Temporal and spatial variations in the discharge and dissolved organic carbon of drip waters in Beijing Shihua Cave,China

To detect the causal relationship between cave drip waters and stalagmite laminae, which have been used as a climate change proxy, three drip sites in Beijing Shihua Cave were monitored for discharge and dissolved organic carbon (DOC). Drip discharges and DOC were determined at 0 to 14‐day intervals over the period 2004–2006. Drip discharges show two types of response to surface precipitation variations: (1) a rapid response; and (2) a time‐lagged response. Intra‐annual variability in drip discharge is significantly higher than inter‐annual variability. The content of DOC in all drip waters varies inter‐ and intra‐annually and has good correlation with drip water discharge at the rapid response sites. High DOC was observed in July and August in the three years observed. The flushing of soil organic matter is dependent upon the intensity of rain events. The DOC content of drip water increases sharply above a threshold rainfall intensity (>50 mm d^?1) and shows several pulses corresponding with intense rain events (>25 mm d^?1). The DOC content was lower and less variable during the dry period than during the rainy period. The shape of DOC peak also varies from year to year as it is influenced by the intensity and frequency of rainfall. The different drip sites show marked differences in DOC response, which are dominated by hydrological behaviour linked to the recharge of the soil and karst micro‐fissure/porosity network. The results explain why not all stalagmite laminae are consistent with climate changes and suggest that the structure of the rainy season events could be preserved in speleothems. Copyright © 2008 John Wiley & Sons, Ltd.     

Counting chronology and climate records with about 1000 annual layers of a Holocene stalagmite from the Water Cave in Liaoning Province, Chinaannual layers of a Holocene stalagmite from the Water Cave in Liaoning Province, China

One active stalagmite from the Water Cave in Liaoning Province contains growth layers of three sizes. Based on thermal ionization mass spectrometry ²³⁰Th dating, we found that middle size layers are annual layers, with each middle layer consisting of one narrow dark layer and a wide bright layer. The small layers within middle layers are sub-annual layers and the large layers are multi-year layers. Based on the layer-counting method, we established a high-resolution time scale for layer thickness. Our results reveal two dramatic century-scale climate cycles over the past 1000 years in this region.     

Grey characteristics of microbanding of stalagmite in Shihua Cave, Beijing and its climatic signification(I)

Grey microstructure of microbanding in thin sections of stalagmite T9501 from Shihua Cave, Beijing was studied. The types of grey and the morphologic features of organic material were classified. The signification of microbanding and annual layer was discussed. The standard distinguishing the false annual layer and the multi-year layer is set up, which provides the theoretic fundaments for paleoclimatic study. Project supported by the National Natural Science Foundation of China (Grant No. 49672134).     

Seasonal isotopic variability of precipitation and cave drip water at Indian Oven Cave,New York

A major assumption in palaeoclimatic studies using speleothems is that cave‐seepage waters are homogenized as they pass through the bedrock, so that they record the average annual isotopic signal of precipitation. A year‐long study during 2001–02 was conducted at Indian Oven Cave in eastern New York State, USA, to investigate how cave‐seepage water isotopic signals relate to those of precipitation. Samples were collected biweekly and analysed for stable isotopes of oxygen and hydrogen. Our study shows that, for this cave, homogenization did not occur, as seepage waters had the same seasonal variability as precipitation. However, mean seepage water isotopic values were very close to those of the mean values for precipitation. Rapid flow‐through times of seepage water show that the speleothems can record climate conditions above the cave contemporaneously. At one location, flow ceased during the winter; therefore, isotopes measured in cave drip waters reflected only the enriched summer isotopes. Under certain circumstances, the analysis of calcite sampled from those drip waters may then lead to a false conclusion of a warming during that period, instead of the fact that it was merely a drier winter period. Copyright © 2005 John Wiley & Sons, Ltd.     

Characteristics of annual laminae gray level variations in a stalagmite from Shihua Cave, Beijing and its climatic significance (II)

The annual laminae gray level variations in the stalagmite TS9501 of Shihua Cave, Beijing are studied in detail. The environmental factors influencing the laminae gray level are also analyzed. The following conditions may be necessary to the study on the lamina gray level. A) The seasonal differences of climate in the studied area are strong. B) The cave has a rapid and simple hydrological connection with the surface, such that the gray level variation is great; therefore, climatic changes can be more clearly recorded in a stalagmite. C) No water from other sources due to lateral flow adds to the seepage over the cave. D) There are more organic impurities than inorganic ones, whose content changes distinctly with time in the sample. By comparison with the modern instrumental climate records, it was found that the gray level of laminae is mainly related to the air temperature, especially the summer mean temperature. Therefore, the gray level can be used as a proxy of the air temperature. The variation of the lamina gray level also represents the oscillation of Indian summer monsoon as identified in the modern climate records. The variability of the temperature in Beijing area over the last 1 ka is reconstructed. The results show that there are several cold periods corresponding to historical records. An important phenomenon is noticed that the climatic pattern before about 1400AD is different from that after about 1400AD. In Beijing area, before about 1400AD, low amplitude and high frequency temperature oscillations dominated the signal. The climate pattern is warm-dry and cold-wet. After about 1400AD, both the temperature and rainfall varied synchronously, temperature oscillated strongly and the Little Ice Age occurred. The climate pattern is cold-dry and warm-wet. This transition of the climate pattern is also observed in other worldwide paleoclimatic records, demonstrating that there was a global climate event at about 1400AD.     

Counting chronology and climate records with about 1000 annual layers of a Holocene stalagmite from the Water Cave in Liaoning Province, China

One active stalagmite from the Water Cave in Liaoning Province contains growth layers of three sizes. Based on thermal ionization mass spectrometry 230Th dating, we found that middle size layers are annual layers, with each middle layer consisting of one narrow dark layer and a wide bright layer. The small layers within middle layers are sub-annual layers and the large layers are multi-year layers. Based on the layer-counting method, we established a high-resolution time scale for layer thickness. Our results reveal two dramatic century-scale climate cycles over the past 1000 years in this region.     

Precise dating of abrupt shifts in the Asian Monsoon during the last deglaciation based on stalagmite data from Yamen Cave, Guizhou Province, China

Based on 33 U/Th dates and 1020 oxygen isotopic data from stalagmite Y1 from Yamen Cave, Guizhou Province, China, a record of the Asian Summer Monsoon (ASM) was established. The record covers the last deglaciation and the early Holocene (from 16.2 to 7.3 ka BP) with an average oxygen isotope resolution of 9 years. The main millennial-scale deglacial events first identified in Greenland (Greenland Interstadial Events: GIS 1e through GIS 1a) and later in China are clearly present in the Y1 record. By analogy to earlier work, we refer to these as Chinese Interstadials (CIS): CIS A.1e to CIS A.1a. The onset of these events in Y1 δ18O records are nominally dated at: 14750±50, 14100±60, 13870±80, 13370±80, and 12990±80 a BP. The end of CIS A.1a or the beginning of the Younger Dryas (YD) event is nominally at 12850±50 a BP and the end of the YD dates to 11500±40 a BP. The δ18O values shift by close to 3‰ during the transition into the Bφlling-Allerφd (BA, the onset of CIS A.1e) and at the end of the YD. Comparisons of Y1 to previously published early Holocene records show no significant phase differences. Thus, the East Asia Monsoon and the Indian Monsoon do not appear to have been out of phase during this interval. The Y1 record confirms earlier work that suggested that solar insolation and North Atlantic climate both affect the Asian Monsoon.     

Geochemical characterization of soil organic matter and variability of a postglacial detrital organic supply (chaillexon lake,france)

Geochemical analysis of sedimentary organic matter in recent lacustrine sediments appears to be a useful tool in providing information concerning past environmental conditions. However, such analysis is often made without knowing the geochemical characteristics of the organic matter derived from the watershed and, more explicitly, its soils. The present work deals with (i) a geochemical investigation (Rock-Eval pyrolysis) of soil organic matter sampled in a lake watershed, and (ii) the study of the sedimentary organic matter trapped in the lake deposits. The research was conducted on Chaillexon Lake which was created by a rock collapse that dammed the palaeovalley of the Doubs River about 12 000 years ago. Since this event, the sediment trap provides a continuous palaeoclimatic record for the Postglacial period. Results obtained lead to two main conclusions. First, the variability of Rock-Eval pyrolysis values observed in soils modifies the common interpretation given to these parameters in the characterization of sedimentary organic matter. Indeed, variations in these parameters point not only to varying proportions of terrestrial and lacustrine organic matter in a lacustrine infilling but also to variations of the terrestrial supply linked with the evolution of vegetal cover in the catchment. The second conclusion is that the story of the Chaillexon lacustrine system is marked by a rather sudden soil and forest development at the Preboreal–Boreal transition (9000 BP ). Copyright © 1998 John Wiley & Sons, Ltd.     

Integrated cave drip monitoring for epikarst recharge estimation in a dry Mediterranean area,Sif Cave,Israel

Understanding recharge mechanisms and controls in karst regions is extremely important for managing water resources because of the dynamic nature of the system. The objective of this study was to evaluate water percolation through epikarst by monitoring water flow into a cave and conducting artificial irrigation and tracer experiments, at Sif Cave in Wadi Sussi, Israel from 2005 through 2007. The research is based on continuous high‐resolution direct measurements of both rainfall and water percolation in the cave chamber collected by three large PVC sheets which integrate drips from three different areas (17, 46, and 52 m²). Barrels equipped with pressure transducers record drip rate and volume for each of the three areas. The combined measured rainfall and cave data enables estimation of recharge into the epikarst and to better understand the relationship of rainfall‐recharge. Three distinct types of flow regimes were identified: (1) ‘Quick flow’ through preferential flow paths (large fractures and conduits); (2) ‘Intermediate flow’ through a secondary crack system; and (3) ‘Slow flow’ through the matrix. A threshold of ～100 mm of rain at the beginning of the rainy season is required to increase soil water content allowing later rainfall events to percolate deeper through the soil and to initiate dripping in the cave. During winter, as the soil water content rises, the lag time between a rain event and cave drip response decreases. Annual recharge (140–160 mm in different areas in the cave) measured represents 30–35% of annual rainfall (460 mm). Copyright © 2011 John Wiley & Sons, Ltd.     

Precise dating of East-Asian-Monsoon D/O events during 95―56 ka BP: Based on stalagmite data from Shanbao Cave at Shennongjia, China

Based on 23 U/Th analyses and 532 oxygen isotopic data, an averaged 80-a stalagmite oxygen isotopic composition series was established through 95 to 56 thousand years before present (ka BP) from two speleothems in Shanbao Cave, Shennongjia, central China. Shanbao Cave record (referred to as SB record) replicates well with Hulu Cave record, extending the characteristics of millennial oscillations in East-Asian-Summer-Monsoon (EASM) to the past 95 ka. The trend of the SB record generally follows mid-July solar insolation at 65°N, suggesting that mid-high northern latitude insolation, in the first order, controls changes of EASM intensity. Millennial oscillations of EASM recorded in the stalagmites are well related to the Greenland interstadials referred to as Dansgaard/Oeschger (D/O) events from 1 to 22, indicating that rapid ocean-atmosphere reorganization in North Atlantic has a remote effect in EASM. The well-dated D/O events by stalagmites probably provide an absolute calibration for chronologies of Greenland ice cores. The timings of D/O events in the SB record are different variously from those in Greenland ice cores. For D/O 19 and 20, the age offsets between the stalagmites' and the Greenland ice cores' record are significant, larger than the uncertainties of uranium-series dating. The two events in the SB record are younger than those in North GRIP time scale by 1―2 ka, and older than the counterparts in GISP2 by approximately 3―4 ka. A comparison between the SB and Brazil stalagmite record shows an anti-phase relation in millennial-scale monsoon precipitation between the two localities. This supports a mode for the coupled ocean-atmosphere "See-saw".     

High-resolution climate variability of southwest China during 57-70 ka reflected in a stalagmite δ18O record from Xinya Cave

A 26-cm-long stalagmite (XY2) from Xinya Cave in northeastern Chongqing of China has been ICP-MS 230Th/U dated, showing a depositional hiatus at 2.3 cm depth from the top. The growth of the 2.3-26 cm interval determined by four dates was between 57 ka and 70 ka, with a linear growth rate of 0.023 mm/a.We have analyzed 190 samples for δ18O and δ13C, mostly in the 2.3-26 cm part. The δ18O and δ13C values between 57 ka and 70 ka reveal decadal-to-centennial climatic variability during the glacial interval of Marine Isotope Stage 4 (MIS4), exhibiting much higher resolution than that of the published Hulu and Dongge records during this interval. Speleothem δ18O in eastern China, including our study area can be used as a proxy of summer monsoon strength, with lighter values pointing to stronger summer monsoon and higher precipitation, and vice versa. Two decreases in the δ18O signature of XY2 record around 59.5 and 64.5 Ka are argued to correspond to the Dansgaard-Oeschger (D-O) events 17 and 18 respectively. The Heinrich event 6 (H6) can be identified in the record as a heavy δ18O peak around 60 ka, indicating significant weakening of the monsoon in Chongqing during the cold period.The XY2 δ18O record shows very rapid change toward to the interstadial condition of the D-O event, but more gradual change toward to the cold stadial condition. This phenomenon found in the Greenland ice core records is rarely observed so clearly in previously published speleothem records. According to SPECMAP δ18O record, the glacial maximum of MIS 4 was around 64.5 ka with the boundary of MIS 3/4 around 60 ka. Unlike the marine record, the speleothem record of XY2, China, exhibits much high frequency variations without an apparent glacial maximum during MIS 4. However, the timing of MIS 3/4 boundary seems to be around 60 ka when the H6 terminated, in agreement with the marine chronology.The growth period of sample XY2 during glacial times probably reflects a local karstic routing of water,rather than having climatic significance.     

Seasonal variability in organic substances in surface and cave waters at Marengo Cave,Indiana

Water samples from forest soils and a shallow cave underlying them were collected for the hydrological year 1996–1997. The soil waters did not display much seasonal variability in concentrations of organic substances in them but the cave waters yielded distinct highest levels in the spring and autumn seasons. The important controls on the amount of organic substances reaching the cave are the seasonal fluctuation in volume of the percolation waters and the soil's ability to provide organic material for these waters. Fluorescence studies of the organic compounds isolated from these waters revealed shorter peak excitation and emission wavelengths for the cave waters than for the soil waters, a result of both differences in concentration and probably also of significant change in the proportional organic assemblages in the waters. Precipitation appears to affect the fluorescence in both waters, with the dry autumn producing the highest yields. Molecular size fractionation revealed how the larger hydrophobic compounds are preferentially removed from the water before it reaches the cave, with the consequence that the smaller hydrophilic compounds become the dominant fluorophore there. Copyright © 2000 John Wiley & Sons, Ltd.     

Epikarst hydrology and implications for stalagmite capture of climate changes at Grotta di Ernesto (NE Italy): results from long‐term monitoring

Grotta di Ernesto is a cave site well suited for palaeoclimate studies because it contains annually laminated stalagmites and was monitored from 1995 to the end of 2008 for microclimate, hydrology and hydrochemistry. Long‐term monitoring highlighted that cave drips show three different hydrological responses to rainfall and infiltration: (1) fast seasonal drips in the upper part of the cave, which are mostly fed by fractures, (2) slow seasonal drips, located at mid‐depth in the cave characterized by mixed feeding and (3) slow drips, mostly located in the deeper gallery, which are fed by seepage flow from bulk porosity with a minor fracture‐fed component. The slow drips display daily cycles during spring thaw. Monitoring also indicated that drip waters are only slightly modified by degassing within the soil zone and aquifer and by prior calcite precipitation. Hydrochemical studies show a clear seasonality in calcite saturation index, which results in most cave calcite precipitation occurring during late autumn and winter with similar amounts of precipitated calcite on most stalagmites, regardless of drip rate (discharge) differences. Drip rate, and drip rate variability, therefore, has a minor role in modulating the amount of annual calcite formation. In contrast, drip rate, when associated with moderate reduction in calcite saturation index, clearly influences stalagmite morphology. Increasing drip rate yields a passage from candle‐, to cone‐ to dome‐shaped stalagmites. Very high drip rates feed speleothems with flowstone morphology. In summary, monitoring provides information about the karst aquifer and how hydrology influences those physical and chemical characteristics of speleothems which are commonly used as climate proxies. Copyright © 2010 John Wiley & Sons, Ltd.     

Continuous fluorescence assessment of organic matter variability on the Bournbrook River,Birmingham, UK

Continuous monitoring of dissolved organic matter (DOM) character and concentration at hourly resolution is rare, despite the importance of analysing organic matter variability at high‐temporal resolution to evaluate river carbon budgeting, river water health by detecting episodic pollution and to determine short‐term variations in chemical and ecological function. The authors report a 2‐week experiment performed on DOM sampled from Bournbrook, Birmingham, UK, an urban river for which spectrophotometric (fluorescence, absorbance), physiochemical (dissolved organic carbon [DOC], electrical conductivity, pH) and isotopic (D/H) parameters have been measured at hourly frequency. Our results show that the river had sub‐daily variations in both organic matter concentration and characteristics. In particular, after relatively high‐magnitude precipitation events, organic carbon concentration increased, with an associated increase in intensity of both humic‐like and tryptophan‐like fluorescence. D/H isotopic ratio demonstrates different hydrological responses to different rainfall events, and organic matter character reflects this difference. Events with precipitation < 2 mm typically yielded isotopically heavy water with relatively hydrophilic DOM and relatively low specific absorbance. Events with precipitation > 2 mm had isotopically lighter water with higher specific absorbance and a decrease in the proportion of microbially derived to humic‐like fluorescence. In our heavily urbanized catchment, we interpret these signals as one where riverine DOM is dominated by storm sewer‐derived ‘old’ organic matter at low‐rainfall amounts and a mixed signal at high‐precipitation amounts where ‘event’ surface runoff‐derived organic matter dominate during storm sewer and combined sewer overflow routed DOM. Copyright © 2009 John Wiley & Sons, Ltd.     

Relationships among dissolved organic matter,iron, and discharge in a moorland stream

Dissolved organic matter (DOM) and iron in a moorland stream were determined at 8-hour intervals over a 6-month period to examine relationships with streamflow. Regression of both solutes on discharge were positive and explained 50–70 per cent of the variance in the solute data, but better predictions were obtained in both cases when a covariate reflecting temporal variation in the relationships was introduced (explained variance 80–90 per cent). Variations in the regression of Fe on DOM were also identified, indicating differences in the complexing power of DOM for Fe and possible variations in the chemical composition of the DOM.     

Changes in hydrological regime caused by human intervention in karst: the case of the Rumin Springs

ABSTRACT

Any human intervention or action in karst terrains can unexpectedly, suddenly, strongly and, generally, dangerously change a local and/or a regional hydrological regime. A characteristic example of the Dinaric karst is given in this paper. The operation of two reservoirs in Livanjsko Polje at an altitude of about 702 m above sea level (m a.s.l.) and hydro-electric development of the Cetina River system started in 1973. This year marked a drastic and instantaneous change in the regional hydrological regime. A significant drop in the minimum, mean and maximum annual discharges of two neighbouring karst springs, Rumin Mali and Rumin Veliki, was caused by this anthropogenic construction. The exits of the two analysed karst springs, Rumin Mali and Veliki, are located at altitudes of about 326.8 m a.s.l. and 307.6 m a.s.l. respectively. The areal distance between them is 640 m. Their hydrological regimes have been altered in different ways. The drop in discharges is stronger for the Rumin Veliki than for the Rumin Mali. The analysis shows that the system development influenced the redistribution of the regional karst aquifer and, in this manner, contributed to the reduction of both karst springs’ recharge areas.

Editor D. Koutsoyiannis Associate editor E. Rozos     

Hydrology of cave drip waters at varying bedrock depths from a karst system in southeastern Australia

The study of how cave drip‐water discharge responds to recharge events is fundamental to evaluating the potential of actively forming speleothems as high‐resolution climate archives. Most previous research has focused on caves of the Northern Hemisphere middle latitudes, where recharge is strongly seasonal. Few studies have explored drip‐water behaviour from regions where the expected seasonal rainfall pattern is significantly perturbed on an irregular basis by changing regional atmospheric circulation patterns. Here, we report the results of a 4‐year study of cave drip‐water–climate relationships from two caves in eastern Australia. The discharge of 10 drip sites located beneath bedrock thicknesses of 12, 22 and 45 m was monitored either continuously (using automated infrared sensors) or at discrete approximately monthly intervals and compared with local rainfall and water balance data. The study period traversed two major droughts, including the severe 2002–2003 El Niño. Drips at 12 and 22 m depths responded almost simultaneously to individual recharge events, although the time lag between individual events varied according to the volume of recharge and pre‐event storage. Overall, a steady decline in discharge is evident through the moisture‐deficit period, with increased flows through phases of positive water balance. Speleothems growing at these and similar shallow‐chamber sites have potential for reconstructing palaeo‐rainfall trends at high‐resolution, although the highly variable nature of year‐to‐year recharge would make it difficult to obtain data on a calendrical time‐scale. Drips at 45 m depth did not respond consistently to individual recharge events and displayed hydrological behaviour markedly dissimilar to one another and to the near‐surface drip sites, indicating great complexity in karst architecture and the absence of fissure flow. Although speleothems at this depth may well preserve information on longer‐term rainfall trends, their potential to encode a palaeo‐rainfall variability signal at interannual resolution is poor. Copyright © 2007 John Wiley & Sons, Ltd.     

Application of multivariate analysis to suspended matter particle size distribution in a karst aquifer

Numerous quantitative and qualitative variables control suspended sediment dynamics in karst systems. The objective of this study was to identify the hydrodynamic variables controlling the transport properties of particles in a karst aquifer (western Paris basin). The particle size distribution of suspended sediment infiltrating via a swallow hole was compared to that in discharge from a spring, allowing identification of the particle transport properties of the karst system. Hill and Smith analysis, a type of multivariate analysis that allows joint examination of quantitative and qualitative variables, was used to identify the hydrodynamic parameters controlling the transport properties of the suspended matter. The results demonstrate that the particle size distribution discharging at the karst spring is controlled by spring discharge and the hydraulic gradient of the system. The hydraulic gradient is defined by the piezometric level and the stage of the Seine River, which is in turn controlled by the tide. This study illustrates the use of Hill and Smith analysis to identify those variables which control suspended sediment transport. It also illustrates the application of this analysis to identify boundary conditions and evaluate variables which control the behaviour of the hydrologic system. Copyright © 2007 John Wiley & Sons, Ltd.