Ceramic production during the Middle Horizon: Wari and Tiwanaku clay procurement in the Moquegua Valley,Peru

As the only place simultaneously occupied by the Middle Horizon (A.D. 600–1000) Andean states, the Tiwanaku and the Wari, the Moquegua Valley in southern Peru is of critical importance to understanding relations between the two states. Visual studies of Tiwanaku and Wari ceramics in the valley have elucidated differences in form and decoration. The procurement of raw clays was central to the production of these ceramics, and understanding where people procured their clay may provide insight into the social and economic interactions between these two states. Survey of the Moquegua Valley indicates the extensive availability of raw clays. Results of laser ablation inductively coupled plasma mass spectrometry (LA‐ICP‐MS) analyses of clays indicate that there is heterogeneity in the chemical signature of the valley's clays and that at least five different clay groups can be distinguished. Comparison of these clays with LA‐ICP‐MS analysis of ceramics from a Tiwanaku site and a Wari site demonstrates that although Tiwanaku and Wari colonists in Moquegua used locally available clays during the Middle Horizon, the clay sources exploited by potters from each state were different and derived from areas located within their respective middle and upper valley territories. This information provides a basis for future chemical analysis of ceramics from the Moquegua Valley and improved understanding of past social and economic interactions. © 2009 Wiley Periodicals, Inc.     

Strontium isotopic evidence for prehistoric transport of gray‐ware ceramic materials in the eastern Grand Canyon region,USA

Through a novel application of strontium (Sr) isotopic analysis, we evaluate geological sources for prehistoric ceramics in the eastern Grand Canyon region of northern Arizona, focusing on two gray‐ware traditions in the Upper Basin of the Coconino Plateau. Building on a conceptual framework for the general potential of Sr isotopes in the analysis of geological materials, we suggest that the eastern Grand Canyon is specifically well suited archaeologically and geologically for: (1) exploring the utility of Sr isotopes for ceramic provenance research and (2) testing long‐standing hypotheses that gray‐ware ceramics were invariably made with local materials. Sr isotopic compositions indicate that the ceramic samples represent at least three different geological sources, and that different raw materials were used in the manufacture of the two gray‐ware traditions found in the Upper Basin. One of the gray‐ware traditions is not compositionally consistent with local geology, indicating that either the ceramics or the raw materials were transported at least 20 km to the Upper Basin. © 2011 Wiley Periodicals, Inc.     

Raw Materials and Pottery Production at the Late Bronze and Iron Age Site of Puig de Sa Morisca,Mallorca, Spain

This paper presents an analytical study of LateBronze andIronAge ceramics and natural clay deposits from the archaeological site ofPuig deSa Morisca in southwestMallorca,Spain. In our study, we combine petrographic, micropaleontological, mineralogical (X‐ray powder diffraction) and textural (laser particle size) analyses of sherds and local clays that may have been used as raw material in ceramic production. This approach allowed us to compare the ceramics’ formal characteristics with those observed in nearby plastic clays and assess raw clay procurement and paste preparation. The results indicate the use of local (<500 m distance) calcareous clays throughout theLateBronze andIron ages. This raw material was mixed with other coarser clays or crushed calcite, as well as other calcareous tempers, such as breccias or calcarenites, located close to the site. The results demonstrate that the same clay deposit was used to make ceramic vessels following different technological choices and recipes. Thus, local communities established a strong connection with the same raw materials through time that were located within the potters’ preferential range of exploitation.     

Stress fields and subsurface crack propagation of single and multiple rock indentation and disc cutting

Summary Indentation stress fields of one- and two-point loads applied on an ideal elastic half-space are presented. Laboratory observations, although few, are in surprisingly good agreement with long median and cone-type tensile cracks predicted by normal principal stresses. Results indicate that simultaneous loading by multiple indenters offers a possibility partly to control the direction and length of such cracks. This suggests the development of new cutter configurations with a possible increase in efficiency, as compared with present rock boring and rock cutting practice. A simple fracture mechanics calculation of the length of subsurface cracks is performed by applying indentation fracture studies of ceramics. Results demonstrate the influence of material parameters such as fracture surface energy, hardness and elastic constants.     

Preliminary study of the microstructure and mineralogy of 12th and 13th century ceramics,Samsat, Southeastern Turkey

The mineralogy and microstructure of 12th and 13th century ceramics from Samsat, Turkey were examined with an X-ray diffractometer and scanning electron microscope. There is a highly vitrified interlayer between the glaze and body in these sherds that probably accounts for the high durability of these ceramics. the lower vitrification and uniformity of the body in these ceramics suggests that leftover glaze was not mixed with paste during manufacture. Finally, the presence of tabular forsterite in the pores of the body points to the use of magnesium rich raw materials.     

工程陶瓷及特种石墨在热熔器结构设计中的应用

根据热熔器壳体所需耐高温和抗氧化等要求,测量和分析了若干工程陶瓷材料的热学性能、力学性能和电学性能,结果表明,可将热熔器壳体材料由渗硅石墨换为工程陶瓷.所选工程陶瓷具有不导电的特点,加热电阻元件可由热解石墨和高强石墨联合承担以形成电流回路.按所确定材料的实验性能设计了新式的热熔器,试验结果达到要求.     

Mechanisms of high-temperature, solid-state flow in minerals and ceramics and their bearing on the creep behavior of the mantle

The problem of applying laboratory silicate-flow data to the mantle, where conditions can be vastly different, is approached through a critical review of high-temperature flow mechanisms in ceramics and their relation to empirical flow laws. The intimate association of solid-state diffusion and high-temperature creep in pure metals is found to apply to ceramics as well. It is shown that in ceramics of moderate grain size, compared on the basis of self-diffusivity and elastic modulus, normalized creep rates compare remarkably well. This comparison is paralleled by the near universal occurrence of similar creep-induced structures, and it is thought that the derived empirical flow laws can be associated with dislocation creep. Creep data in fine-grained ceramics, on the other hand, are found to compare poorly with theories involving the stress-directed diffusion of point defects and have not been successfully correlated by self-diffusion rates.We conclude that these fine-grained materials creep primarily by a quasi-viscous grain-boundary sliding mechanism which is unlikely to predominate in the earth's deep interior. Creep predictions for the mantle reveal that under most conditions the empirical dislocation creep behavior predominates over the mechanisms involving the stress-directed diffusion of point defects. The probable role of polymorphic transformations in the transition zone is also discussed.     

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“南海Ⅰ号”沉船位于我国广东省阳江市,出水大量陶瓷器的产地研究及腐蚀产物研究是“南海Ⅰ号”研究的重要课题。本文利用微聚焦X射线荧光谱仪（μ-XRF）对“南海Ⅰ号”沉船出水部分的青白瓷、青瓷、绿釉陶的胎釉以及绿釉陶的腐蚀物进行成分分析,并利用体视显微镜以及拉曼光谱仪对绿釉陶表面的腐蚀物进行观察和物相组成分析。元素分析结果表明：一类青白瓷样品胎体具有低铝高硅的特点（Al₂O₃含量低于19%,SiO₂含量约73%）,属江西景德镇湖田窑,而另一类青白瓷可能产自福建,具体窑口的确定还有待进一步对比分析才能得出明确的结论;青瓷样品胎体具有高硅低铝的特点（Al₂O₃含量13.32%~19.12%;SiO₂含量72.89%~78.30%）,属浙江龙泉窑;绿釉陶样品的特征与福建地区瓷土较为符合,可能来自于福建磁灶窑。拉曼光谱物相分析结果表明,绿釉陶的主要腐蚀物的矿物组成为炭黑、白铅矿与磷酸铅。此项研究成果为出水陶瓷器的产地研究、陶瓷器腐蚀机理探究、出水陶瓷器保护等提供了重要依据。     

Stratigraphic and geochronological context of human habitation along the Galana River,Kenya

Geoarchaeological investigations along the Galana River, eastern Kenya, document a pattern of channel aggradation and then degradation from the Middle to Late Holocene. Archaeological occupations at six sites in fluvial terraces along a ˜100 km stretch of the Galana River in Tsavo East National Park correspond with fluvial aggradation beginning ca. 6000 years ago. Artifact analyses indicate that the inhabitants of these sites utilized ceramics and stone tools similar to Pastoral Neolithic traditions detected at other penecontemporaneous archaeological sites in East Africa and possessed domesticated cattle from ca. 3700 years ago. The site occupations that occur during this period have dense artifact concentrations of predominantly locally procured items. The Galana River incised after ca. 900 years ago and there is a noticeable paucity of archaeological material, reflecting more peripatetic lifestyles. This shift in settlement pattern may reflect a decrease in reliance on riverine food sources during the Late Holocene, with diminished riparian environments associated with channel incision. © 2007 Wiley Periodicals, Inc.     

Minerals and design of new waste forms for conditioning nuclear waste

Safe storage of radioactive waste is a major challenge for the nuclear industry. Mineralogy is a good basis for designing ceramics, which could eventually replace nuclear glasses. This requires a new storage concept: separation-conditioning. Basic rules of crystal chemistry allow one to select the most suitable structures and natural occurrences allow assessing the long-term performance of ceramics in a geological environment. Three criteria are of special interest: compatibility with geological environment, resistance to natural fluids, and effects of self-irradiation. If mineralogical information is efficient for predicting the behaviour of common, well-known minerals, such as zircon, monazite or apatite, more research is needed to rationalize the long-term behaviour of uncommon waste form analogs.     

电气石原料化学成分、制备方法对电气石陶瓷性能的影响

电气石具有自发电极属性,对改变水团的缔合度具有一定作用。笔者研究了朝鲜多个地区电气石的成分、结构和理化性能,并以其为主要原料制备了不同类型的电气石陶瓷,同时研发了一种间接测量水团缔合度的方法,该方法是利用水溶液的电容和介电损耗值来间接评价水团缔合度,可以反映水团缔合度的相对大小。研究表明,以高钙电气石为原料、适当添加活性剂并经700℃烧结工艺制备的电气石陶瓷,对降低水团缔合度具有明显效果。     

Artisanal ceramic factories using wood combustion:A nanoparticles and human health study

The ceramics industry,resulting from developments of modern compounds,is a segment of great influence in worldwide sustainability.Artisanal ceramic factories based on wood combustion have significant risks for the creation and discharge of atmosphere nanoparticles(NPs)and ultra-fine particles(UFPs).At present,there is insufficient recognition on the influence of engineered-NPs on the atmosphere and health.Real improvements are indispensable to diminish contact with NPs.The present study demonstrates the main NPs and UFPS present in an area of intense artisanal wood-combustion ceramic manufacturing.Particulate matter was sampled for morphological,chemical,and geochemical studies by sophisticated electron microbeam microscopy,X-Ray Diffraction,and Raman spectroscopy.From NPs configuration(<10 nm)we identify nucleation.Several amorphous NPs(>10 nm)were produced around the studied artisanal ceramic factories.This study presents an indication of the recent information on population and work-related contact to NPs in the artisanal ceramic factories and their influence on health.     

Rock‐Magnetic and Archaeointensity Investigation of Pottery and a Burned Floor at the Tzintzuntzan Archaeological Site,Western Mexico

We report a detailed rock‐magnetic and archaeointensity analysis of four pottery fragments and a burned floor recovered from the Tzintzuntzan archaeological site in western Mexico. Results from rock‐magnetic experiments (x‐T curves and first‐order reversal curves [FORC] diagrams) indicate the suitability of most of these materials as faithful geomagnetic field recorders. Potsherds were archaeomagnetically dated by comparing their mean intensity values against the paleosecular variation curve CALS3k, suggesting A.D. 600–941 as the most probable age range. This is younger than ¹⁴C‐dated charcoal from the same burned floor (A.D. 1294–1426). More precise age estimates will require the use of the full geomagnetic vector (declination, inclination, and intensity). Multiple reheatings of the ceramic pieces, evidenced as secondary components in Zijderveld plots, could reflect multiple heating of these objects, perhaps from use as incense burners. Our study demonstrates the potential of archaeomagnetic analysis to both date burned ceramics recovered in situ and provide insight into their use‐history.     

Investigation of Islamic ceramics from Tell Tuneinir using X‐ray diffraction

In this study, X‐ray diffraction (XRD) is applied to select ceramics, particularly dating to the Ayyoubid (A.D. 1174–1250) period from Tell Tuneinir in Syria. Because XRD has not been commonly applied to archaeological ceramics, a thorough background of the technique is given, with emphasis on quantitative measurements of quartz and calcite tempers. Several compositional groups based on raw materials and firing conditions emerge. While most ceramic samples are of local manufacture, Islamic stonepaste wares, and the “grenade” sample emerge as likely imports. We conclude that XRD is a powerful tool in characterizing archaeological ceramics and may be used to semi‐quantitatively gauge the amount of quartz, calcite, and feldspars in a sample. © 2001 John Wiley & Sons, Inc.     

Pore fabrics of ceramic models investigated by magnetic anisotropy

Ceramics was used as model to investigate the pore fabric originated during ductile deformation. The magnetic anisotropy was used to measure the connected pore fabric after pore saturating by the ferromagnetic fluid. The ductile deformation of the ceramics was investigated through measurement of magnetic anisotropy of dry specimens. The character and symmetry of the pore fabric are compatible with those of the deformations forming the fabric of the ceramics.     

Kaolin Deposits of Weathering-Residual in the Coastal Area of Guangdong Province

Kaolin deposits of weathering-residual type make up a large proportion in different types of kaolin depos-its and are widely used in ceramics, electron ceramics, rubber and paper industries. This paper discusses sys-tematically this type of kaolin deposit with respect to their features of occurrence, mineralogical and chemicalcomposition and transformation of minerals during supergene processes, thus providing some basic data forthe rational exploitation and utilization of the kaolin resources.     

El Niño flood deposits at Batán Grande,northern Peru

Recent construction of a 10 × 3 irrigation canal across the Batán Grande–Poma archaeological complex of northern Peru provided an opportunity for inspection of soil profiles and detailed sampling along a five km transect bisecting an important concentration of ceremonial structures built during the past 3000+ years. From laboratory analysis of 80 soil samples we conclude no long-term irrigation agriculture was practiced in this area and it was unimportant as a resource base. Stratigraphic studies indicate few sediments survive from the 1925 El Niño event, but a massive bed attributable to prehistoric slack-water flood sediments has been identified and can be bracketed between ca. A. D. 650–1000 by associated diagnostic funerary ceramics. Other flood deposits representing the same or different events are described, but we conclude intervalley correlations will be difficult until more precise dating methods are available.     

Geoarchaeological investigations of the “potters' quarter” at Sagalassos,southwest Turkey

The potters' quarter of the ancient city of Sagalassos, southwest Turkey, was one of the largest and most enduring ceramic‐producing manufactories in the eastern Mediterranean. The objective of our study was to determine environmental circumstances that favored development of different clay resources in the territory of Sagalassos and to assess utilization of these resources in the local pottery manufactory. The potters' quarter was established where, owing to favorable geological circumstances, a large clay body had developed. The bedrock in the potters' quarter, a tectonized ophiolite sequence, has synclinal structure; hence, surface runoff and groundwater tend to accumulate in its center. The weathering of the basic rock formed a smectite‐rich clay with vertic properties. This clay was mined in antiquity, and mineralogical and chemical analyses indicate that it was used for the production of local ceramics from Hellenistic to Byzantine times. It is likely that colluvium on top of the ophiolitic clay at the potters' quarter is related to deforestation and slope processes after the potters' quarter was abandoned. In sum, environmental circumstances determined the location of the artisanal quarter of Sagalassos, with its clay quarrying operation and ceramic manufactory. However, for the local mass‐produced Sagalassos red slip ware, the results of our chemical and mineralogical analyses indicate that a different, more suitable clay was used: detrital lake sediments, rich in chlorite and chlorite/smectite mixed layers, located about 8 km from the original artisanal quarter. The choice for this clay was determined both by the presence of a suitable clay deposit, as well as socio‐economic circumstances such as land ownership. The site of Sagalassos yielded unique evidence of mining of clay at a ceramic production site, as well as import of nearby clays. The local and imported clays were used side‐by‐side, but one for the production of common wares and building ceramics, and the other for the manufacturing of luxury fine tablewares. © 2003 Wiley Periodicals, Inc.     

坯样中SiO2与Al2O3对电瓷制品机械强度的影响

机械强度是电瓷制品的主要性能之一,与坯料中Ａｌ２Ｏ３与ＳｉＯ２质量分数有密切关系,本次试验结果表明,随着坯料中Ａｌ２Ｏ３质量分散的增加,ＳｉＯ２质量分数的减少,电瓷制品的抗折强度,抗冲击强度也相应提高,本文对其产生机理进行了较详细的讨论。f     

Preliminary chemical and micromorphological observations on Urartu (800–600 B.C.) ceramics,eastern Turkey

Anatolia has long been a major pottery production center of the ancient world, dating back 7000 cal yr B.P. The Early Iron Age Urartu Kingdom (800–600 B.C.) of eastern Anatolia is known for the production of high‐quality pottery, but little is known regarding firing technology and manufacture of these ceramics. Here we present a preliminary study of Urartu ceramic micromorphology and chemistry and suggest that the Urartus had good knowledge of local geology and intentionally used chemical fluxes (Pb, Rb, and Li) to attain desired firing temperatures. The sophisticated production of Urartu ceramics is comparable to later high‐quality Roman pottery (terra sigillata) procured from the same area. © 2010 Wiley Periodicals, Inc.