Adsorption organischer Substanzen unterschiedlicher Molekülgröße an Adsorberpolymeren

Wofatit Y 77 is presented as a novel non-ionogenic hydrophilic adsorbing polymer having a large specific BET surface (800 … 1500 m²/g) and a narrow pore size distribution. By the example of selected aromatic compounds with different molar masses it is shown on the basis of the adsorption of individual substances that the adsorption capacity primarily depends on the molecular size and not on the specific inner surface of the adsorber polymer. Favourable possibilities are derived from that for.     

Hydrothermal circulation beneath Mount Pelée inferred by self potential surveying. Structural and tectonic implications

Self-potential (SP) surveys were made on Mount Pelée volcano (Martinique Island, French West Indies) in 1991 and 1992 in order to recognize its hydrothermal system, the associated groundwater channeling and the main superficial structures of the massif. Almost 70 km of profiles were carried out with an average sample spacing of 50 m. Measurements essentially reveal negative SP anomalies, down to −1700 mV, with high gradients (−1.83 mV/m) due to the infiltration of meteoric water into the massif. Rims of summit calderas Morne Macouba and Etang-Sec present sharp negative SP anomalies on the western, northern, and eastern flanks. Negative SP anomalies indicate no upward water flow beneath Mount Pelée summit. On the southwestern volcano flank, a 3.5×6 km horseshoe-shaped structure corresponding to a southwest flank collapse event, older than 25,000 years BP, is clearly identified by the SP mapping. High gradients border the inner southern rim from Morne Calebasse to St Pierre town and the Caribbean Sea. Along the northern rim of the horseshoe-shaped structure the negative SP anomalies give place to a positive SP anomaly, up to 200 mV, of SW–NE trend. This zone covers the area of two active hot springs (Sources Chaudes and Puits Chaud: 40–65°C). Marine magnetic surveys and bathymetry show that the horseshoe-shaped structure spreads into the Caribbean Sea up to about 10 km from the coast. Buried structural discontinuities are evidenced inside the flank collapse structure. The upper one deviates the groundwater flow coming from the summit toward the south flank where the flow finds an indentation to expand again downwards. This discontinuity is either an old hypothetical caldera rim partly destroyed by the collapse of the south–southwestern flank and covered by recent pyroclastic deposits, or more probably the trace of a bulge landslide. A circulation model of the hydrothermal waters is proposed. Rainfall (5–6 m/year) is partly drained inside the summital calderas and the flank collapse zone through pyroclastic flows down to an impermeable basement. There the groundwater constitutes perched aquifers at the contact of the bulge landslide, or of the hypothetical old caldera rim. Along the inner northern border of the flank collapse structure the phreatic water is reheated. Warm groundwater flows along the northern avalanche structure rim and discharges near the coast in ground and marine outcrops, of medium temperature. Finally, the main part of the meteoric water is channeled along the old caldera rim, or along the bulge landslide towards the south flank of Mount Pelée, where some gaps in the rim exist. There the groundwater finds again a subhorizontal gravitational circulation along Mount Pelée slopes into the Caribbean Sea.     

Decentralized ℋ︁∞ controller design for large‐scale civil structures

Complexities inherent to large‐scale modern civil structures pose many challenges in the design of feedback structural control systems for dynamic response mitigation. With the emergence of low‐cost sensors and control devices creating technologies from which large‐scale structural control systems can deploy, a future control system may contain hundreds, or even thousands, of such devices. Key issues in such large‐scale structural control systems include reduced system reliability, increasing communication requirements, and longer latencies in the feedback loop. To effectively address these issues, decentralized control strategies provide promising solutions that allow control systems to operate at high nodal counts. This paper examines the feasibility of designing a decentralized controller that minimizes the ??_∞ norm of the closed‐loop system. ??_∞ control is a natural choice for decentralization because imposition of decentralized architectures is easy to achieve when posing the controller design using linear matrix inequalities. Decentralized control solutions are investigated for both continuous‐time and discrete‐time ??_∞ formulations. Numerical simulation results using a 3‐story and a 20‐story structure illustrate the feasibility of the different decentralized control strategies. The results also demonstrate that when realistic semi‐active control devices are used in combination with the decentralized ??_∞ control solution, better performance can be gained over the passive control cases. It is shown that decentralized control strategies may provide equivalent or better control performance, given that their centralized counterparts could suffer from longer sampling periods due to communication and computation constraints. Copyright © 2008 John Wiley & Sons, Ltd.     

Mt. Pelée, martinique: may 8 and 20, 1902, pyroclastic flows and surges

The distribution, stratigraphic relationships and fragmental components of the May 8 and 20, 1902, pyroclastic flows from Mt. Pelée, Martinique, together with eyewitness accounts, suggest the following explanation for those eruptions. The eruptions were vertically directed magmatic (perhaps initiated phreatically), and contained abundant juvenile lithics from congealed magma of the dome and neck. This resulted in a two-part eruption column having (1) a dense, lithic-charged part which collapsed into the crater and flowed out of a pre-existing notch in its side, giving rise to pyrochlastic flows, and (2) a magmatically derived column containing gases, juvenile vitric material and crystals which largely by-passed the neck and dome and escaped into the atmosphere. All of the energy of the flows was apparently focused through the notch. They emerged fully turbulent and flowed down Rivière Blanche. Gravity segregation of large and abundant fragments soon resulted in a dense, high-concentration, poorly fluidized block-and-ash flow confined to the valley, leaving above a fully turbulent, high-energy ash-cloud surge. As the ash-cloud surge moved down the mountain, it continued to expand outward. The process of gravity segregation continued as the ash-cloud surge expanded, resulting in secondary block-and-ash underflows. Toward St. Pierre, the secondary block-and-ash flows developed on a gently sloping upland surface 100 m or more above the valley of Rivière Blanche. The turbulent, fragment-depleted surges above the secondary block-and-ash flows maintained sufficient energy to devastate the landscape outward to about 3000 m, including St. Pierre. The surges refracted around obstacles and in one place, moved up a small valley in a direction opposite to the main flows.