Landsystems of Morsárjökull,Skaftafellsjökull and Svínafellsjökull,outlet glaciers of the Vatnajökull Ice Cap,Iceland

This study utilizes a landsystem approach to analyse the landforms and sediments exposed on the forefields of three closely spaced outlet glaciers of the Vatnajökull Ice Cap, southeast Iceland; Morsárjökull, Skaftafellsjökull and Svínafellsjökull, in order to determine how individual glacier and environmental characteristics influence landscape development. Analysis of satellite imagery and fieldwork were used in conjunction to examine the geomorphology and sedimentology of the forefields, and to define the characteristic landsystems of each of the glaciers. Morsárjökull and Skaftafellsjökull have similar proglacial fields, with similarities in the distribution and scale of the landforms, and their characteristics conform to the established active temperate landsystem. Svínafellsjökull differs significantly from the other glaciers having a proglacial field that more closely resembles an early stage debris‐charged landsystem. Variations between the glaciers in terms of their ice distribution (hypsometry, equilibrium line altitude), bedrock type, topography and debris content are important factors that contribute to the landsystem variability evident in their proglacial fields. The forefields of these three glaciers may be used as analogues to enhance understanding of palaeoenvironmental conditions that existed along the southern margin of Pleistocene glaciers that covered much of northern North America and Europe in the past.     

Development of low–centred ice–wedge polygons in the northernmost Ungava Peninsual, Queébec, Canada

Morphological and vegetation mapping and stratigraphic studies were carried out on a 60 by 250 m low–centered polygon field on a flood–plain of the Riviére Deception in the continuous permafrost zone of northernmost Ungava. Analyses of grain size, water and ice content, deformation structures, and macrorests were carried out on drill–core samples, up to a maximum depth of 3.19 m, and radiocarbon dates were obtained from several peat horizons. Five different vegetational habits were identified: uplifted banks, ice–wedge fissures, hummocky centres, wet polygon centres, and water ponds. The stratigraphic analyses revealed many sand layers and organic layers, alternating with a few layers of segregated ice. In the raises banks, brown fen peats represent former wet conditions prior to bank uplift. Total ice volumes of the core samples from polygon centres and banks averaged 60%, and were generally in the form of pore ice. Segregated ice was concentrated in ice wedges. The Low gradient of the polygon field and the shallow active layer are responsible for impded drainage. The origins of this isolated low–centred polygon field are discussed in terms of special local terrain conditions. River flooding since glacio–isostatic emergence at 6000 BP repeatedly spread alluvial sands onto the low flood–plain, which thus became progressively built up to its present elevation. Peat layers buried by these alluvial sands have permitted the changing local drainage conditions to be radiocarbon–dated for the last 2600 years for the core sites. Impeded drainage, low winter temperatures, probable thin snow cover, rapid sedimentation of flood–plain sands, and high volumetric ice contents have created the critical thermal regime necessary for repeated frost cracking in a polygonal pattern, with concomitant ice–wedge dev–elopment. Ice wedges developed at least as early as 2200 BP, causing the formation of low banks. Further growth of ice wedges deformed the peat and sand layers on the bank margins and led to the rise of the latter to heights of 0.5 to 1 m above the intervening low wet polygon centres. More water was then collected in the depressions, leading to a transformations of the vegetation cover from mossy heath to sphagnum bog, wet fen, sedge-covered ponds, and eventually in some cases to open-water pools. The stratigraphic evidence suggests that several generations of high banks formed and disappeared and that their position has changed. Deformation by continued ice–wedge growth has been insignificant since 1000 BP, However. A relatively thick surface peat layer also indicates that sand layers have not been contributed to the polygon field by flooding since ? 500 BP.     

Petrogenetic and Metallogenetic Background of the Dajing Cu–Sn–Ag–Pb–Zn Ore Deposit, Inner Mongolia, and Characteristics of the Mineralizing Fluid

Abstract: The Dajing Cu–Sn–Ag–Pb–Zn ore deposit, Inner Mongolia of China, is a fissure‐filling hydrothermal ore deposit that occurs within the Upper Permian Linxi group. No magmatic pluton and volcanic rocks outcrop on the surface of the deposit. Most of ore veins show clear‐cut boundary with country rocks. Wallrock alterations that include silicification, carbonation, chlori–tization, and sericitization are generally weak and occur in the close vicinity of ore veins. Mineralization is divided into three stages: (1) cassiterite–arsenopyrite–quartz stage, (2) sulfide stage, and (3) Pb–Zn–Ag–carbonate stage. These mineralization stages have distinct ranges of homogenization temperatures, 290–350C for Stage 1, 260–320C for Stage 2, and 150–250C for Stage 3. However, salinities for Stages 1, 2, and 3 overlap and range between 2.2 and 10.4 wt % NaCl equivalent. The dD values relative to V‐SMOW of inclusion water from quartz are lower than –88% and centered at –100 to –130%. The δ³⁴S values relative to CDT of sulfide ore minerals and δ¹³C values relative to PDB of carbonate gangue minerals, vary from –0.3 to +2.6%, and from –7.0 to –2.9%, respectively. Integrated isotopic data point to two major contributions to the mineralizing fluid that include a dominant meteoric‐derived water and the other from hypogene magma for sulfur and carbon species. Analyses of inclusion gas and liquid compositions are performed. The H₂O and CO₂ are the two most abundant gaseous components, whereas SO₄^2‐ and Cl^‐, and Na⁺, Ca²⁺, and K⁺ are the major anions and cations, respectively. A linear trend is shown on the gaseous H₂O versus CO₂ plot. Phase separation is excluded as cause for the trend on the basis of isotope data and fluid inclusion microthermometry. In addition, a weak wallrock alteration does not support fluid‐rock interaction as an efficient mechanism. Hence, the linear H₂O–CO₂ trend is interpreted in terms of absorption or dilution of CO₂–dominant magmatic vapor by meteoric‐derived water. Cooling effects resulting from dilution may have caused precipitation of ore minerals. Major and trace element compositions of regional granites show a high‐K calc–alkaline characteristics and an arc–affinity. Lead isotopic compositions of galena samples from the Dajing deposit exhibit elevated U/Pb and Th/Pb ratios. These characteristics indicate a common source of supra subduction zone mantle wedge for regional granites and metals from the Dajing deposit.     

A wave‐dominated,tide‐modulated model for the Lower Ordovician of the Anti‐Atlas,Morocco

Hybrid depositional systems are created by the interaction of two or more hydrodynamic processes that control facies distribution and their characteristics in terms of sedimentary structures and depositional geometry. The interaction of wave and tide both in the geological sedimentary record and modern environments has been rarely described in the literature. Mixed coastal environments are identified by the evidence of wave and tidal structures and are well identified in nearshore environments, while their recognition in lower shoreface–offshore environments lacks direct information from modern settings. Detailed field analyses of 10 stratigraphic sections of the Lower Ordovician succession (Fezouata and Zini formations; Anti‐Atlas, Morocco) have allowed the definition of 14 facies, all grouped in four facies zones belonging to a storm‐dominated, wave‐dominated sedimentary siliciclastic system characterized by symmetrical ripples of various scales. Peculiar sedimentary organization and sedimentary structures are observed: (i) cyclical changes in size of sedimentary structures under fair‐weather or storm‐weather conditions; (ii) decimetre‐deep erosional surfaces in swaley cross‐stratifications; (iii) deep internal erosion within storm deposits; (iv) discontinuous sandstone layers in most depositional environments, and common deposition of sandstones with a limited lateral extension, interpreted to indicate that deposition at all scales (metric to kilometric) is discontinuous; (v) combined flow–oscillation ripples showing aggrading–prograding internal structures alternating with purely aggrading wave ripples; and (vi) foreshore environments characterized by alternating phases of deposition of parallel stratifications, small‐scale and large‐scale ripples and tens of metres‐wide reactivation surfaces. These characteristics of deposition suggest that wave intensity during storm‐weather or fair‐weather conditions was continuously modulated by another controlling factor of the sedimentation: the tide. However, tidal structures are not recognized, because they were probably not preserved due to dominant action of storms and waves. A model of deposition is provided for this wave‐dominated, tide‐modulated sedimentary system recording proximal offshore to intertidal–foreshore environments, but lacking diagnostic tidal structures.     

Volatile (H<Subscript>2</Subscript>O,CO<Subscript>2</Subscript>, Cl,S) budget of the Central American subduction zone

After more than a decade of multidisciplinary studies of the Central American subduction zone mainly in the framework of two large research programmes, the US MARGINS program and the German Collaborative Research Center SFB 574, we here review and interpret the data pertinent to quantify the cycling of mineral-bound volatiles (H₂O, CO₂, Cl, S) through this subduction system. For input-flux calculations, we divide the Middle America Trench into four segments differing in convergence rate and slab lithological profiles, use the latest evidence for mantle serpentinization of the Cocos slab approaching the trench, and for the first time explicitly include subduction erosion of forearc basement. Resulting input fluxes are 40–62 (53) Tg/Ma/m H₂O, 7.8–11.4 (9.3) Tg/Ma/m CO₂, 1.3–1.9 (1.6) Tg/Ma/m Cl, and 1.3–2.1 (1.6) Tg/Ma/m S (bracketed are mean values for entire trench length). Output by cold seeps on the forearc amounts to 0.625–1.25 Tg/Ma/m H₂O partly derived from the slab sediments as determined by geochemical analyses of fluids and carbonates. The major volatile output occurs at the Central American volcanic arc that is divided into ten arc segments by dextral strike-slip tectonics. Based on volcanic edifice and widespread tephra volumes as well as calculated parental magma masses needed to form observed evolved compositions, we determine long-term (10⁵ years) average magma and K₂O fluxes for each of the ten segments as 32–242 (106) Tg/Ma/m magma and 0.28–2.91 (1.38) Tg/Ma/m K₂O (bracketed are mean values for entire Central American volcanic arc length). Volatile/K₂O concentration ratios derived from melt inclusion analyses and petrologic modelling then allow to calculate volatile fluxes as 1.02–14.3 (6.2) Tg/Ma/m H₂O, 0.02–0.45 (0.17) Tg/Ma/m CO₂, and 0.07–0.34 (0.22) Tg/Ma/m Cl. The same approach yields long-term sulfur fluxes of 0.12–1.08 (0.54) Tg/Ma/m while present-day open-vent SO₂-flux monitoring yields 0.06–2.37 (0.83) Tg/Ma/m S. Input–output comparisons show that the arc water fluxes only account for up to 40 % of the input even if we include an “invisible” plutonic component constrained by crustal growth. With 20–30 % of the H₂O input transferred into the deeper mantle as suggested by petrologic modeling, there remains a deficiency of, say, 30–40 % in the water budget. At least some of this water is transferred into two upper-plate regions of low seismic velocity and electrical resistivity whose sizes vary along arc: one region widely envelopes the melt ascent paths from slab top to arc and the other extends obliquely from the slab below the forearc to below the arc. Whether these reservoirs are transient or steady remains unknown.     

Glaciomarine varves and the character of deglaciation, Säveån valley, southwestern Sweden

Glaciomarine varves, in contrast to glaciolacustrine varves, are primarily dependent upon sedimentation from meltwater overflow. They are usually developed in proximal positions and are a more reliable reflection of deglaciation character within a specific area than 'classical' glaciolacustrine varves, which are generally more distal and greater influenced by bottom topography. The close relationship with ice-front processes in the glaciomarine environment is discussed and utilized to suggest correlations between the varve stratigraphy, ice-front positions and climate shifts during the deglaciation of the Savean valley, where two varve localities have been documented. A varve sequence outside this valley shows similar general trends in varve-thickness variation, and comparison between localities may help in extending the lines connecting positions of concurrent ice-marginal deposition. The study of glaciomarine varves provides a more continuous record of changes in the ice-front character than can be obtained from intermittent moraine positions.     

Cenozoic tectonic events at the border of the Paraná Basin, São Paulo, Brazil

In the last decade, even in areas that had been considered tectonically stable, a great amount of Cenozoic, including the Quaternary period, structural data have been collected throughout Brazil. The main goal of this study is to describe the Cenozoic structures and tectonic evolution of an area that is located at the border of the Paraná Basin in the state of São Paulo.The research methods consisted of the analysis of: (1) brittle structure data, mainly conjugate fractures and fault slip data; (2) lineaments traced on air photos and TM Landsat and radar images; and (3) a second-order base surface map.The study area, during the Cenozoic, has been affected by five strike–slip tectonic events, which generated mainly strike–slip faults, and secondarily normal and reverse ones. The events were named, from the oldest to the youngest, E1-NE, E2-EW, E3-NW, E4-NS, and E5-NNE; and the maximum principal stresses σ1 strike approximately NE–SW, E–W, NW–SE, N–S, and NNE–SSW, respectively. Event E2-EW seems to have been contemporaneous with the deposition of the Rio Claro Formation, the most important Cenozoic deposit of probable Neogenic age, and also to have controlled the distribution of its deposits. Event E3-NW was the strongest one in the area, as is pointed out by structural data, and the maximum principal stress σ1 of event E5-NNE is partially concordant with the orientation of σH-max of well break-out data in the Paraná Basin, suggesting a Neotectonic activity for this event. Finally, discontinuities parallel and correlated to the directions of strike–slip faults of the Cenozoic events seem to have actively controlled the sculpturing of the relief in the study area.     

Timing of high-pressure metamorphism and exhumation of the eclogite type-locality (Kupplerbrunn–Prickler Halt, Saualpe, south-eastern Austria): constraints from correlations of the Sm–Nd, Lu–Hf, U–Pb and Rb–Sr isotopic systems

Sm–Nd, Lu–Hf, Rb–Sr and SIMS U–Pb data are presented for meta‐gabbroic eclogites from the eclogite type‐locality ( Haüy, 1822 ) Kupplerbrunn–Prickler Halt and other areas of the Saualpe (SE Austria) and Pohorje Mountains (Slovenia). Mg‐rich eclogites derived from early gabbroic cumulates are kyanite‐ and zoisite rich, whereas eclogites with lower Mg contents contain clinozoisite ± kyanite. Calculated P–T conditions at the final stages of high‐pressure metamorphism are 2.2 ± 0.2 GPa at 630–740 °C. Kyanite‐rich eclogites did not yield geologically meaningful Sm–Nd ages due to incomplete Nd isotope equilibration, whereas Sm–Nd multifraction garnet–omphacite regression for a low‐Mg eclogite from Kupplerbrunn yields an age of 91.1 ± 1.3 Ma. The Sm–Nd age of 94.1 ± 0.8 Ma obtained from the Fe‐rich core fraction of this garnet dates the initial stages of garnet growth. Zircon that also crystallized at eclogite facies conditions gives a weighted mean U–Pb SIMS age of 88.4 ± 8.1 Ma. Lu–Hf isotope analysis of a kyanite–eclogite from Kupplerbrunn yields 88.4 ± 4.7 Ma for the garnet–omphacite pair. Two low‐Mg eclogites from the Gertrusk locality of the Saualpe yield a multimineral Sm–Nd age of 90.6 ± 1.0 Ma. A low‐Mg eclogite from the Pohorje Mountains (70 km to the SE) gives a garnet–whole‐rock Lu–Hf age of 93.3 ± 2.8 Ma. These new age data and published Sm–Nd ages of metasedimentary host rocks constrain the final stages of the eo‐Alpine high‐pressure event in the Saualpe–Pohorje part of the south‐easternmost Austroalpine nappe system suggesting that garnet growth in the high‐pressure assemblages started at c. 95–94 Ma and ceased at c. 90–88 Ma, probably at the final pressure peak. Zircon and amphibole crystallization was still possible during incipient isothermal decompression. Rapid exhumation of the high‐pressure rocks was induced by collision of the northern Apulian plate with parts of the Austroalpine microplate, following Jurassic closure of the Permo‐Triassic Meliata back‐arc basin.     

Bortnikovite,Pd<Subscript>4</Subscript>Cu<Subscript>3</Subscript>Zn,a new mineral species from the unique Konder placer deposit,Khabarovsk krai,Russia

Bortnikovite, a new mineral species that is an intermetallic compound of Pd, Cu, and Zn with the simplified formula Pd₄Cu₃Zn has been detected at the unique Konder placer deposit in the Ayan-Maya district, Khabarovsk krai. The primary source of this placer is a concentrically zoned alkaline ultramafic massif. The X-ray diffraction pattern is indexed on the assumption of a tetragonal unit cell: a = 6.00 ± 0.02 Å and c = 8.50 ± 0.03 Å, V = 306 ± 0.01 ų, Z = 3, probable space group P4/mmm. The calculated density is 11.16 g/cm³; the mean microhardness VHN is 368 kg/mm². In reflected light, the new mineral is white with a slight grayish beige tint; bireflectance, anisotropy, and internal reflections are not observed. The reflectance spectrum belongs to the concave group of the anomalous type. The measured values of reflectance are as follows: 56.9 (470 nm), 61.7 (546 nm), 63.4 (589 nm), and 65.4% (650 nm). The new mineral is intergrown with isoferroplatinum, titanite, perovskite, V-bearing magnetite, bornite, and chlorite. The origin of bortnikovite is related to the effect of alkaline fluid on ultramafic rocks. The new mineral is named in honor of Professor Nikolai Stefanovich Bortnikov, a prominent mineralogist and researcher of ore deposits and a corresponding member of the Russian Academy of Sciences. Bortnikovite is the first platinum group mineral that contains Zn as a major mineralforming element.     

Negotiated space: Tourists, pilgrims, and the Bahá’í terraced gardens in Haifa

This paper explores the inherent contradiction and conceptual conflict that arises when sacred sites are marketed as secular for the purpose of promoting tourism. The question of conflict is further frustrated within the context of Israel’s contested religious landscape and Israeli policy. Using a Lefebvrian framework, the historical development of the Bahai Gardens in Haifa, Israel, the tourism board’s promotion of the site as Haifa’s primary tourist designation, and the distinct spatial practices that have been used by both constituencies are investigated. Further, the authors posit that the Bahai Gardens are multi-dimensional spaces characterized by two different socio-spatial processes and practices that co-exist—the tourist’s and the pilgrim’s. These practices transform the holy site into a secular shared community asset. The paper concludes with a discussion of the socio-spatial implications of the case and its broader implications concerning the globalization of tourism and the efficacy of developing “layered” Lefebvrian triad to try and avoid conflict.     

Geochemistry of source rocks in the Es<Subscript>3</Subscript> and Es<Subscript>4</Subscript> members in the Shahejie Formation of the Western Depression,Liaohe Oilfield,China

The Western Depression of the Liaohe Basin is the major exploration area of the Liaohe Oilfield, and its main source rocks consist of the third and fourth members of the Shahejie Formation (Es3 and Es4). These source rocks are widely distributed in the depression, with semi-deep lake and fan delta as the main sedimentary facies, brown oil shale and black gray-dark gray mudstone as the main rocks, and a total thickness of 270-1450 m. The kerogens are mainly of the types I and IIA, and partly of the type IIB and least of the type III. The Ro values range from 0.4%-0.8%, indicating an evolution stage from immature to mature. The maturity of Es4 source rocks is rela-tively high, reaching the early mature stage, but their distribution and thickness are lower than those of Es3. Besides, according to biomarker analysis, it is thought that the source rocks of Es3 and Es4 are characterized by mixed input, and most of the source rocks were formed in the brackish water-saline and strongly oxygen-free environment. Fur-thermore, the Qingshui, Niuxintuo and Chenjia sags are believed to possess greater potential for hydrocarbon gen-eration and expulsion, for they are source rocks with a larger thickness, have higher organic carbon contents, belong to better organic matter types and possess higher maturities.     

Ecological characteristics of the invasive Asian date mussel,<Emphasis Type="Italic">Musculista senhousia</Emphasis>, in the Sacca Di Goro (Adriatic Sea,Italy)

A population of the invasive musselMusculista senhousia was monitored bimonthly from May 1999 through April 2000 in the Sacca di Goro, a brackish lagoon of the Po River Delta, Northern Adriatic Sea, in order to give information on the gametogenic cycle, population dynamics, and secondary production of this successful invader. The gonad underwent 4 different stages: spent (December to February), developing (March to May), ripe (June to August), and spawning (September to November). The population was numerically dominated by a single cohort of individuals for most of the year. The mean size of this cohort rapidly increased to 24–25 mm shell length, after which growth slowed and mussels rarely grew larger than 30–32 mm. Summer anoxia may have greatly reduced mussel abundance; annual cohort mortality was 95%. No recruitment was registered on the bed until February 2000, and there was a large pulse of new recruits in April when two cohorts were clearly recognizable. The established bed was the primary site for new recruitment. Secondary production, calculated with two different methods, gave comparable estimates; P:B ratios were 1.5 and 1.7.M. senhousia beds seemed to facilitate the presence of other macrofaunal taxa: abundance of some species (a small gastropod, amphipods, and tube-building polychaetes) were significantly higher within mussel mats at two sites sampled in May 2000 than they were in soft-sediments ∼100 m away.     

Structural styles and tectonic evolution of the Kolia-Boboti sedimentary Basin,Kédougou-Kéniéba inlier,eastern Senegal

New structural data obtained on the Birimian terranes of the Kolia-Boboti sedimentary Basin, the eastern part of the Dialé-Daléma Supergroup in the Kédougou-Kéniéba inlier show two major phases of Eburnean compressional deformation: (1) a D1 phase of thrusting tectonics affected the Lower Birimian B1 tourmalinized sediments. This first tectonic phase is characterized by isoclinals overturned to recumbent folds P1 with N040° 20°NE trending axis, associated with axial plane schistosity S₀S₁ which is mainly transposed in the bedding; (2) a D2 phase of compressional (D2a) and transpressional (D2b) tectonics is responsible for the crossfolds P2a-P2b exhibiting curved axes. These P2 folds are associated with the major schistosity S₂, north-south to SW-NE trending, mainly dipping to the south-east. The S₂ schistosity is mostly displayed in the large shear zones corridors where it steeply dips locally toward the north-west. A north-west vergence thrusting phase (D2c) of flats and ramps, associated with reverse folds, represents the last Eburnean event. This geometrical feature is characteristic of a “positive flower structure”. These different Eburnean compressional phases are separated by extensional deformation which is characterized by sedimentary deposits and volcanic flows.     

Geology, coal quality, and resources of the Antaramut–Kurtan–Dzoragukh coal field, north-central Armenia

The Antaramut–Kurtan–Dzoragukh (AKD) coal deposit is a previously unrecognized coal field in north-central Armenia. Coal has been known to exist in the general vicinity since the turn of the century, but coal was thought to be restricted to a small (1 km²) area only near the village of Antaramut. However, through detailed field work and exploratory drilling, this coal deposit has been expanded to at least 20 km², and thus renamed the Antaramut–Kurtan–Dzoragukh coal field, for the three villages that the coal field encompasses. The entire coal-bearing horizon, a series of tuffaceous sandstones, siltstones, and claystones, is approximately 50 m thick. The AKD coal field contains two coal beds, each greater than 1 m thick, and numerous small rider beds, with a total resource of approximately 31,000,000 metric tonnes. The coals are late Eocene in age, high volatile bituminous in rank, relatively high in ash yield (approximately 40%, as-determined basis) and moderate in sulfur content (approximately 3%, as-determined basis). The two coal beds (No. 1 and No. 2), on a moist, mineral-matter-free basis, have high calorific values of 32.6 MJ/kg (7796 cal/g) and 36.0 MJ/kg (8599 cal/g), respectively. Coal is one of the few indigenous fossil fuel resources occurring in Armenia and thus, the AKD coal field could potentially provide fuel for heating and possibly energy generation in the Armenian energy budget.     

Mineralogy, geochemistry and uses of the mordenite–bentonite ash-tuff beds of Los Escullos, Almería, Spain

The mordenite ore deposit of Los Escullos has a surface area of 10⁶ m² with an average thickness of 5 m and estimated reserves of 7,500,000 tons of mordenite–bentonite. It is made up of horizontal layers of interbedded epiclastic tuffs with volcanic bentonitised materials which have been subjected to hydromagmatic activity. The layers are essentially composed of bentonite and mordenite with lesser amounts of quartz, cristobalite, biotite, plagioclase, chlorite, amphiboles, titanomagnetite, ilmenite and calcite. The harder layers display a higher proportion of plagioclase crystals and are enriched in Al₂O₃, CaO, Fe₂O₃, TiO₂, P₂O₅, Cu, Zn, Co, Cr, Ni and V, while the more altered layers contain larger contents of SiO₂, K₂O and Y. The amount of sodium increases (from 2% to 4%) relative to depth. Alteration processes resulted in a reduction in the contents of CaO, K₂O and MnO and increase in Na₂O and MgO. The beds of volcanic ash-tuffs have been devitrified by hydrothermal solutions giving rise to bentonites and sodium- and silica-rich residual fluids which have partly crystallized as mordenite and cristobalite. The raw material (mordenite–bentonite) can be improved removing biotite (magnetic separation) and plagioclase and quartz (by floating methods); however, the mordenite–bentonite mineral assemblage is practically impossible to separate due to the size of the crystals (average 0.5 μm under SEM–EDAX). In turn, this upgraded raw material has very useful properties (total area=520 m²/g and cation exchange capacity=70 meq/100 g) which may make it suitable for use in absorption processes (e.g. deodorization, cationic exchange), catalysis and molecular sieving.     

Au–Ag–Te Mineralization of the Low‐Sulfidation Epithermal Aginskoe Deposit,Central Kamchatka,Russia

Mineralogic studies of major ore minerals and fluid inclusion analysis in gangue quartz were carried out for the for the two largest veins, the Aginskoe and Surprise, in the Late Miocene Aginskoe Au–Ag–Te deposit in central Kamchatka, Russia. The veins consist of quartz–adularia–calcite gangue, which are hosted by Late Miocene andesitic and basaltic rocks of the Alnei Formation. The major ore minerals in these veins are native gold, altaite, petzite, hessite, calaverite, sphalerite, and chalcopyrite. Minor and trace minerals are pyrite, galena, and acanthine. Primary gold occurs as free grains, inclusions in sulfides, and constituent in tellurides. Secondary gold is present in form of native mustard gold that usually occur in Fe‐hydroxides and accumulates on the decomposed primary Au‐bearing tellurides such as calaverite, krennerite, and sylvanite. K–Ar dating on vein adularia yielded age of mineralization 7.1–6.9 Ma. Mineralization of the deposit is divided into barren massive quartz (stage I), Au–Ag–Te mineralization occurring in quartz‐adularia‐clays banded ore (Stage II), intensive brecciation (Stage III), post‐ore coarse amethyst (Stage IV), carbonate (Stage V), and supergene stages (Stage VI). In the supergene stage various secondary minerals, including rare bilibinskite, bogdanovite, bessmertnovite metallic alloys, secondary gold, and various oxides, formed under intensely oxidized conditions. Despite heavy oxidation of the ores in the deposit, Te and S fugacities are estimated as Stage II tellurides precipitated at the log f Te₂ values ?9 and at log fS₂ ?13 based on the chemical compositions of hypogene tellurides and sphalerite. Homogenization temperature of fluid inclusions in quartz broadly ranges from 200 to 300°C. Ore texture, fluid inclusions, gangue, and vein mineral assemblages indicate that the Aginskoe deposit is a low‐sulfidation (quartz–adularia–sericite) vein system.