Gas chromatographic determination of lignin in sediment

After the oxidation of river and marine sediments with CuO under alkaline conditions, the phenolic compounds in the oxidation products are determined gas chromatographically and compared to that of lignin oxidation products. The method of CuO oxidation is compared to that of nitrobenzen. The quantitative determination of produced phenolic compounds by capillary gas chromatography is examined and the blank and repetibility of the method are tested.     

Acoustical penetration and shear strength in gas‐charged sediment

Abstract

Methane concentrations and sediment shear strengths were measured in three foundation borings taken from areas of variable acoustical penetration in the Mississippi river delta front. Acoustically impenetrable or “turbid”; zones were associated with sedimentary methane concentrations above about 30 ml/liter, measured at atmospheric pressure. Sediments in the high‐gas, acoustically turbid zones demonstrated a smaller percentage increase in shear strength with depth than in zones of low gas concentration. The results indicate that a 3.5‐kHz system used for sub‐bottom profiles is unable to determine the thickness of gas‐charged sediments.     

Dinoflagellate cysts in recent marine sediment from Guangxi, China

Total of 33 species of dinoflagellate cysts were discovered from surface sediment in the searegion of Guangxi, among them 12 cyst types (Diplopsalopsis sp.1, D. sp. 2, D. sp. 3, Cochlodinium sp., Protoperidinium sp. 1, P. sp. 2, P. compressum , Scrippsiella sp. 1, S. sp. 2, Alexandrium sp. 1, A. sp. 2, A. sp. 3) were first reported from the South China Sea. And one cyst type (Cochlodinium sp.) was first reported in the world. Scrippsiella trochoidea is the dominant species in this area, accounting for 45% of all the cysts. There are 2 cysts of toxic dinoflagellate (Alexandrium tamarensis and Gymnodinium catenatum). But there is no relationship between cyst number and grain size distribution.     

Analysis of sediment stability on the Peru‐Chile continental slope

Abstract

Potential sediment mass movement was analyzed at ten locations on the continental slope off Peru and northern Chile, using samples obtained from up to 3 m below the seafloor. Shear strength parameters were obtained from consolidated‐undrained triaxial compression tests. Sediment behavior in these tests reflects the influence of organic matter, which is concentrated in the slope deposits by coastal upwelling. High water content of the organic‐rich sediments and the high de‐formability of organic matter contribute to the prevalent ductile behavior. Aggregation of clays by organic matter is apparently responsible for the high friction angles, up to 44°, displayed by the slope deposits. Sediment stability was assessed using infinite slope analyses. These analyses indicate that gravitational forces alone are not sufficient to cause sediment failure at any of the slope locations. Sediment accumulation on the slope is not rapid enough to generate excess pore pressure and reduce the resistance to gravitational sliding. Effects of earthquakes on slope stability were evaluated by modeling earthquake‐induced inertia forces as static forces and estimating pore pressures developed during cyclic loading. This analysis shows that sediments of the lower slope off Peru possess the highest susceptibility to failure during earthquakes. Earthquake accelerations on the order of 0.2 gravity are sufficient to trigger slumping at all ten slope locations. Indirect evidence suggests that creep and mass flows initiated at shallower water depths are factors that might contribute to sediment failure on the slope.     

Interfacial geochemistry of barium in suspension and sediment from Zhujiang Estuary

Chemical forms of Ba are determined in samples of suspension and sediment from the Zhujiang Estuary. Their interfacial geochemical processes are discussed. Total suspended Ba content is between 2. 4 and 40. 4 μg/L, and mostly exists in the crystalline form (43. 5%), secondly in the Fe-Mn oxidative form (23.1%). Percentages of organic, carbonate and exchangeable forms are 14. 8%, 11. l%and 7.4%, respectively. Total content of Ba in the sediment is between 158. 6 and 48. 0 ug/g. Percentages of crystalline form, Fe-Mn oxidative form and carbonate form are 78. 4% ,13. 5%and 8. 2%, respectively. Organic and exchangeable forms are not detected. The study on the mechanism of interfacial movement suggests that the salinity range of 10 is the turning point for the varied distribution of Ba. The subsidence of crystalline form affects the decrease of Ba content in suspension. The decrease mostly takes place in the salinity range lower than 10, which corresponds to the high value of Ba content in the sediment. The     

Does sediment grain size affect diatom grazing by harpacticoid copepods?

Estuarine soft sediments support a diverse group of eukaryotic and prokaryotic organisms though the role of the sediment per se for the functioning of these organisms remains largely unknown. The present study aimed to test the effect of sediment grain size on the grazing activities of harpacticoid copepods. In controlled experiments, two common intertidal harpacticoid species (Paramphiascella fulvofasciata and Nitokra spinipes) were each offered a mix of two benthic diatom species (Navicula phyllepta and Seminavis robusta) in different sedimentary conditions. Several microcosms were created using a variety of sediment types, including fine silt (<63 microm), coarser grained sands (125-250, 250-450, 100-300 microm), artificial 'sediments' of glass beads (250-500, 2000 microm) and even the absence of sediment was tested. The diatoms were enriched in the stable carbon (13)C to facilitate tracing in the harpacticoids. Both copepod species were able to graze on the diatoms with highest uptake when sediment was absent. In contrast, both harpacticoid species showed no uptake in silty conditions. In general, grazing was favoured when mean sediment grain size increased. The strong negative effect of fine grains on the grazer's efficiency can be explained by the resulting differences in the structure (and accessibility) of the diatom biofilm on the one hand and the mobility of the grazer on the other hand. In view of the subtle equilibrium between primary producers and grazers, these results might have important implications for the effect of siltation of tidal flats due to, e.g., human activities.     

Compression–shear coupling rheological constitutive model of the deep-sea sediment

In deep-sea mining engineering, the compression–shear coupling effect of the sediment on the moving tracked mining vehicle must be considered, since it is proved to be existing in compression–shear creep test of the sediment simulant. Based on the endochronic theory, the compression–shear coupling rheological model is established by the definition of intrinsic time and calculation of deviatoric tensor, where the coupling rheological parameters can be obtained by the compression–shear creep test. For simulating sinkage and traction force of the moving tracked mining vehicle, the compression–shear coupling rheological model as well as compressive rheological model and direct shear rheological model (regardless of coupling rheological effect) is programmed and introduced into RecurDyn software (with only traditional elastic–plastic constitutive model) for comparison. Research results show that the sinkage is the largest, and the traction force is the smallest under the compression–shear coupling rheological model, which could better reflect the worse working situation. The compression–shear coupling rheological model could provide theoretical basis for optimal design and safety assessment of the tracked mining vehicle.     

Arctic margin gravity highs: Deeper meaning for sediment depocenters?

Morphologic, gravity, and seismic reflection/refraction data from ca. 10,000 km of Arctic passive continental margins suggest that the numerous oval free-air gravity anomalies, their +50–150 mGal extrema typically located just landward of shelf breaks, are caused by combinations of rapidly deposited Plio-Pleistocene glacial marine sediment loads, older post-breakup sediments, and perhaps causally related density anomalies (mascons) in the underlying oceanic crust. Dispersed seismicity associated with some gravity highs may reflect ongoing brittle, flexural adjustment to the loads. Multi-channel-seismic-controlled depocenter models for several prominent highs (including the Hornsund gravity high re-examined here) suggest that sediments alone do not suffice to explain the gravity highs, unless depocenter seismic velocities have been significantly underestimated. A flexural backstripping model for the Hornsund anomaly only roughly replicates observed gravity. Subjacent 'mascons', if present below some depocenters, may be caused by (1) anomalous subsidence of initially formed dense/thin crust; (2) depocenter blanketing of early-formed crust, mitigating hydrothermal fracturing and related density reduction; or (3) metastable phase transitions, converting basalt/gabbro to denser phases (Neugebauer–Spohn hypothesis), while cracks close or fill under the increased pressures and temperatures.     

NearCoM-TVD — A quasi-3D nearshore circulation and sediment transport model

The newly developed nearshore circulation model, SHORECIRC, using a hybrid finite-difference finite-volume TVD-type scheme, is coupled with the wave model SWAN in the Nearshore Community Model (NearCoM) system. The new modeling system is named NearCoM-TVD and the purpose of this study is to report the capability and limitation of NearCoM-TVD for several coastal applications. For tidal inlet applications, the model is verified with the semi-analytical solution of Keulegan (1967) for an idealized inlet-bay system. To further evaluate the model performance in predicting nearshore circulation under intense wave–current interaction over complex bathymetry, modeled circulation patterns are validated with measured data during RCEX field experiment (MacMahan et al., 2010). For sediment transport applications, two sediment transport models are applied to predict three sandbar migration events at Duck, NC, during August to October 1994 (Gallagher et al., 1998). The model of Kobayashi et al. (2008) incorporates wave-induced onshore sediment transport rate as a function of the standard deviation of wave-induced horizontal velocities. The modeled beach profile evolution for two offshore events and one onshore event agrees well with the measured data. The second model investigated here combines two published sediment transport models, namely, the total load model driven by currents under the effect of wave stirring (Soulsby, 1997) and the wave-driven sediment transport model due to wave asymmetry/skewness (van Rijn et al., 2011). The model study with limited field data suggests that the parameterization of wave stirring is appropriate during energetic wave conditions. However, during low energy wave conditions, the effect of wave stirring needs to be re-calibrated.     

Suspended sediment transport of the Hangzhou Bay and its related hydrodynamic analyses

The 25-h measurements of current speed, flow direction, water depth, suspended sediment concentration and salinity were carried out at six anchored stations in the study area during spring and neap tides in winter of 1987 and summer of 1989. Caculations and analyses of the data obtained show that large amounts of suspended sediments are moved back and forth under the action of tidal current, and the net transport of sediment is small, with its predominance upstream in winter and downstream in summer. These calculations and analyses also suggest that the advective transport of sediment is dominant, while the vertical gravitational circulation of the suspended sediment comes next. Meantime, it is indicated that tidal currents play a major role in the suspended sediment transport, and residual flows have effect on the net transport of the suspended sediment, which is more remarkable during neap tide than during spring tide.     

Lake sediment phosphorus release management—Decision support and risk assessment framework

The release of phosphorus (P) from the sediments of eutrophic lakes is often associated with the proliferation of nuisance algal blooms, especially cyanobacteria. The successful implementation of management actions aimed at reducing such algal blooms requires an integrated approach, including both external and internal nutrient loads. The internal load of P can be a significant source of P for primary production, with greatest inputs occurring when lakes stratify and the hypolimnetic waters become anoxic. We reviewed the nature and characteristics of New Zealand lakes in relation to factors which affect the application of technologies to manage internal P loads within individual lakes. New Zealand's windy maritime climate causes lakes to mix more deeply than lakes in continental areas, which are characterised by relatively hot, calm summers. We assessed a range of management options which may be used to control internal P loads, and considered these in a de cision‐support framework aimed at identifying the key factors which may limit successful application. Methods to reduce P release from sediments include: physical approaches—such as artificial destratification, hypolimnetic aeration, enhanced lake flushing, and dredging/discing; and geochemical approaches—such as the application of alum and iron as flocculation agents, and other products as “capping” materials. The capping materials may be either a passive physical barrier (e.g., sand, gravel, clay) or an active barrier. The active barrier systems are generally pervious chemical or geochemical materials capable of binding contaminants by adsorption or precipitation processes. A decision‐support and risk assessment framework is provided to assist managers in the development of appropriate strategies for reducing or controlling internal P loads, and thus cyanobacteria blooms. A review of the sediment characteristics of lakes in the Taupo volcanic zone showed marked variability in sediment P content, and elevated geothermal arsenic concentrations in some lake sediments, which may affect the efficacy of chemical capping agents, indicating that site‐specific consideration of capping agent dose is required.     

Sulfur isotopic composition of modern seafloor hydrothermal sediment and its geological significance

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Analysis of influencing factors on fine sediment flocculation in the Changjiang Estuary

Based on the test data in dynamic water and static water, the main factors, which influence the fine sediment flocculation, are analyzed with a gray model method of correlation theory. It is shown that the main influencing factors are water temperature, settling time, salinity, grain size, sediment concentration and current velocity according to the correlation coefficients. Among them, the salinity and the sediment grain size are critical type influencing factors (CrTIF); the settling time, the sediment concentration and the velocity are continuous type influencing factors (CoTIF); and the water temperature has the characteristics of both. When the critical values of CrTIF are reached or exceeded, the fine sediments will be flocculated, but values of CrTIF will not influence the settlement strength of floes. The influence of CoTIF is continuous. The values of the CoTIF will not only influence the occurrence of flocculation but also the settlement strength of the floes.     

Numerical simulation of sediment lifted by waves and transported by tidal currents

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Distribution and composition characteristics of heavy minerals in surficial sediment of Minjiang Estuary

Heavy minerals with a size range of 0.125～49.250 mm in the surficial sediment of Minjiang Estuary are studied. Thirty-four heavy minerals have been identified, with an average content of 1.92%. Major minerals include magnetite, epidote, hematite, hornblende, ilmenite, and zircon mica. These types are the same as those in the 0.063～0. 125 mm range; however, the average content is lower, which reveals that the heavy minerals in Minjiang Estuary are mainly enriched in the very-fine sand fraction. According to the content and distribution characteristics of the major heavy minerals, Minjiang Estuary can be divided into 4 mineral assemblage zones. In each zone the assemblage of heavy minerals is greatly affected by the hydrodynamic condition and the sedimentary environment. Heavy mineral types also show that detrital matters in Minjiang Estuary are originated from the weathering and erosion of the bedrock in the Minjiang River drainage area.     

Influence of asymmetric tidal mixing on sediment dynamics in a partially mixed estuary

To investigate the influence of asymmetric tidal mixing(ATM) on sediment dynamics in tidal estuaries, we developed a vertically one-dimensional idealized analytical model, in which the M₂ tidal flow, residual flow and suspended sediment concentration(SSC) are described. Model solutions are obtained in terms of tidallyaveraged, and tidally-varying components(M₂ and M₄) of both hydrodynamics and sediment dynamics. The effect of ATM was considered with a time-varyin...     

Experimental study on bed-load sediment transport under irregular wave and current combined flow

Using an irregularly oscillating tray and flume,a series of experiments are completed to evaluate bed-load sediment transport rate under irregular wave-current coexistent fild.Testing conditions include three interaction angles 0°,45°,90° and two kinds of median sizes (0.38 and 1.10 mm).The results of transport rate show that the net sediment transport rate can be expressed approximately as the function of the maximum bottom shear stress of waves,mean shear stress of current and the grain size.     

Exchange fluxes of nutrients between sediment and sea water in the Bohai Sea

IrocrIowThere is a linkage in shallow marine systerns between sea-noor biOgaxhemical pmeessesand water column pnductivity (Bereson et al., l998). Benthic fluxes provide a significantsource of nutrients to the overlying water tO supPOrt primary pnduction and play a role in de-.creasing oxygen concentrations (van et al., l999; Cowan and Boynton, l996; Berelson etal., 1998; Friedl et al., l998; Zabel et al., l998). TherefOre, it is imPOrtant to define theediment di8genetic pathways for the …     

A budget for modern‐Holocene sediment on the South Otago continental shelf

A sediment budget for the South Otago continental shelf and coast, between Nugget Point and Otago Peninsula, reveals modern (post 6500 y) sediment input is dominated by the Clutha River (total 3.14 Mt y^‐1; Mt = 10⁶ tonnes). Contributions from the Taieri River (0.6 Mt y^‐1), the adjacent Southland shelf (0.4 Mt y^‐1), and the biogenic production of calcareous shell debris (0.25 Mt y^‐1) account for only 28% of the input. About half of the bedload (sand and gravel) reaching the Otago shelf is stored within a large nearshore sand wedge in the protected waters of Molyneux Bay, off the Clutha River. Bedload that escapes storage (1.1 Mt y^‐1) is transported north‐eastwards to be deposited on beach and inner shelf environments just north of Otago Peninsula. Suspended load (mud) accounts for over half of the sediment input (2.33 Mt y^‐1) and is nearly all transported from the study area to accumulate in north‐easterly shelf and slope depocentres.