Archaean growth structures in the Pilbara,Australia (extended abstract)

Geologie en Mijnbouw -     

Tectonic setting, evolution and orogenic gold potential of the late Mesoarchaean Mosquito Creek Basin, North Pilbara Craton, Western Australia

The geology, evolution, and metallogenic potential of the Mesoarchaean Mosquito Creek Basin remains poorly understood, despite the presence of several orogenic gold deposits. The basin is dominated by medium- to coarse-grained, poorly sorted and chemically immature sandstone and conglomerates, characterised by very high Cr/Th, high Th/Sc, and low Zr/Sc relative to average continental crust. These features are consistent with the presence of significant mafic rocks in the source terrain(s), a limited role for sediment recycling, and deposition in an increasingly distal passive margin setting on the southeastern edge of the Palaeo- to Mesoarchaean East Pilbara Terrane.New U–Pb SHRIMP data on 358 detrital zircons indicate a conservative maximum depositional age of 2972 + 14/−37 Ma (robust median; 96.1% confidence). Zircon provenance spectra from conglomeratic rocks near the base of the unit are consistent with substantial derivation from the East Pilbara Terrane, but finer-grained sandstones higher in the stratigraphy appear to have been sourced elsewhere, as their zircon age spectra are not well matched by any of the exposed Pilbara terranes.The Mosquito Creek Basin was deformed before and during collision with the northern edge of the Mesoarchaean Kurrana Terrane, which resulted in the development of macroscopic north-verging folds, thrust faulting, and widespread sub-greenschist to greenschist facies metamorphism. This collisional event probably took place at ca. 2900 Ma, based on two identical Pb–Pb model ages of 2905 ± 9 Ma from epigenetic galena associated with vein-hosted gold–antimony mineralization. The metallogenic potential of the Mosquito Creek Basin remains largely unevaluated; however, the possibility of a passive margin setting and continental basement points to relatively limited potential for the formation of major orogenic gold deposits.     

Geochronological constraints on early volcanic evolution of the Pilbara Block,Western Australia

U‐Pb isotopic systems of zircons from the Boobina and Spinaway Porphyries from the Precambrian Pilbara Block of Western Australia indicate ages of 3307± 19 Ma and 2768 ± 16 Ma, respectively. The Boobina Porphyry intrudes upper members of the Archaean greenstones of the Warrawoona Group. The Spinaway Porphyry intrudes basal units of the unconformably overlying volcanics and sediments of the Mt Bruce Supergroup. The age of the Boobina Porphyry, together with previous zircon U‐Pb and whole rock Sm‐Nd age determinations on stratigraphically older units, indicate that early Archaean volcanism in the Pilbara took place between 3560 Ma and 3300 Ma. On the basis of the age determination of the Spinaway Porphyry, and the chronometric definition of 2500 Ma for the Archaean—Proterozoic boundary, by the International Subcommis‐sion on Precambrian Stratigraphy (James H. L. 1978, Precambrian Res. 7, 193–204), the lower units of the Mt Bruce Supergroup should now be assigned to the Archaean.     

40Ar/39Ar and U-Pb dating in the eastern Pilbara,Australia; temporal constraints on structural and metamorphic events between 3.5 and 2.8 Ga (extended abstract)

Geologie en Mijnbouw -     

Genesis of the channel iron deposits (CID) of the Pilbara region,Western Australia

Miocene fluvial goethite/hematite channel iron deposits (CID) are part of the Cenozoic Detritals 2 (CzD2), of the Western Australian Pilbara region. They range from gravelly mudstones through granular rocks to intraformational pebble, cobble and rare boulder conglomerates, as infill in numerous meandering palaeochannels in a mature surface that includes Precambrian granitoids, volcanics, metasediments, BIF and ferruginous Palaeogene valley fill. In the Hamersley Province of the Pilbara, the consolidated fine gravels and subordinate interbedded conglomerates, with their leached equivalents, are a major source of export iron ore. This granular ore typically comprises pedogenically derived pelletoids comprising hematite nuclei and goethite cortices (ooids and lesser pisoids), with abundant coarser goethitised wood/charcoal fragments and goethitic peloids, minor clay, and generally minimal porous goethitic matrix, with late-stage episodic solution and partial infill by secondary goethite, silica and siderite (now oxidised) in places. Clay horizons and non-ore polymictic basal and marginal conglomerates are also present. The accretionary pedogenic pelletoids were mostly derived from stripping of a mature ferruginous but apparently well-vegetated surface, developed in the Early to Middle Miocene on a wide variety of susceptible rock types including BIF, basic intrusives and sediments. This deep ferruginisation effectively destroyed most remnants of the original rock textures producing a unique surface, very different to those that produced the underlying CzD1 (Palaeogene) and the overlying CzD3 (Pliocene – Quaternary). The peloids were derived both intraformationally from fragmentation and reworking of desiccated goethite-rich muds, and from the regolith. Tiny wood/charcoal fragments replaced in soil by goethite, and dehydrated to hematite, formed nuclei for many pelletoids. Additionally, abundant small (≤10 mm) fragments of wood/charcoal, now goethite, were probably replaced in situ within the consolidating CID. This profusion of fossil wood, both as pelletoid nuclei and as discrete fragments, suggests major episodic wild fires in heavily vegetated catchments, a point supported by the abundance of kenomagnetite – maghemite developed from goethite in the pelletoids, but less commonly in the peloids. The matrix to the heterogeneous colluvial and intraformational components is essentially goethite, primarily derived from modified chemically precipitated iron hydroxyoxides, resulting from leaching of iron-rich soils in an organic environment, together with goethitic soil-derived alluvial material. Major variations in the granular ore CID after deposition have resulted from intermittent groundwater flow in the channels causing dissolution and reprecipitation of goethite and silica, particularly in the basal CID zones, with surface weathering of eroded exposures playing a role in masking some of these effects. However, significant variations in rock types in both the general CID and the granular ore CID have also resulted from the effects of varied provenance.     

Tectonic evolution of the southern Gawler Craton,South Australia,from electromagnetic sounding

Long-period natural-source electromagnetic data have been recorded using portable three-component magnetometers at 39 sites in 1998 and 2002 across the southern Eyre Peninsula, South Australia that forms part of the Gawler Craton. Site spacing was of order 5 km, but reduced to 1 km or less near known geological boundaries, with a total survey length of approximately 50 km. A profile trending east – west was inverted for a 2D electrical resistivity model to a depth of 20 km across the southern Eyre Peninsula. The main features from the models are: (i) on the eastern side of the Gawler Craton, the Donington Suite granitoids to the east of the Kalinjala Shear Zone are resistive (>1000 Ωm); (ii) the boundary between the Donington Suite granitoids and the Archaean Sleaford Complex, which has much lower resistivity of 10 – 100 Ωm, is almost vertical in the top 10 km and dips slightly westwards; and (iii) two very low resistivity (<1 Ωm) arcuate zones in the top 3 km of Hutchison Group sediments correlate with banded iron-formations, and are probably related to biogenic-origin graphite deposits concentrated in fold hinges. Such features suggest an extensional regime during the time period 2.00 – 1.85 Ga. We suggest that the resistivity boundary between the Donington Suite and the Archaean Sleaford Complex represents a growth fault, typical for rift systems that evolve into a half-graben structure. In the graben basin, low-resistivity shallow-marine Hutchison Group sediments were deposited. Folding of the sediments during the Kimban Orogeny between 1.74 and 1.70 Ga has led to migration of graphite to the fold hinges resulting in linear zones of very low resistivity that correlate with banded iron-formation magnetic anomalies.     

Granite ages within the Archaean Pilbara Block,Western Australia

Within the Pilbara Block of Western Australia, a complex of migmatite, gneissic and foliated granite near Marble Bar is intruded by a stock of younger massive granite (the Moolyella Granite) with which swarms of tin‐bearing pegmatites are associated. The age of the older granite has been determined by the Rb‐Sr method as 3,125 ± 366 m.y., and that of the Moolyella Granite as 2,670 ± 95 m.y. Initial Sr⁸⁷/Sr⁸⁶ ratios suggest that the older granite is close to primary crustal material, but that the Moolyella Granite consists of reworked material. It probably formed by partial remelting of the older granite.     

Accretion and stabilisation of the Archaean Zimbabwe Craton (extended abstract)

Geologie en Mijnbouw -     

Provenance and deformation history of the Eastern Thomson Orogen and implications for the Paleozoic evolution of the Tasmanides (Eastern Australia)

Abstract

Cambrian deformation associated with the Delamerian Orogeny is most evident in the Delamerian Orogen (southwestern Tasmanides) but has also been documented in the Thomson Orogen (northern Tasmanides). The tectonic evolution of the Thomson Orogen in the context of the Delamerian Orogeny is poorly understood. In particular, tectonostratigraphic relationships between the different parts of the Thomson Orogen (Anakie Inlier, Nebine Ridge, and southern Thomson Orogen) are still unclear. New detrital zircon data from the Nebine Ridge revealed an age spectrum that is consistent with published geochronological data from the Anakie Inlier. These results, in conjunction with petrographic observations and the interpretation of geophysical data, suggest that along the eastern part of the Thomson Orogen, the?～?NNE-trending Nebine Ridge represents the southward continuation of the?～?N–S-trending Anakie Inlier. New detrital zircon geochronological data are also presented for metasedimentary rocks from both sides of the Thomson–Lachlan boundary. The results constrain the maximum age of deposition (Ordovician–Devonian), and show that both sides of the Thomson–Lachlan boundary received detritus from a similar provenance. This might suggest that the Thomson–Lachlan boundary did not play a major role as a crustal-scale boundary prior to the Devonian. We speculate that transpressional deformation along this?～?E–W boundary, during the Early Devonian, was responsible for disrupting the original belt that connected the Delamerian Orogen (Koonenberry Belt) with the eastern Thomson Orogen (Nebine Ridge and Anakie Inlier).

1. Highlights

2. The Nebine Ridge is the southward continuation of the Anakie Inlier.

3. The Anakie Inlier and Nebine Ridge represent a northern segment of the Cambrian Delamerian–Thomson Belt.

4. ～E–W-trending crustal-scale structures at the southern Thomson Orogen were active during Devonian.

     

Geochemistry of Archean shales from the Pilbara Supergroup,Western Australia

Archean clastic sedimentary rocks are well exposed in the Pilbara Block of Western Australia. Shales from turbidites in the Gorge Creek Group (ca. 3.4 Ae) and shales from the Whim Creek Group (ca. 2.7 Ae) have been examined. The Gorge Creek Group samples, characterized by muscovite-quartzchlorite mineralogy, are enriched in incompatible elements (K, Th, U, LREE) by factors of about two, when compared to younger Archean shales from the Yilgarn Block. Alkali and alkaline earth elements are depleted in a systematic fashion, according to size, when compared with an estimate of Archean upper crust abundances. This depletion is less notable in the Whim Creek Group. Such a pattern indicates the source of these rocks underwent a rather severe episode of weathering. The Gorge Creek Group also has fairly high B content (85 ± 29 ppm) which may indicate normal marine conditions during deposition.Rare earth element (REE) patterns for the Pilbara samples are characterized by light REE enrichment ($\text{La}{}_{\mathrm{N}}\text{Yb}{}_{\mathrm{N}}\text{≥ 7.5}$) and no or very slight Eu depletion ($\text{Eu}\text{Eu}{}^1\text{= 0.82 – 0.99}$). A source comprised of about 80% felsic igneous rocks without large negative Eu-anomalies (felsic volcanics, tonalites, trondhjemites) and 20% mafic-ultramafic volcanics is indicated by the trace element data. Very high abundances of Cr and Ni cannot be explained by any reasonable provenance model and a secondary enrichment process is called for.     

澳大利亚皮尔巴拉克拉通威思奈尔金矿控矿构造

澳大利亚西部Pilbara(皮尔巴拉)克拉通的金矿化多与岩浆作用及构造形变事件有关。位于Pilbara克拉通中部的Mallina(马利纳)盆地是该区金矿化最为丰富的地区之一,其构造以强烈褶皱及横贯盆地的Mallina剪切带为主要特征,盆地内最大的金矿床Withnell（威思奈尔）矿床位于Mallina剪切带北侧,是典型的赋存于浊积岩中的构造控矿脉型金矿床。通过细致研究地表露头及岩芯特征,使用DIPS软件处理构造数据,揭示区内典型金矿化构造控矿要素,确立在剪切带变形控制下,金矿体的有利赋存构造位置为褶劈理S3发育较好、向南陡倾的剪切构造区,目标矿脉为近直立、向南陡倾的含黄铁矿石英方解石脉,为下一步找矿工作提出新的方向。     

The evolution of Archaean greenstone terrains,Eastern Goldfields Province,Western Australia

Available petrological, structural and geochronological data suggest that metamorphism and deformation of greenstone sequences and the evolution of intrusive granitoids in the Eastern Goldfields Province, Yilgarn Block, were related to a widespread and integrated tectonic event in the time interval 2700-2600 m.y.Polyphase deformation of the greenstone sequences involved the superimposition of a series of upright folds and related subvertical foliations on earlier macroscopic recumbent folds. Metamorphism was imposed rapidly on these previously deformed but relatively unaltered greenstone sequences, synchronously with a third phase of deformation. Static-style metamorphic recrystallization at very low to medium grades occurred over most of the province, but contemporaneous high grade recrystallization of dynamic style was restricted to elongate narrow zones which were also the sites of synkinematic granitoid diapirism. These zones commonly mark the present margins of greenstone belts.The extensive areas between greenstone belts are dominated by outcrops of post-kinematic granitoids whose abundance may be overestimated because of the limited exposure. Their emplacement caused only minor contact metamorphic overprinting on the pre-existing metamorphic patterns. Also present are banded gneisses interpreted as modified basement to the greenstone sequences. These gneisses are enclosed in post-kinematic granitoid batholiths or occur as remnants in synkinematic diapirs within the dynamic domains. All major granitoid groups, including gneisses, are geochemically similar and show parallel but limited variations. Both field and chemical evidence points to the gneisses being parental to intrusive granitoids derived by both anatectic and solid-state processes.The data provide important constraints on any model for greenstone belt evolution. Our preferred model involves a widespread disturbance resembling the kind currently referred to as a “mantle plume”, which initially led to extrusion of mafic and ultramafic magmas via tensional fractures in a sialic crust, then subsequently caused their deformation and metamorphism and generated the intrusive granitoids by widespread reactivation of the basement. The dynamic metamorphic domains may reflect pre-greenstone crustal lineaments that controlled the initial vulcanism. The evolution of Archean greenstone terrains proposed here appears distinct from that of subsequent Proterozoic and Phanerozoic tectonic belts.     

One billion years of Archean history, Pilbara Craton, Western Australia

The Pilbara is an important region for the study of early Earth history, primarily because it contains large areas of volcanics and sediments, as old as 3550 million years, that are commonly extremely well preserved as a result of an exceptionally heterogeneous tectonic overprint during cratonisation. This latter event was completed by 2800 million years ago and hence much of the cover sequence up to the classic Hamersley banded iron formation is Archean in age.     

Constraints on the age of the Warrawoona Group, eastern Pilbara Block, Western Australia

Zircons from mafic and felsic volcanic rocks in the type area of the Warrawoona Group, the basal Archaean greenstone succession of the eastern Pilbara Block, have been dated precisely using the ion-microprobe SHRIMP. The results allow two alternative time-frames for the duration of the Warrawoona Group, dependent on how the dated zircons are considered to relate to the volcanic rocks. Our favoured interpretation requires a hiatus of 135±5 Ma between the Duffer Formation at 3.46 Ga and the overlying felsic volcanic rocks of the Wyman Formation, and a hydrothermal or later magmatic origin for zircons of age 3.33 Ga within one Duffer Formation sample and the underlying metabasalts. The alternative time-frame requires a short time for deposition of the entire Group, less than 15 Ma at 3.33 Ga, and a xenocrystic origin for the 3.46 Ga zircons of the Duffer Formation. Outside the type area of the Warrawoona Group, the age of an intrusive granodiorite requires that greenstones be older than 3.43 Ga and the Group formed over an interval of > 120 Ma.Visibly different zircons within one of the Duffer Formation samples were found to be Palaeozoic in age and presumably constitute hydrothermal growth of new zircon within the rock at low temperature. Similar zircons were found within samples from other rock units but with a spread of Proterozoic ages.     

Lead isotopes and ages of Galenas from the Pilbara region,Western Australia

One of six galena samples from the Pilbara of Western Australia, located in a ‘greenstone’ sequence, appears from its lead‐isotope ratios to be of great age. ‘Linear Model III’ ages of Cumming & Richards (1975) agree with available geological evidence for this, and for one other younger sample located in the Shaw Batholith. Two of the other samples, also from Archaean granitic host rock, appear to be significantly younger than the host; the other two, from within the Lower Proterozoic Fortescue Group, suggest that its age is not yet well known. Previously‐published age information has been adapted to the newly‐accepted values for the decay constants throughout this discussion.     

Tectonic evolution of the Lachlan Orogen,southeast Australia: Historical review,data synthesis and modern perspectives

The Lachlan Orogen,like many other orogenic belts,has undergone paradigm shifts from geosynclinal to plate-tectonic theory of evolution over the past 40 years. Initial plate-tectonic interpretations were based on lithologic associations and recognition of key plate-tectonic elements such as andesites and palaeo-subduction complexes. Understanding and knowledge of modern plate settings led to the application of actualistic models and the development of palaeogeographical reconstructions, commonly using a non-palinspastic base. Igneous petrology and geochemistry led to characterisation of granite types into ‘I’ and ‘S’, the delineation of granite basement terranes, and to non-mobilistic tectonic scenarios involving plumes as a heat source to drive crustal melting and lithospheric deformation. More recently, measurements of isotopic tracers (Nd, Sr, Pb) and U–Pb SHRIMP age determinations on inherited zircons from granitoids and detrital zircons from sedimentary successions led to the development of multiple component mixing models to explain granite geochemistry. These have focused tectonic arguments for magma genesis again more on plate interactions. The recognition of fault zones in the turbidites, their polydeformed character and their thin-skinned nature, as well as belts of distinct tectonic vergence has led to a major reassessment of tectonic development. Other geochemical studies on Cambrian metavolcanic belts showed that the basement was partly backarc basin- and forearc basin-type oceanic crust. The application of ⁴⁰Ar–³⁹Ar geochronology and thermochronology on slates,schist and granitoids has better constrained the timing of deformation and plutonism,and illite crystallinity and b_o mica spacing studies on slates have better defined the background metamorphic conditions in the low-grade parts. The Lachlan deformation pattern involves three thrust systems that constitute the western Lachlan Orogen, central Lachlan Orogen and eastern Lachlan Orogen. The faults in the western Lachlan Orogen show a generalised east-younging (450–395 Ma), which probably relates to imbrication and rock uplift of the sediment wedge, because detailed analyses show that the décollement system is as old in the east as it is in the west. Overall, deformation in the eastern Lachlan Orogen is younger (400–380 Ma), apart from the Narooma Accretionary Complex (ca 445 Ma). Preservation of extensional basins and evidence for basin inversion are largely restricted to the central and eastern parts of the Lachlan Orogen. The presence of dismembered ophiolite slivers along some major fault zones, as well as the recognition of relict blueschist metamorphism and serpentinite-matrix mélanges requires an oceanic setting involving oceanic underthrusting (subduction) for the western Lachlan Orogen and central Lachlan Orogen for parts of their history. Inhibited by deep weathering and a general lack of exposure, the recent application of geophysical techniques including gravity, aeromagnetic imaging and deep crustal seismic reflection profiling has led to greater recognition of structural elements through the subcrop, a better delineation of their lateral continuity, and a better understanding of the crustal-scale architecture of the orogen. The Lachlan Orogen clearly represents a class of orogen, distinct from the Alps, Canadian Rockies and Appalachians, and is an excellent example of a Palaeozoic accretionary orogen.     

Tectonic vs. gravitational morphostructures in the central Eastern Alps (Italy): Constraints on the recent evolution of the mountain range

Deep-seated gravitational slope deformations (DSGSDs) influence landscape development in tectonically active mountain ranges. Nevertheless, the relationships among tectonics, DSGSDs, and topography are poorly known. In this paper, the distribution of DSGSDs and their relationships with tectonic structures and active processes, surface processes, and topography were investigated at different scales. Over 100 DSGSDs were mapped in a 5000 km² sector of the central Eastern Alps between the Valtellina, Engadine and Venosta valleys. Detailed lineament mapping was carried out by photo-interpretation in a smaller area (about 750 km²) including the upper Valtellina and Val Venosta. Fault populations were also analysed in the field and their mechanisms unravelled, allowing to identify different structural stages, the youngest being consistent with the regional pattern of the ongoing crustal deformation. Finally, four DSGSD examples have been investigated in detail by geological and 2D geomechanical modelling.DSGSDs affect more than 10% of the study area, and mainly cluster in areas where anisotropic fractured rock mass and high local relief occur. Their onset and development is subjected to a strong passive control by mesoscopic and major tectonic features, including regional nappe boundaries as well as NW–SE, N–S and NE–SW trending recent brittle structures. The kinematic consistency between these structures and the pattern of seismicity suggests that active tectonics may force DSGSDs, although field evidence and numerical models indicate slope debuttressing related to deglaciation as a primary triggering mechanism.     

Genetic modelling for banded iron-formation of the Hamersley Group, Pilbara Craton, Western Australia

The banded iron-formation (BIF) of the Hamersley Group, Pilbara Craton, Western Australia, particularly from the well studied Dales Gorge Member, is unique in its lateral stratigraphic and petrological continuity throughout an area exceeding 60,000 km², enabling reasonable estimates for the annual input of components to the depository. In the model of this paper, varying supply of materials for the medley of mesoband types, particularly of iron and silica in the oxide BIF, can be accommodated by the interaction of two major oceanic supply systems: (1) surface currents and (2) convective upwelling from mid-oceanic ridge (MOR) or hot-spot activity, both modified by varied input of pyrochastic material. (1) The surface currents were saturated in silica and carried minimal iron due to photic precipitation, but were periodically recharged by storm mixing. Precipitation from them gave rise to the banded chert-rich horizons, including the varves, whose regular and finely laminated iron/silica distribution resulted from seasonal meteorological influences. (2) Precipitation from convection driven upwelling of high iron solution from MOR or hot-spot activity periodically overwhelmed the delicate seasonal patterns of (1) to produce the iron-dominated mesobands. A wide range of intermediate mesoband types resulted where the deep water supply was modified by varied MOR activity, or by partial blocking of upwelling waters by surface currents (such as by the present El Niño). During these periods of oxide-dominated BIF, silica was deposited from saturated solution mainly by evaporative concentration, and iron by oxidation due to photolysis and photosynthetically produced oxygen.Superimposed on these supply differences was the varying effect of fine aluminous ash from dominantly northern distal volcanic sources, changing the meteorological and depositional conditions. Occasional input of extremely fi ash during BIF precipitation produced mesoband (cm) scale variations involving increased carbonate-silicate precipitation. Sustained volcanic periods resulted in S-macroband deposition (chert-carbonate-silicate BIF, with shale), gradually returning to the dominant hematite-magnetite-chert BIF as the volcanic input waned. During volcanic periods, the normally high capacity of sunlight to precipitate ferric iron directly by photolytic oxidation of ferrous iron, and by photosynthetic production of oxygen, was modified by turbidity in the atmosphere (aerosols and dust) and in the water (colloids from reactive ash). S Surface-precipitated ferric hydroxyoxide redissolved in the presence of decaying organic matter in the subphotic zone, augmenting the iron content of the zone. Precursor ferrous carbonates and silicates were precipitated when the iron concentration of this sub-photic zone exceeded their respective solubilities. During volcanism, the increased availability of nutrients, particularly phosphorus, to surface waters increased the organic contribution despite lower light values, leading to an almost total absence of ferric iron oxides in the S macrobands (i.e. no magnetite or hematite). Cooling of warm, silica-saturated sea-water during these periods of “olcanic winter” increased the ratio of precipitation of silica to iron, which, however, was still controlled by seasonal conditions. Intermediate concentrations of organic matter, insufficient to totally convert the ferric compounds either during precipitation or diagenesis, resulted in overgrowths of magnetite on hematite, and eventually in the substantial conversion of hematite to magnetite, where higher temperatures were achieved during low-grade regional metamorphism.Changes in sea-level to explain facies changes in BIF are not required in this model, but are not excluded. The preferred conditions are for a very low oxygen to anoxic atmosphere, a much higher level of MOR activity than at present, the presence of photosynthetic plankton, the absence of si silica-secreting organisms, and a deep sea-water temperature higher than 20°C. However, none of these conditions is essential to the model.A narrow carbonate bank is postulated for part of the Fortescue River Valley area during Marra Mamba Iron Formation times (basal Hamersley Group), with BIF precipitation on either side. The reef is postulated to have grown northward becoming a major shallow-water carbonate platform on the Pilbara continent during upper Marra Mamba Iron Formation and Wittenoom Dolomite times, but ceased to play an important role in subsequent periods.     

Tectonic elements controlling the evolution of the Gulf of Saros (northeastern Aegean Sea, Turkey)

Tectonic elements controlling the evolution of the Gulf of Saros have been studied based upon the high-resolution shallow seismic data integrated with the geological field observations. Evolution of the Gulf of Saros started in the Middle to Late Miocene due to the NW–SE compression caused by the counterclockwise movement of the Thrace and Biga peninsulas along the Thrace Fault Zone. Hence, the North Anatolian Fault Zone is not an active structural element responsible for the starting of the evolution of the Gulf of Saros. The compression caused by the rotational movement was compensated by tectonic escape along the pre-existing Ganos Fault System. Two most significant controllers of this deformation are the sinistral Ganos Fault and the dextral northern Saros Fault Zone both extending along the Gulf of Saros. The most important evidences of this movement are the left- and right-oriented shear deformations, which are correlated with structural elements, observed on the land and on the high-resolution shallow seismic records at the sea. Another important line of evidence supporting the evolution of this deformation is that the transgression started in the early-Late Miocene and turned, as a result of regional uplift, into a regression on the Gelibolu Peninsula during the Turolian and in the north of the Saros Trough during the Early Pliocene. The deformation on the Gelibolu Peninsula continued effectively until the Pleistocene. Taking into account the fact that this deformation affected the Late Pleistocene units of the Marmara Formation, the graben formation of the Gulf of Saros is interpreted as a Recent event. However, at least a small amount of compression on the Gelibolu Peninsula is observed. It is also evident that compression ceased at the northern shelf area of the Gulf of Saros.     

Manganese oxide mineralogy,petrography and genesis,Pilbara Manganese Group,Western Australia

Supergene manganese oxides, occurring in shales, breccias and dolomites of Proterozoic Age, in the Western Australian Pilbara Manganese Group, have Mn/Fe ranging from 1.9 to 254 and Mn⁴⁺ to Mn (Total) of 0.49–0.94. The manganese mineralogy is dominated by tetravalent manganese oxides, especially by cryptomelane, with lesser amounts of pyrolusite, nsutite, manjiroite, romanechite and other manganese oxide minerals. The manganese minerals are commonly associated with iron oxides, chiefly goethite, indicating incomplete separation of Mn from Fe during Tertiary Age arid climate weathering of older, manganiferous formations. These manganese oxides also contain variable amounts of braunite and very minor hausmannite and bixbyite. The braunite occurs in three generations: sedimentary-diagenetic, recrystallised sedimentary-diagenetic, and supergene. The mode of origin of the hausmannite and bixbyite is uncertain but it is possible that they resulted from diagenesis and/or low-grade regional metamorphism. The supergene manganese deposits appear to have been derived from manganiferous Lower Proterozoic banded iron formations and dolomites of the Hamersley Basin and overlying Middle Proterozoic Bangemali Basin braunite-containing sediments.