The rocks of Mars,from far and near

Abstract— The age, structure, composition, and petrogenesis of the martian lithosphere have been constrained by spacecraft imagery and remote sensing. How well do martian meteorites conform to expectations derived from this geologic context? Both data sets indicate a thick, extensive igneous crust formed very early in the planet's history. The composition of the ancient crust is predominantly basaltic, possibly andesitic in part, with sediments derived from volcanic rocks. Later plume eruptions produced igneous centers like Tharsis, the composition of which cannot be determined because of spectral obscuration by dust. Martian meteorites (except Allan Hills 84001) are inferred to have come from volcanic flows in Tharsis or Elysium, and thus are not petrologically representative of most of the martian surface. Remote‐sensing measurements cannot verify the fractional crystallization and assimilation that have been documented in meteorites, but subsurface magmatic processes are consistent with orbital imagery indicating thick crust and large, complex magma chambers beneath Tharsis volcanoes. Meteorite ejection ages are difficult to reconcile with plausible impact histories for Mars, and oversampling of young terrains suggests either that only coherent igneous rocks can survive the ejection process or that older surfaces cannot transmit the required shock waves. The mean density and moment of inertia calculated from spacecraft data are roughly consistent with the proportions and compositions of mantle and core estimated from martian meteorites. Thermal models predicting the absence of crustal recycling, and the chronology of the planetary magnetic field agree with conclusions from radiogenic isotopes and paleomagnetism in martian meteorites. However, lack of vigorous mantle convection, as inferred from meteorite geochemistry, seems inconsistent with their derivation from the Tharsis or Elysium plumes. Geological and meteoritic data provide conflicting information on the planet's volatile inventory and degassing history, but are apparently being reconciled in favor of a periodically wet Mars. Spacecraft measurements suggesting that rocks have been chemically weathered and have interacted with recycled saline groundwater are confirmed by weathering products and stable isotope fractionations in martian meteorites.     

Quantitative compositional analysis of martian mafic regions using the MEx/OMEGA reflectance data: 2. Petrological implications

The primary objectives of this paper are to determine the modal mineralogy of selected low albedo terrains of different ages ranging from Noachian to Amazonian exposed on the surface of Mars. This analysis is conducted using the spectral modeling of the Observatoire pour la Minéralogie, l'Eau, les Glaces, et l'Activité (OMEGA) reflectance data. Results from this work are consistent with the major results of previous spectroscopic studies: plagioclase (40-60% in volume) and high calcium pyroxene (20-40%, HCP) are the dominant minerals of the most regions. Low calcium pyroxene (10-15%, LCP) and minor amounts of olivine are also present. The oldest terrains are characterized by the largest amount of LCP and the lowest concentration of plagioclase. These overall compositions are consistent with two-pyroxene basalts. The particle sizes are in the range of a few hundreds of micrometers, which is in good agreement with the thermal inertia of the martian low albedo regions. In the region around the Nili Fossae, localized concentrations of olivine up to 40% with millimeter particle size similar to picritic basalts observed in situ by the Spirit rover in the Gusev crater are inferred. Chemical compositions are calculated for the first time from OMEGA spectra. They are quite consistent with Gusev rocks and shergottite compositions but they appear to be significantly SiO₂-poorer than Thermal Emission Spectrometer data. A decreasing low calcium pyroxene abundance with the decreasing age of the low albedo regions is reported. This may be indicative of decreasing degree of partial melting as thermal flux decreases with time. We propose that the ancient Noachian-aged, LCP-rich terrains could have been formed from H₂O-bearing melts. Then, dry, basaltic volcanism occurred leading to decreasing LCP abundance with time due to decreasing degree of partial melting. The olivine-bearing material modeled in Nili Fossae resembles the composition of ALH77005 and Chassigny meteorites consistent with prior studies. Implications on the formation of the basaltic Shergottites are discussed.     

Spectroscopic analysis of Martian meteorite Allan Hills 84001 powder and applications for spectral identification of minerals and other soil components on Mars

Abstract— Spectroscopic measurement and analysis of Martian meteorites provide important information about the mineralogy of Mars, as well as necessary ground-truths for deconvolving remote sensing spectra of the Martian surface rocks. The spectroscopic properties of particulate ALH 84001 from 0.3 to 25 μm correctly identify low-Ca pyroxene as the dominant mineralogy. Absorption bands due to electronic transitions of ferrous iron are observed at 0.94 and 1.97 μm that are typical for low-Ca pyroxene. A strong, broad water band is observed near 3 μm that is characteristic of the water band typically associated with pyroxenes. Weaker features near 4.8, 5.2 and 6.2 μm are characteristic of particulate low-Ca pyroxene and can be distinguished readily from the features due to high-Ca pyroxene and other silicate minerals. The reflectance minimum occurs near 8.6 μm for the ALH 84001 powder, which is more consistent with high-Ca pyroxene and augite than low-Ca pyroxene. The dominant mid-infrared (IR) spectral features for the ALH 84001 powder are observed near 9 and 19.5 μm; however, there are multiple features in this region. These mid-IR features are generally characteristic of low-Ca pyroxene but cannot be explained by low-Ca pyroxene alone. Spectral features from 2.5–5 μm are typically associated with water, organics and carbonates and have been studied in spectra of the ALH 84001, split 92 powder and ALH 84001, splits 92 and 271 chip surfaces. Weak features have been identified near 3.5 and 4 μm that are assigned to organic material and carbonates. Another feature is observed at 4.27 μm in many surface spots and in the powder but has not yet been uniquely identified. Spectroscopic identification of minor organic and carbonate components in this probable piece of Mars suggests that detection of small amounts of organics and carbonates in the Martian surface regolith would also be possible using visible-infrared hyperspectral analyses. Laboratory spectroscopic analysis of Martian meteorites provides a unique opportunity to identify the spectral features of minerals and other components while they are embedded in their natural medium.     

Micro Raman spectroscopy of amphiboles and pyroxenes in the martian meteorites Zagami and Lewis Cliff 88516

Abstract— We studied micro Raman spectroscopy of amphiboles and pyroxenes in the martian meteorites Zagami and Lewis Cliff (LEW) 88516. The obtained Raman spectra of the amphiboles are similar to those of kaersutite, reconfirming the previous studies that they are kaersutitic amphiboles enriched in Ca, Al, and Ti. Even though actinolite belongs to the same amphibole group (calcic amphibole) as kaersutite, the Raman spectra of terrestrial actinolite are distinct from those of kaersutite, probably reflecting complex amphibole crystal structures. The Al‐Ti‐rich pyroxene observed in the magmatic inclusions within LEW 88516 olivine is compositionally similar to kaersutite but shows Raman spectra nearly identical to the regular pyroxene rather than amphibole. In contrast to amphibole, this will be due to relatively simple crystal structures of pyroxene. Thus, the Raman spectra of Al‐Ti‐rich phases in the martian meteorites are distinct between kaersutite and Al‐Ti‐rich pyroxene, and this study demonstrates that micro Raman spectroscopy is one of the best tools to perform mineralogical characterization of mineral phases in martian meteorites.     

What we have learned about Mars from SNC meteorites

Abstract— The SNC meteorites are thought to be igneous martian rocks, based on their young crystallization ages and a close match between the composition of gases implanted in them during shock and the atmosphere of Mars. A related meteorite, ALH84001, may be older and thus may represent ancient martian crust. These petrologically diverse basalts and ultramafic rocks are mostly cumulates, but their parent magmas share geochemical and radiogenic isotopic characteristics that suggest they may have formed by remelting the same mantle source region at different times. Information and inferences about martian geology drawn from these samples include the following: Planetary differentiation occurred early at ～4.5 Ga, probably concurrently with accretion. The martian mantle contains different abundances of moderately volatile and siderophile elements and is more Fe-rich than that of the Earth, which has implications for its mineralogy, density, and origin. The estimated core composition has a S abundance near the threshold value for inner core solidification. The former presence of a core dynamo may be suggested by remanent magnetization in SNC meteorites, although these rocks may have been magnetized during shock. The mineralogy of martian surface units, inferred from reflectance spectra, matches that of basaltic shergottites, but SNC lithologies thought to have crystallized in the subsurface are not presently recognized. The rheological properties of martian magmas are more accurately derived from these meteorites than from observations of martian flow morphology, although the sampled range of magma compositions is limited. Estimates of planetary water abundance and the amount of outgassed water based on these meteorites are contradictory but overlap estimates based on geological observations and atmospheric measurements. Stable isotope measurements indicate that the martian hydrosphere experienced only limited exchange with the lithosphere, but it is in isotopic equilibrium with the atmosphere and has been since 1.3 Ga. The isotopically heavy atmosphere/hydrosphere composition deduced from these rocks reflects a loss process more severe than current atmospheric evolution models, and the occurrence of carbonates in SNC meteorites suggests that they, rather than scapolite or hydrous carbonates, are the major crustal sink for CO₂. Weathering products in SNC meteorites support the idea of limited alteration of the lithosphere by small volumes of saline, CO₂-bearing water. Atmospheric composition and evolution are further constrained by noble gases in these meteorites, although Xe and Kr isotopes suggest different origins for the atmosphere. Planetary ejection of these rocks has promoted an advance in the understanding of impact physics, which has been accomplished by a model involving spallation during large cratering events. Ejection of all the SNC meteorites (except ALH84001) in one or two events may provide a plausible solution to most constraints imposed by chronology, geochemistry, and cosmic ray exposure, although problems remain with this scenario; ALH84001 may represent older martian crust sampled during a separate impact.     

NIR spectral trends of HED meteorites: Can we discriminate between the magmatic evolution, mechanical mixing and observation geometry effects?

The Howardite–Eucrite–Diogenite (HED) suite is a family of differentiated meteorites that provide a unique opportunity to study the differentiation of small bodies. The likely parent-body of this meteorite group, (4) Vesta is presently under study by the Dawn mission, scrutinizing its surface in the visible and NIR infrared range. Here, we discuss how well the magmatic trends observed in HED might be retrieved from NIR spectroscopy, by studying laboratory spectra of 10 HED meteorites together with spectra from the RELAB database. We show that although an exsolution process did occur for most eucrites (i.e. decomposition of a primary calcic pyroxene into a high-Ca and low-Ca pyroxene), it does not affect the “bulk pyroxene” trend retrieved from the location of the pyroxene crystal field bands (Band I with a maximum of absorption around at about 1 μm and Band II around 2 μm). Absolute values of the chemical composition appears however to deviate from the expected chemical composition. We show that mechanical mixture (i.e. impact gardening) will produce a linear mixing in the pyroxenes band position diagram (Band I position vs Band II position). This diagram also reveals that howardite are not pure mixtures of an average eucrite and average diogenite. Because asteroid surfaces are expected to show topography, we also study the effect of observation geometry on the NIR spectra of an eucrite and a diogenite by measuring the bi-directional reflectance spectra from 0.4 to 4.6 μm. Results show that these meteorites tend to act as forward scatterers, leading to a decrease of integrated band area (relative to the continuum) at high phase angles. The position of the two strong crystal field bands shows only small variability with observation geometry. Retrieval of the magmatic trends from the Band I vs Band II diagram should not be affected by observation geometry effects. Finally we performed NIR reflectance measurement on olivine diogenites. The presence of olivine can be suggested by using the Band Area Ratio vs Band I diagram, but this phase might affect the retrieval of pyroxene composition from the position of Band I and Band II.     

Ferric iron in SNC meteorites as determined by Mössbauer spectroscopy: Implications for martian landers and martian oxygen fugacity

Abstract— Mössbauer spectra of martian meteorites are currently of great interest due to the Mössbauer spectrometers on the Athena mission MER rovers as well as the European Space Agency Mars Express mission, with its Beagle 2 payload. Also, considerable current effort is being made to understand the oxygen fugacity of martian magmas because of the effect of fO₂ on mineral chemistry and crystallization processes. For these 2 reasons, the present study was conceived to acquire room temperature Mössbauer spectra of mineral separates and whole rock samples of 10 SNC meteorites. The results suggest that mineral identification using remote application of this technique will be most useful when the phases present have distinctive parameters arising from Fe in very different coordination polyhedra; for example, pyroxene coexisting with olivine can be discriminated easily, but opx versus cpx cannot. The MER goal of using Mössbauer spectroscopy to quantify the relative amounts of individual mineral species present will be difficult to satisfy if silicates are present because the lack of constraints on wt% FeO contents of individual silicate phases present will make modal calculations impossible. The remote Mössbauer spectroscopy will be most advantageous if the rocks analyzed are predominantly oxides with known stoichiometries, though these phases are not present in the SNCs. As for the detection of martian oxygen fugacity, no evidence exists in the SNC samples studied of a relationship between Fe³⁺ content and fO₂ as calculated by independent methods. Possibly, all of the Fe³⁺ observed in olivine is the result of dehydrogenation rather than oxidation, and this process may also be the source of all the Fe³⁺ observed in pyroxene. The observed Fe³⁺ in pyroxene also likely records an equilibrium between pyroxene and melt at such low fO₂ that little or no Fe³⁺ would be expected.     

Formation of a martian pyroxenite: A comparative study of the nakhlite meteorites and Theo's Flow

Abstract— The unusual composition of the nakhlites, a group of pyroxenitic martian meteorites with young ages, presents an opportunity to learn about nonbasaltic magmatic activity on another planet. However, the limited number of these meteorites makes unraveling their history difficult. A promising terrestrial analog for the formation of the nakhlites is Theo's Flow in Ontario, Canada. This atypical, 120 m-thick flow differentiated in place, forming distinct layered lithologies of peridotite, pyroxenite, and gabbro. Theo's pyroxenite and the nakhlites share strikingly similar petrographies, with concentrated euhedral to subhedral augite grains set in a plagioclase-rich matrix. These two suites of rocks also share specific petrologic features, mineral and whole-rock compositional features, and size and spatial distributions of cumulus grains. The numerous similarities suggest that the nakhlites formed by a similar mechanism in a surface lava flow or shallow intrusion. Their formation could have involved settling of crystals in a phenocryst-laden flow or in situ nucleation and growth of pyroxenes in an ultramafic lava flow. The latter case is more likely and requires steady-state nucleation and growth of clusters of pyroxene grains (and olivine in the nakhlites), circulating in a strongly convecting melt pool, followed by settling and continued growth in a thickening cumulate pile. Trapped pockets of intercumulus liquid in the pile gradually evolved, finally growing Fe-enriched rims on cumulus grains. With sufficient evolution, the melt reached plagioclase supersaturation, causing rapid growth of plagioclase sprays and late-stage mesostasis growth.     

The silicate inclusions of the Ocotillo IAB iron meteorite

Abstract— The Ocotillo IAB iron meteorite contains small silicate inclusions consisting of olivine, low-Ca pyroxene, chromian diopside, plagioclase, magnesiochromite, apatite, troilite and metal. The ferromagnesian silicates have a small range of Fe/(Fe + Mg) ratios that are not due to zoning. These phases appear to be not well equilibrated. The FeO content of magnesiochromite is lower than values normally seen in silicate assemblages in IAB iron meteorites. The minerals in Ocotillo are generally like silicate assemblages in other IAB meteorites, covering similar composition ranges and exhibiting a metamorphic (granoblastic) texture. An estimate was made of the bulk composition of Ocotillo silicate inclusions. The bulk composition is close to that of ordinary chondrites with the exception of a deficiency in CaO that might be due to a sampling problem associated with the method used to estimate the bulk composition.     

The content of uranium,thorium, and potassium in the rocks of Venus as measured by Venera 8

A gamma ray spectrometer recording on the surface of Venus from Venera 8 reveals a content of radioactive potassium, uranium, and thorium very similar to acid magmatic rocks on the Earth. Venus is evidently a differentiated planet.     

Destination: Earth. Martian Meteorite Delivery

The delivery dynamics of martian meteorites are examined by means of a direct numerical simulation of their orbital evolution. The dynamics in the martian region are dominated by secular resonant effects, not by close encounters with Mars. These secular effects rapidly (∼1 Myr) transport martian ejecta to Earth-crossing orbits. The measured cosmic-ray exposure ages of the martian meteorites are consistent with their being directly launched as small bodies from the martian surface by impacts over the last ?15 Myr. Collisional effects and being driven into the Sun efficiently destroy martian meteoroids in space on time scales of order 10 Myr. The implications of these results for the launch mechanism and microorganism transport are discussed.     

MINERALOGY,PETROLOGY AND CHEMISTRY OF LUNAR ROCK 12039

Rock 12039 belongs to the olivine-depleted group of magmatic rocks characterized by normative and modal SiO₂, absence or very low abundance of olivine, and high FeO/(FeO + MgO), Ti/Cr, and CaO/MgO ratios. Clinopyroxenes in this rock show a complex, essentially continuous, compositional zonation from augite cores through ferroaugite to ferrohedenbergite with an abrupt discontinuity at the pyroxferroite contact and, thus, are different from pyroxene in most other Apollo 12 rocks. Two grains contain thin subcalcic pigeonite zones. Texture, presence of very fine (< 1 μm) exsolution lamallae, and pyroxene zoning indicate a relatively rapid cooling history and pronounced in situ chemical fractionation. Rock 12039, on the basis of mineralogy and bulk composition, is the most highly differentiated member of the olivine-depleted basalt group     

ELEMENTAL COMPOSITIONS OF MAJOR SILICIC PHASES IN CHONDRULES OF UNEQUILIBRATED CHONDRITIC METEORITES

Elemental compositions of olivine, low-Ca pyroxene and mesostasis in chondrules from type-3 ordinary chondrites (OC), CV3, CO3, CM2 and EH3 chondrites were compiled in a search for mineral compositional differences among chondrules of different chondrite groups. Such differences are demonstrated. A few elements occur in silicic phases in amounts proportional to their bulk chondrule concentrations: e.g., Mn in OC chondrules, Ti in CV chondrules, Cr in EH chondrules. However, OC chondrules have higher bulk Cr than CM-CO chondrules, higher Cr in mesostasis, but lower Cr in olivine and low-Ca pyroxene. The higher oxidation state of OC chondrules implies that Cr is more likely to be trivalent, and thus, less likely to enter the olivine crystal structure and more likely to concentrate in pyroxene and mesostasis. CV and OC chondrules have similar high bulk Fe and mesostasis Fe, but OC chondrules have much more FeO in olivine and low-Ca pyroxene. The remaining Fe in CV chondrules is reduced and occurs as metal blebs in the mesostasis. Relative to OC chondrules, EH chondrules have lower bulk Ca, lower Ca in pyroxene and mesostasis, but higher (by a factor of 2) Ca in olivine. EH chondrules may have been incompletely melted, preserving relict refractory lithophile-rich olivine nuclei. OC chondrules are richer than EH chondrules in FeO; they have a lower melting temperature and may have been more completely melted during chondrule formation.     

STUDIES OF BRAZILIAN METEORITES XIV. MINERALOGY,PETROLOGY, AND CHEMISTRY OF THE CONQUISTA,MINAS GERAIS,CHONDRITE

The Conquista chondrite consists of major olivine, low-Ca pyroxene (both ortho- and twinned clino-), troilite and metallic nickel-iron; minor glassy to microcrystalline material and pigeonite; and accessory chromite, high-Ca clinopyroxene and hydrous ferric oxides that formed by terrestrial weathering of metallic nickel-iron. Results of microscopic, electron microprobe, and bulk chemical studies, particularly the compositions of olivine (Fa_17.2) and low-Ca pyroxene (Fs_15.4); the contents of metallic nickel-iron (18.5%) and total iron (25.83%); and the ratios of Fe°/Fe_total (0.64), Fe°/Ni° (9.59) and Fe_total/SiO₂ (0.69) indicate H-group classification. The pronounced, well-developed chondritic texture; the slight compositional variations in constituent phases; the high Ca contents of pyroxene and the presence of pigeonite, glassy to microcrystalline interstitial material rich in alkalis and SiO₂, and of twinned low-Ca clinopyroxene suggest that Conquista is of petrologic type 4.     

Lea County 001, an H5 chondrite,and Lea County 002, an ungrouped type 3 chondrite

Abstract— A search of active deflation basins near Jal, Lea County, New Mexico resulted in the discovery of two meteorites, Lea County 001 and 002. Lea County 001 has mean olivine and low-Ca pyroxene compositions of Fa₁₉ and Fs₁₇, respectively. These and all other mineralogical and petrological data collected indicate a classification of H5 for this stone. Lea County 002 has mean olivine and low-Ca pyroxene compositions of Fa₂ and Fs₄, and is unequilibrated. Although it is mineralogically most similar to Kakangari and chondritic clasts within Cumberland Falls, the high modal amount of forsterite makes Lea County a unique type 3 chondrite. Oxygen isotope data for Lea County 002 fall on an ¹⁶O-mixing line through those of the enstatite meteorites and IAB irons, a feature shared by Kakangari.     

Mineralogy and cooling history of the calcium-aluminum-chromium enriched ureilite,Lewis Cliff 88774

Abstract— The LEW 88774 ureilite is extraordinarily rich in Ca, Al, and Cr, and mineralogically quite different from other ureilites in that it consists mainly of exsolved pyroxene, olivine, Cr-rich spinel, and C. The presence of coarse exsolved pyroxene in LEW 88774 is unique because pyroxene in most other ureilites is not exsolved. The pyroxene has bulk Wo contents of 15–20 mol% and has coarse exsolution lamellae of augite and low-Ca pyroxene, 50 μm in width. The compositions of the exsolved augite (Ca_33.7Mg_52.8Fe_13.5) and host low-Ca pyroxene (Ca_4.4Mg₇₅Fe_20.6) show that these exsolution lamellae were equilibrated at 1280 °C. A computer simulation of the cooling rate, obtained by solving the diffusion equation for reproducing the diffusion profile of CaO across the lamellae, suggests that the pyroxene was cooled at 0.01 °C/year until the temperature reached 1160 °C. This cooling rate corresponds to a depth of at least 1 km in the parent body, assuming it was covered by a rock-like material. Therefore, LEW 88774 was held at this high temperature for 1.2 × 10⁴years. The proposed cooling history is consistent with that of other ureilites with coarsegrained unexsolved pigeonites. Lewis Cliff 88774 includes abundant Cr-rich spinel in comparison with other ureilites. The range of FeO content of spinels in LEW 88774 is from 1.3 wt% to 21 wt% [Fe/(Fe + Mg) = 0.04–0.6]. The Cr-rich and Fe-poor spinel in LEW 88774 has less Fe (FeO, 1.3 wt%) than spinels in other achondrites. We classify this spinel as an Fe, Al-bearing picrochromite. Most ureilites are depleted in Ca and Al, but this meteorite has high-Ca and Al concentrations. In this respect, as well as mineral assemblage and the presence of coarse exsolution lamellae in pyroxene, LEW 88774 is a unique ureilite. Most differentiated meteorites are poor in volatile elements such as Zn, but the LEW 88774 spinels contain abundant Zn (up to 0.6 wt%). We note that such a high Zn concentration in spinel has been observed in the carbonaceous chondrites and recrystallized chondrites. This unusual ureilite has more primitive characteristics than most other ureilites.     

Martian meteorite Dhofar 019: A new shergottite

Abstract— Dhofar 019 is a new martian meteorite found in the desert of Oman. In texture, mineralogy, and major and trace element chemistry, this meteorite is classified as a basaltic shergottite. Olivine megacrysts are set within a groundmass composed of finer grained olivine, pyroxene (pigeonite and augite), and maskelynite. Minor phases are chromite‐ulvöspinel, ilmenite, silica, K‐rich feldspar, merrillite, chlorapatite, and pyrrhotite. Secondary phases of terrestrial origin include calcite, gypsum, celestite, Fe hydroxides, and smectite. Dhofar 019 is most similar to the Elephant Moraine (EETA) 79001 lithology A and Dar al Gani (DaG) 476/489 shergottites. The main features that distinguish Dhofar 019 from other shergottites are lack of orthopyroxene; lower Ni contents of olivine; the heaviest oxygen‐isotopic bulk composition; and larger compositional ranges for olivine, maskelynite, and spinel, as well as a wide range for pyroxenes. The large compositional ranges of the minerals are indicative of relatively rapid crystallization. Modeling of olivine chemical zonations yield minimum cooling rates of 0.5‐0.8 °C/h. Spinel chemistry suggests that crystallization took place under one of the most reduced conditions for martian meteorites, at an fO₂ 3 log units below the quartz‐fayalite‐magnetite (QFM) buffer. The olivine megacrysts are heterogeneously distributed in the rock. Crystal size distribution analysis suggests that they constitute a population formed under steady‐state conditions of nucleation and growth, although a few grains may be cumulates. The parent melt is thought to have been derived from partial melting of a light rare earth element‐ and platinum group element‐depleted mantle source. Shergottites, EETA79001 lithology A, DaG 476/489, and Dhofar 019, although of different ages, comprise a particular type of martian rocks. Such rocks could have formed from chemically similar source(s) and parent melt(s), with their bulk compositions affected by olivine accumulation.     

Ordinary (mesostasis) and not‐so‐ordinary (symplectites) late‐stage assemblages in howardites

Abstract– Two categories of symplectites have been observed in howardites: three‐phase, composed of vermicular intergrowths of ferroan augite, fayalitic olivine, and silica, and two‐phase, composed of vermicular intergrowths of orthopyroxene and troilite. Three‐phase symplectites have been previously shown to represent the breakdown products of metastable pyroxene. In howardites, they appear to be genetically related to gabbroic eucrites. In some cases and under yet‐to‐be specified conditions, ferroan clinopyroxene in gabbroic eucrites may undergo only localized decomposition resulting in oriented exsolution‐like features. Breakdown phases in those cases are fayalitic olivine, silica, and—depending on the MgO content of the system—orthopyroxene. As opposed to three‐phase symplectites, two‐phase symplectites are most likely of diogenitic origin. They probably formed via impact‐induced localized melting of diogenitic orthopyroxene in the presence of troilite (grain boundary melting). Three‐phase symplectites in howardites occasionally contain accessory amounts of ilmenite, troilite, and/or kamacite and are exclusively associated with medium‐grained FeO‐rich pyroxene, silica, and plagioclase. All minerals involved are late‐stage crystallites or mesostasis phases. In general, highly evolved eucritic lithologies constitute only a minor fraction of howardites. However, considering that three‐phase symplectites are generated in a low‐pressure, i.e., near‐surface, environment, FeO‐ and CaO‐rich eucritic rocks may be exposed locally on Vesta’s surface. This, in turn, is highly relevant to the ongoing DAWN mission.     

A Study on the Recovery and Classification of Meteorites from the Mt. Grove Region of Antarctica

The Antarctic Continent has become the largest natural preservatory of meteorites in the world because of its unique geographical position and climatic conditions. Mt. Grove is located in the inland area of the Antarctic Continent where the conditions are favorable for the preservation of meteorites. During China's 15th, 16th and 19th Antarctic Scientific Explorations a large number of meteorites were recovered in the Mt. Grove region. Especially during the 19th Exploration in 2002/03 a total of 4448 meteorites were recovered, which at one stroke put China among countries that have recovered most numbers of meteorites. Here, we report mainly the results of microscope and electron microprobe studies of 28 meteorites recovered during the 16th Exploration. The meteorites are chemically classified based on their mean Fa contents of olivine, mean Fs contents of low-Ca pyroxene and abundances of Fe-Ni metal. We also give a brief account of the meteorite recovery during the three Explorations and of some preli     

Melting in the martian mantle: Shergottite formation and implications for present‐day mantle convection on Mars

Abstract— Radiometric age dating of the shergottite meteorites and cratering studies of lava flows in Tharsis and Elysium both demonstrate that volcanic activity has occurred on Mars in the geologically recent past. This implies that adiabatic decompression melting and upwelling convective flow in the mantle remains important on Mars at present. I present a series of numerical simulations of mantle convection and magma generation on Mars. These models test the effects of the total radioactive heating budget and of the partitioning of radioactivity between crust and mantle on the production of magma. In these models, melting is restricted to the heads of hot mantle plumes that rise from the core‐mantle boundary, consistent with the spatially localized distribution of recent volcanism on Mars. For magma production to occur on present‐day Mars, the minimum average radioactive heating rate in the martian mantle is 1.6 times 10^?12 W/kg, which corresponds to 39% of the Wanke and Dreibus (1994) radioactivity abundance. If the mantle heating rate is lower than this, the mean mantle temperature is low, and the mantle plumes experience large amounts of cooling as they rise from the base of the mantle to the surface and are, thus, unable to melt. Models with mantle radioactive heating rates of 1.8 to 2.1 times 10 ^?12 W/kg can satisfy both the present‐day volcanic resurfacing rate on Mars and the typical melt fraction observed in the shergottites. This corresponds to 43–50% of the Wanke and Dreibus radioactivity remaining in the mantle, which is geochemically reasonable for a 50 km thick crust formed by about 10% partial melting. Plausible changes to either the assumed solidus temperature or to the assumed core‐mantle boundary temperature would require a larger amount of mantle radioactivity to permit present‐day magmatism. These heating rates are slightly higher than inferred for the nakhlite source region and significantly higher than inferred from depleted shergottites such as QUE 94201. The geophysical estimate of mantle radioactivity inferred here is a global average value, while values inferred from the martian meteorites are for particular points in the martian mantle. Evidently, the martian mantle has several isotopically distinct compositions, possibly including a radioactively enriched source that has not yet been sampled by the martian meteorites. The minimum mantle heating rate corresponds to a minimum thermal Rayleigh number of 2 times 10⁶, implying that mantle convection remains moderately vigorous on present‐day Mars. The basic convective pattern on Mars appears to have been stable for most of martian history, which has prevented the mantle flow from destroying the isotopic heterogeneity.