Using stable water isotopes to identify spatio-temporal controls on groundwater recharge in two contrasting East African aquifer systems

Understanding the spatio-temporal variability in groundwater recharge is a prerequisite to sustainable management of aquifers. Spatial analysis of groundwater stable isotopes uncovered predominant controls on groundwater recharge in the Nairobi aquifer system (NAS) and the South Coast aquifer (SC), two exemplar East African aquifers relied upon by 7 million people. We analysed 368 samples for stable isotopes and basic physico-chemical parameters. The NAS groundwater isotopes are controlled by precipitation orographic effects and enriched recharge from impounded lakes/wetlands; the SC isotopes are correlated with water-table depth influencing evapotranspiration. Global Network of Isotopes in Precipitation (GNIP) data revealed groundwater recharge during months of heavy rains in the NAS, whilst the SC experiences spatio-temporally diffuse recharge. Inferred “isoscapes” show: in the NAS, (1) direct, rapid recharge favoured by faults, well-drained soils and ample rainfall in uplands, (2) delayed recharge from impounded lakes and wetlands in mid-lands, and (3) focused, event-based recharge in floodplains; and in the SC, diffuse recharge complicated by significant water-table evapotranspiration processes.     

Origin and type of rainfall for recharge of a karstic aquifer in the western Mediterranean: a case study from the Sierra de Gador–Campo de Dalias (southeast Spain)

Isotope signatures in precipitation from the Global Network for Isotopes in Precipitation around the Mediterranean basin and literature data are compared with isotopic data from a large karstic aquifer in southeast Spain to explain the origin and type of the precipitation events dominating recharge. Analysis of the deuterium excess d at the scale of the Mediterranean basin and at the regional scale allows us to understand the isotopic context of the study area: Campo de Dalias and the Sierra de Gador (Almería province). The origin of precipitation can be determined from its d value. The d value changes as a function of the initial evaporation condition. It depends on the relative humidity and temperature during the evaporation producing the water vapour of the clouds. The water vapour, which dominates the study area, is generated in two areas: the Atlantic Ocean (d = 10‰) and the western Mediterranean basin (d = 15‰). With increasing precipitation volume, the western Mediterranean character dominates. These heavier storms contribute mainly to recharge, as illustrated by the d value of 13·6‰ in deep groundwater of the Campo de Dalias. Weighted d values increase with the volume of precipitation, giving a significant relationship for the southern and eastern coasts of the Iberian Peninsula. This selectivity of d to monthly precipitation was used to estimate the return period of precipitation leading to aquifer recharge at 0·9–4·9 years. Moderate rainfall, which occurs more frequently, still represents ～60–90% of the total precipitation. One of the challenges to meet ever‐growing water demands is to increase recharge from moderate events yielding intermediate quantities per event, but forming the bulk of the annual precipitation. Copyright © 2006 John Wiley & Sons, Ltd.     

Isotopic composition (δ18O and δD) of precipitation and groundwater in a semi‐arid,mountainous area (Guadiana Menor basin,Southeast Spain)

We characterize the precipitation and groundwater in a mountainous (peaks slightly above 3000 m a.s.l.), semi‐arid river basin in SE Spain in terms of the isotopes ¹⁸O and ²H. This basin, with an extension of about 7000 km², is an ideal site for such a study because fronts from the Atlantic and the Mediterranean converge here. Much of the land is farmed and irrigated both by groundwater and runoff water collected in reservoirs. A total of approximately 100 water samples from precipitation and 300 from groundwater have been analysed. To sample precipitation we set up a network of 39 stations at different altitudes (800–1700 m a.s.l.), with which we were able to collect the rain and snowfall from 29 separate events between July 2005 and April 2007 and take monthly samples during the periods of maximum recharge of the aquifers. To characterize the groundwater we set up a control network of 43 points (23 springs and 20 wells) to sample every 3 months the main aquifers and both the thermal and non‐thermal groundwater. We also sampled two shallow‐water sites (a reservoir and a river). The isotope composition of the precipitation forms a local meteoric water line (LMWL) characterized by the equation δD = 7·72δ¹⁸O + 9·90, with mean values for δ¹⁸O and δD of − 10·28‰ and − 69·33‰, respectively, and 12·9‰ for the d‐excess value. To correlate the isotope composition of the rainfall water with groundwater we calculated the weighted local meteoric water line (WLMWL), characterized by the equation δD = 7·40δ¹⁸O + 7·24, which takes into account the quantity of water precipitated during each event. These values of (dδD/dδ¹⁸O)< 8 and d‐excess (δD–8δ¹⁸O)< 10 in each curve bear witness to the ‘amount effect’, an effect which is more manifest between May and September, when the ground temperature is higher. Other effects noted in the basin were those of altitude and the continental influence. The isotopic compositions of the groundwater are represented by the equation δD = 4·79δ¹⁸O − 18·64. The groundwater is richer in heavy isotopes than the rainfall, with mean values of − 8·48‰ for δ¹⁸O and − 59·27‰ for δD. The isotope enrichment processes detected include a higher rate of evaporation from detrital aquifers than from carbonate ones, the effects of recharging aquifers from irrigation return flow and/or from reservoirs' leakage and enrichment in δ¹⁸O from thermal water. Copyright © 2010 John Wiley & Sons, Ltd.     

Impact of septic tank systems on local groundwater quality and water supply in the Pearl River Delta,China: case study

Located at southern coast of China, the Pearl River Delta (PRD) is facing serious water problems in both quantity and quality after its rapid urbanization in the last decade. Most remarkably, the local groundwater, that was used to be the source of drinking water before the urbanization was polluted due to poor management of the septic tanks. In order to study the effects of suburban development on local groundwater flow and water quality in the PRD region, Fengcun of Guangzhou has been chosen as the study area. In Fengcun, drinking water was groundwater before the 1990s, but now piped reservoir water is used by each family because the groundwater has been polluted. This study clarifies the source and process of the groundwater pollution from septic tanks using isotopic and geochemical characteristics, especially nitrate (NO₃^?) concentrations. Water samples were collected from the wells and ponds in Fengcun in March and July 2005 and in July 2006. Based on the pe–pH diagram, NO₃^? and ammonium of groundwater are from the effect of human activities, rather than from nitrification and ammonification of N₂. NO₃^? pollution of groundwater is from point sources, and NO₃^? concentrations decrease from northeast to southwest. Groundwater is polluted rapidly by the leakage of septic tanks. NO₃^? concentrations of pollution sources were lower than 20 mg l^?1 in March 2005, but had increased to about 120 mg l^?1 in July 2006. This implies that groundwater protection should be strengthened in rural areas of the PRD. Copyright © 2007 John Wiley & Sons, Ltd.     

Quantitative reconstruction of Late Cenozoic landscapes: a case study in the Sierra de Atapuerca (Burgos,Spain)

We have developed a method to reconstruct palaeorelief by means of detailed geomorphological and geological studies, geostatistical tools, GIS and a DEM. This method has been applied to the Sierra de Atapuerca (NE Duero Basin, Burgos, Spain), allowing us to model a three‐dimensional reconstruction of the relief evolution from the Middle Miocene to the present. The modelling procedure is based on geostatistical recovery of the palaeosurfaces characteristic of each geomorphological evolution stage, using polynomial regressions, trend surfaces and kriging. The modelling of morphology trends has been useful in establishing new geological and geomorphological relationships in the geodynamic evolution of this basin, such as uplift quantification, correlation of erosion surfaces and sedimentary units, and the evolution of fluvial base levels. The palaeosurface reconstruction together with an analysis of the slope retreat have allowed us to reconstruct the palaeoreliefs that define the Late Cenozoic landscape evolution of this area, where the Lower and Middle Pleistocene archaeopalaeontological sites of the Sierra de Atapuerca are located. Copyright © 2007 John Wiley & Sons, Ltd.     

A study of soil water movement combining soil water potential with stable isotopes at two sites of shallow groundwater areas in the North China Plain

In the shallow groundwater areas of the North China Plain (NCP), precipitation infiltration and evapotranspiration in the vertical direction are the main processes of the water cycle, in which the unsaturated zone plays an important role in the transformation process between precipitation and groundwater. In this paper, two typical sites in Cangzhou (CZ) and Hengshui (HS) of Hebei province with shallow water tables were selected to analyse the relationship among precipitation, soil water and groundwater. At each site, precipitation, soil water at depths 10, 20, 30, 50, 70, 100, 150, 200, 300 cm, and groundwater were sampled to analyse the stable isotope compositions of hydrogen and oxygen. The soil water potentials at the corresponding depths were observed. Although the climates at the two sites are similar, there are some differences in the infiltration process, soil water movement and groundwater recharge sources. Evaporation occurred at the upper depths, which led to the decrease of soil potential and the enrichment of heavy isotopes. At the CZ site, precipitation infiltrated with piston mode, and an obvious mixture effect existed during the infiltration process. Preferential flow may exist in the soil above 100 cm depth. However, at the HS site soil water moved in piston mode, and groundwater was mainly recharged by precipitation. When precipitation recharged the groundwater it experienced a strong evaporation effect. The results of the soil water movement mechanism provides the transformation relationship among precipitation, soil water and groundwater in the middle and eastern NCP. Copyright © 2009 John Wiley & Sons, Ltd.     

The use of isotopes in evolving groundwater circulation models of regional continental aquifers: The case of the Guarani Aquifer System

The Guarani Aquifer System (GAS) has been studied since the 1970s, a time frame that coincides with the advent of isotopic techniques in Brazil. The GAS isotope data from many studies are organized in different phases: (a) the advent of isotope techniques, (b) consolidation and new applications, (c) isotope assessments and hydrochemistry evolution, and (d) a roadmap to a new conceptual model. The reasons behind the phases, their methodological approaches, and impacts on the regional flow conceptual models are examined. Starting with local δ²H and δ¹⁸O assessments of values for water fingerprinting and estimates of recharge palaeoclimate scenarios, studies evolved to more integrated approaches based on multiple tracers. Stable isotope application techniques were consolidated during the 1980s, when new dating approaches dealing with radiogenic and heavy isotopes were introduced. Through the execution of an international transboundary project, the GAS was studied and extensively sampled for isotopes. These results have triggered wider application of isotope techniques, reflecting also world research trends. Presently, hydrochemical evolution models along flow lines from recharge to discharge areas, across large‐scale tectonic features within the entire sedimentary basin, are being combined with residence time estimates at GAS outcrop areas and deep confined units. In a complex system, it is normal that many, and even contradictory hypotheses are proposed, but isotope techniques provide a unique chance to test them. Stable isotope assessments are still needed near recharge areas, and they can be combined with groundwater classical dating procedures, complemented by newer techniques (³H‐³He, CFCs, and SF₆)_. Recent noble gas sampling and world pioneer analytical efforts focused on the confined units in the GAS will certainly led to new findings on the overall GAS circulation. The objective of this article is to discuss how isotope information can contribute to the evolution of conceptual groundwater flow models for regional continental aquifers, such as the GAS.     

Evolution from a freshwater to saline lake: a climatic or hydrogeological change? The case of Gallocanta Lake (northeast Spain)

Sedimentological and hydrogeological studies are combined in order to investigate the environmental conditions of the lacustrine sedimentation during the Holocene in Gallocanta Lake in Spain. Six units have been identified in the sedimentary succession, based on sedimentological facies and mineralogy, and three depositional stages have been defined: (1) alluvial, (2) carbonate lake system, (3) ephemeral carbonate–saline lake system. The transition between stages 2 and 3 implies a reduction in water inflows to the lake. The δ¹³C isotopical analysis of dolomites points to decaying organic matter as a source of carbon for the dissolved inorganic carbon and evinces that the δ¹³C variations in the lake were probably controlled by organic processes. On the other hand, δ¹⁸O values could be controlled by modifications in the hydrological system and not necessarily by climatic changes. In this sense, from the hydrological study, three aquifers can be defined: Triassic, Jurassic–Cretaceous and Cenozoic aquifers. The lack of coincidence between the surface and subterranean watershed suggests that the transition between the second and third stages is controlled by a shift of the subterranean watershed. Copyright © 2006 John Wiley & Sons, Ltd.     

A study on the factors affecting the stable isotopic composition in precipitation of Tamil Nadu,India

Stable isotope measurements in precipitation help us to form the basic inference about the origin and the state of water in different environments. The precipitation samples collected during the South West Monsoon (SWM) during August 2007 from 37 different locations in the state help in deriving the first preliminary local meteoric water line (LMWL) for the Tamil Nadu State. The study reveals that there are three main sources of water vapours, namely South East Arabian Sea (SEAS), Indian Ocean (IO) and evaporation from local water bodies. There are wide variations in the altitude and amount of rainfall received in the state. It is also noted that there is a significant variation in the latitude and the distance from the coast. Hence, an attempt is made in this paper to study the factors controlling the composition of stable isotopes in precipitation with reference to amount of rainfall, latitude, altitude and the continental effect. The altitude and continental effect shows good correlation to the variations in stable isotope composition. Copyright © 2009 John Wiley & Sons, Ltd.     

Geochemical evidence for peat bog contribution to the streamflow generation process: case study of the Vltava River headwaters,Czech Republic

ABSTRACT

A geochemical approach using stable oxygen isotopes was used to understand streamflow generation processes in the highly peaty catchment of the Rokytka Brook in the headwaters of the Vltava River, Czech Republic. The contribution of water from peat bog areas to the total surface runoff was assessed using a hydrological time series, as well as geochemical, hydrochemical and isotope-hydrological approaches for unit hydrogram separation by means of anion deficiency. Using data from the hydrological year 2008, the role of an existing peat bog in the runoff formation dynamics of the Rokytka Brook catchment was determined, and the hydrological cycle was described and assessed using stable ¹⁸O/¹⁶O isotopes. The research findings strongly support the fact that peatland areas within the studied catchment do not significantly communicate hydraulically with surface streams, and their hydrological function in this region is insignificant.

Editor M. C. Acreman; Associate editor not assigned     

Assessment of environmental flows under limited data availability: case study of the Acheloos River,Greece

Abstract

The lower course of the Acheloos River is an important hydrosystem in Greece, heavily modified by a cascade of four hydropower dams upstream, which is now being extended by two more dams in the upper course. The design of the dams and hydropower facilities that are in operation has not considered any environmental criteria. However, in the last 50 years, numerous methodologies have been proposed to assess the negative impacts of such projects to both the abiotic and biotic environment, and to provide decision support towards establishing appropriate constraints on their operation, typically in terms of minimum flow requirements. In this study, seeking a more environmentally-friendly operation of the hydrosystem, we investigate the outflow policy from the most downstream dam, examining alternative environmental flow approaches. Accounting for data limitations, we recommend the basic flow method, which is parsimonious and suitable for Mediterranean rivers, whose flows exhibit strong variability across seasons. We also show that the wetted perimeter–discharge method, which is an elementary hydraulic approach, provides consistent results, even without using any flow data. Finally, we examine the adaptation of the proposed flow policy (including artificial flooding) to the real-time hydropower generation schedule, and the management of the resulting conflicts.

Editor Z.W. Kundzewicz; Guest editor M. Acreman

Citation Efstratiadis, A., Tegos, A., Varveris, A., and Koutsoyiannis, D., 2014. Assessment of environmental flows under limited data availability: case study of the Acheloos River, Greece. Hydrological Sciences Journal, 59 (3–4), 731–750.     

A long‐term study of stable isotopes as tracers of processes governing water flow and quality in a lowland river basin: the upper Thames,UK

A long‐term study of O, H and C stable isotopes has been undertaken on river waters across the 7000‐km² upper Thames lowland river basin in the southern UK. During the period, flow conditions ranged from drought to flood. A 10‐year monthly record (2003–2012) of the main River Thames showed a maximum variation of 3‰ (δ¹⁸O) and 20‰ (δ²H), although interannual average values varied little around a mean of –6.5‰ (δ¹⁸O) and –44‰ (δ²H). A δ²H/δ¹⁸O slope of 5.3 suggested a degree of evaporative enrichment, consistent with derivation from local rainfall with a weighted mean of –7.2‰ (δ¹⁸O) and –48‰ (δ²H) for the period. A tendency towards isotopic depletion of the river with increasing flow rate was noted, but at very high flows (>100 m³/s), a reversion to the mean was interpreted as the displacement of bank storage by rising groundwater levels (corroborated by measurements of specific electrical conductivity). A shorter quarterly study (October 2011–April 2013) of isotope variations in 15 tributaries with varying geology revealed different responses to evaporation, with a well‐correlated inverse relationship between Δ¹⁸O and baseflow index for most of the rivers. A comparison with aquifer waters in the basin showed that even at low flow, rivers rarely consist solely of isotopically unmodified groundwater. Long‐term monitoring (2003–2007) of carbon stable isotopes in dissolved inorganic carbon (DIC) in the Thames revealed a complex interplay between respiration, photosynthesis and evasion, but with a mean interannual δ¹³C‐DIC value of –14.8 ± 0.5‰, exchange with atmospheric carbon could be ruled out. Quarterly monitoring of the tributaries (October 2011–April 2013) indicated that in addition to the aforementioned factors, river flow variations and catchment characteristics were likely to affect δ¹³C‐DIC. Comparison with basin groundwaters of different alkalinity and δ¹³C‐DIC values showed that the origin of river baseflow is usually obscured. The findings show that long‐term monitoring of environmental tracers can help to improve the understanding of how lowland river catchments function. Copyright © NERC 2015. Hydrological Processes © 2015 John Wiley & Sons, Ltd.     

Fluids in early stage hydrothermal alteration of high-sulfidation epithermal systems: A view from the Vulcano active hydrothermal system (Aeolian Island,Italy)

High-sulfidation (HS) epithermal systems have elements in common with passively degassing volcanoes associated with high T, acid fumarole fields or acid crater lakes. They are considered to form in two stages, the first of which involves advanced argillic alteration resulting from intense, strongly acidic fluid–rock interaction. The La Fossa hydrothermal system (Vulcano Island) represents a classic example of such an active HS system and can be considered as a modern analogue of this early stage of alteration, resulting in a core of intense silicic (90–95% pure SiO₂) alteration surrounded by alunitic alteration zones.     

Rapid recharge of fresh water to the halite‐hosted brine aquifer of Salar de Atacama,Chile

We document, analyse, and interpret direct and rapid infiltration of precipitation to the southern margin of the Salar de Atacama halite‐hosted brine aquifer during two intense precipitation events in 2012–2013. We present physical, geochemical, and stable and radioactive isotope data to detail this influx of water. The two events differ distinctly in the mechanisms of recharge. The 2012 event did not produce direct precipitation onto the salar surface, while the 2013 event did. Both events are recorded by abrupt changes in head in observation wells along the halite aquifer margin. Spatially distributed water levels rose by over 30 cm during the larger 2013 event consistent with remotely sensed observations of surface water extent. The lithium concentration and stable isotopic composition of water indicate dilution of brine and dissolution of salt with fresh water. Tritium measurements of precipitation, surface water, and groundwater all indicate modern influx of water to the halite aquifer along the southern margin. We extend these observations by examining the response of the halite aquifer as a whole to precipitation events during the period of 2000–2010. This study suggests that local recharge to the aquifer during sporadic precipitation onto the halite nucleus is an important component of the modern water budget in this hyper‐arid environment. The rapid dissolution and salinization along the southern margin of the salar halite nucleus are aided by such precipitation events contributing a modern fresh water component to the water budget of the economically valuable lithium‐rich brine. Copyright © 2016 John Wiley & Sons, Ltd.     

Application of multivariate statistical procedures to the hydrochemical study of a coastal aquifer: an example from Crete,Greece

A variety of multivariate statistical procedures were applied to three separate sets of quantitative analytical data from a coastal aquifer located in Malia, Crete (Greece), in order to identify the major hydrochemical processes affecting the groundwater quality and to investigate the evolution of groundwater composition in three different sampling periods. Two of them were carried out on October 2001 and September 2002 at the end of the dry season and the third on April 2002 at the end of the wet period. Two factors were found that explained major hydrochemical processes in the aquifer. These factors reveal the existence of an intensive intrusion of seawater and mechanisms of nitrate contamination of groundwater. Bivariate plots of the scores of the two main factors showed that the seawater intrusion and nitrate pollution processes are maintained through three surveys and that the process of nitrate pollution increases from the first to the second dry survey. Q‐mode factor analysis and discriminant analysis of the three sampling periods clearly showed a seasonal variation of the whole chemistry of groundwater samples. This seasonal variation can be attributed to the freshwater recharge and seawater intrusion that affect the groundwater quality of the Malia aquifer. The results of trend surface analysis are in agreement with those of factor analysis. Moreover, the fourth‐order trend surfaces of EC, Cl^? and NO₃^? showed that the salinization process is more intensive during the first dry period and the spatial variation of NO₃^? maxima plumes are strongly affected by the flow regime of the Malia aquifer. Copyright © 2007 John Wiley & Sons, Ltd.     

Enhancing hydrologic modelling through the representation of traditional rainwater harvesting systems: A case study of water tanks in South India

Water tanks as traditional rainwater harvesting systems for agriculture are widely distributed in South India. They have a strong impact on hydrological processes, affecting streamflow in rivers as well as evapotranspiration. This study aims at an accurate representation of water harvesting systems in a hydrologic model to improve model performance and assessment of the catchment water balance. To this end, spatio-temporal variations of water bodies between the years 2016 and 2018 and the months of January and May 2017 were derived from Sentinel-2 satellite data to parameterize the water tanks (reservoir) parameters in the Soil and Water Assessment Tool (SWAT+) model of the Adyar basin, Chennai, India. Approximately 16% of the basin is covered by water tanks. The initial model performance was evaluated for two model setups, with and without water tanks. The best model run was selected with a multi-metric approach comparing observed and modelled monthly streamflow for 5000 model runs. The final model evaluation was carried out by comparing estimated water body areas by the model and remote sensing observations for January to May 2017. The results showed that representing water tanks in the hydrologic model led to an improvement in the representation of the seasonal variations of streamflow for the whole simulation period (2004–2018). The model performance was classified as good and very good for the calibration (2004–2011) and validation (2012–2018) periods as NSE varies between 0.67 and 0.85, KGE varies between 0.65 and 0.72, PBIAS varies between −24.1 and −23.6, and RSR varies between 0.57 and 0.39. The best fit was shown for the high and middle flow segments of the hydrograph where the coefficient of determination (R²) ranges from 0.81 to 0.97 and 0.75 to 0.81, respectively. The monthly variation of water body areas in 2017 estimated by the hydrologic model was consistent with changes observed in remote sensing surveys. In summary, the water tank parametrization using remote sensing techniques enhanced the hydrologic model's efficiency and applicability for future studies.     

Lithium and lithium isotope profiles through the upper oceanic crust: a study of seawater-basalt exchange at ODP Sites 504B and 896A

Ocean Drilling Program (ODP) Hole 504B near the Costa Rica Rift is the deepest hole drilled in the ocean crust, penetrating a volcanic section, a transition zone and a sheeted dike complex. The distribution of Li and its isotopes through this 1.8-km section of oceanic crust reflects the varying conditions of seawater alteration with depth. The upper volcanic rocks, altered at low temperatures, are enriched in Li (5.6-27.3 ppm) and have heavier isotopic compositions (δ⁷Li=6.6-20.8‰) relative to fresh mid-ocean ridge basalt (MORB) due to uptake of seawater Li into alteration clays. The Li content and isotopic compositions of the deeper volcanic rocks are similar to MORB, reflecting restricted seawater circulation in this section. The transition zone is a region of mixing of seawater with upwelling hydrothermal fluids and sulfide mineralization. Li enrichment in this zone is accompanied by relatively light isotopic compositions (−0.8-2.1‰) which signify influence of basalt-derived Li during mineralization and alteration. Li decreases with depth to 0.6 ppm in the sheeted dike complex as a result of increasing hydrothermal extraction in the high-temperature reaction zone. Rocks in the dike complex have variable isotopic values that range from −1.7 to 7.9‰, depending on the extent of hydrothermal recrystallization and off-axis low-temperature alteration. Hydrothermally altered rocks are isotopically light because ⁶Li is preferentially retained in greenschist and amphibolite facies minerals. The δ⁷Li values of the highly altered rocks of the dike complex are complementary to those of high-temperature mid-ocean ridge vent fluids and compatible to equilibrium control by the alteration mineral assemblage. The inventory of Li in basement rocks permits a reevaluation of the role of oceanic crust in the budget of Li in the ocean. On balance, the upper 1.8 km of oceanic crusts remains a sink for oceanic Li. The observations at 504B and an estimated flux from the underlying 0.5 km of gabbro suggest that the global hydrothermal flux is at most 8×10⁹ mol/yr, compatible with geophysical thermal models. This work defines the distribution of Li and its isotopes in the upper ocean crust and provides a basis to interpret the contribution of subducted lithosphere to arc magmas and cycling of crustal material in the deep mantle.     

Isotopes and geochemistry in a managed aquifer recharge scheme: a case study of fresh water injection at the Damascus University Campus,Syria

A combination of stable isotopes (¹⁸O and ²H) and hydrochemistry has been applied to investigate storage processes in relation to aquifer storage and recovery (ASR) of the shallow alluvial Quaternary aquifer in Damascus basin. The stored water, entirely taken from the Figeh springs during flood periods, was injected in a single well having a brackish groundwater. Water samples were collected from four observation wells drilled in the Damascus University Campus (DUC) site during a 3‐year period (2006–2008). The injectant water, which deviates in its chemical and isotopic signatures from that of the ambient groundwater, shows that the stored water plume remains within close proximity to the injection well (IW) (<≈ 100 m). Thus, only two wells (W13 and W14) located at a distance less than 80 m from the injection point were affected by this injection. The observation wells located at longer distances from the IW (≈145 m and ≈ 600 m for wells W15 and WHz, respectively) were completely unaffected by the injection. Although most of the chemical and isotopic parameters usefully reflected the mixing process that occurs between the injectant water and ambient groundwater, the stable isotope (¹⁸O) and chloride (Cl⁻) were the most sensitive parameters that quickly reflect this signature. Using a simple mass balance, the calculated proportion of injectant water reaching the well W13 was in the range of 50–90%. This proportion was even lower (30–55%) in the case of well W14. Although the drought event prevailing during this study did not much help to inject further amounts of water, higher than the injected volume (0·2416 M m³) and also not favourable to better evaluate the fate and subsurface hydrological processes, these findings offer encouragement to continue the ASR activities, as an alternative way for better management of water resources in this basin facing intensive problems. Copyright © 2010 John Wiley & Sons, Ltd.     

Longitudinal distributions of two formation pathways of biogenic gases in continental deposits: A case study from Sebei 1 gas field in the Qaidam Basin, western China

The distribution of two formation pathways of biogenic methane, acetate fermentation and reduction of CO2, has been extensively studied. In general, CO2 reduction is the dominate pathway in marine envi- ronment where acetate is relatively depleted because of SRB consuming. While in terrestrial freshwater or brackish environment, acetate fermentation is initially significant, but decreases with increasing buried depth. In this paper, character of biogenic gases is profiled in the XS3-4 well of the Sebei 1 gas field in the Sanhu depression, Qaidam Basin. It indicates that those two pathways do not change strictly with increasing buried depth. CO2 reduction is important near the surface (between 50 m and 160 m), and at the mesozone (between 400 and 1650 m). While acetate fermentation is the primary pathway at two zones, from 160 to 400 m and from 1650 to 1700 m. δ 13C of methane generated in those two acetate fermentation zones varies greatly, owing to different sediment circumstances. At the sec- ond zone (160-400 m), δ 13C1 ranges from ?65‰ to ?30‰ (PDB), because the main deposit is mudstone and makes the circumstance confined. At the fourth zone of the well bottom (1650-1700 m), δ 13C1 is lighter than ?65‰ (PDB). Because the deposit is mainly composed of siltstone, it well connects with outer fertile groundwater and abundant nutrition has supplied into this open system. The high con- centration of acetate is a forceful proof. δ 13C of methane would not turn heavier during fermentation, owing to enough nutrition supply. In spite of multi-occurrence of acetate fermentation, the commercial gas accumulation is dominated by methane of CO2-reduction pathway. A certain content of alkene gases in the biogenic gases suggests that methanogensis is still active at present.