Nanoporous polystyrene fibers for oil spill cleanup

The development of oil sorbents with high sorption capacity, low cost, scalable fabrication, and high selectivity is of great significance for water environmental protection, especially for oil spillage on seawater. In this work, we report nanoporous polystyrene (PS) fibers prepared via a one-step electrospinning process used as oil sorbents for oil spill cleanup. The oleophilic-hydrophobic PS oil sorbent with highly porous structures shows a motor oil sorption capacity of 113.87 g/g, approximately 3-4 times that of natural sorbents and nonwoven polypropylene fibrous mats. Additionally, the sorbents also exhibit a relatively high sorption capacity for edible oils, such as bean oil (111.80 g/g) and sunflower seed oil (96.89 g/g). The oil sorption mechanism of the PS sorbent and the sorption kinetics were investigated. Our nanoporous material has great potential for use in wastewater treatment, oil accident remediation and environmental protection.     

Equilibrium modeling of the beach profile on a macrotidal embayed low tide terrace beach

Eleven-year long time series of monthly beach profile surveys and hourly incident wave conditions are analyzed for a macrotidal Low Tide Terrace beach. The lower intertidal zone of the beach has a pluriannual cycle, whereas the upper beach profile has a predominantly seasonal cycle. An equilibrium model is applied to study the variation of the contour elevation positions in the intertidal zone as a function of the wave energy, wave power, and water level. When forcing the model with wave energy, the predictive ability of the equilibrium model is around 60% in the upper intertidal zone but decreases to 40% in the lower intertidal zone. Using wave power increases the predictive ability up to 70% in both the upper and lower intertidal zones. However, changes around the inflection point are not well predicted. The equilibrium model is then extended to take into account the effects of the tide level. The initial results do not show an increase in the predictive capacity of the model, but do allow the model free parameters to represent more accurately the values expected in a macrotidal environment. This allows comparing the empirical model calibration in different tidal environment. The interpretation of the model free parameter variation across the intertidal zone highlights the behavior of the different zones along the intertidal beach profile. This contributes to a global interpretation of the four model parameters for beaches with different tidal ranges, and therefore to a global model applicable at a wide variety sites.     

More realistic soil cleanup standards with dual-equilibrium desorption

The desorption of contaminants from soils/sediments is one of the most important processes controlling contaminant transport and environmental risks. None of the currently adopted desorption models can accurately quantify desorption at relatively low concentrations; these models often overestimate the desorption and thus the risks of hydrophobic organic chemicals, such as benzene and chlorinated solvents. In reality, desorption is generally found to be biphasic, with two soil-phase compartments. A new dual-equilibrium desorption (DED) model has been developed to account for the biphasic desorption. This model has been tested using a wide range of laboratory and field data and has been used to explain key observations related to underground storage tank plumes. The DED model relates the amount of a chemical sorbed to the aqueous concentration, with simple parameters including octanol-water partition coefficient, solubility, and fractional organic carbon; thus, it is the only biphasic model, to date, that is based on readily available parameters. The DED model can be easily incorporated into standard risk and transport models. According to this model, many regulatory standards of soils and sediments could be increased without increasing the risks.     

Discarded containers on a kent beach

Winter beach surveys of discarded containers at Sandwich Bay showed a wide range of fabrication materials and contents. These were manufactured world-wide and probably distributed by seaborne disposal from local shipping. Although blow moulded polyethylene bottles containing toilet cleansers were commonly observed, there was no evidence to indicate an accumulation of these items in the marine environment.     

Knowledge gaps in our perceptual model of Great Britain's hydrology

There is a no lack of significant open questions in the field of hydrology. How will hydrological connectivity between freshwater bodies be altered by future human alterations to the hydrological cycle? Where does water go when it rains? Or what is the future space–time variability of flood and drought events? However, the answers to these questions will vary with location due to the specific and often poorly understood local boundary conditions and system properties that control the functional behaviour of a catchment or any other hydrologic control volume. We suggest that an open, shared and evolving perceptual model of a region's hydrology is critical to tailor our science questions, as it would be for any other study domain from the plot to the continental scale. In this opinion piece, we begin to discuss the elements of and point out some knowledge gaps in the perceptual model of the terrestrial water cycle of Great Britain. We discuss six major knowledge gaps and propose four key ways to reduce them. While the specific knowledge gaps in our perceptual model do not necessarily transfer to other places, we believe that the development of such perceptual models should be at the core of the debate for all hydrologic communities, and we encourage others to have a similar debate for their hydrologic domain.     

A morphodynamic model for beach gradients

This paper outlines a general framework for analysis of the problem of beach gradients which divides the system into: (1) the independent controls, (2) the hydrodynamics, (3) the sediment dynamics, and (4) the morphodynamics. A model is derived from the combination of these stages which shows close agreement with field data for wave steepnesses of less than about 0.06, but predicts lower beach gradients than arc observed for steeper waves. The use of ‘analytical feedback’ in the present model rather than the ‘iterative feedback’ which is used in computer simulations demonstrates that differential sediment transport may be responsible for stabilizing the beach gradient.     

Hydrophobic modification of polyurethane foam for oil spill cleanup

To improve the oleophilic/hydrophobic properties of polyurethane (PU) foams for oil spill cleanup, PU samples were modified by grafting with oleophilic monomer Lauryl methacrylate (LMA) in solvent and/or coating with LMA microspheres through heating and curing. Modified PU cubes were characterized by field emission scanning electron microscopy (FE-SEM) and Fourier transform infrared spectroscopy (FTIR). The water sorption of modified PU cubes was decreased by 24-50%, while the diesel or kerosene sorption of modified PU cubes was increased by 18-27%. In water-oil system, compared with blank PU cubes, the sorption capacity of PU cubes grafted with LMA was increased by 44% for diesel and 100% for kerosene. The sorption capacity of PU cubes coated with LMA microspheres was increased by 20% for diesel and 7% for kerosene. The solvent sorption of modified PU cubes could reach 50-69 g/g. The modified PU cubes can be effectively used in oil/solvent spill cleanup.     

A proposed mechanism for storm beach sedimentation

One of the major problems of shingle beach dynamics is the method by which coarse gravel is transferred from beach face to storm beach, the latter often lying several metres above high spring tidal levels. The mechanism which is usually proposed, cites the action of plunging breakers as being central to this problem of sediment transfer. However, the nature of net residual fluid force of plunging breakers is deemed unsatisfactory for any substantial upbeach (onshore) sediment transport during storm conditions on gravel beaches. A mechanism is proposed by which high still water levels due to high astronomical tides, onshore storm force winds and allied wave surge, promote shoaling characteristics and beach profile changes which are conducive to spilling breaker development at tidal extremities. It is the net onshore fluid force vector of the spilling breaker overtopping the beach crest which may be the cause of extreme sedimentation events on the storm beach. An example of such sediment transfer is given for a known storm beach sedimentation event at Llanrhystyd gravel beach, West Wales, during February 1974. Process variables were monitored on several days allowing the use of an inshore breaker steepness criterion, to indicate positions in the tidal regime where plunging breakers give way to spilling forms. This example serves to suggest that more attention should be given to the nature and characteristics of shoaling waves, especially in respect of breaker type, when examining problems of shingle beach dynamics and sedimentation.