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2.
A comprehensive set of measurements of oxygen and hydrogen isotopic ratios in groundwaters as well as waters from rivers,
lakes, hot springs etc. taken from a variety of locations in India has been carried out for the first time. Isotopically the
most depleted samples occur in the high altitude precipitations in the Himalayas e.g. in the lakes of Bhutan and the source
water of the Ganga. The shallow groundwater data display a continental effect where the heavy isotope content decreases with
distance from the coast (about 4 to 6 per mil decrease in δ 18O per 1000 km). The δ D and δ 18O of these fresh waters are linearly related and an analysis of this relation vis-a-vis the meteoric water line shows the
unambiguous effect of enrichment due to evaporation from soils. 相似文献
3.
Post-orogenic mafic dikes are widespread across eastern Shandong Province, North China Craton, eastern China. We here report new U–Pb zircon ages and bulk-rock geochemical and Sr–Nd–Pb isotopic data for representative samples of these rocks. LA-ICP-MS U–Pb zircon analysis of two mafic dike samples yields consistent ages of 118.7 ± 0.25 million years and 122.4 ± 0.21 million years. These Mesozoic mafic dikes are characterized by high ( 87Sr/ 86Sr) i ranging from 0.7082 to 0.7087, low ? Nd( t) values from??17.0 to??17.5, 206Pb/ 204Pb from 17.14 to 17.18, 207Pb/ 204Pb from 15.44 to 15.55, and 208Pb/ 204Pb from 37.47 to 38.20. Our results suggest that the parental magmas of these dikes were derived from an ancient, enriched lithospheric mantle source that was metasomatized by foundered lower crustal eclogitic materials prior to magma generation. The mafic dikes underwent minor fractionation during ascent and negligible crustal contamination. Combined with previous studies, these findings provide additional evidence that intense lithospheric thinning beneath eastern Shandong occurred at ~120 Ma, and that this condition was caused by the removal/foundering of the lithospheric mantle and lower crust. 相似文献
4.
Mineralogy and Petrology - Chromite, ultramafic and mafic rocks from Eldivan, Yapraklı, Ayli Dağ, Küre, Elekdağ and Kızılırmak in northern Turkey have been... 相似文献
5.
Hypotheses for the origin of the Moon involve variants on capture, double-planet, and fission processes. Double-planet and fission hypotheses are examined in the light of siderophile trace elements. The siderophile trace elements chosen (W, Re, Mo, P, Ga, Ge) have well understood geochemical behavior such that appropriate metal/silicate partition coefficients are available and their abundances in the lunar and terrestrial mantles 4.4–4.5 × 10 9 years ago may be reasonably inferred. The fission hypothesis of Ringwood (1979) is not consistent with the behavior of Re, Mo, and P. The hybrid fission hypothesis of Wanke et al. (1983) overcomes many of the deficiencies of ringwood's hypothesis, but is not readily reconcilable with the behavior of Re and Ir. The double-planet hypothesis as most recently advanced by Newsom and Drake (1982, 1983) appears to be consistent with siderophile element behavior in the Moon. 相似文献
6.
研究区位于郯庐断裂南、北两段过渡带构造蜂腰部位,其内充填厚达7000m的古近纪火山-沉积岩系。本文选取火山岩最发育的沙河街组7口代表性钻井进行研究。结果表明,这些始新世火山岩主要为玄武质岩石和粗面质岩石,Si O_2含量为45.20%~59.55%,以碱性系列为主。玄武质岩石弱富集大离子亲石元素和Ti,不亏损Nb、Ta等高场强元素。粗面质岩石具有与玄武质岩石相似的地球化学特征,但Sr、P和Ti明显亏损。玄武质岩石的I_(Sr)=0.7033~0.7042、ε_(Nd)(t)=3.56~5.86,粗面质岩石的I_(Sr)=0.7035~0.7045、ε_(Nd)(t)=3.25~4.46,二者的Sr-Nd同位素组成一致,均与OIB相似。综合研究认为,始新世火山岩是弧后拉张环境下,曾遭受俯冲板片流体交代的地幔岩石部分熔融的产物。岩浆在岩浆房内分异演化形成了两种不同类型的岩石。郯庐断裂辽河段从中生代的板缘环境到古近纪陆内裂谷带,其控制因素可能来源于欧亚大陆板块和太平洋板块间的相互作用。在此过程中郯庐断裂系活化并发生大规模走滑运动,导致辽河裂谷盆地同期地幔来源的火山岩浆活动。 相似文献
7.
The Proterozoic Giles Complex, central Australia contains an almost complete range of anorthosite types from minor or major layers in gabbronorite intrusions to large anorthosite-troctolite bodies to small orthopyroxene anorthosite massifs; each type has a distinctive Sr isotopic signature. Anorthosite-dominated masses have a regular relationship between ferromagnesian mineralogy, initial 87Sr/ 86Sr and anorthite contents in plagioclase: anorthosite-troctolite bodies have significant olivine, relatively low initial 87Sr/ 86Sr (0.7038–0.7043) and An 50–69; orthopyroxene-dominant anorthosites have relatively high 87Sr/ 86Sr (0.7045–0.7063) and An 45−60. The pattern is found worldwide. Detailed study of one intrusion demonstrates that contamination by wall-rock granulite produces the higher 87Sr/ 86Sr values, anti-correlation between 87Sr/ 86Sr and An, and determines olivine/orthopyroxene proportions. Olivine-bearing anorthosites form from a primary aluminous tholeiite magma with plagioclase dominating the liquidus; progressive contamination of this parent magma produces a gradation to orthopyroxene anorthosites. 相似文献
8.
The combined chemical composition, B and Sr isotopes, and the basic geologic setting of geothermal systems from the Menderes Massif in western Turkey have been investigated to evaluate the origin of the dissolved constituents and mechanisms of water–rock interaction. Four types of thermal water are present: (1) a Na–Cl of marine origin; (2) a Na–HCO 3 type with high CO 2 content that is associated with metamorphic rocks of the Menderes Massif; (3) a Na–SO 4 type that is also associated with metamorphic rocks of the Menderes Massif with H 2S addition; and (4) a Ca–Mg–HCO 3–SO 4 type that results from interactions with carbonate rocks at shallow depths. The Na–Cl waters are further subdivided based on Br/Cl ratios. Water from the Cumalı Seferihisar and Bodrum Karaada systems are deep circulated seawater (Br/Cl=sea water) whereas water from Çanakkale–Tuzla (Br/Cl<sea water) are from dissolution of Messinian evaporites. Good correlations between different dissolved salts and temperature indicate that the chemical composition of the thermal waters from non-marine geothermal systems is controlled by: (1) temperature dependent water–rock interactions; (2) intensification of reactions due to high dissolved CO 2 and possibly HCl gasses; and (3) mixing with overlying cold groundwater. All of the thermal water is enriched in B. The B isotopic composition (δ 11B=2.3‰ to 18.7‰; n=6) can indicate either leaching of B from the rocks, or B(OH) 3 degassing flux from deep sources. The large ranges in B concentrations in different rock types as well as in thermal waters from different systems suggest the water-rock mechanism. 87Sr/ 86Sr ratios of the thermal water are used to differentiate between solutes that have interacted with metamorphic rocks ( 87Sr/ 86Sr ratio as high as 0.719479) and carbonate rocks (low 87Sr/ 86Sr ratio of 0.707864). 相似文献
9.
Combined hydrogeological and hydrogeochemical data allow flow systems and the origins of solutes in the Honeysuckle Creek area of the southeastern Murray Basin, which is an area affected by dryland salinity, to be constrained. Recharge occurs both on the uplands that are composed of fractured Violet Town Volcanic rocks and the Riverine Plain that comprises sediments of the Shepparton and Coonambidgal Formations. Groundwater from the Violet Town Volcanics has low salinity (<20 mmol/L Cl) and major ion geochemistry that is controlled largely by dissolution of silicate minerals. Low Cl/Br ratios (as low as 281 molar) suggest that this groundwater has not dissolved halite. Groundwater that recharged through the Riverine Plain sediments has higher Cl/Br ratios (up to 1146) and Cl concentrations of <20 mmol/L, consistent with it dissolving minor halite. Higher salinity (>20 mmol/L) groundwater has intermediate Cl/Br ratios (600–1000), which indicate that the high salinities do not simply result from halite dissolution. Rather, mixing of groundwater homogenises Cl/Br ratios, and evaporation as a consequence of a shallow water table is the dominant process that increases salinity. Oxygen and H isotopes also indicate that mixing and evaporation have occurred. These results indicate that land use over the whole region, not just the uplands, needs to be considered in any salinity management plans. Additionally future development of salinity is controlled by depth to the water table on the plains and the efficiency of recharge rather than by salt stores (halite or brines) in the unsaturated zone. 相似文献
10.
The Hegenshan ophiolite in Inner Mongolia is a remnant of oceanic lithosphere of probable Devonian age. The ophiolite consists of several blocks composed chiefly of serpentinized ultramafic rocks with lesser amounts of troctolite and gabbro, and sparse lavas and dikes. The ultramafic rocks consist chiefly of depleted harzburgite and minor dunite and are interpreted as mantle tectonites. In the Hegenshan block dunite is relatively abundant and is typically associated with podiform chromitite. Both the chromite ore and the residual chromites in this body are relatively aluminous with average Cr numbers of 44–54. A few small chromite bodies and some of the residual chromites have much higher Cr numbers (72–76). Several blocks have well-layered cumulate sequences of gabbro and troctolite. Sheeted dikes are absent but small mafic dikes are common in some of the ultramafic sections. Most of the mafic dikes have flat chondrite-normalized REE patterns and are strongly depleted in incompatible elements, similar to depleted tholeiites from immature island arcs. The basaltic lavas of the Hegenshan ophiolite have two distinctly different chemical signatures—one similar to the mafic dikes and one similar to ocean island basalts. The entire complex was probably formed within an island arc–marginal basin system that was later accreted to the southern margin of the Siberian Altaids. 相似文献
11.
Major and trace element and Rb-Sr isotope systematics of the Manaslu leucogranite, Central Nepal, have been examined to constrain the role of mineral fractionation and fluids in peraluminous granite petrogenesis. Biotite and tourmaline are, for the most part, mutually exclusive, with a predominance of two-mica leucogranites over tourmaline leucogranites. The 87Sr/ 86Sr initial isotopic ratios (Sr i) indicate that leucogranitic melts were derived from two different sources, the two-mica leucogranites having a metagreywacke origin (with Sr i < 0.752 and εNd < −15) and the tourmaline leucogranites a metapelitic one (Sr i> 0.752; εNd > − 15). Such a bimodal nature of the source zone does not directly influence the magmatic evolution, except that probably the higher initial boron content in the metapelitic rocks may increase the Na2O/ K2O ratio. In contrast, the amount of water present during melting principally controls in part anatectic processes and element behaviour. Water-saturated conditions probably occured during melting of metagreywackeous rocks and favoured crystallization of two-mica leucogranites whereas water-absent conditions prevailed during melting of metapelitic layers and favoured biotite, plagioclase and monazite fractionation in the source zone and tourmaline crystallization in the leucogranite. 相似文献
12.
A few eucrites have anomalous oxygen isotopic compositions. To help understand their origin and identify additional samples, we have analyzed the oxygen isotopic compositions of 18 eucrites and four diogenites. Except for five eucrites, these meteorites have Δ 17O values that lie within 2σ of their mean value viz., −0.242 ± 0.016‰, consistent with igneous isotopic homogenization of Vesta. The five exceptional eucrites—NWA 1240, Pasamonte (both clast and matrix samples), PCA 91007, A-881394, and Ibitira—have Δ 17O values that lie, respectively, 4σ, 5σ, 5σ, 15σ, and 21σ away from this mean value. NWA 1240 has a δ 18O value that is 5σ below the mean eucrite value. Four of the five outliers are unbrecciated and unshocked basaltic eucrites, like NWA 011, the first eucrite found to have an anomalous oxygen isotopic composition. The fifth outlier, Pasamonte, is composed almost entirely of unequilibrated basaltic clasts. Published chemical data for the six eucrites with anomalous oxygen isotopic compositions (including NWA 011) exclude contamination by chondritic projectiles as a source of the oxygen anomalies. Only NWA 011 has an anomalous Fe/Mn ratio, but several anomalous eucrites have exceptional Na, Ti, or Cr concentrations. We infer that the six anomalous eucrites are probably derived from five distinct Vesta-like parent bodies (Pasamonte and PCA 91007 could come from one body). These anomalous eucrites, like the isotopically normal, unbrecciated eucrites with 4.48 Gyr Ar-Ar ages, are probably deficient in brecciation and shock effects because they were sequestered in small asteroids (10 km diameter) during the Late Heavy Bombardment following ejection from Vesta-like bodies. The preservation of Vesta’s crust and the lack of deeply buried samples from the hypothesized Vesta-like bodies are consistent with the removal of these bodies from the asteroid belt by gravitational perturbations from planets and protoplanets, rather than by collisional grinding. 相似文献
13.
The Cretaceous to Palaeogene Alpine exhumation of previously buried Variscan basements is recorded in the southern portion of the Western Carpathians in the Gemeric and Veporic units. The Meso-Cenozoic collisional processes resulted in basement exhumation of the Tatric Unit from Palaeogene to Neogene times. According to zircon and apatite fission track data, the Gemeric Unit, an uppermost thick-skinned thrust sheet, cooled from depth levels of ∼10 up to 2.5 km (temperature interval of ∼250–60 °C) about 88–64 Ma ago, after the collapse of overlying Meliata-Turňa-Silica Mesozoic accretionary prism. The middle and lower thick-skinned thrust sheets, Veporic and Tatric units, cooled from the depths of ∼10 up to 2.5 km ∼110–40 Ma ago. The process was controlled by unroofing of footwall from beneath the Gemeric Unit. About 50–20 Ma ago, the internal zone of Tatric Unit gradually exhumed to depth of <2 km and some parts of the unit appeared at the surface level. However, the external zone of Tatric Unit was buried beneath the Eocene to Lower Miocene sedimentary successions and exhumed to the subsurface level at ∼21–8 Ma ago, as a result of oblique collision of the Western Carpathians with the European Platform. 相似文献
14.
The Bindal Batholith is the largest granitoid batholith in the Scandinavian Caledonides, emplaced prior to or during the Scandian collision in a complex scenario of Ordovician to Middle Silurian nappe assembly. The Bindal Batholith ranges in compositon from mafic gabbro to leucogranite, but granites and granodiorites are by far the most abundant rock types. Pb---Pb, Sm---Nd and Rb---Sr isotopic results from plutons of the batholith constrain the origin of the Bindal Batholith magmas. The isotope results suggest the presence of several source reservoirs, giving rise to the granitoid magmas. Both a source relatively depleted in U, Th and Rb and enriched in Sm, a source enriched in U and Rb and depleted in Sm, a source enriched in Th and Rb, but depleted in Sm, and, finally, a source enriched in Th and Sm, but depleted in Rb, is indicated by the initial compositions of the radiogenic isotope ratios. It is suggested that the depleted source reservoirs were contemporaneous depleted mantle and mantle derived rocks in the nappe sequences, that the enriched source reservoir was sediments derived from Proterozoic upper crust of Baltic Shield affinity and that the Th-enriched source reservoir was various Proterozoic rocks, in a lower crustal position, of either Baltic or Laurentian affinity. 相似文献
15.
Major ion and stable isotope geochemistry allow groundwater/surface-water interaction associated with saline to hypersaline lakes from the Willaura region of Australia to be understood. Ephemeral lakes lie above the water table and locally contain saline water (total dissolved solids, TDS, contents up to 119,000 mg/L). Saline lakes that lack halite crusts and which have Cl/Br ratios similar to local surface water and groundwater are throughflow lakes with high relative rates of groundwater outflows. Permanent hypersaline lakes contain brines with TDS contents of up to 280,000 mg/L and low Cl/Br ratios due to the formation of halite in evaporite crusts. These lakes are throughflow lakes with relatively low throughflow rates relative to evaporation or terminal discharge lakes. Variations in stable isotope and major ion geochemistry show that the hypersaline lakes undergo seasonal cycles of mineral dissolution and precipitation driven by the influx of surface water and evaporation. Despite the generation of highly saline brines in these lakes, leakage from the adjacent ephemeral lakes or saline throughflow lakes that lack evaporite crusts is mainly responsible for the high salinity of shallow groundwater in this region. 相似文献
17.
The Nidar ophiolite complex is exposed within the Indus suture zone in eastern Ladakh, India. The suture zone is considered to represent remnant Neo-Tethyan Ocean that closed via subduction as the Indian plate moved northward with respect to the Asian plate. The two plates ultimately collided during the Middle Eocene. The Nidar ophiolite complex comprises a sequence of ultra-mafic rocks at the base, gabbroic rocks in the middle and volcano-sedimentary assemblage on the top. Earlier studies considered the Nidar ophiolite complex to represent an oceanic floor sequence based on lithological assemblage. However, present study, based on new mineral and whole rock geochemical and isotopic data (on bulk rocks and mineral separates) indicate their generation and emplacement in an intra-oceanic subduction environment. The plutonic and volcanic rocks have nearly flat to slightly depleted rare earth element (REE) patterns. The gabbroic rocks, in particular, show strong positive Sr and Eu anomalies in their REE and spidergram patterns, probably indicating plagioclase accumulation. Depletion in high field strength elements (HFSE) in the spidergram patterns may be related to stabilization of phases retaining the HFSE in the subducting slab and / or fractional crystallization of titano-magnetite phases. The high radiogenic Nd- and low radiogenic Sr-isotopic ratios for these rocks exclude any influence of continental material in their genesis, implying an intra-oceanic environment. Nine point mineral–whole rock Sm–Nd isochron corresponds to an age of 140 ± 32 Ma with an initial 143Nd/144Nd of 0.513835 ± 0.000053 (ENd t = + 7.4). This age is consistent with the precise Early Cretaceous age of Hauterivian (132 ± 2 to 127 ± 1.6 Ma) to Aptian (121 ± 1.4 to 112 ±1.1 Ma) for the overlying volcano-sedimentary (radiolarian bearing chert) sequences based on well-preserved radiolarian fossils (Kojima, S., Ahmad, T., Tanaka, T., Bagati, T.N., Mishra, M., Kumar, R. Islam, R., Khanna, P.P., 2001. Early Cretaceous radiolarians from the Indus suture zone, Ladakh, northern India. In: News of Osaka Micropaleontologists (NOM), Spec. Vol., 12, 257–270.) and cooling ages of 110–130 Ma based on 39Ar/40Ar for Nidar–Spontang ophiolitic rocks (Mahéo, G., Berttrand, H., Guillot, S., Villa, I. M., Keller, F., Capiez, P., 2004. The South Ladakh Ophiolites (NW Himalaya, India): an intra-oceanic tholeiitic arc origin with implications for the closure of the Neo-Tethys. Chem. Geol., 203, 273–303.). As these gabbroic and volcanic rocks are interpreted to be arc related, the new Sm–Nd age data may indicate that intra-ocean subduction in the Neo-Tethyan ocean may have started much before 140 ± 32 Ma as this date is interpreted as the age of crystallization of the arc magma. Present and published age data on the arc magmatic rocks from the Indus suture zone may collectively indicate episodic magmatism with increasing maturity of the arc from more basic (during ~ 140 ± 32 Ma) when the arc was immature through intermediate (andesitic/granodioritic) at ~ 100 Ma to more felsic (rhyolitic/dioritic) magmatism at ~ 50–45 Ma, when the Indian and the Asian plates collided. 相似文献
18.
In this study, the chemical evolution of high Cl − Chardon mine groundwaters is modelled as a mixing between an oxidising recharge and an old marine component on which the water–rock interaction is superimposed. Chemical and isotopic similarities with saline Carnmenellis mine groundwaters are emphasised and a general comparison with other brines is discussed.The cation content of deep granitic groundwaters is indicative of the water–rock interaction. In the case of Chardon and Carnmenellis groundwaters, the high Na/Cl ratio can still be related to the contribution of a brine of sedimentary origin to the water salinity. The differences in the hydrochemistry related to their geological context only appears at the trace metals level. On the contrary, brines in plutonic rocks which exhibit a low Na/Cl ratio represent groundwaters having a residence time in the host rock, long enough to equilibrate with secondary aluminosilicates. In that case, the brine origin is difficult to assess if only based on the water cation content. 相似文献
19.
Lithium-rich brine in playas is a major raw material for lithium production. Recently, lithium isotopic ratios (δ 7Li) have been identified as a tool for investigating water–rock interactions. Thus, to constrain the origin of lithium in playas by the use of its isotopes, we conducted leaching experiments on various lacustrine sediment and evaporite deposit samples collected from playas in Nevada, USA. We determined lithium and strontium isotopic ratios and contents and trace element contents of the leachate, estimated the initial δ 7Li values in the water flowing into the playas, and examined the origin of lithium in playas by comparison with δ 7Li values of the possible sources. In samples from the playas, δ 7Li values show some variation, reflecting differences both in isotopic fractionation during mineral formation and in initial δ 7Li value in water flowing into each playa. However, all δ 7Li values in this study are much lower than those in river water and groundwater samples from around the world, but they are close to those of volcanic rocks. Considering the temperature dependence of lithium isotopic fractionation between solid and fluid, these results indicate that the lithium concentrated in playas in Nevada was supplied mainly through high-temperature water–rock interaction associated with local hydrothermal activity and not directly by low-temperature weathering of surface materials. This study, which is the first to report lithium isotopic compositions in playas, demonstrates that δ 7Li may be a useful tracer for determining the origin of lithium and evaluating its accumulation processes in playas. 相似文献
20.
The nature of the oceanic crust produced through rifting and oceanic spreading between North and South America during the
Late Jurassic is a key element for the Caribbean plate tectonic model reconstruction. Located in the Cordillera Central of
Hispaniola, the Loma La Monja volcano-plutonic assemblage (LMA) is composed of gabbros, dolerites, basalts, and oceanic sediments,
as well as metamorphic equivalents, which represent a dismembered fragment of this proto-Caribbean oceanic crust. Petrologic
and geochemical data show that the LMA have a relatively broad diversity in composition, which represent the crystallization
products of a typical low-pressure tholeiitic fractionation of mid-ocean ridge basalts (MORB)-type parental magmas, ranging
from N- to E-MORB. Three geochemical groups have been distinguished in the volcanic sequence: LREE-flat to slightly LREE-enriched
basalts of groups II and III occur interlayered in the lower stratigraphic levels; and LREE-depleted basalts of group I in
the upper levels. Mantle melt modeling suggests that group III magmas are consistent by mixing within a mantle melt column
of low-degree (<1%) melts of a deep garnet lherzolite source and high-degree (>15%) melts of a shallow spinel source, and
groups II and I magmas are explained with moderate to high (14–18%) and very high (>20%) fractional melting degrees of a shallower
spinel mantle source, respectively. Thus, upward in the volcanic sequence of the LMA, the magmas represent progressively more
extensive melting of shallower sources, in a plume-influenced spreading ridge of the proto-Caribbean oceanic crust. Nb/Y versus
Zr/Y systematics combined with recent plate tectonic model reconstructions reveal that Caribbean Colombian oceanic plateau
fragments in Hispaniola formed through melting of heterogeneous mantle source regions related with distinct plumes during
at least from Aptian–Albian (>96 Ma) to Late Campanian. 相似文献
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