http://www.sciencedirect.com/science/article/pii/S1674987112001533

The collision of a divergent ocean ridge may evolve into two end cases:in the continuity of ocean-floor subduction.or in the detachment of the subducted plate.The northern Patagonia active plate margin has the unique situation that in Cenozoic time it has been subjected to two divergent ridge collisions,each one representing one of the end members.The Neogene Antarctica-Nazca divergent ridge collision evolved as a continuous ocean-floor subduction system,promoting a magmatic hiatus at the arc axis,the obduction of part of the ridge ocean-floor in the fore-arc.and basaltic volcanism in the back-arc.In contrast,the Paleogene Farallon-Aluk divergent ridge collision evolved into a transform margin,with the detachment and sinking of the Aluk plate and the development of a large slab window.As in the previous case,this collision promoted a magmatic hiatus at the arc axis,but the tectono-magmatic scenario changed to postorogenic synextensional volcanism that spread to the former fore-arc（basalt,andesite,rhyolite） and former back-arc（bimodal ignimbrite flare-up,basalt）.Geochemistry of this slab window synextensional volcanism shows more MORB-like basalts towards the former fore-arc,and MORB-OIB-like basalts towards the former back-arc.Instead,an isolated undeformable crustal block in the former back-arc,with an "epeirogenic" response to the slab window and extensional regime,was covered by OIB-type basalts after uplift.Major elements show that slab window basalts reach TiCh values up to 3 wt%,as compared with the top value of 1.5 wt%of arc magmas.Besides,the MgO with respect to（FeO^t + Al₂O₃） ratio helps to distinguish slab window magma changes from the former fore-arc to the former back-arc and also with respect to the "epeirogenic" block.Higher contents of HFS elements such as Nb and Ta also help to distinguish this slab window from arc magmas and also,to distinguish slab window magma changes from the former fore-arc to the former back-arc and "epeirogenic" block settings.The isotope compositions of slab window magmatism show a disparate coeval array from MORB to crustal sources,interpreted as a consequence of the lack of protracted storage and homogenization due to the extensional setting.     

Two-dimensional simulations of surface deformation caused by slab detachment

Detachment of the deeper part of subducted lithosphere causes changes in a subduction zone system which may be observed on the Earth's surface. Constraints on the expected magnitudes of these surface effects can aid in the interpretation of geological observations near convergent plate margins where detachment is expected. In this study, we quantify surface deformation caused by detachment of subducted lithosphere. We determine the range of displacement magnitudes which can be associated with slab detachment using numerical models. The lithospheric plates in our models have an effective elastic thickness, which provides an upper bound for rapid processes, like slab detachment, to the surface deformation of lithosphere with a more realistic rheology. The surface topography which develops during subduction is compared with the topography shortly after detachment is imposed. Subduction with a non-migrating trench system followed by detachment leads to a maximum surface uplift of 2–6 km, while this may be higher for the case of roll-back preceding detachment. In the latter situation, the back-arc basin may experience a phase of compression after detachment. Within the context of our elastic model, the surface uplift resulting from slab detachment is sensitive to the depth of detachment, a change in friction on the subduction fault during detachment and viscous stresses generated by sinking of the detached part of the slab. Overall, surface uplift of these magnitudes is not diagnostic of slab detachment since variations during ongoing subduction may result in similar vertical surface displacements.     

Geochemical and isotopic variability in lavas from the eastern Trans-Mexican Volcanic Belt: Slab detachment in a subduction zone with varying dip

Strong compositional variations are observed in the late-Miocene to Quaternary volcanic rocks of the eastern Trans-Mexican Volcanic Belt. Geochemical and isotopic analyses of samples well constrained in age indicate an abrupt change in magma composition in the late-Miocene (∼ 7.5 Ma), when calc-alkaline, subduction-related magmatism was replaced by mafic, alkaline, OIB-like volcanism. Afterwards, volcanism migrated toward the trench and the erupted lavas showed increasing contributions of subduction components reflected in higher Th/Nb, La/Sm(n), Ba/Nb, and Ba/Th ratios. Lavas from volcanic fields located closer to the trench show clearer, although strongly variable, arc signatures as well as evidence of subducted sediment contributions. Farther from the trench, only lavas emplaced in late-Pliocene time appear to be slightly modified by subduction components, whereas the youngest Quaternary lavas can be regarded as intraplate lavas modified by crustal assimilation.The sudden change in magma composition in the late-Miocene is related to detachment of the subducting slab, which allowed the infiltration of enriched asthenospheric mantle into the mantle wedge. After detachment, the subducting plate started to increase its dip because of the loss of slab pull. This caused (1) the migration of the arc toward the trench, (2) convection of enriched asthenosphere into the mantle wedge, and (3) an increasing contribution of slab components to the melts, in a process that resulted in a highly heterogeneous source mantle. The variable contribution of subduction-related components to the magmas is controlled by the heterogeneous character of the source, the depth of the subducting plate, and the previous magmatic history of the areas.     

Rapid magmatic processes accompany arc–continent collision: the Western Bismarck arc, Papua New Guinea

New U–Th–Ra, major and trace element, and Sr–Nd–Pb isotope data are presented for young lavas from the New Britain and Western Bismarck arcs in Papua New Guinea. New Britain is an oceanic arc, whereas the latter is the site of an arc–continent collision. Building on a recent study of the Manus Basin, contrasts between the two arcs are used to evaluate the processes and timescales of magma generation accompanying arc–continent collision and possible slab detachment. All three suites share many attributes characteristic of arc lavas that can be ascribed to the addition of a regionally uniform subduction component derived from the subducting altered oceanic crust and sediment followed by dynamic melting of the modified mantle. However, the Western Bismarck arc lavas diverge from the Pb isotope mixing array formed by the New Britain and the Manus Basin lavas toward elevated ²⁰⁸Pb/²⁰⁴Pb. We interpret this to reflect a second and subsequent addition of sediment melt at crustal depth during collision. ²³⁸U and ²²⁶Ra excesses are preserved in all of the lavas and are greatest in the Western Bismarck arc. High-Mg andesites with high Sr/Y ratios in the westernmost arc are attributed to recent shallow mantle flux melting at the slab edge. Data for two historical rhyolites are also presented. Although these rhyolites formed in quite different tectonic settings and display different geochemical and isotopic compositions, both formed from mafic parents within millennia.     

On island arcs

Older concepts of island arcs, prior to the 1960's, were dominated by the Indonesian model and described in terms of geosynclinal theory, but not altogether fruitfully. Platetectonics theory has given new insights into the genesis, mode of formation, behaviour and ultimate fate of island arcs. Subduction with descent of the lithospheric slab is the governing phenomenon. As the slab descends it contributes directly and indirectly to the formation of a thickened rim (the nascent arc) on the adjacent superposed plate. The direct contribution comes from the upper part of the slab (oceanic crust) and varies progressively in type as the slab sinks more deeply. This results in the island arc series, front to rear, of tholeiitic to calcalkaline to high potash rocks, with concomitant geochemical indices. The indirect contribution stems from the slab's interference with the thermal regime of the intervening mantle and both aids and affects the passage of melts to the surface. A melange of surface and near-surface rocks is piled against the arc edge to form a break in the arc-trench slope and is subject to high pressure metamorphism. As the arc grows in bulk and width, the volcanic axis shifts to the rear. The arc components will then be: trench inner wall—trench slope break—arc trench gap—main volcanic arc. A high temperature metamorphic belt will underly the main arc. Because the hanging slab tends to retreat, and the arc tends to follow, the retroarc area may develop extensional features floored by extrusions from mantle diapirs. The arc will become separated from the nearest continent by a sub-oceanic marginal sea. With further rifting, a remnant arc may be detached from the main arc with an interarc basin between. The subduction zone at this or earlier stage may be choked and flip, with reverse dip, to the other side of the arc. Subsequent retreat consumes the marginal sea so that the arc system re-tracks toward the continent possibly to become accreted to it. Many variables are involved in this general process so that the individual character of arcs is to be expected. Models of continental accretion are not wholly convincing. This, and other primary problems can be solved with more data, but drawn from a wide range of disciplines. In particular, results from experimental geochemistry, seismology and theoretical physics are essential to additional understanding of the major problem, the detailed behaviour of the slab and its effect within the asthenosphere.     

Cenozoic Island Arc Magmatism in Java Island (Sunda Arc, Indonesia): Clues on Relationships between Geodynamics of Volcanic Centers and Ore Mineralization

Abstract. Java island, regarded as a classic example of island arcs, is built through multi events of Cenozoic arc magmatism produced by the subduction of Indian‐Australian oceanic crusts along the southern margin of Eurasian plate. Regional crustal compositions, subducted slabs, and tectonics determined the spatial‐geochemical evolution of arc magmatism and regional metallogeny. Tertiary geodynamics of island arc was dominated by backarc‐ward migrations of volcanic centers. Only after the Miocene‐Pliocene roll‐back effects of retreating slab, slab detachment, and backarc magmatism took place in central Java. The source of arc magmas is mainly partial melting of mantle wedge, triggered by fluids released from dehydrated slabs. Increasing potassium contents of arc magmas towards the backarc‐side and younger magmas is typical for all magmas, while alkali and incompatible trace elements ratios are characteristics for different settings of volcanic centers. The oceanic nature of crust and the likely presence of hot slab subducted beneath the eastern Java determine the occurrences of adakitic magmas. Backarc magmatism has a deeper mantle source with or without contributions from subduction‐related materials. The domination of magnetite‐series magmatism determines the sulfide mineralization for the whole island. District geology, geodynamics, and magma compositions in turn control particular styles and scales of precious metals concentrations. Deep‐seated crustal faults have focused the locations of overlapping volcanic centers and metalliferous fluids into few major gold districts. Porphyry deposits are mostly concentrated within Lower Tertiary (early stage) volcanic centers in eastern Java which are not covered by younger volcanic centers, and whose sulfides are derived from partial melting of basaltic parental materials. On the other hand, high‐grade low‐sulfidation epithermal gold deposits formed in later stages of arc development and are spatially located within younger volcanic centers (Upper Miocene‐Pliocene) that overlap the older ones. Gold in low‐sulfidation epithermal system is likely to be derived from crustal materials. The overall interacting factors resulting in the petrochemical systematics that are applicable for exploration: 1) early‐stage volcanic centers with high Sr/Y and Na₂O/K₂O ratios are more prospective for porphyry mineralization, while 2) later‐stage volcanic centers with high K₂O, total alkali, and K₂O/Na₂O ratios are more prospective for low‐sulfidation epithermal mineralization.     

Local and regional variations in Central American arc lavas controlled by variations in subducted sediment input

The sedimentary section (at DSDP Site 495) on the subducting Cocos Plate has large stratigraphic changes in incompatible elements and element ratios, the result of early carbonate deposition followed by late hemipelagic deposition. Lavas from Central America define both local and regional geochemical trends that reflect the strong influence of the two Cocos Plate sediment units. Element ratios with large stratigraphic variations on the Cocos Plate (e.g. Ba/Th, U/La) define local variations within individual volcanic centers in Central America, indicating that marine stratigraphy controls some geochemical characteristics of the lavas. These local trends can be explained by changing the proportions of hemipelagic sediment input into the magma generation process. These local trends are observed in all the segments of the arc, regardless of the intensity of the slab signature. Regional variations are most clearly seen in element ratios that are nearly constant through the Cocos Plate sediment stratigraphy (e.g. Ba/La, U/Th), suggesting that regional variations reflect differences in the intensity of the flux from the subducting slab. The slab signal is strongest in Nicaragua and along the volcanic front. The signal decreases to the northwest and southeast of Nicaragua and toward the back arc. The large slab signature in the lavas from western Nicaragua occurs in the area with the thinnest continental crust and steepest dip of the slab. The mass flux of incompatible elements into the system is easily estimated, except for elements, like Pb, that have high and variable abundances in the basaltic oceanic crust section. The mass flux of elements out of the system depends on eruption rates, which are variable along the arc and only approximately known. Comparison of input and output fluxes for five different segments of the arc reveals that some elements (K, B, Cs, and Rb) are very efficiently delivered to the volcanoes from the subducted slab. Other elements (Sr, Ba, and U) are returned to the surface with moderate efficiency, whereas some elements (REEs) may come mostly from the mantle wedge with minor slab contribution. The relative order of recycling efficiencies of incompatible elements implies that a hydrous fluid dominates the transfer of material from the slab to mantle. Received: 7 September 1998 / Accepted: 30 September 1999     

Role of back-arc tectonics in the origin of subduction magmas: new Sr,Nd, and Pb isotope data from Middle Miocene lavas of Kunashir Island (Kurile Island Arc)

Sr, Nd, and Pb isotope data for basaltic rocks of different ages from Kunashir Island (southern Kurile island arc) provide clues to investigate the subduction magmatic history. Signatures of a high-temperature slab component (melt and/or supercritical liquid produced by melting of slab sediments) involved in Early Miocene–Pleistocene back-arc basaltic magmatism indicate a relatively hot (> 800 °C) slab surface. Depleted isotope characteristics of Holocene basaltic lavas in both volcanic front and back arc indicate their origin with the participation of a cold aqueous fluid produced by dehydration of altered oceanic crust of the Pacific MORB type. The difference in geological, geochemical and isotope patterns in the Pleistocene and the Holocene lavas may be a response to stress change from extension to compression in the Kurile back-arc basin and the Kurile arc.     

Spatial gaps in arc volcanism: The effect of collision or subduction of oceanic plateaus

One of the major processes in the formation and deformation of continental lithosphere is the process of arc volcanism. The plate-tectonic theory predicts that a continuous chain of arc volcanoes lies parallel to any continuous subduction zone. However, the map pattern of active volcanoes shows at least 24 areas where there are major spatial gaps in the volcanic chains (> 200 km). A significant proportion (~ 30%) of oceanic crust is subducted at these gaps. All but three of these gaps coincide with the collision or subduction of a large aseismic plateau or ridge.The idea that the collision of such features may have a major tectonic impact on the arc lithosphere, including cessation of volcanism, is not new. However, it is not clear how the collision or subduction of an oceanic plateau perturbs the system to the extent of inhibiting arc volcanism. Three main factors necessary for arc volcanism are (1) source materials for the volcanics—either volatiles or melt from the subducting slab and/or melt from the overlying asthenospheric wedge, (2) a heat source, either for the dehydration or the melting of the slab, or the melting within the asthenosphere and (3) a favorable state of stress in the overlying lithosphere. The absence of any one of these features may cause a volcanic gap to form.There are several ways in which the collision or subduction of an oceanic plateau may affect arc volcanism. The clearest and most common cases considered are those where the feature completely resists subduction, causing local plate boundaries to reorganize. This includes the formation of new plate-bounding transform faults or a flip in subduction polarity. In these cases, subduction has slowed down or stopped and the lack of source material has created a volcanic gap.There are a few cases, most notably in Peru, Chile, and the Nankai trough, where the dip of subduction is so shallow that effectively no asthenospheric wedge exists to produce source material for volcanism. The shallow dip of the slab may be a buoyant effect of the plateau imbedded in the oceanic lithosphere.The cases which are the most enigmatic are those where subduction is continuous, the oceanic plateau is subducted along with the slab, and the dip of the slab is clearly steep enough to allow arc volcanism; yet a volcanic gap exists. In these areas, the subducted plateau may have a fundamental effect on the physical process of arc volcanism itself. The presence of a large topographic feature on the subducting plate may affect the stress state in the are by increasing the amount of decoupling between the two plates. Alternatively, the subduction of the plateau may change the chemical processes at depth if either the water-rich top of the plateau with accompanying sediments are scraped off during subduction or if the ridge is compositionally different.     

Along-strike variations of P–T conditions in accretionary wedges and syn-orogenic extension,the HP–LT Phyllite–Quartzite Nappe in Crete and the Peloponnese

Syn-orogenic detachments in accretionary wedges make the exhumation of high-pressure and low-temperature metamorphic rocks possible with little erosion. The velocity of exhumation within the subduction channel or the accretionary complex, and thus the shape of P–T paths, depend upon the kinematic boundary conditions. A component of slab retreat tends to open the channel and facilitates the exhumation. We document the effect of slab retreat on the shape of P–T paths using the example of the Phyllite–Quartzite Nappe that has been exhumed below the Cretan syn-orogenic detachment during the Miocene in Crete and the Peloponnese. Data show a clear tendency toward colder conditions at peak pressure and during exhumation where the intensity of slab retreat is larger. This spatial evolution of P–T gradient is accompanied with an evolution from a partly coaxial regime below the Peloponnese section of the detachment toward a clearly non-coaxial regime in Crete.     

Geodynamics of the divergent double subduction along the Bangong-Nujiang tethyan suture zone: Insights from late mesozoic intermediate-mafic rocks in central Tibet

Bangong-Nujiang Suture Zone (BNSZ) in central Tibet plays an important role in evaluating the formation and uplift mechanism of Tibetan Plateau. However, its Mesozoic tectonic evolution is ambiguous and intensely debated. In this study, Early Cretacesous adakites and sodium-rich arc rocks are identified in Western Qiangtang (WQ) and Northern Lhasa (NL) sub-terranes. Forty-four adakite samples from both WQ and NL have akin geochemical features, and are derived from partial melting of subducted oceanic crust with amphibole residual. Nineteen sodium-rich samples originated from a mixed source region between crustal sediment and enriched lithospheric mantle. These two parallel arc belts separated by the Bangong-Nujiang Suture Zone (BNSZ) represent the divergent double subduction of the Bangong-Nujiang Tethyan Ocean (BNTO). Combined with the previous studies, our new data suggest three significant magmatic flare-ups at ∼240–140 Ma, 135–105 Ma and 92–60 Ma in the WQ and BNSZ, and two at 135–105 Ma and 92–60 Ma in the NL. These asymmetrical magmatic activities indicate that the southern subduction may have commenced at about 135 Ma and experienced slab breakoff at the latest Early Cretaceous, and the northern subduction could trace back to L-Triassic (228 Ma) and experienced episodic low-angle subduction, slab rollback (190-140 Ma) and oceanic ridge subduction (135-100 Ma). The 100–92 Ma magmatic gap, 92–60 Ma magmatic flare-up and L-Cretaceous angular unconformities indicate that the double-sided subduction of the BNTO resulted in soft collision with oceanic lithosphere detachment.     

Boron isotopic composition of subduction-zone metamorphic rocks

Many arc lavas contain material derived from subducted oceanic crust and sediments, but it remains unresolved whether this distinctive geochemical signature is transferred from the subducting slab by aqueous fluids, silicate melts, or both. Boron isotopic measurements have the potential to distinguish between slab transfer mechanisms because ¹¹B fractionates preferentially into aqueous fluids whereas little fractionation may occur during partial melting. Previous studies have shown that δ¹¹B values of island arc lavas (−6 to +7) overlap the range of δ¹¹B values for altered oceanic crust (−5 to +25) and pelagic sediments and turbidites (−7 to +11). Secondary ion mass spectrometry (SIMS) analyses of minerals in subduction-zone metamorphic rocks yield δ¹¹B=−11 to −3 suggesting that slab dehydration reactions significantly lower the δ¹¹B values of subducted oceanic crust and sediments. In order to explain the higher δ¹¹B values reported for arc lavas as compared to subduction-zone metamorphic rocks, the B-bearing component derived from the metamorphosed slab must be enriched in ¹¹B relative to the slab, favoring an aqueous fluid as the slab transfer mechanism.     

Single subduction zone for the generation of Devonian ophiolites and high‐P metamorphic belts of the Variscan Orogen (NW Iberia)

Within the Variscan Orogen, Early Devonian and Late Devonian high‐P belts separated by mid‐Devonian ophiolites can be interpreted as having formed in a single subduction zone. Early Devonian convergence nucleated a Laurussia‐dipping subduction zone from an inherited lithospheric neck (peri‐Gondwanan Cambrian back‐arc). Slab‐retreat induced upper plate extension, mantle incursion and lower plate thermal softening, favouring slab‐detachment within the lower plate and diapiric exhumation of deep‐seated rocks through the overlying mantle up to relaminate the upper plate. Upper plate extension produced mid‐Devonian suprasubduction ocean floor spreading (Devonian ophiolites), while further convergence resulted in plate coupling and intraoceanic ophiolite imbrication. Accretion of the remaining Cambrian ocean heralded Late Devonian subduction of inner sections of Gondwana across the same subduction zone and the underthrusting of mainland Gondwana (culmination of NW Iberian allochthonous pile). Oblique convergence favoured lateral plate sliding, and explained the different lateral positions along Gondwana of terranes separated by Palaeozoic ophiolites.     

Carbon sources in arc volcanism, with implications for the carbon cycle

New CO₂/³ He data from the East Sunda Arc (Indonesia) confirm earlier observations that arc volcanic gases have higher CO₂/³ He ratios than MOR environments.On average, > 80% of arc volcanic CO₂ is recycled, exogene carbon. Addition of a few percent of carbonate-bearing sediments to the mantle wedge explains much of the carbon abundance andcarbon isotopic data of arc gases, but can not explain the He isotope observations. The CO₂/³He in arc volcanoes is not strongly dependent on the composition of modem trough sediments (e.g. deep sea clays vs carbonate-rich sequences), and calcite veins in the hydrothermally altered subducted slab may provide a contribution to the recycled carbon flux of, arcs. The sum of globally deep-subducted sediment and slab carbon exceeds the estimated arc CO₂ flux, and approximately 3.5 teramole of carbon may return annually to the mantle in convergent zones. The modem combined processes of MOR volcanism, slab alteration, and subduction volcanism do not produce a substantial carbon flux into the exosphere, and rate-changes in ocean floor spreading are unlikely to cause major changes in atmospheric CO₂ as a result of changes in the volcanic CO₂ fluxes. Intense pulses of flood basalt volcanism, however, may alter the CO₂ contents of the atmosphere over the course of a millenium or so, and influence global climate.     

青藏高原近南北向裂谷的时空分布特征及动力学机制

青藏高原南部发育的一系列近南北向裂谷是印度-欧亚大陆持续挤压作用下的大型伸展构造,也是揭示高原后碰撞构造演化过程的重要对象。目前,关于南北向裂谷的形成机制存在多种假说模型,并对裂谷时空分布特征做出了不同的预测,这成为约束裂谷成因机制的关键条件。综合关于裂谷启动时间的已有研究成果,进一步梳理了南北向裂谷的时空分布特征,结果表明近南北向裂谷的启动时间似乎具有自西向东逐步减小的趋势,这与拉萨地体广泛出露的后碰撞岩浆作用演化过程一致。在此基础上,结合地球物理观测,推断近南北向裂谷的动力学机制与印度板片向东拆离假说最为契合。印度板片自西向东的拆离建立了向东传播的重力势能梯度,从而驱动岩石圈向东流动,最终导致南北向裂谷依次向东发育。      

Slab decarbonation and CO2 recycling in the Southwestern Colombian volcanic arc

The contribution of subducted carbonate sediments to the genesis of the Southwestern Colombian arc magmas was investigated using a comprehensive petrography and geochemical analysis, including determination of major and trace element contents and Sr, Nd, Hf and Pb isotope compositions. These data have been used to constrain the depth of decarbonation in the subducted slab, indicating that the decarbonation process continues into the sub-arc region, and ultimately becomes negligible in the rear arc. We propose on the basis of multi-isotope approach and mass balance calculations, that the most important mechanism to induce the slab decarbonation is the infiltration of chemically reactive aqueous fluids from the altered oceanic crust, which decreasingly metasomatize the mantle wedge, triggering the formation of isotopically different primary magmas from the volcanic front (VF) with relatively high ¹⁷⁶Hf/¹⁷⁷Hf, high ⁸⁷Sr/⁸⁶Sr, negative values of εNd and lower Pb isotopes compared to the rear arc (RA).The presence of more aqueous fluids at the volcanic front may increase the degree of decarbonation into carbonate-bearing lithologies. Moreover, with increasing pressure and temperature in the subduction system, the decrease in dehydration of the slab, leads to cessation of fluid-induced decarbonation reactions at the rear arc. This development allows the remaining carbonate materials to be recycled into the deep mantle.     

南海西部晚中生代岩浆弧:KP1-1-1井碎屑锆石约束

晚中生代是古太平洋板块俯冲和南海北部岩浆弧发育时期,开展珠江口盆地KP1-1-1井钻遇的浅变质砂岩的近源沉积研究有助于揭示岩浆弧源区的构造特点.根据LA-ICPMS碎屑锆石分析,KP1-1-1浅变质砂岩中存在129~155 Ma、155~172 Ma和172~196 Ma三个年龄组分,这一特点与区域上构造岩浆事件一致.碎屑岩浆锆石流体活动性元素富集（如U和Th）,高场强元素亏损（如Nb、Hf和Ti）;元素组成U/Yb（0.34~3.92）、Sc/Yb（0.48~2.28）、Hf/Th（14.4~186.6）和Th/Nb（24.3~462.7）具有大陆岩浆弧特点;计算的锆石Ti温度为551~786℃,表明属于低温弧岩浆作用.碎屑岩中172~196 Ma锆石组分记录了东沙-大仑-雁荡岩浆弧向西南的进一步延伸,与侏罗纪早期古太平洋斜向俯冲到华南陆块之下有关.155~172 Ma岩浆锆石与古板块强烈俯冲有关,对应于华南165~150 Ma大规模花岗质岩浆活动.129~155 Ma时期板块俯冲减弱或俯冲带后撤,可与浙闽同时期板内强烈火山活动对比.碎屑岩中测得最年轻年龄为128.8 Ma,表明KP1-1-1钻遇浅变质砂岩形成时代晚于128 Ma,应属于白垩系,不是传统上认为的下古生界岩系.      

Evidence from the Mesta half-graben, SW Bulgaria, for the Late Eocene beginning of Aegean extension in the Central Balkan Peninsula

The ENE-tilted Mesta half-graben contains a 3-km-thick section of Priabonian (Late Eocene) to Oligocene sedimentary and volcanic rocks that rest unconformably on basement metamorphic rocks along its west side. Basal strata dip 50–60° E and dip at progressively lower angles upward, indicating synrotational deposition. The southern part of the half-graben contains nested volcanic caldera complexes, formed during the deposition of the middle part of the sedimentary sequence, which have been rotated by about half the total rotation of the sedimentary succession. The half-graben is bounded on the east by a fault that steepens from more deeply exposed structural levels in the south (8–18° W) to shallower exposed structural levels in the north (70° W) and together with the rotation of Paleogene strata during deposition indicate the Mesta half-graben is underlain by a listric detachment fault, the Mesta detachment. Subhorizontal Middle Miocene strata that unconformably overlie tilted Paleogene strata yield an upper age limit to the extension. West and northwest of the Mesta half-graben are many other NNW-trending NE-tilted Paleogene half-grabens which we suggest are part of an important extended area in SW Bulgaria and eastern Macedonia that lies above one or more west-dipping detachment faults and date the beginning of Aegean extension in the southern Balkan region as at least as old as Priabonian. The Mesta detachment is oblique to the trend of a contemporaneous Paleogene magmatic arc in the southern Balkans and the origin of the detachment is probably related to gravitationally induced spreading of thickened hot arc crust and Hellenic trench roll back.     

Insights from trace element geochemistry as to the roles of subduction zone geometry and subduction input on the chemistry of arc magmas

Subduction zones of continental, transitional, and oceanic settings, relative to the nature of the overriding plate, are compared in terms of trace element compositions of mafic to intermediate arc rocks, in order to evaluate the relationship between subduction parameters and the presence of subduction fluids. The continental Chilean Southern Volcanic Zone (SVZ) and the transitional to oceanic Central American Volcanic Arc (CAVA) show increasing degrees of melting with increasing involvement of slab fluids, as is typical for hydrous flux melting beneath arc volcanoes. At the SVZ, the central segment with the thinnest continental crust/lithosphere erupted the highest-degree melts from the most depleted sources, similar to the oceanic-like Nicaraguan segment of the CAVA. The northern part of the SVZ, located on the thickest continental crust/lithosphere, exhibits features more similar to Costa Rica situated on the Caribbean Large Igneous Province, with lower degrees of melting from more enriched source materials. The composition of the slab fluids is characteristic for each arc system, with a particularly pronounced enrichment in Pb at the SVZ and in Ba at the CAVA. A direct compositional relationship between the arc rocks and the corresponding marine sediments that are subducted at the trenches clearly shows that the compositional signature of the lavas erupted in the different arcs carries an inherited signal from the subducted sediments.     

俯冲带硫的地球化学行为及硫循环SCIEI北大核心CSCD

俯冲带是全球最大的物质循环系统,控制着硫(S)在地球内部圈层及表层的循环,影响着大气圈、水圈、生物圈、岩石圈的稳定性以及地球的宜居性。厘清S在俯冲带中的地球化学行为和循环特征对理解地球各储库的氧化还原状态、岩浆作用与演化、成矿物质聚集、以及地球大气成分等具有重要意义。本文首先总结了进入俯冲带之前的大洋岩石圈的S结构模型,对S在大洋板片中的分布状态和地球化学特征进行了系统归纳。随后,系统阐述了俯冲带高压-超高压变质岩记录的板片变质及脱水过程中硫的地球化学行为。岩石学研究表明俯冲板片中的S多以硫化物相存在,硫酸盐矿物在弧前深度就已被释放或分解。相较于熔体,俯冲带流体中S的溶解度更高,是运移硫的更有效方式。DEW模型计算结果显示,流体中S含量总体较低,但在俯冲板片~90km处其含量有一个峰值(浓度0.5%~1.0%)。岩相学证据、地球化学测试结果、磷灰石S近边吸收结构(S-XANES)特征以及模拟结果都显示俯冲深部流体中S多以HS^(-)及H_(2)S形式存在,不含大量的SO_(4)^(2-)及硫酸盐;中f_(S_(2))流体有利于S迁移出俯冲板片,从而促进俯冲带大规模S循环,而高f_(S_(2))流体在流-岩交换过程沿流体通道发生S的锁固作用而不利于俯冲带S循环。质量平衡计算显示全球俯冲带S输入通量为4.65×10^(13)g/yr,弧下深度板片S输出通量为2.91×10^(12)g/yr,板片-岛弧S循环效率仅6.3%。俯冲板片在弧下深度可能存在一个短暂高效的S释放窗口,释放流体的δ^(34)S值为-2.1±3.0‰。基于高压-超高压变质岩中硫化物的研究,初步厘清了俯冲板片中S的地球化学行为,首次从板片角度全面、定量地限定了俯冲带的脱硫通量、效率、种型和同位素特征,提出俯冲带循环的S不是岛弧岩浆的氧化剂,与岛弧环境的正δ^(34)S值也无直接因果联系,对解析俯冲带S循环和理解地球长期的S循环具有重要意义。最后,本文还展望了俯冲带S循环的未来发展方向,应在俯冲带流体氧化还原性质(硫酸盐的命运)、俯冲沉积物对S循环的制约、俯冲带环境下多硫同位素的分馏效应、S循环与其它挥发分(如C等)循环之间的耦合关系、地球历史上深部S循环等方向做出探索,更深入地理解俯冲带及全球S循环过程。