辽宁红透山铜锌矿床含矿岩系地球化学特征及找矿指示

红透山铜锌矿床是产于太古宙绿岩带中的块状硫化物矿床。含矿岩系为角闪斜长片麻岩、角闪斜长(石英)片麻岩、黑云斜长片麻岩、黑云斜长(石英)片麻岩、黑云石英片麻岩。通过对变质岩原岩进行恢复及构造环境判别,得出变质岩原岩均为火山岩,其中角闪斜长片麻岩与角闪斜长(石英)片麻岩的原岩为基性火山岩,黑云斜长片麻岩、黑云斜长(石英)片麻岩与黑云石英片麻岩的原岩为中酸性火山岩,岩性组合为双峰式火山喷发的产物。为探讨含矿岩系地球化学参数作为找矿指标的可能性,对含矿岩系的主量元素、稀土及微量元素进行分析,发现红透山铜锌矿床角闪斜长(石英)片麻岩的Cu元素含量(290.82 μg/g)、SiO₂含量(57.24%)、稀土元素总量(53.78 μg/g)、LREE/HREE比值(4.29)及黑云斜长(石英)片麻岩和黑云石英片麻岩的Cu元素含量(88.09 μg/g)、SiO₂含量(70.50%)可作为重要的找矿指标。     

敦煌地块敖包山晶质石墨矿集区矿床地质特征、变质岩原岩恢复及形成环境

【研究目的】为解决敦煌地块敖包山晶质石墨矿集区晶质石墨矿床研究程度较低的问题,通过对该区变质岩原岩特征及古构造环境进行深入研究,以期为该区的成矿规律研究提供地质依据。【研究方法】本文运用岩石地球化学方法对该区变质岩进行原岩恢复,探讨其形成时的古构造环境。【研究结果】二云石英片岩、黑云斜长片麻岩和斜长角闪岩均具有轻稀土富集的特征。斜长角闪岩K₂O2O,具有弱的Nb、Ta亏损和强烈的Zr、Hf亏损,LREE/HREE=2.21～6.97,轻重稀土元素分馏程度较弱;黑云斜长片麻岩和二云石英片岩K₂O>Na₂O,富集大离子亲石元素Rb、K等,亏损Ba、Nb、Ta、Zr、Hf、Ti、Sr等元素,具有明显的Eu负异常,LREE/HREE平均值分别为12.44和8.89,轻重稀土元素分异较强烈。【结论】敖包山晶质石墨矿集区变质岩原岩形成于浅水区,水动力环境较弱。斜长角闪岩的原岩为亚碱性基性火山岩,形成于岛弧环境;二云石英片岩和黑云斜长片麻岩的原岩为页岩、黏土岩,构造环境为活动大陆边缘,古沉积环境...     

鄂尔多斯盆地北部纳岭沟地区直罗组下段下亚段砂岩岩石地球化学特征及对物源的指示

砂岩的岩石地球化学特征可以指示碎屑物质的来源,物源特征的研究能为盆地的演化以及成矿过程的研究提供新的思路。通过镜下分析、重矿物鉴定以及岩石地球化学分析等手段,对鄂尔多斯盆地北部纳岭沟地区直罗组下段下亚段砂岩进行研究,以确定砂岩的岩石学、矿物学以及岩石地球化学特征,进而确定砂岩的物源特征。研究表明,研究区目的层砂岩以近源沉积的岩屑砂岩为主,砂岩的母岩为中酸性岩浆岩和变质岩;主量元素特征与主动大陆边缘砂岩的主量元素特征相似,反映目的层砂岩的母岩形成于主动大陆边缘的俯冲带构造环境;稀土元素配分曲线与蚀源区岩石稀土元素配分曲线对比发现目的层砂岩的母岩主要为前寒武纪时期的孔兹岩、片麻岩、闪长岩以及海西-印支期的辉长岩和花岗闪长岩,中酸性岩浆岩和变质岩铀含量较高,在沉积阶段为铀的预富集提供了一定量的铀。     

河南新蔡练村铁矿床地质特征与成矿构造背景

新蔡铁矿床位于华北克拉通南缘舞阳—霍邱铁矿成矿带中部,是连接西部舞阳铁矿与东部霍邱铁矿的关键部位,矿体主要呈层状、似层状产于新太古界太华岩群变质岩系中。在研究新蔡地区铁矿床地质特征的基础上,对新蔡地区典型矿床练村铁矿床的矿石及围岩进行系统的主微量元素分析,探讨其成矿构造背景。在稀土配分模式上,铁矿石与原岩为杂砂岩及硅铁沉积物的石英岩类、以及原岩为长英质岩-黏土质杂砂岩的片麻岩类的相似度比较高,而与原岩为玄武岩类的角闪岩类相似度较低,成矿物质可能主要来源于同沉积时期的沉积物,后经区域变质作用而进一步富集成矿。对矿体直接顶底板围岩斜长角闪岩原岩恢复及构造环境判别结果显示,斜长角闪岩原岩应为弧后盆地玄武岩,暗示本区含铁建造沉积时的构造环境亦为弧后盆地。     

江西宁都葛藤嘴浅变质岩离子吸附型稀土矿成矿模式

江西宁都葛藤嘴离子吸附型稀土矿床是新近发现的新类型稀土矿床,成矿母岩为一套浅变质岩系。本文对矿区内的浅变质岩岩石类型、稀土元素含量及风化壳中稀土分布特征进行了研究,总结了成矿模式。矿区内岩石类型有变质砂岩、变质凝灰岩、千枚岩及片岩类。稀土元素含量普遍偏高,平均为384×10-6,变质凝灰岩类可达723×10-6,属于LREE型。风化壳钻孔样品中稀土含量增高,稀土配分继承了母岩特征。此类矿床最为特殊的是成矿母岩呈层产出,母岩的岩石类型、厚度及层位是重要的找矿要素。宁都地区浅变质岩类中良好的成矿母岩主要为变质砂岩和变质凝灰岩,两者不仅稀土含量较高,产出厚度较大,风化壳矿体也较为连续。     

内蒙古锡林浩特岩群岩相学、地球化学特征及构造环境分析

锡林浩特岩群是内蒙古中东部锡林郭勒微地块内原锡林郭勒杂岩的重要组成部分,由一套片麻岩夹层状斜长角闪岩、磁铁石英岩和变粒岩等变质岩组成,形成于中元古代［1］。岩群中片麻岩样品显示轻稀土元素富集的中等分异特征((La/Yb)N=4.71~7.97),斜长角闪岩具有平坦型((La/Yb)N=0.74~0.95)和轻稀土元素微弱富集型((La/Yb)N=1.06~3.63)两种稀土元素配分模式。在微量元素N MORB标准化图解中,斜长角闪岩显示出洋中脊玄武岩和岛弧玄武岩的过渡类型特征。同时结合岩相学和岩石地球化学图解分析,推断片麻岩原岩为富含泥质的亚杂砂岩,而斜长角闪岩原岩为一套具有拉斑质到钙碱性过渡型特征的玄武岩;变质沉积岩形成于活动大陆边缘大陆岛弧环境;变质基性火山岩形成于岛弧弧后盆地。二者指示锡林浩特岩群形成于活动大陆边缘体系。     

安徽省潜山县韩长冲地区的地质构造特征

韩长冲地区主要由超高压变质岩、碱长花岗片麻岩、二长花岗片麻岩组成。前者包括超高压片麻岩、大理岩、榴辉岩和石英硬玉岩等。其中存在由黑云斜长片麻岩、石英硬玉岩、大理岩及层状榴辉岩组成的超高压变质表壳岩组合。超高压变质岩先后经过柯石英榴辉岩相、石英榴辉岩相、角闪岩相及绿片岩相多阶段的变质作用;经过榴辉岩相、角闪岩相、角闪岩相后及脆性等四期变形。其中角闪岩相变形形成本区的主要构造要素,以发育大量Ａ型褶皱及普遍的糜棱岩化为特征。碱长花岗片麻岩及二长花岗片麻岩只经过角闪岩相及其后的变质和变形作用。超高压变质岩与碱长花岗片麻岩呈侵入接触,可能沿缓倾向ＳＳＥ的韧性剪切带逆掩于二长花岗片麻岩之上。     

东昆仑东段中元古代小庙岩组岩石组合、地球化学特征及构造环境分析

小庙岩组是东昆仑造山带前寒武纪变质结晶基底的重要组成部分,是一套中元古代角闪岩相变质地层。详细的野外地质和室内观察表明,小庙岩组主要为一套长英质变质岩夹基性变质岩,长英质变质岩可分为4种岩石组合:石英岩组合、富铝片麻岩组合、长英质片麻岩组合、石英岩—长石石英岩组合。岩石学和地球化学研究表明:含富铝矿物石英片岩和片麻岩的原岩为一套泥质岩,石英岩—长石石英岩原岩为砂岩、杂砂岩或硅质岩,角闪岩和斜长角闪岩原岩为拉斑玄武岩;变沉积岩物源区经历中—低风化程度,处于寒冷干旱的气候区,可能为构造活动区;物源区主要为长英质岩石并且母岩中碱性长石含量较少,或混合有基性火山岩;变沉积岩形于陆壳拉张的裂陷槽或裂谷盆地,变基性岩形成于初始裂解或稍晚期的大陆裂谷环境,二者均指示小庙岩组形成于陆内裂谷环境。     

青藏高原东南缘“三江”地区含角闪石变质岩石的地球化学特征

青藏高原东南缘"三江"地区变质杂岩带中的岩石类型十分复杂,斜长角闪岩和含角闪石斜长片麻岩是本区常见的变质岩石类型。斜长角闪岩可进一步划分为由石榴辉石岩退变而成的和基性原岩经角闪岩相-麻粒岩相变质形成的两种类型。斜长角闪岩的SiO2平均含量50.0%,具有高铝低钛的特点,轻稀土元素相对富集,铕无异常或略具负异常,Zr含量较低,Zr/Y比值较小,其原岩的主微量元素组成具有岛弧玄武岩的特点,反映其原岩形成于俯冲碰撞的构造环境。含角闪石斜长片麻岩的SiO2平均含量63.64%,MgO和TiO2含量低,轻、重稀土元素分馏,轻稀土元素明显富集而重稀土元素相对亏损,具有中等负Eu异常,大离子亲石元素K、Rb、Ba、Th强烈富集,高场强元素Ti、Zr、Hf、Nb和Ta含量较低,其原岩具有安山质岩石或安山质/玄武质岩石的特点,主要形成于板块聚敛边缘的构造环境。     

大理点苍山正片麻岩初步研究

点苍山正片麻岩分为两类：斜长片麻岩和花岗片麻岩。前者属岛孤火山岩，形成于中晚元古代。二者主要化学组分具相关性，花岗片麻岩是由早形成的斜长片麻岩、斜片角闪岩经深熔作用而成。     

河北小觉地区阜平岩群斜长角闪岩及深熔产物的稀土和Nd同位素地球化学研究

工作中重点对河北平山小觉地区阜平岩群两类角闪质岩石深熔作用的地球化学进行了研究。一类为厚层状斜长角闪岩，相邻新生浅色体常量元素组成上向TTG花岗质岩石方向转化，稀土和高场强元素含量明显降低，轻重稀土分离程度增高，tDM减小，εNd(t0)增大。另一类为与黑云变粒岩－片麻岩互层的条带状、石香肠状斜长角闪岩，相邻新生浅色体与之存在不同的地球化学关系：（1）稀土总量相对增高，轻重稀土分离程度有所降低；（2）稀土总量和轻重稀土分离程度都有明显增高。后者Nd同位素组成与斜长角闪岩也存在很大区别。这些现象可用熔融母岩、形成条件等差异得到合理的解释。     

长白山新生代火山岩之下新太古代基底年代学及地球化学特征

对长白山第四系玄武岩覆盖区零星出露的花岗质岩石和片麻岩进行LA-ICPMS锆石U-Pb年龄测定及地球化学分析,结果显示花岗质岩石的年龄为2 509~2 558 Ma;斜长角闪片麻岩的年龄为2 475~2 553 Ma。地球化学特征上,这些岩石均属奥长花岗岩-英云闪长岩-石英闪长岩系列(TTG),稀土元素配分模式图呈右倾型,轻重稀土元素分馏明显(LREE/HREE=3.85~34.48),白云母二长花岗岩具有铕的负异常(δEu=0.41~0.54),富集Rb、K、Th等元素,亏损Nb、Sr、P、Ti等元素;黑云斜长角闪石片麻岩具有铕负异常(δEu=0.67~0.76),富集Rb、K、La、Nd等元素,亏损Th、Nb、Sr、P、Yb等元素;花岗质片麻岩和黑云斜长片麻岩具有铕的弱负-正异常(δEu=0.87~3.3),富集Rb、K、Sr等元素,亏损Nb、Th、P等元素。年代学和地球化学特征与白山地块和和龙地块中的同类岩石基本一致,表明白山地块与和龙地块在晚太古代是同一个陆块(龙岗陆块),二者目前的分布格局是后期北东向左行断裂构造改造的结果。     

鄂尔多斯盆地东胜砂岩型铀矿微量和稀土元素地球化学特征

鄂尔多斯盆地东胜砂岩型铀矿的微量和稀土元素能为铀矿勘查提供地球化学标志。以东胜铀矿层位侏罗系及其中铀矿化为对象,针对砂岩型铀矿石、铀矿化砂岩和围岩几类地质体进行元素地球化学对比研究。东胜砂岩型铀矿微量元素地球化学特征表明,Pb、Mo与U关系极为密切,它们在铀矿石中最富集,铀矿化砂岩中次富集,砂质和泥质围岩中不富集;Pb和Mo可以作为东胜铀矿床矿化的指示元素,Pb、U和Mo蛛网图上构成的"W"式样可作为东胜地区砂岩铀矿化的指示模型。铀矿石、铀矿化砂岩、砂岩以及泥岩表现出相似的REE地球化学特征和配分模式,推断其具有统一的物源、沉积环境和构造背景。部分铀矿石明显富集HREE,显然在沉积成岩后期经历了(热液)改造作用。东胜铀矿化经历了沉积成岩和热液改造作用两个成矿阶段。     

Sources of stream sediments in the granulite terrain of the Walawe Ganga Basin,Sri Lanka,indicated by rare earth element geochemistry

Thirty-eight samples of stream sediments draining high-grade metamorphic rocks in the Walawe Ganga (river) Basin, Sri Lanka, were analysed for their REE contents, together with samples of metamorphic suites from the source region. The metamorphic rocks are enriched in light REE (LREE) compared to heavy REE (HREE) and are characterised by high La/Lu ratios and negative Eu anomalies. The chondrite-normalised patterns for these granulite-grade rocks are similar to that of the average post-Archaean upper crust, but they are slightly enriched with La and Ce. The REE contents of the <63-μm fraction of the stream sediments are similar to the probable source rocks, but the other grain size fractions show more enriched patterns. The <63-μm stream sediments fraction contains lower total REE, more pronouncd negative Eu anomalies, higher Eu_N/Sm_N and lower La _N/Lu_N ratios relative to other fractions. The lower La _N/Lu_N ratio is related to the depletion of heavy minerals in the <63-μm fraction. The 63–125-μm and 125–177-μm grain size fractions of sediments are particularly enriched in LREE (average ΣLREE=2990 μg/g and 3410 μg/g, respectively). The total HREE contents are surprisingly uniform in all size fractions. However, the REE contents in the Walawe Ganga sediments are not comparable with those of the granulite-grade rocks from the source region of the sediments. The enrichment of REE is accounted for by the presence of REE containing accessory mineral phases such as zircon, monazite, apatite and garnet. These minerals are derived from an unknown source, presumably from scattered bodies of granitic pegmatites.     

Petrographic and geochemical characteristics of the Paleogene sedimentary rocks from the North Jiangsu Basin,Eastern China: implications for provenance and tectonic setting

The petrography and geochemistry (major, trace, and rare earth elements) of clastic sedimentary rocks from the Paleogene Dainan Formation (E₂ d) in the North Jiangsu Basin, eastern China, are investigated to trace their provenance and to constrain their tectonic setting. The studied samples are characterized by LREE enrichment, flat HREE, and negative Eu anomaly similar to the upper continental crust composed chiefly of felsic components in the source area. Petrographic observation indicates that the sandstones contain predominant metamorphic and sedimentary clasts that were derived from peripheral recycled orogen and intrabasinal materials. The trace element ratios (Co/Th, La/Sc, La/Th, and Th/U) and the La-Th-Sc ternary plot further confirm that the sandstones are derived from granitic gneiss sources from recycled orogen and the intrabasinal mixed sedimentary provenance. The granitic gneiss source rocks may have derived from the Proterozoic granitic gneiss denuded in the eastern Dabie-Sulu orogen; and the intrabasinal provenance may come from the underlying strata during the Late Paleocene Wubao movement. The chemical index of alteration (CIA) and A-CN-K plot show that these source rocks may have experienced weak to medium chemical weathering. Analysis on tectonic setting of the source area suggests an active continental margin, which is intimate with tectonic feature of the Dabie-sulu orogen and the Yangtze block. In summary, we suggest that the North Jiangsu Basin is an ideal site for the study of the coupling between the uplift of the orogen and the subsidence of the foreland basin.     

Rare Earth Elements in Coal-Bearing Deposits: Distribution Features and Geochemical Significance

The examination of Lower Cretaceous coals and clayey fractions of terrigenous host rocks of the Zyryanka Basin has revealed a generally negative type of the relative REE distribution (with a predominance of LREE over HREE) and a similar behavior of Th and U. Analogous characteristics are typical for metamorphic and igneous rocks of intermediate composition dominating in the provenance. In terms of the concentration and distribution of REE, Th, and U coal-bearing terrigenous rocks of the Zyryanka Basin are close to Phanerozoic clays and silty sandstones of the Russian Platform, while coals of the Zyryanka Basin are similar to metal-free coals of various basins (Kizel, Pennsylvanian, and others). Average REE and Th contents in the studied coals are five times lower than those in host terrigenous rocks. The coals differ from these rocks by relatively elevated HREE concentrations largely due to adsorption mechanism of the HREE accumulation. Data obtained on the REE, Th, and U distribution in coals and clayey fractions of host rocks are of fundamental significance for the comparitive analysis of the behavior of these elements in metal-bearing coals of various basins.     

Petrogenetic significance of rare-earth element behavior in the basement rocks of southern Obudu Plateau, Bamenda Massif, southeastern Nigeria

Rock samples representing various igneous and metamorphic rocks of southern Obudu Plateau were analyzed for rare-earth element ( REE ) behavior by ICP-MS. Results of the analyses indicate a range of REE abundances and distinctive patterns from highly fraetionated patterns with negative Eu anomalies in granitic rocks to relatively low abundances and less REE fractionated flat patterns with little Eu anomaly in some paragneisses, schists, enderbites and dolerites to unfractionated patterns with positive Eu anomalies in some paragneisses and charnockites. Over all, there are low to high ∑ REE contents with negative to positive Eu anomalies. The ratios of different parameters, especially La/Yb and Ce/Yb, show behaviors consistent with crustal to mantle derivation. The heterogeneity of REE abundances and REE patterns reflects mantle to crustal petrogenetic variations of different rock suites on the Plateau. The LREE content is higher than the HREE content in the highly differentiated rocks, as evidenced by their La/Yb,Ce/Yb and La/Sm ratios, which are normally higher in residual products than in primary melts. The dominantly intermediate nature of the source rock of the orthogneisses is suggested by the generally low ∑ REE. The granites enriched in LREE and depleted in HREE and some of the charnockites with negative Eu anomalies were probably formed by partial melting and crystallization.     

鄂尔多斯盆地中部上三叠统延长组物源方向分析与三角洲沉积体系

首次利用稀土元素和微量化学元素,分析鄂尔多斯盆地中部上三叠统延长组母岩类型和物源方向。研究表明盆地中部延长组砂岩和泥岩的稀土元素地球化学特征、REE分配模式及微量化学元素蜘蛛图解相同,表现为轻稀土富集,重稀土亏损,铕、铈元素亏损;REE分配模式均呈“右倾斜、LREE富集、HREE平坦”型;微量化学元素蜘蛛图解具“四峰三谷一平台”型,曲线呈阶梯状分布;砂岩和泥岩的地球化学特征、REE分配模式及微量化学元素蜘蛛图解与盆地东北缘的太古代、元古代变质岩相一致,而与火成岩的重稀土富集、轻稀土亏损、“V”字型REE分配模式和“三峰两谷”型、曲线呈“W”字型分布的蜘蛛图解的特征有显著的差别。说明延长组母岩是盆地东北缘的太古代、元古代变质岩,主要物源方向为北东向。依据物源方向、沉积环境、砂岩岩石学特征、砂岩稀土元素和微量化学元素的地球化学特征,将鄂尔多斯盆地中部上三叠统延长组沉积划分为两大三角洲沉积体系,即北东向的安塞三角洲沉积体系、志靖三角洲沉积体系、安边三角洲沉积体系和北西向的盐定三角洲沉积体系。在三角洲沉积体系划分的基础上,详细阐述了不同三角洲沉积体系的岩石学特征、稀土元素和微量化学元素的地球化学特征及延长组长6-长2期三角洲沉积体系的演化过程。     

Provenance analysis of Eocene–Oligocene turbidite deposits in Pindos Foreland Basin, fold and thrust belt of SW Greece: constraints from framework petrography and bulk-rock geochemistry

The provenance of Eocene–Oligocene turbidites from the Pindos Foreland Basin, SW Greece, has been constrained using petrographical and geochemical techniques. Modal petrographic analysis of the studied sandstones shows that the source area comprises sedimentary, metamorphic, and plutonic igneous rocks deposited in a recycled orogenic environment and in magmatic arc province. The relative proportions of the detrital components indicate that the Late Eocene–Early Oligocene sandstones of West Peloponnesus are quartz-rich and were primarily derived from granitic and metamorphic basement rocks typically of a tectonically active area. Major, trace, and rare earth element (REE) concentrations in both sandstones and mudstones complement the petrographical data indicating an active continental margin/continental island arc signature. All the samples are light REE, enriched relative to heavy REE (HREE), with flat HREE pattern and positive Eu anomalies, suggesting that the processes of intra-crustal differentiation (involving plagioclase fractionation) were not of great importance. The results derived from the multi-element diagrams also suggest an active margin character and a mafic/ultramafic source rock composition.     

喜马拉雅造山带变泥质岩系及其地球化学特征

高喜马拉雅结晶岩系和北喜马拉雅穹隆都发育高角闪岩相-麻粒岩相变泥质岩,岩石组合以富铝质片麻岩类为主,伴生钾质花岗片麻岩、大理岩及基性麻粒岩等.元素地球化学特征表明,其原岩主要为较富铝的长石质砂岩和石英岩质砂岩及少量粘土岩,形成于大陆边缘浅海相沉积环境.这些变泥质岩具有相似的微量元素和稀土元素地球化学特征,表现为大离子亲石元素相对高场强元素较富集,轻稀土较重稀土富集,稀土总量较高,具有较显著的Eu负异常.在变质矿物组合、元素地球化学特征及锆石组成等特征上,它们与青藏高原北缘的康西瓦和阿尔金孔兹岩系相似,可能是来源于冈瓦纳大陆边缘的同一套岩石.