Helium isotopes in some historical lavas from Mount Vesuvius

³He/⁴He ratios in lavas erupted during the last 360 years at Mt. Vesuvius are between 2.2 and 2.7 R_A (R_A = atmospheric ratio of 1.39 × 10⁻⁶), and are among the lowest values measured in young volcanic rocks. They are also identical to values measured in summit crater fumaroles sampled during 1987–1991. This agreement indicates that the ³He/⁴He ratio in the crater fumaroles faithfully tracks the magmatic value. The relatively low and uniform ³He/⁴He ratio in the lavas reflects either a mantle source enriched in (U + Th)/³He, or a mixture of magmatic and crustal components.     

Helium isotopic variations in volcanic rocks from Loihi Seamount and the Island of Hawaii

Helium isotopic ratios ranging from 20 to 32 times the atmospheric ³He/⁴He(R_A) have been observed in a suite of 15 basaltic glasses from the Loihi Seamount. These ratios, which are up to four times higher than those of MORB glasses and more than twice those of nearby Kilauea, are strongly suggestive of a primitive source of volatiles supplying this volcanism. The Loihi glasses measured span a broad compositional range, and the ³He/⁴He ratios were found to be generally lower for the alkali basalts than for the tholeiites. The component with a lower ³He/⁴He ratio appears to be associated with olivine xenocrysts, within which fluid inclusions are probably the carrier of contaminant helium. One Loihi sample has a much lower isotopic ratio (<5 R_A), but a combination of low He concentration, high vesicularity, and presence of cracks lined with clay minerals suggests that the low ratio is due to gas loss and contamination by atmospheric helium.Crushing and melting experiments show that for modest vesicularities (<5% by volume) the Loihi glasses obey a MORB-type partitioning trend, but at higher vesicularities the data show considerably more scatter due to volatile mobilization. The high vesicularities, low extrusion pressure and generally low helium concentrations are consistent with a considerable degree of degassing. Analyses of dunites, plus a correlation between total helium concentrations with xenocryst abundances also suggest that xenocrysts are a significant carrier of contaminating (low ³He/⁴He) helium.³He/⁴He ratios from samples of other Hawaiian volcanoes (Kilauea, Mauna Loa, Hualalai, and Mauna Kea) show a smooth decrease in ³He/⁴He with increasing volcano age and volume. We interpret this to be a synoptic picture of the time evolution of a hot-spot diapir: the earliest stage is characterized by primitive (> 30 R_A) helium with some (variable) component of lithospheric contamination added during “breakthrough”, while the later stages are characterized by a relaxation toward lithospheric ³He/⁴He ratios (～ 8 R_A) due to isolation of the diapir from the mantle below (as the plate moves on), and subsequent mining of the inherited helium and contamination from the surrounding lithosphere. The abrupt contrast in ³He/⁴He ratios between Kilauea and Loihi, despite their close proximity, is indicative of the small lateral extent of the plume.     

Geographical Distribution of 3He/4He Ratios in the Chugoku District, Southwestern Japan

We have collected 34 hot spring and mineral spring gases and waters in the Chugoku and Kansai districts, Southwestern Japan and measured the ³He/⁴He and ⁴He/²⁰Ne ratios by using a noble gas mass spectrometer. Observed ³He/⁴He and ⁴He/²⁰Ne ratios range from 0.054 R_atm to 5.04 R_atm (where R_atm is the atmospheric ³He/⁴He ratio of 1.39 × 10⁻⁶) and from 0.25 to 36.8, respectively. They are well explained by a mixing of three components, mantle-derived, radiogenic, and atmospheric helium dissolved in water. The ³He/⁴He ratios corrected for air contamination are low in the frontal arc and high in the volcanic arc regions, which are consistent with data of subduction zones in the literature. The geographical contrast may provide a constraint on the position of the volcanic front in the Chugoku district where it was not well defined by previous works. Taking into account the magma aging effect, we cannot explain the high ³He/⁴He ratios of the volcanic arc region by the slab melting of the subducting Philippine Sea plate. The other source with pristine mantle material may be required. More precisely, the highest and average ³He/⁴He ratios of 5.88 R_atm and 3.8±1.6 R_atm, respectively, in the narrow regions near the volcanic front of the Chugoku district are lower than those in Kyushu and Kinki Spot in Southwestern Japan, but close to those in NE Japan. This suggests that the magma source of the former may be related to the subduction of the Pacific plate, in addition to a slight component of melting of the Philippine Sea slab.     

Helium-isotope systematics at Nevado del Ruiz volcano, Colombia: implications for the volcanic hydrothermal system

We have collected 14 water and gas samples from 9 thermal springs and gas vents near Nevado del Ruiz volcano, Colombia. The ³He/⁴He and ⁴He/²⁰Ne ratios vary significantly from 0.98 R_atm (where R_atm is the atmospheric ³He/⁴He ratio of 1.4 × 10⁻⁶) to 6.30 R_atm, and from 0.37 to 7.0, respectively. The ³He/⁴He ratio (corrected for air contamination) decreases with increasing distance from the central crater of the volcano to the sampling site. The trend is very similar to that observed at Ontake volcano, Japan. A hydrodynamic porous-media dispersion model can explain the ³He/⁴He trend. The temporal variations in the ³He/⁴He ratio at four sites provide useful information on the apparent velocity of the magmatic fluid flow brought on by a volcanic eruption. The estimated value of several tens m day⁻¹ agrees well with the inferred velocity of flow in Oshima volcano, Japan and is comparable to the largest rate of groundwater movement in a deep sedimentary basin.     

Helium and neon isotopic compositions in the ophiolites from the Yarlung Zangbo River,Southwestern China:The information from deep mantle

The ophiolites from the Yarlung Zangbo River (Tibet),Southwestern China,were analysed for the con-tents of helium and neon and their isotopic compositions by stepwise heating. The serpentinites from Bainang showed a high 3He/4He value of 32.66Ra (Ra is referred to the 3He/4He ratio in the present air) in 700 ℃ fraction. At lower temperature,all of the dolerites displayed as very high 3He/4He ratios as ones investigated for hotspots. It was clear that the high 3He/4He ratio was one of immanent characterics in the magma source formed the dolerites,suggesting that there was a large amount of deep mantle fluids in these rocks. In the three-isotope diagram of neon,the data points from the ophiolites of the Yarlung Zangbo River were arranged along the Loihi Line. This is in agreement with the characteristics of he-lium isotopes,revealing that the high-3He plume from deep mantle had played an important role in the formation of the Neo-Tethyan Ocean. The helium isotopic compositions in the basalts were far higher than atomospheric value but lower than the average value of MORB,although there were various de-grees of alteration. The possible reasons were that basaltic magmas     

Helium isotopes and mantle volatiles in Loihi Seamount and Hawaiian Island basalts and xenoliths

We examine in this paper the use of helium isotope ratios for the study of hotspot volcanism along age-progressive island volcanic chains. The Hawaiian Islands are the original “high ³He” hotspot, with ³He/⁴He ratios as high as 32 × the atmospheric ratio; in the Pacific they stand out against the surrounding sea of MORB (rather uniformly 8 × atmospheric) which fills the entire Pacific with the exception of the Macdonald-Mehetia-Samoa axis in the South Pacific. The recent availability of a variety of alkalic and tholeiitic glasses from the U.S. Geological Survey and our own dredge hauls has prompted us to look first at isotopic variability within a single fresh and new volcano which is probably sitting directly atop a mantle plume. Thus we have looked in some detail at the total helium in glass pillow rims, at He in the enclosed vesicles, and at He in the glass itself, in both tholeiitic and alkalic lavas, and also at helium in associated phenocrysts and xenoliths. The measured ³He/⁴He ratios range from atmospheric to 30 × atmospheric, but we see clear evidence that the highly vesiculated lavas suffer exchange of He between the thin glass walls of vesicles and ambient seawater, so that we observe a post-eruptive isotopic disequilibrium between glass and gas phases. The primary effect is the very large loss of initial He content during eruptive vesiculation, which results in quite large isotopic effects from small additions of ambient He (of the order of 0.02 μcc He per gram of basalt; corresponding to a “water/rock ratio” of 0.5). Phenocrystic He in olivines verifies that the gas-phase He is not affected by vesicularities up to about 5%. Alkali basalt He appears to be independent of vesicularity up to values as high as 35%; this He is somewhat lower in ³He/⁴He ratio, but matches precisely the associated xenolithic He. However, from the present data we cannot exclude the possibility that diffusive exchange with seawater has affected the He ratio in alkalic vesicles.On the large scale, along the 10% of the Hawaiian chain available for subaerial sampling, we find high ³He/⁴He ratios (24 × atmospheric) in 5.5 × 10⁶-year-old lavas on Kauai. Maximum values of the ratio so far observed are in the pre-erosional Kula basalts on Maui, confirming the previous results of Kaneoka and Takaoka. Hawaii, where these high values were first observed is now seen to range from MORB ratios at Mauna Loa to only 15 × R_A at Kilauea fumaroles. Most xenolithic He so far measured is MORB He, but Loihi xenoliths have high values and are quite different in this respect. Finally, we discuss also the hydrogen and carbon isotope results on Loihi lavas, and show that these elements resemble MORB and appear not to show a distinctive plume signature.     

Noble gas systematics for coexisting glass and olivine crystals in basalts and dunite xenoliths from Loihi Seamount

Noble gas isotopes including ³He/⁴He, ⁴⁰Ar/³⁶Ar and Xe isotope ratios were determined for coexisting glass and olivine crystals in tholeiitic and alkalic basalts and dunite xenoliths from Loihi Seamount.Glass and coexisting olivine crystals have similar ³He/⁴He ratios (2.8–3.4) × 10^?5, 20 to 24 times the atmospheric ratio (R_A), but different ⁴⁰Ar/³⁶Ar ratios (400–1000). Based on the results of noble gas isotope ratios and microscopic observation, some olivine crystals are xenocrysts. We conclude that He is equilibrated between glass and olivine xenocrysts, but Ar is not.The apparent high ³He/⁴He ratio (3 × 10^?5; = 21 R_A) coupled with a relatively high ⁴⁰Ar/³⁶Ar ratio (4200) for dunite xenoliths (KK 17-5) may be explained by equilibration of He between MORB-type cumulates and the host magma.Except for the dunite xenoliths, noble gas data for these Loihi samples are compatible with a model in which samples from hot spot areas may be explained by mixing between P (plume)-type and M (MORB)-type components with the addition of A (atmosphere)-type component.Excess ¹²⁹Xe has not been observed due to apparent large mass fractionation among Xe isotopes.     

Volcanology and petrology of Nisyros Island (Dodecanese,Greece)

Nisyros is a totally volcanic island located at the eastern limit of the quaternary calc-alkaline island arc system of the South Aegean Sea. Its age is rather young since K/Ar dating has given an age of 0.2 m.y. B.P. for one of the oldest outcropping products of this volcano. The volcanological evolution of Nisyros has tentatively been reconstructed as follows:

1. after a period (from 3.0? to 0.2 m.y. B.P.) of submarine activity, evidenced by the presence of pillow-lavas and hyaloclastites, the volcano grew above sea level;
2. effusive and explosive subaerial activity from different vents built up a complex stratovolcano, probably around 0.2 m.y. B. P.;
3. at the end of an intense explosive activity (between 0.2 m.y. B.P. and Present) the top of the volcano collapsed forming a caldera which is still perfectly preserved. A post-caldera activity with eruptions of huge and viscous domes and lava flows of uniform composition, both inside and outside the caldera, concluded this stage of the volcano evolution;
4. in historical times, spectacular phreatic explosion craters formed on the caldera floor;
5. presently, a large area of the caldera floor is affected by a considerable hydrothermal activity. The hypothesis is formed that Nisyros volcano is not yet extinct.

Four small volcanic islets — Yali, Stronjili, Pakia and Perigusa — located a few miles on the North and West of Nisyros, although volcanologically independent of one another, are composed of products which are attributable, from the petrologic point of view, to the Nisyros magma. The volcanic rocks of Nisyros and of its neighbouring minor islands as well as the volcanics of the coeval volcanoes of the South Aegean Sea arc (Aegina, Milos, Santorini, etc.) belong to a typical orogenic calc-alkaline series (from basic andesites through andesites-dacites-rhyodacites to strongly silicic rhyolites) with normal K₂O contents. The potassium contents of these rocks are compatible with the depth of 150 km (as inferred from geophysical data) for the inclined seismic zone underneath the active volcanic arc. The existence of a top-caldera as well as the occurrence of a huge amount of xenoliths (hornblende-rich cumulates and contact-metamorphic calcareous rock derivatives) suggest the presence of a magma chamber at a relatively shallow depth beneath the volcano. The rhyolitic obsidians of Yali can be considered as residual liquids from the Nisyros rhyodacites, thus representing the end-members of a fractionation process. Volcanological and petrological arguments are in favour of fractional crystallization as the most probable genetic process for the calc-alkaline differentiation series of Nisyros and of its neighbouring minor islands. However, the lack of any rock with a high alumina basalt composition makes it difficult to define exactly the nature of the parent magma. According to recent geophysical data, continental collision is already in progress at the Hellenic trench. Therefore, Nisyros and the other active volcanoes of the South Aegean Sea arc are approaching the senile stage. What would follow could be a transition to shoshonitic magmatism as a consequence of the deepening of the lithospheric slab under the Aegean microplate. The limited extension and the relatively short-lived calc-alkaline activity of the South Aegean Sea arc could be related to the particular geodynamic pattern of the Mediterranean area which is characterized by a microplates mosaic between the two converging African and Eurasian major plates.     

Chemical and isotopic compositions of thermal springs,fumaroles and bubbling gases at Tacaná Volcano (Mexico–Guatemala): implications for volcanic surveillance

This study presents baseline data for future geochemical monitoring of the active Tacaná volcano–hydrothermal system (Mexico–Guatemala). Seven groups of thermal springs, related to a NW/SE-oriented fault scarp cutting the summit area (4,100m a.s.l.), discharge at the northwest foot of the volcano (1,500–2,000m a.s.l.); another one on the southern ends of Tacaná (La Calera). The near-neutral (pH from 5.8 to 6.9) thermal (T from 25.7°C to 63.0°C) HCO₃–SO₄ waters are thought to have formed by the absorption of a H₂S/SO₂–CO₂-enriched steam into a Cl-rich geothermal aquifer, afterwards mixed by Na/HCO₃-enriched meteoric waters originating from the higher elevations of the volcano as stated by the isotopic composition (δD and δ¹⁸O) of meteoric and spring waters. Boiling temperature fumaroles (89°C at ~3,600m a.s.l. NW of the summit), formed after the May 1986 phreatic explosion, emit isotopically light vapour (δD and δ¹⁸O as low as −128 and −19.9‰, respectively) resulting from steam separation from the summit aquifer. Fumarolic as well as bubbling gases at five springs are CO₂-dominated. The δ¹³C_CO2 for all gases show typical magmatic values of −3.6 ± 1.3‰ vs V-PDB. The large range in ³He/⁴He ratios for bubbling, dissolved and fumarolic gases [from 1.3 to 6.9 atmospheric ³He/⁴He ratio (R _A)] is ascribed to a different degree of near-surface boiling processes inside a heterogeneous aquifer at the contact between the volcanic edifice and the crystalline basement (⁴He source). Tacaná volcano offers a unique opportunity to give insight into shallow hydrothermal and deep magmatic processes affecting the CO₂/³He ratio of gases: bubbling springs with lower gas/water ratios show higher ³He/⁴He ratios and consequently lower CO₂/³He ratios (e.g. Zarco spring). Typical Central American CO₂/³He and ³He/⁴He ratios are found for the fumarolic Agua Caliente and Zarco gases (3.1 ± 1.6 × 10¹⁰ and 6.0 ± 0.9 R _A, respectively). The L/S (5.9 ± 0.5) and (L + S)/M ratios (9.2 ± 0.7) for the same gases are almost identical to the ones calculated for gases in El Salvador, suggesting an enhanced slab contribution as far as the northern extreme of the Central American Volcanic Arc, Tacaná.     

He,Ne and Ar isotopic composition of Fe-Mn crusts from the western and central Pacific Ocean and implications for their genesis

The noble gas nuclide abundances and isotopic ratios of the upmost layer of Fe-Mn crusts from the western and central Pacific Ocean have been determined. The results indicate that the He and Ar nu- clide abundances and isotopic ratios can be classified into two types: low 3He/4He type and high 3He/4He type. The low 3He/4He type is characterized by high 4He abundances of 191×10-9 cm3·STP·g-1 on average, with variable 4He, 20Ne and 40Ar abundances in the range (42.8―421)×10-9 cm3·STP·g-1, (5.40―141)×10-9 cm3·STP·g-1, and (773―10976)×10-9 cm3·STP·g-1, respectively. The high 3He/4He samples are characterized by low 4He abundances of 11.7×10-9 cm3·STP·g-1 on average, with 4He, 20Ne and 40Ar abundances in the range of (7.57―17.4)×10-9 cm3·STP·g-1, (10.4―25.5)×10-9 cm3·STP·g-1 and (5354―9050)×10-9 cm3·STP·g-1, respectively. The low 3He/4He samples have 3He/4He ratios (with R/RA ratios of 2.04―2.92) which are lower than those of MORB (R/RA=8±1) and 40Ar/36Ar ratios (447―543) which are higher than those of air (295.5). The high 3He/4He samples have 3He/4He ratios (with R/RA ratios of 10.4―12.0) slightly higher than those of MORB (R/RA=8±1) and 40Ar/36Ar ratios (293―299) very similar to those of air (295.5). The Ne isotopic ratios (20Ne/22Ne and 21Ne/22Ne ratios of 10.3―10.9 and 0.02774―0.03039, respectively) and the 38Ar/36Ar ratios (0.1886―0.1963) have narrow ranges which are very similar to those of air (the 20Ne/22Ne, 21Ne/22Ne, 38Ar/36Ar ratios of 9.80, 0.029 and 0.187, respectively), and cannot be differentiated into different groups. The noble gas nuclide abundances and isotopic ratios, together with their regional variability, suggest that the noble gases in the Fe-Mn crusts originate primarily from the lower mantle. The low 3He/4He type and high 3He/4He type samples have noble gas characteristics similar to those of HIMU (High U/Pb Mantle)- and EM (Enriched Mantle)-type mantle material, respectively. The low 3He/4He type samples with HIMU-type noble gas isotopic ratios occur in the Magellan Seamounts, Marcus-Wake Seamounts, Marshall Island Chain and the Mid-Pacific Sea- mounts whereas the high 3He/4He type samples with EM-type noble gas isotopic ratios occur in the Line Island Chain. This difference in noble gas characteristics of these crust types implies that the MagellanSeamounts, Marcus-Wake Seamounts, Marshall Is- land Chain, and the Mid-Pacific Seamounts originated from HIMU-type lower mantle material whereas the Line Island Chain originated from EM-type lower mantle material. This finding is consistent with varia- tions in the Pb-isotope and trace element signatures in the seamount lavas. Differences in the mantlesource may therefore be responsible for variations in the noble gas abundances and isotopic ratios in the Fe-Mn crusts. Mantle degassing appears to be the principal factor controlling noble gas isotopic abundances in Fe-Mn crusts. Decay of radioactive isotopes has a negligible influence on the nuclide abundances and isotopic ratios of noble gases in these crusts on the timescale of their formation.     

He and Ne isotopes in oceanic crust: implications for noble gas recycling in the mantle

In an attempt to determine the helium and neon isotopic composition of the lower oceanic crust, we report new noble gas measurements on 11 million year old gabbros from Ocean Drilling Program site 735B in the Indian Ocean. The nine whole rock samples analyzed came from 20 to 500 m depth below the seafloor. Helium contents vary from 3.3×10⁻¹⁰ to 2.5×10⁻⁷ ccSTP/g by crushing and from 5.4×10⁻⁸ to 2.4×10⁻⁷ ccSTP/g by melting. ³He/⁴He ratios vary between 2.2 and 8.6 Ra by crushing and between 2.9 and 8.2 by melting. The highest R/Ra ratios are similar to the mean mid-ocean ridge basalt (MORB) ratio of 8±1. The lower values are attributed to radiogenic helium from in situ α-particle production during uranium and thorium decay. Neon isotopic ratios are similar to atmospheric ratios, reflecting a significant seawater circulation in the upper 500 m of exposed crust at this site. MORB-like neon, with elevated ²⁰Ne/²²Ne and ²¹Ne/²²Ne ratios, was found in some high temperature steps of heating experiments, but with very small anomalies compared to air. These first results from the lower oceanic crust indicate that subducted lower oceanic crust has an atmospheric ²⁰Ne/²²Ne ratio. Most of this neon must be removed during the subduction process, if the ocean crust is to be recirculated in the upper mantle, otherwise this atmospheric neon will overwhelm the upper mantle neon budget. Similarly, the high (U+Th)/³He ratio of these crustal gabbros will generate very radiogenic ⁴He/³He ratios on a 100 Ma time scale, so lower oceanic crust cannot be recycled into either MORB or oceanic island basalt without some form of processing.     

Tectonic and geochemical characteristics and reserved conditions of a mantle source gas accumulation zone in eastern China

Along both sides of the Tancheng-Lujiang Fracture Zone in eastern China, a series of mantle source gas pools constitute a massive-scale tectonic accumulation zone in NNE direction, with the mantle geochemical characteristics of high concentrations of C0₂ and He, high³He/⁴He-⁴⁰Ar/³⁶Ar ratio system and high δ¹³Coo₂ ratios (the main frequency, -3.4%— 4.6%), showing no difference from the tectonic framework of the area. In the area, the tectonic environment is a rift formed as a result of diapiric mantle injection and crust thinning to form graben-type basins and lithospheric fractures. The mantle-derived volcanic rocks and inclusions are well-developed and a high geothermal zone (mantlesource) exists in the area. The characteristics of the three components (solid, liquid and gas) of mantle, concentrated all over the same tectonic space zone, show that the rift system is of a good tectonic environment or passage for mantle degassing and gas migration. The main types of the gas pools are volcano, fault-block, anticline, buried hill and so on, but most of them are combination traps closely related with fracture. For the mantle source gas pools, rift is an optimum tectonic region, and nearby lithospheric fracture, mantle source volcanic rocks or basement uplifts are a favourable structural location when reservoir-caprock association develops.     

Rare gases,water, and carbon in kaersutites

Kaersutites from Kakanui, New Zealand and from three localities in the southwestern United States have been analyzed for rare gases, water and carbon to investigate the volatile signature of the sub-continental mantle. This study does not confirm the high ³He/⁴He and ²¹Ne/²²Ne ratios reported by Saito et al. [1] for the Kakanui kaersutite. Instead, a ³He/⁴He ratio of 6 R_A and atmospheric ²¹Ne/²²Ne ratios were measured which are consistent with our current knowledge of the earth's mantle. A low ⁴⁰Ar/³⁶Ar of 320 and more than 10^?8 cm³/g of ³⁶Ar confirms the argon results of Saito et al. and indicates that significant quantities of ³⁶Ar reside in this portion of the mantle. Kaersutites from the southwestern United States (Arizona) have a heterogeneous helium isotope signature, ranging from 8.8 R_A at San Carlos to 0.46 at Hoover Dam. All D/H ratios for the water in kaersutites (?56‰ to ?78‰) represent typical mantle values with no apparent correlation with ³He/⁴He. The correlation of increasing carbon content (140–400 ppm) with increasing δ¹³C (?24.5‰ to ?16.7‰) may reflect differences in the proportions of oxidized and reduced carbon in these samples.     

Helium isotope studies of the mantle xenoliths and megacrysts from the Cenozoic basalts in the eastern China

Helium isotope compositions of the mantle xenoliths and megacrysts in the Cenozoic basalts in the eastern China were measured. The samples were collected from Ludao of Heilongjiang, Huinan and Jiaohe of Jilin, Kuandian of Liaoning, Hannuoba of Hebei, Nüshan of Anhui, Dingan of Hainan. The³He/⁴He ratios of the mantle xenoliths and megacrysts from the most areas were about 1 × 10^-5, and were similar to those of the MORB, thus reflecting the characteristics of the MORB-typed depleted mantle. The³He/⁴He ratios of the mantle xenoliths from Jiaohe were 4.8×10^-6 and the³He/⁴He ratios of xenoliths from Hannuoba vary from 0.15× 10^-6 to 7.4 ×10^-6, obviously lower than those of the MORB, and even lower than the atmospheric helium isotope ratios, indicating that the continental mantle was strongly replaced in Jiaohe and Hannuoba areas. The helium isotope compositions of the mantle xenoliths and megacrysts in the same region vary in a very wide range. It is inferred that the mantle xenoliths and megacrysts were from different parts of the continental mantle. There were not necessary origin relations between the mantle xenoliths, megacrysts and their host basalts. An extremely high³He/⁴He ratio of garnet megacryst from Hannuoba, Hebei was found.     

Natural tracers for identifying the origin of the thermal fluids emerging along the Aegean Volcanic arc (Greece): Evidence of Arc-Type Magmatic Water (ATMW) participation

The Aegean volcanic arc is the result of a lithosphere subduction process during the Quaternary time. Starting from the Soussaki area, from west to east, the arc proceeds through the islands of Egina, Methana, Milos, Santorini, the Columbus Bank, Kos and Nisyros. Volcano-tectonic activities are still pronounced at Santorini and Nisyros in form of seismic activity, craters of hydrothermal explosions, hot fumaroles and thermal springs. A significant number of cold water springs emerge in the vicinity of hot waters on these islands.Chemical and isotopic analyses were applied on water and fumaroles samples collected in different areas of the volcanic arc in order to attempt the assessment of these fluids. Stable isotopes of water and carbon have been used to evaluate the origin of cold and thermal water and CO₂.Chemical solute concentrations and isotopic contents of waters show that the fluids emerging in Egina, Soussaki, Methana and Kos areas represent geothermal systems in their waning stage, while the fluids from Milos, Santorini and Nisyros proceed from active geothermal systems.The δ²H–δ¹⁸O–Cl^? relationships suggest that the parent hydrothermal liquids of Nisyros and Milos are produced through mixing of seawater and Arc-Type Magmatic Water (ATMW), with negligible to nil contribution of local ground waters and with very high participation of the magmatic component, which is close to 70% in both sites. A very high magmatic contribution to the deep geothermal system could occur at Santorini as well, perhaps with a percentage similar to Nisyros and Milos, but it cannot be calculated because of steam condensation heavily affecting the fumarolic fluids of Nea Kameni before the surface discharge.The parent hydrothermal liquid at Methana originates through mixing of local groundwaters, seawater and ATMW, with a magmatic participation close to 19%. All in all, the contribution of ATMW is higher in the central–eastern part of the Aegean volcanic arc than in the western sector. This difference, which is spotted in the variable isotopic composition of the sampled fluids from west to east along the arc, is probably due to several causes, including the tectonic regime, the depth of the deep reservoir below sea level, the age of volcanic activity and in general the geomorphologic state of each island.     

The origin of josephinites: a new noble gas study

We performed a complete noble gas study on eight different josephinites and one oregonite. The ⁴He/³He ratios range between 100,000 and 330,000 and are probably due to a combination of a MORB He-component from the Josephinite Peridotite massif, where these nickel-iron specimens are found, and either atmospheric He or radiogenic He from the underlying continental or subcontinental basement. The ⁴⁰Ar/³⁶Ar ratios of 302 to 381 are slightly higher than the ratio of air-argon. The neon, krypton and xenon isotopic ratios are identical to the corresponding air ratios. We cannot confirm large³He and²¹Ne excesses published earlier. The observed noble gas isotopic signatures are in agreement with a formation of josephinites near the surface. The data do not favour a deep mantle origin or a formation at the mantle-core boundary as proposed before.     

Mantle source for Oldoinyo Lengai carbonatites: Evidence from helium isotopes in fumarole gases

Oldoinyo Lengai is the world's only active carbonatite volcano and considerable debate still surrounds the genesis of its magmas. Gases were collected from two fumaroles discharging close to the then active vent in October 2003. Measured fumarole temperatures were ≤ 195°C, despite the nearby, vigorous eruptive activity. Gases were sampled and analysed for noble gas isotopes. Freshly erupted natrocarbonatite lavas, a 1917 nephelinite and a sub-recent wollastonite bearing rock were also collected and analysed for noble gas isotopes using vacuum crushing techniques. In all the lava samples the neon, argon, krypton and xenon isotope ratio data are indistinguishable from air implying atmospheric contamination of the hygroscopic rocks. In the fumaroles, measured ³He/⁴He ratios are between 4 and 7 R/R_a. This range is similar to published values for silicate xenoliths of the East African Rift implying a local lithospheric mantle source for the volatile component of the Lengai magmas. It is still unclear if the natrocarbonatites themselves come from this region, or if fractionation and/or liquid immiscibility generate the carbonate magmas from a silicate melt within the crust itself.     

Petrogenesis of Cenezoic volcanic rocks from the Aegean island arc

The Aegean volcanic arc formed in response to northeasterly subduction of the Mediterranean sea floor beneath the Aegean Sea. The active arc lies over 250 km from the Hellenic Trench in a region which has suffered considerable extension and subsidence since the mid-Tertiary. Suites of samples from the different volcanic centres making up the arc have been studied geochemically in order to assess lateral variations and to constrain the contribution of crustal contamination and sediment subduction in their petrogenesis.Lavas from all the major volcanic centres exhibit typical calc-alkaline major-element characteristics, and show enrichment in light REE and LIL elements but low contents of HFS elements. The enrichment in light REE is greater in the eastern (Nisyros, Kos) and western (Milos, Poros, Methana, Aegina) sectors of the arc (Ce_n/Yb_n=4) than in the central Santorini sector (Ce_n/Yb_n=2). All lavas have significant negative Eu anomalies and many have slight negative Ce anomalies. Less coherence is observed in the abundances and ratios of the other LIL elements, compared with the REE, along the island chain.Whereas the effects of crystal fractionation are evident in the trace-element patterns of lavas from individual islands, and are particularly well marked for Santorini, it is clear that there are consistent differences in trace-element abundances and ratios in the lavas of the various islands which reflect compositional differences in the mantle source and/or in melting conditions. Lavas from the eastern and western sectors have much higher levels of Ba and Sr but relatively lower Th, K and Rb than those from Santorini. Although some geochemical features could be explained through involvement of a component of subducted sediment in the source regions of the volcanoes, other element abundances and ratios indicate that this component must be very small. Detailed consideration of the inter-island geochemical variations suggests a complex make-up of the underlying lithosphere, resulting from a long history of subduction. In the region of Santorini, where crustal stretching is greatest, the underlying asthenosphere may be involved in magma production.     

Primitive neon and helium isotopic compositions of high-MgO basalts from the Kerguelen Archipelago,Indian Ocean

The geochemical characteristics of mildly alkalic basalts (24–25 Ma) erupted in the southeastern Kerguelen Archipelago are considered to represent the best estimate for the composition of the enriched Kerguelen plume end-member. A recent study of picrites and high-MgO basalts from this part of the archipelago highlighted the Pb and Hf isotopic variations and suggested the presence of mantle heterogeneities within the Kerguelen plume itself. We present new helium and neon isotopic compositions for olivines from these picrites and high-MgO basalts (6–17 wt.% MgO) both to constrain the enriched composition of the Kerguelen plume and to determine the origin of isotopic heterogeneities involved in the genesis of Kerguelen plume-related basalts. The olivine phenocrysts have extremely variable ⁴He / ³He compositions between MORB and primitive values observed in OIB (∼90,000 to 40,000; i.e., R / R_a ∼8 to 18) and they show primitive neon isotopic ratios (average ²¹Ne / ²¹Ne_ext ∼0.044). The neon isotopic systematics and the ⁴He / ³He ratios that are lower than MORB values for the Kerguelen basalts clearly suggest that the Kerguelen hotspot belongs to the family of primitive hotspots, such as Iceland and Hawaii. The rare gas signature for the Kerguelen samples, intermediate between MORB and solar, is apparently inconsistent with mixing of a primitive component with a MORB-like source, but may result from sampling a heterogeneous part of the mantle with solar ³He / ²²Ne and with a higher (U, Th) / ³He ratio compared to typically high R / R_a hotspot basalts such as those from Iceland and Hawaii.     

Mantle heterogeneity beneath the southern Mid-Atlantic Ridge: trace element evidence for contamination of ambient asthenospheric mantle

We report new trace element data for an extensive suite of quench basalt glasses dredged from the southern Mid-Atlantic Ridge (MAR) between 40°S and 52.5°S. Ratios between highly incompatible trace elements are strongly correlated and indicate a systematic distribution of incompatible element enriched mid-ocean ridge basalt (MORB) (E-type: Zr/Nb=5.9-19, Y/Nb=0.9-8.4, (La/Sm)_n=1.0-2.9) and incompatible element depleted MORB (N-type: Zr/Nb=30-69, Y/Nb=11-29, (La/Sm)_n=0.48-0.79) along this section of the southern MAR. A notable feature of N-type MORB from the region is the higher than usual Ba/Nb (4-9), La/Nb (1.2-2.4) and primitive mantle normalised K/Nb ratios (>1). Ba/Nb ratios in E-type MORB samples from 47.5 to 49°S are especially elevated (>10). The occurrence and geographic distribution of E-type MORB along this section of the southern MAR can be correlated with the ridge-centred Shona and off-axis Discovery mantle plumes. In conjunction with published isotope data for a subset of the same sample suite [Douglass et al., J. Geophys. Res. 104 (1999) 2941], a model is developed whereby prior to the breakup of Gondwana and the opening of the South Atlantic Ocean, the underlying asthenospheric mantle was locally contaminated by fluids/melts rising from the major Mesozoic subduction zone along the south-southwest boundary of Gondwana, leaving a subduction zone geochemical imprint (elevated (K/Nb)_n and ⁸⁷Sr/⁸⁶Sr ratios, decreased ¹⁴³Nd/¹⁴⁴Nd ratios). Subsequent impingement of three major mantle plume heads (Tristan/Gough, Discovery, Shona) resulted in heating and thermal erosion of the lowermost subcontinental lithosphere and dispersal into the convecting asthenospheric mantle. With the opening of the ocean basin, continued plume upwelling led to plume-ridge interactions and mixing between geochemically enriched mantle derived from the Shona and Discovery mantle plumes, material derived from delamination of the subcontinental lithosphere, and mildly subduction zone contaminated depleted asthenospheric mantle.