H<Stack><Subscript>2</Subscript><Superscript>16</Superscript></Stack>O and H<Stack><Subscript>2</Subscript><Superscript>18</Superscript></Stack>O maser emission from gas-dust clouds

The collisional pumping of H₂¹⁶O and H₂¹⁸O masers in hot dense gas-dust clouds has been simulated numerically. New data on the rate coefficients for collisional transitions from Faure et al. (2007) were used in the calculations. The possibility of detecting H₂¹⁸O emission in 22.2-GHz H₂¹⁶O maser sources is investigated. The medium is shown to become optically thick in the H₂¹⁸O lines for which an inverted level population is observed at H₂O column densities of ∼1019–1020 cm⁻². A simultaneous observation of H₂¹⁸O emission and H₂¹⁶O maser emission in the same source will allow the physical conditions in the gas-dust cloud to be refined.     

The expansion field: the value of <Emphasis Type="Italic">H</Emphasis><Subscript>0</Subscript>

Any calibration of the present value of the Hubble constant (H ₀) requires recession velocities and distances of galaxies. While the conversion of observed velocities into true recession velocities has only a small effect on the result, the derivation of unbiased distances which rest on a solid zero point and cover a useful range of about 4–30 Mpc is crucial. A list of 279 such galaxy distances within v < 2,000 km s⁻¹ is given which are derived from the tip of the red-giant branch (TRGB), from Cepheids, and/or from supernovae of type Ia (SNe Ia). Their random errors are not more than 0.15 mag as shown by intercomparison. They trace a linear expansion field within narrow margins, supported also by external evidence, from v = 250 to at least 2,000 km s⁻¹. Additional 62 distant SNe Ia confirm the linearity to at least 20,000 km s⁻¹. The dispersion about the Hubble line is dominated by random peculiar velocities, amounting locally to <100 km s⁻¹ but increasing outwards. Due to the linearity of the expansion field the Hubble constant H ₀ can be found at any distance >4.5 Mpc. RR Lyr star-calibrated TRGB distances of 78 galaxies above this limit give H ₀ = 63.0 ± 1.6 at an effective distance of 6 Mpc. They compensate the effect of peculiar motions by their large number. Support for this result comes from 28 independently calibrated Cepheids that give H ₀ = 63.4 ± 1.7 at 15 Mpc. This agrees also with the large-scale value of H ₀ = 61.2 ± 0.5 from the distant, Cepheid-calibrated SNe Ia. A mean value of H ₀ = 62.3 ± 1.3 is adopted. Because the value depends on two independent zero points of the distance scale its systematic error is estimated to be 6%. Other determinations of H ₀ are discussed. They either conform with the quoted value (e.g. line width data of spirals or the D _n −σ method of E galaxies) or are judged to be inconclusive. Typical errors of H ₀ come from the use of a universal, yet unjustified P–L relation of Cepheids, the neglect of selection bias in magnitude-limited samples, or they are inherent to the adopted models.     

Electronic Sputtering Analysis of Astrophysical Ices

Experimental results on fast ion collision with icy surfaces having astrophysical interest are presented. ²⁵²Cf fission fragments projectiles were used to induce ejection of ionized material from H₂O, CO₂, CO, NH₃, N₂, O₂ and Ar ices; the secondary ions were identified by time-of-flight mass spectrometry. It is observed that all the bombarded frozen gas targets emit cluster ions which have the structure X_nR^±, where X is the neutral ice molecule and R^± is either an atomic or a molecular ion. The shape of the positive or negative ion mass spectra is characterized by a decreasing yield as the emitted ion mass increases and is generally described by the sum of two exponential functions. The positive ion water ice spectrum is dominated by the series (H₂O)_nH₃O⁺ and the negative ion spectrum by the series (H₂O)_nOH⁻ and (H₂O)_nO⁻. The positive ion CO₂ ice spectrum is characterized by R⁺ = C⁺, O⁺, CO⁺, O₂⁺ or CO₂⁺ and the negative one by R⁻ = CO₃⁻. The dominant series for ammonia ice correspond to R⁺ = NH₄⁺ and to R⁻ = NH₂⁻. The oxygen series are better described by (O₃)_nO_m⁺ secondary ions where m = 1, 2 or 3. Two positive ion series exist for N₂ ice: (N₂)_nN₂⁺ and (N₂)_nN⁺. For argon positive secondary ions, only the (Ar)_nAr⁺ series was observed. Most of the detected molecular ions were formed by one-step reactions. Ice temperature was varied from ∼20 K to complete sublimation.     

Origin,Bulk Chemical Composition And Physical Structure Of The Galilean Satellites Of Jupiter: A Post-Galileo Analysis

The origin of Jupiter and the Galilean satellite system is examinedin the light of the new data that has been obtained by the NASA Galileo Project. In particular, special attention is given to a theory of satellite origin which was put forward at the start of the Galileo Mission and on the basis of which several predictions have now been proven successful (Prentice, 1996a–c). These predictions concern the chemical composition of Jupiter's atmosphere and the physical structure of the satellites. According to the proposed theory of satellite origin, each of the Galilean satellites formed by chemical condensation and gravitational accumulation of solid grains within a concentricfamily of orbiting gas rings. These rings were cast off equatorially by the rotating proto-Jovian cloud (PJC) which contracted gravitationally to form Jupiter some 4 billion years ago. The PJC formed from the gas and grains left over from the gas ring that had been shed at Jupiter's orbit by the contracting proto-solar cloud (PSC). Supersonic turbulentconvection provides the means for shedding discrete gas rings.The temperatures T_n of the system of gas rings shed by the PSCand PJC vary with their respective mean orbital radii R_n (n = 0, 1, 2, Ϊ ) according as T_n ∝ R_n ^-0.9. If the planet Mercury condenses at 1640 K, so accounting for the high density ofthat planet via a process of chemical fractionation between iron and silicates, then T_n at Jupiter's orbit is 158 K. Only 35% of the water vapour condenses out. Thus fractionation between rock and ice, together with an enhancement in the abundance of solids relative to gas which takes place through gravitational sedimentation of solids onto the mean orbit of the gas ring, ensures nearly equal proportions of rock and ice in each of Ganymede and Callisto. Io and Europa condense above the H₂O ice point and consist solely of hydrated rock (h-rock). The Ganymedan condensate consists of h-rock and H₂O ice. For Callisto, NH₃ ice makes up ∼5% of the condensate mass next to h-rock (∼50%) and H₂O ice (∼45%). Detailed thermal and structural models for each of Europa, Ganymedeand Callisto are constructed on the basis of the above initial bulk chemicalcompositions. For Europa (E), a predicted 2-zone model consisting of a dehydrated rock core of mass 0.912M_E and a 150 km thick frozen mantle of salty H₂O yields a moment-of-inertiacoefficient which matches the Galileo Orbiter gravity measurement. For Ganymede (G), a 3-zone model possessing an inner core of solid FeS and mass ∼0.116M_G, and an outer H₂O ice mantle of mass ∼0.502M_G is needed to explain the gravity data.Ganymede's native magnetic field was formed by thermoremanent magnetization of Fe₃O₄. A new Callisto (C) model is proposed consisting of a core of mass 0.826M_C containing a uniform mixture of h-rock (60% by mass) and H₂O and NH₃ ices, and capped by a mantle of pure ice. This model may have the capacity to yield a thin layer of liquid NH₃ċ2H₂O at the core boundary, in line with Galileo's discovery of an induced magnetic field This revised version was published online in July 2006 with corrections to the Cover Date.     

Carbon dioxide on planetary bodies: Theoretical and experimental studies of molecular complexes

An absorption band at ∼4.26 μm wavelength attributed to the asymmetric stretching mode of CO in CO₂ has been found on two satellites of Jupiter and several satellites of Saturn. The wavelength of pure CO₂ ice determined in the laboratory is 4.2675 μm, indicating that the CO₂ on the satellites occurs either trapped in a host material, or in a chemical or physical complex with other materials, resulting in a blue shift of the wavelength of the band. In frequency units, the shifts in the satellite spectra range from 3.7 to 11.3 cm⁻¹. We have performed ab initio quantum chemical calculations of CO₂ molecules chemically complexed with one, two, and more H₂O molecules and molecules of CH₃OH to explore the possibility that the blue shift of the band is caused by chemical complexing of CO₂ with other volatile materials. Our computations of the harmonic and anharmonic vibrational frequencies using high levels of theory show a frequency shift to the blue by 5 cm⁻¹ from pure CO₂ to CO-H₂O, and an additional 5 cm⁻¹ from CO₂-H₂O to CO₂-2H₂O. Complexing with more than two H₂O molecules does not increase the blue shift. Complexes of CO₂ with one molecule of CH₃OH and with one CH₃OH plus one H₂O molecule produce smaller shifts than the CO₂-2H₂O complex. Laboratory studies of CO₂:H₂O in a solid N₂ matrix also show a blue shift of the asymmetric stretching mode.     

Astrophysically useful radiative transition parameters for?the?e1Π–X1Σ+ and 1Σ+–X1Σ+ systems of zirconium oxide

The zirconium oxide (ZrO) is well known for its astrophysical importance. The radiative transition parameters that include Franck-Condon (FC) factor, r-centroid, electronic transition moments, Einstein coefficient, band oscillator strengths, radiative life time and effective vibrational temperature have been estimated for e ¹Π–X ¹Σ⁺ and ¹Σ⁺–X ¹Σ⁺ band systems of ⁹⁰ZrO molecule for the experimentally known vibrational levels using RKR potential energy curves. A reliable numerical integration method has been used to solve the radial Schr?dinger equation for the vibrational wave functions of upper and lower electronic states based on the latest available spectroscopic data and known wavelengths. The estimated radiative transition parameters are tabulated. The effective vibrational temperatures of these band systems of ⁹⁰ZrO molecule are found to be below 4200 K. Hence, the radiative transition parameters help us to ascertain the presence of ⁹⁰ZrO molecule in the interstellar medium, S stars and sunspots.     

Transition probabilities and dissociation energy of astrophysical molecule GeH

The Franck-Condon factors andr-centroids, which are very closely related to vibrational transition probabilities, have been evaluated by the more reliable numerical integration procedure for the bands of A ² Δ - X² π_r system of astrophysical molecule GeH, using a suitable potential. The dissociation energy for the electronic ground state of astrophysical molecule GeH has been estimated precisely as D ⁰ ₀ = 2.69 ± 0.05 eV by fitting the empirical potential function to the experimental potential energy curve using correlation coefficient. This revised version was published online in July 2006 with corrections to the Cover Date.     

The <Emphasis Type="Italic">UBV</Emphasis> photometry of variable stars from absolute spectrophotometric data

From the results of long-term observations, data on the energy distribution in the spectra of 116 variable stars of different types have been obtained. From the published response curves of the UBV system, the magnitudes and color indexes were calculated. The mean accuracy of the calculated values is σ _v ≃ 0. ^m 04, σ _bv ≃ 0. ^m 03, and σ _ub ≃ 0. ^m 06.     

HD/H<Subscript>2</Subscript> molecular clouds in the early Universe: The problem of primordial deuterium

We have detected new HD absorption systems at high redshifts, z _abs = 2.626 and z _abs = 1.777, identified in the spectra of the quasars J0812+3208 and Q1331+170, respectively. Each of these systems consists of two subsystems. The HD column densities have been determined: log N _HD^A = 15.70 ± 0.07 for z _A = 2.626443(2) and log N _HD^B = 12.98 ± 0.22 for z _B = 2.626276(2) in the spectrum of J0812+3208 and log N _HD^C = 14.83 ± 0.15 for z _C = 1.77637(2) and log N _HD^D = 14.61 ± 0.20 for z _D = 1.77670(3) in the spectrum of Q1331+170. The measured HD/H₂ ratio for three of these subsystems has been found to be considerably higher than its values typical of clouds in our Galaxy.We discuss the problem of determining the primordial deuterium abundance, which is most sensitive to the baryon density of the Universe Ω_b. Using a well-known model for the chemistry of a molecular cloud, we have estimated the isotopic ratio D/H=HD/2H₂ = (2.97 ± 0.55) × 10⁻⁵ and the corresponding baryon density Ω_b h ² = 0.0205_−0.0020^+0.0025. This value is in good agreement with Ω_b h ² = 0.0226_−0.0006^0.0006 obtained by analyzing the cosmic microwave background radiation anisotropy. However, in high-redshift clouds, under conditions of low metallicity and low dust content, hydrogen may be incompletely molecularized even in the case of self-shielding. In this situation, the HD/2H₂ ratio may not correspond to the actual D/H isotopic ratio. We have estimated the cloud molecularization dynamics and the influence of cosmological evolutionary effects on it.     

The role of a strong far-infrared radiation field in line excitation and cooling of photodissociation regions and molecular clouds

We have theoretically studied the influence of a far-infrared radiation (FIR) field from H_π region on the cooling by C and O atoms, C⁺ ion and CO molecule in a photodissociation region, and a molecular cloud associated with H_π region (hereinafter referred as H_I region) at low temperatures (T _k≤200 K). Comparisons have been made for cooling with and without FIR for two extreme abundances (10⁻⁴ and 10⁻⁷) of the mentioned species for temperatures ranging between 10 and 200K and an hydrogen particle density range 10 cm⁻³≤n _o≤ 10⁷ cm³. The cooling by the species with low line-splitting (C_I, C_π and CO) is significantly influenced by the radiation field for temperaturesT _k < 100 K while the effect of radiation field on cooling by O_I is significant even at higher temperatures (T _k > 100 K). The effect of FIR field on the cooling of CO from low rotational transitions is negligibly small, whereas it is considerable for higher transitions. In general, the cooling terms related to the short-wavelength transitions are more affected by FIR than those related to longer wavelengths. It is also demonstrated here that in the determination of thermal structure of an HI region the dust grains play an important role in the heating of gas only through photoelectron emission following irradiation by far-ultraviolet (FUV) radiation, as the infrared radiation from the dust is too small to have substantial effect on the cooling. It is found that in the H_π /H_I interface the FIR field from grains in the H_π region is not capable of modifying the temperature of the warmest regions but does so in the inner part where the temperature is low enough.     

Europa's atmosphere, gas tori, and magnetospheric implications

A two-dimensional kinetic model calculation for the water group species (H₂O, H₂, O₂, OH, O, H) in Europa's atmosphere is undertaken to determine its basic compositional structure, gas escape rates, and velocity distribution information to initialize neutral cloud model calculations for the most important gas tori. The dominant atmospheric species is O₂ at low altitudes and H₂ at higher altitudes with average day-night column densities of 4.5×¹⁰¹⁴ and 7.7×¹⁰¹³ cm⁻², respectively. H₂ forms the most important gas torus with an escape rate of ∼2×¹⁰²⁷ s⁻¹ followed by O with an escape rate of ∼5×¹⁰²⁶ s⁻¹, created primarily as exothermic O products from O₂ dissociation by magnetospheric electrons. The circumplanetary distributions of H₂ and O are highly peaked about the satellite location and asymmetrically distributed near Europa's orbit about Jupiter, have substantial forward clouds extending radially inward to Io's orbit, and have spatially integrated cloud populations of 4.2×¹⁰³³ molecules for H₂ and 4.0×¹⁰³² atoms for O that are larger than their corresponding populations in Europa's local atmosphere by a factor of ∼200 and ∼1000, respectively. The cloud population for H₂ is a factor of ∼3 times larger than that for the combined cloud population of Io's O and S neutral clouds and provides the dominant neutral population beyond the so-called ramp region at 7.4-7.8 RJ in the plasma torus. The calculated brightness of Europa's O cloud on the sky plane is very dim at the sub-Rayleigh level. The H₂ and O tori provide a new source of europagenic molecular and atomic pickup ions for the thermal plasma and introduce a neutral barrier in which new plasma sinks are created for the cooler iogenic plasma as it is transported radially outward and in which new sinks are created to alter the population and pitch angle distribution of the energetic plasma as it is transported radially inward. The europagenic instantaneous pickup ion rates are peaked at Europa's orbit, dominate the iogenic pickup ion rates beyond the ramp region, and introduce new secondary plasma source peaks in the solution of the plasma transport problem. The H₂ torus is identified as the unknown Europa gas torus that creates both the observed loss of energetic H⁺ ions at Europa's orbit and the corresponding measured ENA production rate for H.     

Comet Hale–Bopp: Velocity Field Of Ions From Fabry-Pérot Imaging

Fabry-Pérot interferograms of comet Hale-Bopp were obtained on several nights in March and April 1997. For this purpose we utilized the 2-channel focal reducer of the Max-Planck-Institute for Aeronomy at the 2-m telescope of the Pik Terskol Observatory. Solid Fabry-Pérot etalons of resolving power 30000 were used in both channels of the focal reducer. The main aim of this study is to measure the velocities and abundances of OH⁺ and H₂O⁺, both ions closely related to the same parent molecule, H₂O. In the blue channel interferograms we identified several individual OH⁺ rotational lines of the A³Π_i - X³Σ⁻ (0-0) transition and measured their Doppler shifts. The target emissions in the red channel were the H₂O⁺ lines of the A²A₁ − X²B₁ (10-0) band. We found that the line of sight velocities, obtained from the Doppler shifted wavelengths of emissions in the comet are higher in sunward direction than in the plasma tail and do not exceed 20 km s^–1. The corresponding values, deprojected in antisolar direction, are consistent with predictions by magnetohydrodynamical models of the solar-wind-comet interaction, when one accounts for the extremely high gas production rate of comet Hale-Bopp. This revised version was published online in July 2006 with corrections to the Cover Date.     

CO clathrate hydrate: Near to mid-IR spectroscopic signatures

Carbon monoxide is the second most abundant molecule after H₂ in the molecular universe, and as such an abundant constituent of interstellar and Solar System ices. To trace the possibility of this molecule to be found in a clathrate hydrate inclusion compound, its pure phase FTIR spectrum is investigated. We confirm the formation of a type I clathrate structure whereas simple guest size estimates would favour a type II clathrate hydrate, revealing interactions of this molecule with its water network during clathrate formation. The observed cage vibrational downshift with respect to pure CO ice is within 5 cm⁻¹. The temperature dependent wavenumber separation between the two enclathrated CO vibrational transitions in the two distinct type I clathrate cages is less than a wavenumber below 140 K, implying that the spectral simplification for detailed spectroscopic analysis of the individual profiles is a difficult task. The dynamics of the CO molecules in its cage change considerably from 5 K to 140 K. At temperatures above 30 K, the molecule is extremely mobile in the cages, as revealed by the infrared profile, significantly different from CO entrapped in water ice and different from observed profiles in astrophysical objects.     

An improved model of radiative transfer for the NLTE problem in the NIR bands of CO<Subscript>2</Subscript> and CO molecules in the daytime atmosphere of Mars. 2. Population of vibrational states

The near-infrared (NIR) emission of the Martian atmosphere in the CO2 bands at 4.3, 2.7, 2.0, 1.6, 1.4, 1.3, 1.2, and 1.05 µm and in the CO bands at 4.7, 2.3, 1.6, and 1.2 µm is mainly generated under nonlocal thermodynamic equilibrium (NLTE) conditions for vibrational states, the transitions from which form the specified bands. The paper presents the results of simulations of the population of these states under NLTE for daytime conditions. In the cold high-latitude troposphere, the NLTE takes place much lower than in the troposphere under typical temperature conditions. If the NIR-radiation reflection from the surface is ignored, the population of high vibrational states substantially decreases, at least, in some layer of the lower atmosphere. However, inelastic collisions of CO₂ and CO molecules with O atoms produce no considerable influence on the values of populations. The population of vibrational states, the transitions from which form NIR bands, is also almost insensitive to possible large values of the quenching-in-collision rate constants of vibrational states higher than CO₂(00⁰1). However, very large errors in the estimates of the population of vibrational states of the CO₂ molecule (rather than the CO molecule!) can be caused by the uncertainty in the values of the rate constant of exchange between CO² molecules by the energy quantum of the asymmetric stretching vibrational mode. For this intermolecular exchange, we recommend a possible way to restrict the vibrational excitation degree of the molecule that is a collision partner and to maintain simultaneously a sufficiently high accuracy in the population estimate.     

Neutral particle release from Europa’s surface

In this paper, we look at space weathering processes on the icy surface of Jupiter’s moon Europa. The heavy energetic ions of the jovian plasma (H⁺, O⁺, S⁺, C⁺) can erode the surface of Europa via ion sputtering (IS), ejecting up to 1000 H₂O molecules per ion. UV photons impinging the Europa’s surface can also result in neutral atom release via photon-stimulated desorption (PSD) and chemical change (photolysis). In this work, we study the efficiency of the IS and PSD processes for ejecting water molecules, simulating the resulting neutral H₂O density. We also estimate the contribution to the total neutral atom release by the Ion Backscattering (IBS) process. Moreover, we estimate the possibility of detecting the sputtered high energy atoms, in order to distinguish the action of the IS process from other surface release mechanisms. Our main results are: (1) The most significant sputtered-particle flux and the largest contribution to the neutral H₂O density come from the incident S⁺ ions; (2) the H₂O density produced via PSD is lower than that due to sputtering by ∼1.5 orders of magnitude; (3) in the energy range below 1 keV, the IBS can be considered negligible for the production of neutrals, whereas in the higher energy range it becomes the dominant neutral emission mechanism; (4) the total sputtering rate for Europa is 2.0 × 10²⁷ H₂O s⁻¹; and (5) the fraction of escaping H₂O via IS is 22% of the total sputtered population, while the escape fraction for H₂O produced by PSD is 30% of the total PSD population. Since the PSD exosphere is lower than the IS one, the major agent for Europa’s surface total net erosion is IS on both the non-illuminated and illuminated side. Lastly, the exospheric neutral density, estimated from the Galileo electron density measurements appears to be higher than that calculated for H₂O alone; this favors the scenario of the presence of O₂ produced by radiolysis and photolysis.     

The Infrared Spectrum of Comet Hele–Bopp as Seen by the Infrared Space Observatory

Spectra of comet C/1995 O1 (Hale-Bopp) were obtained with the Infrared Space Observatory (ISO) at medium resolution with the grating spectrometer in the photometer (PHT-S) and/or at high resolution with the short wavelength spectrometer (SWS) and long wavelength spectrometer (LWS) in April 1996 (Crovisier et al., 1996), September–October 1996 (Crovisier et al., 1997a, b) and December 1997, at distances from the Sun of 4.6, 2.9 and 3.9 AU, respectively. For the first time, high-resolution spectra of a comet covering the entire 2.4 to 200 μm spectral range were obtained. The vibrational bands of H₂O, CO₂ and CO are detected in emission with PHT-S. Relative production rates of 100:22:70 are derived for H₂O:CO₂:CO at 3 AU pre-perihelion. H₂O is observed at high spectral resolution in the ν₃ group of bands around 2.7 μm and the ν₂ group around 6 μm with SWS, and in several rotational lines in the 100–180 μm region with LWS. The high signal-to-noise ratio of the ν₃ band observed on September–October 1996 allows accurate determinations of the water rotational temperature (28 K) and of its ortho-to-para ratio(2.45 ± 0.10, which significantly differs from the high temperature limit and corresponds to a spin temperature of 25 K). Longward of 6 μm the spectrum is dominated by dust thermal continuum emission, upon which broad emission features are superimposed. The wavelengths of the emission peaks correspond to those of Mg-rich crystalline olivine (forsterite). In the September–October 1996 spectra, emission features at 45 and 65 μm and possible absorption at 2.9–3.2 μm suggest that grains of water ice were present at 3 AU from the Sun. The observations made post-perihelion in late December 1997 led to the detections of H₂O, CO₂ and CO at 3.9 AU from the Sun (Figures 1 and 2). The production rates were ≈3.0 × 10²⁸,3.5 × 10²⁸ and ≈1.5 × 10²⁹ s^-1, respectively. This corresponds to H₂O:CO₂:CO = 100:110:500 and confirms that at such distances from the Sun, cometary activity is dominated by sublimation of CO and CO₂ rather than by H₂O. This revised version was published online in July 2006 with corrections to the Cover Date.     

A quantum chemical study on the formation of ethanimine (CH<Subscript>3</Subscript>CHNH) in the interstellar ice

Ethanimine (CH₃CHNH) is an important prebiotic molecule since it is a precursor of amino acid \(\alpha \)-alanine in Strecker synthesis. Two isomers (E and Z) of ethanimine were detected in the molecular cloud Sagittarius B2 north during GBT-PRIMOS survey. A possible radical-molecule reaction pathway has been proposed for the formation of ethanimine in the interstellar medium (ISM) from some previously detected interstellar molecules like methylene (both triplet CH₂ (³B₁) and singlet CH₂ (¹A₁)) and methyenimine (CH₂NH). The mechanism has been studied in the gas phase and in water ice with the help of density functional theory at B2PLYPD/6-311++G (2d, p) level of theory. It is observed that E-ethanimine forms efficiently in gas phase but ice reactions are favorable only in the hot core of molecular clouds. Same is true for the formation of Z-ethanimine which forms only at the surface of water cluster as the height of entrance barrier for formation of Z-ethanimine is similar to that of E-ethanimine. Isomerization from E to Z form is also studied and found to be forbidden due to large entrance barrier. Out of the two reaction system CH₂ (³B₁) + CH₂NH and CH₂ (¹A₁) + CH₂NH, later is more favorable then the former one due to the small entrance barrier. Still, much of the detected abundance of ethanimine comes from the reaction of CH₂ (³B₁) with CH₂NH as since CH₂ (¹A₁) has very low abundance compared to the CH₂ (³B₁) in ISM. The proposed pathway seems to be a promising candidate for the ethanimine formation in ISM.     

The influence of negatively charged heavy ions on the kinetic Alfven wave in a cometary environment

Kinetic Alfven waves are important in a wide variety of areas like astrophysical, space and laboratory plasmas. In cometary environments, waves in the hydromagnetic range of frequencies are excited predominantly by heavy ions. We, therefore, study the stability of the kinetic Alfven wave in a plasma of hydrogen ions, positively and negatively charged oxygen ions and electrons. Each species was modeled by drifting ring distributions in the direction parallel to the magnetic field; in the perpendicular direction the distribution was simulated with a loss cone type distribution obtained through the subtraction of two Maxwellian distributions with different temperatures. We find that for frequencies w^* < w_{cH ⁺}\omega^{*} < \omega_{c\mathrm{H}^{ +}} (ω ^∗ and w_{cH ⁺}\omega_{c\mathrm{H}^{ +}} being respectively the Doppler shifted and hydrogen ion gyro-frequencies), the growth rate increases with increasing negatively charged oxygen ion densities while decreasing with increasing propagation angles, negative ion temperatures and negative ion mass.     

Estimation of cosmological parameters from peculiar velocities of flat EDGE-ON galaxies

We estimate the values of the cosmological parameters using the data about peculiar velocities of 1493 flat edge-on spirals from the RFGC catalogue. The obtained values Ω _m = 0.21_{− 0.09} ^{+ 0.22}, σ₈ = 1.07_{− 0.24} ^{+ 0.28} differ from the WMAP values by approximately 2–3σ, but well agree with modern constraints on these parameters. Due to a strong correlation between these quantities the shape of the 1σ, 2σ and 3σ-boundaries are rather narrow. This gives us the opportunity to use this estimation to verify the corresponding values, obtained by different methods.     

Gas,dust and molecules in the Galaxy

The relative abundances of cool neutral hydrogen, carbon monoxide and formaldehyde are studied using all the available observational data in the literature. The obtained mean valuesN _{H 1}/ ,N _{H 1}/N _CO,N _CO/ are approximately constant in the dark clouds of the solar neighbourhood and in the distant molecular clouds.The observed correlationsN _CO,A _v and ,A _v show that formaldehyde can also be used as an indicator of molecular hydrogen. The ratioN H₁/A _v depends on densities and decays considerably in the ranges of visual absorptions in which the molecules become detectable (A _v 2 mg); an average of /N _{H 1}10 is calculated for the dense dark clouds.Indications of systematic temperature gradiens T/A _v are found for formaldehyde and neutral hydrogen inside the dark clouds, and qualitative comparisons are made with theoretical quantum mechanics calculations.The observed carbon monoxide and formaldehyde abundances, the free electron layer in the Galaxy, the distribution of neutral hydrogen in different states are only compatible if an ionization rate of 10^–16 is accepted, provided presumably by 2 MeV protons of cosmic radiation.Three main states for neutral hydrogen and dust are identified from different kinds of observational data (21 cm line in emission, absorption in galactic radio sources and self-absorption in the hot gas background): (1) a homogeneous intercloud stratum of tenuous gas and dust with a galactic halfwidth of 350 pc and mean parametersn _H=0.2 atom cm^–3, spin temperatureT _s 10000 K andn _d 0.3 mg kpc^–1; (2) cool gas and dust concentrated in spiral features with a galactic half-width of less than 100 pc, probably forming clouds with diffuse and indefinite limits, with mean parametersn _H2 atom cm^–3,T _s <1100 K (probable average,T _s =135 K) andn _d 3 mg kpc^–1; (3) dense gas and dust clouds with a mean diameter of 7 pc and mean parametersn _H700 atom cm^–3 (90% in a molecular state),T _s 63 K andn _d 1 mg pc^–1 on which molecules as CO and H₂CO are formed.The application of the Jeans criteria for gravitational instability shows that the dense clouds are gravitationally bound while the gas in the intermediate state (2) can be protected against collapse by the total internal energy in the medium increasing due to cosmic rays and the magnetic field in the Galaxy.The observed velocity halfwidths and galacticZ-halfwidths in states (1) and (2) are compatible with a total mass density in the galactic layer of 90M pc^–2 (gas plus stars) according to the barometric equation.The relative abundancesN _{H 1}/N _CO, calculated from C¹²O and C¹³O data and comparisons with studies in the 21 cm emission line, show that the antenna temperatureT _A ⁺ in the 2.6 mm line of C¹²O is a good indicator of the cool gas densities in the Galaxy. The possible application of this for studies in galactic structure is discussed and hypothetical distributions of carbon monoxide in the zones outside the galactic planeB=0° are presented.From a synthesis based on the results obtained, a cycle is postulated for the neutral hydrogen in the Galaxy: condensation and cooling of gas molecular formation gravitational collapse and star formation gas dissipation and heating by cosmic rays and UV radiation.