Glacial and deglacial seafloor methane emissions from pockmarks on the northern flank of the Storegga Slide complex

The Storegga Slide complex is a multi-stage slope failure on the Norwegian continental margin where the most recent major event occurred 8.1 ka b.p. (calendar years before present). Its northern flank contains pockmark features that are commonly inferred to be related to the historical and modern venting of methane-bearing fluids. Three jumbo piston cores (JPC), one from a pockmark and two background cores at variable distances from this site (proximal, 5 km, and distal, 15 km) on the northern flank of the slide (806–1,524 m water depths), were sampled at 10 cm resolution to assess the geologic record of methane venting in the Nyegga pockmark field. Six down-core radiocarbon measurements on mixed planktonic foraminifer species reveal ages of 9.4–16.4 ka b.p. Bathymodiolus mussel shell horizons, indicators of methane-rich environments, have been dated at 15.8–17.6 and ~22 ka b.p. in the pockmark core. Stable isotope analyses on planktonic (Neogloboquadrina pachyderma sinistral) and benthic (Islandiella norcrossi, Melonis barleeanum) Foraminifera reveal δ¹⁸O values indicative of a clear glacial/deglacial transition (−1.5‰ shift in planktonic species). Both planktonic and benthic δ¹³C signatures record multiple excursions, interpreted to reflect the influence of methane in the environment; these δ¹³C excursions occur in the pockmark core and also in the distal background core. While authigenic calcite formation on the seafloor may play an important role in producing such excursions, these data together suggest the influence of methane seepage within the pockmark field over the past 25 ka, whereby seepage was particularly active between 13 and 15 ka. This is consistent with previously inferred regional increases in porewater pressure associated with glacial loading and higher sedimentation rates, which can cause gas hydrate and slope instability.     

Pockmarks off Big Sur, California

A pockmark field was discovered during EM-300 multi-beam bathymetric surveys on the lower continental slope off the Big Sur coast of California. The field contains ∼1500 pockmarks which are between 130 and 260 m in diameter, and typically are 8-12 m deep located within a 560 km² area. To investigate the origin of these features, piston cores were collected from both the interior and the flanks of the pockmarks, and remotely operated vehicle observation (ROV) video and sampling transects were conducted which passed through 19 of the pockmarks. The water column within and above the pockmarks was sampled for methane concentration. Piston cores and ROV collected push cores show that the pockmark field is composed of monotonous fine silts and clays and the cores within the pockmarks are indistinguishable from those outside the pockmarks. No evidence for either sediment winnowing or diagenetic alteration suggestive of fluid venting was obtained. ¹⁴C measurements of the organic carbon in the sediments indicate continuous sedimentation throughout the time resolution of the radiocarbon technique (∼45?000 yr BP), with a sedimentation rate of ∼10 cm per 1000 yr both within and between the pockmarks. Concentrations of methane, dissolved inorganic carbon, sulfate, chloride, and ammonium in pore water extracted from within the cores are generally similar in composition to seawater and show little change with depth, suggesting low biogeochemical activity. These pore water chemical gradients indicate that neither significant accumulations of gas are likely to exist in the shallow subsurface (∼100 m) nor is active fluid advection occurring within the sampled sediments. Taken together the data indicate that these pockmarks are more than 45?000 yr old, are presently inactive, and contain no indications of earlier fluid or gas venting events.     

Authigenic carbonates from active methane seeps offshore southwest Africa

The southwest African continental margin is well known for occurrences of active methane-rich fluid seeps associated with seafloor pockmarks at water depths ranging broadly from the shelf to the deep basins, as well as with high gas flares in the water column, gas hydrate accumulations, diagenetic carbonate crusts and highly diverse benthic faunal communities. During the M76/3a expedition of R/V METEOR in 2008, gravity cores recovered abundant authigenic carbonate concretions from three known pockmark sites—Hydrate Hole, Worm Hole, the Regab pockmark—and two sites newly discovered during that cruise, the so-called Deep Hole and Baboon Cluster. The carbonate concretions were commonly associated with seep-benthic macrofauna and occurred within sediments bearing shallow gas hydrates. This study presents selected results from a comprehensive analysis of the mineralogy and isotope geochemistry of diagenetic carbonates sampled at these five pockmark sites. The oxygen isotope stratigraphy obtained from three cores of 2–5?m length indicates a maximum age of about 60,000–80,000?years for these sediments. The authigenic carbonates comprise mostly magnesian calcite and aragonite, associated occasionally with dolomite. Their very low carbon isotopic compositions (–61.0?<?δ¹³C ‰ V-PDB?<?–40.1) suggest anaerobic oxidation of methane (AOM) as the main process controlling carbonate precipitation. The oxygen isotopic signatures (+2.4?<?δ¹⁸O ‰ V-PDB?<?+6.2) lie within the range in equilibrium under present-day/interglacial to glacial conditions of bottom seawater; alternatively, the most positive δ¹⁸O values might reflect the contribution of ¹⁸O-rich water from gas hydrate decomposition. The frequent occurrence of diagenetic gypsum crystals suggests that reduced sulphur (hydrogen sulphide, pyrite) from sub-seafloor sediments has been oxidized by oxygenated bottom water. The acidity released during this process can potentially induce the dissolution of carbonate, thereby providing enough Ca²⁺ ions for pore solutions to reach gypsum saturation; this is thought to be promoted by the bio-irrigation and burrowing activity of benthic fauna. The δ¹⁸O–δ¹³C patterns identified in the authigenic carbonates are interpreted to reflect variations in the rate of AOM during the last glacial–interglacial cycle, in turn controlled by variably strong methane fluxes through the pockmarks. These results complement the conclusions of Kasten et al. in this special issue, based on authigenic barite trends at the Hydrate Hole and Worm Hole pockmarks which were interpreted to reflect spatiotemporal variations in AOM related to subsurface gas hydrate formation–decomposition.     

Late-Quaternary variations in clay minerals along the SW continental margin of India: evidence of climatic variations

Down-core variations in illite, chlorite, smectite and kaolinite (the major clays) in two ¹⁴C-dated cores collected along the SW continental margin of India show that illite and chlorite have enhanced abundance during 20–17, 12.5, 11–9.5, and 5–4.8 ka b.p., whereas smectite accumulation is higher between 17 and 12.5, and after 9 ka b.p. The climate may have been predominantly arid at 17 (20–17), 12.5, 10.5 (11–9.5), and 4.8 ka b.p. The first three dates correspond to the last glacial maximum, Bolling-Allerod, and Younger Dryas events, respectively. The SW monsoon was variable between 17 and 15 ka b.p., and it was more stable and intense after the Younger Dryas until about 6 ka b.p. Received: 2 December 1999 / Revision accepted: 11 April 2000     

Lipid biomarkers for anaerobic oxidation of methane and sulphate reduction in cold seep sediments of Nyegga pockmarks (Norwegian margin): discrepancies in contents and carbon isotope signatures

Distributions and carbon isotopic compositions of microbial lipid biomarkers were investigated in sediment cores from the G11 and G12 pockmarks in the Nyegga sector of the Storegga Slide on the mid-Norwegian margin to explore differences in depth zonation, type and carbon assimilation mode of anaerobic methane-oxidizing archaea (ANMEs) and associated sulphate-reducing bacteria responsible for anaerobic oxidation of methane (AOM) in these cold seep environments. While the G11 site is characterised by black reduced sediments colonized by gastropods and Siboglinidae tubeworms, the G12 site has black reduced sediments devoid of fauna but surrounded by a peripheral occurrence of gastropods and white filamentous microbial mats. At both sites, bulk sediments contained abundant archaeal and bacterial lipid biomarkers substantially depleted in ¹³C, consisting mainly of isoprenoidal hydrocarbons and dialkyl glycerol diethers, fatty acids and non-isoprenoidal monoalkylglycerol ethers. At the G11 site, down-core profiles revealed that lipid biomarkers were in maximum abundance from 10 cm depth to the core bottom at 16 cm depth, associated with δ¹³C values of ?57 to ?136‰. At the G12 site, by contrast, lipid biomarkers were in high abundance in the upper 5 cm sediment layer, associated with δ¹³C values of ?43 to ?133‰. This suggests that, as expected from the benthic fauna characteristics of the sites, AOM takes place mainly at depth in the G11 pockmark but just below the seafloor in the G12 pockmark. These patterns can be explained largely by variable fluid flow rates. Furthermore, at both sites, a dominance of ANME-2 archaea accompanied by their bacterial partners is inferred based on lipid biomarker distributions and carbon isotope signatures, which is in agreement with recently published DNA analyses for the G11 pockmark. However, the present data reveal high discrepancies in the contents and δ¹³C values for both archaeal and bacterial lipid profiles, implying the possible involvement of at least two distinct AOM-related microbial consortia at the inferred AOM depth zonation of G11 and G12 pockmark sediments. In both sediment cores, the δ¹³C profiles for most archaeal lipids suggest a direct assimilation of dissolved inorganic carbon (DIC) in addition to methane by ANMEs (chemoautotrophy); constant and highly depleted δ¹³C profiles for PMI:3, an archaeal lipid biomarker presumably related to ANME-2, suggest a direct assimilation of ¹³C-depleted methane-derived carbon via AOM (methanotrophy). Evidently, the common approach of investigating lipid biomarker contents and δ¹³C signatures in cold seep sediments does not suffice to precisely discriminate between the carbon assimilation mode for each ANME archaeal group and associated bacteria. Rather, this needs to be combined with further specific labelling studies including different carbon sources (methane carbon, methane-derived organic intermediates and DIC) in order to unravel the metabolic pathways of each microbial consortium involved in AOM (ANME-1 vs. ANME-2 vs. ANME-3 archaeal group and associated bacteria).     

Sedimentary and structural control on pockmark development—evidence from the Nyegga pockmark field, NW European margin

The Nyegga region, located at water depths of about 600–800 m on the NW European continental margin, contains more than 200 pockmarks. Recently collected TOPAS seismic profiles and EM1002 bathymetric records now provide high-resolution information on their seabed and shallow sub-seabed geological setting. The identified pockmarks are up to 15 m deep, between 30 m and 600 m across and reach a maximum area of ca. 315,000 m². The pockmarks are sediment-empty features. They do not have any preferred direction of orientation and show large variations in their shape. The pockmarks are restricted to a <16.2 cal. ka old sediment unit. This unit comprises sandy mud and is characterised by sedimentation rates of ca. 1 mm/year. The pockmarks are localised over a thick late Plio-Pleistocene prograding sediment package and a polygonal faulted Miocene-Oligocene ooze-rich unit. The late Plio-Plistocene deposits host bottom simulating reflectors, indicative of gas hydrate-bearing sediments. Inspection of the newly collected high-resolution dataset, combined with previously analysed sediment cores and 2D multichannel seismic profiles, reveals that the Nyegga pockmark field does not show any strong relationship between seabed features, sub-seabed structures and the sedimentary setting. This suggests a more complex evolution history of the Nyegga pockmark field then previously thought.     

Microbially mediated methane and sulfur cycling in pockmark sediments of the Gdansk Basin, Baltic Sea

In the Russian sector of the Gdansk Basin (Baltic Sea), high organic matter influx fuels microbial processes resulting in the formation of reduced sediments with elevated methane concentrations. Investigated areas of geoacoustic anomalies (～245 km²) were found to contain three distinct geomorphologic structures (pockmarks), with a total area of ～1 km². Methane anomalies recorded in the water above one of these pockmarks were traced as high as 10 m above the bottom. In pockmark sediments, sulfate reduction and anaerobic oxidation of methane (AOM) occurred at high rates of 33 and 50 µmol dm^?3 day^?1, respectively. Integrated over 0–180 cm sediment depths, AOM exceeded methanogenesis almost tenfold. High AOM rates resulted from methane influx from deeper sediment layers. The δ¹³C signature of methane carbon (?78.1 to ?71.1‰) indicates the biogenic origin of pockmark methane. In pockmark sediments, up to 70% of reduced sulfur compounds was possibly produced via AOM.     

Pockmarks in the inner Oslofjord,Norway

Multibeam bathymetric surveys of the Inner Oslofjord, Norway have revealed a high density of pockmarks in the 179-km² inner fjord area, which contains over 500 pockmarks of varying size, typically 20–50 m in diameter and 2–10 m deep. These pockmarks have been investigated with a variety of techniques, including acoustic subbottom profiling, sedimentological and geochemical analyses of cores, remotely operated vehicle observation, and morphometry. Both the distribution and shapes of the pockmarks suggest that they are related to structures in the bedrock underlying relatively thin (<50 m) unconsolidated glacial and postglacial sediments. The data provide no direct indication of a particular mode of pockmark formation, but release of large amounts of biogenic, shallow methane seems unlikely. Several lines of evidence point to a continuous process of pockmark formation followed by inactivity, with some pockmarks recently active whereas others have been inactive for a considerable time. Some pockmarks are characterised by coarse sediment in their centres. The density, variety and easy access make this pockmark field an ideal model area for pockmark research. John S. Gray is deceased.     

Character and distribution of exposed glaciodeltaic deposits off outer Cape Cod, Massachusetts, and their effects on hydrogeology and benthic habitats

Seabed outcrops of glaciodeltaic sediments were identified in four places east of Cape Cod, Massachusetts, during seismic-reflection, multibeam bathymetric and backscatter, bottom photographic, and sediment sampling surveys. These strata record coarser-grained ice-proximal glaciofluvial topset to finer-grained distal glaciolacustrine bottomset deposition within deltaic systems that prograded southwestward into glacial lakes from the South Channel lobe about 18 ka b.p. These beds are important because they (1) influence the outer Cape’s hydrogeologic framework, and (2) constitute relatively stable, locally rough habitats within an area of seafloor dominated by mobile sand and gravelly sediment, and benefit the benthic fauna by providing shelter and a substrate amenable to burrow construction.     

The Norwegian–Barents–Svalbard (NBS) continental margin: Introducing a natural laboratory of mass wasting, hydrates, and ascent of sediment, pore water, and methane

Side-scan sonar mapping and ground-truthing of the Norwegian–Barents–Svalbard continental margin shed new light on shelf glaciation, mass wasting, hydrates, and features like the Håkon Mosby mud volcano (HMMV), reflecting upward mobility of gas, pore fluids, and sediments. Detailed HMMV examination revealed thermal gradients to 10°/m, bottom-water CH₄ and temperature anomalies, H₂S- and CH₄-based chemosynthetic ecosystems, and subbottom methane hydrate (to 25%). Seismic and chemical data suggest HMMV origins at 2–3?km depth within the 6-km-thick depocenter. The HMMV and mound fields bordering the Bjørnøyrenna slide valley and pockmarks bordering the Storegga slide may all have formed in response to sediment failure.     

Possible conditions and the formation time of the Chukchi Plateau pockmarks

The study of the bottom sediments accumulated during the last 60–65 ka in the pockmark craters of the Chukchi Plateau in the Arctic Ocean showed that their composition and lithostratigraphy in general are similar to those of the background areas. A specific feature is the presence of sedimentary interlayers and horizons with signs of gravitational stirring, carbonate mineralization, and accumulation under H₂S contamination conditions. The micropaleontological remains found in the pockmark sediments accumulated during the glacial periods are represented by redeposited species from Paleozoic, Mesozoic, and Cenozoic deposits, which are locally exposed in the pockmark walls. It was concluded that the pockmarks were formed under the influence of pulsed fluid flows. The present-day topography of the pockmarks was formed at the last stage of active defluidization (35?20 ka ago).     

Morphology of pockmarks along the western continental margin of India: Employing multibeam bathymetry and backscatter data

This study addresses the morphology of pockmarks along the western continental margin of India using multibeam bathymetry and backscatter data. Here, for the first time we have utilized the application of ArcGIS (Geographical Information System) for understanding the morphology of pockmarks from the western continental margin of India. The pockmarks observed in water depths of 145–330 m are circular, elliptical or elongated in plan-view, with an average length and width of 157 (±72) m and 83 (±19) m respectively. The average pockmark relief and perimeter are 1.9 (±0.9) m and 412 (±181) m, respectively. The pockmarks have average areas and volumes of 10 759 m² and 15 315 m³ respectively. Spatial separation that coincides with 210 m isobath divides the pockmarks into two groups with differing distributions and morphologies. These pockmarks originated from seepages of biogenic or thermogenic gas or from pore fluids from deeper sources, migrated vertically along the faults. Besides a possible structural control, the pockmark morphologies are also affected by bottom currents and/or by submarine slumping. The average acoustic backscatter strength from pockmark centre is higher (−35 dB) than the average backscatter of the total area (−40 dB), which suggests their possible linkage to the precipitation of diagenitic minerals from biodegradation of seepage material.     

Holocene evolution of Apalachicola Bay,Florida

A program of geophysical mapping and vibracoring was conducted to better understand the geologic evolution of Apalachicola Bay. Analyses of the geophysical data and sediment cores along with age control provided by 34 AMS ¹⁴C dates on marine shells and wood reveal the following history. As sea level rose in the early Holocene, fluvial deposits filled the Apalachicola River paleochannel, which extended southward under the central part of the bay and seaward across the continental shelf. Sediments to either side of the paleochannel contain abundant wood fragments, with dates documenting that those areas were forested at 8,000 ¹⁴C years b.p. As sea level continued to rise, spits formed of headland prodelta deposits. Between ∼6,400 and ∼2,500 ¹⁴C years b.p., an Apalachicola prodelta prograded and receded several times across the inner shelf that underlies the western part of the bay. An eastern deltaic lobe was active for a shorter time, between ∼5,800 and 5,100 ¹⁴C years b.p. Estuarine benthic foraminiferal assemblages occurred in the western bay as early as 6,400 ¹⁴C years b.p., and indicate that there was some physical barrier to open-ocean circulation and shelf species established by that time. It is considered that shoals formed in the region of the present barrier islands as the rising sea flooded an interstream divide. Estuarine conditions were established very early in the post-glacial flooding of the bay.     

Pockmarks and seafloor instability in the Olbia continental slope (northeastern Sardinian margin, Tyrrhenian Sea)

The seafloor morphology and the subsurface of the continental slope of the Olbia intraslope basin located along the eastern, passive Sardinian margin (Tyrrhenian Sea) has been mapped through the interpretation of high-resolution multibeam bathymetric data, coupled with air-gun and sparker seismic profiles. Two areas, corresponding to different physiographic domains, have been recognized along the Olbia continental slope. The upper slope domain, extending from 500 to 850 m water depth, exhibits a series of conical depressions, interpreted as pockmarks that are particularly frequent in seafloor sectors coincident with buried slope channels. In one case, they are aligned along a linear gully most likely reflecting the course of one of the abandoned channels. The location of the pockmarks thus highlights the importance of the distribution of lithologies within different sedimentary bodies in the subsurface in controlling fluid migration plumbing systems. A linear train of pockmarks is, however, present also away from the buried channels being related to a basement step, linked to a blind fault. Two bathymetric highs, interpreted as possible carbonate mounds, are found in connection with some of the pockmark fields. Although the genetic linkage of the carbonate mounds with seafloor fluid venting cannot be definitively substantiated by the lack of in situ measurements, the possibility of a close relationship is here proposed. The lower slope domain, from 850 m down to the base of the slope at 1,200 m water depth is characterized by a sudden gradient increase (from 2° to 6°) that is driven by the presence of the basin master fault that separates the continental slope from the basin plain. Here, a series of km-wide headwall scars due to mass wasting processes are evident. The landslides are characterized by rotated, relatively undeformed seismic strata, which sometimes evolve upslope into shallow-seated (less than 10 m), smaller scale failures and into headless chutes. Slope gradient may act as a major controlling factor on the seafloor instability along the Olbia continental slope; however, the association of landslides with pockmarks has been recognized in several continental slopes worldwide, thus the role of over-pressured fluids in triggering sediment failure in the Olbia slope can not be discarded. In the absence of direct ground truthing, the geological processes linked to subsurface structures and their seafloor expressions have been inferred through the comparison with similar settings where the interpretation of seafloor features from multibeam data has been substantiated with seafloor sampling and geochemical data.     

Pockmark-like depressions near the Goliat hydrocarbon field,Barents Sea: Morphology and genesis

Pockmarks are observed worldwide along the continental margins and are inferred to be indicators of fluid expulsion. In the present study, we have analysed multibeam bathymetry and 2D/3D seismic data from the south-western Barents Sea, in relation to gas hydrate stability field and sediment type, to examine pockmark genesis. Seismic attributes of the sediments at and beneath the seafloor have been analysed to study the factors related to pockmark formation. The seabed depths in the study area are just outside the methane hydrate stability field, but the presence of higher order hydrocarbon gases such as ethane and/or propane in the expelled fluids may cause localised gas hydrate formation. The selective occurrence of pockmarks in regions of specific seabed sediment types indicates that their formation is more closely related to the type of seabed sediment than the source path of fluid venting such as faults. The presence of high acoustic backscatter amplitudes at the centre of the pockmarks indicates harder/coarser sediments, likely linked to removal of soft material. The pockmarks show high seismic reflection amplitudes along their fringes indicating deposition of carbonates precipitated from upwelling fluids. High seismic amplitude gas anomalies underlying the region away from the pockmarks indicate active fluid flow from hydrocarbon source rocks beneath, which is blocked by overlying less permeable formations. In areas of consolidated sediments, the upward flow is limited to open fault locations, while soft sediment areas allow diffused flow of fluids and hence formation of pockmarks over a wider region, through removal of fine-grained material.     

Geophysical exploration of an active pockmark field in the Bay of Concarneau,southern Brittany,and implications for resident suspension feeders

About a decade ago, a large field of pockmarks (individual features up to 30 m in diameter and <2 m deep) was discovered in water depths of 15–40 m in the Bay of Concarneau in southern Brittany along the French Atlantic coast, covering an overall area of 36 km² and characterised by unusually high pockmark densities in places reaching 2,500 per square kilometre. As revealed by geophysical swath and subbottom profile data ground-truthed by sediment cores collected during two campaigns in 2005 and 2009, the confines of the pockmark field show a spectacular spatial association with those of a vast expanse of tube mats formed by a benthic community of the suspension-feeding amphipod Haploops nirae. The present study complements those findings with subbottom chirp profiles, seabed sonar imagery and ultrasonic backscatter data from the water column acquired in April 2011. Results show that pockmark distribution is influenced by the thickness of Holocene deposits covering an Oligocene palaeo-valley system. Two groups of pockmarks were identified: (1) a group of large (>10 m diameter), more widely scattered pockmarks deeply rooted (up to 8 ms two-way travel time, TWTT) in the Holocene palaeo-valley infills, and (2) a group of smaller, more densely spaced pockmarks shallowly rooted (up to 2 ms TWTT) in interfluve deposits. Pockmark pore water analyses revealed high methane concentrations peaking at ca. 400 μl/l at 22 and 30 cm core depth in silty sediments immediately above Haploops-bearing layers. Water column data indicate acoustic plumes above pockmarks, implying ongoing pockmark activity. Pockmark gas and/or fluid expulsion resulting in increased turbidity (resuspension of, amongst others, freshly settled phytoplankton) could at least partly account for the strong spatial association with the phytoplankton-feeding H. nirae in the Bay of Concarneau, exacerbating impacts of anthropogenically induced eutrophication and growing offshore trawling activities. Tidally driven hydraulic pumping in gas-charged pockmarks represents a good candidate as large-scale short-term triggering mechanism of pockmark activation, in addition to episodic regional seismic activity.     

More than a century of bathymetric observations and present-day shallow sediment characterization in Belfast Bay, Maine, USA: implications for pockmark field longevity

Mechanisms and timescales responsible for pockmark formation and maintenance remain uncertain, especially in areas lacking extensive thermogenic fluid deposits (e.g., previously glaciated estuaries). This study characterizes seafloor activity in the Belfast Bay, Maine nearshore pockmark field using (1) three swath bathymetry datasets collected between 1999 and 2008, complemented by analyses of shallow box-core samples for radionuclide activity and undrained shear strength, and (2) historical bathymetric data (report and smooth sheets from 1872, 1947, 1948). In addition, because repeat swath bathymetry surveys are an emerging data source, we present a selected literature review of recent studies using such datasets for seafloor change analysis. This study is the first to apply the method to a pockmark field, and characterizes macro-scale (>5 m) evolution of tens of square kilometers of highly irregular seafloor. Presence/absence analysis yielded no change in pockmark frequency or distribution over a 9-year period (1999–2008). In that time pockmarks did not detectably enlarge, truncate, elongate, or combine. Historical data indicate that pockmark chains already existed in the 19th century. Despite the lack of macroscopic changes in the field, near-bed undrained shear-strength values of less than 7 kPa and scattered downcore ¹³⁷Cs signatures indicate a highly disturbed setting. Integrating these findings with independent geophysical and geochemical observations made in the pockmark field, it can be concluded that (1) large-scale sediment resuspension and dispersion related to pockmark formation and failure do not occur frequently within this field, and (2) pockmarks can persevere in a dynamic estuarine setting that exhibits minimal modern fluid venting. Although pockmarks are conventionally thought to be long-lived features maintained by a combination of fluid venting and minimal sediment accumulation, this suggests that other mechanisms may be equally active in maintaining such irregular seafloor morphology. One such mechanism could be upwelling within pockmarks induced by near-bed currents.     

Biomarker records,organic carbon accumulation,and river discharge in the Holocene southern Kara Sea (Arctic Ocean)

Within the Russian–German research project on “Siberian River Run-off (SIRRO)” dealing with freshwater discharge and its influence on biological, geochemical, and geological processes in the Kara Sea, sedimentological and organic-geochemical investigations were carried out on two well-dated sediment cores from the Yenisei Estuary area. The main goal of this study was to quantify terrigenous organic carbon accumulation based on biomarker and bulk accumulation rate data, and its relationship to Yenisei river discharge and climate change through Holocene times. The biomarker data in both cores clearly indicate the predominance of terrigenous organic matter, reaching 70–100 and 50–80% of total organic carbon within and directly north of the estuary, respectively. During the last ca. 9 cal ka b.p. represented in the studied sediment section, siliciclastic sediment and (terrigenous) organic carbon input was strongly influenced by postglacial sea-level rise and climate-related changes in river discharge. The mid-Holocene Climatic Optimum is documented by maximum river discharge between 8.2 and 7.3 cal ka b.p. During the last 2,000 years, river discharge probably decreased, and accumulation of both terrigenous and marine organic carbon increased due to enhanced coagulation of fine-grained material.     

‘Bulls-eye’ pockmarks and polygonal faulting in the Lower Congo Basin: Relative timing and implications for fluid expulsion during shallow burial

This study describes a new type of pockmark association from the Lower Congo Basin offshore West Africa, consisting of up to 8 stacked paleopockmarks separated by intervals of drape and onlap fill. The stacked paleopockmarks occur within the depocentres of polygonally-faulted Plio-Pleistocene sediments and are distributed evenly in the downslope parts of two salt mini-basins. The majority of the stacked pockmarks initiated synchronously in the late Pliocene (~ 3 Ma) with a subordinate initiation phase in the mid Pliocene (~ 4 Ma). The primary agents in pockmark formation are interpreted to be pore water expelled during early-stage compaction together with biogenic methane. Bottom simulating reflections (BSRs) associated with free gas overlain by gas hydrates are currently found in the area. It is speculated that biogenic methane accumulated within and below a clathrate cap, which was repeatedly breached, forming pockmarks at discrete horizons separated by intervals of draping sedimentation. The mid and late Pliocene pockmark initiations appear to coincide with sea-level falls following periods of relatively stable highstand conditions. Several subsequent pockmark horizons may similarly correlate with subsequent sea-level falls during the late Pliocene and early Pleistocene. The stacked paleopockmarks are completely surrounded by polygonal faults and consistently occur within polygonal fault cells that crosscut the succession containing the stacked pockmarks. Early-stage compaction and dewatering of the Pliocene sediments thus preceded polygonal faulting, providing a constraint on the conditions leading to polygonal faulting of the fine-grained host sediments. The relationship documented here is interpreted as due to the presence of a hydrate cap in the Plio-Pleistocene mini-basins which may have retarded the normal compaction processes and facilitated pockmark formation by allowing the build up of gas hydrate and free gas in the basin centres. The relative timing and spatial relationships implies that fluids expelled due to polygonal faulting were not implicated in pockmark formation in this area.     

Comparison of marine gas hydrates in sediments of an active and passive continental margin

Two sites of the Deep Sea Drilling Project in contrasting geologic settings provide a basis for comparison of the geochemical conditions associated with marine gas hydrates in continental margin sediments. Site 533 is located at 3191 m water depth on a spit-like extension of the continental rise on a passive margin in the Atlantic Ocean. Site 568, at 2031 m water depth, is in upper slope sediment of an active accretionary margin in the Pacific Ocean. Both sites are characterized by high rates of sedimentation, and the organic carbon contents of these sediments generally exceed 0.5%. Anomalous seismic reflections that transgress sedimentary structures and parallel the seafloor, suggested the presence of gas hydrates at both sites, and, during coring, small samples of gas hydrate were recovered at subbottom depths of 238m (Site 533) and 404 m (Site 568). The principal gaseous components of the gas hydrates wer methane, ethane, and CO₂. Residual methane in sediments at both sites usually exceeded 10 mll^?1 of wet sediment. Carbon isotopic compositions of methane, CO₂, and ΣCO₂ followed parallel trends with depth, suggesting that methane formed mainly as a result of biological reduction of oxidized carbon. Salinity of pore waters decreased with depth, a likely result of gas hydrate formation. These geochemical characteristics define some of the conditions associated with the occurrence of gas hydrates formed by in situ processes in continental margin sediments.