Spinel assemblages in lunar meteorites Graves Nunataks 06157 and Dhofar 1528: Implications for impact melting and equilibration in the Moon's upper mantle

Magnesium‐rich spinel assemblages occur in the two lunar vitric breccia meteorites—Dhofar (Dho) 1528 and Graves Nunataks (GRA) 06157. Dho 1528 contains up to ~0.7 mm cumulate Mg‐rich spinel crystals associated with Mg‐rich olivine, Mg‐ and Al‐rich pyroxene, plagioclase, and rare cordierite. Using thermodynamic calculations of these mineral assemblages, we constrain equilibration depths and discuss an origin of these lithologies in the upper mantle of the Moon. In contrast, small, 10 to 20 μm spinel phenocryst assemblages in glassy melt rock clasts in Dho 1528 and GRA 06157 formed from the impact melting of Mg‐rich rocks. Some of these spinel phenocrysts match compositional constraints for spinel associated with “pink spinel anorthosites” inferred from remote sensing data. However, such spinel phenocrysts in meteorites and Apollo samples are typically associated with significant amounts of olivine ± pyroxene that exceed the compositional constraints for pink spinel anorthosites. We conclude that the remotely sensed “pink spinel anorthosites” have not been observed in the collections of lunar rocks. Moreover, we discuss impact‐excavation scenarios for the spinel‐bearing assemblages in Dhofar 1528 and compare the bulk rock composition of Dho 1528 to strikingly similar compositions of Luna 20 samples that contain ejecta from the Crisium impact basin.     

Petrography and geochemistry of lunar meteorites Dhofar 1673, 1983, and 1984

The Dhofar 1673, Dhofar 1983, and Dhofar 1984 meteorites are three lunar regolith breccias classified based on their petrography, mineralogy, oxygen isotopes, and bulk chemistry. All three meteorites are dominated by feldspathic lithic clasts; however, impact melt rock clasts and spherules are also found in each meteorite. The bulk chemistry of these samples is similar to other feldspathic highland meteorites with the Al₂O₃ content only slightly lower than average. Within the lithic clasts, the Mg # of mafic phases versus the anorthite content of feldspars is similar to other highland meteorites and is found to plot intermediate of the ferroan‐anorthositic suite and magnesian suite. The samples lack any KREEPy signature and have only minor indications of a mare basalt component, suggesting that the source region of all three meteorites would have been distal from the Procellarum KREEP Terrane and could have possibly been the Feldspathic Highland Terrane. All three meteorites were found within 500 m of each other in the Dhofar region of Oman. This, together with their similar petrography, stable isotope chemistry, and geochemistry indicates the possibility of a pairing.     

Petrogenesis of lunar highlands meteorites: Dhofar 025, Dhofar 081, Dar al Gani 262, and Dar al Gani 400

Abstract— The petrogenesis of four lunar highlands meteorites, Dhofar 025 (Dho 025), Dhofar 081 (Dho 081), Dar al Gani 262 (DaG 262), and Dar al Gani 400 (DaG 400) were studied. For Dho 025, measured oxygen isotopic values and Fe‐Mn ratios for mafic minerals provide corroboratory evidence that it originated on the Moon. Similarly, Fe‐Mn ratios in the mafic minerals of Dho 081 indicate lunar origin. Lithologies in Dho 025 and Dho 081 include lithic clasts, granulites, and mineral fragments. A large number of lithic clasts have plagioclase AN# and coexisting mafic mineral Mg# that plot within the “gap” separating ferroan anorthosite suite (FAN) and high‐magnesium suite (HMS) rocks. This is consistent with whole rock Ti‐Sm ratios for Dho 025, Dho 081, and DaG 262, which are also intermediate compared to FAN and HMS lithologies. Although ion microprobe analyses performed on Dho 025, Dho 081, DaG 262, and DaG 400 clasts and minerals show far stronger FAN affinities than whole rock data suggest, most clasts indicate admixture of ≤12% HMS component based on geochemical modeling. In addition, coexisting plagioclase‐pyroxene REE concentration ratios in several clasts were compared to experimentally determined plagioclase‐pyroxene REE distribution coefficient ratios. Two Dho 025 clasts have concordant plagioclase‐pyroxene profiles, indicating that equilibrium between these minerals has been sustained despite shock metamorphism. One clast has an intermediate FAN‐HMS composition. These lunar meteorites appear to represent a type of highland terrain that differs substantially from the KREEP‐signatured impact breccias that dominate the lunar database. From remote sensing data, it is inferred that the lunar far side appears to have appropriate geochemical signatures and lithologies to be the source regions for these rocks; although, the near side cannot be completely excluded as a possibility. If these rocks are, indeed, from the far side, their geochemical characteristics may have far‐reaching implications for our current scientific understanding of the Moon.     

Magnesian anorthositic granulites in lunar meteorites Allan Hills A81005 and Dhofar 309: Geochemistry and global significance

Abstract– Fragments of magnesian anorthositic granulite are found in the lunar highlands meteorites Allan Hills (ALH) A81005 and Dhofar (Dho) 309. Five analyzed clasts of meteoritic magnesian anorthositic granulite have Mg′ [molar Mg/(Mg + Fe)] = 81–87; FeO ≈ 5% wt; Al₂O₃ ≈ 22% wt; rare earth elements abundances ≈ 0.5–2 × CI (except Eu ≈ 10 × CI); and low Ni and Co in a non‐chondritic ratio. The clasts have nearly identical chemical compositions, even though their host meteorites formed at different places on the Moon. These magnesian anorthositic granulites are distinct from other highlands materials in their unique combination of mineral proportions, Mg′, REE abundances and patterns, Ti/Sm ratio, and Sc/Sm ratio. Their Mg′ is too high for a close relationship to ferroan anorthosites, or to have formed as flotation cumulates from the lunar magma ocean. Compositions of these magnesian anorthositic granulites cannot be modeled as mixtures of, or fractionates from, known lunar rocks. However, compositions of lunar highlands meteorites can be represented as mixtures of magnesian anorthositic granulite, ferroan anorthosite, mare basalt, and KREEP. Meteoritic magnesian anorthositic granulite is a good candidate for the magnesian highlands component inferred from Apollo highland impactites: magnesian, feldspathic, and REE‐poor. Bulk compositions of meteorite magnesian anorthositic granulites are comparable to those inferred for parts of the lunar farside (the Feldspathic Highlands Terrane): ～4.5 wt% FeO; ～28 wt% Al₂O₃; and Th <1 ppm. Thus, magnesian anorthositic granulite may be a widespread and abundant component of the lunar highlands.     

40Ar/39Ar dating and cosmic‐ray exposure time of desert meteorites: Dhofar 300 and Dhofar 007 eucrites and anomalous achondrite NWA 011

Abstract— We performed high‐resolution ⁴⁰Ar‐³⁹Ar dating of mineral separates and whole‐rock samples from the desert meteorites Dhofar 300, Dhofar 007, and Northwest Africa (NWA) 011. The chronological information of all samples is dominated by plagioclase of varying grain size. The last total reset age of the eucrites Dhofar 300 and Dhofar 007 is 3.9 ± 0.1 Ga, coeval with the intense cratering period on the Moon. Some large plagioclase grains of Dhofar 007 possibly inherited Ar from a 4.5 Ga event characteristic for other cumulate eucrites. Due to disturbances of the age spectrum of NWA 011, only an estimate of 3.2–3.9 Ga can be given for its last total reset age. Secondary events causing partial ⁴⁰Ar loss ≤3.4 Ga ago are indicated by all age spectra. Furthermore, Ar extractions from distinct low temperature phases define apparent isochrons for all samples. These isochron ages are chronologically irrelevant and most probably caused by desert alterations, in which radiogenic ⁴⁰Ar and K from the meteorite and occasionally K induced by weathering are mixed, accompanied by incorporation of atmospheric Ar. Additional uptake of atmospheric Ar by the alteration phase(s) was observed during mineral separation (i.e., crushing and cleaning in ultrasonic baths). Consistent cosmic‐ray exposure ages were obtained from plagioclase and pyroxene exposure age spectra of Dhofar 300 (25 ± 1 Ma) and Dhofar 007 (13 ± 1 Ma) using the mineral's specific target element chemistry and corresponding ³⁸Ar production rates.     

Thermal and irradiation history of lunar meteorite Dhofar 280

Dhofar 280 recorded a complex history on the Moon revealed by high‐resolution ⁴⁰Ar‐³⁹Ar dating. Thermal resetting occurred less than 1 Ga ago, and the rock was exposed to several impact events before and afterwards. The cosmic ray exposure (CRE) age spectrum indicates a 400 ± 40 Ma CRE on the lunar surface. A unique feature of this lunar sample is a partial loss of cosmogenic ³⁸Ar, resulting in a (low‐temperature) CRE age plateau of about 1 Ma. This was likely caused by the same recent impact event that reset the (low‐temperature) ⁴⁰Ar‐³⁹Ar age spectrum and preceded the short transit phase to Earth of ≤1 Ma. Dhofar 280 may be derived from KREEP‐rich lunar frontside terrains, possibly associated with the Copernicus crater or with a recent impact event on the deposits of the South Pole–Aitken basin. Although Dhofar 280 is paired with Dhofar 081, their irradiation and thermal histories on the Moon were different. An important trapped Ar component in Dhofar 280 is “orphan” Ar with a low ⁴⁰Ar/³⁶Ar ratio. It is apparently a mixture of two components, one endmember with ⁴⁰Ar/³⁶Ar = 17.5 ± 0.2 and a second less well‐constrained endmember with ⁴⁰Ar/³⁶Ar ≤10. The presence of two endmembers of trapped Ar, their compositions, and the breccia ages seem to be incompatible with a previously suggested correlation between age or antiquity and the (⁴⁰Ar/³⁶Ar)_trapped ratio (Eugster et al. 2001; Joy et al. 2011a). Alternatively, “orphan” Ar of this impact melt breccia may have an impact origin.     

Regolith history of lunar meteorites

Abstract— The regolith evolution of the lunar meteorites Dhofar (Dho) 081, Northwest Africa (NWA) 032, NWA 482, NWA 773, Sayh al Uhaymir (SaU) 169, and Yamato (Y‐) 981031 was investigated by measuring the light noble gases He, Ne, and Ar. The presence of trapped solar neon in Dho 081, NWA 773, and Y‐981031 indicates an exposure at the lunar surface. A neon three‐isotope diagram for lunar meteorites yields an average solar ²⁰Ne/²²Ne ratio of 12.48 ± 0.07 representing a mixture of solar energetic particles neon at a ratio of 11.2 and solar wind neon at a ratio of 13.8. Based on the production rate ratio of ²¹Ne and ³⁸Ar, the shielding depth in the lunar regolith of NWA 032, NWA 482, SaU 169, and Y‐981031 was obtained. The shielding depth of these samples was between 10.5 g/cm² and >500 g/cm². Based on spallogenic Kr and Xe, the shielding depth of Dho 081 was estimated to be most likely between 120 and 180 g/cm². Assuming a mean density of the lunar regolith of 1.8 g/cm³, 10.5 g/cm² corresponds to a depth of 5.8 cm and 500 g/cm² to 280 cm below the lunar surface. The range of regolith residence time observed in this study is 100 Ma up to 2070 Ma.     

Mineralogy and petrology of the LaPaz Icefield lunar mare basaltic meteorites

Abstract— Five basaltic meteorites from the LaPaz ice field are paired on the basis of their mineralogy and texture, and represent a unique basalt type distinct from those in the Apollo or Luna sample collections. LaPaz Icefield (LAP) 02205, LAP 02224, LAP 02226, LAP 02436 and LAP 03632 all contain plagioclase, pyroxene, ilmenite, spinel, olivine, and minor troilite, metal, phosphate, baddeleyite and silica (cristobalite). Brown glassy melt veins are ubiquitous and cross the primary igneous texture. Plagioclase, the major mineral and occurring as laths in a subophitic texture, is of narrow compositional range, from An_85–89. Pyroxene, also a major mineral, is strongly zoned, from augite and pigeonite cores to very iron‐rich rims. Ilmenite laths comprise approximately 3–5% of the basalts. Spinels show a large compositional range, comparable to that documented in Apollo 15 basalts, indicating an early chromite‐rich stage followed by an intermediate to late stage with Cr‐rich ulvöspinel. Relatively large, subhedral to skeletal olivine crystals (Fo_46–62) are sparse, and are too Forich to be in equilibrium with the bulk rock, indicating that these are xenocrysts rather than phenocrysts. The presence of melt veins with a similar composition to the bulk rock, maskelynitized plagioclase feldspar, and metastable cristobalite indicate that these rocks underwent significant shock, between 30 and 50 GPa. Calculated oxygen fugacity, using spinel‐ilmenite‐iron metal equilibria, is within the range defined by previous studies of lunar materials. The bulk composition (low MgO) and low calculated temperatures, together with modelling calculations, indicate an origin by fractional crystallization of a more primitive low TiO₂ parent liquid similar to Apollo 12 olivine basalt.     

The thermal and radiation exposure history of lunar meteorites

Abstract— We have measured the natural and induced thermoluminescence (TL) of seven lunar meteorites in order to examine their crystallization, irradiation, and recent thermal histories. Lunar meteorites have induced TL properties similar to Apollo samples of the same provenance (highland or mare), indicating similar crystallization and metamorphic histories. MacAlpine Hills 88104/5 has experienced the greatest degree of impact/regolith processing among the highland-dominated meteorites. The basaltic breccia QUE 94281 is dominated by mare component but may also contain a significant highland component. For the mare-dominated meteorites, EET 87521 may have a significant highland impact-melt component, while Asuka 881757 and Y-793169 have been heavily shocked. The thermal history of Y-793169 included slow cooling, either during impact processing or during its initial crystallization. Our natural TL data indicate that most lunar meteorites have apparently been irradiated in space a few thousand years, with most <15,000 a. Elephant Moraine 87521 has the lowest irradiation exposure time, being <1,000 a. Either the natural TL of ALHA81005, Asuka 881757 and Y-82192 was only partially reset by lunar ejection or these meteorites were in small perihelia orbits (≤0.7 AU).     

Electrical conductivity of lunar surface rocks and chondritic meteorites

The electrical conductivities of several samples from returned Apollo 11 and 12 lunar rocks and from chondritic meteorites were measured from 300 to 1100K. Collectively the lunar samples represent all three of the major NASA classifications of lunar surface rocks. Of general interest is the observation that the conductivities of the lunar samples are much larger than the values which have previously been used in theoretical discussions of lunar phenomena. It is also found that the conductivity at 300K, (300), is extremely sensitive to the thermal history of the sample for both lunar and meteoritic material. Magnetic measurements are presented to help characterize the changes which occur upon heating.Principal Investigator - Apollo Lunar Science Program, Geophysics Research Laboratory, University of Tokyo, Japan.     

Multiple impact events on the L-chondritic parent body: Insights from SIMS U-Pb dating of Ca-phosphates in the NWA 7251 L-melt breccia

Here we report in situ secondary ionization mass spectrometry Ca-phosphate U-Pb ages for an L-impact melt breccia (NWA 7251), which are integrated with petrological and mineral chemical studies of this meteorite. NWA 7251 is a heavily shocked rock that is composed mainly of the chondrite host, impact melt portion, and melt veins (crosscutting and pervasive type). The host is an L4 chondrite that has been shocked to S4. The impact melt portion has a fine-grained igneous texture, and is composed mainly of olivine, low-Ca pyroxene, high-Ca pyroxene, and albitic glass. The impact melt was generated at pressure of >30–35 GPa and temperature of >1300–1500 °C during an impact event. The Ca-phosphate grains in the host were affected by a shock heating event. Most of the Ca-phosphate grains in the melt were neocrystallized, but relatively large grains enclosed by or adjacent to metal veins or melt globules are likely inherited. The U-Pb isotopic systematics of Ca-phosphates in NWA 7251 yield an upper intercept age of 4457 ± 56 Ma and a lower intercept age of 574 ± 82 Ma on the normal U-Pb concordia diagram. The age of 4457 ± 56 Ma is interpreted to be related to an early shocking event rather than the thermal metamorphism of the parent body. The impact melt and veins in NWA 7251 were generated at 574 ± 82 Ma, resulting from disruption of the L chondrite parent body.     

A noble gas data collection of lunar meteorites

We collected the published noble gas data of altogether 35 lunar meteorites. This compilation includes the stable isotopes of He, Ne, Ar, Kr, and Xe. We also give a summary of cosmogenic, trapped, and radiogenic noble gas components of lunar meteorites for which data are available in the literature.     

Petrography,mineralogy, and trace element geochemistry of lunar meteorite Dhofar 1180

Abstract— Here we report the petrography, mineralogy, and trace element geochemistry of the Dhofar 1180 lunar meteorite. Dhofar 1180 is predominantly composed of fine‐grained matrix with abundant mineral fragments and a few lithic and glassy clasts. Lithic clasts show a variety of textures including cataclastic, gabbroic, granulitic, ophitic/subophitic, and microporphyritic. Both feldspathic and mafic lithic clasts are present. Most feldspathic lithic clasts have a strong affinity to ferroan anorthositic suite rocks and one to magnesian suite rocks. Mafic lithic clasts are moderately to extremely Fe‐rich. The Ti/[Ti+Cr]‐Fe/[Fe+Mg] compositional trend of pyroxenes in mafic lithic clasts is consistent with that of low‐Ti mare basalts. Glasses display a wide chemical variation from mafic to feldspathic. Some glasses are very similar to those from Apollo 16 soils. KREEP components are essentially absent in Dhofar 1180. One glassy clast is rich in K, REE and P, but its Mg/[Mg+Fe] is very low (0.25). It is probably a last‐stage differentiation product of mare basalt. Molar Fe/Mn ratios of both olivine and pyroxene are essentially consistent with a lunar origin. Dhofar 1180 has a LREE‐enriched (La 18 × CI, Sm 14 × CI) pattern with a small positive Eu anomaly (Eu 15 × CI). Th concentration is 0.7 ppm in Dhofar 1180. Petrography, mineralogy, and trace element geochemistry of Dhofar 1180 are different from those of other lunar meteorites, indicating that Dhofar 1180 represents a unique mingled lunar breccia derived from an area on the lunar nearside but far away from the center of the Imbrium Basin.     

Lunar regolith breccia Dhofar 287B: A record of lunar volcanism

Abstract— Dhofar 287 (Dho 287), a recently found lunar meteorite, consists in large part (95%) of low‐Ti mare basalt (Dho 287A) and a minor, attached portion (?5%) of regolith breccia (Dho 287B). The present study is directed mainly at the breccia portion of this meteorite. This breccia consists of a variety of lithic clasts and mineral fragments set in a fine‐grained matrix and minor impact melt. The majority of clasts and minerals appear to have been mainly derived from the low‐Ti basalt suite, similar to that of Dho 287A. Very low‐Ti (VLT) basalts are a minor lithology of the breccia. These are significantly lower in Mg# and slightly higher in Ti compared to Luna 24 and Apollo 17 VLT basalts. Picritic glasses constitute another minor component of the breccia and are compositionally similar to Apollo 15 green glasses. Dho 287B also contains abundant fragments of Mg‐rich pyroxene and anorthite‐rich plagioclase grains that are absent in the lithic clasts. Such fragments appear to have been derived from a coarse‐grained, Mg#‐rich, Na‐poor lithology. A KREEP component is apparent in chemistry, but no highlands lithologies were identified. The Dho 287 basaltic lithologies cannot be explained by near‐surface fractionation of a single parental magma. Instead, magma compositions are represented by a picritic glass; a low‐Ti, Na‐poor glass; and a low‐Ti, Na‐enriched source (similar to the Dho 287A parental melt). Compositional differences among parent melts could reflect inhomogeneity of the lunar mantle. Alternatively, the low‐Ti, Na‐poor, and Dho 287A parent melts could be of hybrid compositions, resulting from assimilation of KREEP by picritic magma. Thus, the Dho 287B breccia contains lithologies from multiple magmatic eruptions, which differed in composition, formational conditions, and cooling histories. Based on this study, the Dho 287 is inferred to have been ejected from a region located distal to highlands terrains, possibly from the western limb of the lunar nearside, dominated by mare basalts and KREEP‐rich lithologies.     

Mechanisms of ringwoodite formation in shocked meteorites: Evidence from L5 chondrite Dhofar 1970

The formation of the high‐pressure compositional equivalents of olivine and pyroxene has been well‐documented within and surrounding shock‐induced veins in chondritic meteorites, formed by crystallization from a liquid‐ or solid‐state phase transformation. Typically polycrystalline ringwoodite grains have a narrow range of compositions that overlap with those of their olivine precursors, whereas the formation of iron‐enriched ringwoodite has been documented from only a handful of meteorites. Here, we report backscattered electron images, quantitative wavelength‐dispersive spectrometry (WDS) analyses, qualitative WDS elemental X‐ray maps, and micro‐Raman spectra that reveal the presence of Fe‐rich ringwoodite (Fa_44‐63) as fine‐grained (500 nm), polycrystalline rims on olivine (Fa_24‐25) wall rock and as clasts engulfed by shock melt in a previously unstudied L5 chondrite, Dhofar 1970. Crystallization of majorite + magnesiowüstite in the vein interior and metastable mineral assemblages within 35 μm of the vein margin attest to rapid crystallization of a superheated shock melt (>2300 K) from 20─25 GPa to ambient pressure and temperature. The texture and composition of bright polycrystalline ringwoodite rims (Fa_44‐63; MnO 0.01─0.08 wt%) surrounding dark polycrystalline olivine (Fa_8‐14; MnO 0.56─0.65 wt%) implies a solid‐state transformation mechanism in which Fe was preferentially partitioned to ringwoodite. The spatial association between ringwoodite and shock melt suggests that the rapidly fluctuating thermal regimes experienced by chondritic minerals in contact with shock melt are necessary to both drive phase transformation but also to prevent back‐transformation.     

Exposure history of lunar meteorites Queen Alexandra Range 93069 and 94269

Abstract— Cosmic-ray produced ¹⁴C (t_1/2 = 5730 years), ³⁶Cl (3.01 × 10⁵ years), ²⁶Al (7.05 × 10⁵ years), and ¹⁰Be (1.5 × 10⁶ years) in the recently discovered lunar meteorites Queen Alexandra Range 93069 (QUE 93069) and 94269 (QUE 94269) were measured by accelerator mass spectrometry. The abundance pattern of these four cosmogenic radionuclides and of noble gases indicates QUE 93069 and QUE 94269 were a paired fall and were exposed to cosmic rays near the surface of the Moon for at least several hundred million years before ejection. After the meteorite was launched from the Moon, where it had resided at a depth of 65–80 g/cm², it experienced a short transition time, ～20–50 ka, before colliding with the Earth. The terrestrial age of the meteorite is 5–10 ka. Comparison of the cosmogenic nuclide concentrations in QUE 93069/94269 and MAC 88104/88105 clearly shows that these meteorites were not ejected by a common event from the Moon.     

Constraining the source regions of lunar meteorites using orbital geochemical data

Lunar meteorites provide important new samples of the Moon remote from regions visited by the Apollo and Luna sample return missions. Petrologic and geochemical analysis of these meteorites, combined with orbital remote sensing measurements, have enabled additional discoveries about the composition and age of the lunar surface on a global scale. However, the interpretation of these samples is limited by the fact that we do not know the source region of any individual lunar meteorite. Here, we investigate the link between meteorite and source region on the Moon using the Lunar Prospector gamma ray spectrometer remote sensing data set for the elements Fe, Ti, and Th. The approach has been validated using Apollo and Luna bulk regolith samples, and we have applied it to 48 meteorites excluding paired stones. Our approach is able broadly to differentiate the best compositional matches as potential regions of origin for the various classes of lunar meteorites. Basaltic and intermediate Fe regolith breccia meteorites are found to have the best constrained potential launch sites, with some impact breccias and pristine mare basalts also having reasonably well‐defined potential source regions. Launch areas for highland feldspathic meteorites are much less well constrained and the addition of another element, such as Mg, will probably be required to identify potential source regions for these.     

Four lunar mare meteorites: Crystallization trends of pyroxenes and spinels

Abstract— We studied crystallization trends of pyroxene and spinel in four Antarctic meteorites known to be derived from mare regions of the Moon: Y-793169 and A-881757 (YA meteorites) are unbrecciated igneous basalts, EET 87521 is a fragmental breccia, and Y-793274 is a regolith breccia. All have relatively low bulkrock TiO₂ content, and the YA meteorites are uncommonly ancient. Our electron probe microanalysis (EPMA) data indicate that the YA meteorites and the dominant mare components of Y-793274 and EET 87521 conform to a general trend for Ti-poor (low-Ti and very low-Ti) mare basalts. Their pyroxenes show a strong correlation between Fe/(Fe + Mg) (Fe#) and Ti/(Ti + Cr) (Ti#), both ratios typically increasing from core to rim. These trends presumably reflect local crystallization differentiation of interstitial melt. Previous studies (M. J. Drake and coworkers) have suggested that the detailed configurations of such Fe# vs. Ti# trends may reflect the bulk TiO₂ contents of the parent magmas (basalts). As a more systematic approach to this problem, we plot bulk-rock TiO₂ as a function of the Fe# = 0.50 intercept of each rock's pyroxene Fe# vs. Ti# trend. We call this intercept the Fe#-normalized Ti#. Based on our data for EET 87521, the YA meteorites, and Apollo 12 basalts 12031 and 12064, plus literature data for several other Ti-poor mare basalts, we find a strong correlation between Fe#-normalized Ti# and the bulk TiO₂ content of the parent basalt. This correlation confirms that fragmental breccia EET 87521 is nearly pure very low-Ti (VLT) basalt and that the YA meteorites, for which bulk-rock TiO₂ results scatter due to unusually coarse grain size (A-881757) or scarcity of available sample (Y-793169), are pieces of an uncommonly Ti-poor, but not quite VLT, variety of low-Ti mare basalt. Extrapolating from this correlation, the dominant mare component of regolith breccia Y-793274 is probably of VLT affinity. Besides the normal mare pyroxene trend of strong correlation between Fe# and Ti#, Y-793274 includes two additional pyroxene compositional trends, both showing a wide range of Ti# despite relatively constant (and low, by mare standards) Fe#. The most magnesian of these trends consists of a single clast with a mode of orthopyroxene + MgO-rich ilmenite. These two trends are of uncertain origin. Possibly one or both represents the highland component of this regolith breccia, although, unlike most highland pyroxenes, these appear relatively unaltered by impact brecciation and metamorphism. Compositions of spinels in the coarse-grained A-881757 show an extraordinary distribution: chromite and ulvöspinel components vary among grains but are nearly constant within grains. Despite its old age and unusually coarse grain sizes, mineralogical evidence (i.e., heterogeneity within both pyroxene and spinel; typical pyroxene exsolution scale very coarse by mare standards but exceeded by the pyroxenes of EET 87521 and Y-793274) indicates that A-881757 was cooled only slightly more slowly than typical mare basalts and may have formed near the center of an uncommonly thick lava flow. Both of the VLT basaltic lunar meteorite breccias, EET 87521 and Y-793274, are composed dominantly of pyroxenes with exsolution coarser than normal for mare basalts. Possibly VLT basalt flows tend to be systematically thicker, and thus more slowly cooled, than more Ti-rich flows.     

Relationship between positive cerium anomaly and adsorbed water in Antarctic lunar meteorites

Abstract— Concentrations of adsorbed water in single mineral grains of Antarctic lunar meteorites were determined with micro infrared (IR) spectroscopy. A relationship was found between the mineral's ability to adsorb water and the extent of Ce anomaly in rare earth element (REE) patterns precisely determined by the isotope dilution method using a thermal ionization mass spectrometer. Asuka (A) 881757, a lunar meteorite from the mare basalt without Ce anomaly, showed no trace of IR absorption due to adsorbed water. On the contrary, Yamato (Y) 791197-109, Y-86032-98, Y-86032-95, Y-791197-115 and Y-82192-55A from the lunar highland exhibiting positive Ce anomaly showed IR absorption due to adsorbed water in some of their minerals. The detected water would be of terrestrial origin, because it was not structurally bound and easy to exchange judging from the spectral band shape. The contrast in concentration of adsorbed water between the lunar highland and the mare basalt is derived from a difference in the density of microfractures in mineral grains. Average concentrations of adsorbed water in the lunar highland meteorites were 3.8 mg/cm³ for pyroxene and olivine, and 1.7 mg/cm³ for plagioclase. This contrast between minerals is noteworthy because it has been known that Ce anomaly of pyroxene and olivine is larger than that of plagioclase both for Antarctic lunar meteorites and some lunar rocks. Furthermore, more adsorbed water was detected for minerals in meteorites that exhibit larger Ce anomaly. The present observations demonstrate that the extent of Ce anomaly correlated with the concentration of adsorbed water, which suggests that active mineral surface resulting in adsorption of water could be a trace of interaction forming Ce anomaly. Terrestrial weathering on Antarctica and REE fractionation on the Moon are discussed for possible origins of the Ce anomaly.     

The lithologic diversity of the Moon recorded in lunar meteorites Northwest Africa 7611 and 10480

Northwest Africa (NWA) 7611/10480 are lunar regolith breccia meteorites, composed of mineral fragments and various clasts including mare basalts, volcanic glasses, gabbroic lithologies, and a diverse variety of highland materials (ferroan anorthosite, Mg-suite, magnesian anorthosite, and alkali suite rocks) as well as different subvarieties of impact melt breccia. The Apollo two-component mixing model calculation reveals that the NWA 7611 source region contains 58 wt% mare materials and 42 wt% highland components, but the estimated mare components in NWA 10480 have a higher abundance (66 wt%). The predominantly very low-Ti (VLT) composition in both fine-grained basaltic and coarse-grained gabbroic lithologies indicates a provenance associated with a thick lava flow or a single magmatic system. The co-occurrence of zoning patterns and fine-scale exsolution lamellae in pyroxene debris supports a cryptomare deposit as the best candidate source. Phosphate Pb–Pb ages in matrix fragments, impact melt breccia, and basaltic clast indicate that the breccia NWA 7611 records geological events spanning approximately 4305–3769 Ma, which is consistent with the ages of ancient lunar VLT volcanism and the products of basin-forming impacts on the lunar nearside. The youngest reset age at ~3.2 Ga is potentially related to the strong shock lithification process of breccia NWA 7611. Moreover, the similar petrology, texture, geochemistry, cosmic-ray exposure data, and crystallization ages support that basaltic component in Yamato (Y)-793274, and Queen Alexandra Range (QUE) 94281, NWA 4884, and NWA 7611 clan came from the same basalt flow.