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古建筑是宝贵的历史文化遗产,雷电灾害是威胁古建筑安全的主要因素之一。本文首先较完整地介绍了古建筑雷电灾害的总体研究进展,分别综述了古建筑构件的雷击破坏特征和机理,以及古建筑雷击起火灾害成因、方式和影响因素等方面研究现状,建议在雷击模拟试验基础上利用数值模拟分析方法研究雷击破坏基础性问题。分析了古建筑绝缘避雷与采用防雷装置接闪泄流两种方法,认为后者科学合理。通过归纳古建筑雷电防护技术研究进展、古建筑防雷新技术方法和装置,分析了古建筑防雷技术标准现状。最后,提出古建筑防雷有待深入研究的方向,包括开展古建筑雷击破坏机理、实用的防雷新技术、古建筑雷击选择性、雷击精细化监测预警等,特别是加强古建筑防雷新技术研究,尽量减小对古建筑原貌的影响,做好古建筑的防雷保护是非常关键和必要的。 相似文献
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通过对古建筑的重要性、火险特性、结构特点、防雷现状及其他因素分析,并结合近几十年来的一些案例,浅析了加强古建筑综合防雷的重要性。 相似文献
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通过对古建筑的重要性、火险特性、结构特点、防雷现状及其他因素分析,并结合近几十年来的一些案例,浅析了加强古建筑综合防雷的重要性。 相似文献
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The kinetics of the aqueous phase reactions of NO3 radicals with HCOOH/HCOO– and CH3COOH/CH3COO– have been investigated using a laser photolysis/long-path laser absorption technique. NO3 was produced via excimer laser photolysis of peroxodisulfate anions (S2O
8
2–
) at 351 nm followed by the reactions of sulfate radicals (SO
4
–
) with excess nitrate. The time-resolved detection of NO3 was achieved by long-path laser absorption at 632.8 nm. For the reactions of NO3 with formic acid (1) and formate (2) rate coefficients ofk
1=(3.3±1.0)×105 l mol–1 s–1 andk
2=(5.0±0.4)×107 l mol–1 s–1 were found atT=298 K andI=0.19 mol/l. The following Arrhenius expressions were derived:k
1(T)=(3.4±0.3)×1010 exp[–(3400±600)/T] l mol–1 s–1 andk
2(T)=(8.2±0.8)×1010 exp[–(2200±700)/T] l mol–1 s–1. The rate coefficients for the reactions of NO3 with acetic acid (3) and acetate (4) atT=298 K andI=0.19 mol/l were determined as:k
3=(1.3±0.3)×104 l mol–1 s–1 andk
4=(2.3±0.4)×106 l mol–1 s–1. The temperature dependences for these reactions are described by:k
3(T)=(4.9±0.5)×109 exp[–(3800±700)/T] l mol–1 s–1 andk
4(T)=(1.0±0.2)×1012 exp[–(3800±1200)/T] l mol–1 s–1. The differences in reactivity of the anions HCOO– and CH3COO– compared to their corresponding acids HCOOH and CH3COOH are explained by the higher reactivity of NO3 in charge transfer processes compared to H atom abstraction. From a comparison of NO3 reactions with various droplets constituents it is concluded that the reaction of NO3 with HCOO– may present a dominant loss reaction of NO3 in atmospheric droplets. 相似文献
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K. Zeller 《Meteorology and Atmospheric Physics》1950,2(4):401-403
Zusammenfassung A. undE. Vassy haben in der Frage der Temperatur-abhängigkeit des Ozongehalts der Atmosphäre aus der Gleichung loge
n
–logJ
n
logK(T
n
) geschlossen, daß auch die Gleichung loge
n
logJ
n
+logK(T
n
) gültig sei. Es wird hier nun gezeigt, daß die bei der ersten Gleichung erlaubten Vernachlässigungen bei der zweiten zu großen Fehlern führen können und daß daher von A. undE. Vassy kein Beweis für die Richtigkeit der Beziehunge=J.K(T) erbracht ist.
Summary In the question of temperature dependence of ozone content of the atmosphere A. andE. Vassy have concluded from the equation loge n –logJ n logK(T n ) that also the formula loge n logJ n +logK(T n ) must be valid. In this paper it is proved that the neglections which may be admitted for the first equation, can conduct to great errors. Therefore A. andE. Vassy have not produced a proof for the correctness of the equatione=J.K(T).
Résumé A. etE. Vassy en étuidant le problème de la teneur de l'ozone atmosphérique en relation avec la température ont admis que l'équation loge n –logJ n logK(T n ) entraînait aussi la relation loge n logJ n +logK(T n ). On montre ici que les simplifications admises pour la première équation conduisent pour l'application de la seconde à de fortes erreurs, et que par conséquent ces auteurs n'ont pas fourni de preuve de la justesse de la relatione=J.K(T).相似文献
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Precipitation samples were collected by filtrating bulk sampler in Kitakyushu City, Japan, from January 1988 to December 1990. Volume weighted annual mean of pH was 4.93, but the pH distribution indicated that most probable value lay in the range pH 6.0–6.4. Volume weighted annual mean concentrations of major ionic components were as follows; SO
4
2–
: 84.2, NO
3
–
: 28.1, Cl–: 86.3, NH
4
+
: 45.5, Ca2+: 63.3, Mg2+: 27.0, K+: 3.4, Na+: 69.0 µ eq l–1. The highest concentrations of these ionic components were observed in winter and the lowest occurred in the rainy season. The ratio of ex-SO
4
2–
/NO
3
–
exhibited the lowest ratio in summer, and the highest ratio in winter. Good correlations were obtained between Cl– and Na+, ex-SO
4
2+
and ex-Ca2+, NO
3
–
and ex-Ca2+, and NH
4
+
and ex-SO
4
2–
, respectively. However, no correlation between Cl– and Na+ with Ca2+ was observed. The relationship of H+ with (ex-SO
4
2–
+ NO
3
–
) - (ex-Ca2+ + NH
4
+
) indicated positive correlation. 相似文献
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The following Henry's law constants (K
H/mol2kg-2atm-1) for HNO3 and the hydrohalic acids have been evaluated from available partial pressure and other thermodynamic data from 0°–40°C, 1 atm total pressure: HNO
3
, 40°C–5.85×105; 30°C–1.50×106; 25°C–2.45×106; 20°C–4.04×106; 10°C–1.15×107; 0°C–3.41×107. HF, 40°C–3.2; 30°C–6.6; 25°C–9.61; 20°C–14.0; 10°C–32.0; 0°C–76. HCl, 40°C–4.66×105; 30°C–1.23×106; 25°C–2.04×106; 20°C–3.37×106; 10°C–9.71×106; 0°C–2.95×107. HBr, 40°C–2.5×108; 30°C–7.5×108; 25°C–1.32×109; 20°C–2.37×109; 10°C–8.10×109; 0°C–3.0×1010. HI, 40°C–5.2×108; 30°C–1.5×109; 25°C–2.5×109; 20°C–4.5×109; 10°C–1.5×1010; 0°C–5.0×1010. Simple equilibrium models suggest that HNO3, CH3SO3H and other acids up to 10x less soluble than HCl displace it from marine seasalt aerosols. HF is displaced preferentially to HCl by dissolved acidity at all relative humidities greater than about 80%, and should be entirely depleted in aged marine aerosols. 相似文献
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Summary ?Above orographically structured terrain considerable differences of the regional wind field may be identified during large-scale
extreme wind events. So far, these regional differences could not be resolved by climate models. To determine the relationships
between large-scale atmospheric conditions, the influence of orography, and the regional wind field, data measured in the
upper Rhine valley within the framework of the REKLIP Regional Climate Project were analyzed and calculations were made using
the KAMM mesoscale model. In the area of the upper Rhine valley, ratios of the wind velocity in the Rhine valley at 10 m above
ground level, νval, and the large-scale flow velocity, νlar, are between νval/νlar ≈ 0.1 and νval/νlar ≈ 1. The νval/νlar ratio exhibits a strong dependence on thermal stratification, δ, and decreases from νval/νlar ≈ 1 at δ = 0 K m−1 to νval/νlar ≈ 0.2 at δ = 0.0075 K m−1. In areas, where the lateral mountainous border of the Rhine valley is interrupted, the νval/νlar ratio increases again with increasing stability or decreasing Froude number. This is obviously due to flow around the Black
Forest under stable stratification. It is demonstrated by model calculations that a complex wind field develops in the Rhine
valley at small Froude numbers (Fr < 1) irrespective of the direction of large-scale flow. The νval/νlar ratio is characterized by small values in the direct lee side (νval/νlar ≈ 0.2) and high values on the windward side of the lateral mountainous border of the Rhine valley (νval/νlar ≈ 0.8).
Received October 22, 2001; revised June 18, 2002; accepted June 23, 2002 相似文献
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