Combined experimental and theoretical studies on methane photolysis at 121.6 and 248 nm—implications on a program of laboratory simulations of Titan’s atmosphere

Methane is, together with N₂, the main precursor of Titan’s atmospheric chemistry. In our laboratory, we are currently developing a program of laboratory simulations of Titan’s atmosphere, where methane is intended to be dissociated by multiphotonic photolysis at 248 nm. A preliminary study has shown that multiphotonic absorption of methane at 248 nm is efficient and leads to the production of hydrocarbons such as C₂H₂ (Romanzin et al., 2008). Yet, at this wavelength, little is known about the branching ratios of the hydrocarbon radicals (CH₃, CH₂ and CH) and their following photochemistry. This paper thus aims at investigating methane photochemistry at 248 nm by comparing the chemical evolution observed after irradiation of CH₄ at 248 and at 121.6 nm (Ly-α). It is indeed important to see if the chemistry is driven the same way at both wavelengths in particular because, on Titan, methane photolysis mainly involves Ly-α photons. An approach combining experiments and theoretical analysis by means of a specifically adapted 0-D model has thus been developed and is presented in this paper. The results obtained clearly indicate that the chemistry is different depending on the wavelength. They also suggest that at 248 nm, methane dissociation is in competition with ionisation, which could occur through a three-photon absorption process. As a consequence, 248 nm photolysis appears to be unsuitable to study methane neutral photochemistry alone. The implications of this result on our laboratory simulation program and new experimental developments are discussed. Additional information on methane photochemistry at 121.6 nm are also obtained.     

Probing Titan’s lower atmosphere with acousto-optic tuning

Narrow-band images of Titan were obtained in November 1999 with the NASA/GSFC- built acousto-optic imaging spectrometer (AImS) camera. This instrument utilizes a tunable filter element that was used within the 500- to 1050-nm range, coupled to a CCD camera system. The images were taken with the Mount Wilson 2.54-m (100 in.) Hooker telescope, which is equipped with a natural guide star adaptive optics system. We observed Titan at 830 and 890 nm and at a series of wavelengths across the 940-nm window in Titan’s atmosphere where the methane opacity is relatively low. We determined the absolute reflectivity (I/F) of Titan and fit the values at 940 nm to a Minnaert function at Titan’s equator and at −30° latitude (closer to the subsolar point) and obtained average values for the Minnaert limb-darkening slope, k, of 0.661 ± 0.007 and 0.775 ± 0.018, respectively. Comparison with models suggests that the equatorial value of k is consistent with rain removal of haze in the lower atmosphere. The higher value of k at −30° is consistent with the southern hemisphere being brighter than the equator. However, the fits are not unique. The data and models at 890 are consistent with no limb brightening or darkening at this wavelength either at the equator or at −30°.     

Vertical distribution of scattering hazes in Titan's upper atmosphere

Radial intensity scars of a Voyager 2 high phase angle image of Titan have been inverted to yield vertical extinction profiles at 1° intervals around the limb. A detached haze layer with peak particle number densities ～0.2 cm^?3 exists at all latitudes south of ～45°N, and at an altitude of 300–350 km. The optical depth 0.01 level lies at a radius of 2932 ± 5 km at the equator and at a radius of 2915 ± 10 km over the poles (altitudes of 357 ± 5 and 340 ± 10 km, respectively). In addition to the haze layer at 300–350 km, there is a small enhancement in the extinction at ～450 km which exists at all latitudes between 75°S and ～60°N.     

Detection of the old stellar component of the major Galactic bar

We present near-infrared colour–magnitude diagrams and star counts for a number of regions along the Galactic plane. It is shown that along the l =27°, b =0° line of sight there is a feature at 5.7±0.7 kpc with a density of stars at least a factor of 2 and probably more than a factor of 5 times that of the disc at the same position. This feature forms a distinct clump on an H versus J − H diagram and is seen at all longitudes from the bulge to about l =28°, but at no longitude greater than this. The distance to the feature at l =20° is about 0.5 kpc further than at l =27°, and by l =10° it has merged with, or has become, the bulge. Given that at l =27° and l =21° there is also a clustering of very young stars, the only component that can reasonably explain what is seen is a bar with half-length of around 4 kpc and a position angle of about 43°±7°.     

Comparison of the thermal and nonthermal radiation characteristics of Jupiter at 6, 11, and 21 cm with model calculations

Four different data sets on Jupiter, one at 6, one at 11, and two at 21 cm, are compared to each other and with the synchrotron radiation model of the magnetosphere developed by I. de Pater (1981, J. Geophys. Res., 86, 3397–3422, 3423–3429). The model agrees with all these data sets, and hence was used to derive and interpret the characteristics of the thermal radiation component at all three wavelengths. The disk temperatures are 233 ± 17, 280 ±20, and 340 ± 26°K at 6, 11, and 21 cm, respectively. A comparison of the data with atmospheric model calculations strongly suggests that the disk is uniform at λ6 and λ11 cm near the center of the disk, where μ > 0.6?0.7. This may indicate a nonuniform distribution of ammonia at layers at and above the visible cloud layers.     

Determination of zonal wind speeds at heights near 530 km from the orbit of Explorer 24 (1964-76A)

The orbit of Explorer 24 (1964–1976A) has been determined at 18 epochs during the five month period prior to its decay in October 1968, using the RAE orbit refinement computer program PROP6. As a balloon, the satellite was strongly influenced by atmospheric perturbations, despite its high perigee altitude near 490 km. It therefore provided an opportunity of determining atmospheric rotation rates at high altitude. The rotation rate, Λ rev day^?1, was estimated from the observed variation in orbital inclination, after the removal of perturbations including those due to solar radiation pressure.The mean rotation rates, averaged over local time, are Λ = 0.98 for 18 May to 18 August 1968 at 542 km; Λ = 1.06 for 18 May to 13 October 1968 at 533 km.For morning conditions, Λ = 0.9 for 22 June to 20 July 1968 at 540 km; Λ = 0.8 during September 1968 at 513 km.For evening conditions, Λ = 1.1 for 18 May to 15 June 1968, and for 26 July to 7 September 1968, at 540 km and 536 km respectively; Λ = 1.3 for 28 September to 13 October 1968 at 484 km.Further, the maximum W to E zonal wind has been estimated to occur at 20.5 h local time, during the period of the analysis.     

Partial melting of the Indarch (EH4) meteorite: A textural,chemical, and phase relations view of melting and melt migration

Abstract— To test whether aubrites can be formed by melting of enstatite chondrites and to understand igneous processes at very low O fugacities, we have conducted partial melting experiments on the Indarch (EH4) chondrite at 1000–1500 °C. Silicate melting begins at 1000 °C, and Indarch is completely melted by 1500 °C. The metal-sulfide component melts completely at 1000 °C. Substantial melt migration occurs at 1300–1400 °C, and metal migrates out of the silicate charge at 1450 °C and ～50% silicate partial melting. As a group, our experiments contain three immiscible metallic melts (Si-, P-, and C-rich), two immiscible sulfide melts (Fe- and FeMgMnCa-rich), and silicate melt. Our partial melting experiments on the Indarch (EH4) enstatite chondrite suggest that igneous processes at low fO₂ exhibit several unique features. The complete melting of sulfides at 1000 °C suggests that aubritic sulfides are not relics. Aubritic oldhamite may have crystallized from Ca and S complexed in the silicate melt. Significant metal-sulfide melt migration might occur at relatively low degrees of silicate partial melting. Substantial elemental exchange occurred between different melts (e.g., S between sulfide and silicate, Si between silicate and metal), a feature not observed during experiments at higher fO₂. This exchange may help explain the formation of aubrites from known enstatite chondrites.     

Origin and transportation history of lunar breccia 14311

In this paper, we compare the U‐Pb zircon age distribution pattern of sample 14311 from the Apollo 14 landing site with those from other breccias collected at the same landing site. Zircons in breccia 14311 show major age peaks at 4340 and 4240 Ma and small peaks at 4110, 4030, and 3960 Ma. The zircon age patterns of breccia 14311 and other Apollo 14 breccias are statistically different suggesting a separate provenance and transportation history for these breccias. This interpretation is supported by different U‐Pb Ca‐phosphate and exposure ages for breccia 14311 (Ca‐phosphate age: 3938 ± 4 Ma, exposure age: ~550–660 Ma) from the other Apollo 14 breccias (Ca‐phosphate age: 3927 ± 2 Ma, compatible with the Imbrium impact, exposure age: ~25–30 Ma). Based on these observations, we consider two hypotheses for the origin and transportation history of sample 14311. (1) Breccia 14311 was formed in the Procellarum KREEP terrane by a 3938 Ma‐old impact and deposited near the future site of the Imbrium basin. The breccia was integrated into the Fra Mauro Formation during the deposition of the Imbrium impact ejecta at 3927 Ma. The zircons were annealed by mare basalt flooding at 3400 Ma at Apollo 14 landing site. Eventually, at approximately 660 Ma, a small and local impact event excavated this sample and it has been at the surface of the Moon since this time. (2) Breccia 14311 was formed by a 3938 Ma‐old impact. The location of the sample is not known at that time but at 3400 Ma, it was located nearby or buried by hot basaltic flows. It was transported from where it was deposited to the Apollo 14 landing site by an impact at approximately 660 Ma, possibly related to the formation of the Copernicus crater and has remained at the surface of the Moon since this event. This latter hypothesis is the simplest scenario for the formation and transportation history of the 14311 breccia.     

Multispectral imaging observations of Neptune’s cloud structure with Gemini-North

Observations of Neptune were made in September 2009 with the Gemini-North Telescope in Hawaii, using the NIFS instrument in the H-band covering the wavelength range 1.477–1.803 μm. Observations were acquired in adaptive optics mode and have a spatial resolution of approximately 0.15–0.25″.The observations were analysed with a multiple-scattering retrieval algorithm to determine the opacity of clouds at different levels in Neptune’s atmosphere. We find that the observed spectra at all locations are very well fit with a model that has two thin cloud layers, one at a pressure level of ∼2 bar all over the planet and an upper cloud whose pressure level varies from 0.02 to 0.08 bar in the bright mid-latitude region at 20–40°S to as deep as 0.2 bar near the equator. The opacity of the upper cloud is found to vary greatly with position, but the opacity of the lower cloud deck appears remarkably uniform, except for localised bright spots near 60°S and a possible slight clearing near the equator.A limb-darkening analysis of the observations suggests that the single-scattering albedo of the upper cloud particles varies from ∼0.4 in regions of low overall albedo to close to 1.0 in bright regions, while the lower cloud is consistent with particles that have a single-scattering albedo of ∼0.75 at this wavelength, similar to the value determined for the main cloud deck in Uranus’ atmosphere. The Henyey-Greenstein scattering particle asymmetry of particles in the upper cloud deck are found to be in the range g ∼ 0.6–0.7 (i.e. reasonably strongly forward scattering).Numerous bright clouds are seen near Neptune’s south pole at a range of pressure levels and at latitudes between 60 and 70°S. Discrete clouds were seen at the pressure level of the main cloud deck (∼2 bar) at 60°S on three of the six nights observed. Assuming they are the same feature we estimate the rotation rate at this latitude and pressure to be 13.2 ± 0.1 h. However, the observations are not entirely consistent with a single non-evolving cloud feature, which suggests that the cloud opacity or albedo may vary very rapidly at this level at a rate not seen in any other giant-planet atmosphere.     

Cassini CIRS update on stratospheric ices at Titan's winter pole

A strong, broad spectral emission feature at 85° N latitude centered at 221 cm⁻¹ remains unidentified after candidate ices of H₂O and pure crystalline CH₃CH₂CN are unambiguously ruled out. A much shallower weak emission feature starts at 160 cm⁻¹ and blends into the strong feature at ∼190 cm⁻¹. This feature is consistent with one formed by an HCN ice cloud composed of ?5 μm radius particles that resides in the lower stratosphere somewhere below an altitude of 160 km. Titan's stratospheric aerosol appears to have a spectral emission feature at about 148 cm⁻¹. The aerosol abundance at 85° N is about a factor 2.2 greater than at 55° S.     

Coronal structure observed at the total solar eclipse of 11 June, 1983 in Indonesia

From the photographs taken at the total solar eclipse of 11 June 1983, we derived the electron density for the north polar rays and for the thread-like fine structures above the active region, which are 10⁸ at 1.4 solar radii and 3×10⁹ at 1.15 solar radii, respectively. The brightness distributions of the corona at the polar region and above the active region, and the flattening index were also derived.Paper presented at the IAU Third Asian-Pacific Regional Meeting, held in Kyoto, Japan, between 30 September–6 October, 1984.     

Spatially-resolved high-resolution spectroscopy of Venus 1. Variations of CO2, CO, HF, and HCl at the cloud tops

Variations of the upper cloud boundary and the CO, HF, and HCl mixing ratios were observed using the CSHELL spectrograph at NASA IRTF. The observations were made in three sessions (October 2007, January 2009, and June 2009) at early morning and late afternoon on Venus in the latitude range of ±60°. CO₂ lines at 2.25 μm reveal variations of the cloud aerosol density (∼25%) and scale height near 65 km. The measured reflectivity of Venus at low latitudes is 0.7 at 2.25 μm and 0.028 at 3.66 μm, and the effective CO₂ column density is smaller at 3.66 μm than those at 2.25 μm by a factor of 4. This agrees with the almost conservative multiple scattering at 2.25 μm and single scattering in the almost black aerosol at 3.66 μm. The expected difference is just a factor of (1 − g)⁻¹ = 4, where g = 0.75 is the scattering asymmetry factor for Venus’ clouds. The observed CO mixing ratio is 52 ± 4 ppm near 08:00 and 40 ± 4 ppm near 16:30 at 68 km, and the higher ratio in the morning may be caused by extension of the CO morningside bulge to the cloud tops. The observed weak limb brightening in CO indicates an increase of the CO mixing ratio with altitude. HF is constant at 3.5 ± 0.2 ppb at 68 km in both morningside and afternoon observations and in the latitude range ±60°. Therefore the observations do not favor a bulge of HF, though HF is lighter than CO. Probably a source in the upper atmosphere facilitates the bulge formation. The recent measurements of HCl near 70 km are controversial (0.1 and 0.74 ppm) and require either a strong sink or a strong source of HCl in the clouds. The HCl lines of the (2-0) band are blended by the solar and telluric lines. Therefore we observed the P8 lines of the (1-0) band at 3.44 μm. These lines are spectrally clean and result in the HCl mixing ratio of 0.40 ± 0.03 ppm at 74 km. HCl does not vary with latitude within ±60°. Our observations support a uniformly mixed HCl throughout the Venus atmosphere.     

Differential rotation of the solar electron corona

Autocorrelation analyses of K-coronameter observations made at Haleakala and Mauna Loa, Hawaii, during 1964–1967 have established average yearly rotation rates of coronal features as a function of latitude and height above the limb. At low latitudes the corona was found to rotate at the same rate as sunspots but at higher latitudes was consistently faster than the underlying photosphere. There were differences as large as 3–4% in the rate at specific latitudes from year to year and between the two hemispheres. In 1967 a nearly constant rotation was found for heights ranging from 1.125 to 2.0 R ₀. For 1966 there was a more complicated pattern of height dependence, with the rate generally decreasing with height at low latitudes and increasing at high latitudes.At Hawaii Institute of Geophysics.     

Thermal periodicities in the Venus atmosphere

A search was made for periodic fluctuations in the thermal brightness temperatures recorded by the Pioneer Venus orbiter's infrared radiometer. Data were averaged in 10 × 10° latitude-longitude bins for each of the 72 days the instrument was in operation. This time series of thermal brightness temperatures was then analyzed to determine the amplitude of fluctuations at periods from 2 to 64 days at four levels in the atmosphere (at the cloud tops and at approximately 70, 80, and 90 km). The amplitude of such fluctuations is small at equatorial latitudes and increases to a maximum at 60–70° latitude at most altitudes. The period of the highest amplitude fluctuation is 5.3±0.4 days (at all altitudes) except at 70–80°, where a 2.9-day period which appears to correspond to the polar dipole dominates the cloud-top channel. The amplitude of the periodic fluctuations is a maximum at the cloud tops, decreasing to a minimum at the 80-km channel, and increasing again at the 90-km channel.     

Gain calibration of CCD systems at VBO

The system gain of two CCD systems in regular use at the Vainu Bappu Observatory, Kavalur, is determined at a few gain settings. The procedure used for the determination of system gain and base-level noise is described in detail. The Photometrics CCD system at the 1-m reflector uses a Thomson-CSF TH 7882 CDA chip coated for increased ultraviolet sensitivity. The gain is programme-selected through the parameter ‘cgain’ varying between 0 and 4095 in steps of 1. The inverse system gain for this system varies almost linearly from 27.7 electrons DN^-1 at cgain = 0 to 1.5 electrons DN^-1 at cgain = 500. The readout noise is ≲ 11 electrons at cgain = 66. The Astromed CCD system at 2.3-m Vainu Bappu Telescope uses a GEC P8603 chip which is also coated for enhanced ultraviolet sensitivity. The amplifier gain is selected in discrete steps using switches in the controller. The inverse system gain is 4.15 electrons DN^-1 at the gain setting of 9.2, and the readout noise ∼ 8 electrons.     

Analysis of Cassini/CIRS limb spectra of Titan acquired during the nominal mission II: Aerosol extinction profiles in the 600–1420 cm spectral range

We have analyzed the continuum emission of limb spectra acquired by the Cassini/CIRS infrared spectrometer in order to derive information on haze extinction in the 3–0.02 mbar range (∼150–350 km). We focused on the 600–1420 cm⁻¹ spectral range and studied nine different limb observations acquired during the Cassini nominal mission at 55°S, 20°S, 5°N, 30°N, 40°N, 45°N, 55°N, 70°N and 80°N. By means of an inversion algorithm solving the radiative transfer equation, we derived the vertical profiles of haze extinction coefficients from 17 spectral ranges of 20-cm⁻¹ wide at each of the nine latitudes. At a given latitude, all extinction vertical profiles retrieved from various spectral intervals between 600 and 1120 cm⁻¹ display similar vertical slopes implying similar spectral characteristics of the material at all altitudes. We calculated a mean vertical extinction profile for each latitude and derived the ratio of the haze scale height (H_haze) to the pressure scale height (H_gas) as a function of altitude. We inferred H_haze/H_gas values varying from 0.8 to 2.4. The aerosol scale height varies with altitude and also with latitude. Overall, the haze extinction does not show strong latitudinal variations but, at 1 mbar, an increase by a factor of 1.5 is observed at the north pole compared to high southern latitudes. The vertical optical depths at 0.5 and 1.7 mbar increase from 55°S to 5°N, remain constant between 5°N and 30°N and display little variation at higher latitudes, except the presence of a slight local maximum at 45°N. The spectral dependence of the haze vertical optical depth is uniform with latitude and displays three main spectral features centered at 630 cm⁻¹, 745 cm⁻¹ and 1390 cm⁻¹, the latter showing a wide tail extending down to ∼1000 cm⁻¹. From 600 to 750 cm⁻¹, the optical depth increases by a factor of 3 in contrast with the absorbance of laboratory tholins, which is generally constant. We derived the mass mixing ratio profiles of haze at the nine latitudes. Below the 0.4-mbar level all mass mixing ratio profiles increase with height. Above this pressure level, the profiles at 40°N, 45°N, 55°N, at the edge of the polar vortex, display a decrease-with-height whereas the other profiles increase. The global increase with height of the haze mass mixing ratio suggest a source at high altitudes and a sink at low altitudes. An enrichment of haze is observed at 0.1 mbar around the equator, which could be due to a more efficient photochemistry because of the strongest insolation there or an accumulation of haze due to a balance between sedimentation and upward vertical drag.     

Bearing strength of lunar soil

Bearing load vs penetration curves have been measured on a 1.3 g sample of lunar soil from the scoop of the Surveyor 3 soil mechanics surface sampler, using a circular indentor 2 mm in diameter. Measurements were made in an Earth laboratory, in air. This sample provided a unique opportunity to evaluate earlier, remotely controlled, in-situ measurements of lunar surface bearing properties. Bearing capacity, measured at a penetration equal to the indentor diameter, varied from 0.02–0.04 N cm^–2 at bulk densities of 1.15 g cm^–3 to 30-100 N cm^–2 at 1.9 g cm^–3. Deformation was by compression directly below the indentor at bulk densities below 1.61 g cm^–3, by outward displacement at bulk densities over 1.62 g cm^–3. Preliminary comparison of in-situ remote measurements with those on returned material indicates good agreement if the lunar regolith at Surveyor 3 has a bulk density of 1.6 g cm^–3 at 2.5 cm. depth; definitive comparison awaits both better data on bulk density of the undisturbed lunar soil and additional mechanical-property measurements on returned material.     

Plasma temperatures from alouette 1 electron density profiles

Values of plasma temperature and vertical temperature gradient were obtained by fitting theoretical models to 60,000 observed electron density profiles, at heights of 400–1000 km. Results show the diurnal and seasonal changes in temperature from 75°S to 85°N near solar minimum. At night the temperature and temperature gradient are both low inside the plasmapause and high outside. Day-time temperatures increase almost linearly with latitude, from 1500 K at the magnetic equator to a maximum of 3500 K at the plasmapause. There is also a sharp peak at 77° latitude, beneath the magnetospheric cleft. Mean vertical temperature gradients are $\text{ca. 0.5}\text{K}\text{km}$ at night, and 1–4 K/km during the day. The downwards flow of heat, during the day, increases from about zero at 10° latitude to a maximum of $\text{4 × 10}{}^9\text{eV}\text{cm}{}^2\text{sec}$ at the plasmapause. Night-time flows are 5–20 times less, inside the plasmasphere. Increases in magnetic activity cause a temperature increase at 400 km, of about 70 K per unit increase in K_p at all latitudes greater than 65°. The temperature peaks at the plasmapause and the magnetospheric cleft show little increase with magnetic activity, but move equatorwards by ca. 2° in latitude per unit K_p.     

Equatorial ozone profiles from the solar maximum mission—a comparison with theory

The u.v. spectrometer polarimeter on the Solar Maximum Mission has been utilized to measure mesospheric ozone vs altitude profiles by the technique of solar occultation. Sunset data are presented for 1980, during the fall equinoctal period within ± 20° of the geographic equator. Mean O₃, concentrations are 4.0 × 10¹⁰ cm^?3at 50 km, 1.6 × 10¹⁰ cm^?3 at 55 km. 5.5 × 10⁹ cm^?3 at 60 km and 1.5 × 10⁹ cm^?3 at 65 km. Som profiles exhibit altitude structure which is wavelike. The mean ozone profile is fit best with the results of a time-dependent model if the assumed water vapor mixing ratio employed varies from 6 ppm at 50 km to 2–4 ppm at 65 km.     

Infrared polarization of venus: Its periodic fluctuations and evidence for thin haze

Infrared polarimetry of Venus over the phase angles from 18 to 171° has been made extending previous measurements (S. Sato, K. Kawara, Y. Kobayashi, H. Okuda, K. Noguchi, T. Mukai, and S. Mukai (1980). Icarus43, 288) in both wavelength λ and phase angle θ. The results of polarization measurements at 2.25 μm ? λ ? 5.0 μm are (i) small positive and negative values at K(2.25 μm), (ii) a remarkable variation with λ in the CVF(2.2?4.2μm) filter region, (iii) a nearly smooth curve as a function of θ having a peak value of ～36% at θ ～ 90° at both 3.6 μm and L′(3.8 μm), and (iv) a decrease with increasing field of view at M(5.0 μm) due to the contamination of thermal emission from the dark crescent. Furthermore, at 3.6 μm and L′(3.8 μm), (v) higher values at the poles than at the equator and (vi) 4.5- to 5.9-day periodic fluctuations are also found. From a comparison with model calculations, the results confirm the existence of a thin haze layer consisting of submicron-size particles above the main clouds of Venus; e.g., its optical thickness is about 0.1 at λ ～ 0.94 μm. In addition, result (vi) could be explained by a variation of the optical thickness of the haze layer or that of the brightness temperature of the main clouds.