太湖梅梁湾沉积物-水界面氮迁移特征初步研究

用乙炔为抑制剂,气相色谱法测定了１９９７年夏季太湖梅梁湾口沉积物－水界面的反硝化率和Ｎ２Ｏ的自然排放率,太湖梅梁湾沉积物的反硝化率为１．４－５．６μｍｏｌＮ２／（ｍ＾２．ｈ）,Ｎ２Ｏ的复原斐和率为０．０８－０．６６μｍｏｌＮ２／（ｍ＾２．ｈ）,探讨了沉积物－水界面ＮＯ＾－３的交换动态。指出沉积物内硝化－反硝化作用是太湖湖泊生态系统氮循环过程中一个重要的环节。在湖泊水土界面氮交换中,沉积物是具有吸收     

Seasonal variation of polychlorinated biphenyl concentrations in the southern part of the Baltic Sea

The impact of seasonal fluctuations in forcing factors such as atmospheric concentration, temperature, and biological productivity on the concentration of polychlorinated biphenyls (PCBs) in the surface water of the southern part of the Baltic Sea was investigated. Water samples were collected on eight cruises over 2 years. A clear seasonal variability in dissolved PCB concentrations was observed with higher levels in summer than in winter and spring. This was attributed to changes in atmospheric concentrations and water temperature, based on measurements showing the PCB levels in the atmosphere and surface water to be close to a partitioning equilibrium. Concentrations in the suspended particulate material (SPM) fraction were also variable, and when the quotient of the organic carbon normalised concentration in SPM and the dissolved concentration was calculated (i.e., the bioaccumulation factor (BAF)), a seasonal pattern was observed which was consistent with kinetic limitations on partitioning into particles caused by plankton growth. However, seasonal variability in the partitioning properties of the SPM may also contribute to this variability.     

Comparative performances of eggs and embryos of sea urchin (Paracentrotus lividus) in toxicity bioassays used for assessment of marine sediment quality

The potential toxicity of sediments from various ports was assessed by means of two different liquid-phase toxicity bioassays (acute and chronic) with embryos and eggs of sea urchin Paracentrotus lividus. Performances of embryos and eggs of P. lividus in these bioassays were compared for their interchangeable applicability in integrated sediment quality assessment. The obtained endpoints (percentages of normally developed plutei and fertilized eggs) were linked to physical and chemical properties of sediments and demonstrated dependence on sediment contamination. The endpoints in the two bioassays were strongly correlated and generally exhibited similar tendency throughout the samples. Therein, embryos demonstrated higher sensitivity to elutriate exposure, compared to eggs. It was concluded that these tests could be used interchangeably for testing toxicity of marine sediments. Preferential use of any of the bioassays can be determined by the discriminatory capacity of the test or vulnerability consideration of the test subject to the surrounding conditions.     

南海蒸发和净淡水通量的季节和年际变化

以19年（1988～2006年）的SSM/I（Special Sensor Microwave/ Imager）卫星观测为基础,计算了南海的逐月海面蒸发量,并结合SSM/I的降雨观测,得到了南海的逐月净淡水通量,并分析其季节和年际变化.研究结果表明：南海的蒸发量年变化基本呈双峰型结构,降雨和净淡水通量呈单峰型结构.1988～2001年,南海的蒸发量呈上升趋势,增长速率为1 mm/yr;2001～2006年,以1.9 mm/yr的速率减少.南海的降雨量和净淡水通量与Nino3指数成负相关,相关系数为-0.62和-0.58.在1997～1998厄尔尼诺暖事件期间,降雨量和净淡水通量均显著下降,且以其为界,降雨量在此之前以1.3 mm/yr的速率增长,净淡水通量升降趋势不明显;而在此之后,降雨以8.5 mm/yr的速率下降,净淡水通量的下降速率为7.5 mm/yr.     

Studies on turbulent diffusion processes and evaluation of diffusivity values from hydrodynamic observations in Corpus Christi Bay

The physical process of dispersion which can be attributed to turbulence (turbulent diffusion) or shear (shear-augmented diffusion) within the flow field is very important as it ultimately governs the distribution of constituents of interest within the environment. A series of diffusion experiments were conducted in Corpus Christi Bay, TX with the purpose of characterizing turbulent diffusion through dispersion coefficients or turbulent diffusivity, K_i (i=x, y, z) dependent on the degree of randomness or turbulence intensity, I.Measured with a boat-mounted acoustic doppler current profiler (ADCP), the Eulerian velocity time-series of fluid particles in random motion, u_i was used in the evaluation of the Eulerian time-scale of turbulence, T^E based on the velocity correlation function, R^E with T^E being related to the Lagrangian time-scale T^L through a scaling parameter, β(=T^L/T^E). Surface currents were obtained with high frequency (HF) Radar equipment deployed over the study area from which the horizontal velocity gradients were determined.Within the spatial scale of the experiment (1000 m), the observed low horizontal gradients (10⁻⁴ s⁻¹) allowed for the generation of velocity time-series from an ADCP mounted on a moving platform. A numerical scheme for evaluating turbulent diffusivity values was developed on the basis of Eulerian current measurements and calibrated through the statistics of an evolving dye patch for the scaling parameter β which in this scheme was found to be in the range 1–3.     

北京地区上空OH转动温度的季节性变化

在北京东北方向的兴隆天文台,自主搭建的大气辐射观测仪器对OH夜气辉从2011年12月开始进行观测.利用高分辨率的OH(8-3)带的振转光谱计算了转动温度,并与TIMED/SABER探测的温度进行了比较.观测表明,两年(2012—2013)的OH(8-3)带转动温度平均值为203.0±11.2 K,有明显的季节变化,冬季高,夏季低,温差可达60 K.与SABER观测温度的季节变化一致.对日平均的转动温度进行年振荡和半年振荡分量的拟合分析表明,年振荡强度(10.8 K)远大于半年振荡(2.7 K).研究还发现,不同夜晚转动温度变化形态差别很大,既有很强的潮汐控制的波动,又有相对短周期的波动.     

Seasonal variation in the behavior of tailing wastes in Buyat Bay, Indonesia

Seasonal variations in temperature, salinity, sigma-t and light transmittance were investigated in Buyat Bay, Indonesia, related to the dumping activity there. More than 2000 tons per day of tailings were disposed through a Submarine Tailing Disposal (STD) method at 82 m depth in Buyat Bay. An 80 m depth of the assumed pycnocline was not well confirmed. The seasonal variability of temperature, salinity and sigma-t showed the pycnocline of 40 m to 135 m at the deepest observation station (140 m) during 1997. Furthermore, the Mixed Layer Depth was in good agreement with the wind stress, and the wind stress affected the spreading of tailings there. The outlet of submarine tailing disposal must be below 135 m in Buyat Bay.     

Impact of environmental variables on spatial and seasonal internal phosphorus loading in a mesoeutrophic lake

Strzeszynskie Lake was formerly a slightly eutrophic (meso-eutrophic) water body. The aim of the current research was to define variables on both spatial and seasonal internal phosphorus loading from bottom sediments at five stations located in zones varying in depth, oxygenation, macrophyte presence, and uses of the neighboring catchment area. Ex situ experiments done with the use of intact bottom sediment cores have shown that the highest phosphorus release occurred in the deepest part of the lake and reached 3.6?mg?P/m²d under anoxic conditions during summer thermal stratification. In turn, the internal loading from littoral sediments, which were well aerated all year round, was clearly lower. Furthermore, phosphorus accumulation in the bottom sediment was observed to reach a maximum of 1.45?mg?P/m² d in autumn. A comparison of the internal loading intensity in lake zones with different land uses of the neighboring catchment area has shown slightly higher values at stations adjacent to the forest catchment area than those used for recreation. Changes in the land use of the catchment area of Strzeszynskie Lake, especially the increase in impermeable surfaces, have led to an increased inflow of external loads after heavy rains, resulting in deterioration in water quality and a delayed increase in internal loading.     

Seasonal variation in the transverse and layered structure of estuarine circulation in Ariake Bay, Japan

Seasonal variation in the transverse and layered structure of estuarine circulation in Ariake Bay, Japan was investigated by box model analysis using monthly salinity data from 1990 to 2000. Two-layered gravitational estuarine circulation was intensified from autumn to spring (vertically well mixed season) accompanied by a small river discharge. Two-layered circulation was weakened accompanying the transversely segregated cyclonic circulation in the upper layer during summer (stratified season) with a large river discharge. Such seasonal variation in the transverse and layered structure of estuarine circulation is because the bay width of Ariake Bay (20 km) is narrower than the external Rossby deformation radius (235 km) but wider than the internal Rossby deformation radius (3–5 km).     

Seasonal variation of fluxes and distributions of dissolved methane in the North Yellow Sea

The concentrations and sea-to-air fluxes of dissolved methane (CH₄) were investigated in the North Yellow Sea during August 2006, January, April and October 2007. Dissolved CH₄ concentrations showed obvious seasonal variation, with maximum values occurring in summer and lowest values occurring in winter. The saturations of dissolved CH₄ in surface waters ranged from 78.7% to 1679.7% with an average of 252.4%. The estimated atmospheric CH₄ fluxes using the Liss and Merlivat (LM86), and Wanninkhof formulae (W92) were (4.2±4.7), (11.6±10.3), (8.5±12.7) and (0.2±1.0), and (6.9±7.3), (14.6±22.3), (13.8±14.3) and (0.4±1.7) μmol·(m² d)⁻¹, respectively, for spring, summer, autumn and winter. Based on the average annual atmospheric CH₄ flux and the area of the North Yellow Sea, the annual CH₄ emission was estimated to be (2.4×10⁻²–4.2×10⁻²) Tg a⁻¹, which suggests that the North Yellow Sea was a net source of atmospheric CH₄.     

Seasonal and interannual variation of the phytoplankton and copepod dynamics in Liverpool Bay

The seasonal and interannual variability in the phytoplankton community in Liverpool Bay between 2003 and 2009 has been examined using results from high frequency, in situ measurements combined with discrete samples collected at one location in the bay. The spring phytoplankton bloom (up to 29.4 mg chlorophyll m⁻³) is an annual feature at the study site and its timing may vary by up to 50 days between years. The variability in the underwater light climate and turbulent mixing are identified as key factors controlling the timing of phytoplankton blooms. Modelled average annual gross and net production are estimated to be 223 and 56 g C m⁻² year⁻¹, respectively. Light microscope counts showed that the phytoplankton community is dominated by diatoms, with dinoflagellates appearing annually for short periods of time between July and October. The zooplankton community at the study site is dominated by copepods and use of a fine mesh (80 μm) resulted in higher abundances of copepods determined (up to 2.5 × 10⁶ ind. m⁻²) than has previously reported for this location. There is a strong seasonal cycle in copepod biomass and copepods greater than 270 μm contribute less than 10% of the total biomass. Seasonal trends in copepod biomass lag those in the phytoplankton community with a delay of 3 to 4 months between the maximum phytoplankton biomass and the maximum copepod biomass. Grazing by copepods exceeds net primary production at the site and indicates that an additional advective supply of carbon is required to support the copepod community.     

Seasonal variation of the total electron content, maximum electron density and equivalent slab thickness at a South-American station

Total electron content (TEC) and foF2 ionosonde data obtained at Tucumán (26.9°S; 65.4°W) from April 1982 to March 1983 (high solar activity period) are analyzed to show the seasonal variation of TEC, NmF2 (proportional to square of foF2) and the equivalent slab thickness EST. Bimonthly averages of the monthly median for January–February, April–May, July–August and October–November have been considered to represent summer, autumn, winter and spring seasons, respectively. The results show that the higher values of TEC and maximum electron density of F2-layer NmF2 are observed during the equinoxes (semiannual anomaly). During daytime, both in TEC and in NmF2 the seasonal or winter anomaly can be seen. At nighttime, this effect is not observed. Also, the observed NmF2 values are used to check the validity of International Reference Ionosphere (IRI) to predict the seasonal variability of this parameter. In general, it is found that averaged monthly medians (obtained with the IRI model) overestimate averaged monthly median data for some hours of the day and underestimate for the other hours.     

华南近海台风突然增强的初秋季节锁相

使用美国台风联合中心(JTWC)的最佳路径资料对近50年(1961—2010年)海南岛至台湾岛之间的华南近海台风路径和强度做统计分析,得到台风增强的季节锁相时段.经过大气变量的物理分解,海陆分布热力强迫的季节风场揭示出:盛夏时节,东亚副热带季风槽位于沿江江南,华南近海盛行西南季风;中秋时节,东亚副热带季风槽南退到南海中部,对华南近海台风的增强没有影响;在夏末秋初的转换季节,东亚副热带季风槽正好位于华南近海,有些台风进入华南近海季风槽中就有可能增强,形成所谓的季节锁相.     

Distribution and sources of organochlorinated contaminants in sediments from Izmir Bay (Eastern Aegean Sea)

Eighteen surface sediment samples representative of the entire Izmir Bay were analyzed for organochlorine pesticides (OCPs) and polychlorinated biphenyls (PCBs). This was in order to provide extensive information concerning the recent deposition of these compounds in this area, together with levels, distribution, possible sources and potential biological risk. Sites that were contaminated by high concentrations of organochlorine compounds were associated with dense population, such as the harbour and the Gediz River estuary. Relatively higher ΣDDT concentrations and high DDT/DDE + DDD ratios in the Gediz River estuary indicated DDT usage, probably linked to public health emergencies. According to the established guidelines for sediment quality, the risk of adverse biological effects from such levels of OCPs and PCBs as recorded at most of the study sites was insignificant. But the higher concentrations in Inner bay and in the Gediz River estuary could cause biological damage.     

[专稿]湖泊沉积物-水界面研究进展与展望

湖泊沉积物-水界面是以水层/沉积层物相为基础、具有一定立体尺度的交接面,界面上所发生的由生物积极参与的物理、化学和生物学微小反应和环境变化,都会对界面附近物质的状态和迁移转化行为产生着复杂影响.本文首先回顾了沉积物-水界面研究100多年来的发展历程及国内外近20年发展.然后系统介绍了国际上对沉积物-水界面的物理尺度与结构的宏观和微观认识;重点综述了沉积物间隙水的取样、物化性质的多维测定与结构表征、过程的静态和动态模拟等湖泊沉积物-水界面研究技术与方法;分析和展示了氮磷等营养物、重金属和持久性有机污染物在湖泊沉积物-水界面迁移转化过程的研究进展;总结和归纳了在沉积物-水界面过程的模型研究、沉积物-水界面物质交换的定量化、界面过程与湖泊生态环境灾害关系等模型与过程效应方面的研究成果.最后对沉积物-水界面信息获取技术的研发方向、界面物质交换定量化研究的关注点,以及加强模型的应用和构建等方面进行了展望.     

Phytoplankton biomass size structure and its regulation in the Southern Yellow Sea (China): Seasonal variability

Phytoplankton size structure plays a significant role in controlling the carbon flux of marine pelagic ecosystems. The mesoscale distribution and seasonal variation of total and size-fractionated phytoplankton biomass in surface waters, as measured by chlorophyll a (Chl a), was studied in the Southern Yellow Sea using data from four cruises during 2006–2007. The distribution of Chl a showed a high degree of spatial and temporal variation in the study area. Chl a concentrations were relatively high in the summer and autumn, with a mean of 1.42 and 1.27 mg m⁻³, respectively. Conversely, in the winter and spring, the average Chl a levels were only 0.98 and 0.99 mg m⁻³. Total Chl a showed a clear decreasing gradient from coastal areas to the open sea in the summer, autumn and winter cruises. Patches of high Chl a were observed in the central part of the Southern Yellow Sea in the spring due to the onset of the phytoplankton bloom. The eutrophic coastal waters contributed at least 68% of the total phytoplankton biomass in the surface layer. Picophytoplankton showed a consistent and absolute dominance in the central region of the Southern Yellow Sea (>40%) in all of the cruises, while the proportion of microphytoplankton was the highest in coastal waters. The relative proportions of pico- and nanophytoplankton decreased with total biomass, whereas the proportion of the micro-fraction increased with total biomass. Relationships between phytoplankton biomass and environmental factors were also analysed. The results showed that the onset of the spring bloom was highly dependent on water column stability. Phytoplankton growth was limited by nutrient availability in the summer due to the strong thermocline. The combined effects of P-limitation and vertical mixing in the autumn restrained the further increase of phytoplankton biomass in the surface layer. The low phytoplankton biomass in winter was caused by vertical dispersion due to intense mixing. Compared with the availability of nutrients, temperature did not seem to cause direct effects on phytoplankton biomass and its size structure. Although interactions of many different environmental factors affected phytoplankton distributions, hydrodynamic conditions seemed to be the dominant factor. Phytoplankton size structure was determined mainly by the size-differential capacity in acquiring resource. Short time scale events, such as the spring bloom and the extension of Yangtze River plume, can have substantial influences, both on the total Chl a concentration and on the size structure of the phytoplankton.     

Seasonal variation of upper layer circulation in the northern part of the East/Japan Sea

Seasonal variation of upper layer circulation in the northern part of the East/Japan Sea and its mechanism were investigated using empirical orthogonal function (EOF) analysis with satellite sea surface heights over the northern East/Japan Sea and a three-dimensional circulation model. The spatial structure and temporal variation of first EOF mode, which explains about 64% of the total variance, indicate that a large cyclonic circulation in the northern East/Japan Sea shows a semi-annual variation with maximum strength in summer and winter. According to numerical model result, the Liman Cold Current, accepted as a major current in the northern East/Japan Sea, is well mixed vertically by the winter monsoon and the current in the upper layer has a relatively deep structure, with a maximum westward speed of about 20 cm/s in winter. On the other hand, in summer the current has a stronger baroclinic structure of velocity than in winter. Numerical experiments showed that in summer the temporal variation of upper layer circulation is controlled by thermal forcing, such as sea surface heat flux and inflow of heat transport into the East/Japan Sea through the Korea/Tsushima Strait. Moreover, the cyclonic circulation in the upper layer of the northern East/Japan Sea is also generated and strengthened by the positive wind stress curl occupying most of the East/Japan Sea during the winter. The seasonal variation of each forcing that drives the circulation is responsible for the strength or weakness of the upper layer circulation in the northern East/Japan Sea. The contribution of each forcing to the seasonal variation of the upper layer circulation is examined through sensitivity experiments. According to these numerical experiments, the upper layer circulation in the northern East/Japan Sea is strengthened twice a year, in winter and summer, and this semi-annual variation is determined by a combination of wind (winter) and thermal (summer) forcing.     

DMSP and DMS in coastal fast ice and under-ice water of Lützow-Holm Bay, eastern Antarctica

The combined concentration of total dimethylsulfoniopropionate and dimethylsulfide (DMSP+DMS) were measured in Antarctic fast ice on the coast of Lützow-Holm Bay, eastern Antarctica. High bulk-ice DMSP+DMS and chlorophyll a concentrations were found at the bottom of the sea ice, and these concentrations were higher than those in the under-ice water. The bulk-ice DMSP+DMS and chlorophyll a concentrations were highly correlated (r²=0.68, P<0.001), suggesting that the high bulk-ice DMSP+DMS concentrations were caused mainly by the presence of algae assemblages in the ice. The calculated brine DMSP+DMS concentrations were as high as 1100 nM in the bottom ice layer, and the vertical profile patterns of brine DMSP+DMS concentrations were almost the same as for the bulk ice, mainly because of the small amount of variability in the vertical brine volume fraction. DMSP+DMS and chlorophyll a concentrations in the under-ice water increased, whereas the salinity of the under-ice water decreased, during the sampling period. These results reflect the supply of freshwater containing high levels of DMSP+DMS to the water just under the ice as the ice melted. These results suggest that sea-ice melting could be important to sulfur cycling in coastal ice-covered regions of the polar oceans.     

Distributions of polycyclic aromatic hydrocarbons in the Daliao River Estuary of Liaodong Bay, Bohai Sea (China)

The distributions of 16 polycyclic aromatic hydrocarbons (PAHs) were determined in the aqueous phase, suspended particulate matter (SPM), sediment, and pore water of the Daliao River Estuary in Liaodong Bay, Bohai Sea (China). Total PAH concentrations ranged from 139.16 to 1717.87 ng L⁻¹ in surface water, from 226.57 to 1404.85 ng L⁻¹ dry weight in SPM, from 276.26 to 1606.89 ng g⁻¹ dry weight in sediments, and from 10.20 to 47.27 μg L⁻¹ in pore water. PAH concentrations were at relatively moderate levels in water, SPM, sediment and pore water in comparison with those reported for other estuary and marine systems around the world. Sedimentary PAH concentrations decreased offshore owing to active deposition of laterally-transported river-borne particles. PCA analysis of the possible PAH source suggested petrogenic and pyrolytic PAH inputs in the studied region.     

Seasonal dynamics of microbial sulfate reduction in temperate intertidal surface sediments: controls by temperature and organic matter

The role of microbial sulfate reduction on organic matter oxidation was studied quantitatively in temperate intertidal surface sediments of the German Wadden Sea (southern North Sea) on a seasonal base in the years 1998–2007. The sampling sites represent the range of sediments found in the back-barrier tidal area of Spiekeroog Island: sands, mixed and muddy flats. The correspondingly different contents in organic matter, metals, and porosities lead to significant differences in the activity of sulfate-reducing bacteria with volumetric sulfate reduction rates (SRR) in the top 15 cm of up to 1.4 μmol cm^?3 day^?1. Depth-integrated areal SRR ranged between 0.9 and 106 mmol m^?2 day^?1, with the highest values found in the mudflat sediments and lower rates measured in sands at the same time, demonstrating the impact of both temperature and organic matter load. According to a modeling approach for a 154-km² large tidal area, about 39, 122, and 285 tons of sulfate are reduced per day, during winter, spring/autumn, and summer, respectively. Hence, the importance of areal benthic organic matter mineralization by microbial sulfate reduction increases during spring/autumn and summer by factors of about 2 and 7, respectively, when compared to winter time. The combined results correspond to an estimated benthic organic carbon mineralization rate via sulfate reduction of 78 g C m^?2 year^?1.