锆石Hf同位素：MC-ICP-MS和LA-MC-ICP-MS分析结果的比较

采用单柱离子色谱法高效提取锆石中的Hf元素，用MC—ICP—MS测定锆石Hf同位素组成。三个锆石样品及其平行样的分析结果显示，同一样品的Hf同位素组成在误差范围内高度一致，表明用单柱离子交换色谱法能够有效分离锆石的Hf元素，可以保证Hf同位素分析结果的再现。对比MC—ICP—MS和LA—MC—ICP—MS分析结果发现，同一样品锆石的Hf同位素在误差范围内一致，具有很好的可对比性。但对颗粒较小的锆石，缩小激光束斑使之不超出锆石颗粒的范围，能够获得更好的结果。     

Ban-1 Zircon: A New Natural Zircon Reference Material for LA-MC-ICP-MS Zr and Hf Isotopic Determinations

New zircon reference materials for in situ zircon radiogenic Hf isotope and stable Zr isotopic determinations made by laser ablation multi-collector inductively coupled plasma-mass spectrometry (LA-MC-ICP-MS) are required due to high data productivity and consequently high reference material consumption rate. This study examines a new natural zircon for Zr isotope ratios by double spike thermal ionisation mass spectrometry (TIMS), and for Hf isotopes by bulk solution nebuliser (SN)-MC-ICP-MS with both Zr and Hf determined by LA-MC-ICP-MS. A total of five zirconium isotope measurements from drilled zircons, determined by TIMS, yield a mean δ^94/90Zr_IPGP-Zr value of -0.09 ± 0.06‰ (2s). Five and eight hafnium isotope measurements for powders from the drilled zircons and Ban-1-4 by SN-MC-ICP-MS, yield mean ¹⁷⁶Hf/¹⁷⁷Hf ratios of 0.282985 ± 0.000011 (2s) and 0.282982 ± 0.000007 (2s), respectively. The mean δ^94/90Zr_IPGP-Zr value and ¹⁷⁶Hf/¹⁷⁷Hf ratio determined by LA-MC-ICP-MS analyses are -0.06 ± 0.09‰ (2s, n = 504) and 0.282985 ± 0.000035 (2s, n = 327), respectively. The isotopic homogeneities suggest that the Ban-1 zircon is a suitable reference material for microbeam Zr and Hf isotopic measurements.     

In Situ Analyses of Trace Elements,U–Pb and Lu–Hf Isotopes in Zircons from the Tongshankou Granodiorite Porphyry in Southeast Hubei Province,Middle-Lower Yangtze River Metallogenic Belt,China

The Tongshankou Cu-Mo deposit, located in southeast Hubei province, is a typical skarn–porphyry type ore deposit closely related to the Tongshankou granodiorite porphyry, characterized by a high Sr/Y ratio.Detailed in situ analyses of the trace elements and U–Pb and Lu–Hf isotopes in zircons from the Tongshankou granodiorite porphyry were performed.Scarcely any inherited zircons were observed, and the analyzed zircons yielded highly concordant results with a weighted mean 206Pb/238 U age of 143.5 ± 0.45 Ma(n=20, mean square weighted deviation was 0.75), which was interpreted to represent the crystallization age of the Tongshankou granodiorite porphyry.The chondrite-normalized rare-earth element pattern was characterized by a slope that steeply rises from the light-group rare-earth elements(LREE) to the heavy-group rare-earth elements(HREE) with a positive Ce-anomaly and inconspicuous Eu-anomaly, which was coincident with the pattern of the zircons from the Chuquicamata West porphyry, Chile.The analyzed zircons also had relatively low 176Hf/177 Hf ratios of 0.282526–0.282604.Assuming t=143 Ma, the corresponding calculated initial Hf isotope compositions(εHf(t)) ranged from-5.6 to-2.9.The results of the in situ analysis of trace elements and U–Pb and Lu–Hf isotopes in zircons from the Tongshankou granodiorite porphyry suggest that a deep-seated process involving a thickened-crust/enriched-mantle interaction may play an important role in the generation of high Sr/Y-ratio magma and potentially in the generation of porphyry Cu-Mo systems.     

锆石微区原位同位素和微量元素测定的新进展

文章简述了二次离子探针质谱(SIMS)、激光剥蚀等离子体质谱(LA-ICP-MS)和激光剥蚀多接受等离子体质谱(LA-MC-ICP-MS)等3种锆石微区原位同位素和微量元素测定方法的原理和优缺点;针对U-Pb定年、铪同位素、锂同位素、多种元素的同时测定,以及仪器改进、测试方法创新、标样研发等方面的新进展进行了评述。     

粤北大宝山北部九曲岭花岗岩锆石U-Pb年龄和Hf同位素特征

采用LA-MC-ICP-MS锆石U-Pb年龄和Hf同位素测定技术,对大宝山北部九曲岭花岗岩进行测定。结果显示来自九曲岭岩体的三个花岗岩样品的U-Pb谐和年龄分别为169.0±1.9 Ma,171.3±1.4 Ma,450.2±2.9 Ma,表明九曲岭花岗岩体为一复式岩体,主体为燕山期花岗岩,但局部有加里东期花岗岩。锆石Lu-Hf同位素组成测定显示:燕山期岩体的锆石具有低的负εHf(t)值(分别为–12.19~–8.51和–19.47~–8.63),二阶段模式年龄(tDM2)为1.45~1.63 Ga,与华南燕山期花岗岩特征一致,表明其主要是下地壳重熔的产物;加里东期岩体的锆石具有高的εHf(t)值(8.89~12.06),tDM2为0.62~0.78 Ga,表明其源区有新生地壳物质的贡献,暗示早古生代加里东期大宝山区域处于伸展环境。     

Precise and Accurate Determination of Lu and Hf Contents,and Hf Isotopic Compositions in Chinese Rock Reference Materials by MC‐ICP‐MS

In this contribution, we report Hf isotopic data and Lu and Hf mass fractions for thirteen Chinese rock reference materials (GBW07 103–105, 109–113 and 121–125, that is GSR 1–3, 7–11 and 14–18, respectively) that span a broad compositional range. Powdered samples were spiked with a ¹⁷⁶Lu‐¹⁸⁰Hf enriched tracer and completely digested using conventional HF, HNO₃ and HClO₄ acid dissolution protocols. Fluoride salts were dissolved during a final H₃BO₃ digestion, and chemical purification was performed using a single Ln resin. All measurements were carried out on a MC‐ICP‐MS. This work provides the first comprehensive report of the Lu‐Hf isotopic composition of Chinese geochemical rock reference materials, and results indicate that they are of comparable quality to the well‐characterised and widely used USGS and GSJ rock reference materials.     

鄂东南地区存在古元古代—太古宙基底——来自铜鼓山岩体锆石U-Pb-Hf同位素的证据

对鄂东南地区位于毛铺—两剑桥断裂带上的铜鼓山岩体进行了野外地质及镜下显微研究及岩石化学分析, 重点分析了其中锆石U-Pb年龄和Hf同位素组成。结果表明铜鼓山岩体为石英闪长玢岩, 岩体形成于(147±2.6) Ma, 属晚侏罗世—早白垩世, 与鄂东南地区其它岩体年龄具有一致性。铜鼓山岩体中存在的大量继承锆石。分析的4个继承锆石形成于古元古代晚期1798~1888 Ma。继承锆石具有高的Th/U比值和极其相似的Lu-Hf同位素组成, 表明它们捕获于同一火成岩。这表明鄂东南地区存在古元古代基底。这些古元古代继承锆石低的εHf(t)值和冥太古代的Hf同位素两阶段模式年代暗示古元古代克拉通化是在太古宙基底上发展的。鄂东南地区和扬子陆块其它众多地区一样存在古元古代—太古宙基底。扬子陆块古元古代—太古宙基底极可能从四川盆地、鄂西崆岭和郧西地区东延至鄂东南地区。     

A New Digestion and Chemical Separation Technique for Rapid and Highly Reproducible Determination of Lu/Hf and Hf Isotope Ratios in Geological Materials by MC-ICP-MS

A new digestion procedure and chemical separation technique has been developed for measurement of Lu/Hf and Hf isotope ratios that does not require high‐pressure bombs or use of HF or HClO₄ acids. Samples are digested in dilute HCl or HNO₃ after flux‐fusion at 110 0 °C in the presence of lithium metaborate. High field strength elements (HFSE) and rare earth elements (REE) are separated from this solution by co‐precipitation with iron hydroxide. The dissolved precipitate (in 2 mol l^?1 HCl) is loaded directly onto a standard cation exchange column which separates remaining sample matrix from the heavy REE (Lu+Yb), and the middle‐light REE and HFSE (Hf). The middle‐light REE and individual HFSE are then separated (10.5, 9 and 6 mol l^?1 HCl) using a miniaturized column containing TEVA spec resin which provides a REE‐, Ti‐ and Zr‐free Hf cut. This chemical separation scheme can also be readily adapted for isotopic analysis of the Sm‐Nd system and/or the other HFSE (Ti, Zr). Total procedural blanks for this technique are < 10 0 pg and < 2 pg for Hf and Lu, respectively, even when digesting large (0.5 g) samples. We present data from replicate digestions of international rock reference materials which demonstrate this technique routinely reproduces Lu/Hf ratios to < 0.2% (2s) and ¹⁷⁶ Hf/¹⁷⁷ Hf isotope ratios to < 30 ppm (2s). Moreover, the technique is matrix‐independent and has been successfully applied to analysis of diverse materials including basalts, meteorites, komatiites, kimberlites and carbonatites. The relative simplicity of this technique, coupled with the ease of digestion (and sample‐spike equilibration) of large difficult‐to‐dissolve samples, and the speed (2 days) with which samples can be digested and processed through the chemical separation scheme makes it an attractive new method for preparing samples for Lu‐Hf isotopic investigation.     

Metamorphic growth and recrystallization of zircon: Distinction by simultaneous in-situ analyses of trace elements,U–Th–Pb and Lu–Hf isotopes in zircons from eclogite-facies rocks in the Sulu orogen

Simultaneous in-situ analyses of trace elements, U–Th–Pb and Lu–Hf isotopes were carried out on distinct domains of zircons in ultrahigh-pressure (UHP) eclogite-facies metamorphic rocks from the main hole of the Chinese Continental Scientific Drilling (CCSD) in the Sulu orogen. For the first time, trace elements are directly linked to Lu–Hf isotopes in metamorphic zircons with reference to their U–Pb dates. This enables methodological integration to distinguish four types of metamorphic zircon: solid-state, replacement and dissolution recrystallizations of protolith zircons, and new growth from the aqueous fluid. Metamorphically grown zircons are characterized by concordant U–Pb ages for the metamorphism, flat HREE patterns typical of the garnet effect, low contents of REE (especially HREE), Y, Nb + Ta and Th + U, high contents of Hf, low (Lu/Gd)_N, Lu/Hf and Th/U (< 0.1) ratios, and elevated ¹⁷⁶Hf/¹⁷⁷Hf ratios relative to solid-state recrystallized zircons. This suggests the effects of both garnet and fluid on the growth of metamorphic zircons. In contrast, metamorphic recrystallization has reset the U–Th–Pb isotope system of protolith zircons to different extents, depending on the extents of fluid action during metamorphism. Solid-state recrystallized zircons exhibit the lowest degrees of resetting and thus almost inherit all geochemical features from the protolith zircons, which are characterized by discordant U–Pb ages close to or below the protolith age, steep MREE–HREE patterns typical of magmatic origin, high contents of trace elements and their ratios, and low ¹⁷⁶Hf/¹⁷⁷Hf ratios. On the other hand, dissolution recrystallized zircons show the highest degrees of reworking and thus have concordant or nearly concordant U–Pb ages for the metamorphism, steep MREE–HREE patterns, lowered contents of trace elements such as REE, Th, U, Y, Nb, Ta and Ti relative to the protolith zircons, and almost unchanged Hf isotope ratios. Replacement recrystallized zircons display intermediate degrees of reworking and thus have their many features of elements and isotopes in between. While the metamorphic growth in the presence of both garnet and fluid is characterized by both depletion of HREE with flat pattern and the low contents of trace elements, the metamorphic recrystallization in the presence of aqueous fluid is indicated by gradual decreases of MREE to HREE without the flat HREE pattern. Therefore, the simultaneous in-situ analyses of metamorphic zircons have the advantage over single-term analyses in making distinction between the new growth and the different types of recrystallization.     

锡林浩特杂岩中斜长角闪岩锆石U-Pb年代学及Hf同位素研究

锡林浩特杂岩是一套经历强变形变质作用的变质岩,主要由黑云斜长片麻岩、角闪斜长片麻岩、斜长角闪片麻岩及变粒岩夹透镜状或脉状斜长角闪岩组成。查明其形成年龄、变质年龄对深入认识中亚造山带的形成演化具有重要意义。本次研究对锡林浩特杂岩中斜长角闪岩进行了SHRIMP锆石U-Pb测年和LA-MC-ICP-MS锆石Hf同位素组成分析,给出了锆石SHRIMP U-Pb的加权平均年龄为(316±4)Ma,该年龄代表斜长角闪岩的原岩形成年龄,表明锡林浩特杂岩不是前寒武纪地质体。通过锆石Hf同位素分析,εHf(t)值主要为正值(+4.1～+17.0),揭示其物源可能来自亏损地幔或壳幔混合。根据亏损地幔和古老地壳的锆石Hf同位素进行两端元的混合计算,得到斜长角闪岩原岩岩浆的源区以幔源增生组分为主体(经过计算壳幔混合比例大约1∶2)。部分锆石的模式年龄在1.8～2.5 Ga之间,表明斜长角闪岩的原岩在形成过程中有古元古代地壳物质的加入,通过兴蒙造山带和锡林浩特杂岩中斜长角闪岩的Hf模式年龄对比可知,物源可能来自兴蒙造山带内部。基于Hf同位素的两端元混合计算表明该区在晚古生代存在地壳增生。根据野外观察和室内岩石特征分析,该套杂岩可能是一套经历强变形与变质作用的晚古生代火山-沉积建造。     

东天山白山斑岩钼矿床深部斑岩体锆石SIMS U-Pb定年、Hf同位素组成及其地质意义

白山钼矿位于东天山康古尔-黄山韧性剪切带三岔口-白山斑岩铜钼矿带中,为典型的斑岩型钼矿。本文以白山钼矿床深部花岗斑岩体为研究对象,对其进行了精确的锆石SIMS U-Pb定年以及锆石原位Hf同位素分析,旨在确定白山钼矿床深部斑岩体的形成时代以及岩石成因,进而分析其形成时的动力学背景。本文获得的白山钼矿床深部斑岩体锆石SIMS U-Pb年龄为(229.7±3.2) Ma,这一结果与前人获得的辉钼矿Re-Os等时线年龄225～229 Ma基本一致,因此可以代表成矿岩体的形成年龄为晚三叠世。锆石原位Hf同位素组成特征显示,εHf(t)均显示正值,为+8.3～+12,地壳模式年龄(TCDM)为556～758 Ma。结合前人研究成果及区域地质演化历史,可以确定白山钼矿床深部斑岩体形成于晚三叠世陆内伸展环境,由新生下地壳部分熔融形成。     

扬子克拉通北缘大洪山地区打鼓石群与神农架地区神农架群的对比:锆石SHRIMP U-Pb年龄及Hf同位素证据

出露于扬子克拉通北缘大洪山地区的打鼓石群一直被认为是一套中元古代沉积地层,其上被花山群不整合覆盖。但是由于缺少可靠的年龄依据,打鼓石群与同属扬子克拉通北缘的神农架群以及其他相关地层的对比关系一直存有争议。本文作者利用高精度高分辨率离子探针质谱仪(SHRIMP)测定了打鼓石群中凝灰岩的锆石U-Pb年龄,并利用激光烧蚀多接收器电感耦合等离子体质谱仪(LA-MC-ICPMS)测定了打鼓石群凝灰岩和基本同时代的神农架地区神农架群上亚群凝灰岩的锆石Lu-Hf同位素。这是迄今为止第一次测得了打鼓石群罗汉岭组凝灰岩年龄(1 225±19) Ma和(1 239±23) Ma;锆石Lu-Hf同位素结果显示打鼓石群罗汉岭组凝灰岩与神农架群上亚群野马河组凝灰岩具有相似的Lu-Hf同位素特征：176Hf/177Hf初始值介于0.282 172~0.282 397,εHf(t)值为4.9~12.0, TCDM=1 150~1 943 Ma。结合现有区域地质资料,我们认为打鼓石群与神农架群上亚群属于同时期沉积物,形成于超级地幔柱主导的哥伦比亚超大陆裂解背景。     

河北雾灵山杂岩体锆石Hf同位素特征及其区域对比研究

雾灵山杂岩体是位于华北克拉通北缘河北省兴隆县境内的一个出露面积为230 km²的大岩基,岩体主要由似斑状碱长正长岩、碱性石英正长岩和碱长正长斑岩组成。对该杂岩体中最早侵位的似斑状碱长正长岩的3件样品进行了锆石U-Pb测年和原位Hf同位素测试,获得的等时线年龄分别为(128.0±0.6) Ma、(127.3±1.2) Ma和(126.8±0.4) Ma,表明该岩体最早侵位于早白垩世;同时,两阶段Hf模式年龄介于1.13～1.75 Ga,ε_Hf(t)值为-7.8~1.7。通过对似斑状碱长正长岩ε_Hf(t)值及其中暗色包体岩相学分析,表明该岩石源区岩浆可能是由地壳重熔形成的花岗质岩浆、岩石圈富集地幔以及亏损地幔岩浆混合形成。通过对华北克拉通北缘早白垩世不同地区A型花岗岩的εHf(t)值的对比分析表明,这些A型花岗岩的源区物质来源具有多元性,并随着时间演化,A型花岗岩中亏损地幔的成分贡献越来越多,表明这个时期大规模的岩石圈减薄近于完成,亏损地幔物质开始上涌,并直接参与了岩浆活动。     

Strategies towards robust interpretations of in situ zircon Lu-Hf isotope analyses

The combination of U-Pb and Lu-Hf compositions measured in zircon crystals is a remarkably powerful isotopic couplet that provides measures on both the timing of mineral growth and the radiogenic enrichment of the source from which the zircon grew.The U-Pb age documents the timing of zircon crystallization/recrystallization and Hf isotopes inform on the degree to which the host melt was derived from a radiogenic reservoir(e.g.depleted mantle) versus an unradiogenic reservoir(e.g.ancient continental crust),or some mixture of these sources.The ease of generating large quantities of zircon U-Pb and Lu-Hf data has been in large part facilitated by instrument advances.However,the dramatic increase in time constrained zircon Lu-Hf analyses in the Earth science community has brought to the fore the importance of careful data collection and reduction workflows,onto which robust geological interpretations may be based.In this work,we discuss the fundamentals of Lu-Hf isotopes in zircon,which then allows us to provide a robust,accessible,methodology for the assessment of data quality.Additionally,we discuss some novel techniques for:data visualization—that facilitates better transparency of data interpretation;integration of geographic information—that may reveal spatial trends where temporal trends were only apparent before;and some novel statistical evaluation tools—that may provide more rigorous interand intra-sample comparisons.     

U–Pb and Lu–Hf isotope systematics of detrital zircons from the Songpan–Ganzi Triassic flysch,NE Tibetan Plateau: implications for provenance and crustal growth

We conducted in situ U–Pb and Lu–Hf isotope analyses of 401 detrital zircons collected from the Songpan–Ganzi Triassic turbidite complex in an attempt to understand the provenance variations of the siliciclastic rocks and the crustal growth history of central China. These detrital zircons exhibit a wide age spectrum with three major peaks at 1.7–2.0 Ga, 750–1050 Ma, and 210–500 Ma. They are dominated by negative ?_Hf(t) values with a large range. Synthesis of the zircon U–Pb and Lu–Hf isotopic data indicate that the Triassic Songpan–Ganzi turbiditic succession could have been derived dominantly from the Tibetan terrains + the Kunlun and Qinling orogens. Our samples are characterized by a common, prominent group of Hf crust formation model ages at 0.8–4.1 Ga with a peak at 2.7–3.4 Ga. This fact indicates that (1) Phanerozoic magmatism in central China could have been predominantly products of crustal reworking with insignificant formation of juvenile crust and (2) the Neoarchaean was an important period of continental growth in central China. In addition, our data set also reveal that three widespread tectonothermal events could have occurred in the region during the late Mesoproterzoic, Palaeozoic, and early Mesozoic, respectively.     

人工合成锆石Lu-Hf同位素标样方法研究

研究了人工合成锆石并加入微量元素的实验方法和条件。人工合成锆石是以氧化锆和硅酸锂为原料,以钼酸锂和氧化钼为助熔剂,并加入其他元素如Hf、Lu、Yb、U、Th、Pb等元素,充分混匀后转入带盖铂金坩埚中,在高温马弗炉中连续加热生长形成锆石晶体。利用激光剥蚀系统与电感耦合等离子体质谱技术分析了合成锆石晶体中微量元素含量和Lu-Hf同位素组成,结果表明合成锆石晶体中Lu、Yb、U、Th、Pb等微量元素含量不均一,而Hf的含量和Lu-Hf同位素组成有很好的均一性。     

Early Archean crustal evolution of the Jack Hills Zircon source terrane inferred from Lu-Hf, Pb/Pb, and δO systematics of Jack Hills zircons

Several lines of isotopic evidence - the most direct of which is from Hadean Jack Hills zircons - suggest a very early history of crust formation on Earth that began by about 4.5 Ga. To constrain both the fate of the reservoir for this crust and the nature of crustal evolution in the sediment source region of the Jack Hills, Western Australia, during the early Archean, we report here initial ¹⁷⁶Hf/¹⁷⁷Hf ratios and δ¹⁸O systematics for <4 Ga Jack Hills zircons. In contrast to the significant number of Hadean zircons which contain highly unradiogenic ¹⁷⁶Hf/¹⁷⁷Hf requiring a near-zero Lu/Hf reservoir to have separated from the Earth’s mantle by 4.5 Ga, Jack Hills zircons younger than ca. 3.6 Ga are more radiogenic than -13ε (CHUR) at 3.4 Ga in contrast to projected values at 3.4 Ga of -20ε for the unradiogenic Hadean reservoir indicating that some later juvenile addition to the crust is required to explain the more radiogenic younger zircons. The shift in the Lu-Hf systematics together with a narrow range of mostly mantle-like δ¹⁸O values among the <3.6 Ga zircons (in contrast to the spread towards sedimentary δ¹⁸O among Hadean samples) suggests a period of transition between 3.6 and 4 Ga in which the magmatic setting of zircon formation changed and the highly unradiogenic low Lu/Hf Hadean crust ceased to be available for intracrustal reworking. Constraining the nature of this transition provides important insights into the processes of crustal reworking and recycling of the Earth’s Hadean crust as well as early Archean crustal evolution.     

甘肃敦煌水峡口地区前寒武纪岩石的锆石U-Pb年龄、Hf同位素组成及其地质意义

敦煌杂岩位于塔里木克拉通的东部,探寻和研究其中的早前寒武纪地质体对于探讨敦煌地块早前寒武纪地壳的形成和演化及其构造归属等问题具有重要的意义.甘肃敦煌水峡口地区的敦煌杂岩主要由英云闪长质片麻岩、花岗闪长质片麻岩以及表壳岩石组成.利用LA-ICP-MS锆石U-Pb定年方法测得水峡口英云闪长片麻岩和花岗片麻岩原岩的形成年龄分别为2561±16Ma和2510±22Ma,确证了在敦煌杂岩中存在太古宙岩石.此外,还获得斜长角闪岩的变质年龄为1806±14Ma,推测其原岩岩浆可能来自古老岩石圈地幔的部分熔融.根据已有的资料提出在古元古代晚期(1.80 ～ 1.85Ga)敦煌杂岩经历了一期较广泛的变质作用.锆石Hf同位素显示～2.5Ga的岩石年龄在敦煌地块代表新太古代晚期重要地壳生长时期,而～1.8Ga的构造-热事件则是以古老地壳物质循环再造为主.这些资料显示敦煌地块和华北克拉通在早前寒武纪经历了类似的地壳形成和演化过程,且共同记录了全球性的Columbia碰撞造山事件信息.     

Late Palaeozoic and early Mesozoic tectonic and palaeogeographic evolution of central China: evidence from U–Pb and Lu–Hf isotope systematics of detrital zircons from the western Qinling region

The western Qinling region of central China is situated centrally in the Kunlun, Qilian, Qinling, Longmenshan, and Songpan–Ganzi orogens. Late Palaeozoic and Early Mesozoic sediments deposited here may provide keys to understanding the tectonic evolution of the Palaeo-Tethys and collision of the North China and Yangtze Cratons. We conducted in situ U–Pb and Lu–Hf isotope analyses of 568 detrital zircons collected from Upper Palaeozoic to Mesozoic sandstones in the central Qinling block, Taohe depression, and Bailongjiang block in western Qinling to constrain the sources of these sandstones. Our results reveal that the Bailongjiang block has affinities with the Yangtze Craton, from which it may have been rifted. Therefore, the Palaeo-Tethyan Animaqen suture between the two cratons lies north of the Bailongjiang block. We identified the North China Craton as the main source for Triassic flysch in central China. It is possible that the Bailongjiang block could have blocked detritus shed from the North China Craton into the main depositional basins in the Songpan–Ganzi area. The dominance of 300–200 Ma detrital zircons of metamorphic origin in Lower Jurassic sandstones indicates that the Dabie–Qinling orogen was elevated during Early Jurassic time. In addition, our Lu–Hf isotopic results also reveal that Phanerozoic igneous rocks in central China were mostly products of crustal reworking with insignificant formation of juvenile crust.     

胶东地区东部晚侏罗世花岗岩锆石U-Pb定年、Hf同位素特征及其对金成矿构造背景的限定SCIEI北大核心CSCD

胶东地区是目前我国最重要的金矿产地,已累积探明黄金储量接近5000t。金矿在胶东地区分布非常不均,主要集中在胶北地体,而胶东东部地区金矿产出较少。晚侏罗世的玲珑花岗岩是胶北金矿区最重要的赋矿围岩之一。虽然胶东东部同样有晚侏罗世花岗岩发育,但赋存金矿较少,因此前人对东部这些花岗岩体的研究相对较少。本文选取胶东东部的文登岩体和垛崮山岩体进行了锆石U-Pb定年和Hf同位素分析,同时收集整理了胶北地体的玲珑岩体数据,通过开展胶东东部及西北部同一时期岩体的差异性研究,为该区金成矿作用的研究提供重要线索。分析结果显示,文登岩体和垛崮山岩体的形成时代为晚侏罗世(~160Ma),与玲珑岩体时代一致。三个岩体均含有较多的三叠纪(~230Ma)和新元古代(~780Ma)的继承锆石,表明晚侏罗世花岗岩的岩浆源区主要为经历了超高压变质作用的扬子板块。不同的是,玲珑岩体中有更多的华北板块物源的年龄记录(~1400Ma、~1700Ma、~2500Ma),垛崮山岩体中这些年龄的继承锆石少于玲珑岩体,而文登岩体更少。文登岩体、垛崮山岩体的新生岩浆锆石ε;(t)值范围分别为-30.7~-20.3和-27.5~-17.9,玲珑岩体的新生岩浆锆石ε;(t)值的变化范围更广,在-29.3~-9.3之间,而且呈现出从文登岩体到垛崮山岩体到玲珑岩体,ε;(160Ma)值逐渐增高的现象。其原因可能是扬子板块与华北板块碰撞后,幔源岩浆底侵并诱发加厚的地壳发生部分熔融,形成花岗岩。在此过程中胶北地体深部受到幔源物质的影响,从而对金及成矿相关元素产生一定的预富集作用,而同时期胶东东部地区未受到明显的地幔物质影响,可能是该区金矿产出较少的原因之一。