Lunar microcraters: Implications for the micrometeoroid complex

The contributions of lunar microcrater studies to understand the overall micrometeoroid environment are summarized and compared to satellite data.In comparison with small-scale laboratory studies, most lunar crater morphologies are compatible only with impact velocities > 3·5 km/sec and projectile densities between 1–8 g/cm³; a mean value is most likely 2–4 g/cm³. The particles arenon-porous and fairly equi-dimensional; needles, platelets, rods, whiskers and other highly asymmetric particle shapes can be excluded. Data on projectile chemistry is sparse and non-diagnostic at present.The crater diameters are converted into projectile masses via small scale laboratory impact experiments. Accordingly, the observed span of crater pit diameters (0·1 μm–1 cm) corresponds to a particle mass range of ≈ 10^?15–10^?3 g. This large, dynamic detection range is a unique feature of the lunar rock detector. Absolute crater densities on different rocks vary from “production” to “equilibrium” conditions. After normalization of such densities, relative microcrater size frequencies are obtained to deduce a mass frequency distribution for particles 10^?15–10^?3 g. There is evidence that this distribution is bimodal. A radiation pressure cutoff at 10^?12 g particle mass does not exist. The micrometeoroid flux obtained from lunar rocks is compatible with satellite data. There is indication that the micrometeoroid flux may have been lower in the past. Some speculative astronomical consequences concerning the origin of micrometeoroids are discussed.     

Observational Results of Full-Disc Helioseismology: Implications for Seismology of Sun-like Stars

A brief review of observational full-disc helioseismology is carried out with emphasis on issues of interest in the developing field of seismology of Sun-like stars. The frequency precision obtained from extended full-disc helioseismic data sets and the activity cycle variation of solar p-mode parameters are summarised and related to recent and potential asteroseismic studies. The potential advantages of sharing approaches to the analysis of real and simulated data between helio- and astero-seismology groups are discussed.     

Lunar helium-3 in marine sediments: Implications for a late Eocene asteroid shower

A late Eocene asteroid shower to the Earth-Moon system resulted in an increased flux of impact ejected ³He-rich lunar matter to Earth, which is recorded by a 2 Ma enduring ³He-anomaly in marine sediments.     

Observed Weak Electron Beam Discharge Driven Grain Acceleration/Accretion with Implications for Planet Formation

Work presented here addresses the issue of grain accretion, an essential yet poorly understood process in planetary system formation, linking the dynamically modeled steps of temperature-dependent condensation of gases after proto-sun gravitational collapse to coalescence of kilometer-size planetesimals into planets. The mechanism for grain accretion has proven difficult to model dynamically. Here, we attempt to test the thesis that the accretion process is electrostatically-driven by non-uniform charging of grains in a low discharge/weak field environment equivalent to periodic conditions in protoplanetary nebulae during solar discharge events such as flares. We simulate in the laboratory the behavior of grains in relationship to surfaces in such an environment. The nature of the observed disaggregation, repulsion, and acceleration of grains away from initial surfaces, and their reaggregation as coatings on surrounding oppositely charged surfaces, provide an empirical experimental basis for an electrostatically-driven model for grain behavior and accretion. Similar weak discharge processes in the protoplanetary disk solar nebula could give rise to increased grain acceleration and collisional compression induced surface coating, necessary conditions for increased accretion. The frequency, timing, and level of energetic output of the proto-sun would influence the effectiveness of such processes in developing stable aggregates, and the nature of the solar system that would result.     

The transition from complex crater to peak-ring basin on the Moon: New observations from the Lunar Orbiter Laser Altimeter (LOLA) instrument

Impact craters on planetary bodies transition with increasing size from simple, to complex, to peak-ring basins and finally to multi-ring basins. Important to understanding the relationship between complex craters with central peaks and multi-ring basins is the analysis of protobasins (exhibiting a rim crest and interior ring plus a central peak) and peak-ring basins (exhibiting a rim crest and an interior ring). New data have permitted improved portrayal and classification of these transitional features on the Moon. We used new 128 pixel/degree gridded topographic data from the Lunar Orbiter Laser Altimeter (LOLA) instrument onboard the Lunar Reconnaissance Orbiter, combined with image mosaics, to conduct a survey of craters >50 km in diameter on the Moon and to update the existing catalogs of lunar peak-ring basins and protobasins. Our updated catalog includes 17 peak-ring basins (rim-crest diameters range from 207 km to 582 km, geometric mean = 343 km) and 3 protobasins (137-170 km, geometric mean = 157 km). Several basins inferred to be multi-ring basins in prior studies (Apollo, Moscoviense, Grimaldi, Freundlich-Sharonov, Coulomb-Sarton, and Korolev) are now classified as peak-ring basins due to their similarities with lunar peak-ring basin morphologies and absence of definitive topographic ring structures greater than two in number. We also include in our catalog 23 craters exhibiting small ring-like clusters of peaks (50-205 km, geometric mean = 81 km); one (Humboldt) exhibits a rim-crest diameter and an interior morphology that may be uniquely transitional to the process of forming peak rings. A power-law fit to ring diameters (D_ring) and rim-crest diameters (D_r) of peak-ring basins on the Moon [D_ring = 0.14 ± 0.10(D_r)^1.21±0.13] reveals a trend that is very similar to a power-law fit to peak-ring basin diameters on Mercury [D_ring = 0.25 ± 0.14(D_rim)^1.13±0.10] [Baker, D.M.H. et al. [2011]. Planet. Space Sci., in press]. Plots of ring/rim-crest ratios versus rim-crest diameters for peak-ring basins and protobasins on the Moon also reveal a continuous, nonlinear trend that is similar to trends observed for Mercury and Venus and suggest that protobasins and peak-ring basins are parts of a continuum of basin morphologies. The surface density of peak-ring basins on the Moon (4.5 × 10⁻⁷ per km²) is a factor of two less than Mercury (9.9 × 10⁻⁷ per km²), which may be a function of their widely different mean impact velocities (19.4 km/s and 42.5 km/s, respectively) and differences in peak-ring basin onset diameters. New calculations of the onset diameter for peak-ring basins on the Moon and the terrestrial planets re-affirm previous analyses that the Moon has the largest onset diameter for peak-ring basins in the inner Solar System. Comparisons of the predictions of models for the formation of peak-ring basins with the characteristics of the new basin catalog for the Moon suggest that formation and modification of an interior melt cavity and nonlinear scaling of impact melt volume with crater diameter provide important controls on the development of peak rings. In particular, a power-law model of growth of an interior melt cavity with increasing crater diameter is consistent with power-law fits to the peak-ring basin data for the Moon and Mercury. We suggest that the relationship between the depth of melting and depth of the transient cavity offers a plausible control on the onset diameter and subsequent development of peak-ring basins and also multi-ring basins, which is consistent with both planetary gravitational acceleration and mean impact velocity being important in determining the onset of basin morphological forms on the terrestrial planets.     

Observed composition of the ionosphere of Venus: Implications for the ionization peak and the maintenance of the nightside ionosphere

Across the nightside of Venus, daily measurements from the PV Orbiter Ion Mass Spectrometer often indicate an ionosphere of relatively abundant concentration, with a composition characteristic of the dayside ionosphere. Such conditions are interspersed by other days on which the ionosphere appears to largely “disappear” down to about 200 km, with ion concentrations at lower heights also much reduced. These characteristics, coupled with observations of strong day to night flows of O⁺ in the upper ionosphere, support arguments that ion transport from the dayside is important for the maintenance of the nightside ionosphere. Also, U.S. and Soviet observations of nightside energetic electron fluxes have prompted consideration of impact ionization as an additional nightside ion source. The details of the ion and neutral composition at low altitudes on the nightside provide an important input for further analysis of the maintenance process. In the range 140–160 km, strong concentrations of O₂⁺ and NO⁺ indicate that the ionization peak is at times composed of at least two prominent ion species. Nightside concentrations of O₂⁺ and NO⁺ as large as 10⁵ and 10⁴/cm³, respectively, appear to require sources in addition to that provided by transport. The most probable sources are considered briefly, and no satisfactory explanation is yet found for the observed NO⁺ concentrations. Further analysis beyond the scope of this paper is required to resolve this issue.     

First Observations from the Multi-Application Solar Telescope (MAST) Narrow-Band Imager

The Multi-Application Solar Telescope is a 50 cm off-axis Gregorian telescope recently installed at the Udaipur Solar Observatory, India. In order to obtain near-simultaneous observations at photospheric and chromospheric heights, an imager optimized for two or more wavelengths is being integrated with the telescope. Two voltage-tuneable lithium-niobate Fabry–Perot etalons along with a set of interference blocking filters have been used for developing the imager. Both of the etalons are used in tandem for photospheric observations in Fe i 6173 Å and chromospheric observation in H\(\alpha\) 6563 Å spectral lines, whereas only one of the etalons is used for the chromospheric Ca II line at 8542 Å. The imager is also being used for spectropolarimetric observations. We discuss the characterization of the etalons at the above wavelengths, detail the integration of the imager with the telescope, and present a few sets of observations taken with the imager set-up.     

The Electrostatic Lunar Dust Analyzer (ELDA) for the detection and trajectory measurement of slow-moving dust particles from the lunar surface

Micron and submicron-sized dust particles can be lifted from the lunar surface due to continual micrometeoroid bombardment and electrostatic charging. The characteristics of these dust populations are of scientific interest and engineering importance for the design of future equipment to operate on the lunar surface. The mobilized grains are expected to have a low velocity, which makes their detection difficult by traditional methods that are based on momentum transfer or impact energy. We describe a newly developed instrument concept, the Electrostatic Lunar Dust Analyzer (ELDA), which utilizes the charge on the dust for detection and analysis. ELDA consists of an array of wire electrodes combined with an electrostatic deflection field region, and measures the mass, charge, and velocity vector of individual dust grains. The first basic prototype of the ELDA instrument has been constructed, tested and characterized in the laboratory. The instrument is set up to measure over a velocity range 1–100 m/s and is sensitive to particles from an approximate mass range from 2×10⁻¹⁶ to 10⁻¹¹ kg, depending on the charge state and velocity.     

Lunar X-ray fluorescence observations by the Chandrayaan-1 X-ray Spectrometer (C1XS): Results from the nearside southern highlands

The Chandrayaan-1 X-ray Spectrometer (C1XS) flown on-board the first Indian lunar mission Chandrayaan-1, measured X-ray fluorescence spectra during several episodes of solar flares during its operational period of ∼9 months. The accompanying X-ray Solar Monitor (XSM) provided simultaneous spectra of solar X-rays incident on the Moon which are essential to derive elemental chemistry. In this paper, we present the surface abundances of Mg, Al, Si, Ca and Fe, derived from C1XS data for a highland region on the southern nearside of the Moon. Analysis techniques are described in detail including absolute X-ray line flux derivation and conversion into elemental abundance. The results are consistent with a composition rich in plagioclase with a slight mafic mineral enhancement and a Ca/Al ratio that is significantly lower than measured in lunar returned samples. We suggest various possible scenarios to explain the deviations.     

Methane evolution from UV-irradiated spacecraft materials under simulated martian conditions: Implications for the Mars Science Laboratory (MSL) mission

Fifteen organic and three inorganic compounds were tested for methane (CH₄) evolution under simulated martian conditions of 6.9 mbar; UVC (200-280 nm) flux of 4 W m⁻²; 20 °C; simulated optical depth of 0.1; and a Mars gas composition of CO₂ (95.3%), N₂ (2.7%), Ar (1.7%), O₂ (0.13%), and water vapor (0.03%). All three inorganic compounds (i.e., NaCl, CaCO₃, graphite) failed to evolve methane at the minimum detection level 0.5 ppm, or above. In contrast, all organic compounds evolved methane when exposed to UV irradiation under simulated martian conditions. The polycyclic aromatic hydrocarbon, pyrene, released the most methane per unit of time at 0.175 nmol CH₄ g⁻¹ h⁻¹, and a spectral reflectance target material used for the MER rovers and Phoenix lander released the least methane at 0.00065 nmol CH₄ cm⁻² h⁻¹. Methane was also released from UV-killed bacterial endospores of Bacillus subtilis. Although all organic compounds evolved methane when irradiated with UV photons under martian conditions, the concentrations of residual organics, biogenic signature molecules, and dead microbial cells should be relatively low on the exterior surfaces of the MSL rover, and, thus, not significant sources of methane contamination. In contrast, kapton tape was found to evolve methane at the rate of 0.00165 nmol CH₄ cm⁻² h⁻¹ (16.5 nmol m⁻² h⁻¹) under the UV and martian conditions tested. Although the evolution of methane from kapton tape was found to decline over time, the large amount of kapton tape used on the MSL rover (lower bound estimated at 3 m²) is likely to create a significant source of terrestrial methane contamination during the early part of the mission.     

Integration and Comparison of Clementine and Lunar Prospector Data: Global Scale Multielement Analysis1 (Fe,Ti, and Th) of the Lunar Surface

In this paper, we present (1) a statistical analysis, based on a systematic clustering method, of a dataset integrating the global abundance maps of the three elements iron, titanium, and thorium derived from Clementine and Lunar Prospector and (2) a comparison of iron abundances between Clementine and Lunar Prospector. Homogeneous geologic units are compositionally characterized and spatially defined in relation to the major rock types sampled on the Moon. With the lowest abundances of Fe, Ti, and Th found on the Moon, the lunar highland terrains are quite homogeneous with two major large feldspathic units, one being slightly more mafic than the other. Two distinct regions with unique compositions are unambiguously identified: the Procellarum KREEP Terrane (PKT) and the South Pole–Aitken (SPA). The PKT, which includes all the units with Th abundances higher than 3.5 ppm (KREEP-rich materials), is delimited by an almost continuous ringlike unit. In particular, it includes the western nearside maria, except for Mare Humorum. With concentrations in Fe, Ti, and Th enhanced relative to the surrounding highlands, the South Pole–Aitken basin floor represents a large mafic anomaly on the far side, suggesting wide deposits of lower crust and possible mantle materials. However, due to indirect residual latitude effects in the CSR (Clementine spectral reflectance) measurements, iron abundances might have been overestimated in SPA, thus implying that crustal materials, rather than mantle materials, might represent the dominant contributor to the mafic component exposed on the basin floor.     

REE abundances in the matrix of the Allende (CV) meteorite: Implications for matrix origin

Abstract— The trace element distributions in the matrix of primitive chondrites were examined using four least‐contaminated matrix specimens from the polished sections of the Allende (CV) meteorite. Analysis of rare earth element (REE), Ba, Sr, Rb, and K abundances by isotope dilution mass spectrometry revealed that the elemental abundances of lithophile elements except for alkali metals (K, Rb) in the specimens of the Allende matrix studied here are nearly CI (carbonaceous Orgueil) chondritic (～1 × CI). Compared to refractory elements, all the matrix samples exhibited systematic depletion of the moderately volatile elements K and Rb (0.1–0.5 × CI). We suggest that the matrix precursor material did not carry significant amounts of alkali metals or that the alkalis were removed from the matrix precursor material during the parent body process and/or before matrix formation and accretion. The matrix specimens displayed slightly fractionated REE abundance patterns with positive Ce anomalies (CI‐normalized La/Yb ratio = 1.32–1.65; Ce/Ce* = 1.16–1.28; Eu/Eu* = 0.98–1.10). The REE features of the Allende matrix do not indicate a direct relationship with chondrules or calcium‐aluminum‐rich inclusions (CAIs), which in turn suggests that the matrix was not formed from materials produced by the breakage and disaggregation of the chondrules or CAIs. Therefore, we infer that the Allende matrix retains the REE features acquired during the condensation process in the nebula gas.     

Titanium isotopic compositions of well‐characterized silicon carbide grains from Orgueil (CI): Implications for s‐process nucleosynthesis

Abstract— We have measured the titanium isotopic compositions of 23 silicon carbide grains from the Orgueil (CI) carbonaceous chondrites for which isotopic compositions of silicon, carbon, and nitrogen and aluminum‐magnesium systematics had been measured previously. Using the 16 most‐precise measurements, we estimate the relative contributions of stellar nucleosynthesis during the asymptotic giant branch (AGB) phase and the initial compositions of the parent stars to the compositions of the grains. To do this, we compare our data to the results of several published stellar models that employ different values for some important parameters. Our analysis confirms that s‐process synthesis during the AGB phase only slightly modified the titanium compositions in the envelopes of the stars where mainstream silicon carbide grains formed, as it did for silicon. Our analysis suggests that the parent stars of the >1 μm silicon carbide grains that we measured were generally somewhat more massive than the Sun (2–3 M_⊙) and had metallicities similar to or slightly higher than solar. Here we differ slightly from results of previous studies, which indicated masses at the lower end of the range 1.5–3 M_⊙ and metallicities near solar. We also conclude that models using a standard ¹³C pocket, which produces a good match for the main component of s‐process elements in the solar system, overestimate the contribution of the ¹³C pocket to s‐process nucleosynthesis of titanium found in silicon carbide grains. Although previous studies have suggested that the solar system has a significantly different titanium isotopic composition than the parent stars of silicon carbide grains, we find no compelling evidence that the Sun falls off of the array defined by those stars. We also conclude that the Sun does lie on the low‐metallicity end of the silicon and titanium arrays defined by mainstream silicon carbide grains.     

行星(月球)自转监测望远镜的原理样机地面验证实验

类地行星(月球)自转监测望远镜的科学目标是在行星(月球)表面现场测量行星(月球)自转并研究其内部结构和物理性质.为了验证全新的观测原理和资料处理方法,项目团队设计制造了一套原理样机,在一台商用天文望远镜的光路前端增加3面反射镜组,使其具有同时观测3个视场的能力.自2017年起在地面上开展了观测实验,获得了混合有3视场星象的图像.通过计算星象在前后图像上的位移实现了归属视场识别,使得观测效果与分视场独立观测等同,证明了用一台设备同时观测多视场的可行性.处理图像并通过3个视场中心的指向变化归算地球自转轴的空间指向,与理论值比较偏差平均约1′′,证明了观测原理和数据处理方法有效.对各种观测误差来源进行了分析,包含大气折射、仪器热稳定性和光学分辨能力的影响等,指出采用更长焦距的望远镜可以提高空间分辨率,优化形变控制可以提高观测稳定性.改进多视场同时观测中的光学设计也有助于精度的提高.     

Geological and geophysical studies of the Agoudal impact structure (Central High Atlas,Morocco): New evidence for crater size and age

Since the discovery of shatter cones (SCs) near the village of Agoudal (Morocco, Central High Atlas Mountains) in 2013, the absence of one or several associated circular structures led to speculation about the age of the impact event, the number, and the size of the impact crater or craters. Additional constraints on the crater size, age, and erosion rates are obtained here from geological, structural, and geophysical mapping and from cosmogenic nuclide data. Our geological maps of the Agoudal impact site at the scales of 1:30,000 (6 km²) and 1:15,000 (2.25 km²) include all known occurrences of SCs in target rocks, breccias, and vertical to overturned strata. Considering that strata surrounding the impact site are subhorizontal, we argue that disturbed strata are related to the impact event. Three types of breccias have been observed. Two of them (br1‐2 and br2) could be produced by erosion–sedimentation–consolidation processes, with no evidence for impact breccias, while breccia (br1) might be impact related. The most probable center of the structure is estimated at 31°59′13.73?N, 5°30′55.14?W using the concentric deviation method applied to the orientation of strata over the disturbed area. Despite the absence of a morphological expression, the ground magnetic and electromagnetic surveys reveal anomalies spatially associated with disturbed strata and SC occurrences. The geophysical data, the structural observations, and the area of occurrence of SCs in target rocks are all consistent with an original size of 1.4–4.2 km in diameter. Cosmogenic nuclide data (³⁶Cl) constrain the local erosion rates between 220 ± 22 m Ma^?1 and 430 ± 43 m Ma^?1. These erosion rates may remove the topographic expression of such a crater and its ejecta in a time period of about 0.3–1.9 Ma. This age is older than the Agoudal iron meteorite age (105 ± 40 kyr). This new age constraint excludes the possibility of a genetic relationship between the Agoudal iron meteorite fall and the formation of the Agoudal impact site. A chronolgy chart including the Atlas orogeny, the alternation of sedimentation and erosion periods, and the meteoritic impacts is presented based on all obtained and combined data.     

Impact melt dikes in the Sudbury multi-ring basin (Canada): Implications from uranium-lead geochronology on the Foy Offset Dike

Abstract To investigate the origin of Offset Dikes and their age relationships to major impact generated lithologies in the Sudbury multi-ring impact structure, such as the Main Mass of the Sudbury “Igneous” Complex, zircon and baddeleyite were dated by the U-Pb chronometer. The rocks analysed are one diorite and two quartz diorites from inside the Foy Offset, one quartz diorite from the contact zone, and two country rock samples collected at 10 and 30 m distances from the contact within the Levack Gneiss Complex. The 21 analysed zircon and baddeleyite fractions yield a crystallization age of 1852 +4/-3 (2σ) Ma for the accessory minerals in the Foy Offset Dike and an age of 2635 ± 5 Ma for the shocked Levack country rock, in which zircons show significant shock effects (multiple sets of planar fractures), in contrast to the totally unshocked zircons of the Offset Dike. Within given errors, the new age of 1852 Ma is identical to the pooled 1850 ± 1 Ma U-Pb age determined by Krogh et al. (1984) as the crystallization age of accessory phases in different lithologies of the Sudbury “Igneous” Complex, which has been interpreted to represent the coherent impact melt sheet of the Sudbury Structure. This excellent agreement of the ages substantiates that emplacement of the Offset Dikes occurred coevally with the formation of the impact melt sheet. Total absence of inherited zircons in the central part of the Foy Offset indicates melting of the precursor material at temperatures well above 1700 °C, which emphasizes the origin of the dike lithologies by impact melting.     

Neptune's satellites: Implications from impact crater morphology

The presence of central peak craters and the absence of central pit craters on Triton implies a surface rigidity similar to the Saturnian and Uranian satellites and stronger than that of the Jupiter satellites Ganymede and Callisto. Tectonically degraded terrain may exist at the antipode of the large impact structure on 1989N1. Dome craters on Triton may represent a form of solid state volcanism.     

Characterization of Mason Gully (H5): The second recovered fall from the Desert Fireball Network

Mason Gully, the second meteorite recovered using the Desert Fireball Network (DFN), is characterized using petrography, mineralogy, oxygen isotopes, bulk chemistry, and physical properties. Geochemical data are consistent with its classification as an H5 ordinary chondrite. Several properties distinguish it from most other H chondrites. Its 10.7% porosity is predominantly macroscopic, present as intergranular void spaces rather than microscopic cracks. Modal mineralogy (determined via PS‐XRD, element mapping via energy dispersive spectroscopy [EDS], and X‐ray tomography [for sulfide, metal, and porosity volume fractions]) consistently gives an unusually low olivine/orthopyroxene ratio (0.67?0.76 for Mason Gully versus ~1.3 for typical H5 ordinary chondrites). Widespread “silicate darkening” is observed. In addition, it contains a bright green crystalline object at the surface of the recovered stone (diameter ≈ 1.5 mm), which has a tridymite core with minor α‐quartz and a rim of both low‐ and high‐Ca pyroxene. The mineralogy allows the calculation of the temperatures and ?(O₂) characterizing thermal metamorphism on the parent body using both the two‐pyroxene and the olivine‐chromite geo‐oxybarometers. These indicate that MG experienced a peak metamorphic temperature of ~900 °C and had a similar ?(O₂) to Kernouvé (H6) that was buffered by the reaction between olivine, metal, and pyroxene. There is no evidence for shock, consistent with the observed porosity structure. Thus, while Mason Gully has some unique properties, its geochemistry indicates a similar thermal evolution to other H chondrites. The presence of tridymite, while rare, is seen in other OCs and likely exogenous; however, the green object itself may result from metamorphism.     

Alkali (Rb/K) abundances in Allende barred-olivine chondrules: Implications for the melting conditions of chondrules

Abstract— In order to study abundances of alkali metals in chondrules, 25 petrographically characterized chondrules, including 18 barred olivine (BO) chondrules from the Allende (CV3) meteorite, were analyzed for alkalis (K and Rb) and alkaline earths (Sr, Ba, Ca and Mg) by mass spectrometric isotope dilution. Most BO chondrules with higher alkalis (>CI level) have nearly CI-chondritic Rb/K ratios, while those with lower alkalis clearly show higher Rb/K ratios than the CI-chondritic. In general, BO chondrules with higher Rb/K exhibit more depletion of alkalis relative to Ca. The mean olivine Fa for individual chondrules positively correlates with bulk alkali concentrations in BO type but not in porphyritic type chondrules. These observations suggest that some BO chondrules formed from more reducing assemblages of precursor minerals, which experienced more intensive vaporization losses of alkalis, accompanied by Rb/K fractionation, during the chondrule-formation melting.     

Aragonite in the Murray (CM2) carbonaceous chondrite: Implications for parent body compaction and aqueous alteration

Abstract— The matrix of the CM2 carbonaceous chondrite Murray contains rare micrometer‐sized prismatic crystals of aragonite that formed during late‐stage parent body aqueous alteration. The aragonite was identified by X‐ray microanalysis coupled with electron backscatter diffraction (EBSD), TEM selected area electron diffraction and cathodoluminescence spectroscopy. The sixteen crystals found all occur within loose and elongate submillimeter‐sized clusters and one cluster is present in each of the two thin sections studied. Orientation determinations using EBSD show that the c axes of aragonite crystals within each cluster lie roughly in a plane, itself aligned approximately parallel to the long axis of the host cluster. Aragonite is inferred to have crystallized after calcite but before completion of static/impact‐related compaction. The clusters developed by growth of aragonite within films of aqueous fluids that had a relatively high Mg/Ca ratio. These fluids were focused within zones of high porosity and permeability along a weak compactional fabric in the matrix and this fabric is also likely to have influenced the orientations of aragonite crystals as they grew. These results suggest that aragonite probably occurs in most of those carbonaceous chondrites that have undergone moderate degrees of parent body aqueous alteration and may provide further insights into the evolution of pore fluid compositions and volumes and the chronology of asteroidal evolution.