Evaluation of the method of collecting suspended sediment from large rivers by discharge-weighted pumping and separation by continuous-flow centrifugation

A method for collecting suspended sediment samples has been developed that pumps a discharge-weighted volume of water from fixed depths at four to 40 locations across a river and separates the suspended sediment in the sample using a continuous-flow centrifuge. The efficacy of the method is evaluated by comparing the particle size distributions of sediment collected by the discharge-weighted pumping method with the particle size distributions of sediment collected by depth integration and separated by gravitational settling. The pumping method was found to undersample the suspended sand sized particles (> 63 μm) but to collect a representative sample of the suspended silt and clay sized particles (< 63 μm). The centrifuge separated the silt and clay sized particles (< 63 μm) into three fractions. Based on the average results of processing 17 samples from the Mississippi River and several of its large tributaries in 1990, about 10% of the silt and clay sized material was trapped in a centrifuge bowl-bottom sealing unit containing the nozzle and consisted of mostly medium and coarse silt from 16 to 63 μm. About 74% was retained on a Teflon liner in the centrifuge bowl and consisted of sizes from 0–1 to 63 μm. About 9% was discharged from the centrifuge in the effluent and was finer than 0–1 μm. About 7% was lost during the processes of removing the wet sediment fractions from the centrifuge, drying and weighing. The success of the discharge-weighted pumping method depends on how homogeneously the silt and clay sized particles (< 63 μm) are distributed in the vertical direction in the river. The degree of homogeneity depends on the composition and degree of aggregation of the suspended sediment particles.     

TEMPORAL AND SPATIAL DYNAMICS OF DIFFERENT PARTICLE SIZE OF SUSPENDED SEDIMENT IN THE LIU RIVER CATCHMENTS,CHINA

1 INTRODUCTION The particle size of sediment eroded from basins can provide basic information about erosion processes (Meyer et al., 1980), which can be divided into sheet wash sediment processes on hill slopes and fluvial sediment processes in rivers. In…     

Composite suspended sediment particles in river systems: their incidence,dynamics and physical characteristics

Most of the existing data on the effective particle size characteristics of fluvial suspended sediment derive from instantaneous sampling methods that may not be representative of the overall suspended sediment loads. This presents difficulties when there is a need to incorporate effective particle size data into numerical models of floodplain sedimentation and sediment‐associated contaminant transfer. We have used a field‐based water elutriation apparatus (WEA) to assemble a large (36 flood) database on the time‐integrated nature of the effective and absolute particle size characteristics of suspended sediment in four subcatchments of the River Exe basin of southwest England. These catchments encompass a wide range of terrains and fluvial environments that are broadly representative of much of the UK and temperate, low relief northwest Europe. The WEA provides important data on the physical characteristics of composite particles that are not attainable using other methods. This dataset has allowed, for the first time, detailed interbasin comparisons of the time‐integrated particle size characteristics of suspended sediment and reliable estimates of the contribution of five effective size classes to the mean annual suspended sediment load of the study catchments. The suspended sediment load of each river is dominated by composite rather than primary particles, with, for example, almost 60% (by mass) of the sediment load of the River Exe at Thorverton transported as composite particles > 16 µm in size. All the effective size classes contain significant clay components. A key outcome of this study is the recognition that each catchment has a distinctive time‐integrated effective particle size signature. In addition, the time‐integrated effective particle size characteristics of the suspended loads in each of the catchments display much greater spatial variability than the equivalent absolute particle size distributions. This indicates that the processes producing composite particles vary significantly between these catchments, and this has important implications for our understanding of the dynamics of suspended sediment properties. Copyright © 2007 John Wiley & Sons, Ltd.     

Effects of the undecomposed layer and semi-decomposed layer of Quercus variabilis litter on the soil erosion process and the eroded sediment particle size distribution

Simulated rainfall experiments were performed on bare, undecomposed litter layer and semi-decomposed litter layer slopes with litter biomasses of 0, 50, 100 and 150 g m⁻², respectively, to evaluate the effect of the undecomposed layer and semi-decomposed layer of Quercus variabilis litter on the soil erosion process and the particle size distribution of eroded sediment. The undecomposed layer and semi-decomposed layer of litter reduced the runoff rate by 10.91–27.04% and 12.91–36.05%, respectively, and the erosion rate by 13.35–40.98% and 17.16–59.46%, respectively. The percentage of smaller particles (clay and fine silt particles) decreased and the percentage of larger particles (coarse silt and sand particles) increased with an increased rainfall duration on all treated slopes, while the extent of the eroded sediment particle content varied among the treated slopes with the rainfall duration, with bare slopes exhibiting the largest variability, followed by undecomposed litter layer slopes and finally semi-decomposed litter layer slopes. The clay and sand particles were transported as aggregates, and fine silt and coarse silt particles were transported as primary particles. Compared with the original soil, sediment eroded from all treated slopes was mainly enriched in smaller particles. Furthermore, the loss of the smaller particles from the undecomposed litter layer slopes was lower than that from the semi-decomposed litter layer slopes, indicating that the undecomposed litter layer alleviated soil coarsening to some extent. The findings from this study improve our understanding of how litter regulates slope erosion and provide a reference for effectively controlling soil erosion.     

Response of nephelometric turbidity to hydrodynamic particle size of fine suspended sediment

Turbidity is used as a surrogate for suspended sediment concentration (SSC), and as a regulatory tool for indicating land use disturbance and environmental protection. Turbidity relates linearly to suspended material, however, can show non-linear responses to particulate organic matter (POM), concomitant with changes in particle size distribution (PSD). In the paper the influence of ultra-fine particulate matter (UFPM) on specific turbidity and its association with POM in suspended sediment are shown for alpine rivers in the Southern Alps of New Zealand. The approach was two-fold: a field-based investigation of the relations between SSC, POM, and turbidity sampled during event flow; and experimental work on hydrodynamic particle size effects on SSC, POM, PSD, and turbidity. Specific turbidity changes over event flow and are sensitive to increasing proportional amounts of sand, UFPM, and POM in suspension. Furthermore, the UFPM is the size fraction (<6 μm) where POM increases. The implications of the current study are that the slopes of turbidity-SSC relations are undesirable in locations that may be dominated by cyclic release of POM or distinct pulses of fine-grained material. At locations where the turbidity-SSC slopes approximate 2, the POM proportion is usually <10% of the total suspended load. However, when turbidity-SSC slopes are <1 this is likely caused by high amounts of side-scatter from UFPM concomitant with higher proportions of POM. Thus, the use of turbidity as a proxy for determining SSC may have serious consequences for the measurement of representative suspended sediment data, particularly in locations where POM may be a significant contributor to overall suspended load.     

Fine sediment delivery and transfer in lowland catchments: modelling suspended sediment concentrations in response to hydrological forcing

Fine sediment delivery to and storage in stream channel reaches can disrupt aquatic habitats, impact river hydromorphology, and transfer adsorbed nutrients and pollutants from catchment slopes to the fluvial system. This paper presents a modelling tool for simulating the time‐dependent response of the fine sediment system in catchments, using an integrated approach that incorporates both land phase and in‐stream processes of sediment generation, storage and transfer. The performance of the model is demonstrated by applying it to simulate in‐stream suspended sediment concentrations in two lowland catchments in southern England, the Enborne and the Lambourn, which exhibit contrasting hydrological and sediment responses due to differences in substrate permeability. The sediment model performs well in the Enborne catchment, where direct runoff events are frequent and peak suspended sediment concentrations can exceed 600 mg l^?1. The general trends in the in‐stream concentrations in the Lambourn catchment are also reproduced by the model, although the observed concentrations are low (rarely exceeding 50 mg l^?1) and the background variability in the concentrations is not fully characterized by the model. Direct runoff events are rare in this highly permeable catchment, resulting in a weak coupling between the sediment delivery system and the catchment hydrology. The generic performance of the model is also assessed using a generalized sensitivity analysis based on the parameter bounds identified in the catchment applications. Results indicate that the hydrological parameters contributing to the sediment response include those controlling (1) the partitioning of runoff between surface and soil zone flows and (2) the fractional loss of direct runoff volume prior to channel delivery. The principal sediment processes controlling model behaviour in the simulations are the transport capacity of direct runoff and the in‐stream generation, storage and release of the fine sediment fraction. The in‐stream processes appear to be important in maintaining the suspended sediment concentrations during low flows in the River Enborne and throughout much of the year in the River Lambourn. Copyright © 2007 John Wiley & Sons, Ltd.     

Composite suspended sediment particles and flocculation in glacial meltwaters: preliminary evidence from Alpine and Himalayan basins

Research over the last decade has shown that the suspended sediment loads of many rivers are dominated by composite particles. These particles are also known as aggregates or flocs, and are commonly made up of constituent mineral particles, which evidence a wide range of grain sizes, and organic matter. The resulting in situ or effective particle size characteristics of fluvial suspended sediment exert a major control on all processes of entrainment, transport and deposition. The significance of composite suspended sediment particles in glacial meltwater streams has, however, not been established. Existing data on the particle size characteristics of suspended sediment in glacial meltwaters relate to the dispersed mineral fraction (absolute particle size), which, for certain size fractions, may bear little relationship to the effective or in situ distribution. Existing understanding of composite particle formation within freshwater environments would suggest that in‐stream flocculation processes do not take place in glacial meltwater systems because of the absence of organic binding agents. However, we report preliminary scanning electron microscopy data for one Alpine and two Himalayan glaciers that show composite particles are present in the suspended sediment load of the meltwater system. The genesis and structure of these composite particles and their constituent grain size characteristics are discussed. We present evidence for the existence of both aggregates, or composite particles whose features are largely inherited from source materials, and flocs, which represent composite particles produced by in‐stream flocculation processes. In the absence of organic materials, the latter may result solely from electrochemical flocculation in the meltwater sediment system. This type of floc formation has not been reported previously in the freshwater fluvial environment. Further work is needed to test the wider significance of these data and to investigate the effective particle size characteristics of suspended sediment associated with high concentration outburst events. Such events make a major contribution to suspended sediment fluxes in meltwater streams and may provide conditions that are conducive to composite particle formation by flocculation. Copyright © 2002 John Wiley & Sons, Ltd.     

The particle size characteristics of fine‐grained channel deposits in the River Exe Basin,Devon, UK

Deposition and storage of fine‐grained (<62·5 μm) sediment in the hyporheic zone of gravel bed rivers frequently represents an important cause of aquatic habitat degradation. The particle size characteristics of such fine‐grained bed sediment (FGBS) exert an important control on its hydrodynamic properties and environmental impact. Traditionally, particle size analysis of FGBS in gravel bed rivers has focused on the absolute size distribution of the chemically dispersed mineral fraction. However, recent work has indicated that in common with fluvial suspended sediment, significant differences may exist between the absolute and the in situ, or effective, particle size composition of FGBS, as a result of the existence of aggregates, or composite particles. In the investigation reported in this paper, sealable bed traps that could be remotely opened to sample sediment deposited during specific storm runoff events and a laser back‐scatter probe were used to quantify the temporal and spatial variability of both the absolute and effective particle size composition of FGBS, and the associated suspended sediment from four gravel bed rivers in the Exe Basin, Devon, UK. The absolute particle size distributions of both the FGBS and suspended sediment evidenced c. >95%<62·5 μm sized primary particles and displayed a seasonal winter–summer fining, while the opposite trend was displayed by the effective particle size distribution of the FGBS and suspended sediment. The effective particle size distributions of both were typically highly aggregated, comprising up to 68%>62·5 μm sized particles. Spatial variation in the effective particle size and aggregation parameters was of secondary importance relative to temporal variation. The effective particle size distribution of the FGBS was consistently coarser and more aggregated than the associated suspended sediment and there was evidence of aggregate break‐up in samples of resuspended bed sediment. The implications of these findings for sediment transport modelling are considered. Copyright © 1999 John Wiley & Sons, Ltd.     

Flume‐ and field‐based evaluation of a time‐integrated suspended sediment sampler for the analysis of sediment properties

Suspended sediment has been identified as a vector for nutrient and contaminant transport in the fluvial environment. A time‐integrated sampler (the Phillips sampler), which emerged over a decade ago as a cost‐effective tool for in situ suspended sediment collection, is increasingly being used to collect samples for the analysis of sediment properties such as particle size composition, and nutrient and contaminant concentrations. This study evaluates the sampler under both flume and field conditions for efficiency in the mass and grain size of the suspended sediment collected. The sampler was tested in a flume using both kaolinite and sediment samples (sieved to < 180 µm) collected from the Quesnel River, British Columbia, Canada. In the kaolinite trails, the sampler preferentially collected coarser grain sizes compared to the original sediment, probably due to finer sediment remaining in suspension and therefore passing through the sampler, and also possibly due to flocculation of the kaolinite upon introduction to the flume. Conversely, the sampler collected river sediment that was finer than the original sediment, probably due to some settling of coarser sediment observed at the bottom of the flume. Once allowance was made for these operational issues associated with the flume, maximum sediment mass efficiency for kaolinite and river sediment was 43% and 87%, respectively. Sediment collected by the time‐integrated sampler during field deployment and adjacent channel bed sediment were also compared. The sampler collected sediment with a representative grain size distribution. However, there were differences in the geochemical (arsenic and selenium) concentrations of channel bed sediment and sediment collected by the Phillips sampler which may be a function of differences in the behavior of geochemical elements associated with the two types of sediment. This work suggests that further research is needed to evaluate the role of the Phillips sampler in collecting sediment for contaminant and nutrient analysis. Copyright © 2014 John Wiley & Sons, Ltd.     

Particle size characteristics of suspended sediment in Southern Ontario rivers tributary to the great lakes

In spite of the important relationship between sediment particle size and the transport/deposition of adsorbed pollutants in fluvial systems, little information regarding the size characteristics of suspended sediment transported by southern Ontario Great Lakes tributaries is currently available. This paper examines long-term sediment and hydrometric data collected by the Water Resources Branch of Environment Canada in order to provide information on (1) typical particle size distributions of suspended sediment, (2) relationships between source material and particle size characteristics of suspended sediment, and (3) temporal variation in the particle size characteristics of suspended sediment from six southern Ontario rivers. Results illustrate the complex behaviour and variability of sediment particle size transport in these rivers and demonstrate the need for a better understanding of seasonal effects on sediment availability and conveyance processes in fluvial systems.     

Contribution of intercepted subsurface flow to road runoff and sediment transport in a logging‐disturbed tropical catchment

Hydrological and sediment fluxes were monitored for a 1 yr period in a tropical headwater catchment where a 3 yr old logging road caused substantial Hortonian overland flow (HOF) and intercepted subsurface flow (ISSF). On a 51·5 m road section, ISSF became an increasingly important component of total road runoff, up to more than 90% for large storms. The proportion of ISSF contributed by road cuts along more or less planar slopes compared with ISSF from a zero‐order basin (convergent slopes) truncated by the road declined with increasing rainfall. During the monitored storms that generated ISSF along the road, on average, 28% of sediment export and 79% of runoff from the road section were directly attributable to ISSF. Estimates of total sediment export from the road surface (170 t ha^?1 yr^?1) and suspended sediment export from the logging‐disturbed catchment (4 t ha^?1 yr^?1) were exceptionally high despite 3 yr of recovery. ISSF caused not only additional road‐generated sediment export, but also exacerbated HOF‐driven erosion by creating a poor foundation for vegetation recovery on the road surface. Copyright © 2007 John Wiley & Sons, Ltd.     

Correction factors for estimating suspended sediment export from loess catchments

This study focuses on problems related to estimating the exact exported suspended sediment quantity and quality from flow‐proportional samples taken at a fixed height at the outlet of a small, agricultural catchment in central Belgium. First, a correction factor is introduced to estimate the real suspended sediment concentration. This factor depends on the stream depth and the grain size distribution of the sediment and is necessary because of the presence of a concentration gradient in the stream. Secondly, water depth is corrected for the sediment volume, and thirdly, the grain size distribution of the exported sediment is corrected. The application of these correction factors leads to a reduction of the estimated total sediment export by 18 per cent (from 4810 Mg over a period of three years to 3930 Mg). Furthermore, the importance of small grain size fractions increases, leading to higher enrichment ratios for the clay fraction and lower ratios for the sand fraction. Suspended sediment export is thus more selective than was previously thought. Due to the overestimation of the sediment export, total phosphorus losses from the catchment are also overestimated by 17 per cent. This paper therefore emphasizes that point sampling of suspended sediment is biased and that a method should be incorporated to correct the sediment export in terms of quantity and quality. Copyright © 2001 John Wiley & Sons, Ltd.     

Importance of soil surface characteristics on water erosion in a small grazed Sahelian catchment

This study concerns the problem of water erosion in the Sahel. Surface water and sediment yields (suspended matter and bedload) were monitored for 3 years (1998–2000) at the outlet of a small grazed catchment (1·4 ha) in the northern part of Burkina Faso. The catchment consists of about 64% sandy deposits (DRY soil surface type), which support most of the vegetation, and about 34% of crusted bare soils (ERO soil surface type). The annual solid‐matter export is more than 90% suspended sediment, varying between 4·0 and 8·4 t ha^?1. The bedload represents less than 10% of soil losses. In a single flood event (10 year return period), the sediment yield can reach 4·2 t ha^?1. During the period studied, a small proportion (20 to 32%) of the floods was thus responsible for a large proportion (80%) of the solid transport. Seasonal variation of the suspended‐matter content was also observed: high mean values (9 g l^?1) in June, decreasing in July and stabilizing in August (between 2 and 4 g l^?1). This behaviour may be a consequence of a reorganization of the soil surfaces that have been destroyed by trampling animals during the previous long dry season, vegetation growth (increase in the protecting effect of the herbaceous cover) and, to a lesser extent, particle‐supply limitation (exhaustion of dust deposits during July). The particle‐size distribution in the suspended matter collected at the catchment outlet is 60% made up of clay: fraction ≤2 µ m. The contribution of this clay is maximum when the water rises and its kaolinite/quartz ratio is then close to that of the ERO‐type surfaces. This indicates that these surfaces are the main source of clay within the catchment. Copyright © 2003 John Wiley & Sons, Ltd.     

Spatial contributions of diffuse inputs and within-channel processes to the form of stream water phosphorus over storm events

Concentrations of suspended particulate matter (SPM), NO₃-N and P fractions: PO₄-P, dissolved organic P (DOP), particulate P (PP) and bioavailable exchangeable P were examined over 5 storm events in two nested agricultural catchments in NE Scotland: a (51 km²) catchment and its headwater (4 km²). NO₃-N showed anticlockwise hysteresis for all storms in both catchments. In contrast, the headwater showed strong clockwise hysteresis of SPM, dissolved and particulate P concentrations, but which weakened through summer to spring. Less pronounced hysteresis of P forms in the larger catchment was attributed to a combination of factors: a less energetic system, nutrient leaching from the floodplain, a point source of a small sewage treatment works and the occurrence of coarser soil and sediment parent materials with less P adsorption and transport capacity. The headwater exhibited a strong ‘first flush’ effect of sediment and dissolved P, particularly following dry conditions, received a significant transfer of readily-solubilized organic P from the surrounding soils in late summer and after manure applications in winter, and was the likely cause of large sediment associated P signals observed in the 51 km² catchment. Our results suggest that steeper gradient headwaters should be targeted for riparian improvements to mitigate soil erosion from headwater fields. The efficiency of riparian erosion controls is also dependant on the size of the store of fine sediment material within the stream channel and this may be large.     

The Igarapé Weir decelerated transport of contaminated sediment in the Paraopeba River after the failure of the B1 tailings dam (Brumadinho)

The B1 dam of Córrego do Feijão Mine, owned by Vale, S.A. mining company and located on the Ferro-Carvão stream, collapsed and injected 2.8 Mm³ of clayey, silty, and sandy iron- and manganese-rich tailings into the Paraopeba River (Minas Gerais state, Brazil). The accident occurred on 25 January 2019 and the tailings have been co-transported with coarser natural sediment since then, being partly trapped in the Igarapé Weir reservoir located on the Paraopeba River nearly 45 km downstream the injection point. The general purpose of the current study was to model suspended sediment transport in the vicinity of the Igarapé Weir aiming to assess the concomitant barrier effect imposed by this structure. Specifically, the spatial distributions of suspended clay, silt, and very fine-grained sand fractions (CSS) of sediment were mapped around the Igarapé Weir under low-flow (16 m³/s) and high-flow (5 to 10,000 years return period stream discharge; 699–2,699 m³/s) regimes, using RiverFlow2D as the modelling tool. The concentrations of the various grain materials in the upstream and downstream sectors were quantified linking the barrier effect to concentration reductions in the direction of stream flow. It was also a study goal to calculate differences of iron and manganese concentrations in the sediment + tailings mixtures along the Paraopeba River. The study results showed reductions in the CSS between 6.6% and 18%, from upstream to downstream of the Igarapé Weir, related with backwater effects, free and submerged hydraulic jumps, bank sedimentation in periods of high flow, and streambed sedimentation controlled by channel sinuosity and tailings density. These reductions were accompanied by drops in the concentrations of iron and manganese present in the clay and silt fractions, which varied between 6% and 42% under low flows and between 16% and 44% under high flows. Bank sedimentation was viewed as a potential threat to the riparian vegetation in the long-term. Dredging is the potentially most effective mitigation measure to help lead the Paraopeba River to a pre-rupture condition. The retention of sediment + tailings transported in suspension is less effective than the trapping of bedload sediment + tailings behind the Igarapé weir. The efficacy of sediment trapping is expected to be larger for natural sediment because it is much coarser than the tailings. In that context, the simulations revealed for the low-flow period that 33.6% of the sediment deposition comprised suspended transport of natural sediment (thus, was comprised 66.4% of bedload transport), this proportion rose to 86.9% for mixtures of natural sediment + tailings, a result that did not differ much for the high-flow periods.     

Virtual velocity of sand transport in water

Using the 160‐m‐long flume at Tsukuba University we undertook an experiment to provide a first estimate of the virtual velocity of sand in the size range 0.5–2.0 mm. For the flow velocity used in our experiment this sediment‐size range would conventionally be regarded as suspended sediment. The virtual velocity was found to be 37–41% of the flow velocity. Paradoxically, virtual velocity decreases as particle size decreases. Such a lower virtual velocity of finer sediment is not inconceivable. First, trapping of the sediment appears to be a function of bed roughness, and there is a probable relationship between bed roughness and trapping efficiency for particles of different sizes. Second, finer particles are more likely to find sheltered positions on a rough bed and thus experience lower mobility, relative to the more exposed coarser grains, as observed for bedload transport. Third, the virtual velocity of particles undergoing bedload transport has been found, in some instances, to be lower for finer clasts. We combine our data with previous studies of virtual velocity of bedload to develop, for the first time, a hypothesis for a holistic analysis of sediment movement in rivers. Copyright © 2017 John Wiley & Sons, Ltd.     

Some observations on suspended sediment dynamics in Storbregrova,Jotunheimen

Observations are reported of the dynamics of suspended sediment transport in the meltstream of Storbreen in the Jotunheimen. Fine sediment is transferred from the subglacial to the proglacial environment during low flow (meltdominated) periods, and then removed from the catchment during high flow (rainfall-controlled) events. Both diurnal and storm period sediment load-discharge relationships involve clockwise hysteresis, but separate multivariate rating curves define variations of load with streamflow according to (1) the relative importance of meltwater and rainfall runoff, and (2) changes in the sediment source areas contributing to the stream at different times. Particle size variations in the suspended sediment also reflect varying source area influences.     

Complex behaviour of suspended sediment grain size downstream from a reservoir: an example from the Hanjiang River,China

Abstract

A study on the suspended sediment transportation downstream from the Danjiangkou Reservoir in China has shown that the dynamics of suspended sediment grain size are complicated. During the period when the reservoir was used for flood retention, the suspended sediment median size decreased gradually; after entering the period when the reservoir was used for water storage, the median size started to increase, reaching a maximum, and then decreased again. These variations correspond to different stages of channel adjustment. At the stage with dominant downcutting, most of the downstream reservoir sediment comes from bed downcutting, and thus the suspended sediment median size becomes coarser and coarser; at the succeeding stage with dominant channel widening, a majority of the suspended sediment comes from bank erosion, and so its median size becomes finer. This phenomenon can be regarded as a reflection of the complex response of channel adjustment in the characteristics of suspended sediment transportation downstream from a reservoir.     

Adsorption of cadmium on riverine sediments: quantitative treatment of the large particles

The effects of solution pH, sediment dose, contact time, and particle size on the adsorption of cadmium ions on bed sediments have been studied for a highly polluted river in western Uttar Pradesh, India. The role of the coarser sediment and the clay and silt fractions has been examined. The optimum contact time needed to reach equilibrium is of the order of 30 and 60 min for 0–75 μm and 210–250 μm sediment size, respectively. The extent of cadmium adsorption increases with increasing pH and adsorbent doses and decreases with adsorbent particle size. The important geochemical phases, iron and manganese oxide, provide the active support material for the adsorption of cadmium. The competitive experiments conducted in the presence of lead and zinc ions indicate that both the ions suppress the ability of cadmium to adsorb on to sediments. The Langmuir and Freundlich adsorption models were used to determine the mechanistic parameters associated with the adsorption process. Copyright © 2000 John Wiley & Sons, Ltd.