Magma batches in the Timber Mountain magmatic system, Southwestern Nevada Volcanic Field, Nevada, USA

The common occurrence of compositionally and mineralogically zoned ash flow sheets, such as those of the Timber Mountain Group, provides evidence that the source magma bodies were chemically and thermally zoned. The Rainier Mesa and Ammonia Tanks tuffs of the Timber Mountain Group are both large volume (1200 and 900 km³, respectively) chemically zoned (57–78 wt.% SiO₂) ash flow sheets. Evidence of distinct magma batches in the Timber Mountain system are based on: (1) major- and trace-element variations of whole pumice fragments; (2) major-element variations in phenocrysts; (3) major-element variations in glass matrix; and (4) emplacement temperatures calculated from Fe-Ti oxides and feldspars. There are three distinct groups of pumice fragments in the Rainier Mesa Tuff: a low-silica group and two high-silica groups (a low-Th and a high-Th group). These groups cannot be related by crystal fractionation. The low-silica portion of the Rainier Mesa Tuff is distinct from the low-silica portion of the overlying Ammonia Tanks Tuff, even though the age difference is less than 200,000 years. Three distinct groups occur in the Ammonia Tanks Tuff: a low-silica, intermediate-silica and a high-silica group. Part of the high-silica group may be due to mixing of the two high-silica Rainier Mesa groups. The intermediate-silica group may be due to mixing of the low- and high-silica Ammonia Tanks groups. Three distinct emplacement temperatures occur in the Rainier Mesa Tuff (869, 804, 723 °C) that correspond to the low-silica, high-Th and low-Th magma batches, respectively. These temperature differences could not have been maintained for any length of time in the magma chamber (cf. Turner, J.S., Campbell, I.H., 1986. Convection and mixing in magma chambers. Earth-Sci. Rev. 23, 255–352; Martin, D., Griffiths, R.W., Campbell, I.H., 1987. Compositional and thermal convection in magma chambers. Contrib. Mineral. Petrol. 96, 465–475) and therefore eruption must have occurred soon after emplacement of the magma batches into the chamber. Emplacement temperatures of the pumice fragments from the Ammonia Tanks Tuff show a continuous gradient of temperatures with composition. This continuous temperature gradient is consistent with the model of storage of magma batches in the Ammonia Tanks group that have undergone both thermal and chemical diffusion.     

Distribution, age and chemical composition of tephra layers in deep-sea sediments off western Indonesia

Tephra layers occur in deep-sea sediments of the northeastern Indian Ocean, adjacent to western Indonesian are. The layers range in age from Recent to Late Miocene. Relative abundance of light and heavy mineral species in all tephra layers have been determined, and pure glass shards from representative samples have been analyzed chemically for major oxides. On the basis of the chemical data, three distinct provinces can be recognized: (1) an extensive province of rhyolitic tephra layers, ranging in age back to Late Miocene, is found adjacent to Sumatra; (2) a more restricted province of dacitic layers, adjacent to Sunda Strait and western Java; and (3) a province of andesitic layers, found adjacent to eastern Java and the Lesser Sunda Islands. Chemical composition of tephra layers in each province remains constant with time. As an example, tephra layers from the rhyolitic province are characterized by a high and restricted range of SiO₂ (75–77%) when expressed on an H₂O-free basis.Tephra layers recovered from the study area were examined for chemical evidence of secondary alteration. The analyses revealed that H₂O is the only major oxide in the glass shards which increases progressively with the age of the tephra layers regardless of the bulk composition. H₂O, however, reaches a “saturation point” of 4–5% in the layers 250–400 thousands of years old and remains constant to the oldest recovered tephra layer (7.5 m.y. old).The decrease in silica content in deep-sea tephra layers eastward along the Indonesian volcanic arc coincides with a similar eastward decrease in average silica content in Indonesian lavas. A relatively high silica content in lavas from Sumatra, with associated ignimbrites and their deep-sea ash-fall equivalents is closely linked to thick pre-Cenozoic crust. In the portion of the arc to the east of Sumatra, the crust is Cenozoic and thin. Difference in silica content of both the lavas and deep-sea tephras along the Indonesian arc is considered in regard to the hypothesis of “magma filtering” which is based on the contrasting density gradients of ascending magma and the upper crust.     

Compositional heterogeneity of distal tephra deposits from the 1912 eruption of Novarupta, Alaska

Physical and chemical analyses of distal tephra from the 1912 eruption of Novarupta, Alaska, show considerable variations in glass and mineral compositions. A combination of a 150°C range in temperature deduced from iron-titanium oxide geothermometry, and curved patterns in bivariant element plots of glass compositions indicate that a chamber of compositionally zoned magma existed prior to the eruption. Magma-mixing cannot explain these features. The magma chamber may have resembled the model recently proposed by McBirney (1980). A highly silicic, quartz-phyric magma with mean phenocryst compositions of An₂₅ plagioclase, Fs₄₂ orthopyroxene, at a temperature of 880°C and a water pressure of 1.4 kbar, was located above a more mafic, hotter magma, bearing phenocrysts of An₄₅ plagioclase and Fs₃₅, orthopyroxene.Our results on distal tephras compare favorably with those from a recently completed study at source by Hildreth (1983), suggesting that useful petrologic information about distant volcanoes can be obtained from both types of deposits. Compositionally heterogeneous abyssal tephra layers are common in the Gulf of Alaska. Eruptions from chambers of zoned magma may account for many of these layers.     

Origin of silicic volcanic rocks in Central Costa Rica: a study of a chemically variable ash-flow sheet in the Tiribí Tuff

Chemical heterogeneities of pumice clasts in an ash-flow sheet can be used to determine processes that occur in the magma chamber because they represent samples of magma that were erupted at the same time. The dominant ash-flow sheet in the Tiribí Tuff contains pumice clasts that range in composition from 55.1 to 69.2 wt% SiO₂. It covers about 820 km² and has a volume of about 25 km³ dense-rock equivalent (DRE). Based on pumice clast compositions, the sheet can be divided into three distinct chemical groupings: a low-silica group (55.1-65.6 wt% SiO₂), a silicic group (66.2-69.2 wt% SiO₂), and a mingled group (58.6-67.7 wt% SiO₂; all compositions calculated 100% anhydrous). Major and trace element modeling indicates that the low-silica magma represents a mantle melt that has undergone fractional crystallization, creating a continuous range of silica content from 55.1-65.6 wt% SiO₂. Eu/Eu*, MREE, and HREE differences between the two groups are not consistent with crystal fractionation of the low-silica magma to produce the silicic magma. The low-silica group and the silicic group represent two distinct magmas, which did not evolve in the same magma chamber. We suggest that the silicic melts resulted from partial melting of relatively hot, evolved calc-alkaline rocks that were previously emplaced and ponded at the base of an over-thickened basaltic crust. The mingled group represents mingling of the two magmas shortly before eruption. Electronic supplementary material to this paper can be obtained by using the Springer LINK server located at http://dx.doi.org/10.1007/s00445-001-0188-8.     

Origin and emplacement of the andesite of Burroughs Mountain,a zoned,large-volume lava flow at Mount Rainier,Washington, USA

Burroughs Mountain, situated at the northeast foot of Mount Rainier, WA, exposes a large-volume (3.4 km³) andesitic lava flow, up to 350 m thick and extending 11 km in length. Two sampling traverses from flow base to eroded top, over vertical sections of 245 and 300 m, show that the flow consists of a felsic lower unit (100 m thick) overlain sharply by a more mafic upper unit. The mafic upper unit is chemically zoned, becoming slightly more evolved upward; the lower unit is heterogeneous and unzoned. The lower unit is also more phenocryst-rich and locally contains inclusions of quenched basaltic andesite magma that are absent from the upper unit. Widespread, vuggy, gabbronorite-to-diorite inclusions may be fragments of shallow cumulates, exhumed from the Mount Rainier magmatic system. Chemically heterogeneous block-and-ash-flow deposits that conformably underlie the lava flow were the earliest products of the eruptive episode. The felsic–mafic–felsic progression in lava composition resulted from partial evacuation of a vertically-zoned magma reservoir, in which either (1) average depth of withdrawal increased, then decreased, during eruption, perhaps due to variations in effusion rate, or (2) magmatic recharge stimulated ascent of a plume that brought less evolved magma to shallow levels at an intermediate stage of the eruption. Pre-eruptive zonation resulted from combined crystallization–differentiation and intrusion(s) of less evolved magma into the partly crystallized resident magma body. The zoned lava flow at Burroughs Mountain shows that, at times, Mount Rainier’s magmatic system has developed relatively large, shallow reservoirs that, despite complex recharge events, were capable of developing a felsic-upward compositional zonation similar to that inferred from large ash-flow sheets and other zoned lava flows.     

Intracrustal origin of Arenal basaltic andesite in the light of solid–melt interactions and related compositional buffering

The origin of Arenal basaltic andesite can be explained in terms of fractional crystallization of a parental high-alumina basalt (HAB), which assimilates crustal rocks during its storage, ascent and evolution. Contamination of this melt by Tertiary calc-alkalic intrusives (quartz–diorite and granite, with ⁸⁷Sr/⁸⁶Sr ratios ranging 0.70381–0.70397, nearly identical with those of the Arenal lavas) occurs at upper crustal levels, following the interaction of ascending basaltic magma masses with gabbroic–anorthositic layers. Fragments of these layers are found as inclusions within Arenal lavas and tephra and may show reaction rims (1–5 mm thick, consisting of augite, hypersthene, bytownitic–anorthitic plagioclase, and granular titanomagnetite) at the gabbro–lava interface. These reaction rims indicate that complete `assimilation' was prevented since the temperature of the host basaltic magma was not high enough to melt the gabbroic materials (whose mineral phases are nearly identical to the early formed liquidus phases in the differentiating HAB). Olivine gabbros crystallized at pressure of about 5–6 kbar and equilibrated with the parental HAB at pressures of 3–6 kbar (both under anhydrous and hydrous conditions), and temperatures ranging 1000–1100°C. In particular, `deeper' interactions between the mafic inclusions and the hydrous basaltic melt (i.e., with about 3.5 wt.% H₂O) are likely to occur at 5.4 (±0.4) kbar and temperatures approaching 1100°C. The olivine gabbros are thus interpreted as cumulates which represent crystallized portions of earlier Arenal-type basalts. Some of the gabbros have been `mildly' tectonized and recrystallized to give mafic granulites that may exhibit a distinct foliation. Below Arenal volcano a zoned magma chamber evolved prior the last eruptive cycle: three distinct andesitic magma layers were produced by simple AFC of a high-alumina basalt (HAB) with assimilation of Tertiary quartz–dioritic and granitic rocks. Early erupted 1968 tephra and 1969 lavas (which represent the first two layers of the upper part of a zoned magma chamber) were produced by simple AFC, with fractionation of plagioclase, pyroxene and magnetite and concomitant assimilation of quartz–dioritic rocks. Assimilation rates were constant (r<sub>1</sub>=0.33) for a relative mass of magma remaining of 0.77–0.80, respectively. Lavas erupted around 1974 are less differentiated and represent the `primitive andesitic magma type' residing within the middle–lower part of the chamber. These lavas were also produced by simple AFC: assimilation rates and the relative mass of magma remaining increased of about 10%, respectively (r₁=0.36, and F=0.89). Ba enrichment of the above lavas is related to selective assimilation of Ba from Tertiary granitic rocks. Lava eruption occurred as a dynamic response to the intrusion of a new magma into the old reservoir. This process caused the instability of the zoned magma column inducing syneruptive mixing between portions of two contiguous magma layers (both within the column itself and at lower levels where the new basalt was intruded into the reservoir). Syneruptive mixing (mingling) within the middle–upper part of the chamber involved fractions of earlier gabbroic cumulitic materials (lavas erupted around 1970). On the contrary, within the lower part of the chamber, mixing between the intruded HAB and the residing andesitic melt was followed by simple fractional crystallization (FC) of the hybrid magma layer (lavas erupted in 1978–1980). By that time the original magma chamber was completely evacuated. Lavas erupted in 1982/1984 were thus modelled by means of `open system' AFCRE (i.e., AFC with continuous recharge of a fractionating magma batch during eruption): in this case assimilation rates were r₁=0.33 and F=0.86. Recharge rates are slightly higher than extrusion rates and may reflect differences in density (between extruded and injected magmas), together with dynamic fluctuations of these parameters during eruption. Ba and LREE (La, Ce) enrichments of these lavas can be related to selective assimilation of Tertiary granitic and quartz–dioritic rocks. Calculated contents for Zr, Y and other REE are in acceptable agreement with the observed values. It is concluded that simple AFC occurs between two distinct eruption cycles and is typical of a period of repose or mild and decreasing volcanic activity. On the contrary, magma mixing, eventually followed by fractional crystallization (FC) of the hybrid magma layer, occurs during an ongoing eruption. Open-system AFCRE is only operative when the original magma chamber has been totally replenished by the new basaltic magma, and seems a prelude to the progressive ceasing of a major eruptive cycle.     

Structural,stratigraphic, and petrologic aspects of the Arenal-Chato volcanic system,Costa Rica: Evolution of a young stratovolcanic complex

Geologic mapping on a scale of 1:10000 and detailed stratigraphic studies of lava flows and tephra deposits of the Arenal-Chato volcanic system reveal a complex and cyclic volcanic history. This cyclicity provides insight into the evolution of magma batches during the growth of the andesitic volcanic system. The Arenal and Chato volcanoes have a central zone comprised of a lava armor and a distal zone comprised of a tephra apron. During Arenal's last two eruptive periods major craters formed near intersections of regional fractures at the lava armortephra apron transition. We suggest that such intersections are potential sites for future major explosions. The earliest rocks, i.e., the Chato lava flows, range in composition from basaltic andesite to andesite. These rocks, except for the andesitic domes of Chatito and La Espina, appear to have evolved from a common parental magma. The last active period of Chato volcano occurred 3550 B. P. The earliest known activity of Arenal volcano is 2900 B. P. Arenal lava flows have 54–56 wt% SiO₂ and may be subdivided into a high-alumina group (HAG, Al₂O₃ = 20 wt%) and a low-alumina group (LAG, Al₂O₃ = 19 wt%). Compared to the HAG, the LAG also has smaller amounts of incompatible elements and higher amounts of FeO and MgO. Arenal tephra deposits were emplaced by Plinian-Sub-Plinian explosions occurring at 300±150-yr intervals. These deposits are compositionally zoned and alternate between dacite and basalt. The stratigraphy reveals an apparent magmatic cycle consisting of (a) dacitic-andesitic tephra, (b) HAG lava flows, (c) LAG lava flows, and (d) andesitic-basaltic tephra. This magmatic cycle is repeated four times during Arenal's history and is interpreted to have developed by the crystal fractionation and crystal redistribution of a single magma batch. The period of this cycle, and consequently the life of a magma batch, is about 800 years. If the cyclic pattern continues, a basaltic explosive phase may occur in the next 250 years.     

Replenishment of a mafic magma in a zoned felsic magma chamber beneath Rishiri Volcano, Japan

The trachytic Tanetomi lava from Rishiri Volcano, northern Japan, provides useful information concerning how a replenished mafic magma mixes with a compositionally zoned felsic magma in a magma chamber. The Tanetomi lava was erupted in the order of Lower lava 1 (LL1, 59.2-59.8 wt.% in SiO₂), Lower lava 2 (LL2, 58.4-59.1 wt.%), and Upper lava (UL, 59.9-65.1 wt.%). Evidence for mixing with a mafic magma is observed only in the LL2, in which a greater amount of crystals derived from the mafic magma occurs in rocks with higher SiO₂ content. The whole-rock compositional trend of the Tanetomi lavas is fairly smooth except for the LL2 lava composition, which scatter along the main composition trend. There is no reasonable composition of basaltic magma on the extrapolation of the LL2 composition trend, and the trend cannot be explained by a simple two-component magma mixing. Before the replenishment, the felsic magma was zoned in composition (58-65 wt.% in SiO₂) and temperature (1030-920°C) in the magma chamber located at the pressure of ~2 kbar. The compositional variation of the main felsic magma was produced by extraction of a fractionated interstitial melt from mush zones along the chamber walls and its subsequent mixing with the main magma (boundary layer fractionation). The LL1 magma tapped the magma chamber soon after the replenishment, before the mafic magma mixed with the overall felsic magma. Then the basalt magma mixed heterogeneously with the upper part of the felsic magma by forced convection as a fountain during injection. The mixing of the basalt magma with compositionally zoned felsic magma resulted in the characteristic composition trend of the LL2. The fraction of basaltic magma in the LL2 magma is estimated to be at most 10%. Despite such a small proportion, the basalt magma was mixed completely with the felsic magma, probably because the crystallinity of undercooled basalt magma was low enough to behave as a liquid.     

Mount St. Helens a decade after the 1980 eruptions: magmatic models,chemical cycles,and a revised hazards assessment

Available geophysical and geologic data provide a simplified model of the current magmatic plumbing system of Mount St. Helens (MSH). This model and new geochemical data are the basis for the revised hazards assessment presented here. The assessment is weighted by the style of eruptions and the chemistry of magmas erupted during the past 500 years, the interval for which the most detailed stratigraphic and geochemical data are available. This interval includes the Kalama (A. D. 1480–1770s?), Goat Rocks (A.D. 1800–1857), and current eruptive periods. In each of these periods, silica content decreased, then increased. The Kalama is a large amplitude chemical cycle (SiO₂: 57%–67%), produced by mixing of arc dacite, which is depleted in high field-strength and incompatible elements, with enriched (OIB-like) basalt. The Goat Rocks and current cycles are of small amplitude (SiO₂: 61%–64% and 62%–65%) and are related to the fluid dynamics of magma withdrawal from a zoned reservoir. The cyclic behavior is used to forecast future activity. The 1980–1986 chemical cycle, and consequently the current eruptive period, appears to be virtually complete. This inference is supported by the progressively decreasing volumes and volatile contents of magma erupted since 1980, both changes that suggest a decreasing potential for a major explosive eruption in the near future. However, recent changes in seismicity and a series of small gas-release explosions (beginning in late 1989 and accompanied by eruption of a minor fraction of relatively low-silica tephra on 6 January and 5 November 1990) suggest that the current eruptive period may continue to produce small explosions and that a small amount of magma may still be present within the conduit. The gas-release explosions occur without warning and pose a continuing hazard, especially in the crater area. An eruption as large or larger than that of 18 May 1980 (0.5 km³ dense-rock equivalent) probably will occur only if magma rises from an inferred deep (7 km), relative large (5–7 km³) reservoir. A conservative approach to hazard assessment is to assume that this deep magma is rich in volatiles and capable of erupting explosively to produce voluminous fall deposits and pyroclastic flows. Warning of such an eruption is expectable, however, because magma ascent would probably be accompanied by shallow seismicity that could be detected by the existing seismic-monitoring system. A future large-volume eruption (0.1 km³) is virtually certain; the eruptive history of the past 500 years indicates the probability of a large explosive eruption is at least 1% annually. Intervals between large eruptions at Mount St. Helens have varied widely; consequently, we cannot confidently forecast whether the next large eruption will be years decades, or farther in the future. However, we can forecast the types of hazards, and the areas that will be most affected by future large-volume eruptions, as well as hazards associated with the approaching end of the current eruptive period.     

Contrasting compositions of Mariana Trough fallout tephra and Mariana Island arc volcanics: a fractional crystallization link

Discrete Quaternary (<400 ka) tephra fallout layers (mostly <1 cm thick) within the siliceous oozes of the central Mariana Trough at 18°N are characterized by medium-K to high-K subalkalic volcanic glasses (K₂O=0.8–3.2 wt.%) with high large-ion lithophile elements (LILE)/high-field-strength elements (HFSE) ratios and Nb depletion (Ba/La35; Ba/Zr3.5; La/Nb4) typical for convergent margin volcanic rocks. Compositional zoning within layers ranges from basaltic to dacitic (SiO₂=48–71 wt.%; MgO=0.7–6.5 wt.%); all layers contain basaltic andesites. The tephra layers are interpreted as single explosive eruptive events tapping chemically zoned reservoirs, the sources being the Mariana arc volcanoes (MAV) due to their proximity (100–400 km) and similar element ratios (MAV: Ba/La=36±7; Ba/Zr=3.5±0.9). The glasses investigated, however, contrast with the contemporaneous basaltic to dacitic lavas of the MAV by being more enriched in TiO₂ (1.2 wt.%; MAV0.8 wt.%), FeO^* (10 wt.%, MAV8–9 wt.%), K₂O (1.1 wt.%; MAV0.8 wt.%) and P₂O₅ (0.4 wt.%; MAV0.2 wt.%). (Semi-)Incompatible trace elements (including Rare Earth Elements (REE)) of the basaltic-andesitic and dacitic glasses match those of the dacitic MAV lavas, which became enriched by fractional crystallization. Moreover, the glasses follow a tholeiitic trend of fractionation in contrast to MAV transitional trends and have a characteristic P₂O₅ trend that reaches a maximum of 0.6 wt.% P₂O₅ at 57 wt.% SiO₂, whereas MAV lavas increase linearly in P₂O₅ from 0.1 to 0.3 wt.% with increasing silica. Both explosive and effusive series are interpreted to have evolved in common magma reservoirs by convective fractionation. Similar parental magmas are suggested to have separated into coexisting Si-andesitic to dacitic and basaltic melts by in situ crystallization. The differentiated melt is interstitial in an apatite-saturated crystalline mush of plag+px±ox±ol at the cooler chamber margins in contrast to the less differentiated basaltic to basaltic-andesitic magmas, which are not yet saturated in apatite and occupy the chamber interior. Reinjection of interstitial melt into the chamber interior and mixing with larger melt fractions of the interior liquid (mixing ratios about 1: 8–9) can explain the paradoxical behavior of apatite-controlled P and MREE variation in the basaltic andesite glasses and their MAV dacite-like fractionation patterns. The process may also account for the exclusively tholeiitic trend of fractionation of the glass shard series, but in situ crystallization alone cannot cause their absolute enrichment in (semi-)incompatible elements. The newly mixed melt is suggested to form the basaltic end member of the glass shard series. However, it must have become physically separated from the main MAV magma body (possibly by density-driven convective fractionation) in order to allow for further evolution of the contrasting geochemical paths as well as differentiation.     

Role of magma mixing in the petrogenesis of tephra erupted during the 1990–98 explosive activity of Nevado Sabancaya,southern Peru

The Nevado Sabancaya in southern Peru has exhibited a persistent eruptive activity over eight years following a violent eruption in May–June 1990. The explosive activity consisted of alternated vulcanian and phreatomagmatic events, followed by declining phreatic activity since late 1997. The mean production rate of magma has remained low (10⁶–10⁷ m³ per year).The 1990–1998 eruptive episode produced andesitic and dacitic magmas. The juvenile tephra span a narrow range of compositions (60–64 wt% SiO₂). While SiO₂ contents do vary slightly, they do not show any systematic variation with time. Phenocryst assemblages in the juvenile rocks consist of mainly plagioclase, associated with high-Ca pyroxene, hornblende, biotite, and iron-titanium oxides. Rare fine-grained magmatic enclaves, with angular to subrounded shapes, are contained within some of the juvenile lava blocks, which were expelled since 1992. They have a homogeneous andesitic composition (57 wt% SiO₂) and show randomly oriented interlocking columnar or acicular crystals (plagioclase and amphibole), with interstitial glass and a few voids, which define a quench-textured groundmass.Textural, mineralogical and chemical evidence suggests that the 1990–1998 eruptions have mainly erupted hybrid andesites, except for the 1990 dacite. The hybrid andesites contain a mixed population of plagioclase phenocrysts: Ca-rich clear plagioclase (An_40–60), Na-rich clear plagioclase (An_25–35), and inversely zoned dusty-rimmed plagioclase with a sodic core (An_25–40) surrounded by a Ca-rich mantle (An_45–65). Melt-inclusions, wavy dissolution surfaces and stepped zoning within the dusty-rimmed plagioclases are compatible with resorption induced by magma recharge events. Chemical and isotopic lines of evidence also show that andesites are hybrids resulting from magma mixing processes. Repeated magma recharge, incomplete homogenisation and different degrees of crustal assimilation may explain the extended range of isotopic signatures.Our study leads to propose an evolution model for the magmatic system at Nevado Sabancaya. The main magma body consisted of dacitic magmas differentiating through extensive open-system crystallization (AFC). Repeated recharge of more mafic magmas induced magma mixing, leading to the formation of hybrid andesites. A partially crystalline boundary layer formed at the interface between the andesites and the recharge magma. The magmatic enclaves were produced by the disruption and dispersion of this andesitic layer as a result of new magma injection and/or sustained tectonic activity.Periodic magma recharge and interactions with groundwater are two processes that have enabled the explosive regime to remain persistent over an 8-year-long period. What precise mechanism triggers the eruptive activity remains speculative, but it may be related either to new magma injection, or to the sustained tectonic activity that occurred at that time in the vicinity of the volcano, or a combination of both.     

Explosive silicic volcanism in Iceland and the Jan Mayen area during the last 6 Ma: sources and timing of major eruptions

Fifty-three major explosive eruptions on Iceland and Jan Mayen island were identified in 0–6-Ma-old sediments of the North Atlantic and Arctic oceans by the age and the chemical composition of silicic tephra. The depositional age of the tephra was estimated using the continuous record in sediment of paleomagnetic reversals for the last 6 Ma and paleoclimatic proxies (δ¹⁸O, ice-rafted debris) for the last 1 Ma. Major element and normative compositions of glasses were used to assign the sources of the tephra to the rift and off-rift volcanic zones in Iceland, and to the Jan Mayen volcanic system. The tholeiitic central volcanoes along the Iceland rift zones were steadily active with the longest interruption in activity recorded between 4 and 4.9 Ma. They were the source of at least 26 eruptions of dominant rhyolitic magma composition, including the late Pleistocene explosive eruption of Krafla volcano of the Eastern Rift Zone at about 201 ka. The central volcanoes along the off-rift volcanic zones in Iceland were the source of at least 19 eruptions of dominant alkali rhyolitic composition, with three distinct episodes recorded at 4.6–5.3, 3.5–3.6, and 0–1.8 Ma. The longest and last episode recorded 11 Pleistocene major events including the two explosive eruptions of Tindfjallajökull volcano (Thórsmörk, ca. 54.5 ka) and Katla volcano (Sólheimar, ca. 11.9 ka) of the Southeastern Transgressive Zone. Eight major explosive eruptions from the Jan Mayen volcanic system are recorded in terms of the distinctive grain-size, mineralogy and chemistry of the tephra. The tephra contain K-rich glasses (K₂O/SiO₂>0.06) ranging from trachytic to alkali rhyolitic composition. Their normative trends (Ab–Q–Or) and their depleted concentrations of Ba, Eu and heavy-REE reflect fractional crystallisation of K-feldspar, biotite and hornblende. In contrast, their enrichment in highly incompatible and water-mobile trace elements such as Rb, Th, Nb and Ta most likely reflect crustal contamination. One late Pleistocene tephra from Jan Mayen was recorded in the marine sequence. Its age, estimated between 617 and 620 ka, and its composition support a common source with the Borga pumice formation at Sør Jan in the south of the island.     

Chemical and optical studies of glass shards in Pleistocene and Pliocene ash layers from DSDP site 192, Northwest Pacific Ocean

Thirty-four ash layers of Pleistocene and Pliocene age from DSDP Site 192, northwestern Pacific Ocean, have been subjected to detailed chemical and optical study to evaluate: (1) the chemical and optical variability in glass shards from deep-sea ash layers, and (2) secondary changes brought about by prolonged exposure to seawater. Glass shards from approximately half of the ash layers studied were found to have uniform compositions which approach the precision of the microprobe chemical analyses, whereas the remainder are compositionally diverse (e.g., SiO₂, variations of 5–15% among shards from the same ash layer) and appear to be the eruptive products of compositionally zoned magma chambers. Optical studies of glass shards confirm the absence of devitrification or the formation of pervasive secondary alteration products. By contrast, chemical studies suggest that the glass shards have experienced progressive hydration with possible minor ion exchange of K, Mg, Ca and Si. The hydration occurs rapidly and leads to a rather uniform water content of 4.5–5% after several hundred thousands of years exposure to seawater. Step-wise heating dehydration experiments, optical effects, and published'oxygen isotope studies indicate that the water of hydration is incorporated uniformly within the glass. Systematic chemical differences between electron microprobe analyses of glass shard interiors and corresponding bulk chemical study by atomic absorption lead us to postulate that glass shard margins have undergone a minor chemical exchange with major cations in seawater. They have gained 0.10–0.20 wt. % K₂0, MgO, and CaO while losing a corresponding amount of Si₂O. Although the glass shards from DSDP Site 192 are hydrated and may have experienced subtle, surficial ion exchange, we stress that they are the most chemically representative samples available of magmas that were explosively erupted from volcanic arcs.     

Ignimbrites of basaltic andesite and andesite compositions from Tanna,New Hebrides Arc

Tanna island is part of a large volcanic complex mainly subsided below sea-level. On-land, two series of hydroclastic deposits and ignimbrites overlie the subaerial remains of a basal, mainly effusive volcano. The ‘Older’ Tanna Ignimbrite series (OTI), Late Pliocene or Pleistocene in age, consists of ash flows and ash- and scoria-flow deposits associated with fallout tephra layers, overlain by indurated pumice-flow deposits. Phreatomagmatic features are a constant characteristic of these tuffs. The ‘younger’ Late Pleistocene pyroclastics, the Siwi sequence, show basal phreatomagmatic deposits overlain by two successive flow units, each comprising a densely welded layer and a nonwelded ash-flow deposit. Whole-rock analyses of 17 juvenile clasts from the two sequences (vitric blocks from the phreatomagmatic deposits, welded blocks, scoriaceous bombs and pumices from the ignimbrites) show basaltic andesite and andesite compositions (SiO₂=53–60%). In addition, 296 microprobe analyses of glasses in these clasts show a wide compositional range from 51 to 69% SiO₂. Dominant compositions at ∼54, 56, 58.5 and 61–62% SiO₂ characterize the glass from the OTI. Glass compositions in the lower – phreatomagmatic – deposits from the Siwi sequence also show multimodal distribution, with peaks at SiO₂=55, 57.5, 61–62 and 64% whereas the upper ignimbrite has a predominant composition at 61–62% SiO₂. In both cases, mineralogical data and crystal fractionation models suggest that these compositions represent the magmatic signature of a voluminous layered chamber, the compositional gradient of which is the result of fractional crystallization. During two major eruptive stages, probably related to two caldera collapses, the OTI and Siwi ignimbrites represent large outpourings from these magmatic reservoirs. The successive eruptive dynamics, from phreatomagmatic to Plinian, emphasize the role of water in initiating the eruptions, without which the mafic and intermediate magmas probably would not have erupted. Received: February 19, 1993/Accepted October 10, 1993     

Silicic magma entering a basaltic magma chamber: eruptive dynamics and magma mixing — an example from Salina (Aeolian islands,Southern Tyrrhenian Sea)

The Pollara tuff-ring resulted from two explosive eruptions whose deposits are separated by a paleosol 13 Ka old. The oldest deposits (LPP, about 0.2 km³) consist of three main fall units (A, B, C) deposited from a subplinian column whose height (7–14 km) increased with time from A to C, as a consequence of the increased magma discharge rate during the eruption (1–8x10⁶ kg/s). A highly variable juvenile population characterizes the eruption. Black, dense, highly porphyritic, mafic ejecta (SiO₂=50–55%) almost exclusively form A deposits, whereas grey, mildly vesiculated, mildly porphyritic pumice (SiO₂=56–67%) and white, highly vesiculated, nearly aphyric pumice (SiO₂=66–71%) predominate in B and C respectively. Mafic cumulates are abundant in A, while crystalline lithic ejecta first appear in B and increase upward. The LPP result from the emptying of an unusual and unstable, compositionally zoned, shallow magma chamber in which high density mafic melts capped low density salic ones. Evidence of the existence of a short crystal fractionation series is found in the mafic rocks; the andesitic pumice results from complete blending between rhyolitic and variously fractionated mafic melts (salic component up to 60 wt%), whereas bulk dacitic compositions mainly result from the presence of mafic xenocrysts within rhyolitic glasses. Viscosity and composition-mixing diagrams show that blended liquids formed when the visosities of the two end members had close values. The following model is suggested: 1. A rhyolitic magma rising through the metamorphic basement enterrd a mafic magma chamber whose souter portions were occupied by a highly viscous, mafic crystal mush. 2. Under the pressure of the rhyolitic body the nearly rigid mush was pushed upwards and mafic melts were squeezed against the walls of the chamber, beginning roof fracturing and mingling with silicic melts. 3. When the equilibrium temperature was reached between mafic and silicic melts, blended liquids rapidly formed. 4. When fractures reached the surface, the eruption began by the ejection of the mafic melts and crystal mush (A), followed by the emission of variously mingled and blended magmas (B) and ended by the ejection of nearly unmixed rhyolitic magma (C).     

The Oligocene Lund Tuff, Great Basin, USA: a very large volume monotonous intermediate

Unusual monotonous intermediate ignimbrites consist of phenocryst-rich dacite that occurs as very large volume (>1000 km³) deposits that lack systematic compositional zonation, comagmatic rhyolite precursors, and underlying plinian beds. They are distinct from countless, usually smaller volume, zoned rhyolite–dacite–andesite deposits that are conventionally believed to have erupted from magma chambers in which thermal and compositional gradients were established because of sidewall crystallization and associated convective fractionation. Despite their great volume, or because of it, monotonous intermediates have received little attention. Documentation of the stratigraphy, composition, and geologic setting of the Lund Tuff – one of four monotonous intermediate tuffs in the middle-Tertiary Great Basin ignimbrite province – provides insight into its unusual origin and, by implication, the origin of other similar monotonous intermediates.The Lund Tuff is a single cooling unit with normal magnetic polarity whose volume likely exceeded 3000 km³. It was emplaced 29.02±0.04 Ma in and around the coeval White Rock caldera which has an unextended north–south diameter of about 50 km. The tuff is monotonous in that its phenocryst assemblage is virtually uniform throughout the deposit: plagioclase>quartz≈hornblende>biotite>Fe–Ti oxides≈sanidine>titanite, zircon, and apatite. However, ratios of phenocrysts vary by as much as an order of magnitude in a manner consistent with progressive crystallization in the pre-eruption chamber. A significant range in whole-rock chemical composition (e.g., 63–71 wt% SiO₂) is poorly correlated with phenocryst abundance.These compositional attributes cannot have been caused wholly by winnowing of glass from phenocrysts during eruption, as has been suggested for the monotonous intermediate Fish Canyon Tuff. Pumice fragments are also crystal-rich, and chemically and mineralogically indistinguishable from bulk tuff. We postulate that convective mixing in a sill-like magma chamber precluded development of a zoned chamber with a rhyolitic top or of a zoned pyroclastic deposit. Chemical variations in the Lund Tuff are consistent with equilibrium crystallization of a parental dacitic magma followed by eruptive mixing of compositionally diverse crystals and high-silica rhyolite vitroclasts during evacuation and emplacement. This model contrasts with the more systematic withdrawal from a bottle-shaped chamber in which sidewall crystallization creates a marked vertical compositional gradient and a substantial volume of capping-evolved rhyolite magma. Eruption at exceptionally high discharge rates precluded development of an underlying plinian deposit.The generation of the monotonous intermediate Lund magma and others like it in the middle Tertiary of the western USA reflects an unusually high flux of mantle-derived mafic magma into unusually thick and warm crust above a subducting slab of oceanic lithosphere.     

Compositions of deep-sea ash layers derived from north pacific volcanic arcs: variations in time and space

Glass separates from 115 ash layers derived from the Kamchatkan (DSDP Site 192; 34 layers), the eastern Aleutian (DSDP Site 183; 56 layers) and the Alaska Peninsula (DSDP Site 178; 25 layers) volcanic arcs have been analyzed for up to 28 elements. In addition, the abundance and diversity of associated mafic phenocrysts have been evaluated. The resulting data set has made possible an evaluation of the late Miocene to Recent changes in composition of ashes derived from North Pacific volcanic arcs and of the factors controlling the evolution of highly siliceous magmas.We find no evidence for a general transition from arc tholeiite to calc-alkalic magma parentage of ashes derived from the volcanic arcs during the last 10 m.y., but instead find 0.1- to 0.5-m.y. intervals during which particular types of volcanism are prevalent. Most convincing is the transition from arc tholeiite to calc-alkalic for ashes derived from Kamchatka during the last 0.8 m.y., a change believed to be associated with a landward shift in the site of magma generation. Considered together, ashes derived from North Pacific volcanic arcs have been becoming more siliceous during the last 1.5 m.y. and may be associated with accelerated subduction during the same time interval.Hydrous phenocrysts (e.g., biotite) are typically associated with low-silica deep-sea ashes, but not with terrestrial volcanic rocks of comparable silica contents, suggesting the important role of water in the evolution of siliceous magma. REE patterns and relative abundances of mafic phenocrysts demonstrate the importance of fractional crystallization in controlling the evolution of highly siliceous arc magmas. REE increase with increasing silica, but become less concentrated in ashes with SiO₂ > 64%. Eu anomalies increase throughout the SiO₂ range. Initial fractionation is dominated by clinopyroxene and plagioclase with amphibole strongly influencing fractionation above 64% SiO₂.     

Magma degassing and basaltic eruption styles: a case study of 2000 year BP Xitle volcano in central Mexico

To investigate the relationship between volatile abundances and eruption style, we have analyzed major element and volatile (H₂O, CO₂, S) concentrations in olivine-hosted melt inclusions in tephra from the 2000 yr BP eruption of Xitle volcano in the central Trans-Mexican Volcanic Belt. The Xitle eruption was dominantly effusive, with fluid lava flows accounting for 95% of the total dense rock erupted material (1.1 km³). However, in addition to the initial, Strombolian, cinder cone-building phase, there was a later explosive phase that interrupted effusive activity and deposited three widespread ash fall layers. Major element compositions of olivine-hosted melt inclusions from these ash layers range from 52 to 58 wt.% SiO₂, and olivine host compositions are Fo_84–86. Water concentrations in the melt inclusions are variable (0.2–1.3 wt.% H₂O), with an average of 0.45±0.3 (1σ) wt.% H₂O. Sulfur concentrations vary from below detection (50 ppm) to 1000 ppm but are mostly ≤200 ppm and show little correlation with H₂O. Only the two inclusions with the highest H₂O have detectable CO₂ (310–340 ppm), indicating inclusion entrapment at higher pressures (700–900 bars) than for the other inclusions (≤80 bars). The low and variable H₂O and S contents of melt inclusions combined with the absence of less soluble CO₂ indicates shallow-level degassing before olivine crystallization and melt inclusion formation. Olivine morphologies are consistent with the interpretation that most crystallization occurred rapidly during near-surface H₂O loss. During cinder cone eruptions, the switch from initial explosive activity to effusive eruption probably occurs when the ascent velocity of magma becomes slow enough to allow near-complete degassing of magma at shallow depths within the cone as a result of buoyantly rising gas bubbles. This allows degassed lavas to flow laterally and exit near the base of the cone while gas escapes through bubbly magma in the uppermost part of the conduit just below the crater. The major element compositions of melt inclusions at Xitle show that the short-lived phase of renewed explosive activity was triggered by a magma recharge event, which could have increased overpressure in the storage reservoir beneath Xitle, leading to increased ascent velocities and decreased time available for degassing during ascent.     

Magma mixing recorded in intermediate rocks associated with high-Mg andesites from the Setouchi volcanic belt, Japan: implications for Archean TTG formation

Calc-alkaline intermediate rocks are spatially and temporally associated with high-Mg andesites (HMAs, Mg#>60) in Middle Miocene Setouchi volcanic belt. The calc-alkaline rocks are characterized by higher Mg# (strongly calc-alkaline trend) than ordinary calc-alkaline rocks at equivalent silica contents. Phenocrysts in the intermediate rocks have petrographical features such as: (1) coexisting reversely and normally zoned orthopyroxene phenocrysts in single rock; (2) sieve type plagioclase in which cores are mantled by higher An%, melt inclusion-rich zone; and (3) reversely zoned amphibole phenocrysts with opacite cores. In addition, mingling textures and magmatic inclusions were observed in some rocks. These petrographic features and the mineral chemistry indicate that magma mixing was the most important process in producing the strongly calc-alkaline rocks. The core composition of normally zoned orthopyroxene phenocrysts and the mantle composition of reversely zoned orthopyroxene phenocrysts have relatively high Mg# (85–90) in maximum. Although basaltic and high-Mg andesitic magmas are candidate as possible mafic end-member magmas, basaltic magma is excluded in terms of phenocryst assemblage and bulk composition. HMA magmas are suitable mafic end-member magmas that precipitated high Mg# (90) orthopyroxene, whereas andesitic to dacitic magma are suitable felsic end-members. In contrast, it is difficult to produce the strongly calc-alkaline trend through fractional crystallization from a HMA magma, because it would require removal of plagioclase together with mafic minerals from the early stage of crystallization, whereas the precipitation of plagiolase is suppressed due to the high water content of HMA magmas. These results imply that Archean Mg#-rich TTGs (>45–55), which are an analog of the strongly calc-alkaline rocks in terms of chemistry and magma genesis, can be derived from magma mixing in which a HMA magma is the mafic end-member magma, rather than by fractional crystallization from a HMA magma.     

40Ar/39Ar Ages and stratigraphy of the Latera caldera,Italy

The Latera caldera is a well-exposed volcano where more than 8 km³ of mafic silica-undersaturated potassic lavas, scoria and felsic ignimbrites were emplaced between 380 and 150 ka. Isotopic ages obtained by ⁴⁰Ar/³⁹Ar analysis of single sanidine crystals indicate at least four periods of explosive eruptions from the caldera. The initial period of caldera eruptions began at 232 ka with emplacement of trachytic pumice fallout and ignimbrite. They were closely followed by eruption of evolved phonolitic magma. After roughly 25 ky, several phonolitic ignimbrites were deposited, and they were followed by phreatomagmatic eruptions that produced trachytic ignimbrites and several smaller ash-flow units at 191 ka. Compositionally zoned magma then erupted from the northern caldera rim to produce widespread phonolitic tuffs, tephriphonolitic spatter, and scoria-bearing ignimbrites. After 40 ky of mafic surge deposit and scoria cone development around the caldera rim, a compositionally zoned pumice sequence was emplaced around a vent immediately northwest of the Latera caldera. This activity marks the end of large-scale explosive eruptions from the Latera volcano at 156 ka.