Aerosol Hygroscopicity during the Haze Red-Alert Period in December 2016 at a Rural Site of the North China Plain

A humidification system was deployed to measure aerosol hygroscopicity at a rural site of the North China Plain during the haze red-alert period 17–22 December 2016. The aerosol scattering coefficients under dry [relative humidity (RH) < 30%] and wet (RH in the range of 40%–85%) conditions were simultaneously measured at wavelengths of 450, 550, and 700 nm. It is found that the aerosol scattering coefficient and backscattering coefficient increased by only 29% and 10%, respectively when RH went up from 40% to 80%, while the hemispheric backscatter fraction went down by 14%, implying that the aerosol hygroscopicity represented by the aerosol scattering enhancement factor f(RH) is relatively low and RH exerted little effects on the aerosol light scattering in this case. The scattering enhancement factors do not show significant differences at the three wavelengths, only with an approximate 2% variation, suggesting that the aerosol hygroscopicity is independent of the wavelength. Aerosol hygroscopicity is highly dependent on the aerosol chemical composition. When there is a large mass fraction of inorganics and a small mass fraction of organic matter, f(RH) reaches a high value. The fraction of NO₃^– was strongly correlated with the aerosol scattering coefficient at RH = 80%, which suggests that NO₃^– played an important role in aerosol hygroscopic growth during the heavy pollution period.     

Influence of water vapor and aerosol on the integral transparency of the atmosphere

The temporal variability of the total atmospheric water content W and the connection of the coefficient of integral transparency P ₂, reduced to the air mass m = 2, with W and aerosol optical depth τ _a ,λ₀ at a wavelength of 550 nm were analyzed and studied from the observational data of the Meteorological Observatory of Moscow State University for 50 years (1955–2004). The regression equations between mean daily and monthly τ _a ,λ₀ and τ₂ = ?ln P ₂ were derived in different months and seasons and can be used for retrieving τ _a ,λ₀ from the coefficient of the integral transparency for the temperate latitudes. The P ₂ intervals are given for which these equations can be used.     

Spectral investigation of the diffuse-to-direct solar beam irradiances ratio (UV–VIS) in the urban Athens atmosphere

This study explores the influence of air gaseous pollutants–aerosols and solar zenith angle (SZA) on the spectral diffuse-to-direct beam E _dλ/E _bλ irradiances ratio. It does so using ground-based spectroradiometric measurements taken over the Athens atmosphere during May 1995. It was found that the spectral E _dλ/E _bλ ratio decreases rapidly with increasing wavelength and regression curves of the form E _dλ/E _bλ = aλ^?b fitted the experimental data. These curves are strongly modified by aerosols–air pollutants, aerosol optical properties, and SZA. The log–log plot of E _dλ/E _bλ versus λ reveals a significant departure from linearity, which is likely to be associated with aerosol physical properties and SZA effects. The effect of atmospheric turbidity, as expressed through the aerosol optical at 500 nm and SZA on the spectral E _dλ/E _bλ ratio, is investigated in detail for two discernible atmospheric conditions observed in the urban Athens atmosphere. The first case includes different atmospheric turbidity levels under the same SZA, while the second corresponds to different SZA values under the same turbidity levels. It was found that the correlation between E _dλ/E _bλ and spectral aerosol optical depth can be a useful tool in determining the aerosol optical properties and aerosol types composition.     

Measurement of IO radical concentrations in the marine boundary layer using a cavity ring-down spectrometer

An open-path cavity ring-down spectroscopy (CRDS) instrument for measurement of atmospheric iodine monoxide (IO) radicals has been tested in the laboratory and subsequently deployed in Roscoff on the north-west coast of France as part of the Reactive Halogens in the Marine Boundary Layer (RHaMBLe) project in September 2006. In situ measurements are reported of local IO mixing ratios in the marine boundary layer. To obtain these mixing ratios, accurate absorption cross sections of IO are required at the selected wavelengths used for spectroscopic measurements. Absorption cross sections at the bandheads of the IO A²Π_3/2–X²Π_3/2 (3,0) and (2,0) vibronic bands were thus verified by a combination of spectral simulation methods, inter-comparison of prior determinations of cross-sections at high and low spectral resolution, and by measurement of rates of loss of IO by its self-reaction. The performance of the open-path CRDS instrument was tested by measuring concentrations of NO₂ in ambient air, both within and outside the laboratory, with results that were in excellent agreement with a previously validated continuous wave CRDS apparatus for NO₂ detection. During the RHaMBLe campaign, the open-path CRDS instrument was located within a few metres of the shoreline and operated at wavelengths close to 435 nm to detect the absorption of light by trace levels of IO. The IO mixing ratios were obtained on two days, peaked close to low tide, and were approximately 5–10 times higher than values calculated from column densities previously reported by long-path, differential optical absorption spectroscopy (DOAS) in coastal regions. The typical detection limit of the instrument was estimated to be 10 pptv of IO, with some fluctuation around this value depending on the conditions of wind and atmospheric aerosol particles, and the total accumulation time was 30 s for each data point. The observations of relatively high concentration of IO, compared to the values previously reported by DOAS, are consistent with the concurrent observations using a LIF (Laser induced Fluorescence) instrument (Whalley et al. in press). The first such measurements of localized IO by CRDS and LIF should contribute to an improved understanding of the chemistry of halogen compounds and the formation of iodine oxide aerosol particles in the marine boundary layer.     

Measurement of the photodissociation coefficient of NO2 in the atmosphere: I. Method and surface measurements

An instrument, specifically designed for measurements from a balloon platform in the stratosphere, has been used to obtain ground-level values of the atmospheric photodissociation coefficient of nitrogen dioxide, J _{NO 2}.A typical clear-sky value is 8.0×10^-3 s^-1 when the solar zenith angle is 40°. Measurements were made as a function of solar zenith angle and correlated with a calibrated Eppley UV radiometer. It is shown that J _{NO 2}may be expressed as a simple function of the radiometer output so that estimates of J _{NO 2}can be made using just an upward looking radiometer to an accuracy of about 20%. The measurements are also found to be in good agreement with calculations of J _{NO 2}using a simplified isotropic multiple scattering computer routine.     

Available energy and energy balance closure at four coniferous forest sites across Europe

The available energy (AE), driving the turbulent fluxes of sensible heat and latent heat at the earth surface, was estimated at four partly complex coniferous forest sites across Europe (Tharandt, Germany; Ritten/Renon, Italy; Wetzstein, Germany; Norunda, Sweden). Existing data of net radiation were used as well as storage change rates calculated from temperature and humidity measurements to finally calculate the AE of all forest sites with uncertainty bounds. Data of the advection experiments MORE II (Tharandt) and ADVEX (Renon, Wetzstein, Norunda) served as the main basis. On-site data for referencing and cross-checking of the available energy were limited. Applied cross checks for net radiation (modelling, referencing to nearby stations and ratio of net radiation to global radiation) did not reveal relevant uncertainties. Heat storage of sensible heat J _H, latent heat J _E, heat storage of biomass J _veg and heat storage due to photosynthesis J _C were of minor importance during day but of some importance during night, where J _veg turned out to be the most important one. Comparisons of calculated storage terms (J _E, J _H) at different towers of one site showed good agreement indicating that storage change calculated at a single point is representative for the whole canopy at sites with moderate heterogeneity. The uncertainty in AE was assessed on the basis of literature values and the results of the applied cross checks for net radiation. The absolute mean uncertainty of AE was estimated to be between 41 and 52 W m^?2 (10–11 W m^?2 for the sum of the storage terms J and soil heat flux G) during mid-day (approximately 12% of AE). At night, the absolute mean uncertainty of AE varied from 20 to about 30 W m^?2 (approximately 6 W m^?2 for J plus G) resulting in large relative uncertainties as AE itself is small. An inspection of the energy balance showed an improvement of closure when storage terms were included and that the imbalance cannot be attributed to the uncertainties in AE alone.     

Fourier transform measurement of NO2 absorption cross-section in the visible range at room temperature

New laboratory measurements of NO₂ absorption cross-section were performed using a Fourier transform spectrometer at 2 and 16 cm^-1 (0.03 and 0.26 nm at 400 nm) in the visible range (380–830 nm) and at room temperature. The use of a Fourier transform spectrometer leads to a very accurate wavenumber scale (0.005 cm^-1, 8×10^-5 nm at 400 nm). The uncertainty on the new measurements is better than 4%. Absolute and differential cross-sections are compared with published data, giving an agreement ranging from 2 to 5% for the absolute values. The discrepancies in the differential cross-sections can however reach 18%. The influence of the cross-sections on the ground-based measurement of the stratospheric NO₂ total amount is also investigated.     

Effects of seed particle size and composition on heterogeneous nucleation of n-nonane

Heterogeneous nucleation of supersaturated n-nonane vapour on seed particles of different size and composition has been investigated using a fast expansion chamber. Monodisperse seed particle sizes were ranging from about 4 nm up to about 24 nm in diameter. By using different types of particle generators WO_x, Ag and (NH₄)₂SO₄ particles were generated. For direct comparison between different particle compositions overlapping sizes have been generated for WO_x and Ag at about 7 nm particle diameter as well as for Ag and (NH₄)₂SO₄ at about 15 nm. Nucleation temperature was kept constant at about 278 K. Experimental data were compared to Kelvin equation and Fletcher theory including the effect of line tension. It was found that heterogeneous nucleation of n-nonane seems to be independent of seed particle composition and starts well below the Kelvin curve. Good agreement was achieved with Fletcher theory including the effect of line tension.     

A Closure Study of Aerosol Hygroscopic Growth Factor during the 2006 Pearl River Delta Campaign

Measurements of aerosol physical, chemical and optical parameters were carried out in Guangzhou, China from 1 July to 31 July 2006 during the Pearl River Delta Campaign. The dry aerosol scattering coefficient was measured using an integrating nephelometer and the aerosol scattering coefficient for wet conditions was determined by subtracting the sum of the aerosol absorption coefficient, gas scattering coefficient and gas absorption coefficient from the atmospheric extinction coefficient. Following this, the aerosol hygroscopic growth factor, f(RH), was calculated as the ratio of wet and dry aerosol scattering coefficients. Measurements of size-resolved chemical composition, relative humidity (RH), and published functional relationships between particle chemical composition and water uptake were likewise used to find the aerosol scattering coefficients in wet and dry conditions using Mie theory for internally- or externally-mixed particle species [(NH₄)₂SO₄, NH₄NO₃, NaCl, POM, EC and residue]. Closure was obtained by comparing the measured f(RH) values from the nephelometer and other in situ optical instruments with those computed from chemical composition and thermodynamics. Results show that the model can represent the observed f(RH) and is appropriate for use as a component in other higher-order models.     

Trend analysis of rainfall time series for Sindh river basin in India

The main goal of this paper is to estimate a set of optimal seasonal, daily, and hourly values of atmospheric turbidity and surface radiative parameters Ångström’s turbidity coefficient (β), Ångström’s wavelength exponent (α), aerosol single scattering albedo (ω_o), forward scatterance (F_c) and average surface albedo (ρ_g), using the Brute Force multidimensional minimization method to minimize the difference between measured and simulated solar irradiance components, expressed as cost functions. In order to simulate the components of short-wave solar irradiance (direct, diffuse and global) for clear sky conditions, incidents on a horizontal surface in the Metropolitan Area of Rio de Janeiro (MARJ), Brazil (22° 51′ 27″ S, 43° 13′ 58″ W), we use two parameterized broadband solar irradiance models, called CPCR2 and Iqbal C, based on synoptic information. The meteorological variables such as precipitable water (u_w) and ozone concentration (u_o) required by the broadband solar models were obtained from moderate-resolution imaging spectroradiometer (MODIS) sensor on Terra and Aqua NASA platforms. For the implementation and validation processes, we use global and diffuse solar irradiance data measured by the radiometric platform of LabMiM, located in the north area of the MARJ. The data were measured between the years 2010 and 2012 at 1-min intervals. The performance of solar irradiance models using optimal parameters was evaluated with several quantitative statistical indicators and a subset of measured solar irradiance data. Some daily results for Ångström’s wavelength exponent α were compared with Ångström’s parameter (440–870 nm) values obtained by aerosol robotic network (AERONET) for 11 days, showing an acceptable level of agreement. Results for Ångström’s turbidity coefficient β, associated with the amount of aerosols in the atmosphere, show a seasonal pattern according with increased precipitation during summer months (December–February) in the MARJ.     

Determination des echanges verticaux moyens dans la couche limite planetaire a partir des donnees statistiques obtenues par les radiosondages de temperature

We have studied the vertical structure of the planetary boundary layer (PBL) as well as the vertical exchanges between this layer and the free atmosphere, using average macroscopic temperature data obtained from radiosondes. For this study we have used, for seven months in 1972, twice-daily radiosondes (00 and 12 H) from Trappes (Paris area) and PointK (Atlantic Ocean). The vertical structure of the PBL is given in the first part of the present work in terms of monthly average statistical parameters (vertical temperature gradient, frequency and level of inversion layers, frequency and thickness of mixing layers). We have thus demonstrated for the continental station, the influence of the daily cycle on the vertical temperature gradient; we have determined the monthlyH _M level above which the daily variation is not noticed. However, for the oceanic station, the absence of a daily cycle makes the temperature gradients at 00 and 12 H identical. The study of temperature inversion layers clearly indicates a high probability of their existence between 1500 and 2000 m; this probability is more than 80% both in summer at PointK, and in winter at Trappes. Similarly, we have demonstrated the annual evolution of the level of these elevated inversions at the two stations. An identical process has been performed in the case of the mixing layers. In the second part of our study, we have used a relationship between the vertical temperature gradient and the coefficients of matter exchange (K _z ), obtained from natural radioactive tracers (Guedaliaet al., 1974). Statistics have thus been obtained on the values ofK _z in the various layers above the two stations. These statistics prove that for the two stations and above 1500 m, values of the coefficients between 1 and 5 m² s^?1 are the most frequent; on the other hand, below 1500 m, the distribution of the coefficientsK _z offers different characteristics according to the month and to the station considered. Finally, we have used the concept of ‘equivalent coefficient’ -K _e - to characterize the exchanges between two levels considered as a whole. We have made a comparison of the values ofK _e when in the 0–1000 m layer and when in the 0–2000 m layer. The equivalent coefficientK _e allows us to compare the average exchanges above the two areas; thus, in summer, between the 0 and 1000 m level, the exchanges are more important above Trappes than they are above Point K. On the other hand, whatever may be the vertical structure of the PBL below, the value ofK _e in the 0–2000 m-layer is always between 1 and 5 m² s^?1. A generalisation of such a study applied to better chosen continental and oceanic sites would allow a comprehensive view of the structure of the PBL as well as of the turbulent exchanges between the PBL and the free atmosphere.     

A comparison of ABL heights inferred routinely from lidar and radiosondes at noontime

The height of the atmospheric boundary layer (ABL) obtained with lidar and radiosondes is compared for a data set of 43 noon (12.00 GMT) cases in 1984. The data were selected to represent the synoptic circulation types appropriately. Lidar vertical profiles at 1064 nm were used to obtain three estimates for the ABL height (h _lid), based on the first gradient in the back-scatter profile, namely, at the beginning, middle and top of the gradient. The boundary-layer height obtained with the radiosondes (h _s) was determined with the dry-parcel-intersection method in unstable conditions. As a first guess for near-neutral and stable conditions, the height of the first significant level in the potential temperature profile was taken. Overall, the boundary-layer thickness estimates agree surprisingly well (regression lineh _lidb=h_s:cc.=0.93 and the standard error=121 m). However, in 10% of the cases, the lidar estimate was significantly lower (difference>400 m) than the routinely inferredh _s. These outliers are discussed separately. For stable conditions, an estimate of ABL height (h _N) is also made based on the friction velocity and the Brunt-Väisälä frequency. The agreement betweenh _Nandh _lidbis good. Discrepancies between the two methods are caused by:

1. rapid growth of the boundary layer arround the measurement time;
2. the presence of a deep entrainment layer leading to a large zone in which quantities are not well mixed;
3. a large systematic error of 100–200 m in the estimate of boundary-layer height obtained from the radiosonde due to the way that profiles are recorded, as a series of significant points.

     

Oxidation of sulphur compounds in the atmosphere: I. Rate constants of OH radical reactions with sulphur dioxide,hydrogen sulphide,aliphatic thiols and thiophenol

The reactions of OH radicals with SO₂, H₂S, thiophenol, and a series of aliphatic thiols (1–5 C-atoms) have been investigated in 201 and 381 reaction chambers at 1 atm total pressure and 300 K using a competitive kinetic technique. Initially, OH radicals were produced by photolysis of CH₃ONO/NO mixtures in air. Applying this OH source rate constants for OH with SO₂, H₂S, and thiophenol in synthetic air were determined to be (1.1±0.2)×10^-12, (5.5±0.8)×10^-12 and (1.1±0.2)×10^-11 cm³ s^-1, respectively. However, when this method was applied to the aliphatic thiols the rate constants obtained were found to be dependent on the partial pressures of O₂ and NO. These effects have been attributed to the built-up of a radical species, not yet identified, which leads to uncontrolled chain reactions in the system. Using the photolysis of H₂O₂ at wavelengths greater than 260 nm as the OH source in 1 atm N₂, rate constants for the 1–5 aliphatic thiols in the range 2.9 to 5.6×10^-11 cm³ s^-1 were obtained. The rate constants obtained in the present study are compared with recent literature values.     

Impact of surface variations on the momentum flux above the urban canopy

Based on the momentum flux–wind profile relationship of the Monin–Obukhov Similarity (MOS) theory, the observational data from the urban boundary layer field campaign in Nanjing are used to calculate the friction velocity ( $ {u_*} $ ) at the top of the urban canopy and the calculated results are evaluated. The urban surface roughness parameters (the roughness length z ₀ and zero-plane displacement height z _d) are estimated with the Ba method (Bottema’s morphological method). Two different regimes are employed for the calculations. In the homogeneous approach, z ₀ and z _d are averagely derived from the surface elements in the whole study area; while in the heterogeneous approach, z ₀ and z _d are locally derived from the surface elements in the corresponding upwind fetches (or source areas). The calculated friction velocities are compared to the measurement data. The results show that the calculated friction velocities from the heterogeneous approach are in better agreement with the observed values than those from the homogeneous approach are. This study implies that the local roughness parameters can properly represent the dynamical heterogeneity of urban surface, and its application can significantly improve the performance of parameterizations based on the MOS theory in the urban roughness sublayer.     

High resolution spectral features of a series of aromatic hydrocarbons and BrO: Potential interferences in atmospheric OH-measurements

Naphthalene (C₁₀H₈), several other hydrocarbons, mostly derivates of naphthalene, and bromine oxide (BrO) were analyzed for narrow band (0.01 nm) absorption lines in the wavelength range between 307.7 and 308.3 nm to study their potential impact on OH radical measurements by differential absorption spectroscopy.Only naphthalene showed narrow band absorption lines in this wavelength region. From nine naphthalene lines the differential absorption cross-section was determined.The strongest naphthalene line at 308.002 nm is close to the Q ₁(2) OH line, but about a factor of 200 weaker (=(65.2±15.3)×10^-20 cm²/molec). The corresponding detection limit for naphthalene is about 15 ppt. We re-evaluated some spectra of our OH measurement campaign in July 1987 with respect to naphthalene and obtained an upper limit of 30 ppt for its concentration.BrO was recorded in the larger wavelength interval between 307.7 and 308.7 nm. Structured absorptions were only observed at wavelengths above 308.2 nm and no significant structures were found in the vicinity of the Q ₁(2) and Q ₁(3) OH lines.     

True gravity in ocean dynamics Part 1 Ekman transport

The direction normal to the Earth spherical (or ellipsoidal) surface is not vertical (called deflected vertical) since the vertical direction is along the true gravity g (= ig_λ+ jg_φ+ kg_z). Here, (λ, φ, z) are (longitude, latitude, depth), and (i, j, k) are the corresponding unit vectors. The spherical (or ellipsoidal) surfaces are not horizontal surfaces (called deflected-horizontal surfaces). The most important body force g (true gravity) has been greatly simplified without justification in oceanography to the standard gravity (-g₀k) with g₀ = 9.81 m/s². Impact of such simplification on ocean dynamics is investigated in this paper using the Ekman layer model. In the classical Ekman layer dynamic equation, the standard gravity (-g₀k) is replaced by the true gravity g(λ, φ, z) with a constant eddy viscosity and a depth-dependent-only density ρ(z) represented by an e-folding near-inertial buoyancy frequency. New Ekman spiral and in turn new formulae for the Ekman transport are obtained for ocean with and without bottom. With the gravity data from the global static gravity model EIGEN-6C4 and the surface wind stress data from the Comprehensive Ocean-Atmosphere Data Set (COADS), large difference is found in the Ekman transport using the true gravity and standard gravity.     

Experiments on scalar dispersion within a model plant canopy,part III: An elevated line source

An experiment is reported in which heat was released as a passive tracer from an elevated lateral line source within a model plant canopy, with h _s = 0.85 h _c (h _s and h _c being the source and canopy heights, respectively). A sensor assembly consisting of three coplanar hot wires and one cold wire was used to measure profiles of mean temperature % MathType!MTEF!2!1!+-% feaafeart1ev1aaatCvAUfeBSjuyZL2yd9gzLbvyNv2CaerbuLwBLn% hiov2DGi1BTfMBaeXatLxBI9gBaerbd9wDYLwzYbItLDharqqtubsr% 4rNCHbGeaGqiVu0Je9sqqrpepC0xbbL8F4rqqrFfpeea0xe9Lq-Jc9% vqaqpepm0xbba9pwe9Q8fs0-yqaqpepae9pg0FirpepeKkFr0xfr-x% fr-xb9adbaqaaeGaciGaaiaabeqaamaabaabaaGcbaGaaiikamaana% aabaGaeqiUdehaaiaacMcaaaa!390C!\[(\overline \theta )\], temperature variance (Σ_θ ²), vertical and streamwise turbulent heat fluxes, and third moments of wind and temperature fluctuations. Conclusions were:

1. Despite the very heterogeneous flow within the canopy, the observed dispersive heat flux (due to spatial correlation between time-averaged temperature and vertical velocity) was small. However, there is evidence from the plume centroid (which was lower than h _s at the source) of systematic recirculating motions within the canopy.
2. The ratio % MathType!MTEF!2!1!+-% feaafeart1ev1aaatCvAUfeBSjuyZL2yd9gzLbvyNv2CaerbuLwBLn% hiov2DGi1BTfMBaeXatLxBI9gBaerbd9wDYLwzYbItLDharqqtubsr% 4rNCHbGeaGqiVu0Je9sqqrpepC0xbbL8F4rqqrFfpeea0xe9Lq-Jc9% vqaqpepm0xbba9pwe9Q8fs0-yqaqpepae9pg0FirpepeKkFr0xfr-x% fr-xb9adbaqaaeGaciGaaiaabeqaamaabaabaaGcbaGaeq4Wdm3aaS% baaSqaaiabeI7aXjaab2gacaqGHbGaaeiEaaqabaGccaGGVaWaa0aa% aeaacqaH4oqCaaWaaSbaaSqaaiaab2gacaqGHbGaaeiEaaqabaaaaa!41DF!\[\sigma _{\theta {\text{max}}} /\overline \theta _{{\text{max}}} \] (of maximum values on vertical profiles) decreased from 1 near the source to an asymptotic value of 0.4 far downstream, in good agreement with previous experimental and theoretical work for concentration fluctuations in the surface layer well above the canopy.
3. The eddy diffusivity for heat from the line source (K _HL ) increased, downstream of the source, to a nearly constant ‘far-field’ vertical profile. Within the canopy, the far-field K _HL was an order of magnitude larger than K _HP , the equivalent diffusivity for a plane source; well above the canopy, the two were equal. The time scale defined by (far-field K _HL )/(vertical velocity variance) was independent of height within the canopy.
4. Budgets for temperature variance, vertical heat flux and streamwise heat flux are remarkably similar to the equivalent budgets for an elevated line source in the surface layer well above the canopy, except in the lower part of the canopy in the far field, where vertical transport is much more important than in the surface layer.
5. A random flight simulation of the mean height and depth of the temperature plume was generally in good agreement with experiment. However, details of the temperature and streamwise turbulent heat flux profiles were not correct, suggesting that the model formulation needs to be improved.

     

气溶胶散射相函数的单站观测研究

利用2014年夏季在河北饶阳开展的“华北区域光化学立体试验”观测得到气溶胶辐射特性,根据三波长角散射浊度仪Aurora 4000测量获取的前向角散射系数（10°~90°）和后向散射系数,提出了一种基于浊度仪直接测量的气溶胶角散射系数和改进的HG相函数近似获取气溶胶散射相函数、不对称因子的拟合估算方法。分析了2014年6月16日—8月18日夏季观测试验期间河北饶阳地区大气气溶胶细粒子（PM_2.5）在635 nm,525 nm,450 nm 3个波段的不对称因子、相函数等的变化特征。结果表明:用改进的HG相函数近似能够较好地拟合河北饶阳实际观测的PM_2.5的气溶胶散射相函数。拟合得到河北饶阳地区观测期间干气溶胶细粒子在3个波段的平均不对称因子（g）分别为0.53±0.04（635 nm）,0.57±0.05（525 nm）和0.57±0.07（450 nm）。     

The specular and diffuse scattering of the sound in stratified media

Summary The atmosphere and the ocean are greatly distinct in two aspects that determine their fundamental qualitative difference of the sound scattering. (1) A sharp distinction between the state equations in both media. This leads to a great difference in mechanisms of the volume scattering which is mainly caused by directional (dipole and quadruple) and omnidirectional contributors, respectively, in the atmosphere and in the ocean. (2) Atmospheric kinetic coefficients (thermoconductivity, diffusion and viscosity) are close to each other and substantially exceed any of those of the seawater; besides, the latter very differ between each other. These features, with account of commonly employed sound wavelengths and intensities of the turbulence in both media, essentially eliminates an existence of sound specular scattering (reflection) in the atmosphere, however, makes it quite possible in the ocean. Reflective properties of the thin layers in the seawater strongly depend on which type of stratification dominates. At initial stage the temperature layer excels the salinity one in reflectivity by factor 4.7; however, the lifetime of the latter is longer in dozens of times. Theoretically derived amplitude and evolution features of the scattering from the salt layer have been confirmed in laboratory experiment. One more experimental series has been carried out to distinguish the scattering from the reflective layer and microstructure, both co-existing in the wake past a cylinder. An employment of bistatic sounding configuration allows separating both the reflection and diffuse scattering effects, the former is stronger by factor 50. The volume scattering cross-sections, obtained both by an acoustic way and derived by processing of the optical image spectra, are in agreement and follow the function k^–7 of the wave number k.