Focused groundwater discharge of phosphorus to a eutrophic seepage lake (Lake Væng, Denmark): implications for lake ecological state and restoration

A study on Lake Væng in Denmark demonstrates a high potential for loading of phosphorous via groundwater to seepage lakes. Groundwater discharges are displayed as an important source of phosphorous to a lake due to: (1) high concentrations in the aquifer just below the lake, and (2) the main flow paths through the aquifer–lakebed interface either being overland flow through a seepage face, or focused in zones with very high discharge rates. In-lake springs have measured discharge of up to 7.45 m³ per m² of lakebed per day. These findings were based on seepage meter measurements at 18 locations, stable isotope (δ¹⁸O) analyses, temperature profiles and mapping of ice cover distribution. Groundwater–lake interaction was modelled with a 2D conceptual flow model (MODFLOW) with hydrogeology interpreted from catchment multi electrode profiling, on-lake ground-penetrating radar, well logging and borehole data. Discharge was found to be much focused and opposite to expected increase away from the shoreline. The average total phosphorus concentration in discharging groundwater sampled just beneath the lakebed was 0.162 mg TP/l and thereby well over freshwater ecological thresholds (0.043–0.612, median = 0.117 mg TP/l). The study illustrates a direct link between groundwater and lake chemistry.     

The Holocene record of Alberca de Tacámbaro,a tropical lake in western Mexico: evidence of orbital and millennial-scale climatic variability

Laminated sediments in a core from Alberca de Tacámbaro, western central Mexico, provide a high-resolution record of palaeoclimatic variability for most of the Holocene. Using compositional and textural characteristics we identified 14 facies classified in biogenic, clastic and volcaniclastic groups, in which diatoms and other algal remains are the most common components. In addition to facies analysis, high-resolution geochemical data from continuous core scanning XRF and the analysis of discrete samples for organic and inorganic carbon content, provide the basis for palaeoclimatic reconstruction. The age model indicates that the record spans from 9.4 cal ka bp toad 1760. Three main phases in the sequence are identified, controlled by millennial-scale variability. During the period between 9.4 and 5.7 cal kabp , the lake is dominated by siliceous organisms. Drier conditions between 8.2 and 6.3 cal kabp are linked to decreases in summer insolation and solar irradiance. By 5.7 cal kabp , the change in sedimentation is related to the increase in El Niño Southern Oscillation frequency. Evidence of the occurrence of dry conditions during the archaeological Late Classic period (ad 600–900) and historical droughts are also documented in the Alberca de Tacámbaro record. Unprecedented changes in the landscape are recorded afterad 1520.     

Lake Müggelsee —the use of lake water and its consequences

Lake Müggelsee (Groer Müggelsee) — the largest lake in the area of Berlin — is the main drinking water reservoir for Berlin (East), but also a center of numerous recreational activities and fishing. The use of the lake and its catchment area has continuously increase during the past decase and has caused a substantail deterioration of the lake water quality. Mass development of algae has become a limiting factor to all future utilizations of the lake. Since the beginning of this century up to the seventies the lake water has shown signs of a permanently growing eutrophication, e.g. the content of particulate matter in the lake water has nearly doubled. During and after World War II the lake quality (Secchi depth and seston content) improved remarkably due to a reduced input of nutrients.According to time series analyses of buoyant seston and meterologica elements the development of blue-green algae seems to depend more on weather conditions than on the nutrient content of the lake water.Therefore, a certain probability of blue-green algae blooms will remain, also in the case of reduced nutrient input. Phosphorous is the main cause for eutrophication. It was responsible for distinctly higher mass developments of algae during spring and autumn in the past two decades. As a consequence, comprehensive measures are to be taken to reduce phosphorus inputs into the Spree river and lake Müggelsee, e.g. by the substitution of P in detergents, construction of tertiary sewage treatment plants and a substantially reduced application of fertilizers in agriculture.     

Contrasting Ordovician high- and low-pressure metamorphism related to a microcontinent-arc collision in the Eastern Cordillera of Perú (Tarma province)

High-pressure conditions of 11–13 kbar/500–540 °C during maximum burial were derived for garnet amphibolite in the Tapo Ultramafic Massif in the Eastern Cordillera of Peru using a PT pseudosection approach. A Sm–Nd mineral-whole rock isochron at 465 ± 24 Ma dates fluid influx at peak temperatures of ∼600 °C and the peak of high pressure metamorphism in a rodingite of this ultramafic complex. The Tapo Ultramafic Complex is interpreted as a relic of oceanic crust which was subducted and exhumed in a collision zone along a suture. It was buried under a metamorphic geotherm of 12–13 °C/km during collision of the Paracas microcontinent with an Ordovician arc in the Peruvian Eastern Cordillera. The Ordovician arc is represented by the western Marañon Complex. Here, low PT conditions at 2.4–2.6 kbar, 300–330 °C were estimated for a phyllite–greenschist assemblage representing a contrasting metamorphic geotherm of 32–40 °C/km characteristic for a magmatic arc environment.     

Micropaleontological record of Holocene estuarine stages in the Bahía Blanca estuary,Argentina

Holocene paleoenvironmental changes have been interpreted on the basis of benthic foraminifera and calcareous nannofossils recovered in samples from Napostá Grande Stream, Bahía Blanca estuary, southern Buenos Aires Province. Samples are fine sands and clay sediments from a Holocene outcrop and were studied with quantitative techniques. The benthic foraminiferal assemblage is dominated by Ammonia parkinsoniana, Ammonia tepida, Bolivina pseudoplicata, Bolivina striatula, Bolivina sp., Buccella peruviana, and Elphidium spp. The calcareous nannofossil assemblage recovered is a typical cold-water association, dominated by Calcidiscus leptoporus, Coccolithus pelagicus, Emiliana huxleyi and Gephyrocapsa oceanica. A dendrogram classification by cluster analysis was made for each microfossil group. The results of these analyses were coincident, showing a liaison between changes in the assemblages of benthic foraminifera and calcareous nannofossils. Those results, jointly with the sedimentological information, lead to the identification of three different paleoenvironments along the Napostá N1 site. The lower part of the succession represents an estuarine environment with larger marine connection. The middle part represents a gradual passage to a more restricted estuarine environment, and the upper part represents the establishment of the modern continental fresh-water environment.     

Middle Miocene vertebrates from the Amazonian Madre de Dios Subandean Zone,Perú

A new middle Miocene vertebrate fauna from Peruvian Amazonia is described. It yields the marsupials Sipalocyon sp. (Hathliacynidae) and Marmosa (Micoureus) cf. laventica (Didelphidae), as well as an unidentified glyptodontine xenarthran and the rodents Guiomys sp. (Caviidae), “Scleromys” sp., cf. quadrangulatus-schurmanni-colombianus (Dinomyidae), an unidentified acaremyid, and cf. Microsteiromys sp. (Erethizontidae). Apatite Fission Track provides a detrital age (17.1 ± 2.4 Ma) for the locality, slightly older than its inferred biochronological age (Colloncuran-early Laventan South American Land Mammal Ages: ∼15.6–13.0 Ma). Put together, both the mammalian assemblage and lithology of the fossil-bearing level point to a mixture of tropical rainforest environment and more open habitats under a monsoonal-like tropical climate. The fully fluvial origin of the concerned sedimentary sequence suggests that the Amazonian Madre de Dios Subandean Zone was not part of the Pebas mega-wetland System by middle Miocene times. This new assemblage seems to reveal a previously undocumented “spatiotemporal transition” between the late early Miocene assemblages from high latitudes (Patagonia and Southern Chile) and the late middle Miocene faunas of low latitudes (Colombia, Perú, Venezuela, and ?Brazil).     

Occurrence and spatial distribution of metals in intertidal sediments of a temperate estuarine system (Bahía Blanca,Argentina)

Intertidal sediments of the inner and middle zone from the Bahía Blanca estuary were sampled for geochemical and environmental assessment of metals (Cd, Cu, Pb, Zn, Mn, Ni, Cr and Fe). Results indicate that both the organic matter content and the sediment grain size plays an important role in controlling the differential concentrations of the metals found in sediments from both zones. For most of the elements (except Mn), sediment metal concentrations were greater in the middle zone, although the concentrations did not exceed the maximums for quality of marine sediments. In this sense, anthropogenic impact (i.e., sewage drain) appears to be a key factor in the distribution of metals within the estuarine system. Comparing the levels obtained with quality levels (LEL and SEL), except Cu that showed levels slightly above the LEL, the rest of the concentrations of metals were lower to those levels. The low metal concentrations obtained within this highly impacted estuarine system suggest that the great volume of water that flooding the extensive flats in each tidal cycle has much importance. Although the potential risks of metals to the estuarine environment were low, taking into account the toxicity of some of these metals, continuity of monitoring is highly recommended.     

Behaviour of REE during weathering of granite in a tropical climate

Weathering is essentially a leaching process and thus, one way of determining the extent of weathering is to monitor the mobility of different elements. Rate of loss of elements in a weathering profile can be determined by comparing the concentrations of …     

Hydrologic Dynamics of a Subtropical Estuary Using Geochemical Tracers,Celestún,Yucatan, Mexico

Oxygen isotopes and strontium concentrations were used as geochemical tracers to discern the sources of water to Celestún Lagoon, a small subtropical estuary on the western side of the Yucatán Peninsula of Mexico. Celestún Lagoon is underlain by karstified limestone with numerous locations where groundwater is observed discharging directly to the lagoon. In this study, samples of groundwater, lagoon surface water, and seawater (SW) were collected in April 2008 and June 2009 and analyzed for salinity, stable isotopes of oxygen, and strontium (Sr²⁺) concentrations. These geochemical tracers were used in two tertiary mixing models to calculate the relative ratio inputs of fresh groundwater, brackish groundwater, and SW to the lagoon. Two sources of groundwater were found to contribute to the surface water in the lagoon; one fresh and the other brackish with an average salinity of 19 psu. The fresh groundwater had an oxygen isotopic signature (δ¹⁸O) and strontium concentration (Sr²⁺) of δ¹⁸O?=?-3.30‰ and Sr²⁺?=?0.03 mmol/l, respectively. The brackish groundwater observed in the northern end of the lagoon add a dissimilar oxygen isotopic signature and Sr²⁺ concentration of δ¹⁸O?=?3.01‰ and Sr²⁺?=?0.12 mmol/l, respectively. Local SW had an isotopic oxygen signature and Sr²⁺ concentration between the two fresher sources (δ¹⁸O?=?1.40‰, Sr²⁺?=?0.09 mmol/l). The lagoonwide results of the two tracer mixing models (δ¹⁸O and Sr²⁺) agreed well (within 5 %) and indicated a ratio of brackish groundwater–fresh groundwater– SW of 31 %–26 %–43 % (±5 %) for the Sr²⁺ model and 35 %–25 %–40 % (± 5 %) for the δ¹⁸O model. Brackish groundwater is dominant in the northern portion of the lagoon, while SW dominates the southern portion. Fresh groundwater discharge is a significant contributor of water along the entire eastern boundary of the lagoon where mangrove forests are the dominant vegetation.     

Sorption and desorption of mercury(II) in saline and alkaline soils of Bahía Blanca, Argentina

The objective of this work was to study sorption–desorption and/or precipitation–dissolution processes of Hg(II) compounds considering an eventual contact of soils with Hg-bearing wastes. In addition, this study contributes new data about Hg(II) chemistry in alkaline systems. Saline and alkaline soils with low organic matter (<1 %) and high clay content (60–70 %) were obtained near a chlor-alkali plant. Batch techniques were used to perform the experiments using 0.1 M NaNO₃ solutions. Total Hg(II) concentrations ranged from 6.2 × 10^?8 to 6.3 × 10^?3 M. Sorption of Hg(II) was evaluated at two concentration ranges: (a) 6.2 × 10^?8 to 1.1 × 10^?4 M, and (b) 6.4 × 10^?4 to 6.3 × 10^?3 M. At low Hg(II) concentrations, adsorption occurred with a maximum sorption capacity ranging from 4 to 5 mmol/kg. At high Hg(II) concentrations, sorption–precipitation reactions occurred and maximum sorption capacity ranged from 17 to 31 mmol/kg. The distribution of Hg(II) hydrolysis products showed that Hg(OH)₂ was the predominant species under soil conditions. According to sorption experiments, X-ray diffraction and chemical speciation modelling, the presence of Hg(OH)₂ in the interlayer of the interstratified clay minerals can be proposed. Hg(OH)₂ was partially desorbed by repeated equilibrations in 0.1 M NaNO₃ solution. Desorption ranged from 0.1 to 0.9 mmol/kg for soils treated with 5.8 × 10^?5 M Hg(II), whereas 2.1–3.8 mmol/kg was desorbed from soils treated with 6.3 × 10^?3 M Hg(II). Formation of soluble Hg(II) complexes was limited by low organic matter content, whereas neutral Hg(OH)₂ was retained by adsorption on clay mineral surfaces.     

Quaternary Lake Deposits of Nam Co, Tibet, with a Discussion of the Connection of Nam Co with Ring Co-Jiuru Co

Shorelines are widespread and lake deposits and lake geomorphology are well developed on the northern Tibetan Plateau. Through field observations of lacustrine deposits of Nam Co-the highest and largest Quaternary lake in Tibet, the authors found four-step shore terraces composed of sands and clays with well-developed horizontal bedding and 3-12 m, 15-22 m, 25-30 m and 35-45 m higher than the lake surface respectively, lacustrine deposits resting on the bedrocks and 60-150 m higher than the lake surface, and up to -50 levees composed of oblate lakeshore gravels. Moreover they found lacustrine and lakeshore deposits making up the terraces and levees on the bottoms of wide dividing valleys connecting Nam Co with the Rencoyuema, Rencogongma and Jiuru Co northwest of Nam Co (the valley bottoms are 20 m, 90 m and 60 m higher than the above-mentioned three lakes) and on slopes north of it, i.e. terraces II and III of Nam Co. Thus they confirm that Nam Co and Ring Co-Jiuru Co had connected with each other seve     

Structural and biological control of the Cenozoic epithermal uranium concentrations from the Sierra Pe?a Blanca, Mexico

Epithermal uranium deposits of the Sierra Pe?a Blanca are classic examples of volcanic-hosted deposits and have been used as natural analogs for radionuclide migration in volcanic settings. We present a new genetic model that incorporates both geochemical and tectonic features of these deposits, including one of the few documented cases of a geochemical signature of biogenic reducing conditions favoring uranium mineralization in an epithermal deposit. Four tectono-magmatic faulting events affected the volcanic pile. Uranium occurrences are associated with breccia zones at the intersection of fault systems. Periodic reactivation of these structures associated with Basin and Range and Rio Grande tectonic events resulted in the mobilization of U and other elements by meteoric fluids heated by geothermal activity. Focused along breccia zones, these fluids precipitated under reducing conditions several generations of pyrite and uraninite together with kaolinite. Oxygen isotopic data indicate a low formation temperature of uraninite, 45–55°C for the uraninite from the ore body and ～20°C for late uraninite hosted by the underlying conglomerate. There is geochemical evidence for biological activity being at the origin of these reducing conditions, as shown by low δ³⁴S values (～?24.5‰) in pyrites and the presence of low δ¹³C (～?24‰) values in microbial patches intimately associated with uraninite. These data show that tectonic activity coupled with microbial activity can play a major role in the formation of epithermal uranium deposits in unusual near-surface environments.     

Kinetics of metal ion sorption on lake sediments — approaches to the analysis of experimental data

Two different mathematical techniques have been used to analyse data obtained from a set of experiments in which a range of radiotracers were sorbed onto two contrasting lake sediments. The advantages and disadvantages of the two techniques have been evaluated. Both approaches to the analysis were capable of providing rate parameters which can be used to determine the mobility and rate of removal of trace species from the water column. However, the values of the parameters were often different, depending upon which approach was used and, in some cases, even the number of sorption processes identified was method dependent.     

Temporal and Spatial Distribution of Elements in a Small Catchment, and Buffer Function of Wetland in Longgan Lake, China

Wetland is the conjunction of lake and terrene where human activities are concentrated. From the viewpoints of material transport and cycling in the terrene-lake system, wetland is the buffer where sand and mud, heavy metals, pollutants and nutrients are tarried. In this paper, we provide a case study based on the temporal and spatial distribution of elements in the Wangling River catchment, a small sub-catchment of Longgan Lake in the middle reaches of the Yangtze River. We have found that wetland can buffer major heavy metals such as Cr, Cu, etc.significantly, but has a little buffer function to some active elements such as Fe and Mn, which are always transported as solutions. Human activities not only influence the distribution of elements, but also weaken the buffer function of wetland. Intensive human activities in the Longgan Lake area in the past 70 years have been recorded in stream, wetland and lake sediments, especially the human activity events such as deforesting and reclaiming on a large scale in 1958 and the 1980‘s. Human activities caused the increase of sedimentation rates since the 1950‘ s, as well as the increase of elements‘ concentrations. The extensive use of fertilizers and pesticides since the 1960‘ s have led to the increase of total P concentrations. Increasing SO2 emission accelerate the process of cation exchange in soil, and enhance the leaching of Mn out of soils. Permanent storing of water causes the soil gleyification that also intensifies the leaching of Mn.These are two major reasons for the obvious increase of manganese concentrations in recent 20 years in Longgan Lake. Intensive human activities since the 1950s‘ have intensified the population in this region and thus destroyed the buffer function of wetland.     

Weathering and climate change since l820 AD in Hoh Xil, Qinghai-Xizang Plateau, China——Evidence from element geochemistry of lake sediments of Gulug Co Lake

Element geochemistry of lake sediments has been widely used to detect climate change because element composition and ratios can reflect the weathering degree in the source area. Given the dement composition of lake sediments from Gulug Co Lake, Hoh Xil, Qing- hai-Xizang Plateau, chemical index of alteration （CIA）, index of composition variability （ICV） and other element ratios have been used to establish the weathering sequence of this area since 1820 AD. The weathering is so weak that the element composition change is more sensitive to climate change and autochthonous processes. From 1820 to 1984 AD, there were two drier periods with a wetter interval from 1870 to 1945 AD. After 1984 the weather showed a tendency of becoming wet.     

Impacts of European settlement (1840–present) in a Great Lake watershed and lagoon: Frenchman’s Bay, Lake Ontario, Canada

The northern shore of Lake Ontario is one of the longest settled parts of Canada beginning around 1795. Accelerated settlement and deforestation after 1840 resulted in massive soil loss from easily-eroded Pleistocene glacial landscapes and the siltation of creeks and lagoons. Channel capacity was reduced but river flow was enhanced by diminished infiltration resulting in straightening of meandering channels, accelerated erosion of stream banks, increased incidence of downstream flooding and large influxes of mud to Lake Ontario. Conservation measures after World War II were successful but rapid urban sprawl after 1970 hardened watersheds and badly impacted the quality and quantity of surface and ground waters flowing to Lake Ontario. The Frenchman’s Bay watershed (27 km²) 50 km east of Toronto is one of the country’s most urbanized (pop: 100,000; 76 % urban cover) and is crossed by Canada’s busiest highway (Highway 401). The watershed drains to Lake Ontario through a coastal lagoon (Frenchman’s Bay) in which pre-settlement postglacial carbonate is abruptly overlain by a ‘European settlement’ mud layer rich in weed pollen and organic debris; the uppermost ‘urban’ part of this deposit shows elevated level of metals and other contaminants. This layer records soil loss after 1840 and more recently, the influx of contaminated urban waters and sediment. Some 7,600 tonnes of road salt have been applied to the lagoon watershed each year producing spikes of brackish surface runoff during winter thaws. Some 50 % of the total salt applied to the entire watershed is conveyed directly to Frenchman’s Bay Lagoon via surface runoff; the rest enters the groundwater system resulting in year-round brackish baseflow to creeks. Chloride continues to be stored in underlying aquifers such that the system has yet to reach a steady-state discharge. Future salinity of baseflow reaching the lagoon can be expected to increase by about 40 %. Rapid migration of contaminated groundwater is facilitated by the widespread presence of thick (<8 m) coarse-grained and heterogeneous fill materials of the built landscape. The watershed is experiencing ongoing changes in land use as urban infilling proceeds. The aquatic ecology of inflowing creeks to the lagoon has been greatly impacted resulting in major loss of wetlands and submergent vegetation and distinct changes in the structure of fish populations. This is the most detailed study of an urban watershed in Canada; lack of knowledge elsewhere is a constraint on the design and testing of mitigation measures and is a major impediment to assessing the impact of ongoing climate change on urban water resources, and the effects of urban runoff on Great Lakes water quality.     

Stability analysis and remedial measures of a landslip at Keifang,Mizoram – a case study

Landslips are often triggered due to non-engineered excavation of potential unstable slopes. Such slips can be stabilized by implementing suitable remedial measures.A landslip occurred at a drilling site of Oil India Limited in Mizoram State due to slope excavation. There was an immediate concern to protect the slope as the drilling platform and the highway at the top of the slope are at risk if further landslide occurs in future. Slope stability analysis of the failed slope was carried out to design suitable control measures for the protection of the slope from further sliding. Slope stability using various methods indicated that the slope is marginally stable. To improve the stability of the slope, suitable retaining structure at the toe of the slope was suggested and designed. Stability analysis performed with inclusion of retaining wall showed a significant increase in factor of safety of the slope. The suggested remedial measure has been implemented at the site and there is no landslip reported since then. The paper presents the results of the slope stability analysis and the design details of the retaining structure prescribed as the protection measure.     

Investigation of water quality on Gökçekaya dam lake using multivariate statistical analysis,in Eskişehir,Turkey

Gökçekaya Dam is one of the dams located on the Sakarya River (Eski?ehir) in Turkey and is approximately 38 years old. No study regarding to the water quality of the dam lake has been hitherto made. This study aimed at determining the seasonal variations with physical, chemical, and biological parameters of the water quality of the dam lake. Depth-wise water samples were taken from five selected stations, in seasonal periods during 2005–2008, and anlayzed. The quality of water was classified in accordance with the results and taking into consideration many parameters. At the same time, number and type diversities of dissolved heavy metals and algae population were analyzed. Using principal component analysis (PCA) and classification analysis (CA) methods, differences between these parameters and samples from stations have been determined . The analysis showed that Gökçekaya dam lake, formerly an oligotrophic lake, has become a mesotrophic lake. And according to the results thereof the Lake has mezotrophic characteristics due to the sudden changes (including household waste water inflow and opening the Sar?yar dam lake shutters) in certain periods and in some stations. Hierarchical clustering analysis, revealed no significant difference between the measured parameters. And according to the Water Pollution Control Regulations in Turkey (WPCR) Gökçekaya dam lake is in the first class quality in terms of anions, cations, heavy metals, temperature, and pH values. However, the is of first class quality presence of nitrite reduces the water quality in the lake and causes this lake to be classified in the fourth class quality.