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1.
Climate factors play critical roles in controlling chemical weathering, while chemically weathered surface material can regulate climate change. To estimate global chemical weathering fluxes and CO2 balance, it is important to identify the characteristics and driving factors of chemical weathering and CO2 consumption on the Tibetan Plateau, especially in glaciated catchments. The analysis of the hydro-geochemical data indicated that silicate weathering in this area was inhibited by low temperatures, while carbonate weathering was promoted by the abundant clastic rocks with fresh surfaces produced by glacial action. Carbonate weathering dominated the riverine solute generation (with a contribution of 58%, 51%, and 43% at the QiangYong Glacier (QYG), the WengGuo Hydrological Station (WGHS), and the lake estuary (LE), respectively). The oxidation of pyrite contributed to 35%, 42%, and 30% of the riverine solutes, while silicate weathering contributed to 5%, 6%, and 26% of the riverine solutes at the QYG, WGHS, and LE, respectively. The alluvial deposit of easily weathering fine silicate minerals, the higher air temperature, plant density, and soil thickness at the downstream LE in comparison to upstream and midstream may lead to longer contact time between pore water and mineral materials, thus enhancing the silicate weathering. Because of the involvement of sulfuric acid produced by the oxidation of pyrite, carbonate weathering in the upstream and midstream did not consume atmospheric CO2, resulting in the high rate of carbonate weathering (73.9 and 75.6 t km−2 yr−1, respectively, in maximum) and potential net release of CO2 (with an upper constraint of 35.6 and 35.2 t km−2 yr−1, respectively) at the QYG and WGHS. The above results indicate the potential of the glaciated area of the Tibetan Plateau with pyrite deposits being a substantial natural carbon source, which deserves further investigation.  相似文献   

2.
A study has been made of weathering in Glendye, an upland catchement of heather moorland underlain mainly by granite with some gneiss in north-east Scotland. The concentrations of a range of elements and ions in precipitation and river water were measured over a twelve-month period. The total input and output of each element or ion was calculated. The resulting balances show net outputs of all species except hydrogen ion. Large net outputs of silicon (38.5 kg ha?1 a?1) and bicarbonate (48 kg ha?1 a?1) indicate considerable chemical weathering. A large net output of chloride (32 kg ha?1 a?1) indicates the importance of dry deposition of oceanic aerosols. When this is allowed for the rate of output of elements due to weathering is. Si>Ca>Na>Mg>K>Fe>Al. These results were compared with the abundance of elements in bedrock and differential weathering ratios calculated. These are compared with data from the Hubbard Brook study in New Hampshire. In both cases calcium is by far the most mobile element. The relative importance of the atmosphere and of chemical weathering as sources of each element was calculated, and the results compared with those of a study at Wet Sleddale in the Lake District. Similar patterns emerge in both cases.  相似文献   

3.
Mineral weathering rates and a forest macronutrient uptake stoichiometry were determined for the forested, metabasaltic Hauver Branch watershed in north‐central Maryland, USA. Previous studies of Hauver Branch have had an insufficient number of analytes to permit determination of rates of all the minerals involved in chemical weathering, including biomass. More equations in the mass‐balance matrix were added using existing mineralogic information. The stoichiometry of a deciduous biomass term was determined using multi‐year weekly to biweekly stream‐water chemistry for a nearby watershed, which drains relatively unreactive quartzite bedrock. At Hauver Branch, calcite hosts ~38 mol% of the calcium ion (Ca2+) contained in weathering minerals, but its weathering provides ~90% of the stream water Ca2+. This occurs in a landscape with a regolith residence time of more than several Ka (kiloannum). Previous studies indicate that such old regolith does not typically contain dissolving calcite that affects stream Ca2+/Na+ ratios. The relatively high calcite dissolution rate likely reflects dissolution of calcite in fractures of the deep critical zone. Of the carbon dioxide (CO2) consumed by mineral weathering, calcite is responsible for approximately 27%, with the silicate weathering consumption rate far exceeding that of the global average. The chemical weathering of mafic terrains in decaying orogens thus may be capable of influencing global geochemical cycles, and therefore, climate, on geological timescales. Based on carbon‐balance calculations, atmospheric‐derived sulfuric acid is responsible for approximately 22% of the mineral weathering occurring in the watershed. Our results suggest that rising air temperatures, driven by global warming and resulting in higher precipitation, will cause the rate of chemical weathering in the Hauver Branch watershed to increase until a threshold temperature is reached. Beyond the threshold temperature, increased recharge would produce a shallower groundwater table and reduced chemical weathering rates. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   

4.
The glaciers on Tibetan Plateau play an important role in the catchment hydrology of this region. However, our knowledge with respect to water circulation in this remote area is scarce. In this study, the HBV light model, which adopts the degree‐day model for glacial melting, was employed to simulate the total runoff, the glacier runoff and glacier mass balance (GMB) of the Dongkemadi River Basin (DRB) at the headwater of the Yangtze River on the Tibetan Plateau, China. Firstly, the daily temperature and precipitation of the DRB from 1955 to 2008 were obtained by statistical methods, based on daily meteorological data observed in the DRB (2005–2008) and recorded by four national meteorological stations near the DRB (1955–2008). Secondly, we used 4‐year daily air temperature, precipitation, runoff depth and monthly evaporation, which were observed in the DRB, as input to obtain a set of proper parameters. Then, the annual runoff, the glacier runoff and GMB (1955–2008) were calculated using the HBV model driven by interpolated meteorological data. The calculated GMB fits well with the observed results. At last, using the temperature and precipitation predicted by climate models, we predicted the changes of runoff depth and GMB of the DRB in the next 40 years. Under all climate‐change scenarios, annual glacier runoff shows a significant increase due to intensified ice melting. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   

5.
Springs are the point of origin for most headwater streams and are important regulators of their chemical composition. We analysed solute concentrations of water emerging from 57 springs within the 3 km2 Fool Creek catchment at the Fraser Experimental Forest and considered sources of spatial variation among them and their influence on the chemical composition of downstream water. On average, calcium and acid neutralizing capacity (bicarbonate-ANC) comprised 50 and 90% of the cation and anion charge respectively, in both spring and stream water. Variation in inorganic chemical composition among springs reflected distinct groundwater sources and catchment geology. Springs emerging through glacial deposits in the upper portion of the catchment were the most dilute and similar to snowmelt, whereas lower elevation springs were more concentrated in cations and ANC. Water emerging from a handful of springs in a geologically faulted portion of the catchment were more concentrated than all others and had a predominant effect on downstream ion concentrations. Chemical similarity indicated that these springs were linked along surface and subsurface flowpaths. This survey shows that springwater chemistry is influenced at nested spatial scales including broad geologic conditions, elevational and spatial attributes and isolated local features. Our results highlight the role of overlapping factors on solute export from headwater catchments.  相似文献   

6.
Glaciers are commonly located in mountainous terrain subject to highly variable meteorological conditions. High resolution meteorological (HRM) data simulated by atmospheric models can complement meteorological station observations in order to assess changes in glacier energy fluxes and mass balance. We examine the performance of two snow models, SnowModel and Alpine3D, forced by different meteorological data for winter mass balance simulations at four glaciers in the Canadian portion of the Columbia Basin. The Weather Research and Forecasting model (WRF) with resolution of 1 km and the North American Land Data Assimilation System with ~12 km resolution, provide HRM data for the two snow models. Evaluation is based on the ability of the snow models to simulate snow depth at both point locations (automated snow weather stations) and over the entire glacier surface (airborne LiDAR [Light Detection and Ranging] surveys) during the 2015/2016 winter accumulation. When forced with HRM data, both models can reproduce snow depth to within ±15% of observed values. Both models underestimate winter mass balance when forced by HRM data. When driven with WRF data, SnowModel underestimates winter mass balance integrated over the glacier area by 1 and 10%, whilst Alpine3D underestimates winter mass balance by 12 and 22% compared with LiDAR and stake measurements, respectively. The overall results show that SnowModel forced by WRF simulated winter mass balance the best.  相似文献   

7.
We present a statistical model of soil and rock weathering in deep profiles to expand the capacity to assess weathering to heterogeneous bedrock types, which are common at the Earth's surface. We developed the Weathering Trends (WT) model by extending the fractional mass change calculation (tau) of the geochemical mass balance model in two important ways. First, WT log transforms the elemental ratio data, to discern the log‐linear patterns that naturally develop from thermodynamic and kinetic laws of chemistry. Second, WT statistically fits log‐transformed element concentration ratio data – log(cj/ci), the only depth‐varying term in tau – as a function of depth to determine characteristic depths of transitions in weathering processes, along with confidence intervals. With no prior assumptions, WT estimates average parent material composition, average composition of the upper weathered zone and mean fractional mass change of each element over the entire weathering profile. WT displays the mean shape of weathering profiles of log‐transformed geochemical data bounded by calculated confidence intervals. We share the WT model code as an open‐source R package ( https://github.com/fisherba/WeatheringTrends ). The WT model was designed to interpret two 21 m cores from the Laurels Schist bedrock in the Christina River Basin Critical Zone Observatory in the Pennsylvania Piedmont, where our morphological and elemental data provided inconclusive estimates of bedrock depth. The WT model differentiated between rock variability and weathering to delineate the maximum extent of weathering at 12.3 m (CI 95% [9.2, 21.3]) in Ridge Well 1 and 7.2 m (CI 95% [4.3, 13.0]) in Interfluve Well 2. The water table was 5–8 m below fresh rock at Ridge Well 1, but at the same depth as fresh rock at the lower elevation interfluve. We assess statistical approaches to identify the best immobile element for use in WT and tau calculations. Copyright © 2017 John Wiley & Sons, Ltd.  相似文献   

8.
The initial stages of cobble weathering, measured as increasing percentage porosity, were calculated for sets of cobbles taken from the foreland of Storbreen, a cirque glacier in the Jotunheimen, Norway. Cobbles were taken from in front of the 1998 glacier snout, from the 1928, 1870, 1810 and 1750 moraine crests and from the ~10 000‐year‐old land surface beyond the Neoglacial foreland limit. Three microenvironments were examined within each site: (1) lichen‐free surfaces from exposed cobbles, (2) lichen‐covered surfaces from exposed cobbles and (3) buried cobbles taken from a soil depth of ~40 cm. Percentage porosity within plagioclase minerals was calculated using backscatter electron images of prepared thin sections. Porosity was calculated from five depth profiles into each cobble. Depth profiles were subdivided into a sequence of 50 µm × 50 µm rectangles running to at least a nominal depth of 500 µm within each cobble. Three cobbles from each dated land surface were sampled, except for the 1750 surface, which had five cobbles. Statistical analysis was by analysis of variance of rank‐order transformed data. Findings indicate that cobbles close to the glacier snout are largely unweathered; also, weathering is generally weak in the 1928, 1870 and 1810 positions, but statistically significantly higher in the 1750‐ and 10 000‐year‐old positions. Weathering of buried cobbles always exceeded weathering of exposed cobbles and may possibly reach a value beyond which it cannot progress while retaining surface cohesion. The degree of weathering on lichen‐free and lichen‐covered cobble surfaces is not initially distinguishable, but diverges sharply after ~250 years, when lichen‐covered surfaces experience significantly higher totals. Overall, the weathering trend in cobbles matches that found in soils at the same sites. Copyright © 2007 John Wiley & Sons, Ltd.  相似文献   

9.
Long-term data (2003–2015) on meltwater chemistry, mass balance and discharge of a benchmark glacier (Chhota Shigri Glacier, India) were studied to determine any association between these variables. To infer the factors governing the alteration of chemical weathering processes in glacierized basins, multi-annual records of the hydrochemical indices (Ca2++Mg2+/Na++K+) and the C-ratio were also examined. A succession of negative mass balance years has resulted in a decline in solute concentrations in the runoff, as discharge has increased. The (Ca2++Mg2+/Na++K+) and C-ratio are highest during periods of negative annual mass balance, when the spatial extent of the channelized drainage system increases. Conversely, these ratios are lowest in positive mass balance years, when the spatial extent of the channelized drainage system decreases, and chemical weathering in the distributed drainage system becomes more dominant. This paper is the first to show the inter-annual linkages between meltwater chemistry, mass balance and discharge for a valley glacier.  相似文献   

10.
Potential hydrological impacts of climate change on long‐term water balances were analysed for Harp Lake and its catchment. Harp Lake is located in the boreal ecozone of Ontario, Canada. Two climate change scenarios were used. One was based on extrapolation of long‐term trends of monthly temperature and precipitation from a 129‐year data record, and another was based on a Canadian general circulation model (GCM) predictions. A monthly water balance model was calibrated using 26 years of hydrological and meteorological data, and the model was used to calculate hydrological impact under two climate change scenarios. The first scenario with a warmer and wetter climate predicted a smaller magnitude of change than the second scenario. The first scenario showed an increase in evaporation each month, an increase in catchment runoff in summer, fall and winter, but a decrease in spring, resulting in a slight increase in lake level. Annual runoff and lake level would increase because the precipitation change overrides evaporation change. The second scenario with a warmer, drier climate predicted a greater change, and indicated that evaporation would increase each month, runoff would increase in many months, but would decrease in spring, causing the lake level to decrease slightly. Annual runoff and lake level would decrease because evaporation change overrides precipitation change. In both scenarios, the water balance changes in winter and spring are pronounced. Copyright © 2009 John Wiley & Sons, Ltd.  相似文献   

11.
Carbon storage values in the Amazon basin have been studied through different approaches in the last decades in order to clarify whether the rainforest ecosystem is likely to act as a sink or source for carbon in the near future. This water balance, dissolved organic carbon (DOC) and nutrient export study were carried out in a micro‐scale heath forest (Campina) catchment in central Amazonia, Brazil. For a 1‐year study period (18 March 2007 until 19 March 2008), rainfall amounted to 3054 mm; of which, 1532 mm was evaporated by the forest (4.1 mm day?1). Rainfall interception loss amounted to 15.6% of gross rainfall. Surface runoff amounted to 485 mm, whereas another 1071 mm was discharged as regional groundwater outflow. Accumulated DOC exports in surface runoff amounted to 15.3 g m?2 year?1, whereas the total carbon exported was 55.9 g m?2. This is much higher than that observed for a nearby tall rainforest catchment in central Amazonia (DOC export < 20 g m?2). As Campina heath forest areas cover a significant proportion of the Amazon Basin, these differences in ecosystem hydrological carbon exports should be taken into account in future studies assessing the carbon budget for the Amazon Basin. Macro‐nutrient exports were low, but those of calcium and potassium were higher than those observed for tall rainforest in the Amazon, which may be caused by a lower retention capacity of the heath forest ecosystem. Copyright © 2015 John Wiley & Sons, Ltd.  相似文献   

12.
Modelling melt and runoff from snow‐ and ice‐covered catchments is important for water resource and hazard management and for the scientific study of glacier hydrology, dynamics and hydrochemistry. In this paper, a distributed, physically based model is used to determine the effects of the up‐glacier retreat of the snowline on spatial and temporal patterns of melt and water routing across a small (0·11 km2) supraglacial catchment on Haut Glacier d'Arolla, Switzerland. The melt model uses energy‐balance theory and accounts for the effects of slope angle, slope aspect and shading on the net radiation fluxes, and the effects of atmospheric stability on the turbulent fluxes. The water routing model uses simplified snow and open‐channel hydrology theory and accounts for the delaying effects of vertical and horizontal water flow through snow and across ice. The performance of the melt model is tested against hourly measurements of ablation in the catchment. Calculated and measured ablation rates show a high correlation (r2 = 0·74) but some minor systematic discrepancies in the short term (hours). These probably result from the freezing of surface water at night, the melting of the frozen layer in the morning, and subsurface melting during the afternoon. The performance of the coupled melt/routing model is tested against hourly discharge variations measured in the supraglacial stream at the catchment outlet. Calculated and measured runoff variations show a high correlation (r2 = 0·62). Five periods of anomalously high measured discharge that were not predicted by the model were associated with moulin overflow events. The radiation and turbulent fluxes contribute c. 86% and c. 14% of the total melt energy respectively. These proportions do not change significantly as the surface turns from snow to ice, because increases in the outgoing shortwave radiation flux (owing to lower albedo) happen to be accompanied by decreases in the incoming shortwave radiation flux (owing to lower solar incidence angles) and increases in the turbulent fluxes (owing to higher air temperatures and vapour pressures). Model sensitivity experiments reveal that the net effect of snow pack removal is to increase daily mean discharges by c. 50%, increase daily maximum discharges by >300%, decrease daily minimum discharges by c. 100%, increase daily discharge amplitudes by >1000%, and decrease the lag between peak melt rates and peak discharges from c. 3 h to c. 50 min. These changes have important implications for the development of subglacial drainage systems. Copyright © 2002 John Wiley & Sons, Ltd.  相似文献   

13.
Because of the different geochemical behaviour of rubidium and strontium in earth surface processes, variations of the Rb/Sr ratios in lake sediments were used as a geochemical proxy of chemical weathering and past climate in a single watershed. Low magnetic susceptibility, low CaCO3, low Sr concentration and, hence, high Rb/Sr ratio in the lake sediments indicate weak chemical weathering under a cold but wet climate during the Little Ice Age (LIA) in the closed Daihai Lake watershed. The concordant change in both Sr and CaCO3 concentrations with δ18O values in the Dunde ice core suggests that weak chemical weathering during the wet LIA was controlled by air temperature. After the LIA, however, precipitation played a dominant role in chemical weathering. Copyright © 2001 John Wiley & Sons, Ltd.  相似文献   

14.
Understanding how explicit consideration of topographic information influences hydrological model performance and upscaling in glacier dominated catchments remains underexplored. In this study, the Urumqi glacier no. 1 catchment in northwest China, with 52% of the area covered by glaciers, was selected as study site. A conceptual glacier‐hydrological model was developed and tested to systematically, simultaneously, and robustly reproduce the hydrograph, separate the discharge into contributions from glacier and nonglacier parts of the catchment, and establish estimates of the annual glacier mass balance, the annual equilibrium line altitude, and the daily catchment snow water equivalent. This was done by extending and adapting a recently proposed landscape‐based semidistributed conceptual hydrological model (FLEX‐Topo) to represent glacier and snowmelt processes. The adapted model, FLEXG, allows to explicitly account for the influence of topography, that is, elevation and aspect, on the distribution of temperature and precipitation and thus on melt dynamics. It is shown that the model can not only reproduce long‐term runoff observations but also variations in glacier and snow cover. Furthermore, FLEXG was successfully transferred and up‐scaled to a larger catchment exclusively by adjusting the areal proportions of elevation and aspect without the need for further calibration. This underlines the value of topographic information to meaningfully represent the dominant hydrological processes in the region and is further exacerbated by comparing the model to a model formulation that does not account for differences in aspect (FLEXG,nA) and which, in spite of satisfactorily reproducing the observed hydrograph, does not capture the influence of spatial variability of snow and ice, which as a consequence reduces model transferability. This highlights the importance of accounting for topography and landscape heterogeneity in conceptual hydrological models in mountainous and snow‐, and glacier‐dominated regions.  相似文献   

15.
Min Xu  Hao Wu  Shichang Kang 《水文研究》2018,32(1):126-145
The Tianshan Mountains represent an important water source for the arid and semi‐arid regions of Central Asia. The discharge and glacier mass balance (GMB) in the Tianshan Mountains are sensitive to changes in climate. In this study, the changes in temperature, precipitation, and discharge of six glacierized watersheds of Tianshan Mountains were explored using non‐parametric tests and wavelet transforms during 1957–2004. On the basis of the statistical mechanics and maximum entropy principle model, the GMB at the watershed scale were reconstructed for the study period. The discharge and GMB responses to climate change were examined in different watersheds. The results showed that regional climate warming was obvious, especially after 1996. The warming trend increased gradually from east to west, and the increase in temperature was greater on the north slope than on the south slope. The changing trends in precipitation increased from eastern region to central region, and then, the trend decreased in the western region, although the value was higher than that in the eastern region. The discharge presented significant periods of 2.7–5.4 years and increased from east to west. Significant periodicity indicated that the discharge in the different watersheds exhibited obviously different patterns. The GMB losses were larger in south and east than in north. The large glaciers had more stable interannual variations in discharge, and large fluctuations in discharge will be observed as the glacier areas shrink. Precipitation was the dominant factor for discharge during the study period, although the influence of increasing temperatures on hydrological regimes should not be neglected in the long term. Systematic differences in discharge and the GMB in glacierized watersheds in response to climate change are apparent in the Tianshan Mountains.  相似文献   

16.
17.
Abstract

Two topographically similar adjacent catchments near Johannesburg, South Africa, one suburban, the other natural grassland, were monitored over a five year period to detect differences in runoff and hydrological balance. A network of raingauges, boreholes, flow gauges and water meters was installed. Evapotranspiration was modelled using observed weather data. Groundwater was estimated from tracer and other borehole tests. Surface runoff from the undeveloped and suburban catchments was 4% and 15% of rainfall respectively. Evapotranspiration was 63% of rainfall for both catchments. Sewage outflow was 83% of water consumption for the suburban catchment. Little change in water table level occurred in the suburban catchment, and garden watering probably balanced the high evaporation. Piped water supply was 16% of the precipitation on the catchment.  相似文献   

18.
Soil degradation, including rocky desertification,of the karst regions in China is severe. Karst landscapes are especially sensitive to soil degradation as carbonate rocks are nutrient-poor and easily eroded. Understanding the balance between soil formation and soil erosion is critical for long-term soil sustainability, yet little is known about the initial soil forming processes on karst terrain. Herein we examine the initial weathering processes of several types of carbonate bedrock containing varying amounts of non-carbonate minerals in the SPECTRA Critical Zone Observatory, Guizhou Province, Southwest China. We compared the weathering mechanisms of the bedrock to the mass transfer of mineral nutrients in a soil profile developed on these rocks and found that soil formation and nutrient contents are strongly dependent upon the weathering of interbedded layers of more silicate-rich bedrock(marls). Atmospheric inputs from dust were also detected.  相似文献   

19.

利用MOD10A1和MYD10A1冰雪反照率数据, 分析了大高加索山脉地区加拉巴西冰川和德扬库特冰川的反照率时空分布特征, 并使用五种反照率聚合方法, 对这两条冰川2002—2019年夏季反照率与物质平衡关系开展相关性研究.结果表明, 加拉巴西冰川和德扬库特冰川反照率随年份增加而明显减小, 两条冰川在夏季都出现了最低反照率, 加拉巴西冰川在冬季出现最高反照率, 而德扬库特冰川则出现在春季; 加拉巴西冰川夏季高海拔和低海拔区域的反照率差异较德扬库特冰川更为明显; 两条冰川夏季反照率均与夏季物质平衡表现出一定的正相关性, 其中加拉巴西冰川的相关性更加显著, 使用平均最小反照率方法时两者相关系数最大可达0.874(p<0.05), 德扬库特冰川使用加权平均反照率方法时两者相关系数最大为0.765(p<0.05).德扬库特冰川反照率与物质平衡相关性较低的原因可能是坡向和低海拔导致了其更易受暖湿气流影响, 冰川消融中短波辐射能占比较低, 反照率对其消融的影响小.

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20.
We present a field‐data rich modelling analysis to reconstruct the climatic forcing, glacier response, and runoff generation from a high‐elevation catchment in central Chile over the period 2000–2015 to provide insights into the differing contributions of debris‐covered and debris‐free glaciers under current and future changing climatic conditions. Model simulations with the physically based glacio‐hydrological model TOPKAPI‐ETH reveal a period of neutral or slightly positive mass balance between 2000 and 2010, followed by a transition to increasingly large annual mass losses, associated with a recent mega drought. Mass losses commence earlier, and are more severe, for a heavily debris‐covered glacier, most likely due to its strong dependence on snow avalanche accumulation, which has declined in recent years. Catchment runoff shows a marked decreasing trend over the study period, but with high interannual variability directly linked to winter snow accumulation, and high contribution from ice melt in dry periods and drought conditions. The study demonstrates the importance of incorporating local‐scale processes such as snow avalanche accumulation and spatially variable debris thickness, in understanding the responses of different glacier types to climate change. We highlight the increased dependency of runoff from high Andean catchments on the diminishing resource of glacier ice during dry years.  相似文献   

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