基于测井曲线物理建模技术在煤系岩相分析中的应用

侏罗纪煤田煤层顶板水是制约煤矿安全生产的重要因素,研究煤层顶板岩性对防治上覆砂岩含水层显得尤为重要。首先利用常规测井曲线对煤层顶板岩性进行精细解释,获得顶板岩性的体积模型,在此基础上应用xu-white方法建立岩石物理模型,模拟出岩石的纵波速度、横波速度和密度测井曲线;将模拟密度曲线与实测密度曲线、录井岩性与测井解释岩性等进行对比,验证所建模型的合理性。以袁大滩井田2号煤层顶板岩性解释为例,通过建模计算,其正演密度曲线与实测密度曲线误差小于8%;合成记录振幅与地震振幅的相关系数高达90%,表明岩石物理模型正演速度与地震速度高度吻合,依此获得的波阻抗直方图有效的区分出2煤顶板的岩性。     

利用常规测井资料基于岩石物理和多矿物分析反演横波速度

测井横波速度是测井地震联合反演的重要标定参数.为克服大量老井缺少横波速度资料和现有横波速度估算方法的不足, 基于孔隙介质岩石物理理论, 通过常规测井资料求取多矿物组分, 利用VRH模型求得地层的等效弹性模量; 最后利用纵波速度作为约束条件, 根据Biot-Gassmann方程得到地层横波速度.计算结果与实测结果对比表明, 平均相对误差限在5%左右, 与Xu-White模型相比, 该方法物理意义更为明确, 使用更简便, 计算精度提高一倍左右.      

基于岩石物理模型的页岩孔隙结构反演及横波速度预测

准确预测储层的等效孔隙纵横比对页岩储层岩石物理建模及横波速度预测具有重要意义。为分析页岩储层孔隙纵横比及预测横波速度,提出了基于岩石物理模型的页岩孔隙纵横比反演及横波速度预测方法。本文首先通过岩石物理模型建立岩石的纵、横波速度与孔隙纵横比、孔隙度和矿物组分等参数之间的定量关系,寻找最佳孔隙纵横比;然后通过使理论预测与实际测量的纵波速度之间误差达到最小的方式反演孔隙纵横比,并以此为约束预测横波速度。实际测井数据反演结果表明,龙马溪组页岩地层的孔隙纵横比稳定,而围岩的孔隙纵横比变化范围较大;说明与围岩相比,页岩的孔隙结构更为稳定。同时,预测得到的页岩横波速度与实测横波速度的误差较小,另外对于缺少矿物组分资料的页岩层段,用平均矿物组分预测得到的横波速度误差仍较小;说明与矿物组分相比,龙马溪组页岩的纵、横波速度对孔隙纵横比参数更敏感。综上所述,利用该方法可预测到较为准确的等效孔隙纵横比和横波速度。     

基于人工鱼群算法和SCA等效理论的井中横波速度预测方法

在建立页岩岩石物理模型的基础上,根据等效自相容近似(SCA)岩石物理模型,构建出岩石的纵波速度、横波速度与岩石密度、组分和孔隙度等的定量关系,得出使理论纵波速度和实际纵波速度最接近的孔隙纵横比,进而将该孔隙纵横比作为约束条件来实现横波速度预测。反演算法利用人工鱼群算法来计算最佳孔隙纵横比,并将预测的横波速度与实际测得的横波速度对比,证明了人工鱼群算法的有效性。     

基于Buckingham模型和Biot-Stoll模型的南沙海域沉积物声速分布特征

为了选择合理的南海南部海底沉积物的声速反演模型,分别利用Wood方程、Buckingham模型、Biot-Stoll模型等声波传播理论模型计算了沉积物的纵波声速,结合沉积物实测声速和物理参数等,对比了模型计算声速与实测声速的变化特征。声速实测值与模型计算值的对比表明,Buckingham模型计算值与实测值的平均偏差最小。研究区实测声速比和模型计算声速比的分布表明,声速的变化特征与沉积环境具有相关性,声速模型计算值与实测值具有相似的变化特征;模型计算声速与实测声速的垂向变化规律不相同,模型计算声速随深度基本不变,而实测声速在陆架、陆坡和海槽等沉积环境中呈现出多种垂向分布特征。研究结果认为,侧重于沉积物孔隙性的Biot-Stoll理论仅适用于陆架区粗颗粒沉积物,兼具流体和弹性固体双重性质的Buckingham理论具有更广的适用范围。该研究对获取南海南部海域沉积物声速分布特征有重要意义,可为多波束测深或浅地层精细解释等提供基础资料。     

基于SC-Gassmann模型的纵横波速度预测

通过自相容近似模型和Biot理论相结合建立岩石物理模型,提出基于SC-Gassmann模型的速度预测方法。从实际测井资料中提取岩石物性参数,利用测井资料基于V-R-H模型来计算岩石基质弹性模量,然后通过自相容近似模型和Biot理论结合建立的岩石物理模型来计算干岩样骨架弹性模量,最后通过Gassmann方程加入流体,求得饱和岩石弹性模量,并预测储层岩石纵横波速度。实际资料计算表明,通过岩石物理模型计算的饱和岩石纵横波速度与实际数据吻合较好,符合实际地质情况,证明该方法可靠有效。     

南海神狐海域天然气水合物声波测井速度与饱和度关系分析

利用南海北部神狐海域A站位的地震和测井资料综合分析神狐海域含天然气水合物沉积层的声波测井速度及水合物饱和度的分布特征和变化规律,并对水合物饱和度的理论计算值和实测值进行对比分析,同时对水合物稳定带的纵波速度特征与饱和度的关系进行了综合研究。结果表明：神狐海域A站位的水合物层厚度约20 m,纵波速度在1 873～2 226m/s之间,水合物饱和度在15.0%～47.3%之间变化,水合物饱和度值相对较高;受海底复杂地质因素的影响,根据岩心孔隙水的氯离子淡化程度实测的水合物饱和度随声波速度的变化并不是单一的正比例关系,而是随声波速度的升高而上下波动,波动幅度在10%～20%之间,总体趋势上随声波速度的升高而升高,并集中分布在理论曲线附近;利用热弹性理论速度模型计算并校正后的水合物饱和度随声波速度的增加而有规律地增加,水合物饱和度的理论计算值与实测数据比较吻合,说明所建立的岩石物理模型正确,模型参数选取合理。根据声波速度计算水合物饱和度这一方法可扩展到整个研究区域,并为研究区的水合物资源量评价提供基础数据。     

综合成岩作用和孔隙形状的岩石物理模型及其应用

横波速度对于地震模拟、AVO分析以及流体识别具有重要意义,实际测井数据中横波速度信息缺乏,因此横波速度预测已经成为岩石物理研究的一个焦点。综合Xu-White模型以及Pride模型,提出了一种新的用于计算干岩石模量的岩石物理模型。该模型综合考虑了孔隙形状和成岩作用对干岩石体积模量、剪切模量的影响,因此该模型更加合理并具有更高的精度。同时联合Gassmann理论,建立了饱和流体岩石的纵波、横波速度计算模型。将该模型成功地应用于实验室测量数据和实际测井数据的横波速度预测中,预测结果表明,基于本文提出的岩石物理模型的横波速度预测方法是行之有效的。     

反射波法在人工挖孔桩桩端持力层岩土性状分析中应用探讨

通过某工程人工挖孔桩低应变反射波法实测结果与钻芯法检测结果对比分析,认为低应变反射波法检测结果可定性判断人工挖孔灌注桩桩端持力层岩土性状,岩体的纵波速度与岩石的完整程度、岩石风化程度等因素关系密切~([1~2]),本文利用低应变反射波法检测结果计算了人工挖孔灌注桩持力层纵波速度,利用计算的持力层纵波速度对人工挖孔桩持力层岩土性状进行了探讨。     

基于声波测井的冻土区孔隙型水合物储层水合物饱和度估算方法

水合物饱和度参数的准确计算对于水合物资源量的评价至关重要。本文提出利用超声波测井资料与等效介质模型相结合的方法,可有效评价祁连山冻土区孔隙型水合物储层水合物饱和度变化特征,并在典型孔隙型水合物钻孔DKXX 13进行了应用。基于等效介质理论的弹性波速度模型正演模拟的纵波速度相比基于双相介质理论的弹性波速度模型更加吻合实际测井纵波速度,可用于分析孔隙型水合物储层的纵波速度特征;通过正演模拟的纵波速度与实际测井纵波速度的对比,识别出X30. 0~X30. 2m、X30. 3~X30. 4m、X31. 1~X31. 6m、X31. 7~X31. 9m、X32. 0~X32. 2m井段存在水合物,水合物赋存井段地层的水合物饱和度变化范围为13. 0%~85. 0%,平均值为61. 9%,与标准阿尔奇公式估算结果和现场岩芯测试结果基本一致。研究结果可为祁连山冻土区水合物地层测井评价与地震勘探提供理论依据和技术支撑。     

http://www.sciencedirect.com/science/article/pii/S1674987115000584

The spatial distribution patterns of surficial sediment samples from different sedimentary domains(shallow to deep-sea regions) of the eastern Arabian Sea were studied using sediment proxies viz.environmental magnetism,geochemistry,particle size and clay mineralogy.Higher concentrations of magnetic minerals(high x_(lf)) were recorded in the deep-water sediments when compared with the shallow water sediments.The magnetic mineralogy of one of the shallow water samples is influenced by the presence of bacterial magnetite as evidenced from the x_(ARM)/x_(lf)~(vs).x_(arm_/x_(fd)biplot.However,the other samples are catchment-derived.The high correlation documented for x_(lf).anhysteretic remanent magnetisation(x_(arm)) and isothermal remanent magnetisation(IRM) with Al indicates that the deep-sea surficial sediments are influenced by terrigenous fluxes which have been probably derived from the southern Indian rivers,the Sindhu(the Indus) and the Narmada-Tapti rivers.A lower Mn concentration is recorded in the upper slope sediments from the oxygen minimum zone(OMZ) but a higher Mn/Al ratio is documented in the lower slope and deep-sea sediments.Clay minerals such as illite(24-48.5%),chlorite(14.1-34.9%),smectite(10.6-28.7%) and kaolinite(11.9-27.5%) dominate the sediments of shallow and deep-sea regions and may have been derived from different sources and transported by fluvial and aeolian agents.Organic carbon(OC) data indicate a low concentration in the shallow/shelf region(well oxygenated water conditions) and deeper basins(increased bottom-water oxygen concentration and low sedimentation rate).High OC concentrations were documented in the OMZ(very low bottom-water oxygen concentration with high sedimentation rate).The calcium carbonate concentration of the surface sediments from the continental shelf and slope regions( 1800 m) up to the Chagos-Laccadive Ridge show higher concentrations(average = 58%) when compared to deep basin sediments(average = 44%).Our study demonstrates that particle size as well as magnetic grain size,magnetic minerals and elemental variations are good indicators to distinguish terrigenous from biogenic sediments and to identify sediment provenance.     

Calcium isotope evidence for suppression of carbonate dissolution in carbonate-bearing organic-rich sediments

Pore fluid calcium isotope, calcium concentration and strontium concentration data are used to measure the rates of diagenetic dissolution and precipitation of calcite in deep-sea sediments containing abundant clay and organic material. This type of study of deep-sea sediment diagenesis provides unique information about the ultra-slow chemical reactions that occur in natural marine sediments that affect global geochemical cycles and the preservation of paleo-environmental information in carbonate fossils. For this study, calcium isotope ratios (δ^44/40Ca) of pore fluid calcium from Ocean Drilling Program (ODP) Sites 984 (North Atlantic) and 1082 (off the coast of West Africa) were measured to augment available pore fluid measurements of calcium and strontium concentration. Both study sites have high sedimentation rates and support quantitative sulfate reduction, methanogenesis and anaerobic methane oxidation. The pattern of change of δ^44/40Ca of pore fluid calcium versus depth at Sites 984 and 1082 differs markedly from that of previously studied deep-sea Sites like 590B and 807, which are composed of nearly pure carbonate sediment. In the 984 and 1082 pore fluids, δ^44/40Ca remains elevated near seawater values deep in the sediments, rather than shifting rapidly toward the δ^44/40Ca of carbonate solids. This observation indicates that the rate of calcite dissolution is far lower than at previously studied carbonate-rich sites. The data are fit using a numerical model, as well as more approximate analytical models, to estimate the rates of carbonate dissolution and precipitation and the relationship of these rates to the abundance of clay and organic material. Our models give mutually consistent results and indicate that calcite dissolution rates at Sites 984 and 1082 are roughly two orders of magnitude lower than at previously studied carbonate-rich sites, and the rate correlates with the abundance of clay. Our calculated rates are conservative for these sites (the actual rates could be significantly slower) because other processes that impact the calcium isotope composition of sedimentary pore fluid have not been included. The results provide direct geochemical evidence for the anecdotal observation that the best-preserved carbonate fossils are often found in clay or organic-rich sedimentary horizons. The results also suggest that the presence of clay minerals has a strong passivating effect on the surfaces of biogenic carbonate minerals, slowing dissolution dramatically even in relation to the already-slow rates typical of carbonate-rich sediments.     

REE示踪沉积物物源研究进展

ＲＥＥ作为一种重要的沉积物物源示踪剂运用很广。在介绍了ＲＥＥ性质的基础上，对海水、河水、沉积岩、河流及边缘海沉积物中的ＲＥＥ元素丰度与配分模式特征进行了深入综述，概述了影响和控制ＲＥＥ丰度、模式及分馏特征的主要因素；论述了ＲＥＥ的物泊示踪意义以及在国内外应用情况与存在问题：源岩风化对ＲＥＥ分馏的影响；颗粒运及沉积时水动力分选对ＲＥＥ分馏可能造成的影响，即不同粒级中的ＲＥＥ不同的丰度与配分模式和碎屑     

中太平洋海盆表层沉积物及其与锰结核的关系

通过对中太平洋海盆表层沉积物与相伴生的锰结核的研究表面,丰度、品位等有明显的差异,在深海粘土中锰结核干度最度,钙质软泥多,锰结核的发现聚集与沉积物类型,沉积速率、孔隙度、金属含量及形成时的氧化还原条件,水深、底层流等的影响.锰结核的形成,发育与富集是受多种因素所控制,是一个模式内的约制。     

Clay‐coat diversity in marginal marine sediments

The specific mineralogy of clay grain coats controls the ability of the coat to inhibit quartz cementation in sandstones during prolonged burial and heating. How and why clay‐coat mineralogy varies across marginal marine systems is poorly understood, even though these eogenetic phenomena strongly influence subsequent mesodiagenesis and reservoir quality. The novel development of the ability to predict the distribution of clay‐coat mineralogy would represent an important development for sandstone reservoir quality prediction. In marginal marine sediments, clay minerals occur as grain‐coats, floccules, mud intraclasts, clay‐rich rock fragments or as dispersed material. However, the relationships between clay mineralogy, the amount of clay, and its distribution is poorly understood. This study focused on the Ravenglass Estuary, UK. The key aim was to develop and apply a novel methodology utilising scanning electron microscope – energy dispersive spectrometry, for the first time, on grain coats in modern sediments, to differentiate the clay‐coat mineral signature from that of the bulk sediment, and reveal the distribution of clay minerals across marginal marine sediments. The study showed that marginal marine sediments principally have their clay mineral assemblage present as clay‐coats on sand grains. These clay‐coats have a mixed clay mineralogy and are spatially heterogeneous across the range of marginal‐marine depositional environments. The study further showed that clay‐coat mineralogy is governed initially by the hydrologically‐controlled segregation of the clay minerals within inner estuarine depositional environments, and subsequently by the selective abrasive removal of specific clay mineral types during reworking and transport into the outer estuary and the marine environment. The highest relative abundance of grain‐coating chlorite was in sand‐flat and tidal‐bar depositional environments. The availability of an analogue data set, and an understanding of the controlling processes of clay‐coat mineralogy, offer crucial steps in building a predictive capability for clay‐coat derived elevated reservoir quality in deeply buried sandstones.     

黏土矿物颗粒特征对含水合物的沉积物力学特性影响研究

含水合物的沉积物力学参数是水合物储层稳定性评价的基础数据。我国南海神狐海域含水合物的沉积物中含大量的黏土,深入了解黏土矿物对沉积物力学特性的影响对水合物开采具有十分重要的意义。基于PFC三轴压缩模拟,首先分析了沉积物中不含水合物时,黏土矿物颗粒特征的力学效应,然后分析了水合物对颗粒的胶结作用和围压对沉积物力学特性的影响。结果表明,不含水合物模型的偏应力-应变曲线呈明显的应变硬化特征。黏土矿物的含量、颗粒形状和排列对沉积物三轴压缩特性具有显著影响。黏土矿物含量的增多对沉积物力学强度具有明显的降低作用,黏土矿物形状为条形的沉积物强度和弹性模量要明显高于圆颗粒模型,在细观上受颗粒平均接触数影响,条形黏土颗粒的定向排列使模型的力学参数具有各向异性。水合物对颗粒的胶结作用可显著提高模型的峰值强度和弹性模量,随着颗粒胶结程度的增大和围压的减小,含水合物的沉积物的破坏方式由塑性破坏向脆性破坏转换。     

柴达木盆地西部北区新近系非常规低渗储集层特征及控制因素分析

柴达木盆地西部北区新近系储集层岩石成分复杂,矿物成分包括石英、长石等陆源碎屑,也有较多碳酸盐矿物和黏土矿物,且粒度偏细,通过一般薄片鉴定难以准确进行岩性定名。本文主要对该区南翼山、油泉子、小梁山和咸水泉四个含油构造储集层岩石类型进行分析,基于岩芯观察和薄片鉴定,借助X射线全岩矿物分析,认为该区储集层岩石为陆源碎屑物质和化学成因的碳酸盐混合沉积的岩石类型,按黏土含量、碳酸盐含量和石英长石含量做出矿物三角图,提出岩性分类方案,将储集层岩性划分为泥岩、砂岩、碳酸盐岩和混合沉积类。该区储集层岩石物性普遍较差,孔隙类型包括粒间溶蚀孔隙、微裂缝和微孔隙等。压实作用、溶蚀作用及胶结充填作用是控制储集层性能的主要因素。     

The extent of oxygen isotope exchange between clay minerals and sea water

The extent of oxygen isotopic exchange between detrital clay minerals and sea water was investigated by analyzing $\text{O}{}^{18}\text{O}{}^{16}$ ratios of separated fine-grained size fractions of deep-sea sediments from three North Pacific ocean cores. Isotopic results were interpreted according to models based on the assumption that the extent of isotopic exchange should increase with decreasing particle size and increasing time of exchange between the sediment and sea water. The data indicate that information concerning the provenance and mode of formation of detrital clay minerals can be obtained from the $\text{O}{}^{18}\text{O}{}^{16}$ ratios of the coarser-than-0.1 μm fraction of deep-sea sediments younger than several million years and the finer-than-0.1 μm fraction of deep-sea sediments younger than several tens of thousands of years. Furthermore, if the extent of chemical reaction between detrital clays and sea water is similar to the extent of oxygen isotopic exchange, such reaction may be important in regulating the chemistry of sea water.     

Adams和Couch法古盐度恢复结果的可靠性检验——以青海湖布哈河口区沉积物为例

Adams公式和Couch公式是利用沉积物中硼元素浓度对沉积水体古盐度进行定量恢复的常用方法,但由于两种方法的恢复结果经常存在较大差异,古盐度的计算结果常难以让人信服。为了验证Adams公式和Couch公式的可靠性,本次研究采集了青海湖布哈河口区不同沉积环境的表层沉积物和底层水体样品,处理后分别分析了沉积物中硼元素浓度、总有机碳（TOC）含量及矿物组成,同时对水体盐度及其硼浓度进行了测量,结果表明:湖泊水体中硼浓度与盐度存在极好的线性正相关性,但沉积物中硼元素的浓度与沉积水体中硼的浓度并无直接联系。根据沉积物中硼的浓度及黏土矿物含量和组成,分别采用Adams公式和Couch公式对水体盐度进行计算,盐度计算值均远高于水体盐度实测值,其中Adams公式的计算结果与实测值差别最大,盐度计算值与沉积物中硼含量呈正相关关系。沉积物中的硼元素主要由继承自母岩的硼、黏土矿物吸附硼和有机质中富集的硼三部分组成,只有黏土矿物中的吸附硼能够反映水体盐度。青海湖布哈河口区沉积物富含有机质,有机质对硼强烈的富集作用是导致Adams公式和Couch公式盐度恢复结果失效的重要原因,同时不同类型黏土矿物对硼吸附能力的差异也对恢复结果有重要影响:黏土矿物在盐水中的浸泡试验表明蒙脱石对硼的吸附能力最强,次为伊利石,高岭石吸附能力最差,推翻了Couch关于伊利石对硼吸附能力最强的认识。原Adams公式和Couch公式仅没有考虑有机质对硼的影响,对不同类型黏土矿物吸附能力的认识有误,不适合陆相沉积物沉积水体古盐度的恢复。沉积物黏土矿物中吸附硼浓度仍是反映沉积水体盐度的可靠指标,古盐度的恢复首先必须消除沉积物中有机质对硼的影响,然后根据一系列的浸泡试验确定不同类型黏土矿物对硼的吸附系数,并建立新的计算公式。     

An infrared study of clay minerals, 2. The identification of kaolinite-group clays in deep-sea sediments

The kaolinite-group mineral in deep-sea sediments is usually identified as kaolinite, and occasionally as halloysite. A study has been made of the infrared spectra of these two minerals; their absorption bands have been described, and compared to those of the other principal clay groups, i.e., illites, montmorillonites and chlorites, found in deep-sea sediments. It is shown that kaolinite and halloysite have diagnostic absorption bands at ca. 915 cm^?1 and ca. 3700 cm^?1. These bands are made the basis of a rapid infrared technique for the identification of kaolinite and or halloysite in deep-sea sediments.