundum deposits formed at different stages in the geological evolution of the island and in contrasting environments. Four main settings are identified: (1) Gem corundum formed in the Precambrian basement within the Neoproterozoic terranes of southern Madagascar, and in the volcano-sedimentary series of Beforona, north of Antananarivo. In the south, high-temperature (700 to 800 °C) and low-pressure (4 to 5 kbar) granulites contain deposits formed during the Pan-African orogenesis between 565 and 490 Ma. They accompany mafic and ultramafic complexes (ruby deposits of the Vohibory group), skarns at the contact between Anosyan granites and the Proterozoic Tranomaro group (sapphire deposits of the Tranomaro–Andranondambo district), and shear-zone corridors cross-cutting feldspathic gneisses, cordieritites and clinopyroxenites in the Tranomaro, Vohimena and Androyan metamorphic series (biotite schist deposits of Sahambano and Zazafotsy, cordieritites of Iankaroka and Ambatomena). The circulation of fluids, especially along discontinuities, allowed in-situ alkaline metasomatism, forming corundum host rocks related to desilicified granites, biotitites, “sakenites” and “corundumites”. (2) Gem corundum also occurs in the Triassic detrital formations of the Isalo group, as giant palaeoplacers in the Ilakaka–Sakaraha area. Here, sapphires and rubies may come from the metamorphic granulitic terranes of southern Madagascar. (3) Gem corundum deposits occur within the Neogene-Quaternary alkali basalts from Ankaratra (Antsirabe–Antanifotsy area) and in the Ambohitra Province (Nosy Be, Ambato and Ambondromifehy districts). Primary deposits are rare, except at Soamiakatra where ruby in gabbroic and clinopyroxenite xenoliths within alkali-basalts probably derive from mantle garnet peridotites. The blue-green-yellow sapphires typical of basaltic fields are always recovered in palaeoplacer (in karst formed upon Jurassic limestones from the Montagne d'Ambre, Antsiranana Province) and alluvial and soil placers (Ankaratra volcanic massif). (4) Deposits occur within Quaternary eluvial, colluvial and alluvial concentrations, such as high-quality rubies from the Andilamena and Vatomandry deposits.     

The optical features and hydrocarbon-generating model of “barkinite” from Late Permian coals in South China

Leping coal is known for its high content of “barkinite”, which is a unique liptinite maceral apparently found only in the Late Permian coals of South China. “Barkinite” has previously identified as suberinite, but on the basis of further investigations, most coal petrologists conclude that “barkinite” is not suberinite, but a distinct maceral. The term “barkinite” was introduced by (State Bureau of Technical Supervision of the People's Republic of China, 1991, GB 12937-91 (in Chinese)), but it has not been recognized by ICCP and has not been accepted internationally.In this paper, elemental analyses (EA), pyrolysis-gas chromatography, Rock-Eval pyrolysis and optical techniques were used to study the optical features and the hydrocarbon-generating model of “barkinite”. The results show that “barkinite” with imbricate structure usually occurs in single or multiple layers or in a circular form, and no definite border exists between the cell walls and fillings, but there exist clear aperture among the cells.“Barkinite” is characterized by fluorescing in relatively high rank coals. At low maturity of 0.60–0.80%R_o, “barkinite” shows strong bright orange–yellow fluorescence, and the fluorescent colors of different cells are inhomogeneous in one sample. As vitrinite reflectance increases up to 0.90%R_o, “barkinite” also displays strong yellow or yellow–brown fluorescence; and most of “barkinite” lose fluorescence at the maturity of 1.20–1.30%R_o. However, most of suberinite types lose fluorescence at a vitrinite reflectance of 0.50% Ro, or at the stage of high volatile C bituminous coal. In particular, the cell walls of “barkinite” usually show red color, whereas the cell fillings show yellow color under transmitted light. This character is contrary to suberinite.“Barkinite” is also characterized by late generation of large amounts of liquid oil, which is different from the early generation of large amounts of liquid hydrocarbon. In addition, “barkinite” with high hydrocarbon generation potential, high elemental hydrogen, and low carbon content. The pyrolysis products of “barkinite” are dominated by aliphatic compounds, followed by low molecular-weight aromatic compounds (benzene, toluene, xylene and naphthalene), and a few isoprenoids. The pyrolysis hydrocarbons of “barkinite” are mostly composed of light oil (C₆–C₁₄) and wet gas (C₂–C₅), and that heavy oil (C₁₅⁺) and methane (C₁) are the minor hydrocarbon.In addition, suberinite is defined only as suberinized cell walls—it does not include the cell fillings, and the cell lumens were empty or filled by corpocollinites, which do not show any fluorescence. Whereas, “barkinite” not only includes the cell walls, but also includes the cell fillings, and the cell fillings show bright yellow fluorescence.Since the optical features and the hydrocarbon-generating model of “barkinite” are quite different from suberinite. We suggest that “barkinite” is a new type of maceral.     

Depths to density discontinuities beneath the Adamawa Plateau region, Central Africa, from spectral analyses of new and existing gravity data

New gravity data from the Adamawa Uplift region of Cameroon have been integrated with existing gravity data from central and western Africa to examine variations in crustal structure throughout the region. The new data reveal steep northeast-trending gradients in the Bouguer gravity anomalies that coincide with the Sanaga Fault Zone and the Foumban Shear Zone, both part of the Central African Shear Zone lying between the Adamawa Plateau and the Congo Craton. Four major density discontinuities in the lithosphere have been determined within the lithosphere beneath the Adamawa Uplift in central Cameroon using spectral analysis of gravity data: (1) 7–13 km; (2) 19–25 km; (3) 30–37 km; and (4) 75–149 km. The deepest density discontinuities determined at 75–149 km depth range agree with the presence of an anomalous low velocity upper mantle structure at these depths deduced from earlier teleseismic delay time studies and gravity forward modelling. The 30–37 km depths agree with the Moho depth of 33 km obtained from a seismic refraction experiment in the region. The intermediate depth of 20 km obtained within region D may correspond to shallower Moho depth beneath parts of the Benue and Yola Rifts where seismic refraction data indicate a crustal thickness of 23 km. The 19–20 km depths and 8–12 km depths estimated in boxes encompassing the Adamawa Plateau and Cameroon Volcanic Line may may correspond to mid-crustal density contrasts associated with volcanic intrusions, as these depths are less than depths of 25 and 13 km, respectively, in the stable Congo Craton to the south.     

Recognition of the regional lineaments of Iran: Using geospatial data and their implications for exploration of metallic ore deposits

The relationship between major structural lineaments and locations of ore deposits in Iran has been investigated using geospatial data. In the course of lineament extraction, satellite images, aeromagnetic data, digital elevation model (DEM) and structural maps were processed and the lineaments and large-scale faults were identified. The extracted lineaments, based on subjective assessment, from each dataset were imported into GIS software and the “lineament map of Iran” was prepared by data integration. The analysis for selecting significant lineament was mainly based on fault correlated lineament and lineament with field map fractures, which was sets as benchmarks for compiling a final output map. Four major regional lineament trends of N–S, E–W, NW–SE and NE–SW were identified in the data of all images, which are corresponded to the structural zones and the major fault systems of Iran. The mineral deposits (active and abandoned) and mineral indications database compiled are based on the published maps, papers, reports and the ore deposits data files of Geological Survey of Iran. Integrating the output of these two datasets by GIS software resulted in the “Combined Map of Lineaments and Gold, Copper, Lead, Zinc and Iron Deposits of Iran”. The number and distance of ore deposits toward the lineaments were processed by the counting and cumulative methods in the GIS software's. Approximately, over 90% of the ore deposits of Iran are located in the central part of the lineaments (15 km on each side) which are concordant with a definition of large lineament. About 50% of these mineral deposits are closer than 5 km to the lineaments. There are significant correlations between lineament density and intersections with ore deposits occurrences. The observed associations at this scale are informative in establishing exploration strategy and decreasing exploration risks for detailed work on ore deposit scale.