Geochemistry of a Rapakivi Granite Suite in a Proterozoic Rift Trough in Beijing and Its Vicinity

Controlled by E-W-trending faults, a Proterozoic (1.4-1.8 Ga old) rapakivi granite suite was intruded inBeijing and the area to its east (within Hebei Province), forming three parallel belts of igneous rocks. Theisotopic, trace element and rare earth element geochemical data of a bimodal rock association made up ofanorthosite, gabbro and alkali basalt and olivine-bearing quartz-syenite, rapakivi granite and trachyte as wellas potassic A-type granites and anorogenic granites—— all suggest that there exists an incipient rift in thestudy area. Fractional crystallization of a mixed magma formed by the magma derived from the upper mantleand the magma derived by small degrees of fusion of the lower crust produced anorthosite cumulates. Thewater-deficient granitic magma was differentiated into a subalkaline series. When the fractional crystallizationwas incomplete, rhythmic eruptions took place.     

The Petrology and Origin of the Tertiary Lundy Granite (Bristol Channel, UK)

The British Tertiary Volcanic Province (BTVP) comprises within-platecentral igneous complexes associated with plateau lavas andregional dyke swarms. Lundy is the southernmost complex of theBTVP and comprises granite ({small tilde}90%) emplaced intodeformed Devonian sedimentary rocks within the Hercynian Cornubiangranite province of southwest England. The complex is intrudedby a northwest-southeast trending dyke swarm. In common withother BTVP igneous complexes, Lundy is associated with positivegravity and magnetic anomalies which are interpreted in termsof the presena of an underlying basic intrusion at shallow depth,with a volume exceeding that of the overlying granite. The Lundy intrusion is a coarse-grained megacrystic granitecontaining up to 20% alkali feldspar megacrysts in a coarse-grainedgroundmass composed of alkali feldspar, quartz, lithium-bearingmuscovite, and ‘biotite’ (lithian siderophyllite),with a range of aaxssory minerals. The main granite has a coarse-grained(locally miarolitic) pegmatitic facies and is intruded by thinsheets and veins of fine-grained aplite and microgranite. Themineralogy indicates crystallization of the Lundy granite froma highly fractionated H₂O- and halogen-rich magma at a relativelyshallow crustal level. The main Lundy granite is a peraluminous leucogranite with Na₂O=3–4%,K₂O{small tilde}5%, low TiO₂, MeO, CaO, Zr, and Sr, and highRb and Rb/Sr in comparison with many other peralurninous granites,including those from the Cornubian batholith and the BTVP. Anew Rb-Sr whole-rock isochron for the granite yields an ageof 58?7?1?6 Ma with an initial ⁸⁷Sr/86Sr of 0?715?0?006. _Ndvalues for the granite (–0?9 to –1?9) plot betweencontemporaneous mantle (positive _Nd and Cornubian granites (_Nd=ca.–11). The trace element data (Rb, Y, Nb) show affinities with syn-collisionand within-plate granites. As the Sr isotope data indicate amajor crustal component, and the Nd isotope data suggest bothmantle and crustal components, we propose that the Lundy graniteis derived from a parental magma comprising crustal components(derived from a similar source to that of the Cornubian granitebatholith) and a mantle-derived component (derived from a differentiateof contemporaneous basaltic magma This magma experienced fractionalcrystallization of plagioclase, alkai feldspar, Fe-Mg minerals,and REE-bearing accessory minerals before emplacement, and theLundy granite experienced further in situ fractional crystallization,associateded with crustal contamination by the Devonian shaleafter emplacement.     

Petrogenetic relationships between peralkaline rhyolite dykes and mafic rocks in the post-Variscan gabbroic complex from Bocca di Tenda (northern Corsica, France)

The Lower Permian complex from Bocca di Tenda (Corsica island, France) consists of a gabbroic sequence crosscut by chilled dykes ranging in composition from basalt to trachyandesite and peralkaline rhyolite. The gabbroic sequence is mostly composed of olivine gabbronorites, quartz gabbronorites/diorites locally displaying high ilmenite amounts, and hornblende-rich tonalites. The quartz gabbronorites/diorites and the hornblende-rich tonalites have similar initial ε_Nd values (+0.9 to ?1.1) and record a fractional crystallization process driven by separation of plagioclase, pyroxene, and ilmenite. The olivine gabbronorites have slightly higher initial ε_Nd than the quartz gabbronorites/diorites and the hornblende-rich tonalites, thereby documenting that the early evolution of the melts that gave rise to the gabbroic sequence was controlled by concomitant fractional crystallization and crustal assimilation. The trachyandesite dykes are rare and rich in dark mica. The selected trachyandesite has initial ε_Nd of +0.4, which is slightly lower than the ε_Nd of the basalt dykes. The basalt and the trachyandesite dykes are most likely genetically related through a process of fractional crystallization controlled by segregation of plagioclase, clinopyroxene and minor ilmenite, and assimilation of crustal material. The peralkaline rhyolites have initial ε_Nd values ranging from +0.3 to ?0.3. Whole-rock chemical variations and trace element compositions of Na-amphibole (arfvedsonite) indicate that the peralkaline rhyolite dykes record a process of fractional crystallization mainly controlled by separation of alkali feldspar and minor ilmenite and arfvedsonite. A plausible petrogenetic hypothesis for the genesis of the peralkaline rhyolite melts implies a protracted process of fractional crystallization from the trachyandesitic melts. This fractionation process would be initially ruled by separation of plagioclase, dark mica, and minor ilmenite. An alternative hypothesis for the origin of the peralkaline rhyolite melts implies partial melting of nearly coeval amphibole-rich mafic intrusives, which formed by crustally contaminated mantle-derived melts. The genesis of the peralkaline rhyolites is in any case correlated with mantle-derived melts that experienced extensive crustal contamination.     

Magmatic Evolution of the Ordovician Snowdon Volcanic Centre, North Wales (UK)

The Ordovician Snowdon Volcanic Centre (SVC) of North Walescomprises a bimodal basalt–subalkaline/peralkaline associationemplaced around a caldera within a shallow marine environment.The tectonic setting was associated with closure of the LowerPalaeozoic Iapetus Ocean and cessation of ocean plate subduction.The SVC volcanic products include basaltic lavas and pyroclasticrocks, rhyolitic pyroclastic flow deposits, high-level intrusions,domes, and flows, together with reworked equivalents. A programmeof detailed field mapping, sampling, and chemical analysis hasbeen used to evaluate the structure and magmatic evolution ofthe SVC volcanic system. SVC basalts show a range in chemicalcharacteristics between volcanic arc type and within-plate,ocean island basalt (OIB) type. Subalkaline, silica-oversaturatedintermediate intrusions (icelandites) and five chemically distinctgroups of extrusive and intrusive subalkaline/peralkaline rhyolites(termed A1, A2, B1, B2, and B3) were emplaced during the evolutionof the SVC. This evolution was driven by material and thermalinput from basaltic magma. The SVC basaltic lavas were derivedas partial melts from a heterogeneous volcanic arc to OIB-typespinel lherzolite mantle and experienced up to 60% olivine gabbrofractionation during storage in sill networks in the sub-crustor lower crust. Some magma batches experienced further fractionalcrystallization ({small tilde}70%) and minor crustal contamination({small tilde}10%) to yield the icelandites. Trace element andNd isotope data do not favour an origin for the rhyolites bypartial or total fusion of likely crustal material, and thefive rhyolite groups are regarded as distinct homogeneous batchesof magma derived from varied basaltic magmas. The icelanditesand peralkaline rhyolites (group B3) result, respectively, from{small tilde}50% and {small tilde}80–90% zircon-free fractionalcrystallization of SVC basalts. The subalkaline rhyolites (groupsA1 and B1) result from {small tilde}80–90% fractionalcrystallization of subduction-related basalts similar to thoseof Ordovician basalts which pre-date the Lower Rhyolitic TuffFormation, and groups A2 and B2 were formed by mixing and homogenizationof A1, B1, and B3 magma batches. These data and interpretationsprovide the basis of a model for the complex evolution of asilicic magma system below the SVC caldera around the time ofcessation of Caledonian subduction in North Wales. Rhyolitemagma chambers were short lived and discontinuous; the largestwas probably disc shaped and was almost entirely evacuated duringa >60-km³ ash-flow eruption.     

Petrogenesis and tectonic setting of the peralkaline Pine Canyon caldera, Trans-Pecos Texas, USA

The Pine Canyon caldera is a small (6–7 km diameter) ash-flow caldera that erupted peralkaline quartz trachyte, rhyolite, and high-silica rhyolite lavas and ash-flow tuffs about 33–32 Ma. The Pine Canyon caldera is located in Big Bend National Park, Texas, USA, in the southern part of the Trans-Pecos Magmatic Province (TPMP). The eruptive products of the Pine Canyon caldera are assigned to the South Rim Formation, which represents the silicic end member of a bimodal suite (with a “Daly Gap” between 57 and 62 wt.% SiO₂); the mafic end member consists primarily of alkali basalt to mugearite lavas of the 34–30 Ma Bee Mountain Basalt. Approximately 60–70% crystallization of plagioclase, clinopyroxene, olivine, magnetite, and apatite from alkali basalt coupled with assimilation of shale wall rock (M_a/M_c = 0.3–0.4) produced the quartz trachyte magma. Variation within the quartz trachyte–rhyolite suite was the result of 70% fractional crystallization of an assemblage dominated by alkali feldspar with subordinate clinopyroxene, fayalite, ilmenite, and apatite. High-silica rhyolite is not cogenetic with the quartz trachyte–rhyolite suite, and can be best explained as the result of  5% partial melting of a mafic granulite in the deep crust under the fluxing influence of fluorine. Variation within the high-silica rhyolite is most likely due to fractional crystallization of alkali feldspar, quartz, magnetite, biotite, and monazite. Lavas and tuffs of the South Rim Formation form A-type rhyolite suites, and are broadly similar to rock series described in anorogenic settings both in terms of petrology and petrogenesis. The Pine Canyon caldera is interpreted to have developed in a post-orogenic tectonic setting, or an early stage of continental rifting, and represents the earliest evidence for continental extension in the TPMP.     

Geochemical and geochronological study of the Sanshui basin bimodal volcanic rock suite,China: Implications for basin dynamics in southeastern China

Sanshui basin is one of the typical Mesozoic–Cenozoic intra-continental rift basins with voluminous Cenozoic volcanic rocks in southeastern China. Thirteen cycles of volcanic eruptions and two dominant types of volcanic rocks, basalt and trachyte–rhyolite, have been identified within the basin. Both basalt and trachyte–rhyolite members of this bimodal suit have high values of εNd (+2.3 to +6.2) and different Sr isotopic compositions (initial ⁸⁷Sr/⁸⁶Sr ratios are 0.70461–0.70625 and 0.70688–0.71266 for basalts and trachyte–rhyolite, respectively), reflecting distinct magma evolution processes or different magma sources. The results presented in this study indicate that both of the trachyte–rhyolite and basaltic magmas were derived from similar independent primitive mantle, but experienced different evolution processes. The trachyte-rhyolitic magma experienced significant clinopyroxene and plagioclase fractionational crystallization from deeper magma chamber with significant crustal contamination, while the basaltic magmas experienced significant olivine and clinopyroxene fractionational crystallization in shallower magma chamber with minor crustal contamination. New zircon U–Pb dating confirms an initial volcanic eruption at 60 Ma and the last activity at 43 Ma. Geologic, geochemical, and geochronological data suggest that the inception of the Sanshui basin was resulted from upwelling of a mantle plume. The Sanshui basin widened due to subsequent east–west extension and the subsequent volcanism constantly occurred in the center of the basin. Evidence also supports a temporal and spatial association with other rift basins in southeastern China. The upwelling mantle plume became more active during late Cenozoic time and most likely triggered opening of other basins, including the young South China Sea basin.     

广东三水盆地始新世火山岩地球化学特征

广东三水盆地的演化伴随着强烈的火山活动.为研究三水盆地各类岩石之间的演化关系, 对在盆地内的玄武岩、粗面岩和流纹岩样品进行常量、微量元素地球化学分析.对样品的地球化学投图表明: 玄武岩样品表现为轻稀土富集的板内玄武岩稀土配分模式, 而其微量元素也具有Nb、Ti富集、Sr弱亏损的特征, 由部分熔融产生;粗面岩与流纹岩样品稀土与微量元素配分模式相似, 两类岩石均经历以斜长石为主的分离结晶过程.华南陆缘在始新世早期处于与红海相似的大陆裂谷环境, 喷发来源于深部软流圈地幔的岩浆, 但在42 Ma之后, 火山活动因区域挤压作用而停止.其后的南海扩张可能是两种作用的叠加影响的结果.      

A potassium-rich Alkalic Suite from the Deccan Traps,Rajpipla, India

The Rajpipla Alkalic Suite is the most potassium-enriched group of basaltic rocks so far described from the Deccan Traps. In the same area however early tholeiitic flows and late tholeiitic dykes show the potassium-poor nature characteristic of most Deccan Trap magmas. The rocks of the alkalic suite are highly porphyritic and their major element variation can be interpreted in terms of crystal fractionation dominated by clinopyroxene. Plagioclase, which is an important phenocryst phase, has fractionated only in relatively small amounts as a result of a lack of density contrast between it and the liquids. A dyke-like form for the magma chambers in which fractionation has taken place is postulated to account for the abundance of highly porphyritic types. The Rajpipla area is also notable as being one of the few Deccan localities where rhyolites are found.Abbreviations AB ankaramitic basalt - PB porphyritic basalt - PTB porphyritic trachybasalt - FPM feldsparphyric mugearite - M mugearite - TR trachyte - P. RHY potassic rhyolite - Th. B. tholeiitic basalt - Th. D. tholeiitic dolerite - Af alkali feldspar     

Geochemical constraints on the origin of bimodal magmatism at the Okinawa Trough, an incipient back-arc basin

The magmatism at the axial zone of the middle Okinawa Trough, a young continental back-arc basin, comprises a bimodal basaltic–rhyolitic suite, accompanied by minor intermediate rocks. We report major and trace element and Sr–Nd isotopic data for the intermediate to silicic suites, to provide constraints on their petrogenesis. The rhyolites, recovered as lava and pumice, fall into three geochemical groups (type 1, 2, and 3 rhyolites). Type 1 rhyolites have ⁸⁷Sr/⁸⁶Sr (0.7040–0.7042) and ¹⁴³Nd/¹⁴⁴Nd (0.5128–0.5129) identical to those of associated basalts, and are characterized by highly fractionated REE patterns. Petrogenesis of type 1 rhyolites is explicable in terms of fractional crystallization of the associated basalt. In contrast, type 2 rhyolites and andesite have slightly higher ⁸⁷Sr/⁸⁶Sr (0.7044–0.7047) but similar ¹⁴³Nd/¹⁴⁴Nd (0.5128) compared to those of the basalts. The compositions of type 2 rhyolite and andesite can be explained by assimilation and fractional crystallization (AFC) processes of the basalt magma; quantitative analysis suggests assimilation/fractional crystallization (M_a/M_c) ratios of ≤0.05. Hybrid andesite generated by mixing of evolved basalt and type 1 rhyolite is also present. We emphasize that mechanical extension in this part of the Okinawa Trough involves gabbroic lower crust that resulted from fractionation of mantle-derived basaltic magmas. Type 3 rhyolite occurs only as pumice, which makes its derivation questionable. This rhyolite has major and trace element compositions and Sr–Nd isotopic ratios, which suggests that it may be derived from volcanic activity on the southern Ryukyu volcanic front, and arrived in the Okinawa Trough by drifting on the Kuroshio Current.     

Petrology of the Nandewar Volcano,N.S.W., Australia

The Nandewar Mountains, N.S.W., Australia, are the remains of a Miocene continental alkaline volcano whose products range from olivine basalts to comendites and alkali rhyolites. Intermediate hawaiites, mugearites and benmoreites predominate in the shield, in which olivine basalts are rare, and the trachytic rocks form many intrusions into the shield. The Nandewar alkaline series shows extreme fractionation of a relatively differentiated alkali olivine basalt magma, saturated with silica, to yield extremely oversaturated peralkaline comendites and peraluminous alkali rhyolites. The nature of the ferromagnesian phases forming was controlled by low oxygen fugacities. Throughout the series clinopyroxenes range from diopsidic augite, through sodic ferrohedenbergites to hedenbergite-acmite solid solutions. Riebeckite-arfvedsonite solid solutions appear in the trachytes and comendites, and aenigmatite appears in some of the peralkaline rocks. The feldspars in the series fractionate from calcic labradorite through potash oligoclase and calcic anothoclase towards the minimum melting alkali feldspar composition, Ab₆₅Or₃₅. The compositions of the alkali rhyolites approach the minimum in the system SiO₂-KAlSi₃O₈-NaAlSi₃O₈. All the mineralogical and chemical evidence points to the development of the Nandewar series by the processes of extreme crystallization differentiation of an alkali olivine basalt parent magma. No significant contamination occurred, xenoliths and xenocrysts are absent, and volatile transfer and metasomatism played a minor role.     

Malani Rhyolites — A Review

The late Proterozoic Malani bimodal volcanics constitute the largest suite of anorogenic acid volcanics in India. The volcanism took place during 745±10 Ma ago, succeeding the granitic activity of Abu pluton and ceased before the onset of Marwar sedimentation.On the basis of field evidences, three stages of igneous activity have been recognised. Volcanics of the first stage are mostly basalt with occasional andesite or trachybasalts. These are subsequently covered by the voluminous outpouring of peralkaline and peraluminous rhyolite, basalt, dacite and trachyte flows. The third stage ceased with the outburst of ash flow deposits.The dominant felsic volcanics are rhyolites and rhyodacites spread over an area of about 31, 000 km². The other rock types associated with rhyolite are trachytes, dacites, pitchstone, welded tuff, vitric, lithic and crystal ash, ignimbrite, obsidian, pyroclastic slates, agglomerate, volcanic breccia and volcanic conglomerates. Majority of the acid volcanics are high potassic and a few are calcalkaline or low potassic in composition.Feldspar geothermometry suggests the temperature of equilibrium to be above 650°C. Similar results were obtained by magnetite-ulvospinel geothermometry. Oxygen fugacity is estimated to be about 10⁻¹⁸ under FMQ-Ni-NiO buffer conditions.Malani volcanism was essentially under terrestrial conditions, although deposition by aqueous conditions are also indicated. The volcanic eruptions have been through fissures, shield volcanoes and central cones. The volcanism was triggered in an extensional tectonic regime of continental crust, where geotherm was raised by the repeated influx of basic magma. The initial basaltic magma was possibly generated at deeper depth by ‘hot spot’ activity. This magma while migrating upwards supplied additional heat for the partial melting of lower sialic crust resulting in the generation of felsic magma. The crustal extension has helped in the upward advancement of the felsic magma.     

Origin of metaluminous and alkaline volcanic rocks of the Latir volcanic field,northern Rio Grande rift,New Mexico

Volcanic rocks of the Latir volcanic field evolved in an open system by crystal fractionation, magma mixing, and crustal assimilation. Early high-SiO₂ rhyolites (28.5 Ma) fractionated from intermediate compositionmagmas that did not reach the surface. Most precaldera lavas have intermediate-compositions, from olivine basaltic-andesite (53% SiO₂) to quartz latite (67% SiO₂). The precaldera intermediate-composition lavas have anomalously high Ni and MgO contents and reversely zoned hornblende and augite phenocrysts, indicating mixing between primitive basalts and fractionated magmas. Isotopic data indicate that all of the intermediate-composition rocks studied contain large crustal components, although xenocrysts are found only in one unit. Inception of alkaline magmatism (alkalic dacite to high-SiO₂ peralkaline rhyolite) correlates with, initiation of regional extension approximately 26 Ma ago. The Questa caldera formed 26.5 Ma ago upon eruption of the >500 km³ high-SiO₂ peralkaline Amalia Tuff. Phenocryst compositions preserved in the cogenetic peralkaline granite suggest that the Amalia Tuff magma initially formed from a trace element-enriched, high-alkali metaluminous magma; isotopic data suggest that the parental magmas contain a large crustal component. Degassing of water- and halogen-rich alkali basalts may have provided sufficient volatile transport of alkalis and other elements into the overlying silicic magma chamber to drive the Amalia Tuff magma to peralkaline compositions. Trace element variations within the Amalia Tuff itself may be explained solely by 75% crystal fractionation of the observed phenocrysts. Crystal settling, however, is inconsistent with mineralogical variations in the tuff, and crystallization is thought to have occurred at a level below that tapped by the eruption. Spatially associated Miocene (15-11 Ma) lavas did not assimilate large amounts of crust or mix with primitive basaltic magmas. Both mixing and crustal assimilation processes appear to require development of relatively large magma chambers in the crust that are sustained by large basalt fluxes from the mantle. The lack of extensive crustal contamination and mixing in the Miocene lavas may be related to a decreased basalt flux or initiation of blockfaulting that prevented pooling of basaltic magma in the crust.     

二连盆地北缘晚中生代火山岩Ar-Ar年代、地球化学及构造背景

中国东北二连盆地周缘分布有三组时代不同的晚中生代火山岩,其中早、中期为两套地球化学性质不同的流纹岩,晚期为玄武质火山岩。本文通过测定火山岩基质Ar-Ar同位素年龄,表明早期查干诺尔组流纹岩形成于142Ma,晚期不拉根哈达组基性火山岩形成于129Ma,可见二连盆地北缘晚中生代火山岩时代均为早白垩世。通过对主、微量元素地球化学特征和Sr-Nd-Pb同位素组成研究,以及与邻区同期满克头鄂博组英安岩和流纹岩、玛尼吐组英安岩、霍林河地区查干诺尔组英安岩、流纹岩对比,认为早期查干诺尔组流纹岩来源于新成下地壳,岩浆演化过程经历了强烈分异作用;中期流纹岩源区为中上地壳或下地壳岩浆经历了上地壳强烈同化混染作用;晚期不拉根哈达组基性火山岩则源于受俯冲洋壳流体交代的富集岩石圈地幔。结合早白垩世区域岩石圈减薄背景,本文认为研究区早白垩世火山岩形成于陆内伸展构造环境。     

内蒙古正蓝旗地区中生代火山岩锆石U-Pb年龄与板内伸展环境成因讨论

内蒙古东南部正蓝旗地区中生代火山岩广泛出露,岩性主要包括流纹岩、粗面岩、碎斑熔岩、熔结凝灰岩以及黑曜岩等,以碎斑熔岩发育为显著特征。本次研究测得流纹岩、霏细质碎斑熔岩及熔结凝灰岩的LA-ICP-MS锆石U-Pb年龄分别为(141.4±0.7)Ma、(141.6±0.6)Ma和(139.4±0.7)Ma,三者在误差范围内一致,表明研究区火山活动(从溢流、爆发到侵出)持续的时间很短,时代为早白垩世早期,属张家口组。除个别样品,正蓝旗地区晚期侵出的碎斑熔岩与早期溢流相的流纹岩、粗面岩在地球化学特征上极为一致,均为富硅富钾,贫Ca、Mg和Al,属粗面岩-流纹岩组合,部分样品具有碱性流纹岩的特征;富集Rb、Th、U等大离子亲石元素,而强烈亏损Ba、Sr、Ti、P;轻稀土元素(LREE)富集,Eu强烈亏损,轻、重稀土元素分馏较强(LaN/YbN主要介于6.87~42.74)。碎斑熔岩体相较于早期熔岩更加富硅贫碱,表明流纹岩-粗面岩喷溢之后,岩浆房中剩余岩浆又经过一定程度的分异,向更为富硅贫碱方向演化之后侵出地表。正蓝旗地区火山岩具有A型花岗岩的特征,为A_1型为主,A_1—A_2过渡的地球化学特征。碎斑熔岩体与流纹岩-粗面岩的Nb/Ta介于10.46~24.02,在地壳和地幔岩浆Nb/Ta比值之间;Y/Nb、Ti/Yb、Ti/Zr均体现出壳幔混合的特点;Rb/Sr介于0.61~64.51,为壳源特征。因此,研究区火山岩是造山后向板内非造山转换并以板内非造山为主的伸展环境下,经较为强烈地幔物质改造的下地壳部分熔融的产物。     

Chemical and Isotopic Characteristics of the Kuroko‐Forming Volcanism

The Miocene northeast Honshu magmatic arc, Japan, formed at a terrestrial continental margin via a stage of spreading in a back‐arc basin (23–17 Ma) followed by multiple stages of submarine rifting (19–13 Ma). The Kuroko deposits formed during this period, with most forming during the youngest rifting stage. The mode of magma eruption changed from submarine basalt lava flows during back‐arc basin spreading to submarine bimodal basalt lava flows and abundant rhyolitic effusive rocks during the rifting stage. The basalts produced during the stage of back‐arc basin spreading are geochemically similar to mid‐ocean ridge basalt, with a depleted Sr–Nd mantle source, whereas those produced during the rifting stage possess arc signatures with an enriched mantle source. The Nb/Zr ratios of the volcanic rocks show an increase over time, indicating a temporal increase in the fertility of the source. The Nb/Zr ratios are similar in basalts and rhyolites from a given rift zone, whereas the Nd isotopic compositions of the rhyolites are less radiogenic than those of the basalts. These data suggest that the rhyolites were derived from a basaltic magma via crystal fractionation and crustal assimilation. The rhyolites associated with the Kuroko deposits are aphyric and have higher concentrations of incompatible elements than do post‐Kuroko quartz‐phyric rhyolites. These observations suggest that the aphyric rhyolite magma was derived from a relatively deep magma chamber with strong fractional crystallization. Almost all of the Kuroko deposits formed in close temporal relation to the aphyric rhyolite indicating a genetic link between the Kuroko deposits and highly differentiated rhyolitic magma.     

Major and trace element, and Sr-Nd isotope constraints on the origin of Paleogene volcanism in South China prior to the South China Sea opening

Paleogene volcanic rocks crop out in three sedimentary basins, namely, Sanshui, Heyuan and Lienping, in the attenuated continental margin of south China. Lavas from the Sanshui basin which erupted during 64-43 Ma are bimodal, consisting of intraplate tholeiitic basalt and trachyte/rhyolite associations. Similar to Cretaceous A-type granites from the nearby region, the felsic member shows peralkaline nature [Na₂O + K₂O ≈ 10–12%; (Na + K)/Al≈ 0.98−1.08], general enrichment in the incompatible trace elements and significant depletion in Ba, Sr, Eu, P and Ti. Although both types of the Sanshui lavas have rather uniform Nd isotope compositions [_Nd(T) ≈ +6 to +4]that are comparable to Late Cenozoic basalts around the South China Sea, the felsic rocks possess apparently higher initial Sr isotope ratios (I_Sr up to 0.713) and form a horizontal array to the right in the Nd vs. Sr isotope plot. Closed system differentiation of mantle-derived magmas in a ‘double diffusive’ magma chamber is considered for the bimodal volcanism, in which the trachytes and rhyolites represent A-type melts after extensive crystal fractionation in the upper portion of the chamber. Such A-type melts were later contaminated by small amounts (1–3%) of upper crustal materials during ascent. On the other hand, composition of lavas in the other two basins varies from tholeiitic basalt to andesite. Their Sr and Nd isotope ratios [I_Sr ≈ 0.705 to 0.711; _Nd(T) ≈ +1 to − 5] and generally correlative Nb-Ta depletions suggest a distinct magma chamber process involving fractional crystallization concomitant with assimilation of the country rock. We conclude that these Paleogene volcanic activities resulted from the lithospheric extension in south China that migrated southwards and eventually led to opening of the South China Sea during 30-16 Ma.     

Petrogenetic Evolution of the Torfaj?kull Volcanic Complex, Iceland II. The Role of Magma Mixing

In southern Iceland, tholeiitic basalt magmas propagating laterallyfrom the active Eastern Rift Zone into the older cmstal segmentof the South Eastern Zone have been injected into Torfaj?kull,a mature volcanic centre dominated by rhyolites. Eruptions ofcomplex suites of mixed and hybrid rocks have been triggered,involving tholeiites of the rift zone and transitional basaltsand rhyolites of the Torfaj?kull centre. Three-component hybridsare an unusual feature of the activity. The distribution ofvarious magma mixing and hybrid types is related to the periodicinjection of tholeiite into a magma chamber, or chambers, whererhyolite overlies parental transitional basalts. Pre-postglacial rhyolites (>10000 y) at Torfajokull are predominantlyperalkaline, whereas later rhyolites are, with few exceptions,subalkaline. Furthermore, the injection of rift zone magmas,and the consequent abundance of rhyolite-basalt mixing, havebeen important features of magmatism at the centre only in postglacialtimes. Reduced repose times in the magma reservoirs have preventedthe production of peralkaline rhyolites. These trends are interpretedin terms of the southerly migration of the Eastern Rift Zone.     

内蒙古敖汉旗朝吐沟组火山岩LA-ICP-MS锆石U-Pb年龄

内蒙古赤峰敖汉旗一带的朝吐沟组由变基性岩、变质酸性火山岩夹云母石英片岩组成。采用LA-ICP-MS技术,对朝吐沟组2件变流纹岩样品进行了U-Pb同位素测定,获得的锆石206Pb/238U年龄加权平均值分别为359.4±1.4Ma和360.3±1.4Ma,即晚泥盆世法门期,表明朝吐沟组形成于晚泥盆世,而非前人认为的早石炭世。朝吐沟组火山岩石组合为变玄武岩和变流纹岩,显示出典型的双峰式火山岩特征,揭示该区在晚泥盆世处于伸展构造环境。     

Aptian bimodal volcanic associations and granitoids in the northern margin of the Amur microcontinent: Age, sources of material, and geodynamic environments

Data on the composition, age, and source of material of Aptian rocks composing a bimodal volcanic complex and related granitoids in the northern margin of the Amur microcontinent indicate that the granodiorites of the Talalinskii Massif and subalkaline granites of the Dzhiktandiunskii Massif crystallized at 117 ± 2 and 119 ± 2 Ma, respectively (⁴⁰Ar/³⁹Ar method), and their crystallization ages coincide with the age of volcanic rocks of the Gal’kinskii bimodal complex. These data make it possible to combine the rocks within a single volcano-plutonic association. Geochemical and isotopic-geochemical features of trachybasaltic andesites of the Gal’kinskii bimodal complex suggest that the parental melts were derived from such sources as PREMA (or DM) and an enriched source of the EMII type at a subordinate contribution of a crustal source. The parental melts of rhyolites of the Gal’kinskii Complex and granitoids of the Talalinskii and Dzhiktandinskii massifs were derived from crustal material with minor amounts of juvenile material. The bimodal volcanic association and related granitoids dated at 119–115 Ma were most likely formed in geodynamic environments implying the ascent of the asthenospheric mantle.     

Rise and fall of a basalt-trachyte-rhyolite magma system at the Kane Springs Wash Caldera,Nevada

Magmas erupted at the Kane Springs Wash volcanic center record the buildup and decay of a silicic magma chamber within the upper crust between 14.1 and 13.2 Ma ago. Intrusion of a variety of mantle-derived basaltic magmas into the crust sustained the system thermally, but only alkali basalts appear to be parental. Fractionation of alkali basalt, together with 10–20% contamination by partial melts of the lower crust, generated trachyandesite magmas. Mafic trachytes, with magma temperatures of 1,000° C, were initially generated from trachyandesites at depths greater than 15 km. Continued fractionation combined with assimilation of upper crustal melts at a depth of 5–10 km produced more evolved trachytes and high-silica rhyolites. These silicic magmas erupted as the Kane Wash Tuff 14.1 Ma ago from a chamber zoned from fayalite-bearing alkali rhyolite near 820° C at the roof to a trachytic dominant volume. Initial ash flows of the Kane Wash Tuff, Member V1, are metaluminous, whereas later cooling units, Members V2 and V3, are mildly peralkaline and have higher Fe, Zr, and Hf and lower Ca, Th/Ta, Rb/ Zr, and LREE/HREE. Less than 1 % upper crustal component was involved in generation of Members V2 and V3 from trachytic magma. Eruption of 130 km³ of magma resulted in collapse of the Kane Springs Wash caldera. Trachytic magma from deeper levels of the system was extruded onto the caldera floor shortly afterward, forming a central trachyte/syenite complex. Replacement of this magma by hotter, more mafic magma may have induced additional melting of the already heated chamber walls, as high-silica rhyolites that erupted in the moat surrounding the central complex have a large crustal component. Early moat rhyolites had temperatures near 800° C and, in contrast to the Kane Wash Tuff, are ferroedenite-bearing, have higher Al, K/Na, Th/Ta, and Ba, and have lower Fe, REE, and Zr. Fractional crystallization of this magma within the cooling and crystallizing magma chamber formed biotite-bearing rhyolite in isolated pockets. The most evolved of these had temperatures near 700° C, elevated F contents, H₂O contents of 5 wt.%, Rb> 500 ppm, chondrite-normalized LREE/HREE <1, and formed vapor-phase topaz. Declining temperatures and Cl/ F from the Kane Wash Tuff through the moat rhyolites may reflect decreasing basalt input into the base of the system and increasing proportions of upper crustal melts in the silicic magmas.