珊瑚混凝土在海洋环境中氯离子扩散实验

采用自然扩散法研究了珊瑚混凝土在海水环境中的氯离子扩散特性,探讨了养护龄期、暴露时间和环境差异性对珊瑚混凝土表观氯离子扩散系数的影响。结果表明:随着暴露时间的延长,珊瑚混凝土的表观氯离子扩散系数呈幂指数衰减规律;且延长养护龄期可降低珊瑚混凝土的表观氯离子扩散系数;随着强度等级增加,混凝土的表观氯离子扩散系数降低。我国实际海洋工程中珊瑚混凝土结构的表观氯离子扩散系数比实验室条件要提高3个数量级。因此,适当延长养护时间、提高强度等级有助于延长珊瑚混凝土结构在海洋环境的服役寿命。     

综合机制下氯离子扩散迁移模型及敏感性研究

缩短钢筋混凝土结构使用寿命的主要原因之一是氯离子对混凝土的扩散侵蚀。研究各种因素对氯离子扩散的影响,准确预测氯离子侵蚀程度是修复和加固钢筋混凝土结构的重要依据。作者基于Fick第二定律,推导出混凝土氯离子综合机制扩散迁移模型,确定了温度、时间、混凝土结合作用以及结构劣化效应与氯离子扩散系数之间的关系,并对各种影响机制的内在相关性和重要性进行了敏感性分析。经过工程实验验证,证明了改进后的氯离子扩散迁移模型的正确性和合理性。     

基于广义扩散方程海工混凝土结构耐久寿命概率评估方法

针对国内现有的氯离子侵蚀寿命预测模型存在的问题,提出了基于广义扩散方程(GDF)的海洋环境下混凝土结构耐久寿命预测的概率方法.以某海上混凝土工程原位取粉测试及室内快速试验为手段,获得不同环境分区的时变模型参数统计值.采用随机抽样方法,实现结构各部位混凝土使用寿命的概率预测.通过对模型参数的敏感性分析讨论了该模型的优点.最后,提出了周期性检测,不断更新模型参数的动态寿命评估思路.     

人工鱼礁在自然海水条件下的腐蚀寿命研究

有氯盐侵蚀的钢筋腐蚀,是钢筋混凝土结构性能劣化的主要原因之一,混凝土构件使用寿命的关键是氯离子的传输速率和使钢筋产生锈蚀的时间。本文以人工鱼礁混凝土构件为研究对象,分析海水氯离子在C30、C35和钢渣复合材料人工鱼礁混凝土中的扩散系数,以混凝土中钢筋锈蚀的临界氯离子浓度为寿命预测的边界条件,利用氯离子扩散模型预测C30、C35和钢渣复合材料人工鱼礁在海水中的腐蚀寿命。研究结果表明,氯离子在混凝土人工鱼礁中的扩散规律基本满足Fick第二定律。通过模型计算得出C30、C35和钢渣复合材料混凝土人工鱼礁的腐蚀寿命分别为51.6,54.8和56.8年。     

人工鱼礁在自然海水条件下的腐蚀寿命研究

有氯盐侵蚀的钢筋腐蚀,是钢筋混凝土结构性能劣化的主要原因之一,混凝土构件使用寿命的关键是氯离子的传输速率和使钢筋产生锈蚀的时间。本文以人工鱼礁混凝土构件为研究对象,分析海水氯离子在C30、C35和钢渣复合材料人工鱼礁混凝土中的扩散系数,以混凝土中钢筋锈蚀的临界氯离子浓度为寿命预测的边界条件,利用氯离子扩散模型预测C30、C35和钢渣复合材料人工鱼礁在海水中的腐蚀寿命。研究结果表明,氯离子在混凝土人工鱼礁中的扩散规律基本满足Fick第二定律。通过模型计算得出C30、C35和钢渣复合材料混凝土人工鱼礁的腐蚀寿命分别为51.6,54.8和56.8年。     

海港码头混凝土结构干湿交替区域氯离子侵蚀规律研究

基于对乍浦港混凝土结构现场检测数据,分析干湿交替区域氯离子侵蚀状况存在差异的原因,建立表面氯离子浓度和扩散系数随高程、季节、材料、及服役时间的关系,提出基于海域气象条件推定扩散模型统计参数的经验计算公式,并根据设计潮位确定氯离子严重侵蚀区域范围,可为耐久性设计和维护提供理论依据。     

海洋混凝土结构表面自由氯离子含量时变规律及对其寿命影响

表面氯离子含量(C_s)是研究海洋环境条件下混凝土结构耐久性和服役寿命的氯离子扩散方程的边界条件,是海洋混凝土结构耐久性分析和定量设计的重要参数。依据国内外大量自然暴露试验与工程实测数据,通过采用Excel、Origin等数据分析软件进行数据统计和回归分析,确定了海洋混凝土结构表面自由氯离子含量(C_(sf))与表面总氯离子含量(C_(st))之间的相互关系,探讨了海洋混凝土结构的C_(sf)时变规律,建立了C_(sf)与暴露时间之间的关系表达式及其取值范围,并运用可靠度理论和修正氯离子扩散理论分析了C_(sf)时变性对海洋混凝土结构寿命的影响。结果表明:C_(sf)与C_(st)线性相关,且C_(sf)随着暴露时间的延长呈指数或者幂函数的增长关系;采用不同的C_(sf)时变性规律,对海洋混凝土结构寿命具有重大的影响。     

海水环境下钢筋混凝土人工鱼礁的耐久性寿命预测

根据人工模拟的流动海水环境(流速约为0.15m/s)下的混凝土侵蚀试验测得的混凝土中氯离子质量分数,分别测定了腐蚀350,380,400d后混凝土的氯离子扩散系数,并计算和预测了混凝土人工鱼礁的耐久性寿命。研究结果表明:氯离子在混凝土人工鱼礁中的扩散规律基本上遵循Fick第二定律;钢筋混凝土人工鱼礁的耐久性寿命与保护层厚度的平方成正比;海水盐度对混凝土人工鱼礁的耐久性寿命影响较大。     

海水环境粉煤灰混凝土结构耐久性现场检测与评估分析

对服役12年的华南某跨海大桥典型构件开展碳化性能、氯离子扩散性能等指标的耐久性检测,评估了海水环境下掺粉煤灰的高性能混凝土长期耐久性。研究表明:随高程的增加混凝土碳化深度逐渐增大,其中大气区浪溅区水位变动区,碳化作用对粉煤灰混凝土结构耐久性的影响较小;粉煤灰可显著提升实体结构混凝土抗氯离子侵蚀性能,粉煤灰高性能混凝土的氯离子扩散系数不大于0.40×10-12m2/s,比普通混凝土氯离子扩散系数降低了约6倍;利用规范计算了引桥承台混凝土中氯离子含量计算值,其计算值与实测值吻合较好,可用于实体工程混凝土结构的耐久性评估,评估结果显示采用粉煤灰高性能的桥梁典型构件满足100年设计使用寿命的要求。     

粗骨料对混凝土界面过渡区氯离子扩散性能影响

通过室内干湿循环条件下混凝土中氯离子扩散试验,实测得到6种不同粗骨料体积分数的混凝土试件在不同时刻、不同深度处的氯离子浓度。经回归分析得到了不同粗骨料体积分数下混凝土的氯离子整体扩散系数,其值随粗骨料体积分数的增加而减小。同时,探讨了粗骨料的稀释、曲折和界面过渡区效应对混凝土中氯离子扩散的影响。在此基础上,同时考虑粗骨料体积分数Vf和界面过渡区厚度h的影响系数α(Vf,h),建立混凝土界面过渡区氯离子扩散系数模型,界面过渡区氯离子扩散系数随粗骨料体积分数的增大呈近乎线性地减小,随界面过渡区厚度的增大先显著减小而后逐渐趋于平稳。最后,将建立的界面过渡区氯离子扩散系数模型应用于混凝土中氯离子扩散的三维细观数模中。结果表明:细观数模计算结果与物理试验实测数据在变化趋势和数值大小上均能够吻合,可验证界面过渡区氯离子扩散系数模型的正确性与合理性。     

海上大直径钢管桩打桩过程中桩周土强度弱化研究

海上大直径钢管桩打桩过程中,桩周土体受到强烈扰动而发生强度弱化,掌握桩周土体强度弱化规律对于准确预测打桩过程、保证工程安全具有重要意义。为研究土体强度弱化规律,开展了环剪试验模拟打桩对桩周土体的扰动,测试土体强度随剪切速率的变化规律,建立了描述土体强度弱化规律的拟合公式,引入到打桩分析软件中。研究结果表明：土体的强度折减程度不仅与土体本身的性质有关还受到土体的埋深和剪切速率的影响,埋深越深土体强度折减程度越低,剪切速率越高土体强度折减越高,在打桩分析中可采用这里推荐的线性折减方法来模拟不同深度处土体强度的折减规律。     

Phylogenetic diversity and phenotypic characterization of cultivable bacterioplankton isolated from polar oceans

A set of 27 marine planktonic bacteria isolated from the polar regions was characterized by 16S rDNA sequencing and physiological and biochemical testing. More than half of these bacteria were positive for caseinase, gelatinase and 13-glucosidase, and could utilize glucose, maltose or malic acid as carbon source for cell growth. Twelve isolates expressed nitrate reduction activities. Except for one antarctic isolate BSwlO175 belonging to Actinobacteria phylum, these isolates were classified as γ-Proteobacteria, suggesting that γ-Proteobacteria dominated in cultivable marine bacterioplankton at both poles. Genus Pseudoalteromonas was the predominant group in the Chukchi Sea and the Bering Sea, and genus ShewaneUa dominated in cultivable bacterioplankton in the Prydz Bay. With sequence similarities above 97%, genus Psychrobacter was found at both poles. These 27 isolates were psychrotolerant, and significant 16S rDNA sequence similarities were found not only between arctic and antarctic marine bacteria （ 〉 99% ）, but also between polar marine bacteria and bacteria from other aquatic environments （ ≥ 98.8% ）, including temperate ocean, deep sea, pond and lake, suggesting that in the polar oceans less temperature-sensitive bacteria may be cosmopolitan and have a bipolar, even global, distribution at the species level.     

Estimation of Sediment Properties during Benthic Impact Experiments

Sediment properties, such as water content and density, have been used to estimate the dry and wet weights, as well as the volume of sediment recovered and discharged, during benthic impact experiments conducted in the Pacific and Indian Oceans. The estimates show that the weights of dry (355-1332 t) and wet sediment (1651-4888 t) recovered during the experiments, are not only a function of the total duration and distance covered during the experiment, but also depend on water content and density of the sediment. Estimation of dry sediment and its volumetric ratio in the discharge, are key parameters for calculating the discharged volume. The estimated volume of wet sediment recovered (1427-4049 m 3 ) as well as discharged (2693-6951 m 3 ) during the experiments, provide important inputs to evaluate the sediment resettlement and migration. Using these estimates, the average depth of excavation on the seafloor, can also been calculated. However, the stages of sediment recovery and discharge are expressed differently in some of the experiments. In order to standardize these, different stages have been identified, and definitions of certain terms have been suggested, for use in the future. The methods of calculating different properties, as well as weight and volume of discharged sediment are described in the paper for use in other applications concerning deep-sea discharges.     

A Tidal Flow Model for the Gulf of Kachchh, India

A vertically integrated model has been used to study the tidal circulation and currents in the Gulf of Kachchh along the west coast of India. The model is fully nonlinear and uses a semiexplicit finite difference scheme to solve the basic hydrodynamic equations on a staggered grid. The model is forced by prescribing the tides along the open boundary of the model domain. The flow is simulated both with and without the presence of the proposed tidal barrage across the Hansthal Creek in the Gulf of Kachchh. The results show a considerable change in the behavior of the tidal flow in the presence of the barrage.     

利用中国GF-3卫星SAR和HY-2A卫星微波散射计的首次台风联合定量观测

<正>The typhoon,as a mature tropical cyclone that develops in the western part of the North Pacific Ocean with high wind speed and heavy rainfall,is one of the most lethal and costly of natural disasters for the densely populated countries of East Asia.It can be easily detected by space-borne sensors operated at microwave,visible or infrared bands(Liu et al.,2014).Synthetic Aperture Radar(SAR)is     

Increased Particle Fluxes at the INDEX Site Attributable to Simulated Benthic Disturbance

Particle fluxes were measured 7 m above the sea bottom during the predisturbance, disturbance, and postdisturbance periods by using time series sediment traps attached to seven deep-sea moorings deployed in the INDEX experiment site in the Central Indian Basin. The predisturbance particle fluxes varied between 22.3 to 55.1 mg m -2 day -1 . Increased and variable particle fluxes were recorded by the sediment traps during the disturbance period. The increase observed was 0.5 to 4 times more than the background predisturbance fluxes. The increases in particle fluxes (~4 times) recorded by the sediment trap located in the southwestern direction (DMS-1) were the greatest, which could be the result of preferential movement of resuspended particles generated during the deep-sea benthic disturbance along the general current direction prevailing in this area during the experimental period. Also, the traps located closer to the disturbance area recorded greater fluxes than did the traps far away, across the Deep Sea Sediment Resuspension System path. This variability in recorded particle fluxes by the traps around the disturbance area clearly indicates that physical characteristics such as grain size and density of the resuspended particles produced during the disturbance had an important effect on particle movement. The postdisturbance measurements during ~5 days showed a reduction in particle fluxes of ~50%, indicating rapid particle settlement.     

A Review of Some Environmental Issues Affecting Marine Mining

This article reviews information recently available from existing marine and coastal mining for responses to environmental issues affecting marine mining at different depths. It is particularly but not exclusively concerned with those issues affecting seabed biodiversity impact and recovery. Much information has been gathered in the past 10 years from shallow mining operations for construction aggregate, diamonds, and gold, from coastal mines discharging tailings to shallow and deep water, and from experimental deep mining tests. The responses to issues identified are summarized in a series of eight tables intended to facilitate site-specific consideration. Since impacts can spread widely in the surface mixing layer SML, and can affect the biologically productive euphotic zone, the main issues considered arise from the depth of mining relative to the SML of the sea. Where mining is below the SML, the issue is whether it is environmentally better to bring the extraction products to the surface vessel for processing (and waste discharge), or to process the extraction products as much as possible on the seabed. Responses to the issues need to be sitespecific, and dependent on adequate preoperational environmental impact and recovery prediction. For deep tailings disposal from a surface vessel, there are four important environmental unknowns: (1) the possible growth of "marine snow" (bacterial flocs) utilizing the enormous quantities of fine tailings particles (hundreds or thousands of metric tons per day) as nuclei for growth, (2) the possibility that local keystone plankton and nekton species may migrate diurnally down to and beyond the depth of deep discharge and hence be subjected to tailings impact at depth, (3) the burrow-up capability of deep benthos and their ability to survive high rates of tailings deposition, and (4) the pattern and rate of dispersion of a tailings density current through the deep water column from discharge point to seabed. Actions to obtain relevant information in general and site-specifically are suggested.     

离子交换—原子吸收光谱法测定海水中痕量铜、铅、锌、镉、铁、锰

本文介绍了用国产D401型螯合树脂分离富集海水中铜、铅、锌、镉、铁、锰等痕量元素,并用原子吸收光谱仪测定其含量的方法。讨论了各元素的分离条件选择及干扰元素的影响,并与溶剂萃取法的结果作了比较。各元素检测的定量下限为:铜0.5μg/L、铅0.1μg/L、锌1.0μg/L、镉0.01μg/L、铁2.0μg/L、锰2.0μg/L。方法精密度在4—8％之间,回收率为90—102％。