Carbon isotopic compositions of 1,2,3,4-tetramethylbenzene in marine oil asphaltenes from the Tarim Basin: Evidence for the source formed in a strongly reducing environment

Although 1-alkyl-2,3,6-trimethylbenzenes and a high relative amount of 1,2,3,4-tetramethylbenzene have been detected in marine oils and oil asphaltenes from Tabei uplift in the Tarim Basin, their bio-logical sources are not determined. This paper deals with the molecular characteristics of typical ma-rine oil asphaltenes from Tabei and Tazhong uplift in the Tarim Basin and the stable carbon isotopic signatures of individual compounds in the pyrolysates of these asphaltenes using flash pyrolysis-gas chromatograph-mass spectrometer (PY-GC-MS) and gas chromatograph-stable isotope ratio mass spectrometer (GC-C-IRMS), respectively. Relatively abundant 1,2,3,4-tetramethylbenzene is detected in the pyrolysates of these marine oil asphaltenes from the Tarim Basin. δ 13C values of 1,2,3,4-tetrame-thylbenzene in the pyrolysates of oil asphaltenes vary from-19.6‰ to-24.0‰, while those of n-alkanes in the pyrolysates show a range from-33.2‰ to-35.1‰. The 1,2,3,4-tetramethylbenzene in the pyro-lysates of oil asphaltenes proves to be significantly enriched in 13C relative to n-alkanes in the pyro-lysates and oil asphaltenes by 10.8‰―15.2‰ and 8.4‰―13.4‰, respectively. This result indicates a contribution from photosynthetic green sulfur bacteria Chlorobiaceae to relatively abundant 1,2,3,4-tetramethylbenzene in marine oil asphaltenes from the Tarim Basin. Hence, it can be speculated that the source of most marine oil asphaltenes from the Tarim Basin was formed in a strongly reducing water body enriched in H2S under euxinic conditions.     

Hydrogen isotope composition of natural gases from the Tarim Basin and its indication of depositional environments of the source rocks

By measuring carbon and hydrogen isotope compositions for C1, C2 and C3 of 74 gas samples, natural gases from the Tarim Basin can be divided into six groups on the basis of their origins: (1) coal-type gas derived from coal measures; (2) coal-type gas generated from the T-J lacustrine mudstones; (3) oil-type gas derived from the Cambrian and low Ordovician marine source rocks; (4) oil-type gas from the source rocks deposited in the marine-transitional facies; (5) mixing gas between gas derived from the Carboniferous transitional source rocks and the Mesozoic humic gas, and (6) mixing gases of thermal genetic gas and little deep gas in the Southwest depression of the Tarim Basin. The δ D values of methane in natural gases originating from different type kerogens are affected by both palaeo-environments of the source rock formation (kerogen types) and thermal maturity, with sedimentary environment (kerogen type) as the main controlling factor. Under the similar thermal maturity, the hydrogen isotope composition of methane is more enriched in deuterium in marine environments than lacustrine one. With the increase of thermal maturity and the increase of carbon atomic numbers of gaseous alkanes, the hydrogen isotopes become enriched in deuterium. The δ D values of ethane and propane (δ D2, δ D3) are controlled mainly by thermal maturity and to a lesser degree by sedimentary environment of the source rock formation. The partial reversal of hydrogen isotopes for gaseous alkanes would be related to the microbial oxidation, mixing of sapropelic and humic gases and / or mixing of gases from similar kerogen sources with various thermal maturities. In the oil-type gas, the sulfate reduction reaction would result in the reversed order of δ D1 and δ D2 (e.g. δ D1>δ D2).     

Nd isotopic compositions of the Tethyan Himalayan Sequence in southeastern Tibet

The Himalayan orogen consists of three major lithologic units that are separated by two major north-dipping faults: the Lesser Himalayan Sequence (LHS) below the Main Central Thrust (MCT), the Greater Himalayan Crystalline Complex (GHC) above the MCT, and the Tethyan Himalayan Sequence (THS) juxtaposed by the South Tibet Detachment fault (STD) over the GHC. Due to widespread meta-morphism and intense deformation, differentiating the above three lithologic units is often difficult. This problem has been overcome by the use of Sm-Nd isotopic analysis. The previous studies suggested that the LHS can be clearly distinguished from the GHC and THS by their Nd isotope compositions. However, the lack of detailed and systematic Sm-Nd isotopic studies of the THS across the Himalaya in general has made differentiation of this unit from the nearby GHC impossible, as the two appear to share overlapping Nd compositions and model ages. To address this problem, we systematically sam-pled and analyzed Nd isotopes of the THS in southeastern Tibet directly north of Bhutan. Our study identifies two distinctive fields in a εNd -TDM plot. The first is defined by the εNd(210 Ma) values of -3.45 to -7.34 and TDM values of 1.15 to 1.29 Ga from a Late Triassic turbidite sequence, which are broadly similar to those obtained from the Lhasa block. The second field is derived from the Early Cretaceous meta-sedimentary rocks with εNd(130 Ma) values from -15.24 to -16.61 and TDM values from 1.63 to 2.00 Ga; these values are similar to those obtained from the Greater Himalayan Crystalline Complex in Bhutan directly south of our sampling traverse, which has εNd(130 Ma) values of -10.89 to -16.32 and Nd model ages (TDM) of 1.73 to 2.20 Ga. From the above observations, we suggest that the Late Triassic strata of the southeast Tibetan THS were derived from the Lhasa block in the north, while the Early Cretaceous strata of the THS were derived from a source similar to the High Himalayan Crystalline Complex or Indian craton in the south. Our interpretation is consistent with the existing palaeocurrent data and provenance analysis of the Late Triassic strata in southeastern Tibet, which indicate the sediments derived from a northern source. Thus, we suggest that the Lhasa terrane and the Indian craton were close to one another in the Late Triassic and were separated by a rift valley across which a large submarine fan was transported southward and deposited on the future northern margin of the Indian continent.     

Multifractal of spatial distribution of seismicity in Liaoning area

Making use of multifractal theory and corresponding computational method and according to the feature of evolution of spatial distribution with respect to seismicity by earthquake data in Liaoning area, earthquake activity of the area has been studied in detail. The results show that the evolution of increase in seismicity and distributive process in space are a multifractal structure. Whole characteristic of evolution in fractal increasing process of seismicity is described by obvious variation in regard toτ(q)-q curve,f(α) spectrum and other parameters before and after moderate and strong earthquakes.     

Nitrogen isotopic geochemical characteristics of crude oils in several basins of China

Nitrogen occupies a high content in crust and in atmospheric circle. It is one of the main elements in organism and an important element in sedimentary circle. Although nitrogen is little in crude oil, to a cer-tain degree, it influences the physical and chemical properties of oil, such as viscosity and density[1]. In reservoir the nitrogen-bearing compounds can form ion bonds or hydrogen bonds with substances on rock and form van der Vaals’ force among moleculae so they affect and alter the …     

Coda wave attenuation in the Parecis Basin,Amazon Craton,Brazil: sensitivity to basement depth

Small local earthquakes from two aftershock sequences in Porto dos Gaúchos, Amazon craton—Brazil, were used to estimate the coda wave attenuation in the frequency band of 1 to 24 Hz. The time-domain coda-decay method of a single backscattering model is employed to estimate frequency dependence of the quality factor (Q _c) of coda waves modeled using Q_c = Q₀ f^hQ_{\rm c} =Q_{\rm 0} f^\eta , where Q ₀ is the coda quality factor at frequency of 1 Hz and η is the frequency parameter. We also used the independent frequency model approach (Morozov, Geophys J Int, 175:239–252, 2008), based in the temporal attenuation coefficient, χ(f) instead of Q(f), given by the equation c(f)=g+\fracpfQ_e \chi (f)\!=\!\gamma \!+\!\frac{\pi f}{Q_{\rm e} }, for the calculation of the geometrical attenuation (γ) and effective attenuation (Q_e^-1 )(Q_{\rm e}^{-1} ). Q _c values have been computed at central frequencies (and band) of 1.5 (1–2), 3.0 (2–4), 6.0 (4–8), 9.0 (6–12), 12 (8–16), and 18 (12–24) Hz for five different datasets selected according to the geotectonic environment as well as the ability to sample shallow or deeper structures, particularly the sediments of the Parecis basin and the crystalline basement of the Amazon craton. For the Parecis basin Q_c = (98±12)f^(1.14±0.08)Q_{\rm c} =(98\pm 12)f^{(1.14\pm 0.08)}, for the surrounding shield Q_c = (167±46)f^(1.03±0.04)Q_{\rm c} =(167\pm 46)f^{(1.03\pm 0.04)}, and for the whole region of Porto dos Gaúchos Q_c = (99±19)f^(1.17±0.02)Q_{\rm c} =(99\pm 19)f^{(1.17\pm 0.02)}. Using the independent frequency model, we found: for the cratonic zone, γ = 0.014 s^− 1, Q_e^-1 = 0.0001Q_{\rm e}^{-1} =0.0001, ν ≈ 1.12; for the basin zone with sediments of ~500 m, γ = 0.031 s^− 1, Q_e^-1 = 0.0003Q_{\rm e}^{-1} =0.0003, ν ≈ 1.27; and for the Parecis basin with sediments of ~1,000 m, γ = 0.047 s^− 1, Q_e^-1 = 0.0005Q_{\rm e}^{-1} =0.0005, ν ≈ 1.42. Analysis of the attenuation factor (Q _c) for different values of the geometrical spreading parameter (ν) indicated that an increase of ν generally causes an increase in Q _c, both in the basin as well as in the craton. But the differences in the attenuation between different geological environments are maintained for different models of geometrical spreading. It was shown that the energy of coda waves is attenuated more strongly in the sediments, Q_c = (78±23)f^(1.17±0.14)Q_{\rm c} =(78\pm 23)f^{(1.17\pm 0.14)} (in the deepest part of the basin), than in the basement, Q_c = (167±46)f^(1.03±0.04)Q_{\rm c} =(167\pm 46)f^{(1.03\pm 0.04)} (in the craton). Thus, the coda wave analysis can contribute to studies of geological structures in the upper crust, as the average coda quality factor is dependent on the thickness of sedimentary layer.     

An evaluation method of hydrocarbon generating potential of highly mature and over-mature marine carbonate

How to restore the residual organic carbon and residual hydrocarbon-generating potential is discussed based on the hydrocarbon degradability of source rock. The results indicate there is linear function relationship between the restoring coefficient of residual organic carbon (K_c) and the vitrinite reflectance (R _o%) of various kinds of source rock, but the relationship is secondary functional between the restoring coefficient of residual hydrocarbon-generating potential (K_s) and the vitrinite reflectance (R _o%). It is pointed out thatKc = (1 -Dresidual)/(1 -D _primary),Ks= Kc (D _primary/D _residual). The restoration of residual organic carbon and hydrocarbon-generating potential of the Cambrian and Ordovician highly mature marine carbonate in the Tarim Basin and North China region shows that the lower limit value of hydrocarbon generating potential and the organic matter abundance of carbonate source rock are basically the same as that of clastic rock. The technical difficulty in hydrocarbon generating evaluation of highly mature and overmature carbonate is solved.     

Aoyitake plagiogranite in western Tarim Block, NW China: Age, geochemistry, petrogenesis and its tectonic implications

SHRIMPP U-Pb zircon age and geochemical and Nd isotopic data are reported for the Aoyitake plagiogranite in western Tarim Block, NW China. The plagiogranite intruded the Middle Pro- terozoic and Lower Carboniferous with an exposure area of ca. 60 km2 and crystallized at 330.7±4.8 Ma. Rock types mainly include tonalite, trondhjemite and minor amounts of diorite and quartz-diorite. Feldspars in the rocks are dominated by oligoclase-andesine, and minor perthite observed locally. The granites are sodic with Na/K ratios (molar) between 4 and 87. Total REE (50-220 ppm) show a clear positive correlation with SiO2. There is no LRRE/HREE fractionation (LaN/YbN=0.5-1.5), me- dium negative Eu anomalies (δ Eu=0.3-0.6), high Y content and low Sr/Y ratio (~1.0). These granites exhibit relatively juvenile Nd T2DM model ages of 470 to 580 Ma and positive εNd(331 Ma) values of 6.23 to 7.65. The aforementioned characteristics are similar to those of ocean island or ocean ridge plagiogranites. However, the regional geology, especially its scale, precludes that the plagiogranite pluton was derived directly from fractionational crystallization of mantle-derived basaltic magma. We interpreted that the primary magma of the pluton might be tonalitic in composition generated by ca. 50% partial melting of the juvenile basaltic crust. The primary magma experienced intensive frac- tionational crystallization, and intruded into the middle to upper crusts to form the granite pluton. In combination with the previous regional geological data, it is concluded that the plagiogranite pluton was emplaced within the Tarim Block in respond to the Carboniferous continental rifting along the Tianshan orogenic belt.     

Bacterial community in deep subseafloor sediments from the western Pacific “warm pool”

The bacterial community in deep subseafloor sediments at a depth of 230 cm from the western Pacific “warm pool” is studied by construction of 16S rDNA clone library and PCR-RFLP (Restriction Fragment Length Polymorphism) analysis. The results indicate that the bacterial community in these sediments is mainly composed of five groups: α-Proteobacteria, β-Proteobacteria, CFB group (Cytophaga / Flexibacteria / Bacteroides), Acidobacteria and gram positive bacteria, with a few genera detected in each group. The most abundant bacteria group is α-Proteobacteria, and the next is β-Proteobacteria. The dominant species in α-and β-Proteobacteria are Sphingomonas paucimobilis and Pseudomonas alcaligenes respectively. The CFB group is simply composed of members belonging to Flavobacterium. The gram positive bacteria are rich, and mainly consists of the genus Geobacillus. The analysis of bacterial community indicates that organic matter is still abundant in the subseafloor sediments at the depth of 230 cm in the western Pacific “warm pool”. These bacteria in this deep biosphere may play an important role in the nitrogen cycle of deep sea sediments at “warm pool”. Supported by the National Key Basic Research Support Foundation of China (Grant No. G2000078500) and China Ocean Mineral Resources R&D Association Project (Grant No. DY105-4-2-4)     

Mineralogical analyses and in vitro screening tests for the rapid evaluation of the health hazard of volcanic ash at Rabaul volcano, Papua New Guinea

The continuous ash and gas emissions from the Tavurvur cone in Rabaul caldera, Papua New Guinea, during 2007–08, raised concerns regarding how exposure would affect the respiratory health of nearby populations and impact on the environment. As part of a formal evaluation of the effects of volcanic emissions on public health, we investigated the potential health hazard of the ash using a suite of selected mineralogical analyses and in vitro toxicity screening tests. The trachy-andesitic ash comprised 2.1–6.7 vol.% respirable (sub-4 μm diameter) particles. The crystalline silica content was 1.9–5.0 wt.% cristobalite (in the bulk sample) with trace amounts of quartz and/or tridymite. Scanning electron microscopy showed that the ash particles were angular with sparse, fibre-like particles (∼3–60 μm max. diameter) observed in some samples, which we confirmed to be CaSO₄ (gypsum, at <6 wt.% in the bulk samples) and not asbestiform fibres. The ash specific surface area was low (0.1–2.7 m² g⁻¹). The leached solution from one of the ash samples was slightly acidic (pH 5.6), but did not contain high levels of toxic metals (such as F, Cu, Zn, Mn, As, Ni and Cd) when compared to previously tested volcanic ash leachates. Ash samples generated potentially-harmful hydroxyl radicals through an iron-mediated catalytic reaction, in the range of 0.15–2.47 μmol m⁻² (after 30 min of reaction). However, measurement of particle oxidative capacity (potential oxidative stress reaction using ascorbic acid) and silica-like injury to red blood cells (erythrolysis assay, i.e. measurement of cell death) nevertheless revealed low biological reactivity. The findings suggest that acute exposure to the ash would have a limited potential to exacerbate pre-existing conditions such as asthma or chronic bronchitis, and the potential for chronic exposure leading to silicosis was low.     

Prediction of rockburst probability given seismic energy and factors defined by the expert method of hazard evaluation (MRG)

In this paper we suggest that conditional estimator/predictor of rockburst probability (and rockburst hazard, P ^T (t)) can be approximated with the formula P ^T (t) = P ₁(θ ₁)…P _N (θ _N )·P _dyn ^T (t), where P _dyn ^T (t) is a time-dependent probability of rockburst given only the predicted seismic energy parameters, while P _i (θ _i ) are amplifying coefficients due to local geologic and mining conditions, as defined by the Expert Method of (rockburst) Hazard Evaluation (MRG) known in the Polish mining industry. All the elements of the formula are (approximately) calculable (on-line) and the resulting P ^T value satisfies inequalities 0 ≤ P ^T (t) ≤ 1. As a result, the hazard space (0–1) can be always divided into smaller subspaces (e.g., 0–10⁻⁵, 10⁻⁵–10⁻⁴, 10⁻⁴–10⁻³, 10⁻³–1), possibly named with symbols (e.g., A, B, C, D, …) called “hazard states” — which saves the prediction users from worrying of probabilities. The estimator P ^T can be interpreted as a formal statement of (reformulated) Comprehensive Method of Rockburst State of Hazard Evaluation, well known in Polish mining industry. The estimator P ^T is natural, logically consistent and physically interpretable. Due to full formalization, it can be easily generalized, incorporating relevant information from other sources/methods.     

Features and physical process of the dynamic evolution pattern of ground resistivity precursor front

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Alignment silkworms as seismic animal anomalous behavior (SAAB) and electromagnetic model of a fault: a theory and laboratory experiment

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Effects of abnormally high heat stress on petroleum in reservoir

An igneous intrusion of 94m thick was discovered intruding into the Silurian sandstone from Tazhong 18 Well. The petroleum previously preserved in the Silurian sandstone reservoir was altered into black carbonaceous bitumen by abnormally high heat stress induced by the igneous intrusion. The reflectance of the carbonaceous bitumen reaches as high as 3.54%, indicating that the bitumen had evolved into a high thermal evolution level. Similar to the Silurian samples from the neighboring Tazhong 11, Tazhong 12, Tazhong 45 and Tazhong 47 wells, the distribution of C₂₇, C₂₈ and C₂₉ steranes of the carbonaceous bitumen is still “V”-shaped and can still be employed as an efficient parameter in oil source correlation. The “V”-shaped distribution indicates that the hydrocarbons from the Tazhong 18 and the neighboring wells were all generated from the Middle-Upper Ordovician hydrocarbon source rocks. However, the oil source correlation parameters associated with and terpanes had been changed greatly by the high heat stress and can no longer be used in oil source correlation. The δ ¹³C values of the petroleum from the neighboring wells are between −32.53%. and −33.37%., coincident with those of the Paleozoic marine petroleum in the Tarim Basin. However, the δ ¹³C values of the carbonaceous bitumen from the Tazhong 18 Well are between −27.18%. and −29.26%., isotopically much heavier than the petroleum from the neighboring wells. The content of light hydrocarbons (nC₁₄−nC₂₀) of the saturated hydrocarbon fraction in the carbonaceous bitumen is extremely higher than the content of heavy hydrocarbons. The light/heavy hydrocarbon ratios (ΣnC₂₁ ⁻/ΣnC₂₂ ⁺ are between 4.56 and 39.17. In the saturated fraction, the even numbered hydrocarbons are predominant to the odd numbered, and the OEP (Odd to Even Predominance) values are between 0.22 and 0.49. However, the content of light hydrocarbons in the petroleum from the neighboring wells is relatively low and the content of the even numbered hydrocarbons is almost equal to that of the odd numbered. Compared with the samples from the neighboring wells, the abundance of non-alkylated aromatic hydrocarbons, such as phenanthrenes, and polycyclic aromatic hydrocarbons (PAHs), such as fluoranthane, pyrene, benzo[a]anthracene and benzofluoranthene, are relatively high. Supported by the National Key Basic Research and Development Project (Grant No. 2005CB422103)     

Discovery and its geological significance of the mantle-derived helium in the inclusions of the Ordovician oil-bearing reservoir rocks in the Huanghua depression,China

The values of the helium isotopes in the inclusions of the Ordovician reservoir rocks in the Kongxi buried hill belt in the Huanghua depression were first measured and the source of helium and its geological significance were investigated in comparison with those of the helium isotopes in the conclusions in the Ordovician rocks in the Ordos basin and the Tarim basin. The input of the mantle-derived helium into the inclusions in the carbonate reservoir rocks was found from the Konggu 3 well, the Konggu 4 well, and the Konggu 7 well in the Kongxi buried hill belt. The 3He/4He and R/Ra in the conclusions in the Ordovician oil-bearing reservoir rocks in the Konggu 7 well average 2.54×10-6(3) (sample quantity, the same below) and 1.82(3), respectively. The percent of the mantle-derived helium in the inclusions of the reservoir rocks in the Konggu 7 well reaches up to an average of 23.0%(3). The age of the contribution of the mantle-derived helium to the inclusions in the Kongxi buried hill belt is in the La     

U-Pb zircon geochronology and Hf isotope study of metamorphosed basic-ultrabasic rocks from metamorphic basement in southwestern Zhejiang: The response of the Cathaysia Block to Indosinian orogenic event

A combined study using LA-ICP-MS U-Pb dating, Hf isotopes, trace elements and the Ti-in-zircon geo-thermometer was carried out on zircons from the metamorphosed basic-ultrabasic rocks in the meta-morphic basement of the Cathaysia Block, southwestern Zhejiang Province. The formation and meta-morphic ages of the rocks from the metamorphic basement of the Cathaysia Block were determined based on zircon U-Pb geochronology. The age for the magmatic crystalline zircons from the protolith is about 1.85 Ga. The εHf(t) values of the older zircons were from ?7 to ?3, with two-stage model Hf ages (TDM2LC) of about 2.9 to 3.4 Ga, indicating that the source material was derived from anatexis and recy-cling of the Archean crust. The newly formed metamorphic zircons yielded U-Pb ages of 260―230 Ma. The metamorphic temperature calculated using the Ti-in-zircon geothermometer ranged from 610 to 720℃, consistent with the results from petrographic observations, indicating that the Cathaysia Block experienced an amphibolite facies metamorphism during the Indosinian. Results from this study pro-vided an important timeframe for the tectonic evolution in South China and the Southeast Asia during the Late Permian and Early Triassic times.     

抚仙湖秋、冬季光衰减特征及其与有色可溶性有机物的关系

为了研究抚仙湖紫外辐射(UVR)和光合有效辐射(PAR)衰减的时空特征及其与有色可溶性有机物(CDOM)、悬浮物(SS)、浮游植物(叶绿素a表征)等因子的关系,于2014年10月(秋季)、2015年1月(冬季)开展现场调查,结果显示:秋季不同波长(段)的漫射衰减系数Kd(305)、Kd(340)和Kd(PAR)分别为1.27±0.12、0.68±0.11和0.32±0.13 m-1,冬季分别为1.13±0.10、0.63±0.07和0.36±0.07 m-1;秋季CDOM的不同波长吸收系数ag(254)、ag(305)和ag(340)分别为4.09±0.26、1.18±0.09和0.57±0.05 m-1,冬季分别为2.95±0.24、0.61±0.11和0.11±0.07 m-1,秋季ag(254)、ag(305)和ag(340)显著高于冬季;秋季Kd(305)显著大于冬季,这与秋季(雨季)较高的CDOM丰度、浮游植物生物量(及SS浓度)有关.秋季ag(305)/Kd(305)、ag(340)/Kd(340)均显著高于冬季;秋季及秋冬季整体而言,ag(254)与Kd(305)、Kd(340)呈显著正相关,各多元逐步回归方程中均包含ag(254),说明CDOM吸收对UVR的衰减有重要贡献.空间差异方面,秋季北部的ag(254)、Kd(305)和Kd(340)显著高于南部,冬季南北部无明显差异,或与雨旱季北岸河流输入的CDOM和SS的情况有关.此外,浮游植物对UV-B衰减的影响和SS(与CDOM的交互作用)对UV-A衰减的影响更在于季节变化方面,而影响UVR、PAR衰减的各因子的相对贡献有待进一步量化.     

Carbon isotope composition of the Lower Triassic marine carbonates, Lower Yangtze Region, South China

The Early Triassic is a critical period in earth his- tory. A series of events such as volcano eruptions[1,2], sea-level fluctuations, changes in environmental con- ditions[3], mass extinctions[4,5] as well as global negative carbon isotope excursions[6-9] have been discovered in the uppermost Permian or across the Permian-Triassic boundary. Large scale sea-level rise[10-12], restoration of environment conditions, re- covery of ecosystem[13], including gradual carbon iso- tope rise[14] occur…     

Paleomagnetism and Cyclostratigraphy of the Middle Ordovician Krivolutsky Suite,Krivaya Luka Section,Southern Siberian Platform: Record of Non-Synchronous NRM-Components or a Non-Axial Geomagnetic Field?

The Middle Ordovician Volginsky and Kirensky fossil zones were sampled in the Krivaya Luka section (Krivolutsky suite) that outcrops along the Lena river in Siberia. The Volginsky and Kirensky zones are coeval to the Llandeilo in the global geologic time scale. The Krivaya Luka section consists of siltstones, clays, sandstones, and limestones, and displays a remarkably distinct sedimentary cyclicity, especially in its reddish middle part.Stepwise thermal demagnetization yields three NRM components. Component A, isolated in the 100—250°C interval can be either normal or reversed. The normal A-component has a direction close to recent local magnetic field. The reversed A-component directions are scattered around a direction close to that of the lower Triassic Siberian traps. Component B has unblocking temperatures that range from 400 to 500°C and is represented mainly by normal polarity directions. The B-component, isolated from rocks of the middle part of the section is of a normal polarity with D = 176.5°, I = 30.0° and a North pole position at 16.2°S, 111.3°E. The other parts of the section are characterized by intermediate B-directions, which resulted possibly by partially overlapping A- and C-components. The highest temperature dual-polarity component C was isolated in the 550—670°C interval, resulting in the detection of two complete polarity zones and three magnetic reversals. The C-component is characterized by the following mean directions: for the reversed component D = 335.7°, I = 6.9°, and for the normal component D = 188.6°, I = 28.0°, which is very close to the normal polarity directions of the B-component. The corresponding paleomagnetic North pole for reversed polarity rocks is 32.6°S, 137°E, which is typical of Middle Ordovician rocks from Siberia – the mean pole for Llanvirn-Llandeilo is 30°S, 136°E (cf. Smethurst et al., 1998) – whereas for normal polarity rocks the pole position 17.2°S, 99.1°E is markedly different. Nevertheless, we assume that the C-component records the ancient geomagnetic field of Ordovician times, even though it does not pass the reversals test. This could be explained by overlapping NRM unblocking temperature spectra for the B and C components. In this case, the paleomagnetic pole positions should be interpreted with some caution.In addition, the section was logged and sampled in detail for cyclostratigraphic purposes. Spectral analysis in the depth domain using the high-field susceptibility as input parameter showed that the observed cyclicity is most likely orbitally forced. Detected spectral peaks (significant at the 95% confidence level) were close to the expected positions of the periodicities of precession, obliquity and eccentricity for the Ordovician. Consequently, the average sediment accumulation rate is estimated at 3.5 cm/kyr. Extrapolating this sedimentation rate yields a total duration of at least 1 Myr for the Volginsky fossil zone and 1.2 Myr for the entire Krivaya Luka section.     

Numerical simulations of transport of non-ergodic solute plumes in heterogeneous aquifers

Transport of non-ergodic solute plumes by steady-state groundwater flow with a uniform mean velocity, μ, were simulated with Monte Carlo approach in a two-dimensional heterogeneous and statistically isotropic aquifer whose transmissivity, T, is log-normally distributed with an exponential covariance. The ensemble averages of the second spatial moments of the plume about its center of mass, <S _{i i} (t)>, and the plume centroid covariance, R _{i i} (t) (i=1,2), were simulated for the variance of Y=log T, σ _Y ²=0.1, 0.5 and 1.0 and line sources normal or parallel to μ of three dimensionless lengths, 1, 5, and 10. For σ _Y ²=0.1, all simulated <S _{i i} (t)>−S _{i i} (0) and R _{i i} (t) agree well with the first-order theoretical values, where S _{i i} (0) are the initial values of S _{i i} (t). For σ _Y ²=0.5 and 1.0 and the line sources normal to μ, the simulated longitudinal moments, <S ₁₁(t)>−S ₁₁(0) and R ₁₁(t), agree well with the first-order theoretical results but the simulated transverse moments <S ₂₂(t)>−S ₂₂(0) and R ₂₂(t) are significantly larger than the first-order values. For the same two larger values of σ _Y ² but the line sources parallel to μ, the simulated <S ₁₁(t)>−S ₁₁(0) are larger than but the simulated R ₁₁ are smaller than the first-order values, and both simulated <S ₂₂(t)>−S ₂₂(0) and R ₂₂(t) stay larger than the first-order values. For a fixed value of σ _Y ², the summations of <S _{i i} (t)>−S _{i i} (0) and R _{i i} , i.e., X _{i i} (i=1,2), remain almost the same no matter what kind of source simulated. The simulated X ₁₁ are in good agreement with the first-order theory but the simulated X ₂₂ are significantly larger than the first-order values. The simulated X ₂₂, however, are in excellent agreement with a previous modeling result and both of them are very close to the values derived using Corrsin's conjecture. It is found that the transverse moments may be significantly underestimated if less accurate hydraulic head solutions are used and that the decreasing of <S ₂₂(t)>−S ₂₂(0) with time or a negative effective dispersivity, defined as , may happen in the case of a line source parallel to μ where σ _Y ² is small.